Professional Documents
Culture Documents
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.41 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies base of text
The bond dissociation energy (enthalpy change) for a bond A 9 B which is broken through the reaction
AB : A B
is dened as the standard-state enthalpy change for the reaction at a specied temperature, here at 298 K.
That is,
All values refer to the gaseous state and are given at 298 K. Values of 0 K are obtained by subtracting 32RT
from the value at 298 K.
To convert the tabulated values to kcal/mol, divide by 4.184.
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Al 9 Al 186(9) Sb 9 O 372(84)
Al 9 As 180 Sb 9 P 357
Al 9 Au 326(6) Sb 9 S 379
Al 9 Br 439(8) Sb 9 Te 277.4(38)
Al 9 C 255
Al 9 Cl 494(13) Arsenic
AlCl 9 Cl 402(8)
AlCl 2 9 Cl 372(8) As 9 As 382(11)
AlO 9 Cl 515(84) As 9 Cl 448
Al 9 Cu 216(10) As 9 Ga 209.6(12)
Al 9 D 291 As 9 H 272(12)
Al 9 F 664(6) As 9 N 582(126)
AlF 9 F 546(42) As 9 O 481(8)
AlF2 9 F 544(46) As 9 P 534(13)
AlO 9 F 761(42) As 9 S (478)
Al 9 H 285(6) As 9 Se 96
Al 9 I 368(4) As 9 Tl 198(15)
Al 9 Li 176(15)
Al 9 N 297(96) Astatine
Al 9 O 512(4)
AlCl 9 O 540(41) At 9 At (115.9)
AlF 9 O 582
Al 9 P 213(13) Barium
Al 9 Pd 259(12)
Al 9 S 374(8) Ba 9 Br 370(8)
Al 9 Se 334(10) Ba 9 Cl 444(13)
Al 9 Si 251(3) Ba 9 F 487(7)
Al 9 Te 268(10) Ba 9 I 431(4)
Al 9 U 326(29) Ba 9 O 563(42)
Ba 9 OH 477(42)
Antimony Ba 9 S 400(19)
Sb 9 Sb 299(6) Beryllium
Sb 9 Br 314(59)
Sb 9 Cl 360(50) Be 9 Be 59
Sb 9 F 439(96) Be 9 Br 381(84)
Sb 9 N 301(50) Be 9 Cl 388(9)
short
standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE
top of rh
4.42 SECTION 4 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.43 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
top of rh
4.44 SECTION 4 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Cs 9 Cs 41.75(93) Cr 9 Cu 155(21)
Cs 9 Br 397.5(42) Cr 9 F 437(20)
Cs 9 Cl 439(21) Cr 9 Ge 170(29)
Cs 9 F 514(8) Cr 9 H 280(50)
Cs 9 H 178.1(38) Cr 9 I 287(24)
Cs 9 I 339(4) Cr 9 N 378(19)
Cs 9 O 297(25) Cr 9 O 427(29)
Cs 9 OH 385(13) OCr 9 O 531(63)
O2Cr 9 O 477(84)
Chlorine Cr 9 S 339(21)
Cl 9 Cl 242.580(16) Cobalt
Cl 9 C 338(42)
Cl 9 CH 3 339(21) Co 9 Co 167(25)
Cl 9 CH3 213 Co 9 Br 331(42)
Cl 9 C(CH 3 )3 328.4 Co 9 Cl 398(8)
Cl 9 CH 2Cl 310(13) Co 9 Cu 162(17)
Cl 9 CCl 3 293(21) Co 9 F 435(63)
Cl 9 CF3 360(33) Co 9 Ge 239(25)
Cl 9 CCl 2 F 305(8) Co 9 I 235(81)
Cl 9 CClF2 318(8) Co 9 O 368(21)
Cl 9 CF2CF2 346.0(71) Co 9 S 343(21)
Cl 9 CH " CH 2 351
Cl 9 CN 439 Copper
Cl 9 COCl 328
Cl 9 COCH 3 349.4 Cu 9 Cu 202(4)
Cl 9 COC6 H 5 310(13) Cu 9 Br 331(25)
Cl 9 Cl 393 Cu 9 Cl 383(21)
