TARGET IIT-JEE

XIII REVIEW TEST - 1

DATE : 22-08-2010
XII UNIQUE TEST - 4

ANSWER KEY WITH SOLUTION

CHEMISTRY
SECTION - A
1. D 2. B 3. A 4. B 5. C 6. A 7. B
8. C 9. A 10. C 11. A,C D 12. AC 13. A, B,C,D 14. AD
15. C,D
SECTION – B
1. A –P, S B–Q, R, S C –S D–P, T
SECTION – C

1. 0500 2. 0000 3. 0023

PHYSICS
SECTION - A
1. A 2. A 3. C 4. C 5. C 6. A 7. C
8. D 9. A 10. A 11. A,B,D 12. A 13. A,B,C,D 14. A,C
15. A,B,D
SECTION - B

1. (A) →R, S ; (B) → S, R, T ; (C) → Q,R ; (D) → Q, R,T

SECTION - C
1. 0003 2. 0120 3. 0009

MATHEMATICS

SECTION – A
1. D 2. B 3. A 4. D 5. D 6. D
7. A 8. C 9. A 10. A 11. A 12. A,B,C
13. A,B,D 14. A,B 15. A,B,C,D
SECTION - B
1. (A) P, Q, R, S, T; (B) Q, R, S, T; (C) P, Q, R, S, T; (D) T
SECTION – C
1. 0001 2. 0004 3. 2010

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 CHEMISTRY
SECTION – A 1000 mL solution has H3PO4
1000 mL = (1800 g) solution has H3PO4 = 18 × 98 g
8. C
2+ – 2+ H 3 PO 4 by mass % (by weight of solution) =
Only Fe is oxidised and MnO4 is reduced to Mn
3+ – 18 × 98
25 × M (Fe ) = 25 × 0.02 × 5(MnO4 ) ×100= 98%
M = 0.10 M 1800
or
9. A (1800 – 18 × 98)g H2O (solvent) H3PO4 = 18 × 98 g
2+ 3+
Total Fe in second part (including that of from Fe ) 2 g solvent has H3PO4 = 98 g = 1 mol H3PO4
25 × y = 40 × 0.02 × 5 1 kg = 1000 g solvent has H3PO4 = 500 molal
y = 0.16 M = 0.16 N Thus, 98 %, 500 molal
3+ 2+
Fe = 0.16 – 0.10 (Fe ) = 0.06 M 2. 0000
10. C 3. 23
2+
25 mL of 0.10 M Fe = V1 mL of 0.02 M K2Cr2O7 M2CO3 = 2HCl → 2MCl + H2O + CO2
= V1 × 0.02 × 6 N K2Cr2O7 M is a monovalent cation.
V1 = 20.83 mL
2– 3+ molar mass
(Cr2O7 is reduced to Cr ) Thus, equivalent weight of M2CO3 =
2+ 3+ 2
Similarly for 0.16 ( Fe to Fe )
= M + 30
V2 = 33.33 mL Let unsed HCl be v mL.
SECTION – B V mL of N HCl ≡ 100 mL of 0.5 N NaOH
1. A –P, S B–Q, R, S C –S D–P, T V = 50 mL
1N HCl used = 150 = 100 mL = 0.1 equiv.
SECTION – C
1. 500 5. 3
equiv. of M2CO3 = = 0.1
Density = 1.8 g/mL M + 30
Molarity = 18 M = 18 mol H3PO4 in 1 L solution M = 23

PHYSICS
SECTION - A
3. C
1. A
u pulling mass = x .λ block
table
θ M
a m1
where λ = x
L
2 2usin θ
u sin 2θ where m1 = mass of chain
R= , T=
g g & L = length of chain
1  2u sin θ  2 2au 2 sin2 θ 2u2 sin θ cos θ xλg
x= a   = = Mass pulled = M + (L – x)λ ∴ a =
2  g  g2 g M + (L − x ) λ
a As x↑ with time, a↑ because Nr ↑ & Dr ↓
sin θ = cos θ ⇒ tan θ = (g/a) dv
g a= = slope ⇒ x↑ slope of v – t ↑
dt
2. A 4. C
A u cos θ f1
F = 13 ma
f1 = umg ≥ ma m f2
rmin v cos α T
α f2 – T = 4ma 2m 4m
α
v T = 3ma
mg 6m F
u2 cos2 θ u2 cos 2 θ f2 = µ (4mg) ≥ 7ma
mg = m ⇒ rmin =
rmin g
 F  52
u cos θ 7   ≤ 4 µ mg ⇒ F ≤ µmg
⇒ v cos α = u cos θ ⇒ v =  
13 7
cos α
2 u 2
cos 2
θ 52
mv Fmax = µmg
mg cos α = =m 2 7
R cos α R
u2 cos2 θ 1 rmin
R= =
g 3
cos α cos 3
α
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5. C 14.
, A,C
6. A C & D would acceleration
F + R2 – R1 = ma F up just after cut
F > ma
dv
because R1 & R2 the blocks =a Spring 1 C
R2 R1 dt
slow down rods motion
∴ F – ma = R1 – R2 > 0 B D
⇒ R1 > R2
∴ ∫ dv = ∫ ad t
⇒ More force on B wrt A v – u = a (t – t0)
∴ B moves first here u=0 A
7. C & t = t0 ∴v=0
(1) force is independent of frame where t0 = time of cut ∴ v=0
(2) 'µ' depends on contract surfaces roughness & 15. A,B,D
relateed properties not on frame of refrence. v2
at A aA = g sin θ = 8 m/s2 at B aB =
8(D) 9(A) 10(A) l
from E.C between A & B
B 1
y mg l (1–cos θ) = mv2
2
b 2lg(1 − cos θ)
5 kg v2 = 2lg (1 – cos θ) ⇒ aB = = 1 m/s2
a
l
θ A a
N1 θ 10 kg x θ SECTION - B

