B.Sc. (1 Year) Examination. Pre final-2014.

CHEMISTRY Paper-1
Time: 3 hours.
Max.marks:100

Section A (Marks: 410=40)

Answer all questions in about 4 pages each.

Answer all questions serially. Answer any two bits from each question.
1) a) write the preparation and structure of borazine and boron nitride
b) Write about pseudo halogens
c) Define organo metallic compounds. Write the preparation of methyl lithium and methyl
magnesium bromide.
d) Write the applications of Grignard reagent
2) a) explain the Huckel rule
b) Write nitration of benzene with mechanism.
c) Explain the markonkovs & anti markonikovs rule.
d) Write a note on Bayers Strain Theory
3)
a) derive the Vanderwaals equation of real gases. How do the gases deviate from ideal
behavior?
b) Derive Braggs equestion
c) Derive an expression for Longmuir Adsorption Isotherm.
d) Explain the Henrys law. Write its applications.
4) a) what is Dual nature of small particles. Explain the debroglies wave equation.
b) Draw the molecular diagram of O2 and calculate Bond order
c) What are enantiomers and dia stereomers. Explain with examples.
d) Explain bonding and anti bonding Orbitals on the basis of molecular orbital theory.

Section B (Marks: 125=60)

Answer any twelve questions in about 1page each. Each question carries 5
marks.

5) What is Diagonal relationship? Explain the diagonal relationship between Be & Al.
6) Write the preparation & applications of silicones.
7) What are inter halogen compounds. Explain the structure and bonding of AX5 & AX7.
8) Explain the preparation and structure of Diborane.
9) Explain the reactivity of alkanes and write the mechanism of chlorination of methane.
10) What are organic reagents? Explain with examples.
11) Explain the hyper conjugation with a suitable example.
12) What are conjugated dienes. Give examples. Write Diels Alders reactions.
13) What are ortho,para & meta directing groups. Explain with examples.
14) Explain the band theory of semi conductors and write its applications.
15) What are Liquid Crystals? Write the applications of liquid crystals.
16) Write about conformational isomers of n-butane.
17) What is a critical phenomena? Define Pc,Tc,Vc.
18) Explain Raoults law and how it is useful in the determination of molecular weight of non
volatile liquid.
19) Write the significance of
and
20) Define photo electric and Compton effect.

21) What is common ion effect? What is its importance in the qualitative analysis?
22) Explain Joule-Thomson effect?