Cl 9 ClO 143.3(42) Cu 9 F 431(13)
O3Cl 9 ClO4 243 Cu 9 Ga 216(15)
Cl 9 F 250.54(8) Cu 9 Ge 209(21)
O3Cl 9 F 255 Cu 9 H 280(8)
Cl 9 N 389(50) Cu 9 I 197(21)
Cl 9 NCl 280 Cu 9 Ni 206(17)
Cl 9 NCl 2 381 Cu 9 O 343(63)
Cl 9 NF2 ca. 134 Cu 9 S 285(17)
Cl 9 NH 2 251(25) Cu 9 Se 293(38)
Cl 9 NO 159(6) Cu 9 Sn 177(17)
Cl 9 NO2 142(4) Cu 9 Te 176(38)
Cl 9 O 272(4)
OCl 9 O 243(13) Curium
O2Cl 9 O 201(4)
Cl 9 P 289(42) Cm 9 O 736
Cl 9 SiCl 3 464
Dysprosium
Chromium
Dy 9 F 527(21)
Cr 9 Cr 155(21) Dy 9 O 611(42)
Cr 9 Br 328(24) Dy 9 Se 322(42)
Cr 9 Cl 366(24) Dy 9 Te 234(42) short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.45 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Er 9 F 565(17) Ga 9 O 285(63)
Er 9 O 611(13) Ga 9 P 230(13)
Er 9 S 418(42) Ga 9 Sb 209(13)
Er 9 Se 326(42) Ga 9 Te 251(25)
Er 9 Te 239(42)
Germanium
Europium
Ge 9 Ge 274(21)
Eu 9 Eu 33.5(165) Ge 9 Br 255(29)
Eu 9 Cl ca. 326 Ge 9 Cl 431.8(4)
Eu 9 F 528(18) Ge 9 F 485(21)
Eu 9 O 557(13) Ge 9 H 321.3(8)
Eu 9 S 364(15) Ge 9 O 662(13)
Eu 9 Se 301(15) Ge 9 S 551.0(25)
Eu 9 Te 243(15) Ge 9 Se 490(21)
Ge 9 Si 301(21)
Fluorine Ge 9 Te 402(8)
F9F 156.9(96)
Gold
F 9 F 251
F 9 CH 3 452(21) Au 9 Au 221.3(21)
F 9 C(CH 3 )3 439 Au 9 B 368(11)
F 9 C6 H 5 485 Au 9 Be 285(8)
F 9 CCl 3 444(21) Au 9 Bi 293(84)
F 9 CCl 2 F 460(25) Au 9 Cl 343(10)
F 9 CClF2 490(25) Au 9 Co 215(13)
F 9 CF3 523(17) Au 9 Cr 215(6)
F 9 COCH 3 498 Au 9 Cu 232(9)
F 9 FO 272(13) Au 9 Fe 187(17)
F 9 FO2 81.0 Au 9 Ga 294(15)
F9N 301(42) Au 9 Ge 277(15)
F 9 NF 318(25) Au 9 H 314(10)
F 9 NF2 243(8) Au 9 La 80(5)
F 9 NO 235.6(42) Au 9 Li 68.0(16)
F 9 NO2 197(25) Au 9 Mg 243(42)
Au 9 Mn 185(13)
Gadolinium
Au 9 Ni 274(21)
Gd 9 F 590(27) Au 9 Pb 130(42)
Gd 9 O 716(17) Au 9 Pd 143(21)
Gd 9 S 525(15) Au 9 Rh 231(29)
Gd 9 Se 431(15) Au 9 S 418(25)
Au 9 Si 312(12)
Gallium Au 9 Sn 244(17)
Au 9 Te 247(67)
Ga 9 Ga 138(21) Au 9 U 318(29)
Ga 9 Br 444(17)
(CH 3 )3Ga 9 CH 3 253 Hafnium
Ga 9 Cl 481(13)
Ga 9 F 577(15) Hf 9 C 548(63)
Ga 9 H 274 Hf 9 N 534(29)
short
Ga 9 I 339(10) Hf 9 O 791(8)
standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE
top of rh
4.46 SECTION 4 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.47 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
In 9 In 100(8) Lanthanum
In 9 Br 418(21)
In 9 Cl 439(8) La 9 La 247(21)
In 9 F 506(15) La 9 C 506(63)
In 9 O 360(21) La 9 F 598(42)
In 9 P 197.9(85) La 9 N 519(42)
In 9 S 289(17) La 9 O 799(13)
In 9 Sb 152(11) La 9 S 577(25)
In 9 Se 247(17)
In 9 Te 218(17) Lead
Iodine Pb 9 Pb 339(25)
Pb 9 Br 247(38)
I9I 152.549(8) Pb(CH 3 )3 9 CH 3 207(42)
I 9 Br 179.1(4) Pb 9 Cl 301(29)
I 9 CH 3 232(13) Pb 9 F 356(8)
