50 Đề Thi Thử THPT Quốc Gia Môn Hóa 2017 (Có Đáp Án Chi Tiết)

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2017
50 THI TH
THPT QUC GIA
MN HA NM
2017
S GD T THI TH LN 1 THPT QUC GIA NM 2017
TNH VNH PHC Mn: KHOA HC T NHIN HA HC
Thi gian lm bi: 50 pht, khng k thi gian pht
( thi c 40 cu / 4 trang)
M : 303
Cho bit nguyn t khi ca cc nguyn t :
H =1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S =32; Cl = 35,5; K = 39; Ca = 40; Cr = 52;
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi thy phn hp cht hu c X (khng c phn ng trng bc) trong mi trng axit ri
trung ha axit th dung dch thu c c phn ng trng bc. X l:
A. Anehit axetic B. Ancol etylic C. Saccaroz D. Glixerol
Cu 2: Cho kim loi Ba d vo dung dch Al2(SO4)3, thu c sn phm c:
A. Mt cht kh v hai cht kt ta. B. Mt cht kh v khng cht kt ta.
C. Mt cht kh v mt cht kt ta. D. Hn hp hai cht kh.
Cu 3: to thnh thy tinh hu c (plexiglat), ngi ta tin hnh trng hp:
A. CH3-COO-C(CH3)=CH2 B. CH2=CH-CH=CH2
C. CH3-COO-CH=CH2 D. CH2=C(CH3)-COOCH3
Cu 4: Hiu sut ca qu trnh iu ch anilin (C 6H5NH2) t benzen (C6H6) t 30%. Khi lng
anilin thu c khi iu ch t 156 gam benzen l:
A. 186,0 gam B. 111,6 gam C. 55,8 gam D. 93,0 gam
Cu 5: Pht biu no sau y ng ?
A. Cc amino axit l cht rn iu kin thng.
B. Cc amin iu kin thng l cht kh hoc cht lng.
C. Cc protein u dc tan trong nc.
D. Cc amin khng c.
Cu 6: phn bit cc dung dch: CaCl2, HCl, Ca(OH)2 dng dung dch ?
A. NaNO3 B. NaOH C. NaHCO3 D. NaCl
Cu 7: un nng tristearin trong dung dch NaOH thu c glixerol v ?
A.C17H35COONa B. C17H33COONa C. C15H31COONa D. C17H31COONa
Cu 8: Nhng mt thanh st (d) vo 100ml dung dch CuSO 4 x mol/l. Sau khi cc phn ng xy ra
hon ton thy khi lng thanh st tng 0,4 gam. Bit tt c Cu sinh ra u bm vo thanh st. Gi
tr ca x l:
A. 0,05 B. 0,5 C. 0,625 D. 0,0625
Cu 9: ng phn ca glucoz l:
A. Xenluloz B. Fructoz C. Saccaroz D. Sobitol
Cu 10: Cht no di y l etyl axetat ?
A. CH3COOCH2CH3 B. CH3COOH
C. CH3COOCH3 D. CH3CH2COOCH3
Cu 11: un nng 5,18 gam metyl axetat vi 100ml dung dich NaOH 1M n phn ng hon ton.
C cn dung dch sau phn ng, thu c m gam cht rn khan. Gi tr ca m l:
A. 8,20 B. 6,94 C. 5,74 D. 6,28
Cu 12: Cht no sau y cn c gi l ng mt ong ?
A. Saccaroz B. Fructoz C. Glucoz D. Amilopectin
Cu 13: Ln men hon ton a gam glucoz, thu c C2H5OH v CO2. Hp th ht CO2 sinh ra vo
dung dch nc vi trong d, thu c 15 gam kt ta. Gi tr ca a l:
A. 30,6 B. 27,0 C. 15,3 D. 13,5
Bin son: NXT-diendanthpt.com 2

Cu 14: Mt phn t polieilen c khi lng phn t bng 56000u. H s polime ha ca phn t
polietylen ny l:
A. 20000 B. 2000 C. 1500 D. 15000
Cu 15: Polime c cu trc mng li khng gian l:
A. Polietilen B. Poli(vinyl clorua) C. Amilopectin D. Nha bakelit
Cu 16: Cho dy cc dung dch sau: C6H5NH2, NH2CH2COOH, HOOC[CH2]2CH(NH2)COOH
C2H5NH2, NH2[CH2]2CH(NH2)COOH. S dung dch trong dy lm i mu qu tm ?
A. 4 B. 5 C. 2 D. 3
Cu 17: Cho cc cht sau: CH3COOCH3, HCOOCH3, HCOOC6H5, CH3COOC2H5. Cht c nhit
si thp nht l:
A. HCOOC6H5 B. CH3COOC2H5 C. HCOOCH3 D. CH3COOCH3
Cu 18: Khng nh no sau y ng ?
A. un nng tinh bt vi dung dch axit th xy ra phn ng khu mch polime.
B. Trng hp axit -amino caproic thu c nilon-6.
C. Polietilen l polime trng ngng.
D. Cao su buna c phn ng cng.
Cu 19: Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c
vi dung dch AgNO 3 ?
A. Fe, Ni, Sn B. Zn, Cu, Mg C. Hg, Na, Ca D. Al, Fe, CuO
A. Phn ng gia ancol vi axit cacboxylic c gi l phn ng x phng ha.
B. Phn ng x phng ha l phn ng thun nghch.
C. Trong cng thc ca este RCOOR, R c th l nguyn t H hoc gc hidrocacbon.
D. Phn ng este ha l phn ng mt chiu.
Cu 21: Nhn xt no sau y ng ?
A. a s cc polime d ha tan trong cc dung mi thng thng.
B. a s cc polime khng c nhit nng chy xc nh.
C. Cc polime u bn vng di tc ng ca axit, baz.
D. Cc polime d bay hi.
Cu 22: Trong cc cht di y, cht no l amin bc hai ?
A. H2N(CH2)6NH2 B. CH3NHCH3
C. C6H5NH2 D. CH3CH(CH3)NH2
Cu 23: Mt tripeptit X mch h c cu to t 3 amino axit l glyxin, alanin, valin. S cng thc
cu to ca X l:
A. 6 B. 3 C. 4 D. 8
Cu 24: Cacbohidrat no sau y c dng lm nguyn liu sn xut t visco ?
A. Saccaroz B. Tinh bt C. Glucoz D. Xenluloz
Cu 25: Ha tan hon ton 21,5 gam hn hp X gm Al, Zn, FeO, Cu(NO 3)2 cn dng ht 430 ml
dung dch H2SO4 1M thu c hn hp kh Y (ktc) gm 0,06 mol NO v 0,13 mol H 2, ng thi thu
c dung dch Z ch cha cc mui sunfat trung ha. C cn dung dch Z thu c 56,9 gam mui
khan. Thnh phn phn trm ca Al trong hn hp X c gi tr gn nht l:
A. 25,5% B. 18,5% C. 20,5% D. 22,5%
Cu 26: Ha tan m (g) hn hp X gm Al v Na c t l mol 1:2 vo nc d thu c 4,48 (l) kh
(ktc). G tr ca m l:
A. 7,3 B. 5,84 C. 6,15 D. 3,65
Cu 27 : Cho s chuyn ha sau :
t0
(1) C4H6O2 (M) + NaOH (A) + (B)
t0
(2) (B) + AgNO3 + NH3 +H2O (F) + Ag + NH 4NO3
0
(3) (F) + NaOH (A) + NH3
t
+ H2 O
Cht M l:
A. HCOO(CH2)=CH2 B. CH3COOCH=CH2 C. HCOOCH=CHCH3 D. CH2=CHCOOCH3
Cu 28: Cho 2 hp cht hu c X, Y c cng cng thc phn t l C 3H7NO2 . Khi phn ng vi
dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z, cn Y to ra CH2=CHCOONa v kh
T. Cc cht Z v T ln lt l:
A. CH3OH v NH3 B. CH3OH v CH3NH2
C. CH3NH2 v NH3 D. C2H3OH v N2
Cu 29: Cht hu c X c cng thc phn t C 3H9O2N. Cho 9,1 gam X tc dng vi dung dch
NaOH va . C cn dung dch sau phn ng thu c 6,8 gam cht rn khan. S cng thc cu to
ca X ph hp vi tnh cht trn l:
A. 1 B. 2 C. 3 D. 4
Cu 30: Tin hnh cc th nghim sau:
(a) Cho Cu d vo dung dch Fe(NO 3)3.
(b) Sc kh CO2 d vo dung dch NaOH.
(c) Cho Na2CO3 d vo dung dch Ca(HCO 3)2.
(d) Cho bt Fe vo dung dch FeCl 3 d.
S th nghim cui cng cn li dung dch cha 1 mui tan l:
A. 2 B. 1 C. 4 D. 3
Cu 31: t chy hon ton 1 lng hn hp 2 este. Dn sn phm chy ln lt qua bnh (1) ng
P2O5 d v bnh (2) ng dung dch Ca(OH) 2 d, thy khi lng bnh (1) tng 6,21 gam, cn bnh
(2) thi c 34,5 gam kt ta. Cc este trn thuc loi este no sau y ?
A. Este no, n chc, mch h B. Este khng no
C. Este thm D. Este a chc
Cu 32: t chy hon ton m gam hn hp X gm 2 este ng phn cn dng 4,704 lt kh O 2 , thu
c 4,032 lt CO2 v 3,24 gam H2O. Nu cho m gam X tc dng ht vi 110 ml dung dch KOH
1M. C cn dung dch sau ph ng th thu c 7,98 gam cht rn khan, trong c a mol mun Y
v b mol mui Z (MY > MZ ). Cc th tch kh u o iu kin chun. T l a : b l:
A. 2 : 3 B. 3 : 2 C. 2 : 1 D. 1 : 5
Cu 33: Thy phn m gam hn hp X gm 1 tetrapeptit A v 1 pentapeptit B (A v B u h cha
ng thi Glyxin v Alanin trong phn t) bng 1 lng dung dch NaOH va . C cn dung dch
sn phm cho (m+ 15,8) gam hn hp mui. t chy ton b lng mui sinh ra bng 1 lng oxi
va , thu c Na2CO3 v hn hp hi Y gm CO2 , H2O v N2. Dn Y i qua bnh ng dung
dch NaOH c d, thy khi lng thy khi lng bnh tng thm 56,04 gam so vi ban u v c
4,928 lt kh duy nht (ktc) thot ra khi bnh. Xem nh N 2 khng b nc hp th , cc phn ng
xy ra hon ton. Thnh phn phn trm khi lng ca B trong hn hp X l:
A.35,37% B. 58,92% C. 46,94% D. 50,92%
Cu 34: Braikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l:
Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg
Khi thu phn khng hon ton peptit ny, thu c bao nhiu tripeptit m trong thnh phn c
phenyl alanin (Phe) ?
A. 4 B. 3 C. 6 D. 5
Cu 35: Hn hp X gm metyl fomat, anehit acrylic v metyl acrylat. t chy hon ton m gam X
ri hp th ht sn phm chy vo dung dch Ca(OH) 2 d, thu c 9 gam kt ta v khi lng
dung dch gim 3,78 gam. Gi tr ca m l :
A. 1,95 B. 1,54 C. 1,22 D. 2,02
Cu 36: Poli(vinyl clorua) c iu ch t kh thin nhin (cha 95% metan v th tch) theo s
chuyn ho v hiu sut (H) nh sau :
H 15% H 95% H 90%
Metan Axetilen Vinyl clorua Poli(vinyl clorua).
Th tch kh thin nhin (ktc) cn iu ch c 1 tn PVC l :
A. 5589,08 m3 B. 1470,81 m3 C. 5883,25 m3 D. 3883,24 m3
Cu 37: Cho hn hp X gm hai cht hu c, no n chc, mch h (cha C, H, O) tc dng va
vi 20ml dung dch NaOH 2M thu c mt mui v mt ancol. un nng lng ancol thu c vi
axit H2SO4 c 170C thu c 0,015 mol anken (l cht kh iu kin thng). Nu t chy
lng X nh trn ri cho sn phm qua bnh ng CaO d th khi lng bnh tng 7,75 gam. Bit
cc phn ng xy ra hon ton. Pht biu no sau y ng ?
A. Khi lng ca cht c phn t khi ln hn trong X l 2,55 gam.
B. Tng phn t khi ca hai cht trong X l 164.
C. Thnh phn phn trm khi lng cc cht trong X l 49,5% v 50,5%.
D. Mt cht trong X c 3 cng thc cu to ph hp vi iu kin bi ton.
Cu 38: Sc 13,44 lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1,5M v NaOH 1M. Sau
phn ng thu c dung dch Y. Cho dung dch Y tc dng vi 200 ml dung dch hn hp BaCl 2
1,2M v KOH 1,5M thu c m gam kt ta. Gi tr ca m l:
A. 66,98 B. 39,4 C. 47,28 D. 59,1
Cu 39: Cho cc pht biu sua :
(a) Hidro ho hon ton glucoz to ra axit gluconic
(b) Phn ng thu phn xenluloz xy ra c trong d dy ca ng vt n c.
(c) Xenluloz trinitrat l nguyn liu sn xut t nhn to.
(d) Saccaroz b ho en trong H 2SO4 c.
(e) Trong cng nghip dc phm, saccaroz c dng pha ch thuc.
Trong cc pht biu trn, s pht biu ng l:
A. 3 B. 2 C. 4 D. 5
Cu 40: Cht X c cng thc phn t C 2H7O3N. Khi cho X tc dng vi dung dch HCl hoc dung
dch NaOH un nng nh u thy kh thot ra. Ly 0,1 mol X cho vo dung dch cha 0,25 mol
KOH. Sau phn ng c cn dung dch c cht rn Y, nung nng Y n khi lng khng i c
m gam cht rn. Gi tr ca m l:
A. 16,6 B. 18,85 C. 17,25 D. 16,9
----------HT----------

PHN TCH HNG DN GII CHI TIT
THI TH LN 1 S GD & T TNH VNH PHC M 303
Cu 1: Chn C.
- Thy phn saccaroz:
H O
C12H22O11
C6H12O6 (glucoz) + C6H12O6 (fructoz)
2
H
- Phn ng trng bc ca sn phm:
to
C6H12O6 + 2[Ag(NH3)2]OH CH2OH[CHOH]4COONH4 + 2Ag + 3NH3 + H2O
Cu 2: Chn C.
- Th t phn ng xy ra nh sau:
Ba + 2H2O
Ba(OH)2 + H2 (1)
Ba(OH)2 + Al2(SO4)3
Al(OH)3 trng keo + BaSO4 trng (2)
2Al(OH)3 + Ba(OH)2
Ba(AlO2)2 + 4H2O (3)
3BaSO4 2BaAlO2 4H 2
- Hay c th vit gn li: 5Bad 4H 2O Al 2 (SO4 )3
Vy sn phm thu c c mt cht kh (H2) v mt cht kt ta (BaSO 4).
Cu 3: Chn D.
- Phng trnh phn ng:
COOCH3
n CH2 C COOCH3 to, p, xt

