APPENDIKS

1.

Menghitung suhu secara teoritis

Persamaan Antoine :
Untuk anilin : A = 16,6748 B = 3857,52 C = -73,15
Untuk air

: A = 18,3036 B = 3816,44 C = -46,13

P operasi = 760 mmHg

P operasi = Poair + Poanilin
ln ()
P

B
A
C +T
B
A
C +T

= exp ()air + exp ()anilin

760 = exp ()air + exp ()anilin 16

18,3036
6748

3816,52
3857
44
73
46,15
13 + T

T = 371 K atau 98 oC
Jadi, T teoritis adalah 98 oC
2.

Menghitung Po Anilin dan Po Air secara teoritis

log Psat = A -

B
Dimana : Psat = tekanan T + C operasi (mmHg)

A, B, C = konstanta komponen
T = temperatur operasi (C)
# Air

A = 7,06252
B = 1650,27
C = 226,346
T

log Psat air

= 98oC

= 7,06252 -

1650,27

226,346 + 98
= 1,974528
Psat air

= 94,3035 mmHg

# Anilin :

A = 6,43196
B = 1722,154
C = 205,082
T

= 98oC

log Psat anilin = 6,43196 -

1722,154
205,082+98

= 0,7498
Psat anilin = 5,621 mmHg
Po Anilin = 5,621 mmHg
Po Air

= 0,0596

94,3035 mmHg

Jadi, perbandingan Po Anilin dan Po Air secara teoritis adalah 0,0596

3.

Menentukan Perbandingan M anilin dan M air secara teoritis

a1 = Po1 * BM anilin = 5,621 * 93 = 0,30796

a2 Po2 * BM air 94,3035 * 18
4.

Menentukan M anilin dan M air dengan percobaan

Menghitung densitas air berdasarkan literatur pada T = 31 oC :
air

= 0,99708

(31-25) * (0,99568-0,99708)
(32-25)

air

= 0,99588 gram/ml

= 1,03 gram/mL

anilin

PIKNOMETER A
m1 + m 2 + m3
3
m1 + m 2 + m3
3

m pikno A kosong rata-rata =

= 12,0361 gram
m (pikno A + aquadest) rata-

rata = = 16,8263 gram

m aquadest = 16,8687 gram 12.0361 gram = 4,8326gram
volume pikno A = massa aquadest = 4,8326gram
air

= 4,8127 ml

0,99588 gram/ml

PIKNOMETER B
m1 + m 2 + m3
3
m1 + m 2 + m3
3

m pikno B kosong rata-rata =

= 9,6912 gram
m (pikno B + aquadest) ratarata = = gram

m aquadest = 16,8687 gram 12.0361 gram = 4,8326gram

volume pikno A = massa aquadest = 4,8326gram
air

= 4,8127 ml

0,99588 gram/ml

DESTILAT 1
LAPISAN ATAS
Massa piknometer A + lapisan atas = 16,8265+16,8266+16,8264 = 16,8265 gram
3
m destilat = m piknometer+lapisan atas -m piknometer
= 16,8265-12,0361 = 4,7904 gram
1 =

m destilat = 4,7904 gram =1,012 gram/ml

v piknometer

4,8127 ml

mlapisan atas = mair + manilin

lapisan atas . Vlapisan atas

= air . Vair + anilin . Vanilin

0.9953

= 0,99588 Vair + 1,03 (43-Vair)

. 43

42,7979

= 44,29 - 0,03412 Vair

Vair

= 37,30 ml

Vanilin

= 43 Vair = 5,7 ml

LAPISAN BAWAH
Massa piknometer B+lapisan bawah = =27,2879 gram
3
m1 m pikno = 272879 17,6546 = 9,6333 gram
1 =

9,6333

= 1,0179 gram/ml

9,46389
m1 = 1 V1 = 1,0179 x 15 = 15,2685 gram
mlapisan bawah = mair + manilin
lapisan bawah . Vlapisan bawah
1,0179 . 15
15,2685

a1 =

= air . Vair + anilin . Vanilin

= 0,99588 Vair + 1,03 (15 - Vair)

= 15,45 - 0,03412 Vair

Vair

= 5,31946 ml

Vanilin

= 15 5,31946 = 9,68054 ml

(2,0428 + 9,68054) *1,03

= 0.13735

a2 (82,9572 + 5,31946) * 0.99588

RUN II
LAPISAN ATAS
Massa piknometer+lapisan atas = 27,1005+27,1005+27,1004 = 27,1005 gram
3
m1 m pikno = 27,1005 17,6546 = 9,4459 gram
1 = 9,4459 = 0,9976 gram/ml
9,469
m1 = 1 V1 = 0,9976 x 83 = 82,8008 gram
mlapisan atas = mair + manilin

lapisan atas . Vlapisan atas

0,9976 . 83
82,8008

= air . Vair + anilin . Vanilin

= 0,99588 Vair + 1,03 (83-Vair)

= 85,49 - 0.03412 Vair

Vair
Vanilin

= 78,8159 ml
= 83 78,8159= 4,1841 ml

LAPISAN BAWAH
Massa piknometer+lapisan bawah = 27,2624+27,2625+27,2624 =27,2624 gram
3
m1 m pikno = 27,2624 17,6546 = 9,6078 gram
1 =

9,6078

= 1,0147 gram/ml

9,469
m1 = 1 V1 = 1.0147 x 17 = 17,2499 gram
mlapisan bawah = mair + manilin
lapisan bawah . Vlapisan bawah
1.0147 . 17
17,2499

= air . Vair + anilin . Vanilin

= 0,99588 Vair + 1,03 (17 - Vair)

= 17,51 - 0,03412 Vair

Vair

= 7,6231 ml

Vanilin

= 17 7,6231 = 9,3769 ml

a1 = (4,1841 + 9,3769) * 1.03

a2

= 0,1622

(78,8159 + 7,6231) *0,99588

RUN III
LAPISAN ATAS
Massa piknometer+lapisan atas = 27,1212+27,1211+27,1210 = 27,1211 gram
3
m1 m pikno I = 27,1211 17,6546 = 9,4665 gram
1 = 9,4665 = 0.9997 gram/ml

9,469
m1 = 1 V1 = 0.9997 x 82 = 81.9754 gram
mlapisan atas = mair + manilin
lapisan atas . Vlapisan atas
0,9997 . 82
81,9754

= air . Vair + anilin . Vanilin

= 0,99588 Vair + 1,03 (82-Vair)

= 84,46 - 0,03412 Vair

Vair

= 72,8195 ml

Vanilin

= 82 72,8195 = 9,1805 ml

LAPISAN BAWAH
Massa piknometer+lapisan bawah = 27,1478+27,2478+27,2479 =27,2478 gram
3
m1 m pikno II = 27,2478 17,6546 = 9,5932 gram
1 =

9,5932 = 1.0131 gram/ml

9,469

m1 = 1 V1 = 1,0131x 18 = 18,2358 gram

mlapisan bawah = mair + manilin
lapisan bawah . Vlapisan bawah
1.0131 . 18
18,2358

= air . Vair + anilin . Vanilin

= 0,99588 Vair + 1,03 (18 - Vair)

= 18,54 - 0,03412 Vair

Vair

= 8,91559 ml

Vanilin

= 18 8,91559 = 9,08441 ml

a1 = (9,1805 + 9,08441) * 1,03

a2

= 0,2311

(72,8195 + 8,91559) * 0,99588

rata rata = 0,13735 + 0,1622 +

3
Jadi, perbandiangan ( M

anilin

/M

air

a1
a2

0,2311 = 0,1769

a1
a2

dari percobaan adalah 0,1769