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Vo Co Qua Cac Ki Thi
Vo Co Qua Cac Ki Thi
M 1
M 8
m(Li)=0,40
m(Na)=0,71
m(K)=0,81
m(Rb)=0,90
m(Cs)=0,94
Kh vo
N2
NH3
O2
HCl
HCl + Cl2
Bi 4 (Phi kim)
3
Cho n tn th k XIX th thuc sng en l vt liu n duy nht m loi ngi c bit. Tri
qua nhiu nm th thuc sng en c dng vo mc ch qun s.
Ngy nay n ch yu c s dng trong k thut biu
din tn hiu (tn hiu tn la, pho hoa) cng nh lm
u n cho cc sng ngn th thao. Thnh phn ca
thuc sng en c th rt khc nhau nhng lun cha
nhng thnh phn c bn: dim tiu (kali nitrat), lu
hunh v than. Tin hnh phn tch ha hc thuc sng
en cho kt qu l 75% dim tiu, 13% cacbon v 12%
lu hunh v khi lng.
a) Vit phn ng th hin s chy ca thuc sng en vi cc thnh phn ny. Cho bit vai tr
ca tng loi nguyn liu.
b) Nu nh thnh phn cc nguyn liu trong thuc sng en c thay i th c th thu c
cc loi sn phm chy no? Minh ha bng phng trnh ha hc.
p n:
a) T l thnh phn cc nguyn liu l KNO3 : C : S = 0,743 : 1,08 : 0,375 = 2 : 3 : 1
iu ny ph hp vi phn ng:
2KNO3 + 3C + S = K2S + N2 + 3CO2
KNO3 l cht oxy ha, S l cht buc (binder) cn C l nguyn liu (cht kh)
b) Cc sn phm khc c th c l: KNO2, SO2, K2CO3; K2SO3; K2SO4
4KNO3 + C + S = 4KNO2 + CO2 + SO2
4KNO3 + 2C + 3S = 2K2CO3 + CO2 + N2
2KNO3 + C + S = K2SO4 + CO2 + N2
4KNO3 + 3C + 2S = 2K2SO3 + 3CO2 + 2N2
b) B = Na3[RhCl6].12H2O
c) C = Rh2S3 . 3H2S
d) loi b cc mui tan (ch yu l NaCl).
e) 2Rh + 6NaCl + 3Cl2 = 2Na3[RhCl6]
Na3[RhCl6].12H2O = Na3[RhCl6] + 12H2O
2Na3[RhCl6] = 2Rh + 6NaCl + 3Cl2
2Na3[RhCl6] + 3H2S = Rh2S3.3H2S + 6NaCl + 6HCl
Bi 7 (Phi kim)
Hydro mi sinh l mt tc nhn kh c hiu qu nht. X l mt lng natri nitrit bng hn hng
natri kim loi cho ra mt mui c 43,38% natri v 26,43% nit v khi lng. Mt sn phm khc
ca phn ng ny l natri hydroxit. trnh s lm bn sn phm cui ny th qu trnh tng hp
c tin hnh trong kh quyn tr nh mi trng nit hay argon
a) Xc nh cng thc mui.
b) V cng thc ba chiu anion ca mui ny.
c) Nu phn ng c tin hnh trong khng kh th s to thnh tp cht no?
d) Vit phng trnh tng hp mui.
e) Tng tc gia mui ny vi cacbon dioxit sinh ra mt cht kh. Vit phng trnh phn ng.
p n:
a) Na2N2O2 natri hyponitrit.
b) Theo l thuyt th anion N2O 22 th c ng phn cis, trans. Thc nghim chng minh
c rng ion ny ch yu dng trans.
1,902 0,8977
162,2
= 1,20mmol
Nh vy b rn cui cng cha (0,01018 3.0,00120) = 6,58 mmol FeOCl v 1,20 mmol
Fe2O3.
8
a) Vit cng thc cc cht ha hc cp trn. Cho bit tn hin i ca cc cht ny.
b) Vit phng trnh cc phn ng ha hc ni trn. Qua cc phn ng ny th ta quan st
c s thay i cc tnh cht vt l no? Gii thch.
c) Ti sao thu tinh nc li nht ?
d) Nh gi kim nh lm g t nhng cht ny? ng dng ca chng ngy nay l g ?
e) Cho bit s khc bit v cu trc v tnh cht ca cht th nht v cht th hai. Gii thch
s khc nhau .
Ch thch:
Ounce, i khi c phin sang ting Vit thnh aox, thng c vit tt l oz, l mt n v o khi lng ca h
o lng Anh, h o lng M. N thng c dng o khi lng ca vng; 1 ounce = 28,3495 gam
p n:
a) Xng cha ch yu Ca3(PO4)2 hay Ca5(PO4)3(OH). Dung dch nht ca vitriol l H2SO4.
Ct ch yu l SiO2. Thu tinh nc l dung dch m c ca natri silicat m c th c
biu din di dng n gin l Na2SiO3.
b) Trc khi vit cc phn ng chng ta phi tnh vi i lng.
T l mol ca H2SO4 so vi Ca3(PO4)2 l 7.310 so vi 11.98 tc xp x 2 : 1.
Do vy phng trnh phn ng l:
2H2SO4 + Ca3(PO4)2 = Ca(H2PO4)2 + 2CaSO4
SiO2 khng phn ng vi hn hp sn phm v c lc ra. Khi thm thu tinh nc vo
th phn ng xy ra nh sau:
3Ca(H2PO4)2 + 3Na2SiO3 = 2Ca3(PO4)2 + 3H2SiO3 + 2Na3PO4
10
11
Bi 11 (Vt liu)
tm ra cc cht siu dn nhit cao th cc nh ha hc phi i mt vi vn lm sao iu
ch c vt liu siu dn nhit thng. Mt nhm hp cht ha hn c trin vng pht
trin thnh cht siu dn nhit cao bao gm cc thnh phn ca ximng ytri, bari v ng.