CH2 C
n
CH3 CH3
Cu 4: Chn C.
HNO 6H, t o
- Qu trnh phn ng: C6H 6
3
C6H5 NO2
C6H5 NH 2 , H = 30%
o
H 2SO4 ,t Fe HCl
156
- Ta c: nC6H 5NH 2 nC6H6 .H% .0,3 0,6 mol mC6H6 55,8(g)
78
Cu 5: Chn A.
A. ng, Cc amino axit u l cht rn iu kin thng.
B. Sai, Ch c -metyl, -imetyl, -trimetyl v etyl amin l cht kh iu kin thng.
C. Sai, Ch c cc dng protein hnh cu tan tt trong nc, cn protein dng si th hon ton khng
tan trong nc.
D. Sai, Hu ht cc amin u c.
Cu 6: Chn C.
CaCl2 HCl Ca(OH)2
A. NaNO3 Khng phn ng Khng phn ng Khng phn ng
B. NaOH Khng phn ng Khng hin tng Khng phn ng
C. NaHCO3 Khng phn ng Thot kh khng mu Kt ta trng
D. NaCl Khng phn ng Khng phn ng Khng phn ng
Cu 7: Chn A.
0
- Phn ng: (CH3[CH2]16COO)3C3H5 + 3NaOH t
3CH3[CH2]16COONa + C3H5(OH)3
Tristearin Natri sterat (X) Glixerol
Cu 8: Chn B.
m 0,4 0,05
TGKL
nCu2 0,05mol CM(CuSO4 ) 0,5M
M CuFe 8 0,1
Cu 9: Chn B.
Cu 10: Chn A.
Cu 11: Chn B.

t0
- Phn ng: CH 3COOCH 3 NaOH CH 3COONa CH 3OH
0,07mol 0,1mol 0,07mol
mrn khan 40nNaOH(d ) 82nCH 3COONa 6,94(g)

Cu 12: Chn B.
- Saccaroz hay cn gi l ng ma, ng tht nt.
- Fructoz l thnh phn chnh ca mt ong (fructoz c ngt ln nht trong cc loi cacbohidrat).
- Glucoz hay cn gi l ng nho, ng tri cy.
- Amilopectin l mt on mch ca tinh bt.
Cu 13: Chn D.
nCO2 nCaCO3
- Ta c: nglucoz 0,075mol mglucoz 0,075.180 13,5(g)
2 2
Cu 14: Chn B.
56000
- Ta c: M ( CH 2 CH 2 )n 56000 n 2000
28
Cu 15: Chn D.
- Cc polime mch phn nhnh thng gp l amilopectin v glicozen.
- Cc polime mch khng gian thng gp l cao su lu ha v nha rezit (nha bakelit).
- Cc polime mch khng phn nhnh thng gp l cn li.
Cu 16: Chn D.
- Cc amin c tnh baz nn c kh nng lm i mu qu tm chuyn thnh mu xanh tr anilin (v
ng ng ca n) khng lm i mu qu tm do c tnh baz yu.
- i vi cc amino axit c dng (H 2N)x-R-(COOH)y th :
+ Nu x > y : qu tm chuyn sang mu xanh
+ Nu x = y : qu tm khng i mu.
+ Nu x < y : qu tm chuyn sang mu .
Vy c 3 dung dch lm i mu qu tm l:
Dung dch HOOC[CH2]2CH(NH2)COOH C2H5NH2 NH2[CH2]2CH(NH2)COOH
Mu qu tm Xanh Xanh
Cu 17: Chn C.
Cc yu t nh hng n nhit si:
- Phn t khi: nu nh khng xt n nhng yu t khc, cht phn t khi cng ln th nhit si
cng cao.
- Lin kt Hiro: nu hai cht c phn t khi xp x nhau th cht no c lin kt hiro s c nhit
si cao hn.
- Cu to phn t: nu mch cng phn nhnh th nhit si cng thp.
Dy sp xp nhit si gim dn ca cc hp cht c nhm chc khc nhau v phn t khi xp x
nhau:
Axit > ancol > amin > este > xeton > anehit > dn xut halogen > ete > CxHy
Vy cht c nhit si thp nht l HCOOCH3.
Cu 18: Chn D.
A. Sai, un nng tinh bt vi dung dch axit th xy ra phn ng ct mch polime .
B. Sai, Trng hp axit -aminocaproic thu c nilon-6.
C. Sai, Polietilen l polime c iu ch t phn ng trng hp.
D. ng, Trong phn t cao su buna: ( CH2 CH CH CH2 ) cn lin kt i C = C, nn c th
tham gia phn ng cng.
Cu 19: Chn A.
- Cc kim loi ng trc cp H +/H2 c th tc dng c vi HCl.
- Cc kim loi ng trc cp Ag +/Ag c th tc dng c vi AgNO 3.
Vy cc kim loi va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO 3 l
Mg, Zn, Al, Fe, Ni v Sn.

Cu 20: Chn D.
A. Sai, Phn ng gia ancol vi axit cacboxylic c gi l phn ng este ha.
B. Sai, Phn ng x phng ha l phn ng mt chiu.
C. ng.
D. Sai, Phn ng este ha l phn ng thun nghch.
Cu 21: Chn B.
A. Sai, a s cc polime khng tan trong cc dung mi thng thng.
B. ng, Hu ht cc polime khng c nhit nng chy xc nh, nng chy nhit kh rng.
C. Sai, Ly v d nh:
D. Sai, Cc polime khng bay hi.

Cu 22: Chn B.
- Bc ca amin c tnh bng s nguyn t H trong phn t aminoac b thay th bi gc
hidrocacbon do vy ch c CH 3NHCH3 l amin bc 2.
Cu 23: Chn A.
- C 6 cng thc cu to l:
GlyAlaVal, GlyValAla, AlaGlyVal, AlaValGly, ValGlyAla, ValAlaGly.
Cu 24: Chn D.
- T visco c to thnh t phn ng gia xenluloz vi CS2 v NaOH to thnh mt dung dch
nht gi l visco. Bm dung dch ny qua nhng l rt nh ri ngm trong dung dch H 2SO4 to
thnh t visco.
Cu 25: Chn C.
- Khi cho 21,5 gam X tc dng vi 0,43 mol H 2SO4 th :
m 98n H 2SO 4 30n NO 2n H 2 m Z

BTKL
n H 2O X 0, 26 mol
18
2n 2n H 2O 2n H 2 n n NO

BT:H
n NH 4 H 2SO4 0, 02 mol n Cu(NO3 ) 2 NH 4 0, 04 mol
4 2
2n H 2SO4 10n NH 4 4n NO 2n H 2
- Ta c n O(trong X) n FeO 0, 08mol
2
3n Al 2n Zn 3n NO 2n H 2 8n NH 4 0, 6
n Al 0,16 mol
- Xt hn hp X ta c:
27n Al 65n Zn m X 72n FeO 188n Cu(NO3 ) 2 8, 22 n Zn 0, 06 mol

27.0,16
%m Al .100 20, 09
21,5
Cu 26: Chn B.
BT:e
3nAl nNa 2nH2 3x 2x 0,4 x 0,08 m 27nAl 23nNa 5,84(g)

Cu 27: Chn B.
- Cc phn ng xy ra:
0
(1) CH3COOCH=CH2 (M) + NaOH
t
CH3COONa (A) + CH3CHO (B)
0
(2) CH3CHO (B) + AgNO 3 + NH3
t
CH3COONH4 (F) + Ag + NH4NO3
0
(3) CH3COONH4 (F) + NaOH
t
CH3COONa (A) + NH3 + H2O
Cu 28: Chn A.
- X v Y ln lt l NH2CH2COOCH3 v CH2 = CH COONH4.
0
NH 2CH 2COOCH3 (X) NaOH
t
NH 2CH 2COONa CH3OH(Z)
0
CH 2 CH COONH 4 (Y) NaOH t
CH 2 CH COONa NH3 (T) H 2O
Cu 29: Chn B.
- X c 2 ng phn cu to l HCOONH 3C2H5 v HCOONH(CH3)2.
0
HCOONH3C2 H5 NaOH
t
HCOONa C2 H5 NH 2 H 2O
0
HCOONH 2 (CH3 ) 2 NaOH
t
HCOONa CH3 NHCH3 H 2 O
Cu 30: Chn A.
(a) Cu(d) + 2Fe(NO3)3
Cu(NO3)2 + 2Fe(NO3)2
(b) CO2 (d) + NaOH
NaHCO3
(c) Na2CO3 (d) + Ca(HCO3)2
CaCO3 + 2NaHCO3 (ngoi ra cn Na 2CO3 d)
(d) Fe d + 2FeCl3 3FeCl2
Vy c 2 th nghim dung dch thu c ch cha 1 mui tan l (b), (d).
Cu 31: Chn A.
mbnh 1 tng mbnh 2 tng
- t chy hn hp este th: nH2O 0,345mol v nCO2 nCaCO3 0,345mol
18 100
- Nhn thy rng nH2O nCO2 , nn trong X ch cha cc este no, n chc, mch h.
Cu 32: Chn D.
- Khi t chy m gam X ta nhn thy nCO2 nH 2O X cha 2 este no, n chc mch h.
BT:O 2nCO2 nH 2O 2nO2 n
nCOO nX 0,06mol CX CO2 3(C3H 6O2 )
2 nX
- Khi cho m gam X trn tc dng vi 0,11 mol KOH th :
68nHCOOK 82nCH3COOK mrn khan 56nKOH 5,18 nHCOOK 0,05mol n 0,01 1
CH3COOK
nHCOOK nCH3COOK nX 0,06 nCH3COOK 0,01mol nHCOOK 0,05 5
Cu 33 : Chn C.
- Quy i hn hp X thnh C2H3ON (a mol), -CH2 (b mol) v H2O (c mol).
- Khi cho X tc dng vi dung dch NaOH th c hn hp quy i gm C 2H4ONNa (a mol) v CH2
(b mol). Xt qu trnh t chy hn hp mui ta c h sau:
97n NH CH COONa 14n CH (57n C H ON 14n CH 18n H O ) m 40a 18c 15,8 a 0, 44
2 2 2 2 3 2 2

44n CO 2 18n H 2O m bnh Z 102a 62b 56, 04 b 0,18
BT:N a 0, 44 c 0,1
n C2H3ON 2n N 2

- Ta c: n Ala n CH2 0,18mol n Gly 2n N2 n Ala 0, 26mol
n A n B n H 2O n A n B 0,1 n A 0, 06 mol
- Xt hn hp X ta c :
4n A 5n B 2n N 2 4n A 5n B 0, 44 n B 0, 04 mol
- Gi peptit A v B ln lt l (Gly)x (Ala)4x v (Gly) y (Ala)5y (v i x 4 v y < 5) .
BT:Gly
nA .x nB.y nGly 0,06x 0,04y 0,26 x 3 v y = 2 (tha)

0,04.M Gly 2Ala3 0,04.345
%mB .100% 46,94
mX 57.0,44 14.0,18 18.0,1
Cu 34: Chn D.
- Khi thu phn khng hon ton peptit trn th thu c 5 tripeptit m trong thnh phn c
phenylalanin (Phe) l: Pro-Gly-Phe, Gly-Phe-Ser, Phe-Ser-Pro, Ser-Pro-Phe v Pro-Phe-Arg.
Cu 35: Chn D.

- V dng 1 lng d Ca(OH) 2 nn n CO2 n CaCO3 0,09 mol
vi mdd gim mCaCO3 (44nCO2 18nH2O ) 3,78 nH2O 0,07mol
- Xt hn hp cc cht trong X: HCOOCH3 (k=1); CH2=CH-CHO (k=2) v CH2=CH-COOCH3 (k=2)
quan h
CO v H O
nC3H4O nC4H6O2 nCO2 nH2O 0,02 mol
2 2
n CO 2 4n C4H 6O 2
- m X(min) th n C2H 4O2 min khi v ch khi: n C3H 4O 0 n C2H 4O 2 0, 005 mol
2
m X(min) 60n C2H 4O 2 86n C4H 6O 2 2, 02 (g) (tha mn vi p n ca ).
0, 02
- Lu : Nu ta cho n C3H 4O n C 4H 6O 2 0, 01 mol th lc ny ta s gii ra c chnh xc p
2
n ca bi cho.
Cu 36: Chn C.
H .H .H 2nC2H3Cl
- Ta c : H 1 2 3 0,12825 nCH 4 0,25.103 mol
100 H
nCH 4
VCH 4 (trong t nhin) .22,4 5883,25(m3 )
0,95
Cu 37: Chn C.
- Khi t chy X c nCO2 nH2O 44nCO2 18nH 2O mbnh t ng 44a 18a 7,75 a 0,125mol
- Xt qu trnh X tc dng vi NaOH :
+ Nhn thy rng, nNaOH nanken , trong trong X cha 1 este v 1 axit. Khi dehirat ha ancol th :
neste(A) nanken 0,015mol naxit(B) nX neste 0,025mol
- Gi CA v CB ln lt l s nguyn t C ca este A v axit B (vi C A 3, CB 1)
nA .CA nB.CB nCO2 0,015CA 0,025CB 0,125 CA 5 v CB 2(tha)

Vy (A) l C5H10O2 v (B) l C2H4O2
A. Sai, chnh lch khi lng gia A v B l: m 102nA 60nB 0,03(g)
B. Sai, Tng khi lng phn t khi ca A v B l 162.
102nA
C. ng, %mA .100% 50,5 %mB 49,5
102nA 60nB
D. Sai, Este A c 7 ng phn tng ng l: CH3COO-C3H7 (2 ng phn) ; HCOO-C4H9 (4 ng
phn) ; C2H5COOC2H5 (1 ng phn) v axit B ch c 1 ng phn l CH3COOH.
Cu 38: Chn D.
- Khi cho 0,6 mol CO2 tc dng vi dung dch X gm 0,3 mol Ba(OH)2 v 0,2 mol NaOH:
n BT: C
V OH nCO2 nOH nCO32 nOH nCO2 0,2mol nHCO3 nCO2 nCO32 0,4mol
2
- Khi cho dung dch Y tc dng vi dung dch cha 0,24 mol BaCl 2 v 0,3 mol KOH th:
HCO3 OH Ba2
BaCO3 H 2O
0,4mol 0,3mol 0,54mol 0,3mol
mBaCO3 0,3.197 59,1(g)

Cu 39: Chn A.
(a) Sai, Hidro ha glucoz thu c soritol:
0
HOCH2[CHOH]4CHO + H2 Ni,t
HOCH2[CHOH]4CH2OH
(b) ng, Trong d dy ca cc ng vt nhai li nh tru, b c cha enzim xenlulaza c th lm
thy phn xenluloz.
(c) Sai, Xenluloz trinitrat l cht d chy v n mnh c dng lm thuc sng.
(d) ng, Do H2SO4 c c tnh ho nc nn khi cho H 2SO4 vo ng saccaroz th :

C12(H2O)11 + H2SO4(c) C(en) + H2SO4.11H2O
(e) ng, Trong cng nghip dc phm, saccaroz c dng pha ch thuc.
Vy c 3 pht biu ng l (b), (d) v (e)
Cu 40: Chn A.
t0
- Phng trnh phn ng : CH 3NH 3HCO3 2KOH K 2CO3 CH 3NH 2 H 2O
mrn 138nK 2CO3 56nKOH(d ) 16,6(g)

M : 135
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi ni v kim loi, pht biu no sau y sai ?

