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  • Kinket K Jum

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    Ary Susanto
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    The document contains data on the pressure (Pa) of gas over time (minutes) from an experiment. It then shows several methods to determine the reaction order from the data: 1) A cubic polynomial curve fit equation is determined with an R2 value of 0.9999. 2) The tabulated data is used to calculate reaction rates based on zero, first, and second order kinetics. 3) A plot of ln(-rA) vs ln(PA) is made and a linear regression yields a reaction order of 1.6 with an R2 value of 0.9854.

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    Kinket k Jum

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    The document contains data on the pressure (Pa) of gas over time (minutes) from an experiment. It then shows several methods to determine the reaction order from the data: 1) A cubic polynomial curve fit equation is determined with an R2 value of 0.9999. 2) The tabulated data is used to calculate reaction rates based on zero, first, and second order kinetics. 3) A plot of ln(-rA) vs ln(PA) is made and a linear regression yields a reaction order of 1.6 with an R2 value of 0.9854.

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    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    6 views4 pages

    Kinket K Jum

    Uploaded by

    Ary Susanto
    The document contains data on the pressure (Pa) of gas over time (minutes) from an experiment. It then shows several methods to determine the reaction order from the data: 1) A cubic polynomial curve fit equation is determined with an R2 value of 0.9999. 2) The tabulated data is used to calculate reaction rates based on zero, first, and second order kinetics. 3) A plot of ln(-rA) vs ln(PA) is made and a linear regression yields a reaction order of 1.6 with an R2 value of 0.9854.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 4

    800

    t (menit) Pa (mmhg)
    f(x) =700- 0.1278409091x^3 + 5.45995671x^2 - 90.3273809524x + 759.696969697
    0
    760
    R =600
    0.9999200355
    2
    600
    500
    4
    475
    400
    Pa (mmHg)
    6
    390
    300
    8
    320
    200
    10
    275
    100
    12
    240
    0
    0
    2
    4
    6
    8 10 12 14 16
    14
    215
    t (menit)

    Persamaan --> -0,1278x3 + 5,46x2 -90,327x + 759,7


    Deferensial --> (-3(0,1278)^2) + (2(5,64)^1) - (90,327)

    Dengan Cara Tabulasi


    Orde = 0 --> PA = PA0 - K0 t --> K0 = (PA0 - PA)/t
    Orde = 1 --> PA = PA0 EXP (-K1 t) --> K1 = (ln PA0 -ln PA)/t
    Orde = 2 --> 1/PA = 1/PA0 + K2 t --> K2 = (1/PA - 1/PA0)/t
    t (menit) PA
    0
    2
    4
    6
    8
    10
    12
    14

    (mmHg)
    760
    600
    475
    390
    320
    275
    240
    215

    ln PA
    K0
    K1
    K2
    6.633318
    0
    0
    0
    6.39693
    80
    0.118194 0.000175
    6.163315
    71.25
    0.117501 0.000197
    5.966147 61.66667 0.111195 0.000208
    5.768321
    55
    0.108125 0.000226
    5.616771
    48.5
    0.101655 0.000232
    5.480639 43.33333 0.096057 0.000238
    5.370638 38.92857 0.090191 0.000238

    -rA
    90.327
    70.0206
    52.7814
    38.6094
    27.5046
    19.467
    14.4966
    12.5934

    ln rA
    4.503436
    4.248789
    3.966159
    3.653496
    3.314353
    2.968721
    2.673914
    2.533173

    ln PA
    6.633318
    6.39693
    6.163315
    5.966147
    5.768321
    5.616771
    5.480639
    5.370638

    5
    4.5
    4
    3.5
    3
    2.5
    ln rA
    2
    1.5
    1
    0.5
    0

    f(x) = 1.6183140939x - 6.1049625745


    R = 0.9854382384

    Orde = 1.6
    Maka ;
    K = 0.002232 -rA = 0,002 PA^1,6

    5.2

    5.4

    5.6

    5.8

    ln PA

    6.2

    6.4

    6.6

    6.8

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