Professional Documents
Culture Documents
Product name
: Sika-CNI
Supplier/Manufacturer
Telephone no.:
Fax no.
Use of the substance/
mixture
1.
Nama Produk
: Sika-CNI
Pembekal/ Pengilang
No. Telefon:
No. Faks
Penggunaan bahan/
persediaan
2.
Composition/information on ingredients
Calcium nitrite
13780-06-8 10 <30
No.
No.
Tiada.
Tiada.
Calcium nitrite
13780-06-8 10 <30
: 11
Solubility
3.
: 11
Kelarutan
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4.
Sika-CNI
Hazards identification
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification
: O; R8
T; R25
N; R50
Health hazards
: Toxic if swallowed.
Physical/chemical hazards
Environmental hazards
Additional hazards
See Section 11 for more detailed information on health effects and symptoms.
4.
Pengenalpastian bahaya
Produk ini dikelaskan sebagai berbahaya menurut Arahan 1999/45/EC dan pindaannya.
Klasifikasi
: O; R8
T; R25
N; R50
Bahaya Kesihatan
: Toksik jika ditelan.
Bahaya Fizikal/Bahan Kimia : Sentuhan dengan bahan mudah terbakar boleh menyebabkan kebakaran.
Bahaya Alam Sekitar
Bahaya Tambahan
Lihat Seksyen 11 untuk maklumat lebih lanjut tentang kesan-kesan dan gejala-gejala kesihatan.
5.
: Get medical attention immediately. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Ingestion
: Get medical attention immediately. Wash out mouth with water. Remove dentures
if any. Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If material has been swallowed and the exposed person is conscious,
give small quantities of water to drink. Stop if the exposed person feels sick as
vomiting may be dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Skin contact
: Get medical attention immediately. Flush contaminated skin with plenty of water.
Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 10
minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Eye contact
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Protection of first-aiders
: No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
: In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
See Section 11 for more detailed information on health effects and symptoms.
5.
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5.
Sika-CNI
Fire-fighting measures
Extinguishing media
Suitable
Not suitable
: None known.
Hazardous combustion
products
Special protective
equipment for fire-fighters
: Contact with combustible material may cause fire. This material increases the risk
of fire and may aid combustion. In a fire or if heated, a pressure increase will occur
and the container may burst.
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool. This material is very toxic to
aquatic organisms. Fire water contaminated with this material must be contained
and prevented from being discharged to any waterway, sewer or drain.
: Decomposition products may include the following materials:
nitrogen oxides
metal oxide/oxides
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
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6.
Fire-fighting measures
6.
Tidak sesuai
Produk pembakaran
berbahaya
Alat perlindungan khas
untuk ahli bomba
7.
Personal precautions
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment (see Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large quantities.
Large spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Do not absorb in sawdust or
other combustible material. It may lead to a fire risk when it dries out. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local
regulations. Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product.
Small spill
: Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Do not absorb in sawdust or other
combustible material. It may lead to a fire risk when it dries out. Dispose of via a
licensed waste disposal contractor.
Note: see section 9 for personal protective equipment and section 13 for waste disposal.
7.
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7.
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: Tiada tindakan yang membabitkan risiko peribadi perlu diambil atau tanpa latihan
yang sewajarnya. Kosongkan kawasan persekitaran. Halang kakitangan tidak
berkaitan dan tidak dilindungi daripada masuk. Jangan sentuh atau jalan melalui
bahan tertumpah. Tutup semua sumber pencucuhan. Tiada menyala, merokok
atau nyalaan di kawasan bahaya. Jangan menyedut wap atau kabus. Sediakan
ventilasi yang mecukupi. Pakai alat pernafasan yang sesuai apabila ventilasi tidak
mencukupi. Pakai kelengkapan perlindungan peribadi bersesuaian (Lihat Seksyen
8).
Peringatan alam sekitar
: Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh dengan tanah,
jalan air, longkang dan pembetung. Beritahu pihak berkuasa yang berkaitan jika
produk menyebabkan pencemaran persekitaran (pembetung, aliran air, tanah atau
udara). Bahan mencemar air. Boleh memudaratkan alam sekitar jika terlepas
dalam jumlah yang banyak.
Tumpahan besar
: Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan.
Gunakan alat kalis percikan dan peralatan kalis letupan. Pendekatan lepas dari
arah angin bertiup jauh dari kamu, bukan ke arah kamu. Cegah kemasukan ke
dalam pembetung, aliran air, basemen atau ruang terbatas. Jangan diserap ke
dalam habuk gergaji atau lain-lain bahan yang boleh terbakar. Ia boleh membawa
kepada risiko kebakaran apabila kering. Siram tumpahan ke dalam loji perawatan
efluen atau teruskan seperti berikut. Bendung dan kumpul tumpahan dengan
bahan serap tidak mampu bakar seperti pasir, tanah, vermikulit dan tanah diatom,
dan letakkan dalam bekas untuk pembuangan mengikut peraturan tempatan.
