PAPER Adva PI Sol PDF

1
FIITJEE
JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
CRTI
(Paper-1)
Q. No.
ALL INDIA TEST SERIES
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students
from Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
AITS-CRT-I(Paper-1)-PCM (Sol)-JEE (Adv)/14
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
A.
9.
10.
11.
A, B, C
A, C
A, B, C
12.
A, B, C, D
B, C
A, B, C, D
13.
B, C, D
A, C
A, D
14.
A, B, C
A, B, C
B, C
15.
A, B, C
A, C
B, C
1.
2.
3.
4.
5.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
1.
Urel g t 10 1
= 10 m/s
1
S1 g(1) 5m
2
1
Srel S1 ure are t 2 = 5 + 10 3 + 0 = 35 m
2
2.
sin =
mgh = mg cos (/2)
/2
/2
h cos
tan =
2
3.
4.
5.
6.
Centre of mass does not move in the absence of external force so

m1x1 = m2x2
x1 m 2
x 2 m1
dA1 r 2 d r 2

dt
2 dt
2
2
L = Mr
L = 2MA
A
Gm(M m)
0
r2
dF G
(M 2m) 0
dm r 2
M = 2m
m = (M/2)
Ag
s
A
s
g
h
7.
ghr 2 (2rdh)gh
0
ghr 2 2rg
r2
h2
2
h
2
r=h
3
8.
Avg. speed 3
(v r t)2 (v mr t)2
t
v 2r 5 9
vr 2m / s
1 t
1
v v
3v
2
2
2
t
4
9.
v avg
10.
m
m
gT a
2
2
T cos 60 =
(i)
ma
cos 60
(ii)
Solving (i) and (ii) acceleration of ring =
11.
2kq2
mv 2
T
2
R
R
1
1
mgR + mu2 mgR mv 2
2
2
(i)
mg
if T = 0 umin 5gR
12.
2g
9
(ii)
2Kq2
mR
dU
5(2x 4)
dx
At mean position F = 0 x = 2m
Umin 20 J
F
a = 50 2(x 2)
= 10 rad/sec
T = /5 sec
V
g mg
(i)
3
If the volume immersed when the system accelerates is V then
g
mg
V
V ' g mg
V'
2
2
3
13.
If the volume immersed initially is (V/3). Then
14.
The potential of the two surface will be equal when the whole charge Q flows from inner to other
shell.
SECTION C
1.
Consideration refraction at glass-water interface
2 2 1
v
u
R
4
3
( 4 / 3) ( 3 / 2)
3v 2r
r
(27r/20)
(4/5)r
4
4
3
1
3v 2r
6r
v=
r
5
Now refraction at water air surface
4
9r
r
5
5
2 1 2 1
v
u
1 4 5 1 ( 4 / 3)
v 3 9r
1
20
v
27r
27r
v=20
u = - r
so height above centre = 2r =

2.
27r
20
40r 27r
13
=
r = 13 cm.
20
20
Mg T = Ma
T mg = ma
2Mmg
T=
(M m)
T
2Mmg
A A(M m)
(i)
(ii)
2mg
2 109
m
A 1
M
m
M
M = 1.86 Kg
3.
Relative motion between block and table

will start when
m2 r sin (mg m 2r cos ) (i)
t (ii)
solving (i) and (ii)
t 500 22.4 sec .
3 cm
m r
g
= 1 rad/sec
R
4.
5.
N1 + N2 = mg
N1 = N2
mg
N2 =
1 2
N1 =
4 cm
. . . (1)
. . . (2)
N1
N2
N1
mg
1 2
N2
mg
Torque about centre of mass

5
1
mR2
2
2 N1 N2
2 1 g
=
=
mR
1 2 R
(N1 + N2)R =
2 = 20 2
=
=
20
2
20 1 2 R
2 2 1 g
Hence number of turns

02R 1 2
N=
=
2
4 1 g.2
N=
20R 1 2
8g 1
Chemistry
PART II
SECTION A
1.
In A bond is at bridge head which is not stabilized in the given structure;