A. Kim loi c cng ln nht l Cr.
B. Kim loi dn in tt nht l Cu.
C. Kim loi c nhit nng chy cao nht l W.
D. Kim loi c khi lng ring nh nht l Li.
Cu 2: Vinyl axetat c cng thc cu to thu gn l:
A. CH3COOCH2-CH3 B. CH3COOCH3
C. CH3COOCH=CH2 D. CH2=CH-COOCH3
Cu 3: Trong iu kin thng, X l cht rn, dng si mu trng. Phn t X c cu trc mch khng
phn nhnh, khng xon. Thy phn X trong mi axit, thu c glucoz.Tn gi ca X l:
A. Fructoz B. Amilopectin C. Xenluloz D. Saccaroz
Cu 4: Trong nhng nm 30 ca th k XX, cc nh ha hc ca hng Du Pont (M) thng bo
pht minh ra mt loi vt liu mng hn t nhn, bn hn thp v p hn la. Theo thi gian, vt
liu ny c mt trong cuc sng hng ngy ca con ngi, ph bin trong cc sn phm nh lp
xe, d, qun o, tt, Hng Du Pont thu c hng t la mi nm bng sng ch v loi vt
liu ny. Mt trong s vt liu l t nilon-6. Cng thc mt on mch ca t nilon-6 l:
A. (-CH2-CH=CH-CH2)n B. (-NH-[CH2]6-CO-)n
C. (-NH-[CH2]6-NH-CO-[CH2]4-CO-)n D. (-NH-[CH2]5-CO-)n
Cu 5: Khi thay nguyn t H trong phn t NH 3 bng gc hidrocacbon, thu c ?
A. amino axit B. amin C. lipt D. este
Cu 6: Hp cht khng lm i mu giy qu tm m l:
A. NH3 B. H2N-CH2-COOH C. CH3COOH D. CH3NH2
Cu 7: Glucoz ln men thnh ancol etylic theo phn ng sau:
C6H12O6 men
3035 C0 2C 2 H 5OH 2CO 2
thu c 92 gam C 2H5OH cn dng m gam glucoz. Bit hiu sut ca qu trnh ln men l 60%.
Gi tr m l:
A. 360 B. 108 C. 300 D. 270
Cu 8: un nng 14,6 gam Gly-Ala vi lng d dung dch NaOH. Sau khi phn ng xy ra hon
ton, thu c dung dch cha m gam mui. Gi tr m l:
A. 22,6 B. 18,6 C. 20,8 D. 16,8
Cu 9: Hp cht no di y thuc loi amino axit ?
A. CH3COOC2H5 B. HCOONH4 C. C2H5NH2 D. H2NCH2COOH
Cu 10: Thy phn 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy
ra hon ton, c cn dung dch, thu c m gam cht rn khan. Ga tr ca m l:
A. 8,20 B. 10,40 C. 8,56 D. 3,28
Cu 11: Cho m gam hn hp kim loi Zn, Cu vo dung dch HCl (d). Sau khi cc phn ng xy ra
hon ton, thu c 4,48 lt H 2 (ktc) v 2,0 gam kim loi khng tan. Ga tr ca m l:
A. 8,5 B. 18,0 C. 15,0 D. 16,0
Cu 12: X phng ha tristearin bng NaOH, thu c glixerol v cht X. Cht X l:
A. CH3[CH2]16(COOH)3 B. CH3[CH2]16COOH
C. CH3[CH2]16(COONa)3 D. CH3[CH2]16COONa

Cu 13: Cho dy cc kim loi: Na, Ca, Cu, Fe, K. S kim loi trong dy tc dng vi H 2O to dung
dch baz l:
A. 2 B. 4 C. 3 D. 1
Cu 14: Polime no sau y l polime thin nhin ?
A. Amiloz B. Nilon-6,6 C. Cao su isopren D. Cao su buna
Cu 15: ng fructoz c nhiu trong mt ong, ngoi ra cn c trong cc loi hoa qu v rau xa nh
nh i, cam, xoi, rau dip xon, c chuart tt cho sc khe. Cng thc phn t ca fructoz l:
A. C12H22O11 B. C6H12O6 C. C6H10O5 D. CH3COOH
Cu 16: Polime no sau y c cu trc mch phn nhnh ?
A. Amilopectin B. Xenluloz C. Cao su isopren D. PVC
Cu 17: iu kin thng, amin X l cht lng, d b oxi ha khi ngoi khng kh. Dung dch X
khng lm i mu qu tm nhng tc dng vi nc brom to kt ta trng. Amin X l:
A. anilin B. metylamin C. imetylamin D. benzylamin
Cu 18: Cho 9,0 gam glucoz phn ng hon ton vi lng d dung dch AgNO 3 trong NH3 (un
nng), thu c m gam Ag.Ga tr ca m l :
A. 16,2 B. 21,6 C. 5,4 D. 10,8
Cu 19: Hai cht no sau y u tham gia phn ng trng hp to ra polime ?
A. Vinyl clorua v caprolactam B. Axit aminoaxetic v protein
C. Etan v propilen D. Butan-1,3-ien v alanin
Cu 20: Tin hnh phn ng kh oxit X thnh kim loi bng kh CO (d) theo s hnh v:
Oxit X l:
A. Al2O3 B. K2O C. CuO D. MgO
Cu 21: Mt on mch PVC c 1000 mt xch. Khi lng ca on mch l:
A. 12500 vC B. 62500 vC C. 25000 vC D. 62550 vC
Cu 22: Cho C2H4(OH)2 phn ng vi hn hp gm CH 3COOH v HCOOH trong mi trng axit
(H2SO4), thu c ti a s este thun chc l:
A. 3 B. 2 C. 4 D. 1
Cu 23: Ba dung dch: glucoz, saccaroz v fructoz c tnh cht chung no sau y ?
A. un nng vi Cu(OH) 2 c kt ta gch.
B. Ha tan Cu(OH)2 cho dung dch mu xanh lam.
C. u tc dng vi dung AgNO 3/NH3 to kt ta Ag.
D. u tham gia phn ng thy phn.
Cu 24: Cht trng thi lng iu kin thng l:
A. Natri axetat B. Tripanmetin C. Triolein D. Natri fomat
Cu 25: Hn hp X gm Fe2O3, FeO v Cu (trong st chim 52,5% v khi lng). Cho m gam X
tc dng vi 420 ml dung dch HCl 2M d, thu c dung dch Y v cn li 0,2 m gam cht rn
khng tan. Cho dung dch AgNO 3 d vo Y thu c kh NO v 141,6 gam kt ta. Bit cc phn
ng xy ra hon ton. Gi tr ca m l:
A. 20 B. 32 C. 36 D. 24
Cu 26: Hn hp M gm mt peptit X v mt peptit Y u mch h ( c cu to t 1 loi amino
axit, tng s nhm CO-NH- trong 2 phn t l 5 ) vi t l mol X : Y=1 : 3. Khi thy phn hon ton
m gam M thu c 81 gam glyxin v 42,72 gam alanin. Gi tr ca m l:
A. 116,28 B. 109,5 C. 104,28 D. 110,28
Cu 27: Cho 34 gam hn hp X gm 2 este n chc mch h u thuc hp cht thm (t khi hi
ca X so vi O2 lun bng 4,25 vi mi t l mol ca 2 este). Cho X tc dng va vi 175 ml dung

dch NaOH 2M. C cn dung dch sau phn ng thu c hn hp Y gm hai mui khan. Thnh phn
phn trm v khi lng ca 2 mui trong Y l:
A. 46,58% v 53,42% B. 56,67% v 43,33% C. 55,43% v 55,57% D. 35,6% v 64,4%
Cu 28: Cho cc pht biu sau:
(a) Thy phn hon ton vinyl axetat bng NaOH thu c natri axetat v andehit fomic.
(b) Polietilen c iu ch bng phn ng trng ngng.
(c) iu kin thng anilin l cht kh.
(d) Tinh bt thuc loi polisaccarit.
(e) iu kin thch hp triolein tham gia phn ng cng hp H 2.
S pht biu ng l:
A. 2 B. 4 C. 5 D. 3
Cu 29: Cho 0,05 mol hn hp 2 este n chc X v Y phn ng va vi dung dch NaOH thu
c hn hp cc cht hu c Z. t chy hon ton Z thu c 0,12 mol CO2 v 0,03 mol Na2CO3
.Nu lm bay hi hn hp Z thu c m gam cht rn khan .Gi tr ca m l:
A. 3,48 B. 2,34 C. 4,56 D. 5,64
Cu 30: Cho cc cht sau: amiloz, amilopectin, saccaroz, xenluloz, fructoz, glucoz. S cht
trong dy b thy phn khi un nng vi dung dch axit v c l:
A. 3 B. 5 C. 6 D. 4
Cu 31: Hn hp no sau y thuc loi ipeptit ?
A. H2 N CH2 CO NH CH(CH3 ) COOH
B. H 2 N CH 2 CH 2 CO CH 2 COOH
C. H 2 N CH 2 CO NH CH 2 CO NH CH 2 COOH
D. H 2 N CH 2 CH 2 CO NH CH 2 CH 2 COOH
Cu 32: ha tan hon ton hn hp X gm 11,2 gam Fe v 4,8 gam Fe 2O3 cn dng ti thiu V
ml dung dch HCl 2M, thu c dung dch Y .Cho dung dch AgNO 3 vo d vo Y thu c m gam
kt ta . Gi tr ca V v m ln lt l:
A. 290 v 83,23 B. 260 v 102,7 C. 290 v 104,83 D. 260 v 74,62
Cu 33: X phng ha hon ton m gam triglixerit X bng lng va NaOH thu c 0,5 mol
gilixerol v 459 gam mui khan. Gi tr ca m l:
A. 444 B. 442 C. 443 D. 445
Cu 34: Cho hn hp X gm 0,56 gam Fe v Mg tc dng vi 250 ml dung dch CuSO 4. Sau khi cc
phn ng xy ra hon ton, thu c 0,92 gam kim loi. Nng mol/l ca dung dch CuSO 4 l:
A. 0,02M B. 0,04M C. 0,05M D. 0,10M
Cu 35: Cho 20 gam hn hp gm 3 amin no, n chc, l ng ng lin tip ca nhau (c trn
theo t l mol 1 : 10 : 5 v th t phn t khi tng dn) tc dng va vi dung dch HCl, thu c
31,68 gam hn hp mui. Cng thc phn t ca ba amin l :
A. C2H7N, C3H9N, C4H11N B. C3H7N, C4H9N, C5H11N
C. CH5N, C2H7N, C3H9N D. C3H8N, C4H11N, C5H13N
Cu 36: Cho 86,3 gam hn hp X gm Na, K, Ba v Al 2O3 (trong oxi chim 19,47% v khi
lng) tan ht vo nc, thu c dung dch Y v 13,44 lt kh H2 (ktc). Cho 3,2 lt dung dch HCl
0,75M vo dung dch Y. Sau khi cc phn ng xy ra hon ton, thu c m gam kt ta. Gi tr ca
m l:
A. 10,4 B. 27,3 C. 54,6 D. 23,4
Cu 37: X phng ha cht bo X, thu c glixerol v hn hp hai mui l natriolat, natri panmitat
c t l mol 1:2. Hy cho bit cht X c bao nhiu cng thc cu to ?
A. 3 B. 4 C. 1 D. 2
Cu 38: Nhn xt no sau y khng ng ?
A. Tripeptit Gly-Ala-Gly c phn ng mu biure.
B. Lin kt peptit l lin kt CO-NH- gia hai n v -amino axit.
C. Cc dung dch Glyxin, Alanin, Lysin u khng lm i mu qu tm.
D. Polipeptit b thy phn trong mi trng axit hoc kim.

Cu 39: Hn hp E gm cht X (C3H10N2O4) v cht Y (C3H12N2O3). X l mui ca axit hu c a
chc, Y l mui ca mt axit v c. Cho 3,86 gam E tc dng vi dung dch NaOH d, un nng, thu
c 0,06 mol hai cht kh (c t l mol 1 : 5) v dung dch cha m gam mui. gi tr ca m l:
A. 5,92 B. 4,68 C. 2,26 D. 3,46
Cu 40: Thc hin phn ng chuyn ha PVC thnh t clorin bng cch cho Clo tc dng vi PVC.
Trong t clorin, Clo chim 66,67% v khi lng. S mc xch trung bnh ca PVC phn ng vi
1 phn t Clo l:
A. 2 B. 3 C. 4 D. 1
----------HT----------

PHN TCH HNG DN GII
Cu 1: Chn B.
A. ng, Kim loi cng nht l Cr, kim loi mm nht l Cs.
B. Sai, dn in gim dn theo dy: Ag > Cu > Au > Al > Fe.
C. ng, Kim loi c nhit nng chy cao nht l W, kim loi c nng chy thp nht l Hg.
D. ng, Kim loi c khi lng ring ln nht l Os, kim loi c khi lng ring nh nht l Li.
Cu 2: Chn C.
Cng thc cu to CH3COOC2H5 CH3COOCH3 CH3COOCH=CH2 CH2=CH-COOCH3
Tn gi Etyl axetat Metyl axetat Vinyl axetat Metyl acrylat
Cu 3: Chn C.
- Fructoz v saccaroz iu kin thng tn ti dng tinh th mu trng.
- Amilopectin l mt on mch ca tinh bt c mch phn nhnh, l cht rn v nh hnh khng tan
trong nc ngui, trong nc nng (khong 65 oC) to thnh dung dch keo (gi l h dn).
- Xenluloz iu kin thng l cht rn, dng si mu trng, phn t c cu trc mch khng phn
nhnh, khng xon v c cu to t cc mc xch glucoz nn khi thy phn trong mi trng
axit thu c glucoz.
Vy cht rn X cn tm l xenluloz.
Cu 4: Chn D.
- iu ch t nilon-6 bng phn ng trng ngng axit--aminocaproic:
xt,p,t o
nH 2N [CH 2 ]5 COOH ( HN [CH 2 ]5 CO ) n nH 2O
Cu 5: Chn B.
Cu 6: Chn B.
Hp cht NH3 H2N-CH2-COOH CH3COOH CH3NH2
Mu qu m Xanh Khng mu Xanh
Cu 7: Chn C.
n C2H5OH 5
- Ta c: n C6H12O6 m C6 H12O6 300 (g)
2.H% 3
Cu 8: Chn C.
14,6
- Ta c: nGlyNa nAlaNa nGly Ala 0,1mol mmui 97nGlyNa 111nAlaNa 20,8(g)
146
Cu 9: Chn D.
- Amino axit l nhng hp cht hu c tp chc phn t cha ng thi nhm amino ( -NH2) v nhm
cacboxyl (-COOH).
Cu 10: Chn D.
0
- Phn ng : CH 3COOC 2 H 5 NaOH
t
CH 3COONa C2 H 5OH
0,1mol 0,04 mol 0,04 mol
m CH 3COONa 3, 28(g)
Cu 11: Chn C.
BT:e
nZn nH2 0,2mol m 65nZn mCu(rn khng tan) 15(g)

Cu 12: Chn D.
0
Cu 13: Chn C.
- Cu khng tc dng vi H2O trong khi Fe tc dng vi nc nhit cao to thnh cc oxit st
tng ng.
Vy c 3 kim loi Na, Ca v K trong dy tc dng vi nc nhit thng to dung dch baz
ln lt l NaOH, Ca(OH) 2 v KOH.
Cu 14: Chn A.
Polime thin nhin Polime tng hp
amiloz Nilon-6,6, cao su isopren, cao su buna
Cu 15: Chn B.
Cng thc C12H22O11 C6H12O6 (C6H10O5)n CH3COOH
Tn gi Saccaroz Glucoz Tinh bt Axit axetic
Mantoz Fructoz Xenluloz
Cu 16: Chn A.
- Cc polime mch phn nhnh thng gp l amilopectin v glicozen
- Cc polime mch khng gian thng gp l cao su lu ha v nha rezit.
- Cn li l cc polime mch phn nhnh.
Cu 17: Chn A.
- Cht X l anilin (C6H5NH2) khi ngoi khng kh th b oxi trong khng kh oxi ha thnh mu
nu en. Dung dch anilin khng lm i mu qu tm nhng tc dng vi nc brom to kt ta
trng theo phng trnh sau :
Cu 18: Chn D.
- Ta c : nAg 2nC6H12O6 0,1.108 10,8(g)
Cu 19: Chn A.
- Trng hp caprolactam to t capron
CH2 CH2 C O
n CH2 to N (CH2)5 C
CH2 CH2 C N n
H O
- Trng hp vinyl clorua to t poli(vinyl clorua)
n CH2 to, p, xt
CH CH2 CH
Cl Cl n
Cu 20: Chn C.
- nhit cao, kh CO, H2 c th kh c cc oxit kim loi ng sau Al trong dy in ha.
Vy oxit X l CuO.
Cu 21: Chn B.
- Ta c n = 1000, vy M (CH2 CH(Cl))1000 1000M C2H3Cl 62500
Cu 22: Chn A.
- C 3 este thun cha thu c l: C 2H4(OOCCH3)2, C2H4(OOCH)2 v HCOOCH2CH2OOCCH3.
- Lu : Este thun chc l este m trong phn t ch cha chc este m khng cha cc nhm chc
khc.
Cu 23: Chn B.
A. Sai, Ch c glucoz v fructoz un nng vi Cu(OH) 2 c kt ta gch.
B. ng, Tt c cc cht trn u ha tan Cu(OH) 2 cho dung dch c mu xanh lam.
C. Sai, Ch c glucoz v fructoz tc dng vi dung dch AgNO3/NH3 to kt ta Ag.
D. ng, Ch c saccaroz tham gia phn ng thy phn.
Cu 24: Chn C.
- Cc cht bo c to thnh t cc gc axt bo no thng trng thi rn cn cc cht bo c
to thnh t cc gc axt bo khng no thng trng thi lng.