N1 = 10a 1. (A) →R, S ; (B) → S, R, T ; (C) → Q,R ; (D) → Q, R,T

a cos θ = b sin θ
b = a cot θ SECTION - C
mg
b 1. 0003
mg – N2 = m   N2
2 Q 50N 50N
b a cot θ B
⇒ N2 = mg –m = mg – m 250kg
2 2 500
A
5a
N2 = 50 – cot θ
2 vAB = vA – vB = x/2
N
50 1 50 1
a aA = = aB = =
250 5 500 10
2
1 1 3
10 kg aAB = + =
N1 5 10 10
a 5a x
N – N1 = 5 ⇒ N = N1 + = a AB .t ⇒ x = 3
2 2 2
= 10a + 2.5a = 12.5a
2. 0120 B x C
11. A,B,D
Time taken to cross the
12. A
13. A,B,C,D d
river is t =
v cos θ
N1 In this duration drift BC is u
N1
d v θ vR
A
B x = (u – v sin θ ) × v cos θ A
ud
mg
= secθ – d tan θ
v
mg dx
This drift x is minimum when =0
(A) True Q no horizontal force on A dθ
(B) (aAB)x = (aA)x – (aB)x dx ud
= 0 – (–ve) = sec θ tan θ − d sec 2 θ = 0
dθ v
= +ve True 1
(C) (aB)x = –ve (from FBD or B) True ⇒ sin θ = ⇒ θ = 30°
2
(D) aCB is along the incline up True ⇒ ∠ from stream direction = 120°
Q aBC is along the incline down.
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3. 0009 1 2
T

v=
ds 2 ∫
aT = bt cos θ.dt

dt a θ at 0
A 1
T

t
bt
2 ∫
(a / b)T 2 = t cos θ.dt ...(2)
∫ ds = v dt∫
0
b θ 0
Put value from eq. (2) into eq. (1)

1 2 1  bT 2 − 2l 
t
aT / b =  
 (Q S=l )
S = v dt ∫
0
B 2 a 2 
Put value a and b, l = 8 m
vBA = vB – vA = bt – at cos θ
1 1  3T 2 − 16 
T .1.T 2 / 3 =  

bT 2
T 2 1 2 
∫
S = (bt − at cos θ).dt ⇒
0
S=
2 ∫
− at cos θ.dt
T= 6
0
T
bT 2 1
.b.T 2 ⇒ S = 9 m
∫
0
at cos θ.dt =
2
−S ...(1)
S=
2

MATHEMATICS
14. A,B
SECTION – A f (x) + sin x · f (x + π) = sin2x ....(1)
1. D x→x + π f (x + π) + sin(π + x) · f (x + 2π) = sin2(π + x)
 π  f (x + π) – sin x f (x) = sin2x ....(2)
–1 ≤ [sin x] . cos   ≤ 1 & domain of f(x) is R – (–1, 1)
 [ x − 1]  sin 2 x − f ( x )
 π  from (1) – f (x + π) =
so [sin x] . cos   = ± 1 sin x
 [ x − 1]  from (2) f (x + π) = sin2x + sin x · f (x)
 π  sin 2 x − f ( x )
so either [sin x] = 1, cos   = – 1 ∴ sin2x + sin x · f (x) =
 [ x − 1]  sin x
π sin3x + sin2x · f (x) = sin2x – f (x)
x = (4n + 1) ; [x – 1] = ± 1 f (x) [1 + sin2x] = sin2x (1 – sin x)
2
x ∈ [0, 1] ∪ (2, 3) sin 2 x (1 − sin x )
x∈φ ∴ f (x) =
1 + sin 2 x
 π  15. A,B,C,D
or [sin x] = – 1 ; cos   = 1
 [ x − 1]  denominator ≠ 0 & numerator
 π  (x4 + 3x2 + 2) − 2x (x2 + 1) = (x2 + 1) ((x − 1)2 + 1)
but cos   ± 1 , x ∈ φ
 [ x − 1]  1. (A) P, Q, R, S, T; (B) Q, R, S, T; (C) P, Q, R, S, T; (D) T
2. B SECTION – C
n4 + n + 1 n +1 1. 0001
( −1) n n! + 3
Lim 1+ x2
n→∞ (n + 1)! + 3n x ∈ [–1, 0] ; x + = – 2x ; x = –3 ± 2 2
2
Divide Nr & Dr by (n + 1)!. [|10 a|] = 1, 10
4
Also n + n + 1 is odd. 2. 0004
| (α + β) – (β + γ) |2 = | α – γ |2
8,9,10 C,A,A
p=4 p12 + p 22 − 2p1p 2 = p32 − 4q 3
2
8 + 2 [x] – [x] ≥ 0 ; ([x] – 4) ([x]+2) ≤ 0 or p12 + p 22 − p 32 = 2p1p2 – 4q3
–2 ≤ [x] ≤ 4 ; y ∈ [–2, 5)
12. A,B,C
|||ly p 22 + p 32 − p12 = 2p2p3 – 4q1
Maxmum value of 2y – y2 = 1 and p 32 + p12 − p 22 = 2p3p1 – 4q2
Maxmum value tan–1 (2y – y2) = π/4
Maxmum value 2tan–1 (2y – y2) π/2 adding p12 + p 22 + p 32 = 2 ∑ p1 p 2 – 4 ∑ q1
Maxmum value of sin–1 x = π/2
(p1 + p2 + p3)2 = 4[ ∑ p1 p 2 − ∑ q1 ]
⇒ only possibility & then
x = 1 & 2y – y2 = 1
x=1;y=1 3. 2010

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