CN
In B the product is
;
ACOH
In D the product is
HO
2.
O
H 2N
OH
NH2
OH
IMPT
5.
HO
OH2
NH
H2 O
OH
N
H O
N
HO
CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.
PCl5 g
PCl3 g Cl2 g
6.
Let initially no. of moles
at equilibrium volume V
x
x 1
OH
6
Kc
x 2 2
n
, also Kp = Kc(RT) g
x 1 V
V
, initial concentration of PCl5 doubles and its degree of dissociation is
2
increased but Kp does not change, as it is characteristic constant for a reaction at constant
temperature.
on reducing volume to
7.
Al2Cl6 12H2 O
2H3 Al OH 6 6HCl ;
10.
In blast furnace,
In combustion zone, CO is produced ultimately which reduce Fe2O3 to Fe3O4 in reduction zone,
which is uppermost zone.
11.
P=
Q=
O
R=
CH3 COOH C 2H5 OH ;
Oxidation by XO
C2H5 OH
CH3CHO
O
O
S=
12.
Due to hydrogen bonding Gauche conformation of H2C
CH2
NH2and H C
2
NH2
CH2F
OH
are more stable than their anti-conformations.

In case of ClCH2CH2Cl, on increasing temperature, % of Gauche conformation increases. Hence
dipole moment increases. In case of option (D) boat conformation is most stable.
13.
Mn appears colourless in reducing flame in Borax Bead Test.

Fe3 K 4 Fe CN6 Fe 4 Fe CN 6 K
Prussian blue
Na2 S2O3 .5H2 O

Na2 S5 Na2 SO4 H2 O
14.
At pH = pI, amino acid exists as Zwitter Ion, they are highly soluble in polar solvents.
7
15.
pH of 108 M HCl (aq) is 6.96 and pH of 108 M NaOH (aq) is 7.04
1.
= CRT i
hence i = 1.1; so = 0.1
hence [H+] = c = 0.1 0.1 = 102 M
pH = 2
2.
It has only one CH2OH group.
3.
Three equivalents to remove three hydrogens from CH3 group and one for attack on C of CHO
group.
4.
BaCrO4 Yellow, soluble in dil HNO3

Hg2CrO4 Red, soluble in conc. HNO3
ZnS White, soluble in Conc. HNO3
BaSO4 White, insoluble in all mineral acids
BaS2O3, CH3COOAg and AgNO2 all are white solid and are soluble in dilute HNO3 solution.
SECTION C
Cl
5.
Except
and
Cl
Mathematics
PART III
SECTION A
1.
[y + [y]] = 2 cosx [y] = cosx

1
y = [sinx + [sinx + [sinx]]] = [sinx]
3
[sinx] = cosx
Number of solution in [0, 2] is 0
Hence total solution is 0.
both are periodic with period 2
2.
(x 0)2 + (y k)2 = k2
x2 + (y k)2 = k2
dy
2x + 2 (y k)
0
dx
dy
x
dx
y k
yk=
k=y+
xdx
dy
xdx
dy
8
2
xdx
xdx
x2 + y y
y
dy
dy
dx
dx
2xydx
x + x y2 x 2
dy
dy
dy
2xydx
x 2 = y2 +
dy
2
(x2 + y2)
dy
2xy 0
dx
3.
Given < < < also sin = sin = sin = sin = k

and , , , are smallest positive angles
= , = 2 + , = 3
as sin = sin and >
sin = sin and >
sin = sin and >
Putting these values in the given expansion, we have given expression
= 2 sin cos 2 1 sin 2 1 k

2
2
4.
x3 x < a2 + a
2
3 3
f(x) = x3 x
f(x) = 3x2 1 = 0
1
x=
3
In positive region minimum value of f(x) =
So, a2 + a
2
3 3
>
1
3 3
2
3 3
2
3 3
a2 a < 0
a (0, 1)
5.
6.
3x 2 4x 4 5x 1 4x 5
v
u
p
q
u2 v2 = x + 6 = p2 q2
uv=pq
solving (1) and (2)
we get, 2 4x 4 2 5x 1
x=3
(1)
(2)
Limit be equal to y
1
logy = lim log n 1 log n 2 ...
n n n
n
n
n r
1
1
lim
= lim
log
n n r 1 n
n n
log 1 log 1 x dx
r 1
0
9
4
= . 2 log2 = [log4 loge] = log
2
e
4
logy = log
e
, represent the region of complex plane lying in the first quadrant and bounded by x4
axis and the line y = x
|2z 4i| = 2|z 2i|
least value of |z 2i| is length of perpendicular from (0, 2) to y = x, which is 2
So the least value of 2 |2z 4i| is 4
7.
0 argz
8.
Let f(x) = 2x3+ 3x2 12x + 3

f(x) = 0 has three real roots (, , )
3
++=
2
1 1 1
= , , which lies on x = y = z.
Centroid =
,
,
3
3
3 2 2 2
9.
If a > b > c and a2 = b =
c then b < 1 cot1x < 1 x > cot1
10.
a 4sinA
11.
a, b and A are given in ABC,

