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CHEMISTRY STPM Trial First Term 2013
CHEMISTRY STPM Trial First Term 2013
NAMA SEKOLAH
Name : .
Form :
SUMMATIVE ASSESSMENT
FIRST TERM
STPM
2013
CHEMISTRY 962/1
One hour and a half hours
2
Section A [15 marks]
Answer all questions in this section.
12
14
C and
Stability
Nuclear charge
Nucleon number
Relative isotopic mass
Relative
intensity
20
40
60
80
m/e
Which of the following unknown organic compound will release a spectrum as the one shown
above?
A
B
C
D
3
C4H8
C8H16
C10H20
C10H22
Vanadium has the electronic configuration of 1s22s22p63s23p63d34s2. Which ion does not exist?
A
VO42-
B VO3-
VO2+
D VO2+
The energy-level diagram for a hydrogen atom shows several electronic transitions with frequencies
f1, f2, f3, f4 and f5.
Energy
n=
n=4
n=3
f4
f1
f2
n=2
f5
n=1
f3
I and II
I and IV
II and III
III and IV
Based on the band theory, the conductivity of metal is due to delocalized electrons in the conduction
band. How many electrons are found in the conduction band of a 10.0 g magnesium metal strip?
[Relative atomic mass of Mg is 24.0; Avogadro constant is 6.02 x 1023 mol-1]
A
2.51 x 1023
5.02 x 1023
C 2.51 x 1024
Sulphur.
Diamond.
Sodium chloride.
Magnesium oxide.
3.01 x 1024
[III]
2-
S
O
O
H
B
C
D
F
F
H
The diagram above shows the body-centred cubic structure of a unit cell. How many atoms are there
in the unit cell above?
A
9
B 2
C 3
D 4
Fraction of
molecules
T2
T1
Ea
Energy
At temperature T1,
I
II
III
IV
I and II
I and IV
II and III
III and IV
Pressure / Pa
611
O
A
Temperature / K
273.16
What can you deduced from the phase diagram?
A
B
C
D
11
The kinetic data for the reaction A + 2B C at a certain temperature is shown in the following
table.
Experiment
1
2
3
Initial
cencentration
[A]o
[B]o
a
b
2a
b
a
2b
Initial rate of
reaction
r
4r
r
k[A]2
B k[B]2
C k[A][B]2
D k[A]2[B]
A 2.0 dm3 stoppered flask at T oC contains 0.50 mol of SO2, 0.010 mol of O2 and 4.6 mol of SO3 at
equilibrium. Calculate Kc for the following equilibrium at T oC.
2SO2 (g) + O2 (g)
A
B
C
2SO3 (g)
D
1.7 x 104 dm3 mol-1
13
14
The solubility product, Ksp of magnesium hydroxide in pure water at 25 oC is 2.0 x 10-11 mol3 dm-9.
What is the solubility of magnesium hydroxide when an excess of solid magnesium hydroxide is
shaken in 1 dm3 of 0.1 mol dm-3 sodium hydroxide?
A
B
C
D
15
1.0
1.0
Mole fraction
Trichloromethane
Benzene
Ethanol
Carbon disulphide
Q
Propanone
Methylbenzene
Water
Propanone
Percentage
abundance
(a)
Write the formula of ions responsible for each of the peaks labelled A, B, C and D.
[2 marks]
(b)
A : -----------------------------
B: ---------------------------------
C: ------------------------------
D: ---------------------------------
(i)
(ii)
(c)
relative atomic
The four naturally occurring stable isotopes of iron are given in the table below.
Relative atomic mass
Relative abundance / %
[2 marks]
53.94
5.82
55.93
91.80
56.94
2.10
57.93
0.28
Determine the
mass of iron.
17.
The diagram below represents the energy levels of the orbitals in atoms of the third period.
Energy
(a)
Indicate the type of orbitals at each energy level electrons in the diagram above.
[2 marks]
(b)
Draw and label all the possible shapes of orbitals at the energy level, n = 2.
[4 marks]
(c)
In the above diagram, mark the valence electron configuration for phosphorus, using arrows to
represent electrons in the diagram above.
[3 marks]
(a)
Ammonia is a colourless gas with a pungent smell. It reacts with hydrogen ions in acids to form
ammonium ions, NH4+. Draw a Lewis structure for ammonia and the ammonium ion.
[2 marks]
(b)
The HNH bond angles in ammonia and ammonium ion are 107 and 109.5 respectively.
Explain the difference in these bond angles.
[4 marks]
(c)
The reaction between fluorine and nitrogen dioxide was carried out at T K.
F2(g) + 2NO2(g)
2NO2F(g)
The following data were obtained when the reaction was carried out using different
concentrations of the gases.
(a)
[4 marks]
[ 1 mark ]
[4 marks]
Nitrogen monoxide, NO can be prepared from the reaction between nitrogen and oxygen.
N2(g) + O2(g)
2NO(g)+
H = +180.5 kJ
State how (i) Kc and (ii) the amount of NO will change when an equilibrium mixture of N 2, O2 and
NO is subjected to the following changes.
(i)
(ii)
(iii)
(iv)
More O2 is added
The volume is increased
The temperature is decreased
A catalyst is used
[8 marks]
(b)
H2(g) + CO2(g)
2.20 mol of CO(g) and 1.71 mol of H2O are placed in an empty 1.00 dm3 flask at T C. After
10
equilibrium was reached, the concentration of CO was 0.78 mol dm -3. Calculate
(i)
(ii)
(iii)
20.
[2 marks]
[2 marks]
[3 marks]
(a)
(i)
(ii)
(b)
A 25.0 cm3 sample of saturated, aqueous magnesium hydroxide required 19.2 cm3 of 0.050 mol dm-3
hydrochloric acid for neutralisation. Calculate
(i)
(iii)
[2 marks]
[2 marks]
(c)
The buffer system, H2PO4 - / HPO4 2- in blood helps to keep the pH of blood at about 7.40.
(i)
(ii)
[3 marks]
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12