Cu 25: Chn B.
amol bmol Cu(d ) :0,2m(g)
HCl(d )
- Qu trnh: Fe2O3 ,FeO,Cu
Fe2 ,Cu2 ,Cl ,H (d )
AgNO3
Ag,AgCl NO
m(g) cmol
dung dch Y 141,6(g)
m 143,5nAgCl
- Xt hn hp kt ta ta c :
BT:Cl
nAgCl nHCl 0,84mol nAg 0,195mol
108
- Khi cho X tc dng vi HCl v dung dch Y tc dng vi AgNO 3 th ta c h sau :
160nFe2O3 72nFeO 64nCu(p ) m m rn 160a 72b 64a 0,8m
a 0, 05
m 56.2a 56b b 0,2

Theo ta c Fe
0,525
0,525
mX m
c 0,035

BT:e
nFeO 2nCu(p ) 3nNO nAg b 2a 3c 0,195
m 32
nHCl 6nFe2O3 2nFeO 4nNO 6a 2b 4c 0,84
Cu 26: Chn C.
- Khi gp X v Y vi t l mol tng ng l 1 : 3 c X 3Y
XY3 3H 2O
nGly 1,08 9
+ T: XY3 l (Gly)9k (Ala) 4k .
nAla 0,48 4
m s mc xch(min) < s mc xch ca XY3 < s mc xch(max) 7.1 13k 7.3 k 1
(52).nX 9k 4k (52).nZ
nGly nAla nX nXY3 0,12mol

+ Vi k = 1 n(Gly)3 Ala nXY3 0,12mol
9 4 nY 3nXY3 0,36mol
- Khi thy phn m gam M th : nH2O nM nX nY 0,48mol v
- Quy i hn hp M thnh H2O, CH2 v C2H3ON.
+ Ta c : nC2H3ON nGly nAla 1,56mol v nCH 2 nAla 0,48mol
mM 57nC2H 3ON 14nCH 2 18nH 2O 104,28(g)
Cu 27: Chn A.
nNaOH
- Nhn thy rng 1 2 , nn trong hn hp este c 1 este c to thnh t phenol (hoc
neste
ng ng). Theo d kin bi ta c M X = 136 (C8H8O2), mc khc dung dch Y ch cha hai mui
khan nn hn hp X cha HCOOCH2C6H5(A) v HCOOC6H4CH3 (B) .
nA nB nX nA nB 0,25 nA 0,1mol
- Khi cho X tc dng vi NaOH th:
2nA nB nNaOH 2nA nB 0,35 nB 0,15mol
mmui 68nHCOONa 116nCH 3C6H 4ONa 36,5(g) %mHCOONa 46,58 v %mCH3C6H 4ONa 53,42
Cu 28: Chn A.
0
(a) Sai, Phn ng: CH3COOCH=CH2 + NaOH
t
CH3COONa + CH3CHO (andehit axetic)
xt,t o ,p
(b) Sai, Polietilen c iu ch bng phn ng trng hp: CH2 CH2 ( CH2 CH2 ) .
(c) Sai, iu kin thng anilin l cht lng.
(d) ng, Tinh bt v xenluloz thuc loi polisaccarit.
Ni, t 0
(e) ng, Phn ng: (C17 H33COO)3 C3H5 3H 2 (C17 H35COO)3 C3H5
triolein tristearin
Vy c 2 pht biu ng l (d) v (e)
Cu 29: Chn C.

nNaOH
- Nhn thy rng 1 2 , nn trong hn hp este c cha este c to thnh t phenol (hoc
neste
ng ng). Gi 2 este l A v B (vi CA 2 v C B 7)
nA nB 0,05 nA 0,04mol
- Este tc dng vi NaOH th :
nA 2nB nNaOH 0,06 nB 0,01mol
- Khi t hn hp Z th :
BT:C CA 2(HCOOCH 3 )
nA .CA nB.CB nNa2CO3 nCO2 0,04CA 0,01CB 0,15
CB 7(HCOOC6 H 5 )
mmui 68nHCOONa 116nC6H 5ONa 4,56(g)
Cu 30: Chn D.
- C 4 cht trong dy khi thy phn khi un nng vi dung dch axit v c l: amiloz, amilopectin,
saccaroz v xenluloz.
Cu 31: Chn A.
- ipeptit c to thnh t 2 n v - amino axit c s lin kt peptit l 1.
- Lu : cu B, D cht ban u khng c to thnh t cc - amino axit nn khng c gi l
peptit.
Cu 32: Chn B.
0,52
- Ho tan hon ton X th: nHCl(ti thiu) 2nFeCl 2 2(nFe 2nFe2O3 ) 0,52mol VHCl 0,26(l)
2

BT:e
nAg nFeCl 2 0,26mol
- Khi cho dung dch Y tc dng vi AgNO3 th:
nAgCl nHCl(ti thiu) 0,52mol
- Khi : m 108nAg 143,5nAgCl 102,7(g)
Cu 33: Chn D.
- Ta c: nNaOH(p ) 3nC3H 5(OH)3 1,5mol
BTKL
mx phng mmui 40nNaOH 92nC3H5(OH)3 445(g)
Cu 34: Chn B.
TGKL
nMg.M CuMg nFe(p ) .M CuFe mrn mFe,Mg(ban u) 0,005.40 8x 0,24 x 0,005
BT:e
nCuSO4 nMg nFe(p ) 0,01mol CM(CuSO4 ) 0,04M

Cu 35: Chn A.
- Gi X l cht c khi lng phn t nh nht trong 3 amin. Cho amin tc dng vi HCl th:
m mamin
nHCl mui
BTKL
0,32mol nX 0,02mol; nY 0,2mol v nZ 0,1mol
36,5
nX M X nY (M X 14) nZ (M X 28) mamin 2 M X 45
Vy 3 amin c CTPT ln lt l : C2H 7N,C3H 9N v C4H11N
Cu 36: Chn D.
n O(trong X) 86,3.0,1947
- Theo ta c : n Al2O3 0,35mol
3 16.3
- Khi ha tan hn hp X bng nc. Xt dung dch Y ta c:
+ n AlO2 2n Al2O3 0, 7 mol BTDT
n OH 2n H 2 2n AlO 2 0,5 mol
- Khi cho dung dch Y tc dng vi 2,4 mol HCl, v: n AlO2 n n H 4n AlO2 n
OH OH
4n AlO2 (n H n OH )
n Al(OH)3 0,3mol m Al(OH)3 23, 4(g)
3
Cu 37: Chn D.

- Gi A l gc C17H33COO- (oleat) v B l gc C15H31COO- (panmitat)
- X c hai cng thc cu to tha mn vi cc gc sau: A B B v B A B.
Cu 38: Chn C.
A. ng, Cc peptit c 2 lin kt CONH tr ln u tham gia phn ng mu biure.
B. ng, Lin kt peptit l lin kt CO-NH gia hai n v -amino axit.
C. Sai, Ch c lysin lm qu tm ha xanh, cn glyxin v alanin khng lm i mu qu tm.
D. ng, Tt c cc polipeptit b thy phn trong mi trng axit hoc kim.
Cu 39: Chn D.
- Gi a v b ln lt l s mol ca X v Y. Khi cho E tc dng vi NaOH th :
t0
NH 4OOC COONH 3CH 3 NaOH (COONa)2 NH3 CH3NH 2 H 2O
amol amol amol amol
t0
(CH 3NH 3 )2 CO3 NaOH 2CH 3NH 2 Na2CO3 H 2O
bmol 2bmol bmol
a 2b 0,05 a 0,01mol
Ta c mmui 134n(COONa)2 106nNa2CO3 3,46(g)
a 0,01 b 0,02mol
Cu 40: Chn A.
- Phn ng: (C2H3Cl)n + Cl2 C2nH3n-1Cln+1 + HCl
35,5(n 1)
- Ta c: %Cl 0,6667 n 2
12.2n 3n 1 35,5(n 1)

S GD T BC NINH THI TH LN 1 THPT QUC GIA NM 2017
THPT NGUYN NG O Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: t chy hon ton m gam hn hp gm xenluloz, tinh bt, glucoz v sacaroz cn 2,52lt O2
(ktc), thu c 1,8 gam nc. Gi tr ca m l
A. 3,06 B. 5,25 C. 3,15 D. 6,02
Cu 2: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c
th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam
X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88
gam cht rn khan. Gi tr ca m l:
A. . 10,56 B. 7,20 C. 8,88 D. 6,66
Cu 3: Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung
dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng
d dung dch AgNO3 trong NH3 th lng Ag thu c l.:
A. 0,095 mol B. 0,090 mol. C. 0,12 mol. D. 0,06 mol.
Cu 4: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau
phn ng thu c khi lng x phng l
A. 18,38 gam B. . 18,24 gam C. 16,68 gam D. 17,80 gam
Cu 5: Mt cht bo c cng thc: CH2(OCOC17H33) -CH(OCOC15H31)CH2(OCOC17H29 ). S mol H2
cn hiro ho hon ton 1 mol cht bo l:
A. 4 B. 5 C. 3 D. 1
Cu 6: Cho 8,8 gam CH3COOC2H5 phn ng ht vi dung dch NaOH (d), un nng. Khi lng mui
CH3COONa thu c l:
A. 12,3 gam. B. 16,4 gam C. 4,1 gam D. 8,2 gam
Cu 7: Hn hp X gm mt axit cacboxylic T (hai chc, mch h), hai ancol n chc cng dy ng
ng v mt este hai chc to bi T v hai ancol . t chy hon ton agam X, thu c 8,36gam CO2.
Mt khc un nng a gam X vi 100 ml dung dch NaOH 1M, sau khi phn ng xy ra hon ton, thm
tip 20 ml dung dch HCl 1M trung ho lng NaOH d, thu c dung dch Y. C cn Y thu c m
gam mui khan v 0,05 mol hn hp hai ancol c phn t khi trung bnh nh hn 46. Gi tr ca m l:
A. 7,09 B. 5,92 C. 6,53 D. 5,36
H 2 d (Ni, t o ) NaOH d ,t o HCl
Cu 8: Cho s chuyn ho: Triolein X Y Z
Triolein X Y Z. Tn ca Z l:
A. axit oleic B. axit panmitic. C. axit stearic. D. axit linoleic.
Cu 9: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi
dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1, C =12,
O = 16, Na = 23):
A. CH3COOC2H5. B. HCOOCH(CH3)2 C. C2H5COOCH3 . D. HCOOCH2CH2CH3
Cu 10: Este hai chc, mch h X c cng thc phn t C6H8O4 v khng tham gia phn ng trng bc.
X c to thnh t ancol Y v axit cacboxyl Z. Y khng phn ng vi Cu(OH)2 iu kin thng; khi
un Y vi H2SO4 c 170C khng to ra anken. Nhn xt no sau y ng?
A. Trong X c ba nhm CH3
B. Cht Z khng lm mt mu dung dch nc brom.
C. Cht Y l ancol etylic.
D. Phn t cht Z c s nguyn t cacbon bng s nguyn t oxi.
Cu 11: Este X c cng thc phn t C2H4O2 . un nng 9,0 gam X trong dung dch NaOH va n
khi phn ng xy ra hon ton thu c m gam mui. Gi tr ca m l:
A. 8,2 B. 10,2 C. 15,2 D. 12,3
Cu 12: Trong cng nghip sn xut rut phch nc ngi ta thc hin phn ng no sau y?
A. Cho dd axit fomic phn ng vi dung dch AgNO3 / NH3
B. . Cho anehyt fomic phn ng vi dung dch AgNO3 / NH3
C. Cho axetilen phn ng vi dung dch AgNO3 / NH3
D. . Cho dd glucoz phn ng vi dung dch AgNO3 / NH3
Cu 13: Hn hp hai cht hu c tc dng vi dung dch NaOH thu c hai mui ca hai axit n chc v
mt ru. Hai cht hu c l:
(1) X, Y l hai este ca cng mt ru. (2) X, Y l hai este ca cng mt axit.
(3) X, Y l mt este v mt axit. (4) X, Y l mt este v mt ru.
Nhng cu ng l
A. (1), (2). B. (2), (3). C. (3), (4). D. (1), (3).
Cu 14: Pht biu khng ng l:
A. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O
B. Thy phn (xc tc H+ ,to ) saccaroz cng nh mantoz u cho cng mt monosaccarit
C. Dung dch fructoz ho tan c Cu(OH)2
D. Sn phm thy phn xenluloz (xc tc H+ ,to ) c th tham gia phn ng trng gng
Cu 15: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2 , phn ng
c vi dung dch NaOH nhng khng c phn ng trng bc l
A. 4 B. 5 C. 9 D. 8
Cu 16: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s
nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d)
th lng NaOH phn ng l 10 gam. Gi tr ca m l
A. 16,5 B. 17,5 C. 14,5 D. 15,5
Cu 17: Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit
axetylsalixylic (o-CH3COO-C6H4COOH) dng lm thuc cm(aspirin). phn ng hon ton vi
43,2gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l:
A. 0,96 B. 0,24 C. 0,48 D. 0,72
Cu 18: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l:
A. 2 B. 3 C. 4 D. 1
Cu 19: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn
ng. Tn gi ca este l:
A. etyl axetat. B. metyl fomiat C. n-propyl axetat. D. metyl axetat
Cu 20: Cht no sau y khng thy phn trong mi trng axit?
A. Xenluloz B. Saccaroz. C. Tinh bt D. Glucoz
Cu 21: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch
nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi
lng dung dch nc vi trong ban u. Gi tr ca m l:
A. 20,0 B. 30,0 C. 13,5 D. 15,0
Cu 22: Polime thin nhin X c sinh ra trong qu trnh quang hp ca cy xanh. nhit thng,
X to vi dung dch iot hp cht c mu xanh tm. Polime X l:
A. saccaroz B. glicogen C. Tinh bt D. Xenluloz
Cu 23: Triolein khng tc dng vi cht (hoc dung dch) no sau y?
A. H2O (xc tc H2SO4 long, un nng) B. H2 (xc tc Ni, un nng).
C. Cu(OH)2 ( iu kin thng) D. Dung dch NaOH (un nng).
Cu 24: Thy phn este c cng thc phn t C4H6O2 (vi xc tc axit), thu c 2 sn phm hu c X
v Y. T X c th iu ch trc tip ra Y. Vy cht X l
A. . etyl axetat B. . ru etylic. C. ru metylic. D. axit fomic
Cu 25: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c
axetanehit. Cng thc cu to thu gn ca este l:
A. CH3COO-CH=CH2. B. CH2CH-COO-CH3.
C. HCOO-C(CH3)=CH2. D. HCOO-CH=CH-CH3
Cu 26: Mnh khng ng l:
A. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui
B. CH3CH2COOCH=CH2c th trng hp to polime
C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2

D. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3
Cu 27: t chy hon ton a mol X (l trieste ca glixerol vi cc axit n chc, mch h), thu c b
mol CO2 v c mol H2O (b c = 4a). Hiro ha m gam X cn 6,72 lt H2 (ktc), thu c 39 gam Y (este
no). un nng m1 gam X vi dung dch cha 0,7 mol NaOH, c cn dung dch sau phn ng, thu c
m2 gam cht rn. Gi tr ca m2 l:
A. 53,2 B. 52,6 C. 42,6 D. 57,2
Cu 28: Este X c cc c im sau:
- t chy hon ton X to thnh CO2 v H2Oc s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s
nguyn t cacbon bng mt na s nguyn t cacbon trong X).
Pht biu khng ng l:
A. Cht Y tan v hn trong nc.
B. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O
C. un Z vi dung dch H2SO4 c 170oC thu c anken
D. Cht X thuc loi este no, n chc.
Cu 29: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch
KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp
X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh
tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l:
A. C2H5COOH v C2H5COOCH3 B. CH3COOH v CH3COOC2H5
C. HCOOH v HCOOC3H7. D. HCOOH v HCOOC2H5
Cu 30: t chy hon ton 10 ml mt este cn 45 ml O2 thu c VCO2 : VH 2O 4 : 3 . Ngng t sn
phm chy thy th tch gim 30 ml. Cc th tch o cng iu kin. Cng thc ca este l:
A. C4H6O2 B. C4H6O4 C. C4H8O2 D. C8H6O4
Cu 31: Cho s chuyn ho sau:
C3 H 4O2 NaOH X Y ; X H 2 SO4long Z T
Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l:
A. HCHO, CH3CHO. B. CH3CHO, HCOOH.
C. HCOONa, CH3CHO. D. HCHO, HCOOH
Cu 32: Poli(metyl metacrylat) c to thnh t monome tng ng l
A. CH2=CH-COOCH3 B. CH=C(CH3)- COOCH2CH3
C. CH3COO-CH=CH2 D. CH2=C(CH3)-COOCH
Cu 33: Hp cht hu c mch h X c cng thc phn t C6H10O4 . Thu phn X to ra hai ancol n
chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l:
A. CH3OCO-COOC3H7 B. CH3OOC-CH2-COOC2H5
C. CH3OCO-CH2-CH2-COOC2H5. D. C2H5OCO-COOCH3
Cu 34: Hn hp E gm hai este n chc, l ng phn cu to v u cha vng benzen. t chy
hon ton m gam E cn va 8,064 lt kh O2 (ktc), thu c 14,08 gam CO2 v 2,88 gam H2O. un
nng m gam E vi dung dch NaOH (d) th c ti a 2,80 gam NaOH phn ng, thu c dung dch T
cha 6,62 gam hn hp ba mui. Khi lng mui ca axit cacboxylic trong T l:
Cu 35: Pht biu no sau y l ng?
A. Glucoz b kh bi dung dch AgNO3 trong NH3 .
B. Saccaroz lm mt mu nc brom
C. Amilopectin c cu trc mch phn nhnh.
D. Xenluloz c cu trc mch phn nhnh.
Cu 36: Cho s chuyn ho:
C3 H 6
ddBr2
X
NaOH
Y CuO , t o
Z
O2 , xt
T
CH3OH , To , xt
E
(este a chc) (este a chc)
Tn gi ca Y l:
A. propan-1,3-iol B. glixerol C. propan-1,2-iol D. propan-2-ol
Cu 37: Hn hp X gm 3 este n chc, to thnh t cng mt ancol Y vi 3 axit cacboxylic (phn t
ch c nhm -COOH); trong , c hai axit no l ng ng k tip nhau v mt axit khng no (c ng
phn hnh hc, cha mt lin kt i C=C trong phn t). Thy phn hon ton 5,88 gam X bng dung

dch NaOH, thu c hn hp mui v m gam ancol Y. Cho m gam Y vo bnh ng Na d, sau phn
ng thu c 896 ml kh (ktc) v khi lng bnh tng 2,48 gam. Mt khc, nu t chy hon ton 5,88
gam X th thu c CO2 v 3,96 gam H2O. Phn trm khi lng ca este khng no trong X l:
A. . 38,76%. B. 40,82%. C. 34,01%. D. 29,25%.
Cu 38: Dy gm cc dung dch u tham gia phn ng trng bc l:
A. Glucoz, mantoz, axit fomic, anehit axetic.
B. Glucoz, glixerol, mantoz, axit fomic
C. Glucoz, fructoz, mantoz, saccaroz
D. Fructoz, mantoz, glixerol, anehit axetic.
Cu 39: Cht X c cng thc phn t C H O , l este ca axit axetic. Cng thc cu to thu gn ca X l
A. HCOOC2H5 B. CH3COOCH3 C. HO-C2H4-CHO D. C2H5COOH
Cu 40: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng
A. . thy phn B. trng gng C. trng ngng D. ho tan Cu(OH)2
p n
1-C 6-D 11-B 16-A 21-D 26-D 31-B 36-A 41- 46-
2-C 7-A 12-D 17-D 22-C 27-B 32-D 37-C 42- 47-
3-A 8-C 13-D 18-B 23-C 28-C 33-B 38-A 43- 48-
4-D 9-A 14-B 19-B 24-B 29-B 34-C 39-B 44- 49-
5-A 10-D 15-C 20-D 25-A 30-A 35-C 40-A 45- 50-
HNG DN GII
Cu 1: Chn C
Phn tch: Nhn vo bi ta thy xenluloz, tinh bt, glucoz v saccaroz u l cacbohidrat nn ta gi
cng thc chung ca chng l Cn(H2O)m.
Khi t chy ta c: Cn(H2O)m + nO2 nCO2 + mH2O
Ta c: nCO2 nO2 2,52 22, 4 0,1125 mol
p dng nh lut bo ton khi lng ta c
m mO2 mCO2 mH 2O m 0,1125.44 1,8 0,1125.32 3,15 g
Cu 2: Chn C
Gi cng thc ca X l CnH2n+22kO2 (k < 2)
3n 1 k
Cn H 2 n 2 2 k O2 O2 nCO2 n 1 k H 2O
2
nO2 1 k 1 k
1,5 7/ 6 1/ 3
nCO2 2n 2n
Trong X c nhm COOH c 1 lin kt ri nn ta ch thay
k=1 hoc 2
k=1 suy ra n=3 ( nhn )
k=2 suy ra n=4,5 (loi)
Do CTPT l C3H6O2 , CT este duy nht l CH3COOCH3
CH3COOCH3 + KOH CH3COOK + CH3OH
Gi s mol KOH phn ng l x mol
nCH3COOK nCH 3OH nKOH p = x mol
nKOH 0,14, nKOH d = 0,14 x
mc cn = (0,14 x). 56 + 98x = 12,88 x = 0,12.
Vy khi lng este l: 0,12.74=8,88g
Cu 3: Chn A
H 75%
Saccaroz Glucoz + Fructoz
0,02 0,02.75% 0,02.75%
H 75%
Mantoz 2Glucoz
0,01 0,01.2.75%
Vy sau phn ng thy phn dung dch X gm: Glucoz: 0,03; Fructoz: 0,015; Saccaroz: 0,005;
nmantoz: 0,0025

Khi X tham gia phn ng trng bc ch c Glucoz, Fructoz v Mantoz phn ng to 2Ag
Vy s mol Ag l: 0, 03.2 0, 015.2 0, 0025.2 0, 095 mol
Cu 4: Chn D
Gi cng thc chung ca cht bo l (RCOO)3C3H5
(RCOO)3C3H5+3NaOH3RCOONa+C3H5 (OH)3
0,02 0,06 0,06 0,02
1
nC3 H5 OH nNaOH 0, 02 mol.
3
3
p dng nh lut bo ton khi lng ta c:
mEste mNaOH mx phng mC3H5 OH mx phng 17, 24 0, 06.40 0, 02.92 17,8 g
3
Cu 5: Chn A
Phn tch : Ta nhn thy ngay mch C17H33 c cha 1 lin kt pi , mch C15H31 l mch C no v mch
C17H29 cha 3 lin kt pi . M H2 ch cng vo mch C cha no ca cht bo nn s mol H2 cn hidroha
1 mol cht bo l 4mol
Cu 6: Chn D nCH3COONa nCH3COOC2 H5 8,8 / 88 0,1 mCH3COONa 0,1.82 8, 2 g
Cu 7: Chn A
Gi s mol axit, 2 ancol v este 2 chc l a,b,c mol.
nNaOH b 0,1 mol. nNaOH d nHCl 0,02 nNaOH p 0,08 2a 2c 1
Cu 8: Chn C
(C17H33COO)3C3H5+3H2(C17H35COO)3C3H5 (X)
(C17H35COO)3C3H5+3NaOH3C17H35COONa+C3H5 (OH)3 (Y)
C17H35COONa+HClC17H35COOH(Z) + NaCl
T ta c th suy ra Z l axit stearic.
Cu 9: Chn A
Phn tch: X l este no, n chc c t khi i vi CH4 l 5,5 nn MX = 88.
Gi cng thc ca este X l RCOOR1 .
Ta c: R +44 + R1 = 88 R +R1 = 44
Nu em un 2,2 gam este X vi dung dch NaOH d thu c 2,05g mui.
2, 2 2, 05
nmui nX 0, 025 mol Mmui 82
88 0, 025
R 44 23 82 R 15 R1 29.
Vy cng thc cu to thu gn ca X: CH3COOC2H5
Cu 10: Chn B
Phn tch: Este 2 chc mch h C6H8O4(k = 3) nn X l este khng no, hai chc .
TH1: X to bi 2 ancol n chc v 1 axit 2 chc
Ta c th phn tch ngc bi ton t di ln, t Y ta c: Y l ancol khi un nng Y vi H2SO4 c 1700C
khng to ra anken nn Y c cng thc l CH3OH loi p n C
Vy ancol khng no th 2 l: CH2 = CH CH2 OH
Vy axit no hai chc phi l (COOH)2 khng lm mt mu dung dch Brom. chn p n B
Vy CT ca X l CH2 = CH CH2 OOC COOCH3
TH2: X to bi 1 ancol 2 chc v 2 axit n chc
Nu X to bi ancol hai chc (Y) v hai axit n chc.
+ Y khng phn ng vi Cu(OH)2 iu kin thng n 3.
Nu n =3, cng thc phn t C3H6(OH)2 (ancol no, hai chc), hai axit HCOOH v CH3COOH (axit no, n
chc). Khng ph hp v este c phn ng trng gng v tha 2 nguyn t H. Nu n = 4, Cng thc phn
t C4H6(OH)2 (ancol khng no, hai chc), axit HCOOH (axit no, n chc). Khng ph hp v este c phn
ng trng gng
Cu 11: Chn B
Phn tch: Este X c cng thc phn t C2H4O2 nn X ch c cng thc l CH3 .
Khi un nng 9g X trong dung dch NaOH va n khi phn ng xy ra hon ton ta c PTHH
HCOOCH3 + NaOH HCOONa +CH3OH

9
nHCOONa nX 0,15 m 0,15.68 10, 2 g
60
Cu 12: Chn D
Phn tch: Trc ht cc em phi bit c rng trong cng nghip sn xut rut phch th sn phm sinh ra
phi c Ag nn ta loi c p n C. i vi p n A,B vi phn ng sn xut trong cng nghip ta cn 1
lng rt ln cht tham gia nhng m axit fomic v anehit fomic rt kh iu ch 1 lng ln v n cn
rt c hi nn Glucoz l la chn ng. Ta chn p n D.
Cu 13: Chn D
Phn tch: Hn hp hai cht hu c khi tc dng vi NaOH thu c hai mui ca hai axit n chc v ch
thu c 1 ru vy hai cht phi l este v hai este ca cng 1 ru. (1) ng. Hoc l 1 trong hai
cht 1 este v 1 axit c gc axit khc nhau (3) ng.
Vy p n l (1) v (3).
Cu 14: Chn B
A. Dung dch Mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O . ng
B. Sai V Thy phn (xc tc H+,t0) Saccaroz thy phn ra Glucoz v Fructoz cn Mantoz khi thy
phn ch cho ra 1 monosaccarit l Glucoz.
C. Dung dch fructoz ha tan c Cu(OH)2. ng
D. Sn phm thy phn xenluloz (xc tc H+,t0) c th tham gia phn ng trng gng. ng
Cu 15: Chn C
Phn tch: Cng thc phn t C5H10O2 , phn ng c vi dung dch NaOH nhng khng phn ng trng
bc th cht X phi l axit hoc l este nhng este y khng cha gc HCOO-.
Vy cc CTCT cn tm l: CH3CH2CH2CH2COOH, CH3CH(CH3 )CH2COOH,
CH3CH2CH(CH3 )COOH, CH3C(CH3 )2COOH CH3CH2CH2COOCH3 , CH3CH2COOCH2CH3 ,
CH3CH(CH3 )COOCH3 , CH3COOCH2CH2CH3 , CH3COOCH(CH3)CH3
Vy c tt c l 9 CT
Cu 16: Chn A
Gi cng thc ca X l (RCOO)2C2H4 .
Phn tch: Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Vy nn trong phn t
este c 5C. M nhn vo CT ca X ta thy 4C nn CT ca X l HCOOC2H4OOCCH3 .
1 1 10
V este ny l 2 chc nn: neste nNaOH . 0,125
2 2 40
Vy khi lng m l: m = 0,125.132 = 16,5g
Cu 17: Chn D
CH3COO-C6H4 -COOH+3KOHCH3COOK+KOC6H4 -COOH+2H2O
43, 2
naxit axetylsalixylic 0, 24 nKOH 3.0, 24 0, 72 mol V 0, 72 lt
180
Cu 18: Chn B
Phn tch: Cng thc C2H4O2 ng vi cc cng thc este no v axit no, n chc, mch h, hoc l tp chc
Vy CTCT ca X l HCOOCH3 , CH3COOH,OH-CH2 -CHO
Vy c tt c 3 cng thc.
Cu 19: Chn B
Phn tch: Gi cng thc ca este no, n chc l CnH2nO2 .
3n 2
Phn ng t chy: CnH 2 nO2 O2 nCO2 nH 2O
2
3n 2
V sau phn ng: nCO2 nO2 n n 2
2
Vy CTCT este ch c: HCOOCH3 (metyl fomiat)
Cu 20: Chn D
Cht khng phn ng thy phn trong mi trng axit l Glucoz.
Ch : i vi cacbohirat th ch c Glucoz v Fructoz l khng thy phn c trong mi trng axit.
Cu 21: Chn D
C6H12O6 2C2H5OH + 2CO2
Cu 22: Chn C

