JIS L 1940-1:2014 (ISO 24362-12014)

Textiles-Methods for determination of certain aromatic amines derived from azo

colorants-Part1:Detection of the use of certain azo colorants accessible with and
without extracting the fibres
1

1
1

6
4

8
7

8.1

8.2

8.3

8.4

8.5

8.6

9
8

9.1

9.2

9.3

9.4

9.5

10

9.6

10

10

11

10.1

11

10.2

11

10.3

11

11

11

A
12

B
15

C
16

D
17

E
19

F
22

L 1940-1
2014 (ISO 24362-12014)
2

12 1
JTETC
JSA

JIS L 1940

JIS
L
1940-1

 1
JIS
L
1940-3
3 4-
2

JIS
L
1940-1
2014

(ISO 24362-1
2014

Textiles-Methods for determination of certain aromatic

amines derived from azo colorantsPart 1: Detection of the use of certain azo colorants
accessible with and without extracting the fibres

2014 1 ISO 24362-1

2
L 1940-1
2014 (ISO 24362-12014)

ISO 24362-1:2014
TextilesMethods for determination of certain aromatic amines derived from azo
colorantsPart 1: Detection of the use of certain azo colorants accessible with and
without
extracting the fibresIDT
IDTISO/IEC Guide 21-1

ISO 3696:1987
Water for analytical laboratory useSpecification and test methods
3

1
3
L 1940-1
2014 (ISO 24362-12014)

No CAS INDEX EC

1
92-67-1
612-072-00-6
202-177-1
-4-
4-

2
92-87-5
612-042-00-2
202-199-1

3
95-69-2
612-196-00-0
202-441-6
4--o-
4

91-59-8
612-022-00-3
202-080-4
2-
5
a)

97-56-3
611-006-00-3
202-591-2
o-
4--2',3-
4-o--o-
6
a)

99-55-8
612-210-00-5
202-765-8
5--o-
2--4-
7
106-47-8
612-137-00-9
203-401-0
4-
8
615-05-4
612-200-00-0
210-406-1
4--m-
2,4-
9
101-77-9
612-051-00-1
202-974-4
4,4'-
4,4'-
10 91-94-1
612-068-00-4
202-109-0 3,3'-
3,3'--4,4'-
11 119-90-4
612-036-00-X
204-355-4 3,3'-
o-
12 119-93-7
612-041-00-7
204-358-0 3,3'-
4,4'--o-
13 838-88-0
612-085-00-7
212-658-8 4,4'--o-
14 120-71-8
612-209-00-X
204-419-1 6--m-
p-
15 101-14-4
612-078-00-9
202-918-9 4,4'---2-
2,2'--4,4'-
16 101-80-4
612-199-00-7
202-977-0 4,4'-
17 139-65-1
612-198-00-1

205-370-9 4,4'-
18 95-53-4
612-091-00-X
202-429-0 o-
2-
19 95-80-7
612-099-00-3
202-453-1 4--m-
2,4-
2,4-
20 137-17-7
612-197-00-6
205-282-0 2,4,5-
21 90-04-0
612-035-00-4
201-963-1 o-
2-
22
b)

60-09-3
611-008-00-4
200-453-6
4-
1 2,4-CAS No.95-68-1 2,6-CAS No.87-62-7

2 INDEX EEC 67/548/EEC

Annex I

3 EC European Inventory of Existing

Commercial
Chemical Substances7

a)

CAS
No.97-56-3No.5 99-55-8No.6 CAS No.95-53-4No.18 95-807No.19

b)

4-CAS No.62-53-3
1.4-
CAS No.106-50-3
JIS L 1940-3
4
L 1940-1
2014 (ISO 24362-12014)

pH6 70

pH6
70

t-

t-

5.1
1

5.2

5.3
GLP

5.4

6.1

6.2

5
L 1940-1
2014 (ISO 24362-12014)

6.3

6.4
t
6.5
n
6.6
pH6c0.06 mol/mL
1)

6.7
200 mg/mL
2)

6.8

6.9
1 No.1No.21 1,4-

6.10

6.10.1
1 mL 300 g

6.10.2
6.10.1 1 mL
15.0 g

6.10.3
1 mL 2 g50 g

6.10.4
IS 1 mL 1.0 mg

GC/MS

IS1-d8CAS No.92890-63-6
IS2-d8CAS No.1146-65-2
IS32.4.5-CAS No..636-30-6
IS4-d10CAS No.1719-06-8
DAD TLC

IS1 -d8CAS No.92890-63-6

6.11
10 %
6.12
ISO 3696 3

1)

2)