I 9 C2 H 5 223.8 Pb 9 H 176(21)
I 9 CH(CH 3 )2 222 Pb 9 I 197(38)
I 9 C(CH 3 )3 207.1 Pb 9 O 378(4)
I 9 CH 2CF3 234(4) Pb 9 S 346.0(17)
I 9 CF2CH 3 216(4) Pb 9 Se 303(4)
I 9 C3 F7 209(4) Pb 9 Te 251(13)
I 9 CH " CHCH 3 172
I 9 C6 H 5 268(4) Lithium
I 9 C6 F5 276
I 9 Cl 213.3(4) Li 9 Li 106(4)
I 9 COCH 3 219.7 Li 9 Br 423(21)
I 9 CN 305(4) Li 9 Cl 469(13)
I9F 280(4) Li 9 F 577(21)
I9N 159(17) Li 9 H 247
I 9 NO 71(4) Li 9 I 352(13)
I 9 NO2 75(4) Li 9 Na 88
I9O 184(21) Li 9 O 341(6) short
Li 9 OH 427(21) standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE
top of rh
4.48 SECTION 4 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Lutetium Molybdenum
Lu 9 Lu 142(34) Mo 9 I 372
Lu 9 F 569(42) Mo 9 O 607(34)
Lu 9 O 695(13) MoO 9 O 678(84)
Lu 9 S 507(15) MoO2 9 O 565(84)
Lu 9 Te 326(17)
Neodymium
Magnesium
Nd 9 F 545(13)
Mg 9 Mg 8.522(4) Nd 9 O 703(34)
Mg 9 Br 297(63) Nd 9 S 474(15)
Mg 9 Cl 318(13) Nd 9 Se 385(17)
Mg 9 F 462(21) Nd 9 Te 305(17)
MgF 9 F 569(42)
Mg 9 H 197(50) Neon
Mg 9 I ca. 285
Mg 9 O 394(35) Ne 9 Ne 3.93
Mg 9 OH 238(21)
Mg 9 S 310(75) Neptunium
Manganese Np 9 O 720(29)
Mn 9 Mn 42(29) Nickel
Mn 9 Br 314(10)
Mn 9 Cl 361(10) Ni 9 Ni 261.9(25)
Mn 9 F 423(15) Ni 9 Br 360(13)
Mn 9 I 283(10) Ni 9 Cl 372(21)
Mn 9 Cu 159(17) Ni 9 F 435
Mn 9 O 402(34) Ni 9 H 289(13)
Mn 9 S 301(17) Ni 9 I 293(21)
Mn 9 Se 201(13) Ni 9 O 391.6(38)
Ni 9 S 360(21)
Mercury Ni 9 Si 318(17)
Hg 9 Hg 17.2(21) Niobium
Hg 9 Br 72.8(42)
CH 3 9 HgCH 3 240.6 Nb 9 O 753(13)
C2 H 5 9 HgC2 H 5 182.8(42)
C3 H 7 9 HgC3 H 7 197.1 Nitrogen
Isopropyl 9 Hgisopropyl 170.3
C6 H 5 9 HgC6 H 5 285 N9N 945.33(59)
Hg 9 Cl 100(8) N 9 Br 276(21)
Hg 9 F 130(38) ON 9 Br 28.7(15)
Hg 9 H 39.8 N 9 Cl 389(50)
Hg 9 I 38 ON 9 Cl 159(6)
Hg 9 K 8.24(21) O2 N 9 Cl 142(4)
Hg 9 Na 6.7 N9F 301(42)
Hg 9 S 213 FN 9 F 318(21)
Hg 9 Se (167) F2 F 9 N 243(8)
Hg 9 Te (142) ON 9 F 236(4)
O2 N 9 F 188(21) short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.49 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
top of rh
4.50 SECTION 4 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Pr 9 Se 446(23) Sc 9 Sc 163(21)
Pr 9 Te 326(42) Sc 9 Br 444(63)
Sc 9 C 393(63)
Promethium Sc 9 Cl 318
Sc 9 F 589(13)
Pm 9 F 540(42) Sc 9 N 469(84)
Pm 9 O 674(63) Sc 9 O 674(13)
Pm 9 S 423(63) Sc 9 S 478(13)
Pm 9 Se 339(63) Sc 9 Se 385(17)
Pm 9 Te 255(63) Sc 9 Te 289(17)
Radium Selenium
Ra 9 Cl 343(75) Se 9 Se 332.6(4)
Se 9 Br 297(84)
Rhodium Se 9 C 582(96)
Se 9 Cl 322
Rh 9 Rh 285(21) Se 9 F 339(42)
Rh 9 B 476(21) Se 9 H 305(2)
Rh 9 C 583.7(63) Se 9 N 381(63)
Rh 9 O 377(63) Se 9 O 423(13)
Rh 9 Si 395(18) Se 9 P 364(10)
Rh 9 Ti 391(15) Se 9 S 381(21)
