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Article history:
Received 11 January 2010
Received in revised form
19 August 2010
Accepted 18 September 2010
Available online 25 October 2010
Biochar production and mixing in soil are seen as the best options for atmospheric carbon sequestration,
providing simultaneous benets to soil and opportunities for distributed energy generation. The proximity of biomass source and biochar dispersal greatly reduces the energy and emissions footprint of the
whole process. The viability of the whole biochar process is examined from two boundary points: is there
enough biomass around to have signicant impact on the atmospheric CO2 levels and is there enough
soil area for biochar dispersal. The answers are soundly positive, both for the world as a whole and for
Canada, for which a more detailed analysis was done. However, the massive adoption of biochar solution
is critically dependent on proper recognition of its carbon sequestration impact its soil improvement
potentials. To that extent the International Biochar Initiative, together with national chapters, including
recently formed Canadian Biochar Initiative, are actively promoting biochar related research and policy
framework. This paper addresses the questions of availability of sources and sites that would benet
from its dispersal.
2010 Elsevier Ltd. All rights reserved.
Keywords:
Biochar
Carbon sequestration
Global warming
Forestry
Forest re
Biomass
1. Introduction
Current trend in atmospheric CO2 concentration calls for
dramatic reduction in anthropogenic CO2 emissions in order to
avoid runaway scenario of potentially catastrophic temperature
and sea level rise. The annual mean CO2 growth rate was signicantly higher for the period from 2000 to 2005 (4.1 0.1 Pg/yr),
compared with the ux in the 1990s (3.2 0.1 Pg/yr), even though
only 45% of combined anthropogenic emissions have remained in
the atmosphere, the rest being naturally sequestered by terrestrial
and oceanic systems ([1], p. 515). In addition to curbing the fossil
fuel and cement industry CO2 emissions, several strategies for CO2
sequestration are being proposed. A special IPCC report on carbon
capture and storage (CCS) [2] lists seven climate change mitigation
options: carbon capture and storage, energy efciency, switch to
low-carbon fuels, nuclear power, renewable energy, enhancement
of biological sinks and reduction of non-CO2 greenhouse gas
emissions. Of these options, only enhancement of biological sinks
and CCS from biomass combustion products can remove CO2
already in the atmosphere. Other mitigation options only reduce or
prevent further emissions. CCS is energy intensive option requiring
additional emissions associated with carbon capture. A natural gas
power plant (even when in combined cycle) emits equal or less
amount of CO2 than the one run on coal, with CCS [3]. It is estimated
that CCS in Europe in 2020 will result in an increase in the
production cost of electricity by coal and natural gas technologies of
30e55% [4]. Little is known about the long-term storage issues [5],
from slow seepage into the atmosphere or sea water to the catastrophic release as in the case of LakeNyos disaster [6]. Overall, CCS
has many obstacles to overcome, if it was to become a viable carbon
emissions reduction strategy, and even then, the expected time
frame for full implementation may be around 2050 [2]. Other
proposed methods include injecting CO2 into chemically reactive
rock, even dead wood burial [7].
Production and deposition of biochar (or black carbon, as it is
sometimes called [8]) into the soil are rapidly gaining recognition as
a viable option in permanent carbon storage, while its benets to
soil fertility continue to emerge.
A number of methods can be used for producing biochar.
Modern biochar is a product that can be manufactured from
almost any uncontaminated organic matter, such as crop residues,
bark, stem timber (logs), non-stem logging residues (bark,
branches, tree-tops), various grasses and agricultural plant residues. The main processes for modern char production are fast or
slow pyrolysis (biomass heating without air or oxygen) or gasication (run in the regime that leaves charcoal residue). Biochar
production is typically self sufcient in energy requirements and
can produce surplus energy as heat or biofuel for use in various
energy conversion processes, including transportation and electricity production.
2012
2013
Fig. 1. The global annual carbon cycle with anthropogenic uxes adjusted for the 2000e2005 period, showing the main annual uxes (arrows) and reservoir sizes (gures in boxes).
All units are in GtC for reservoirs and GtC/yr for uxes. Pre-industrial natural uxes and reservoir sizes are shown in black, anthropogenic ones are shown in red. Source: IPCC
Fourth Assessment Report, 2007, p. 515, adjusted with Tables 7.1 and 7.2 data from the same report.
analysis data. The effect of black carbon on the soil fertility is still
based mostly on anecdotal evidence, albeit strong one. McCann et
al. [24] attribute the benets to the introduction of charged (active)
surfaces and the increase in soil pH, suppressing Al activity toxic to
soil biota. Glasser et al. [23] attribute longevity of black carbon in
the Terra preta soil to the carbon polyaromatic structure, making it
chemically and microbially resistant, able to survive in the environment over thousands of years. Complex structure and
morphology of the charcoal are illustrated by the sample taken
from a ponderosa pine forest in Northern Idaho, which was
exposed to re 79 years prior to collection [25], Fig. 2. As more
research is done in correlating the crops yield with mixing of biochar into the soil, there will be more solid experimental evidence,
and certainly additional best practice recommendations.
