JIS L 1940-3:2014

(ISO 24362-32014)

Textiles-Methods for determination of certain aromatic amines derived from azo

colorants-Part3:Detection of the use of certain azo colorants which may release 4aminoazobenzene
1

1
1

6
3

8
4

8.1

8.2

8.3

8.4

8.5

8.6
4-

8.7

8.8

8.9

9
7

9.1

9.2

10

A
8

B
13

C
14

D
15

L 1940-3
2014 (ISO 24362-32014)
2

12 1
JTETC
JSA

JISL1940

JIS
L
19401
1
JIS
L
19403

 3 4-
2

JIS
L
1940-3
2014

(ISO 24362-3
2014

3 4-

Textiles-Methods for determination of certain aromatic amines derived

from
azo colorants-Part 3: Detection of the use of certain azo colorants, which
may release 4-aminoazobenzene

2014 1 ISO 24362-3

4-JIS L 1940-1
1,4

4-

JIS L 1940-1 4-

4-
Solvent
Yellow 1
4

ISO243623:2014
TextilesMethods for determination of certain aromatic amines derived from azo
2
L 1940-3
2014 (ISO 24362-32014)

colorants Part 3: Detection of the use of certain azo colorants, which may release
4-aminoazobenzeneIDT
IDTISO/IEC Guide 21-1

JISL19401
1

ISO 24362-1TextilesMethods for determination

of certain aromatic amines
derived from azo colorantsPart 1: Detection of the use of certain azo colorants accessible with
and
without extracting the fibresIDT
ISO3696
Water for analytical laboratory useSpecification and test methods
3

4-

14-
CAS INDEX EC

22 60-09-3
611-008-00-4
200-453-6 4-

 1 INDEX EEC 67/548/EEC

Annex I

2 EC European Inventory of Existing

Commercial
Chemical Substances7

JIS L 1940-1

40

4- t-

t-
4- A
4-

5.1
4-

3
L 1940-3
2014 (ISO 24362-32014)

5.2

5.3
GLP

5.4

6.1

1)

200 mg/mL 1


6.2

2)

2 %
6.3
n

6.4

6.5

6.6
t

6.7

6.8
4

6.9
IS IS
IS1-d8CAS No.92890-63-6
IS2-d8CAS No.1146-65-2
IS32.4.5-CAS No.636-30-6
IS4-d10CAS No.1719-06-8
6.10

6.10.1
IS t- 10.0 g/mL
6.10.2
4
4- 500 g/mL
6.11
ISO 3696 3

1)

2)

7.1
20 mL50 mL
7.2
1
NS 29/32

100
mL NS 29/32


4
L 1940-3
2014 (ISO 24362-32014)

1
2
3
4

1

7.3
40 2
7.4
3 000
7.5

7.6

7.7
160 W
7.8
1 5 20 mm50 mm
7.9

7.9.1
GC MS
7.9.2
HPLC DAD

MS
7.9.3
TLCHPTLC

7.9.4
CE DAD
A
8

8.1

JISL19401
1,4-
8.3 8.4
8.2

5
L 1940-3
2014 (ISO 24362-32014)

1 g 8.3

7.2

8.5

8.3

8.3.1

7.2
25 mL 30

7.5 45 60
6.47 mL
2 2 1 7.7
1

1 mL
3
2 4-C.I.Disperse Yellow 23

LC-DAD-MS
8.3.2

8.3.3

A BJIS L 1940-1 8.4

7.2
n-
6.3 t-6.6

7 mL
8.4

A BJIS L 1940-1 8.4

 7 mL
8.5

7.19 mL

6.2
1.0 mL 6.1

40 2 30
1 20 25
8.6
4

5 mL t-6.6 5 mL IS t-
6.10.1
7 g 6.7
6
L 1940-3
2014 (ISO 24362-32014)