Se 9 Si 531(25)
Rubidium Se 9 Te 268(8)
Rb 9 Rb 45.6(21) Silicon
Rb 9 Br 389(13)
Rb 9 Cl 448(21) Si 9 Si 327(10)
Rb 9 F 494(21) Si 9 Br 343(50)
Rb 9 H 167(21) Si 9 C 435(21)
Rb 9 I 335(13) Si 9 Cl 456(42)
Rb 9 O 255(84) Si 9 F 540(13)
Rb 9 OH 351(8) Si 9 H 298.49(46)
Si 9 I 339(84)
Ruthenium Si 9 N 439(38)
Si 9 O 798(8)
Ru 9 O 481(63) Si 9 S 619(13)
O3 Ru 9 O 439 Si 9 Se 531(25)
Ru 9 Si 397(21) H 3Si 9 SiH 3 339(17)
Ru 9 Th 592(42) (CH 3 )3Si 9 Si(CH 3 )3 339
(Aryl)3Si 9 Si(aryl)3 368(31)
Samarium Si 9 Te 506(38)
Sm 9 Cl 423(13) Silver
Sm 9 F 531(18)
Sm 9 O 619(13) Ag 9 Ag 163(8)
Sm 9 S 389 Ag 9 Au 203(9)
Sm 9 Se 331(15) Ag 9 Bi 193(42)
Sm 9 Te 272(15) short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.51 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Ag 9 Br 293(29) Ta 9 N 611(84)
Ag 9 Cl 341.4 Ta 9 O 805(13)
Ag 9 Cu 176(8)
Ag 9 F 354(16) Tellurium
Ag 9 Ga 180(15)
Ag 9 Ge 175(21) Te 9 B 354(20)
Ag 9 H 226(8) Te 9 H 268(2)
Ag 9 I 234(29) Te 9 I 193(42)
Ag 9 In 176(17) Te 9 O 391(8)
Ag 9 O 213(84) Te 9 P 298(10)
Ag 9 Sn 136(21) Te 9 S 339(21)
Ag 9 Te 293(96) Te 9 Se 268(8)
Sodium Terbium
Na 9 Na 77.0 Tb 9 F 561(42)
Na 9 Br 370(13) Tb 9 O 707(13)
Na 9 Cl 410(8) Tb 9 S 515(42)
Na 9 F 481(8) Tb 9 Te 339(42)
Na 9 H 201(21)
Na 9 I 301(8) Thallium
Na 9 K 63.6(29)
Na 9 O 257(17) Tl 9 Tl 63
Na 9 OH 381(13) Tl 9 Br 333.9(17)
Na 9 Rb 59(4) Tl 9 Cl 372.8(21)
Tl 9 F 445(19)
Strontium Tl 9 H 188(8)
Tl 9 I 272(8)
Sr 9 Br 332(19)
Sr 9 Cl 406(13) Thorium
Sr 9 F 542(7)
Sr 9 H 163(8) Th 9 Th 289
Sr 9 I 263(42) Th 9 C 484(25)
Sr 9 O 454(15) Th 9 N 577.4(21)
Sr 9 OH 381(42) Th 9 O 854(13)
Sr 9 S 314(21) Th 9 P 377
Sulfur Thullium
top of rh
4.52 SECTION 4 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Uranium Zn 9 Zn 29
Zn 9 Br 142(29)
U9O 761(17) C2 H 5C 9 C2 H 5 ca. 201
OU 9 O 678(59) Zn 9 Cl 229(20)
O2 U 9 O 644(88) Zn 9 F 368(63)
U9S 523(10) Zn 9 H 85.8(21)
Zn 9 I 138(29)
Vanadium Zn 9 O 284.1
Zn 9 S 205(13)
V9V 242(21) Zn 9 Se 136(13)
V 9 Br 439(42) Zn 9 Te 205
V9C 469(63)
short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE
top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.53 base of rh
cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text
Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol
Zr 9 C 561(25) Zr 9 O 760(8)
Zr 9 F 623(63) Zr 9 S 575(17)
Zr 9 N 565(25)
Source: T. L. Cottrell, The Strengths of Chemical Bonds, 2d ed., Butterworth, London, 1958; B. deB. Darwent, National
Standard Reference Data Series, National Bureau of Standards, no. 31, Washington, 1970; S. W. Benson, J. Chem. Educ.
42:502 (1965); and J. A. Kerr, Chem. Rev. 66:465 (1966).
short
standard