Lampiran Perhitungan

1. Pembuatan larutan baku asam oksalat

Diket : Massa C2H2O4 = 1,6080 gram
Mr C2H2O4 = 126 gram/mL
Volume C2H2O4 total = 250 mL
Volume C2H2O4 yang digunakan = 10 mL
Ditan : N C2H2O4 ?
Jawab: N C2H2O4 = M C2H2O4 x ev
Massa C 2 H 2 O 4 1000
= Mr x Volume C 2 H 2O 4 x ev

1,6080 gram 1000

= 126 gram/mL x 250 mL x1

= 0,0510 N

2. Normalitas NaOH (menentukan konsentrai larutan baku sekuder)

Diket : N C2H2O4 = 0,0510 N
V C2H2O4 = 10 mL
V NaOH = Erlenmeyer A = 8,0 mL
= Erlenmeyer B = 8,1 mL
= Erlenmeyer C = 8,0 mL
Ditan : N NaOH ?
Jawab :
A Molek C2H2O4 = Molek NaOH
MxVxn =MxVxn
0,0510 N x 10 mL x 2 = M x 8 mL x 1
N NaOH = 0,1275 N

B Molek C2H2O4 = Molek NaOH

MxVxn =MxVxn
0,0510 N x 10 mL x 2 = M x 8,1 mL x 1
N NaOH = 0,1259 N

C Molek C2H2O4 = Molek NaOH

MxVxn =MxVxn
0,0510 N x 10 mL x 2 = M x 8 mL x 1
N NaOH = 0,1275 N

(0,1275 N +0,1259 N +0,1275 N )

Rata-rata Konsentrasi NaOH = 3

= 0,1270 N

Perhitungan kadar CH3COOH dalam cuka merk DIXI

Diket : - N NaOH : 0,1270 N

- Massa Cuka merk DIXI

= (massa cuka dalam piknometer massa piknometer)

= (48,5406 gram 23,4420 gram)

= 25,0986 gram

- Volume Cuka merk DIXI : 150 mL

- Volume Cuka merk DIXI di erlenmeyer: 10 mL
- Volume piknometer : 25 mL
- Volume NaOH: A = 33,7 mL
B = 33,8 mL
C = 33,9 mL

Ditan : Kadar CH3COOH dalam cuka merk DIXI ?

Jawab:

massa cuka
P cuka = volume piknometer
25,0986
= 25

= 1,0040 gram/mL
Massa Cuka (sampel) = P cuka x V cuka di erlenmeyer
= 1,0040 gram/mL x 10 mL
= 10,04 gram

Titrasi A

Molek NaOH = Molek CH3COOH

N1 x V1 = N2 x V2
0,1270 N x 33,7 mL = N2 x 10 mL
N2 = 0,4280 N
N CH3COOH M CH3COOH

0,4280 N
0,4280 M
Gram CH3COOH = M x Mr x V

= 0,4280 mol/L x 60 gram/mol x 0,01 L

= 0,2568 gram
 0,2568 gram
% CH3COOH = 10,04 gram x 100 %

= 2,5578 %

Titrasi B
Molek NaOH = Molek CH3COOH
N1 x V1 = N2 x V 2
0,1270 N x 33,8 mL = N2 x 10 mL
N2 = 0,4293 N
N CH3COOH M CH3COOH

0,4293 N
0,4293 M
Gram CH3COOH = M x Mr x V

= 0,4293 mol/L x 60 gram/mol x 0,01 L

= 0,2576 gram

0,2576 gram
% CH3COOH = 10,04 gram x 100 %

= 2,5655 %

Titrasi C
Molek NaOH = Molek CH3COOH
N1 x V1 = N2 x V 2
0,1270 N x 33,9 mL = N2 x 10 mL
N2 = 0,4305 N
N CH3COOH M CH3COOH

0,4305 N
0,4305 M
Gram CH3COOH = M x Mr x V

= 0,4305 mol/L x 60 gram/mol x 0,01 L

= 0,2583 gram

0,2583 gram
% CH3COOH = 10,04 gram x 100 %

= 2,5727 %
Kadar rata-rata CH3COOH dalam cuka merk DIXI =
(2,5578 +2,5655 +2,5727)
3

= 2,5653 %