Phn tch: Trong qu trnh quang hp cy xanh to ra cht X, X to vi dung dch iot hp cht c mu xanh
tm. Polime X l tinh bt
6nCO2 5nH 2O as
C6 H10O5 n 6nO2
Cu 23: Chn C
Phn tch: trc ht chng ta phi bit c CT ca triolein l (C17H33COO)3C3H5 .
N c y tnh cht ca 1 este khng no, a chc.
A. ng v este c phn ng thy phn.
B. ng v este khng no c phn ng vi H2, xc tc Ni.
C. Sai v este khng c kh nng phn ng vi Cu(OH)2 iu kin thng.
D. ng v este c tc dng vi NaOH
Cu 24: Chn B
Phn tch: Thy phn este no, n chc thu c 2 sn phm hu c X v Y.
T X c th iu ch trc tip ra Y nn X phi l ru v Y l axit.
Vy ta c th loi c p n A v D
Nu X l ru metylic th th este c CTCT l C2H5COOCH3 .
Ta nhn thy t CH3OH khng th iu ch trc tip ra C2H5COOH nn loi p n C
Nu X l ru etylic th este c CTCT l CH3COOC2H5 .
Ta nhn thy t C2H5OH c th iu ch c trc tip ra CH3COOH nn chn p n B
C2 H 5OH O2 men giam
CH 3COOH H 2O
Cu 25: Chn A
Phn tch: Khi thy phn este c cng thc phn t l C4H6O2 nn trong mch Cacbon c 1 lin kt . Khi
thy phn trong mi trng axit thu c axetanehit c cng thc l CH3CHO nn cng thc ca este l
CH3COO CH = CH2
Cu 26: Chn D
A. ng v CH3CH2COOCH=CH2+NaOHCH3CH2COONa+CH3CHO+H2O
B. ng
C. ng v y l este khng no nn c th tc dng c vi dung dch Brom.
D. Sai v CH3CH2COOCH = CH2 c ni i gc ru cn CH2 = CHCOOCH3 c ni i gc axit nn
chng khng th l ng ng ca nhau.
Cu 27: Chn B
Phn tch: Gi cng thc Trieste ca glixerol v axit n chc, mch h l CnH2n42kO6 (k l s lin kt
trong gc axit). Gi s mol ca X l x mol.
CnH2n42kO6 nCO2 + (n 2 k)H2O
Ta c: nCO2 nH2O 4nX nx x n 2 k 4x k 2
Vy cng thc ca X l CnH2n8O6 .
CnH2n8O6 + 2H2 CnH2n4O6
x 2x
6, 72
nH 2 0,3 2 x x 0,15
22, 4
p dng nh lut bo ton khi lng ta c: mX mH 2 mY mX 39 0,3.2 38, 4 g
X + 3NaOHmui +C3H5 (OH)3
0,15 0,7
Vy sau phn ng NaOH d
Ta c : nC3H5 OH nX 0,15 mol
3
p dng nh lut bo ton khi lng ta c

mCR mX mNaOH mC3H5 OH 38, 4 0, 7.40 0,15.92 52, 6
3
Cu 28: Chn C
Phn tch: Thy phn X trong mi trng axit thu c cht Y v Z. t chy hon ton X to thnh s mol
CO2 bng s mol nc nn X phi l este no, n chc, mch h. Khi X l este no, n chc, mch h thy
phn ra cht Y tham gia c phn ng trng gng nn Y l HCOOH. Vy CT este l HCOOCnH2n+1

Vy cht Z l CnH2n+1OH, trong Z c s nguyn t C bng mt na s nguyn t C trong X nn ta c:
n 1
n n 1
2
Vy CT este l HCOOCH3.
A. ng v Y l HCOOH tan v hn trong nc.
B. ng v 1 mol C2H4O2 khi t chy sinh ra 2 mol CO2 v 2 mol nc.
C. Sai v Z l CH3OH khi un vi dung dch H2SO4 c 1700C th thu c xeton ch khng phi l anken.
D. ng v X l este no, n chc.
Cu 29: Chn B
Phn tch : Cho hn hp X gm hai cht hu c no, n chc tc dng va vi dung dch KOH thu c
mt mui v mt ancol nn X c th gm :
RCOOR R OH RCOOH
hoc hoc (R ' H )
RCOOH RCOOR ' R ' OH
Ta c : nKOH = 0,04mol > nancol = 0,015mol
n y, nhn vo 4 p n ta thy X phi l RCOOR v RCOOH
nRCOOR nancol 0,015 v nRCOOH 0,04 0,015 0,025mol
t cng thc ca hai cht trong X l CnH2nO2 v CmH2mO2 (n<m)
nCn H 2 nO2 0, 025mol; nCm H 2 mO2 0, 015mol nH 2O nCO2 0, 025n 0, 015m C
mbnh tng mCO2 mH 2O (0, 025n 0, 015m).(44 18) 6,82 22 5n 3m n 2 v m 4
Vy X gm CH3COOH v CH3COOC2H5 .
Ch : Khi cho hn hp CO2 v H2O vo bnh ng dung dch Ca(OH)2 th khi lng bnh tng chnh l
khi lng CO2 v H2O thm vo. Cn khi lng dung dch thay i l do khi lng kt ta CaCO3 tr i
tng khi lng CO2 v H2O thm vo.
Cu 30: Chn A
Phn tch: Khi ngng t sn phm chy thy th tch gim 30ml , vy th tch gim chnh l th tch ca
nc.
VH 2O 30ml VCO2 40ml
10 ml este X + 45ml O240 ml CO2+ 30ml H2O
p dng nh lut bo ton nguyn t ta c:
VO 2.40 30 45.2 20 ml
Gi CT este l CxHyOz
Ta c: x 40 :10 4; y (30.2) :10 6; z 20 :10 2
Vy CTPT ca X l C4H6O2
Cu 31: Chn B
Phn tch: Nhn vo p n ta thy khi thy phn C3H4O2 trong NaOH thu c X,Y m Y trong p n
khng c nc, vy X y ch c th l este.
V C3H4O2 c 1 lin kt trong mch Cacbon, m p n Y ch l mui hoc anehit vy este phi c dng
HCOOCH = CH2
HCOOCH = CH2 + NaOH HCOONa + CH3CHO + H2O
V X tc dng c vi H2SO4 nn X l HCOONa.
2HCOONa + H2SO4 Na2SO4 + 2HCOOH (Z)
Vy Y, Z ln lt l CH3CHO,HCOOH
Cu 32: Chn D
Poli(metyl metacrylat ) c to thnh t monome tng ng l CH2 = C(CH3 ) COOCH3
Cu 33: Chn B
Phn tch: X c cng thc l C6H10O4 khi thy phn to ra 2 ancol n chc nn X l este c 2 chc ancol
Vy X c dng ROOC-R1-COOR2. S Cacbon trong R, R1, R2 l 4. to ra hai ancol trong s Cacbon
trong 2 ancol gp i nhau vy 2 ancol l H3OH v C2H5OH . Vy CT ca X l: CH3OOC CH2
COOC2H5
Cu 34: Chn C
14, 08 8, 064 2,88
nCO2 0,32; nO2 0,36; nH 2O 0,16
44 22, 4 18

mE mO2 mCO2 mH 2O mE 5, 44 g
Cu 35: Chn C
A. Sai v Glucoz b oxi ha bi dung dch AgNO3/NH3
B. Sai v Saccaroz khng lm mt mu dung dch Brom. Ch c Glucoz v Mantoz mi lm mt mu
dung dch Brom.
C. ng
D. Sai v Xenluloz c cu trc mch thng.
Cu 36: Chn A
PTHH: C3H6 + Br2 C3H6Br2 (X)
C3H6Br2 +2NaOH C3H6 (OH)2 (Y) + 2NaBr
to
C3H6 (OH)2 + CuO CH2 (CHO)2 (Z) + Cu+ H2O
xt
CH2 (CHO)2 + O2 CH2 (COOH)2 (T)
xt,to
CH2 (COOH)2+2CH3OH CH2 (COOCH3 )2+2H2O (E)
T y ta c th suy ra c C3H6 y l xicloankan nn khi cng Brom th ch cng m vng C1 v C3
nn Y l propan-1,3-iol
Cu 37: Chn C
Phn tch: i vi cc dng bi ton ny, ta c cch tnh t di tnh ln. Ta s xut pht t ancol Y. V cc
este u n chc nn khi thy phn ta cng thu c ancol Y n chc.
0,896
Xt ancol Y c dng R OH, nH 2 0, 04
22, 4
1
R OH Na R ONa H 2
2
0,08 0,08 0,08 0,04
Ta c khi lng bnh tng mY mH 2 2, 48 mY 2, 48 0, 04.2 2,56 g
2,56
MY 32 Y : CH 3OH
0, 08
neste nY 0,08 nO X 0,16 mO 2,56
3,96
nH 2O 0, 22
18
p dng nh lut bo ton khi lng trong X ta c:
2,88
mC mX mO mH 5,88 2,56 0, 22.2 2,88 g nCO2 nC 0, 24 mol
12
Ta c khi t chy este no, n chc th s mol CO2 bng s mol nc, khi t chy este khng no c 1 lin
kt C=C th
neste khng no nCO2 nH 2O 0, 24 0, 22 0, 02 neste no 0, 08 0, 02 0, 06
nCO2 0, 24
C 3
nX 0, 08
2 este no l HCOOCH3 (a mol) v CH3COOCH3 (b mol),
cn este khng no l CnH2n2O2 0,02 mol
p dng nh lut bo ton C ta c:
2a 3b 0, 02n 0, 24 v a b 0, 06 b 0, 02n 0,12 n 6
axit khng no c ng phn hnh hc th s C trong axit khng no t nht phi bng 4.
Vy trong este ca axit vi CH3OH s C t nht l 5 vy n=5
Vi n 5 b 0, 02, a 0, 04 mHCOOCH3 mCH3COOCH3 3,88 g
meste khng no 5,88 3,88 2 g %meste khng no 2 5,88 . 100% 34, 01%
Cu 38: Chn A
Phn tch: Cc cht tham gia phn ng trng bc l sau phn ng sn phm sinh ra c Ag.
A. ng
B. Sai v Glixerol khng tham gia phn ng trng bc.
C. Sai v Saccaroz khng tham gia phn ng trng bc.
D. Sai v Glixerol khng tham gia phn ng trng bc.
Cu 39: Chn B
Cht X c cng thc phn t l C3H6O2 l este ca axit axetic nn c dng CH3COOCH3 .
Cu 40: Chn A
Tinh bt, xenluloz, saccaroz v mantoz u c phn ng thy phn.
B. Sai v tinh bt v saccaroz khng tham gia phn ng trng gng.
C. Sai
D. Sai v tinh bt khng ha tan Cu(OH)2

THPT YN LC Thi gian lm bi: 50 pht, khng k thi gian pht

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Ln men m gam glucoz vi hiu sut 72%. Lng CO2 sinh ra c hp th ton ton vo 500
ml dd hn hp gm NaOH 0,1M v Ba(OH )2 0,2M sinh ra 9,85 gam kt ta. Gi tr ca m l
Cu 2: Thy phn 324 g tinh bt vi hiu sut ca phn ng l 75%, khi lng glucoz thu c l:
A. 360 gam B. 270 gam C. 250 gam D. 300 gam
Cu 3: Phng n no di y c th phn bit c saccaroz, tinh bt v xenluloz dng bt?
A. Cho tng cht tc dng vi dung dch iot.
B. Cho tng cht tc dng vi dung dch
C. Ho tan tng cht vo nc, sau un nng v th vi dung dch iot.
D. Cho tng cht tc dng vi vi sa
Cu 4: t chy hon ton mt amin n chc, no, bc 2 thu c CO2 v H2O vi t l mol tng
ng l 2:3. Tn gi ca amin l
A. imetylamin. B. ietylamin.
C. metyl iso-propylamin. D. etyl metylamin.
Cu 5: Ru no sau y dng iu ch andehit propionic:
A. etylic B. i-propylic C. n-butylic D. n-propylic
Cu 6: Ion OH c th phn ng c vi cc ion no sau y:
A. Fe3 ; Mg 2 ; Cu 2 ; HSO4
B. Fe2 ; Zn 2 ; HS ; SO42
C. Ca 2 ; Mg 2 ; Al 3 ; Cu 2
D. H ; NH 4 ; HCO3 ; CO32
Cu 7: Tng s p, e, n trong hai nguyn t A v B l 142, trong tng s ht mang in nhiu hn tng
s ht khng mang in l 42. S ht mang in ca B nhiu hn ca A l 12. S hiu nguyn t ca A
v B l
A. 17 v 29 B. 20 v 26 C. 43 v 49 D. 40 v 52
Cu 8: t chy hon ton m gam mt ancol (ru) n chc X thu c 4,4 gam CO2 v 3,6 gam H2O
. Oxi ho m gam X (c xc tc) thu c hn hp Y (h = 100%). Cho Y tc dng ht vi dung dch
AgNO3 trong NH3 thu c 30,24 gam Ag. S mol anehit trong Y l
A. 0,04 mol. B. 0,05 mol. C. 0,06 mol. D. 0,07 mol.
Cu 9: Cho 360 g glucoz ln men thnh ancol etylic v cho ton b kh CO2 sinh ra hp th vo dd
NaOH d c 318 g mui. Hiu sut phn ng ln men l

A. 75,0% B. 80,0% C. 62,5% D. 50,0%.
Cu 10: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt mu
hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml dd NaOH
0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l
A. 35,24% B. 45,71% C. 19,05% D. 23,49%
Cu 11: Ha tan ht 7,74 gam hn hp Mg, Al bng 500ml dung dch HCl 1M v H2SO4 long 0,28 M
thu c dung dch X va 8,736 lt H2. C cn dung dch X thu c khi lng mui l
Cu 12: Cho 10,0 lt H2 v 6,72 lt Cl2 (ktc) tc dng vi nhau ri ho tan sn phm vo 385,4 gam
nc ta thu c dung dch X. Ly 50,000g dung dch X tc dng vi dung dch AgNO3 thu c 7,175
gam kt ta. Hiu sut phn ng gia H2 v Cl2 l:
A. 33,33% B. 45% C. 50% D. 66,67%.
Cu 13: Cho 6,4 gam Cu vo bnh cha 500 ml dung dch HCl 1M, sau cho tip 17 gam NaNO3 thy
thot ra V lt kh NO (ktc). Tnh V
A. 1,12lt B. 11,2lt C. 22,4 lt D. 1,49 lt.
Cu 14: C bao nhiu este mch h c cng thc phn t l C5H8O2 khi b x phng ha to ra mt
anhit? (Khng tnh ng phn lp th)
A. 2 B. 4 C. 1 D. 3
NH3 H 2O
Cu 15: Cho s : X Y Z T X .
0 0
t t
Cc cht X, T (u c cha nguyn t C trong phn t) c th ln lt l