7.1

1
NS 29/32

100
mL NS 29/32

6
L 1940-1
2014 (ISO 24362-12014)
1
2
3
4

1

7.2
160 W
7.3
20 mL50 mL
7.4
70 2
7.5
20 g 6.8 25 m
m30 mm
130 mm150 mm

20
g
7.6

7.7

7.8

7.8.1
TLCHPTLC

7.8.2
HPLC DAD
MS
7.8.3

GC FIDMS

7.8.4
CE
A
7
L 1940-1
2014 (ISO 24362-12014)

8.1

1 g 9.1

7.1

9.3
8.2

3)

1 g

0.5 g

C b) 2
0.2 g
0.2
g

3)

8.3

2
2

8
L 1940-1
2014 (ISO 24362-12014)

D
8.4

9.1

3
3

A B C D
A

AD 2

8.5

D
9.2

8.6

8.6.1

8.6.2

3
3
3
3 3

3
9.1
9.2 3
8.6.3
3

1 g 3
3 5 mg/kg30 mg/kg

30 mg/kg

9.1

9.1.1

7.1 25 mL
30

7.6 45 60

9
L 1940-1
2014 (ISO 24362-12014)

1 mL 2 1 7.2

9.1.2

9.1.3

 A B8.4

n-6.5 t-
6.4

2 mL
9.2

A B8.4

2 mL 6.3
9.3

7.370

15 mL 6.670 2 30 1

3 mL 6.7

70 2 30 1
2 20 25
9.4

6.110.2 mL

7.515
t-10 mL15 t
100 mL

7.6
t-10 mL 60 mL t-

t- 50 1 mL

6.2 t-

2.0 mL
24 18
1

2 2,4- 2,4-

10
L 1940-1
2014 (ISO 24362-12014)

9.5

7.8

1
3

9.6

9.6.1

6.10.1100 L
30 g
2.0 mL 15 mL
6.6

9.39.5 6.10.2

9.6.2

V
V
A
A
A
A
S
ISS
C
ISC
S
C
S

g/mL
A
S

A
C

A
ISS

A
ISC

V 9.4 mL
V
S

mL

g/mL
9.6.3

V
V
A
A
S
C
S
C
S

g/mL
A
S

A
C

V 9.4 mL
V
S

mL

g/mL

No.1No.4No.7No.9No.17 No.20No.21
70 %
No.8
20 %
No.18 No.19

50 %
No.5No.6 No.22

1
a)

b)

70 %

11
L 1940-1
2014 (ISO 24362-12014)

10

10.1

6.10.2 5 mg/kg

6.10.3

g/mL
10.2

1 kg wmg/kg
E
S

m
V
w

g/mL
V 9.4 mL
m
E

g
JIS Z 8401 B
10.3

B
11


a)

b)

c)

d)

e)

f)
mg/kg
g)
mg/kg
30
mg/kg

C
12
L 1940-1
2014 (ISO 24362-12014)

A.1

A.2
TLC
A.2.1
1
HPTLC F254 60200 mm100 mm

2L5 L
1
9010
1
NO
x

1 mL

2
1 mol KOH 0.2 %
-

1 F254 TLC

2
UV 1 2 5

A.2.2
2
TLC
F254 60200 mm100 mm

10.0 L
2
603010
3
955
4
n- 3070

2 3

1 F254 TLC
2
UV 1 2 5

A.2.3
3
TLC
60200 mm200 mm

10.0 L
2
603010
3
955
2 3

13
L 1940-1
2014 (ISO 24362-12014)

A.3
HPLC
A.3.1
HPLC/DAD
1

2
0.68 g 1 000 mL 150 mL

Zorbax Eclipse XDB C183.5 m

150 mm4.6 mm

0.6 mL2.0 mL/min

32

5 L

DAD

240 nm280 nm305 nm 380 nm

min 1% mL
0.00
10.0
0.6
22.50
55.0
0.6
27.50
100.0
0.6
28.50
100.0
0.95
28.51
100.0
2.0
29.00
100.0
2.0
29.01
10.0
2.0
31.0
10.0
0.6
35.00
10.0
0.6
A.3.2
HPLC/MS
1

2
5 mmol 1 000 mL pH3.0

Zorbax Eclipse XDB C183.5 m

2.1 mm50 mm

300 L/min

1 10 %1.5 1 20 %6
1 90 %

40

2.0 L

API 120 V
A.4
GC/MS

DB-35MS (J&W) 35 m 0.25 mm 0.25 m

14
L 1940-1
2014 (ISO 24362-12014)

260

100 2 100 310 15 /min310 2

1.0 L 115

MS
A.5
CE
9.4200 L 50 L c0.01 mol/L0.2 L

1
560 mm 50 m agilent
2
560 mmPVA 50 m
agilent

c50 mmol/L
pH2.5

25

30 kV

DAD214 nm254 nm

X
Y 240 nm mAU
1,4-

No.1No.21
1

A.1HPLC/DAD-
15
L 1940-1
2014 (ISO 24362-12014)

B.1
B.1 A

x
r
a)

(r)

a)

(R)