b2 c 2 a2
cos A =
2bc
c2 2bc cos A + (b2 a2) = 0
c2 (2b cos A)c + (b2 a2) = 0
which is quadratic in c and gives two values of c and let these are c1 and c2
c1 + c2 = 2b cos A
and c1 c2 = (b2 a2)
c12 c 22 2c1c 2 cos2A
= (c1 + c2)2 2c1c2 (1 + cos 2A)
= 4b2 cos2 A 2 (b2 a2) (2 cos2 A)
= 4b2 cos2 A 4b2 cos2 A + 4a2 cos2 A
= 4a2 cos2 A
a
4 R2
sin A
so for any point (x, y) inside the circumcircle, x 2 +y2 < 4
|xy| < 2
12.
2 5
1
5 8
1
8 11
n terms
5 (n 1)3 2 (n 1)3
5 2
8 5
11 8

3
3
3
3
3n 2 2
3n 2 2
3
3 3n 2 2
n
3n 2 2
10
13.
2 3n 2
n
3n
24 R 2

R 2 1 cosec
24
sin
sin cos
2
2
(A) is true
1 cosec
sin A
(D) is true
14.
x2 + x + 1 = |[x]|
Hence only 2 solutions exist
i.e. x = 1 and another lie 2 < x < 1
15.
sin x + cos x = 1 a sin x cos x

a2 sin2x cos2x 2(a + 1) sin x cos x = 0
2
sin2x a sin 2x 2 a 1 = 0
2
Hence sin2x = 0 a R
n
x=
,nI
2
4 a 1
And sin2x =
a (, 2 2 2 ] [2 + 2 2 , )
a2
SECTION C
1.
a=
, b
2
r 1
a=
r 1
1
2
1
2
... and b =
1
2
1
2
1
2
1 2
3
4
1 3
5
72
1
1
1
1
1
1
1
b = 2 2 2 2 ... 2 2 2 ...
3
4
4
6
1 2
2
1
1
1
1
1
1
1
b = 2 2 2 2 ... 2 1 2 2 ...
3
4
3
1 2
2 2
1
b=a a
4
3
b = a
4
a 4
b 3
2.
(2r 1)
...
f 1(x)dx t f (t)dt
11
= t f t 0 t sin t dt
= 2
1 1
2
2
2
2
k=2
=
3.
Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers

4
= 3 P4 = 72
Case II: When we use 5 at ten thousand place and 6, 7 or 8 at thousand place then number of
numbers is
= 1 3 3P3 = 18
hence the required numbers of numbers is 72 + 18 = 90
4.
f(x) is an odd function

g(x) is f 1(x)
2
Area =
f 1 y dy
2
= x f x 0
5.
x f x dx
0
x sin x dx = 22
2 2 2

a b b c c a = 2 a2 b2 c 2 2 a b b c c a

= 2(4 + 9 + 16) 2 a b b c c a

= 58 2 a b b c c a .
2
Now a b c 0

a2 + b2 + c2 2 a b b c c a

2 a b b c c a 29
2 2 2
a b b c c a 87

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ALL INDIA TEST SERIES

AITS-CRT-I(Paper-1)-PCM (Sol)-JEE (Adv)/14

mgh = mg cos (/2)

Centre of mass does not move in the absence of external force so

Solving (i) and (ii) acceleration of ring =

If the volume immersed initially is (V/3). Then

Consideration refraction at glass-water interface

Now refraction at water air surface

so height above centre = 2r =

Relative motion between block and table

Torque about centre of mass

Hence number of turns

In A bond is at bridge head which is not stabilized in the given structure;

CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.

CH3 COOH C 2H5 OH ;

Due to hydrogen bonding Gauche conformation of H2C

are more stable than their anti-conformations.

Mn appears colourless in reducing flame in Borax Bead Test.

Na2 S2O3 .5H2 O

pH of 108 M HCl (aq) is 6.96 and pH of 108 M NaOH (aq) is 7.04

It has only one CH2OH group.

BaCrO4 Yellow, soluble in dil HNO3

[y + [y]] = 2 cosx [y] = cosx

Given < < < also sin = sin = sin = sin = k

= 2 sin cos 2 1 sin 2 1 k

Let f(x) = 2x3+ 3x2 12x + 3

If a > b > c and a2 = b =

c then b < 1 cot1x < 1 x > cot1

a, b and A are given in ABC,

sin x + cos x = 1 a sin x cos x

Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers

f(x) is an odd function

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