45 5
t-

4-7.9
50
t-
1 mL

24 18

1 5

2 8.5

4-

3 4-

8.7

8.7.1

5 mL t-6.6 5 mL IS t-
6.10.1
100 L 4-6.10.2

 4-95 %100 %

8.7.2

100 L 4-6.10.2 6.9 mL 6.49 mL

6.2
1 mL 6.11 7 g 6.7 5 mL t-
6.6 5 mL IS t-6.10.1

45 5
t-

8.8

8.8.1

100 L 4-8.7.1 8.5

4- 60 %
8.7.1 1.0 mL

8.8.2

100 L 4-8.7.2 6.9 mL

8.5
4- 60 %
1.0 mL

7
L 1940-3
2014 (ISO 24362-32014)

8.9

4- 7.9

4-

9.1

4- 1 kg mg
B

JIS Z 8401 B

9.2

C
10

a)

b)

c)

d)

e)

f)
4-mg/kg
4- 30 mg/kg
D

8
L 1940-3
2014 (ISO 24362-32014)

A.1

A.2
TLC
A.2.1
1
HPTLC F254 60200 mm100 mm

2 L5 L
1
9010

1 F254 TLC
2 UV 1 2

1
NO
x

1 mL

2
1 mol KOH
0.2 % -
A.2.2
2
TLC
F254 60200 mm100 mm

10.0 L
2
603010
3
955
4
n- 3070

2 3

1 F254 TLC
2 UV 1 2
5

A.2.3
3
TLC
60 200 mm200 mm

10.0 L
2
603010
3
955
9
L 1940-3
2014 (ISO 24362-32014)

2 3

1 2 5
A.3

HPLC
A.3.1
HPLC/DAD
1

2
0.68 g 1 000 mL 150 mL

Zorbax Eclipse XDB C183.5 m

150 mm4.6 mm

0.6 mL/min2.0 mL/min

32

5 L

DAD

240 nm380 nm

min
1%
mL
0.00
10.0
0.6
22.50
55.0
0.6
27.50
100.0
0.6
28.50
100.0
0.95
28.51
100.0
2.0
29.00
100.0
2.0
29.01
10.0
2.0
31.0
10.0
0.6
35.00
10.0
0.6
A.3.2
HPLC/MS
1


2
5 mmol 1 000 mL pH 3.0

Zorbax Eclipse XDB C183.5 m

2.1 mm50 mm

300 L/ min

1 10 %1.5 1 20 %6
1 90 %

40

2.0 L

API 120 V
10
L 1940-3
2014 (ISO 24362-32014)

A.4
GC/MS

DB-35MS (J&W) 35 m 0.25 mm 0.25 m

260

100 2 100 310 15 310 2

1.0 L 115

MS
A.5
CE
8.4200 L 50 L c0.01 mol/L0.2 m

1
560 mm 50 m agilent
2
560 mm PVA 50 m
agilent

c50 mmol/L pH2.5

25

30 kV

DAD214 nm254 nm

240 nm 380 nm
X
Y
1
2

4-

A.14-GC/MS
11
L 1940-3
2014 (ISO 24362-32014)
X m/z
Y

A.24- GC/MS70eV
X
Y
1
2

mAU
240 nm
380 nm

A.34-HPLC/DAD
12
L 1940-3
2014 (ISO 24362-32014)

X nm
Y mAU

A.44-HPLC/DAD
13
L 1940-3
2014 (ISO 24362-32014)

B.1

4-4-
B.2
B.3
W mg/kg

 JIS Z 8401 B
B.2

E
ISS
C
ISC
S
C

m
A
A
V
A
A
W

4-

mg/kg

4-g/mL
A
S

4-

A
C

4-

A
ISS

A
ISC

8.3
mL
m
E

g
B.3


E
C
S
C

m
A
V
A
W

4-
mg/kg

4-g/mL
A
S

4-

A
C

4-

8.3
mL
m
E

g
14
L 1940-3
2014 (ISO 24362-32014)

C.1

1)

C.1 4-

GC/MS
HPLC
GC/MS
HPLC
10
11
10
9

0301

10 8 10 8

x mg/kg
77.3 80.7 71.1 52.7
rmg/kg
22.6 11.2 32.6 10.0
s
r

mg/kg
8.1 4.0 11.6 3.6
Rmg/kg
54.7 52.3 54.3 48.2
s
R

mg/kg
19.6 18.7 19.4 17.2

BVL64LFGB

11

1)

64LFGB BVL B 82.02-9 2006 9 4-

a)

8.5

b)
4-

8.6

c)
GC/MS

4-

4-

15
L 1940-3
2014 (ISO 24362-32014)

REACH 1907/2006/
17
30 mg/kg

4- 30 mg/kg

30 mg/kg

a)
4-30 mg/kg

4-

b)
4-30 mg/kg

JIS Z 8401