Laird [26] offered an interesting paradigm change by arguing
that the biomass debate should shift from the current how much
Table 1
Potentials for worldwide carbon sequestration via biochar production and dispersion over agricultural land.
Item
Value
Comments
2014
can be harvested without doing too much damage into how to design
integrated agricultural biomass-bioenergy systems that build soil
quality and increase productivity so that both food and bioenergy
crops can be sustainably harvested.
3. Potentials for carbon removal: Canada
Canadian CO2 emissions history in a post-Kyoto period is illustrated in Fig. 3 [27]. It is clear from the graph that the trend of CO2
emissions has been the opposite from the Kyoto targets for the
most of the post-Kyoto period. Small temporary drops in the 1991
and 2001 can be explained mainly by economic downturns, while
the drop in the 2004e2006 period illustrates the major contribution of tar-sands to the overall Canadian emissions. The data for
total above do not include land use, land-use change and forestry
(45 Mt CO2 [27]) and Canadian share of international aviation
(w7 Mt CO2, assuming total aviation as 2% of total emissions, i.e.
w15 Mt CO2 minus 7.7 Mt CO2 emissions from domestic aviation,
already included in the total). These sources add up 50 Mt CO2/yr, or
6.7% of the reported total. Together, the new total becomes
w797 Mt CO2/yr, or 217 Mt C/yr (conversion factor 3.67 tCO2/tC).
We will examine here if conversion of biomass from forest and
agricultural sources could offset this total.
Using the same assumptions as for the world production above
(Table 1) we would need approximately 271 Mt of bone-dry
biomass per year (producing w136 MtC/yr of biochar for dispersal,
i.e. converting 50% of the original biomass and offsetting additional
81 MtC/yr of emissions by displacing fossil fuel, i.e. 30% of the
original biomass e either as a syngas, methane or liquid biofuel).
Where would that biomass potentially come from? We next
examine 4 potential sources in Canada: forestry resources, forest
re reduction, pine beetle infested trees and agricultural residues.
2015
between 0.63 and 7.1 Mha [30], with the average of 2.33 Mha.
Compared to a typical harvested area of w1 Mha, the average area
under the re is more than twice the total harvested area! Using
average biomass density (95.4 t/ha), this represents the range of
60e676 Mt/yr, with the average of 222 Mt/yr or 82% of the total
target biomass. Can this amount or a portion of it be turned into
char instead of ash and dead biomass? Fire is a central part of the
life cycle of many Canadian ecosystems. Robust new trees quickly
emerge to replace the burnt aged forest. In some species (e.g. Pinus
banksiana), it also opens the seed cones, allowing the species to
reproduce and survive [30].
Annual CO2 emissions from forest res reported to the IPCC
were between 11 and 291 Mt CO2/yr in a 1990e2007 time span
[31]. These are apparently low values, since the emissions corresponding to the average forest density of 187 tCO2/ha would be an
order of magnitude larger (117 and 1327 Mt CO2/yr, respectively).
Clearly, only a small proportion of the biomass is immediately
burnt, but the remaining dead biomass continues to release GHG
gases slowly in subsequent years. For the most part, converting
biomass into biochar and spreading it locally would have similar
ecological impact as the wildre itself, with one substantial
difference: the organic carbon would be mostly converted into
inorganic, black carbon, instead of being pumped back into the
atmosphere as CO2, thus it would be a long lasting carbon
sequestration vehicle. How could that be done, to what extent it is
feasible to replace naturally occurring re, knowing fully well that
it is impossible to eliminate re altogether, should be a subject of
intensive research, technical innovation and public debate.
Here, we estimate that 20% of the total average area of forest
burnt annually could be converted to biochar, enlarging the re
corridors and achieving similar ecological impact as if that area
burnt naturally, but xing the biomass carbon instead of releasing it
to the atmosphere, either as an immediate release, or a slow release
due to the dead biomass decay. This amounts to 222 Mt/yr biomass,
representing 82% of the total target biomass that would fully offset
current Canadian GHG emissions.
Table 2
Sources of biomass in Canada, in absolute amounts and as a percentage of the pool of
271 Mt/yr, required to offset total Canadian GHG emissions from fossil fuels, cement
industry and land use.
Biomass source
Mt/yr
% of 271 Comments
Mt/yr
178.7
66
222
82
271
100
Agricultural residues
Fast rotation silviculture
44
840
16
310
Total
1555.7 574
This would represent 16% of the target biomass. While this may
look like a small amount compared with the other sources surveyed
above, this is the low hanging fruit in terms of biochar operations,
since the biomass is right where the biochar is needed most, i.e. in
the farmers elds.
3.5. Fast rotation silviculture
4. Conclusions
Biochar is indeed a viable carbon sequestration option for the
planet as a whole, as well as for Canada. The overall biomass
2016