Buang melalui kontraktor pelupusan sisa yang berlesen. Bahan penyerap yang
tercemar boleh mendatangkan bahaya yang sama seperti produk tertumpah.
Tumpahan kecil
: Hentikan kebocoran jika tidak berisiko. Alih bekas daripada kawasan tumpahan.
Gunakan alat kalis percikan dan peralatan kalis letupan. Cairkan dengan air dan
seka bersih jika terlarut air. Sebagai alternatif, atau jika tidak terlarut air, serap
dengan bahan kering yang lengai dan isikan dalam bekas pelupusan bahan
buangan yang wajar. Jangan diserap ke dalam habuk gergaji atau lain-lain bahan
yang boleh terbakar. Ia boleh membawa kepada risiko kebakaran apabila kering.
Buang melalui kontraktor pelupusan sisa yang berlesen.
Nota: Lihat seksyen 9 untuk peralatan perlindungan peribadi dan seksyen 13 untuk pelupusan sisa.
8.
Recommended monitoring
procedures
: Not available.
: S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S61- Avoid release to the environment. Refer to special instructions/safety data
sheet.
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring
standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.
Exposure controls
Occupational exposure
controls
Hygiene measures
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.
Respiratory protection
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8.
Hand protection
Eye protection
Skin protection
Environmental exposure
controls
8.
Sika-CNI
: Tiada.
Ungkapan keselamatan
: S45- Dalam hal kemalangan atau jika anda merasa kurang sihat, dapatkan nasihat
perubatan dengan segera (tunjukkan label jika perlu).
S61- Elakkan daripada melepaskan ke persekitaran. Rujuk kepada arahan khas/
risalah data keselamatan.
Langkah pemantauan
: Jika produk ini mengandungi ramuan dengan had pendedahan, pemantauan
peribadi, suasana tempat kerja atau biologi mungkin perlu untuk menentukan
yang disyorkan
keberkesanan pengudaraan (untuk peredaran udara) atau lain-lain langkah kawalan
dan/atau keperluan menggunakan peralatan perlindungan pernafasan. Rujukan
harus dibuat atas piawai pemantauan yang berkenaan. Rujukan kepada dokumen
panduan negara bagi kaedah penentuan zat berbahaya juga dikehendaki.
Kawalan-kawalan pendedahan
Kawalan pendedahan
pekerjaan
Langkah-langkah
kebersihan
: Basun kedua tangan, lengan dan muka sehingga bersih setelah mengendali produk
kimia, sebelum makan, merokok dan menggunakan tandas dan pada akhir waktu
kerja. Teknik yang sesuai harus digunakan apabila menanggalkan pakaian yang
mungkin tercemar. Basuh pakaian tercemar sebelum memakai semula. Pastikan
tempat mencuci mata dan pancuran air keselamatan berdekatan dengan lokasi
tempat kerja.
: Guna alat penulen udara atau alat pernafasan bekal udara yang muat dengan baik
yang mendapat kelulusan piawai jika risiko penilaian menunjukkan ianya perlu.
Pemilihan alat pernafasan mesti berdasarkan tahap pendedahan diketahui atau
dijangka, bahaya produk dan had pekerjaan selamat alat pernafasan yang dipilih itu.
: Sarung tangan kedap penentang bahan kimia, yang mematuhi piawaian yang
diluluskan hendaklah dipakai pada setiap masa apabila mengendalikan produk
kimia jika penilaian risiko menunjukkan ini adalah perlu. Dengan
mempertimbangkan parameter yang ditetapkan oleh pengilang sarung tangan,
pastikan semasa digunakan bahawa sarung tangan masih mengekalkan ciri-ciri
perlindungannya. Harus diperhatikan bahawa jangka masa hingga terobos untuk
mana-mana bahan sarung tangan mungkin berbeza mengikut pengilang sarung
tangan. Bagi kes campuran, yang terdiri daripada beberapa zat, jangka masa
perlindungan sarung tangan tidak dapat dianggarkan dengan tepat.
: Kacamata keselamatan yang mematuhi kelulusan piawai perlu digunakan apabila
risiko penilaian menunjukkan ianya perlu untuk mengelakkan pendedahan kepada
percikan cecair, kabus atau debu. Jika sentuhan mungkin terjadi, perlindungan
berikut harus dipakai, kecuali taksiran menunjukkan tahap perlindungan lebih tinggi:
cermin mata keselamatan dengan pelindung sisi.
Perlindungan respiratori
Perlindungan tangan
Perlindungan mata
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8.
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Perlindungan kulit
: Peralatan perlindungan peribadi untuk badan perlu dipilih berdasarkan tugas yang
dilakukan dan melibatkan risiko dan perlulah diluluskan oleh pakar sebelum
mengendali produk ini.
