Scribd Logo
Upload

Welcome to Scribd!

  • Reaksi A. Reaksi Minyak + I: CH - O-C (CH) CH

    Uploaded by

    Mario Moore
    9 views10 pages
    The document describes several chemical reactions: 1) The reaction of iodine with various unsaturated fatty acid esters found in oils, which involves the addition of iodine across carbon-carbon double bonds over multiple steps. 2) The reaction of cholesterol with acetic anhydride and sulfuric acid, which forms acetylated products. 3) The reaction of bilirubin with nitric acid, which oxidizes bilirubin to form biliverdin and other products through multiple steps involving the loss of hydrogen atoms.

    Original Description:

    kimia

    Original Title

    Reaksi Lipid New_22

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    The document describes several chemical reactions: 1) The reaction of iodine with various unsaturated fatty acid esters found in oils, which involves the addition of iodine across carbon-carbon double bonds over multiple steps. 2) The reaction of cholesterol with acetic anhydride and sulfuric acid, which forms acetylated products. 3) The reaction of bilirubin with nitric acid, which oxidizes bilirubin to form biliverdin and other products through multiple steps involving the loss of hydrogen atoms.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    9 views10 pages

    Reaksi A. Reaksi Minyak + I: CH - O-C (CH) CH

    Uploaded by

    Mario Moore
    The document describes several chemical reactions: 1) The reaction of iodine with various unsaturated fatty acid esters found in oils, which involves the addition of iodine across carbon-carbon double bonds over multiple steps. 2) The reaction of cholesterol with acetic anhydride and sulfuric acid, which forms acetylated products. 3) The reaction of bilirubin with nitric acid, which oxidizes bilirubin to form biliverdin and other products through multiple steps involving the loss of hydrogen atoms.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 10

    2.

    Reaksi
    a. Reaksi Minyak + I2
    O

    CH2-O-C (CH2)14CH3
    O

    CH- O-C (CH2)7 CH=CH (CH2)7 CH3 + 3I2


    O

    CH2-O-C (CH2)7 CH=CHCH2CH=CH(CH2)4 CH3


    O

    CH2-O-C (CH2)14CH3
    O

    CH- O-C (CH2)7 CH=CH (CH2)7 CH3 + 3I - I


    O

    CH2-O-C (CH2)7 CH=CHCH2CH=CH(CH2)4 CH3


    O

    CH2-O-C (CH2)14CH3
    O

    H
    CH- O-C (CH2)7 C-C (CH2)7 CH3 + 3I + 3I
    O
    H
    H
    CH2-O-C (CH2)7 C-C CH2C-C (CH2)4 CH3
    H
    HH

    CH2-O-C (CH2)14CH3
    O

    H I
    CH- O-C (CH2)7 C-C (CH2)7 CH3 + 2I + 3I
    O
    H
    H
    CH2-O-C (CH2)7 C-C CH2C-C (CH2)4 CH3
    H
    HH
    O

    CH2-O-C (CH2)14CH3
    O

    H I
    CH- O-C (CH2)7 C-C (CH2)7 CH3
    O
    H
    H I

    + I + 3I

    CH2-O-C (CH2)7 C-C CH2C-C (CH2)4 CH3


    H
    HH
    O

    CH2-O-C (CH2)14CH3
    O

    I
    CH- O-C (CH2)7 C-C (CH2)7 CH3
    O
    HH
    H I
    I
    CH2-O-C (CH2)7 C-C CH2C-C (CH2)4 CH3
    H
    HH

    + 3I

    CH2-O-C (CH2)14CH3
    O

    I I
    CH- O-C (CH2)7 C-C (CH2)7 CH3
    + 2I
    O
    HH
    H I
    I
    CH2-O-C (CH2)7 C-C CH2C-C (CH2)4 CH3
    H
    HH

    CH2-O-C (CH2)14CH3
    O

    I I
    CH- O-C (CH2)7 C-C (CH2)7 CH3
    +I
    O
    HH
    H I
    I I
    CH2-O-C (CH2)7 C-C CH2C-C (CH2)4 CH3
    H
    HH

    O
    CH2-O-C (CH2)14CH3
    O
    I I
    CH- O-C (CH2)7 CH-CH (CH2)7 CH3
    O
    I
    I
    I
    CH2-O-C (CH2)7 CH

    CH CH2

    CH CH(CH2)4 CH3

    b. Kolesterol + Asam asetat anhidrat + H2SO4

    Kolesterol

    Asam Asetat Anhidrat

    c. Bilirubin + HNO3
    O

    O
    O

    H2C
    H3C

    H2C

    H3C

    CH3H3C

    Biliverdin

    HO

    N
    O

    HNO3

    O
    O

    H2C
    H3C

    H2C

    H3C

    CH3H3C

    + HO

    H
    O

    H2C

    H2C

    H3C

    CH3H3C

    H2C

    CH3H3C

    O H

    + HO
    -

    O
    -

    H2C

    H3C

    CH3H3C

    O H

    O
    O

    H2C

    H2C

    H3C

    H3C

    HO

    O
    O

    H3C

    O
    O

    H3C

    +
    -

    HO

    N
    O

    O
    O

    H 2C
    H3C

    H2C

    H3C

    CH3H3C

    + HO
    +

    H3C

    H2C

    H3C

    CH3H3C

    OH

    Bilirubin

    O
    O

    H2C

    + HO
    N

    N
    H

    N
    O

    You might also like