* * 2008

: . + . :
) (
03 :
- -

. I:
3.5) :(
10ml ) (HCl 1mol/L 20ml 250ml
Mg m=0.03g
) V(ml ) (t:
-1
)35 V(ml
Mg )(
30 ( Mg 2+ / Mg ), ( H + / H 2 ) :
25 -2 -
20 -
Srie2
15 - ) (mol
10

T= 20 0C P= 101300pa
5
)t(min .R= 8.318 SI
0
-3 - .
-
0

8
10

12

14

16

18

.
- t= 13min Vm= 22.4 L/mol
-4 10ml HCl 2mol/L 20ml .
- .
M(Mg)=24.3g/mol
4.5) :(
C 6 H 5 COOH R COOH )/( :
) .( R COOH / R COO
-1 -I .

-2 Ka ) ( R COOH / R COO
-3 Ka 25 0C 6.3 . 10-5 PKa.
-4 ) .( R COOH / R COO
-5 PH 6.0 .
-II )) ( Na (aq)+ OH-(aq
+

6/1
 CS= 2 . 10-1mol/L VS
PH
) PH=f(VS:
-1 .
-2 :
- )(
) (.
- ).(E

- PKa ) ( R COOH / R COO
)(3-I
-3
) n1(A ).n1(A
-4
-

8.2-10.0 3.2-4.4

.II:
4) :(
. U 238
238

-1 - Z A X Y .
N
- ) (4) (3
Po .
130 )(1 - ).(3
X - eV ).(4
128
(2) Bi -2 t=0 210
126 (3) Y m0=10mg
T= 138jours
)(4 -
124
Pb .t=0
- 99%
.
-

84 Po 82 Pb
206 214

N A = 6.02.10 23 mol 1 , m( 42 He) = 4.002u , m( 206

82 Pb) = 205.930u :

84 Po) = 209.937u , M ( Po ) = 210 g / mol , 1u 931.5 MeV

m( 210

3) :(

E=12V R= 100 K C
L . r

6/2
 -I :
t=0 ) (1
.-1-
-1 .
-2 . UC
-3 ) U C = U (1 e t / U
-4 .
-II :
) (2 t=0
UC -2-
-1 .
-2 T .L
-3 ) (L,C .t= 2ms
)U(V )U(V

5
-1-
-5
-2-
2
)t(ms )t(ms
2 1
5) :(
m= 54g V= 137cm g= 9.8m/s air = 1.3Kg / m 3
2 3

-I ) ( OZ .
t=0 . t=0
-1 ) (.
-2 h= 100m
.
-II :
. (K= 10-3 SI) f= Kv2 :
-1 .
-2 ) (v .
-3 . vL
-4 .t=0
-III v0= 11.1m/s

v0 = 45 0
M H= 0.5m
.
-1 ).Y(t) X(t
H -2 .
'
-3 h = 0.91m D= 11.89m
) (
- .
6/3

.I
3.5) :(
) MnO4 ( aq ) H 2 C 2 O4 ( aq
.( MnO4 ( aq ) / Mn 2+ ) ( CO2( aq ) / H 2 C 2 O4 ( aq ) ) :
-1 .
V1=20ml C1= 0.2mol/L
) ( V2= 20ml C2= 0.5mol/L
) C=f(t:
)C(mmol/L
100 -2 -
95
90 C0
85
80 .
75
70 - .
65
60 - .
55
50 -3 - ) x(t
45
40 ) C0 C(t V .
35
30 -
25
20 t=4min
15
10 )t(min .
5
0 -4 ) (
0 0,5 1 1,5 2 2,5 3 3,5 4 4,5 5 5,5 6 6,5 7 7,5 8 8,5 9
. t=4min
4.5) :(
HIO - ) ( HIO / IO PKa1=10.6 NH3
- ) ( NH 4+ / NH 3 PKa2=9.2 V1= 10ml S1
C1= 0.15mol/L S1 V2= 5ml S2
. C2= 0.1mol/L
-1 - S2 S1 .K
-2 - .
- Qr ,i .
- .
-3 - .
-
-4 - ) (.
- . f
- ) (.
.II:
4) :(
E= 6.0V
L r -1-
-1 ) (-1- UG=E
. UL

6/4
 'R

E=6V L,r E= 6V L,r

-2- -1-

-2 UL= 5.95V I= 410mA . r

-3 R'= 10 K -2-
) (t=0 )i(t
)i(mA :
-
). i(t
- .
-4 :
-
.L
- ) I0 (
- UL
. t= 10ms
-
. t= 10ms
)t(ms -5 r
E R' I0 .
2.75) :(
) (S m= 250g ) (R
K .
)(S
)(R ) (S X G
G ) (X'OX G O :

'X O
i
) (S ) ( O, i X
.
)VG(m/s
0,3 -1 -
0,25
).(S
0,2
0,15 - .
0,1 -2
0,05
)t(s ) VG (S t
0
-0.050,00
-0,05 0,25 0,50 0,75 1,00 1,25 1,50 1,75 2,00
:
-0,1 ) (S
-0,15 2
-0,2 (X (t ) = X m cos .t + ) :
T0
-0,25
-0,3 2 = 10

6/5
 :
- T0 . K
- Xm
- .
5.25) :(
2
. g= 10m/s
-I l= 40cm O ) (S
m=500g 0 = 7 0 ) (
:
l
0 -1 .
-2 T0 .
+ -3 ) (t=0 )(S
.
-II = 60 )V1=0 (-1-
0

-1 V2 )(-2-
-2 ) (S ) (3 = 45
0

V 0 = V 3 :
- . V3
Z
-
) (S
) (O',X,Z )(S
).(t=0
- .
1
V0 - )(S
X 'O ).(OX
3 - .
2

6/6