A. CO2 , NH 4 , HCO3 B. CO, NH 4 HCO3
C. CO2 , NH 4 2 CO3 D. CO2 , Ca HCO3 2

Cu 16: Mt pentapeptit c to ra t glyxin v alanin c phn t khi 345 vc . S gc glyxin v
alanin trong chui peptit trn l:
A. 3 v 2 B. 1 v 4 C. 4 v 1 D. 2 v 3.
Cu 17: Dy cc cht u c phn ng thu phn l
A. tinh bt, xenluloz, protein, saccaroz, PE.
B. tinh bt, xenluloz, protein, saccaroz, lipit.
C. tinh bt, xenluloz, protein, saccaroz, glucoz.
D. tinh bt, xenluloz, fructoz.
Cu 18: C bao nhiu ancol thm, cng thc C8H10O5 khi tc dng vi CuO un nng cho ra anehit ?
A. 3 B. 5 C. 4 D. 2
Cc ancol thm, cng thc C8H10O khi tc dng vi CuO un nng cho ra anehit l :
C6 H 4 CH3 CH2OH o, m, p ; C6 HCH 2CH 2OH
Cu 19: Dy gm cc cht u lm qu tm m chuyn sang mu xanh l
A. amoni clorua, metyl amin, natri hidroxit B. anilin, metyl amin, amoniac
C. anilin, amoniac, natri hidroxit D. metyl amin, amoniac, natri axetat.
Cu 20: C cc cp cht sau: Cu v dung dch FeCl3 ; H 2O v dung dch CuSO4; H2S v dung dch
FeCl3; dung dch AgNO3 v dung dch FeCl3
S cp cht xy ra phn ng iu kin thng:

A. 3 B. 2 C. 1 D. 4.
Cu 21: phn bit cc dung dch glucoz, saccaroz v anehit axetic c th dng cht no trong cc
cht sau lm thuc th ?
A. Cu OH 2 / OH B. NaOH C. HNO3 D. AgNO3 / NH 3
Cu 22: Thy phn 34,2 gam mantozo trong mi trng axit (hiu sut 80%) sau trung ha axit d
th thu c dung dch X. Ly X em tc dng vi lng d dung dch AgNO3 / NH 3 thu c bao
nhiu gam bc:
Cu 23: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam
mui ca axit hu c. Cng thc cu to thu gn ca X l:
A. CH 2 CHCOOH B. CH 2CH 3COOH C. CH 3COOH D. HC CCOOH
Cu 24: Hirat ha 2 anken ch to thnh 2 ancol. Hai anken l:
A. 2-metylpropen v but-1-en. B. propen v but-2-en.
C. eten v but-2-en. D. eten v but-1-en.
Cu 25: Hn hp kh X gm C2 H 6 , C3 H 6 v C4 H 6 .T khi ca X so vi H2 bng 24. t chy hon
ton 0,96 gam X trong oxi d ri cho ton b sn phm chy vo 1 lt dung dch Ba(OH)2 0,05M. Sau khi
cc phn ng xy ra hon ton, thu c m gam kt ta. Gi tr ca m l:
A. 13,79 gam B. 9,85 gam C. 7,88 gam D. 5,91 gam.
nCO 2 3,5nx 0, 07 mol ta c nBaOH 0,05 mol nBaCO3 0,03 mol v nBa HCO3 0, 02 mol
2 2
m 0, 03.197 5,91 gam

Cu 26: C bao nhiu ankin ng vi cng thc phn t C5H8
A. 2 B. 3 C. 1 D. 4
Cu 27: Ho tan hon ton m gam Al vo dung dch HNO3 rt long th thu c hn hp gm 0,015
mol kh NO2 v 0,01mol kh NO (phn ng khng to NH4NO3). Gi tr ca m l
Cu 28: S ng phn dn xut halogen bc I c CTPT C4H9Cl l:
A. 4 B. 3 C. 5 D. 2
Cu 29: C 3 cht lng: benzen , anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn
bit 3 cht lng trn l:
A. dd phenolphtalein B. dd NaOH C. dd Br2 D. Qu tm
Cu 30: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z),
este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc
dng c vi dung dch HCl l
A. X, Y, Z, T B. X, Y, T C. X, Y, Z D. Y, Z, T
Cu 31: un nng 13,875 gam mt ankyl clorua Y vi dung dich NaOH, tch b lp hu c, axit ha
phn cn li bng dung dich HNO3, nh tip vo dd AgNO3 thy to thnh 21,525 gam kt ta. CTPT
ca Y l
A. C4H9Cl B.C2H5Cl C. C3H7Cl D. C5H11Cl
Cu 32: Hp th ton b 0,896 lt CO2 vo 3 lt dd Ca(OH)2 0,01M c:
A. 1g kt ta B. 2g kt ta. C. 3g kt ta D. 4g kt ta
Cu 33: Cho cc phn ng sau:
a. Cu(HNO3)2 long e, HCHO Br2 H 2O
b. Fe2O3+ H2SO4 f, glucozo

men
c. FeS + dung dch HCl g, C2 H 6 Cl2

askt
d. NO2 + dung dch NaOh h, glixerol + Cu OH 2

S phn ng thuc loi phn ng oxi ha - kh l:
A. 6 B. 7 C. 5 D. 4
Cu 34: Trong cc th nghim sau:
(1) Thm mt lng nh bt MnO2 vo dung dch hiro peoxit
(2) Sc kh SO2 vo dung dch Br2 ri un nng.
(3) Cho kh NH3 tc dng vi CuO t nng.
(4) Cho KClO3 tc dng vi dung dch HCl c.
(5) Cho kh O3 tc dng vi dung dch KI.
(6) Cho t t n d dung dch NaOH vo dung dch AlCl3
(7) Cho dung dch Na2S vo dung dch AlCl3
S th nghim to ra n cht l
A. 3 B. 6 C. 4 D. 5
Cu 35: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48
lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va
n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l:
A. isopropyl axetat B. etyl axetat
C. metyl propionate D. etyl propionat.
Cu 36: Trong phn t benzen, c 6 nguyn t C u trng thi lai ho:
A. sp 2 B. sp3 C. sp D. sp 2 d
Cu 37: Dy gm cc cht u phn ng vi phenol l:
A. nc brom, anehit axetic, dung dch NaOH.
B. nc brom, axit axetic, dung dch NaOH.
C. dung dch NaCl, dung dch NaOH, kim loi Na.
D. nc brm, anhidrit axetic, dung dch NaOH .
Cu 38: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t
ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l:
A. 75% B. 62,5% C. 50% D. 55%
Cu 39: Cho 0,94 g hn hp hai anehit n chc, no, k tip nhau trong dy ng ng tc dng vi
dung dch AgNO3 trong NH3 thu c 3,24 gam Ag. CTPT ca hai anehit l
A. butanal v pentanal B. etanal v propanal
C. propanal v butanal D. etanal v metanal.
Cu 40: Cht no sau y c tn gi l vinyl axetat?
A. CH 2 CH COOCH 3 B. CH 3COO CH CH 2
C. CH 3COOC2 H 5 D. CH 2 C CH3 COOCH3

P N V LI GII
Cu 1:
p n : A
Hng dn :
n OH
nNaOH 2nBaOH 0, 05 0,1.2 0, 25mol
2
9,85
n nBaCO3 0, 05mol nBa HCO3 nBa OH nBaCO3 0,1 0, 05 0, 05mol
197 2 2

nNaHCO3 nCO2 2nBa HCO3 nBaCO3 nNaOH
2
nCO2 0,05 2.0,05 0,05 0, 2mol
Ta c: C6 H12O6
le
n men
2C2 H 5OH 2CO2
nCO2 1 0,1 5mol

nGlu . . mGlu 25gam
2 H % 0,72 35
Cu 2:
p n : B
2
mol
Hng dn : nC H
6 10O5 n
C6 H10O5 n nH2O nC6 H12O6

nC6 H12O6 2.0, 75 1,5mol mC6 H12O6 1,5.180 270 gam
Cu 3:
p n : C
Hng dn : - Ha tan cc cht vo nc, xenlulozo khng tan, tinh bt v saccarozo tan(Tinh bt tan 1
phn)
- Cho I2 vo, tinh bt b ha xanh
Cu 4:
p n : D
Hng dn : nCO2 : nH 2O 2 : 3 nC : nH 1: 3
admin tha mn : C3 H9 N CH3 NHCH 2CH3 : etyl metylamin
Cu 5:
p n : D
Hng dn : CH3CH 2CH 2OH CuO CH3CH 2CHO Cu OH 2
Cu 6:
p n : A
Fe3 3OH Fe OH 3
Mg 2 2OH Mg (OH ) 2
Hng dn :
Cu 2 2OH Cu OH 2
HSO4 + OH SO42 + H 2O
Cu 7:
p n : B

Hng dn : t s p v n ca A; s p v n B ln lt l : x, y; z, t
2 x y 2 z t 142 2 x 2 z 92
z 2
Ta c : 2 x 2 z y t 42 y t 50
2 z 2 x 12 z x 6 x 20

S hiu nguyn t ca A v B l 20 v 26
Cu 8:
p n : A
Hng dn : nCO2 0,1 mol; nH 2O 0, 2mol Ancol no, n chc
nancol nH 2O nCO2 0,1mol CH 3OH
Ta c 4nCH3OH nAg 0, 28 mol >2nCH3OH nn khi oxi ha CH3OH ta thu c HCHO v HCOOOH .
nHCHO nHCOOH nCH3OH 0,1

nHCHO 0, 04

4nHCHO 2nHCOOH nAg 0, 28 nHCOOH 0, 06

Cu 9:
p n : A
318
Hng dn : nGlu 2 mol; nNa2CO3 3 mol (V NaOH d nn ch sinh ra Na2CO3)
106
Cu 10:
p n : C
Hng dn: nBr2 0, 02 mol
mCH3COOH mCH 2CHCOOH mCH 3CH 2COOH 3,15

Ta c : nCH 2CHCOOH nBr2 0, 02 mol

nCH3COOH nCH 2CHCOOH nCH 3CH 2COOH nNaOH 0, 045 mol
60nCH3COOH 72nCH 2CHCOOH 74nCH3CH2COO 3,15 nCH3COOH 0, 01

nCH 2CHCOOH nBr2 0, 02 mol nCH2CHCOOH 0, 02

nCH3COOH nCH 2CHCOOH nCH3CH2COOH 0, 045 mol nCH3CH2COOH 0, 015
mCH COOH 0,6 gam %CH3COOH x 19,05%
3
Cu 11:
p n : B
Hng dn : nH 2 0,39 mol , nH nHCl 2nH2 SO4 0,78 mol =2nH2
mx mkim loai mCl mSO2 38,93 gam

4
Cu 12:
p n : D
Hng dn :
7.175
Ta c nAgCl 0, 05 mol nHCl 0, 05 mol
143.5
Mt khc , c 50g hn hp A th c 0,05 mol HCl, ngha l trong cn 48,175g H2O

Vy c 48,175g H2O th c 0,05 mol HCl => 385,4g H2O th c 0,4 mol HCl
Ta c H2 + Cl2 2HCl
0, 4
VH 2 VCl2 H 2 d v tnh H% theo Cl2 H % 66, 67%
0,56
Cu 13:
p n : D
Hng dn : nNaNO3 0, 2 mol; nCu 0,1 mol
3Cu 8H 2 NO3 3Cu 2 2 NO 4 H 2O

Ban u 0,1 0,5 0,2
4 1
Phn ng 0,1
15 15
VNO = 1,49l
Cu 14:
p n : B
Hng dn : C5 H8O2 2
Cc este mch h c cng thc phn t l C5H8O2 khi b x phng ha to ra mt anhit (Khng tnh
ng phn lp th) l :
HCOOCH=CHCH2CH3 , CH3COOCH=CHCH3, CH3CH2COOCH=CH2, HCOOCH=C(CH3)CH3
Cu 15:
p n : A
Hng dn : CO2 2 NH3 NH 2 2 CO2 H 2O
NH2 2 CO2 H2O NH4 2 CO3

NH4 2 CO3 NH4 HCO3 NH3
NH 4 HCO3 NH3 CO2 H 2O
Cu 16:
p n : D
Hng dn :
Gi s gc glyxin v alanin trong chui peptit ln lt l a, b
Ta c : 345 75a 89b 4.18 75a 89b 72 v a b 5
a=2 v b=3
Cu 17: p n : B
Cu 18:
p n : C
Hng dn : C8 H10O 4
Cu 19:
p n : D
Hng dn : A loi amoni clorua, B v C loi anilin.
Cu 20:

p n : D
Hng dn : Cc cp cht xy ra phn ng iu kin thng:
Cu v dung dch FeCl3; H2S v dung dch CuSO4 dung dch AgNO3 v dung dch FeCl3
Cu 21:
p n : A
Hng dn :
- Saccaroz , glucoz : dung dch mu xanh lam ; anhit axetic : kt ta gch nhn ra anhit
axetic
- un nng cc dung dch mu xanh lam, l no cho kt ta gch khi un nng l glucoz
Cu 22:
p n : C
Hng dn : nman 3, 42 : 342 0,1 mol
Mantoz 2Glucoz , nn
nGlu 0,1.2.0,8 0,16 mol
nAg 2nGlu 2nman d 0,36 mol m Ag 38,88 gam
Cu 23:
p n : A
Hng dn : Gi axit hu c X n chc, mch h l RCOOH
Ta c 2RCOOH + CaCO3 (RCOO)2Ca + H2O + CO2
5,76 1 7, 28
.
R 45 2 40 R 44 .2
Cu 24: p n : C
Cu 25:
p n :D
Hng dn : MX = 48, nn cng thc chung ca X l C C3,5H6
Cu 26:
p n : B
Hng dn :
Cc ankin ng vi cng thc phn t C5H8:
CH C CH2 CH2 CH3, CH C CH(CH3) CH3, CH3 C C CH2 CH3
Cu 27:
p n : D
Hng dn :
p dng phng php bo ton e, ta c :
3nAl 8nN2O 3nNO 8.0, 015 3.0, 01 0,15 n Al 0, 05 mol m Al 1,35 gam
Cu 28:
p n :D

Hng dn : ClCH 2CH2CH2CH3 , ClCH2CH CH3 CH3
Cu 29:
p n : C
Hng dn :
- Bezen khng lm mt mu nc Br2 ngay c khi un nng
- Stiren lm mt mu nc Br2 ngay c nhit thng
- Anilin to kt ta trng vi Br2
Cu 30:
p n : B
Hng dn: Amin khng tc dung vi NaOH
Cu 31:
p n : A
Hng dn : n nAgCl 0,15 mol nY 0,15 M Y 92,5
CTPT ca Y l C4H9Cl
Cu 32:
p n : B
Hng dn : nCO2 0,04 mol; nCaOH 0,03 mol
2
Gi s mol CaCO3 l a, s mol Ca(HCO3)2 l b, ta c:
nOH nHCO3 2co32

2a 2b 0, 06 a 0, 02

nCO2 nHCO nCO2 a 2b 0, 04 b 0, 01
3 3
Vy khi lng kt ta l 2g
Cu 33:
p n : C
Hng dn : Cc phn ng thuc loi phn ng oxi ha - kh l a, d, e, f,g.
Cu 34:
p n : C
Hng dn : 1, 3,4,5.
Cu 35:
p n : C
Hng dn : nCO2 nH 2O 0, 2 mol; mO2 phan ng mCO2 mH 2O mX 8 gam nO2 phan ng 0, 25
nO X 0,1 mol Trong X, nC : nH : nO 2 : 4 :1 hay X l C4H8O (metyl propionat)
Cu 36:
p n : A
Hng dn : Trong phn t benzen, cc nguyn t C trng thi lai ho sp2 lin kt vi nhau v vi cc
nguyn t H thnh mt phng phn t benzen.