Cng thc chung ca loi hp cht ny c th c biu din dng YBa 2Cu3Ox. Gi tr ca x dao
ng trong khong 6 7 ph thuc vo iu kin phn ng v thnh phn cc nguyn liu u.
a) Vit cng thc ha hc ca loi ximng ytri-bari-ng trong ton b nguyn t ng
u c s oxy ha +2.
b) S oxy ha ca ng trong YBa2Cu3O7 l bao nhiu?
Gi tr ca x trong mt loi ximng ytri-bari-ng c xc nh t kt qa ca hai th nghim sau:
th nghim th nht th 1,686g mu c ho tan trong axit long.
c) Axit no trong s cc axit clohydric, sunfuric, photphoric, nitric l tt nht? Gii thch.
d) Cho rng thnh phn ca mu l YBa2Cu3O7. Vit phng trnh ion ca phn ng ny.
Dung dch thu c c un si, lm lnh chuyn vo bnh nh mc v pha long n 500mL.
Ly 25,00mL dung dch ny kt hp vi lng d KI ri chun bng dung dch natri thiosunfat
thy tn ht 12,30 mL dung dch chun natri thiosunfat 0,03095M.
e) Ti sao phi un si dung dch trc khi thm kali iodua vo?
f) Vit phng trnh phn ng xy ra trong th nghim trn.
th nghim th hai th ly 0,1054g mu ximng ho tan vo axit long cha mt lung d ion
iodua ri chun thy tn ht 19,28 mL dung dch chun natri thiosunfat 0,03095M.
g) Vit phng trnh phn ng gia YBa2Cu3O7 vi axit long khi c mt lng d iodua.
Gii thch ti sao phi dng d iodua?
h) Da vo kt qa cc th nghim hy cho bit cng thc ca mu ximng.
p n:
a) YBa2Cu3O6,50
b) Mi cng thc cha ba nguyn t ng, hai nguyn t s oxy ha +2, mt nguyn t s
oxy ha +3.
c) Axit nitric l ph hp nht do axit sunfuric phn ng to kt ta BaSO 4, axit clohydric sinh
ra kh clo cn axit photphoric phn ng qu chm.
d) Phn ng: 4YBa2Cu3O7 + 52H+ = 4Y3+ + 8Ba2+ + 12Cu2+ + O2 + 26H2O
12
e) Dung dch phi c un si loi b oxy phn t c th oxy ha iot. Bn cnh vic loi
b oxy th hn hp phn ng cng c cha hydropeoxit c th phn hu bng cch un si.
f) Phn ng
2Cu2+ + 4I
= 2CuI + I2
= 2CuI + 2I2
13
c) L do l s d ly ca V2O5: V2O5 = VO 2 + VO 3
d) VO2 c tnh lng tnh nn pH ca n gn 7.
14
184,8
= 924 g/mol
0,2
924.0,5494
924 200,6 4.126,9
=
4
nguyn
t
iot
v
=
126,9
107,9
15
(vng)
b) Lng kh thot ra khi tin hnh phn ng kh kim loi bng axit nitric l 22,4 = 19,9
117
269
16
8,3
4,1 6,75m
Khng h c bt k mt sn phm no cha nit tho mn phng trnh ny. Tuy nhin
phn ng gia kim loi vi axit nitric cng to ra c mt lng nh hydro. Gi thit ny
th khng lm tri vi bi. tnh t khi ca hn hp sn phm i vi khng kh th
u tin chng ta phi tnh khi lng phn t trung bnh:
=
g/mol.
m
MP
= 0,792 g/L
V
RT
c) Tt c cc sn phm kh u sinh ra bng s kh axit nitric. Cht cho electron duy nht
trong phn ng ny l kim loi:
-
2N+5 + 10e = N2
N+5 + 3e = N+2
2H+ + 2e = H2
3
vy khi lng phn t ca kim loi l: M = 10 82,2 = 12.16 g/mol.
17
Bi 15 (Phi kim)
Khi un nng mt nguyn t A trong khng kh th sinh ra oxit B. Phn ng ca B vi dung dch
kali bromat trong s c mt ca axit nitric cho cc hp cht C, D, v mui E l thnh phn ca
thuc sng en. nhit v p sut tiu chun th D l mt cht lng mu . Hn hp ca C vi
axit clohydric l mt trong s t cc ha cht c th ho tan c kim loi F. Khi xy ra phn ng
ny th sinh ra hp cht B v G v dung dch c mu vng sng.
a) Xc nh cc cht t A n G, bit rng trong G th clo chim 41,77% v khi lng v t
1,00 g B cho 1,306 g ca C. Nu l do.
b) Vit cc phn ng ha hc xy ra trong th nghim.
c) Khi hp cht A c un si vi dung dch Na2SO3 th mt hp cht mi H c hnh
thnh, H cha 15,6% lu hunh v khi lng. Xc nh thnh phn ha hc v cng thc
phn t H.
d) ngh hai cch chuyn kim loi F v dng dung dch. Vit cc phng trnh ha hc
cho cc phn ng tng ng.
p n:
a) Cht lng mu D l brom (Br2), E l kali nitrat (KNO3).
Phn ng gia B vi kali bromat l: B + HNO3 + KBrO3 C + Br2 + KNO3
iu ny cho php ta gi thit rng C l mt hydroxit.
M(H x AO y )
1.x 16.y A
1,306
mC
Nh vy: 1,00
1
1
mB
M(A 2 O z )
(2.A 16z)
2
2
x2
y4
z4
19