HPLCDAD
p- 31.6
(20.6)
2.2 12.7
(40.2)
4.5

GCMS
p- 31.8
(21.4)
2.4 10.9
(34.3)
3.8

r
mg/kg
R
mg/kg
x
mg/kg
s

6.5

6.8

(r)

mg/kg
s
(R)

mg/kg

a)

B.2 11
B.2

x
r
a)

(r)

a)

(R)

HPLC
3,3- 25.9 4.9
(18.9)
1.7 12.7
(49.1)
4.5
HPLC

29.7
5.3
(17.8)
1.9 11.5
(38.7)
4.1
HPLC
3,3- 22.5
(12.9)
1.0 7.9
(35.1)
2.8
HPLC
4,4-

17.7 3.0
(16.9)
1.1 7.5
(42.4)
2.6
HPLC
o- 22.6
4.4
(19.5)
1.6 13.8
(61.1)
4.9

r
mg/kg
R
mg/kg
x
mg/kg
s
(r)

mg/kg
s
(R)

mg/kg

a)

16
L 1940-1
2014 (ISO 24362-12014)

2.9

REACH 1907/2006/
17
30 mg/kg

30 mg/kg

30 mg/kg

a)
30 mg/kg
1)

b)
30 mg/kg
1)
30 mg/kg
2)

2.1) 42-4--m-

2.2) 42-

2.3) 4-m- 4--m-

2--4-

2--4- 4-
-m
1

c)

4 4-
C.I.Disperse
Yellow 23 1,4-
1,4-
4-

JIS L 1940-3
17
L 1940-1
2014 (ISO 24362-12014)

D.1

D.1

a)

a)

XX
XX

XX
(X)
X
X
(X)
XX
X
X
(X)
(X)
(X)
X
X

XX
XX XX XX XX

XX
X

XX X XX (X) X

XX
X

XX
X
(X)
(X)
(X)
X

XX
(X)
X

XX
XX
X
XX
XX
X

X
X
X
(X)
XX

a)

9.1.1 20

D.2

D.2.1

18
L 1940-1
2014 (ISO 24362-12014)

D.2.2

19
L 1940-1
2014 (ISO 24362-12014)

E.1

7.5
1

1 5 mg/kg100 mg/kg

8
E.2

E.2.1

6.10.1


1 mL 6.0 g

GC/MSE.2.3
E.2.2

1 mL 0.8 g20 g

GC/MS E.2.3

E.2.3
IS
t-6.41 mL IS15 g GC/MS

IS1-d8CAS No.92890-63-6
IS2-d8CAS No.1146-65-2
IS32,4,5-CAS No.636-30-6
IS4-d10CAS No.1719-06-8
DAD TLC

IS1-d8CAS No.92890-63-6

E.2.4
40 w/w
E.2.5

E.3

E.3.1
1 5 20 mm50 mm
E.3.2
3 000 rpm
20
L 1940-1
2014 (ISO 24362-12014)

E.4

E.4.1

E.4.1.1

7.1 25 mL

30
45 60
0.5 mL 2

E.4.1.2

E.4.1.3

A B8.4

n-6.5 t-6.4

1 mL

E.4.2

A B8.4

6.31 mL
E.4.3

6.68 mL 70
2 30
1
6.73 mL

70 2 30 1
2 20 25
E.4.4

E.2.40.5 mLE.2.57 g

E.2.35 mL E.3.1 15 1

50 t- 1
mL

t-
2 mL

24 18
1

21
L 1940-1
2014 (ISO 24362-12014)

2 2,4- 2,4-


E.4.5

7.8

1
3
HPLC/DAD

GC/MS
E.4.6

6.10.1100 L
30 g
1.0 mL 3.0 mL 8 mL
6.6

E.4.4 E.4.5

E.2.1

No.1No.4No.7No.9No.17 No.20No.21
70 %
No.8
20 %
No.18 No.19
50 %
No.5No.6 No.22

1
a)
b)

70 %
22
L 1940-1
2014 (ISO 24362-12014)

F.1

F.2

9.1 9.2 4
9.3


9.4
9.5
9.6
10
F.3

F.3.1

F.3.2

200 mg
F.4

2.0 mL 9.3

F.5

10.2 wmg/kg
F.6

11
23
L 1940-1
2014 (ISO 24362-12014)

[1] JIS L 1940-3 3 4-

ISO 24362-3TextilesMethods for determination of

certain aromatic amines
derived from azo colorantsPart 3: Detection of the use of certain azo colorants,
which may release
4-aminoazobenzeneIDT
[2]

JIS Z 8401

[3]

EN 14362-1TextilesMethods for determination of certain aromatic amines

derived from azo colorantsPart

1: Detection of the use of certain azo colorants accessible with
and without extracting the fibres
[4] EN 14362-3TextilesMethods for determination of certain aromatic amines
derived from azo colorantsPart
3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene
[5] Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals
(REACH)establishing a
European Chemicals Agency