Chemistry 482 Spring 2013 Problem Set 1 Due Friday, Feb.

1, 2013
Problem 1: At what wavelength does the maximum in the energy-density distribution function for a blackbody occur at a Temperature of 600 K? What is the color of a blackbody at this temperature?

Problem 2:

In a photoelectric eect experiment, a gold surface is irradiated with laser light with a wavelength of 186 nm . a. b. c. How much energy (in Joules) is contained in each photon of laser light? Given gold's work function of 4.3 eV, what will be the maximum velocity (in m/s) of the photoelectrons emitted? If the laser power is 30 mW, what is the maximum number of photoelectrons that can be released per second?

Problem 3:

In an electron microscope a beam of electrons is accelerated to a kinetic energy of 200,000 Volts and focused onto the sample specimen. What is the de Broglie wavelength for the electrons in this beam? If z = 2x + 3iy provide (a) Re(z*) (b) Re(z2) (c) Im (z2) (d) Re(z*z) Im(z*z)

Problem 4:

Problem 5:

Express the following numbers in the polar form z rei (a)14 (b)14i (c)9+3i (d) 9-2i

Problem 6:

Express the following numbers in the form z = x + yi (a) 18e18i (b) 2ei 2ei (c) 2ei 2ei

Problem 7:

Use Euler's formula, ei cos i sin , to show that

z n r n (cos i sin )n r n (cos n i sin n )

-r

.~

.,

:,. <3

.:: 2. ~~

~l";:)

IV\.

K,
-b
;:0...

_:1
"C

2"6~

~ Iv

,.... I(

Lf. '6 a v. 'v

""\..

b~

LL{v"i~t~
I
q

~A

1;.. r-

.V'

t-'\f".) "\.J

- \>~ '-

Cf:4..1

'A =- \

"'6'~ "--"

-=-")

IL
2. <6 1~ ,0
\

Iub-

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u- ~

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l'-_----

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3 . 2D

'J.- 10

\f'

c::

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-J'

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/.

_I'{

10 -12... m

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).

i=
(0)

,.2 'X

-t

3iif
R.e(J?(-3i~)=[3X

.
~

R(,)~"):::

2l
cr

(bl

Re..

U(l::: Re ( 2'X + 3i(j)

( .2')( + 37'(j.J-,

- Re ( 4rxZ
le)
()

T bi':x~

- G-?<~ - ~ f
:::

61;'51'1 -5

~.l

1in~(22)

l' 'Xg
2

o-r-

or

/2 ] ReC4i +q(/')
OT

Re

(2* ~):::::

Re ( 2')(+ 31'a ) (2X- 30~)::=

,
W)

.:rm
(4

'" i 4-::4? -+
Ul(. z.)
:=:

~1

~~.2

I~ ]

~) Z=
(Cf)

Ie iCP

l::= 0.+

'b

= O1ctan (t-)
OvfCtOJ) (0):= 0

r =: Jl:-. ~* =

~C\:2+ b;l

0.=-14 /

b=0

--II

r= 14 :::
= 14-]

0=-0

. ~ r~'~j
b= 3

b = 14

r== 14-

q, =

V,5 rut of

C\=-

q/

r-= J-=--=-4\-3~ =- g, 4q ~_
cp:=
.

DJ'Ct-M
f).

(q)

:.:= 0, 32{

Y'ad

'. _~=
[~

qJf-g e

~~llTil J.
::::: CJ ,2:2

Cr=

q -' b = -2
-=

r== j q:>.+ (-2)2

OJ'c-twJ
'<

(~2 )

= -

o. 2/g

rad