Kawalan pendedahan alam : Pengeluaran daripada pengudaraan atau peralatan proses kerja hendaklah
diperiksa untuk memastikan ianya mematuhi keperluan perundangan perlindungan
sekitar
alam sekitar. Bagi sesetengah kes, penyental wasap, penuras atau
pengubahsuaian kejuruteraan terhadap peralatan proses adalah perlu bagi
mengurangkan pengeluaran ke tahap yang dibenarkan.
9.
Handling
Storage
Packaging materials
Recommended use
9.
: Put on appropriate personal protective equipment (see Section 8). Eating, drinking
and smoking should be prohibited in areas where this material is handled, stored
and processed. Workers should wash hands and face before eating, drinking and
smoking. Remove contaminated clothing and protective equipment before entering
eating areas. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Avoid release to the environment. Refer to special instructions/
safety data sheet. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Keep away from
combustible material. Empty containers retain product residue and can be
hazardous. Do not reuse container.
: Store in accordance with local regulations. Store in original container protected
from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
materials (see Section 10) and food and drink. Separate from reducing agents and
combustible materials. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
: Use original container.
Pengendalian
Penyimpanan
Bahan pembungkusan
Penggunaan yang
disyorkan
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10.
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Stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
10.
Kestabilan
Keadaan-keadaan yang
mesti dielak
Bahan yang harus dielak
Produk pereputan
berbahaya
11.
Toxicological information
Eye contact
Maklumat toksikologi
: Pendedahan kepada produk penguraian boleh membahayakan kesihatan. Kesankesan serius mungkin tertunda berikutan dedahan.
: Toksik jika ditelan.
: Mungkin merengsakan kulit.
: Mungkin menyebabkan rengsaan mata.
Ecological information
Environmental effects
12.
Maklumat ekologi
Disposal considerations
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
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13.
Disposal considerations
Methods of disposal
13.
Sika-CNI
Maklumat pembuangan
Sisa harus dibuangkan mengikut peraturan persekutuan, negeri dan kawalan alam sekitar tempatan.
Kaedah pembuangan
: Penghasilan sisa perlulah dielakkan atau diminimumkan sekiranya boleh. Sisa-sisa
produk buangan tidak harus dilupuskan melalui pembetung tetapi diproses dalam
loji rawatan kumbahan yang sesuai. Pembuangan lebihan dan hasilan yang tidak
boleh dikitar semula melalui kontraktor pelupusan sisa yang berlesen. Pelupusan
produk ini, larutan dan sebarang produk sampingan perlulah pada setiap masa
mematuhi keperluan perlindungan alam sekitar dan perundangan pelupusan sisa
dan sebarang keperluan pihak berkuasa serantau tempatan. Bungkusan buangan
harus dikitarkan semula. Penunuan atau kambus tanah hanya harus
dipertimbangkan apabila tidak mungkin dikitar semula. Bahan ini dan bekasnya
hendaklah dilupuskan dengan cara yang selamat. Hati-hati apabila mengendalikan
bekas yang telah dikosongkan tetapi belum dibersihkan atau dibilas. Bekas atau
pelapik kosong mungkin mengandungi sisa-sisa produk. Elakkan penyebaran
bahan tertumpah dan aliran dan bersentuh dengan tanah, jalan air, longkang dan
pembetung.
14.
Transport information
: No.
IATA
Not regulated.
14.
Maklumat pengangkutan
: No.
IATA
Not regulated.
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15.
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Regulatory information
EU regulations
Hazard symbol or symbols
Contains
Oxidizing, Toxic
: R8- Contact with combustible material may cause fire.
R25- Toxic if swallowed.
R50- Very toxic to aquatic organisms.
: S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S61- Avoid release to the environment. Refer to special instructions/safety data
sheet.
: Calcium nitrite
237-424-2
Product use
: Professional applications.
Risk phrases
Safety phrases
15.
Maklumat pengawalan
Peraturan-Peraturan EU
Simbol bahaya
Mengandungi
Pengoksidaan, Toksik
: R8- Sentuhan dengan bahan mudah terbakar boleh menyebabkan kebakaran.
R25- Toksik jika ditelan.
R50- Sangat toksik kepada organisma akuatik.
: S45- Dalam hal kemalangan atau jika anda merasa kurang sihat, dapatkan nasihat
perubatan dengan segera (tunjukkan label jika perlu).
S61- Elakkan daripada melepaskan ke persekitaran. Rujuk kepada arahan khas/
risalah data keselamatan.
: Calcium nitrite
237-424-2
Kegunaan Produk
: Aplikasi profesional.
Ungkapan risiko
Ungkapan keselamatan
16.
Other information
History
Date of printing
: 05.12.2014.
Date of issue
Date of previous issue
: 05.12.2014.
: 04.12.2014.
Version
: 2
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please
consult the product data sheet prior to any use and processing.
16.
Maklumat lain
Sejarah
Tarikh cetakan
: 05.12.2014.
Tarikh keluaran
Tarikh Keluaran Terdahulu
: 05.12.2014.
Versi
: 2
: 04.12.2014.
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16.
Sika-CNI
Maklumat lain
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