Useful Information

Constants and Conversion factors:

Speed of light

c=3.00 10 m s

Plancks constant h=6.626 1034 J s

Avogadros number

N A =6.022 1023

Gas constant

R=0.08314 L mol K =8.314 J mol K

Length

1 nm=1109 m

Pressure

1 pm=1 1012 m

1 0.9869 atm=750.01Torr=100 kPa

Energy

1 L 100 J

Equations
H= U + P V
U =q+W

W =P V

E=h

h=KE+

E=2.18 1018

1 1

n2f n2i

Ptot =P1 + P2+

n=2d sin

q=m C s T

q=C T

h
mv

xm v=

K . E .= m v 2

ln

P2 vap H
=
P1
R

( )

(Daltons law)

h
4

c=

( T1 T1 )
2

Psoln =X solvent Posolvent (Raoults law)

(Braggs law)

For nonelectrolytes:

T b=K b m

T f =K f m

=MRT

Cubic unit cell edge lengths:

simple: l=2 r

body-centered:

o
o
o
r H =n f H ( products )n f H ( reactants )

l=

4r
3

face-centered:

l=2 2r

CHEM-1111 Final Exam Fall 2016

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