Practice 9-1

Name each of the following acids:

OH
a) CH3CH2CF2CH2COOH

b) CH3 - CH2 - CH - COOH

COOH

COOH
c)

d)
HO

CH3

OH

NH2
e) CH3 - CH - COOH

f)

OH

Answer
a) 3,3-difluoropentanoic acid

b) 2-hydroxybutanoic acid

c) 3,4-dihydroxybenzoic acid

d) 3-methylbenzoic acid

e) 2-aminopropanoic acid

f) 2-ethylhexanoic acid

Practice 9-2
Complete the following reaction and name the carboxylic acid salt formed.
CH3 - CH2 - COOH + NaOH

Answer

CH3 - CH2 - COOH + NaOH

CH3 - CH2 - COO Na + H2O

sodium propanoate

9-1

Practice 9-3
Complete the following esterification reaction:
[H+]

O
OH

CH3 - CH2 -OH

Answer
removal of OH
and H produces the ester
O

[H+]

OH + CH3 - CH2 -OH

O- CH2 - CH3

+ H2O

Practice 9-4
Write the name for each of the following esters.
O
a) CH3(CH2)6 CH2COCH 3

b)

O
CO

CH3
CH
CH3

O
c)

O
OCH 2CH3

d) CH3CH2CO

CH 2CH2CH3

Answer

a) methyl octanate

b) isopropyl benzoate

c) ethyl butanoate

e) propyl propanoate

9-2

Practice 9-5
Complete the following reactions:
O

H+

CH3CH2-C-OCH2CH3 + H2O
O

H2O

CH3CH2-C-OCH2CH3 + NaOH

Answer
O
CH3CH2-C-OCH2CH3+ H2O
O
CH3CH2-C-OCH2CH3+ NaOH

CH3CH2-C-OH +

CH3CH2OH

H2O

CH3CH2-C-O Na +

CH3CH2OH

Practice 9-6
Name each of the following:
NH2
a)

NH2

b)

Br
Br

c) CH3(CH2)5-NH-CH2CH3

d)

Answer
a) cyclopentylamine

b) 3,4-dibromoaniline

c) ethylhexylamine

d) diethylmethylamine

9-3

Practice 9-7
Name each of the following amides:
O
O H

C - NH - CH2-CH3

a) CH 3 - C - N

b)
O

c) CH3 - CH2 - CH3 - CH2 - C - NH

Answer

a) N-cyclohexylacetamide
c) N-isopropylpentanamide

b) N-ethylbenzamide

Practice 9-8
Draw the structures of the products in each of the following hydrolysis reactions.
O
C - NH 2

heat

+ HCl

+ H2O
O
CH3 - CH2 - C - NH - CH3

heat
+ NaOH

Answer
O

O
C

NH2
+ H2O

+ HCl

O
CH3 - CH2 - C - NH - CH3 + NaOH

heat

heat

OH
+ NH4+Cl-

O
-

CH3 - CH2 - C - O Na + CH3-NH2

9-4