Cu 37: p n : D
Cu 38:
p n : B
Hng dn : nCH3COOH 0, 2 mol; nC2 H5OH 0,3 mol, nCH 3COOC2 H 5 0,125 mol
0,125
V nCH3COOH nC2 H5OH nn ta tnh H% theo nCH3COOH H % 62,5%
0, 2
Cu 39:
p n : C
Hng dn : nAg 0, 03 mol nCHO 0, 015
0,94
M anehit 62, 67 CTPT ca hai anhit l C3H6O v C4H8O
0, 015
Cu 40: p n : B
1A 2B 3C 4D 5D 6A 7B 8A 9A 10C
11B 12D 13D 14B 15A 16D 17B 18C 19D 20D
21A 22C 23A 24C 25D 26B 27D 28D 29C 30B
31A 32B 33C 34C 35C 36A 37D 38B 39C 40B

THPT YN LC 2 Thi gian lm bi: 50 pht, khng k thi gian pht

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: E l este mch khng nhnh ch cha C, H, O, khng cha nhm chc no khc. un nng mt
lng E vi 150ml dung dch NaOH 1M n kt thc phn ng. trung ha dung dch c cn 60ml
dung dch HCl 0,5M. C cn dung dch sau khi trung ha c 11,475 gam hn hp hai mui khan v
5,52 gam hn hp 2 ancol n chc. Cng thc cu to ca este l
A. C2H5 COO C2H5 B. CH3CH2CH2 OOC CH2CH2COOCH3 C.
HCOOCH3 v CH3COOC2 H5 D. CH3 CH2 OOC CH2COOCH3
Cu 2: t chy m gam hn hp gm 2 amin no n chc mch h thu c 28,6 gam CO2 v 18,45
gam H 2O . m c gi tr l:
A. 12, 65gam B. 11, 95gam C. 13gam D. 13,35gam
Cu 3: Cht hu c X mch h c dng H2 N R COOR ' (R, Rl cc gc hidrocacbon), thnh phn
% v khi lng ca Nito trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH,
ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c andehit Y (ancol ch b oxi ha
thnh andehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH 3 thu c 12,96
gam Ag kt ta. Gi tr ca m l:
A. 5,34 B. 2,67 C. 3,56 D. 4,45
Cu 4 : Cho cht hu c X c cng thc phn t C2H8O3 N2 tc dng vi dung dch NaOH, thu c
cht hu co n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l
A. 68 B. 46 C. 45 D. 85
Cu 5: Tnh th tch dung dch HNO3 96%(D 1,52g / ml) cn dng tc dng vi lng d xenlulozo
to 29,7 kg xenlulozo trinitrat.
A. 15,00 lt B. 1,439 lt C. 24,39 lt D. 12,952 lt
Cu 6: Tripeptit l hp cht
A. m mi phn t c 3 lin kt peptit
B. c lin kt peptit m phn t c 3 gc amino axit ging nhau
C. c lin kt peptit m phn t c 3 gc amino axit khc nhau
D. c 2 lin kt peptit m phn t c 3 gc -amino axit
Cu 7: Loi du no sau y khng phi l este ca axit bo v glixerol?
A. Du luyn B. Du lc (u phng) C. Du da D. Du vng (m)
Cu 8: Phn tch este X ngi ta thu c kt qu: %C 40 v %H 6, 66 . Este X l
A. metyl axetat B. etyl propionat C. metyl fomat D. metyl acrylat
Cu 9: Nguyn nhn Amin c tnh bazo l
A. C kh nng nhng proton
B. Phn ng c vi dung dch axit
C. Trn N cn mt i electron t do c kh nng nhn H
D. Xut pht t amoniac
Cu 10: Tn gi amin no sau y l khng ng?
A. C6 H5 NH 2 alanin B. CH3 CH2 CH2 NH2 n propylamin C.
CH3CH(CH3 ) NH2 isopropyla min D. CH3 NH CH3 dimetylamin

Cu 11: t chy ht 1,62 gam hn hp hai este mch h, n chc, no ng ng k tip cn va
1,904 lt Oxi (ktc). CTPT hai este l
A. C4 H8O2 v C5H10O2 B. C2 H4O2 v C3H6O2
C. C4H8O2 v C3H6O2 D. C2 H4O2 v C5H10O2
Cu 12: Cp cht no sau y khng phi l ng phn ca nhau?
A. Tinh bt v xenlulozo B. Fructozo v glucozo
C. Metyl fomat v axit axetic D. Mantozo v saccarozo
Cu 13: Mt dung dch c tnh cht sau:
-Tc dng c vi dung dch AgNO3 / NH3 v Cu(OH)2 khi un nng
-Ha tan c Cu(OH)2 to ra dung dch mu xanh lam
-B thy phn nh axit hoc enzim
Dung dch l:
A. Glucozo B. Xenlulozo C. Mantozo D. Saccarozo
Cu 14: Khi ni v peptit v protein, pht biu no sau y l sai?
A. Protein c phn ng mu biure vi Cu(OH)2
B. Thy phn hon ton protein n gin thu c cc -amino axit
C. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit
D. Tt c cc protein u tan trong nc to thnh dung dch keo
Cu 15: S ng phn ca hp cht este n chc c CTPT C4 H8O2 tc dng vi dung dch
AgNO3 / NH3 sinh ra Ag l
A. 4 B. 1 C. 2 D. 3
Cu 16: Hp cht hu c X c cng thc C2 H8 N 2O4 . Khi cho 12,4 gam X tc dng vi 200ml dung
dch NaOH 1,5M thu c 4,48 lt (ktc) kh Y lm xanh qu tm m. C cn dung dch sau phn ng thu
c m gam cht rn khan. Gi tr ca m l
A. 13,4 B. 17,4 C. 17,2 D. 16,2
Cu 17: Cho dy chuyn ha:
1500o C H O H O C H
CH 4 X 2 Y
2 Z
2 T
2 2 M
Cng thc cu to ca M l
A. CH3COOCH3 B. CH2 CHCOOCH3
C. CH3COOC2 H5 D. CH3COOCH3 CH2
Cu 18: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l
A. Cu(OH)2 B. Dung dch HCl C. Dung dch NaOH D. Dung dch NaCl
Ni
Cu 19: AxitX 2H 2 axitY . Tn gi ca axit X v Y ln lt:
A. Axit oleic v axit stearic B. Axit linoleic v axit stearic
C. Axit panmitic; axit oleic D. Axit linoleic v axit oleic
Cu 20: Pht biu no sau y v tnh cht vt l ca amin l khng ng?
A. tan trong nc ca amin gim dn khi s nguyn t cc bon trong phn t tng
B. Anilin l cht lng kh tan trong nc, mu en
C. Cc amin kh c mi tng t amoniac, c
D. Metyl amin, imetyl amin, etyl amin l cht kh, d tan trong nc
Cu 21 : Ly 14,6 g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M.
Th tch dung dch HCl tham gia phn ng:
A. 0,23 lt B. 0,2 lt C. 0,4 lt D. 0,1 lt
Cu 22: Thy phn 1kg khoai (cha 20% tinh bt) trong mi trng axit. Nu hiu sut phn ng 75%
th lng glucozo thu c l:
A. 150g B. 166,6g C. 120g D. 200g
Cu 23: Cht hu c X c cng thc phn t C4 H6O4 tc dng vi dung dch NaOH (ung nng) theo
phng trnh phn ng:
C4H6O4 2NaOH 2Z Y

oxi ha ht a mol Y th cn va 2a mol CuO (ung nng), sau phn ng to thnh a mol cht T
(bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l:
A. 118 vC B. 44 vC C. 58 vC D. 82 vC
Cu 24: Hn hp X gm 3 peptit A,B,C u mch h c tng khi lng l m v c t l s mol l
n A : n B : n C 2 : 3: 5 . Thy phn hon ton X thu c 60 gam Glyxin; 80,1 gam Alanin v 117 gam
Valin. Bit s lin kt peptit trong C, B, A theo th t to nn 1 cp s cng c tng l 6. Gi tr ca m l:
A. 256,2 B. 262,5 C. 252,2 D. 226,5
Cu 25: Glucozo khng c tnh cht no di y?
A. Tnh cht ca poliol B. Ln men to anlcol etylic
C. Tnh cht ca nhm andehit D. Tham gia phn ng thy phn
Cu 26: Khi thy phn trilinolein trong mi trng axit ta thu c sn phm l
A. C17 H31COOH v glixerol B. C15H31COOH v glixerol
C. C17 H35COONa v glixerol D. C15H31COONa v etanol
Cu 27: Cacbonhidrat Z tham gia chuyn ha:
Cu(OH) /OH to
Z 2 dung dch xanh lam kt ta gch
Vy Z khng th l cht no trong cc cht cho di y?
A. Saccarozo B. Glucozo C. Mantozo D. Fructozo
Cu 28 : Thy phn 51,3 gam mantozo trong mi trng axit vi hiu sut phn ng t 80% thu c
hn hp X. Trung ha X bng NaOH thu c dung dch Y. ChoY tc dng ht vi lng d dung dch
AgNO3 trong NH 3 un nng, sinh ra m gam Ag. Gi tr ca m l:
A. 58,82 B. 58,32 C. 32,40 D. 51,84
Cu 29: Cho dung dch cha cc cht sau:
X1 : C6H5 NH2 ; X2 : CH3 NH2 ; X3 : NH 2 CH 2 COOH; .
X4 : HOOC CH2 CH2 CHNH2COOH; X5 : H 2 N CH 2 CH 2 CH 2 CHNH 2COOH
Dung dch no lm qu tm ha xanh?
A. X 2 , X3 , X 4 B. X2 , X5 C. X1, X3 , X5 D. X1, X 2 , X5
Cu 30: Cho 23 gam C2 H5OH tc dng vi 24 gam CH3COOH (xc tc H 2SO 4 ) vi hiu sut phn
ng 60%. Khi lng este thu c l:
A. 23,76 gam B. 26,4 gam C. 21,12 gam D. 22 gam
Cu 31): Cht X c cng thc phn t C3H6O2 , l este ca axit axetic. Cng thc cu to thu gn ca X
l:
A. HCOOC2H5 B. HO C2 H4 CHO C. C2 H5COOH D. CH3COOCH3
Cu 32: Tnh cht ca lipit c lit k nh sau:
(1) Cht lng
(2) Cht rn
(3) Nh hn nc
(4) Tan trong nc
(5) Tan trong xng
(6) D b thy phn trong mi trng kim hoc axit
(7) Tc dng vi kim loi kim gii phng H 2
(8) D cng H 2 vo gc axit

S tnh cht ng vi mi loi lipit l
A. 4 B. 3 C. 1 D. 2
Cu 33: Nh dung dch iot ln ming chui xanh thy xut hin mu xanh tm l do chui xanh c cha
A. Glucozo B. Saccarozo C. Tinh bt D. Xenlulozo
Cu 34 Cht no sau y c phn ng trng gng?
A. Tinh bt B. Saccarozo C. Xenlulozo D. Glucozo
Cu 35 : t chy hon ton 14,8 gam este X thu c 13,44 lt CO2 (ktc) v 10,8 gam H 2O . CTPT
ca X l:
A. C2 H 4O2 B. C4 H8O2 C. C5H10O2 D. C3H6O2
Cu 36: Este etyl fomat c cng thc l
A. HCOOC2H5 B. HCOOCH3 C. HCOOCH CH2 D. CH3COOCH3
Cu 37: Amino axit no sau y c hai nhm amino?
A. Lysin B. Valin C. Axit glutamic D. Alanin
Cu 38: Cht A c phn trm cc nguyn t C, H, N, O ln lt l 40, 45%;7,86%;15, 73%; cn li l O.
Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd
HCl, c ngun gc t thin nhin. Cng thc cu to ca A l
A. H2 N (CH2 )3 COOH B. H2 N CH2 COOH
C. CH3 CH(NH2 ) COOH D. H2 N (CH2 )2 COOH
Cu 39: Thy phn hon ton 0,1 mol este X cn va 0,2 mol NaOH thu c 15 gam mui natri ca
2 axit cacboxylic v etylen glicol. Pht biu no di y khng ng khi ni v X:
A. A l este no, khng c phn ng trng bc B. X l este no, hai chc
C. X c CTPT l C5H8O4 D. X tham gia phn ng trng bc
Cu 40: Cho cc cht: X : Glucozo; Y : Saccarozo; Z : Tinh bt;
T : Glixerin; H : Xenlulozo. Nhng cht b thy phn l:
A. Y, Z, H B. X, Y, Z C. X, Z. H D. Y, T, H

p n
1-B 6-D 11-C 16-B 21-B 26-A 31-D 36-A
2-D 7-A 12-A 17-D 22-B 27-A 32-B 37-A
3-B 8-C 13-C 18-A 23-C 28-B 33-C 38-C
4-C 9-C 14-D 19-B 24-D 29-B 34-D 39-A
5-D 10-A 15-C 20-B 25-D 30-C 35-D 40-A
HNG DN GII CHI TIT

Cu 1:
Phng php: Bo ton khi lng, xc nh dng cu to ca este da vo sn phm phn ng.
B1: Xc nh dng cu to ca E
V E + NaOH to 2 alcol nn s nhm COO c t nht l 2
M E khng phn nhnh E l este 2 chc c dng R1OOC R COOR 2
B2: Tm ME CTPT
Xt c qu trinnhf E NaOH HCl mui khan + ancol n chc H2O
n NaCl n HCl 0,03(mol) n NaOH(puE) 0,15 0,03 0,12(mol) n E n R(COONa)2 0,06(mol)
n H2O n HCl 0,03(mol)
Bo ton khi lng: mE mNaOH mHCl m muoi khan mancol mH2O
mE 10, 44g ME 174g
E c CTPT l: C8H14O4
B3: Tm CTPT mui R(COONa)2
Hn hp mui khan gm 0,06 mol R(COONa)2 v 0,03 mol NaCl
0, 06.(R 134) 0, 03.58,5 11, 475
R 28(C2 H 4)
Mui : C2H4 (COONa)2
B4: Tm CTPT ca E
T CTPT ca mui hu c E c dng C2H4 (COONa)2 C4H10
V to hn hp 2 ancol nn ch c 1 cng thc tha mn l: C3H7OOCC2H4COOCH3
p n B
Cu 2
Phng php: Bo ton khi lng; tng quan v s mol cc sn phm phn ng.
B1: Tm s mol N2 v O2
Amin n chc no c dng: Cn H2n 3
PT : Cn H2n 3 N O2 nCO2 (n 1,5)H2O 0,5N2
n H2O nCO2 3n N2 n N2 0,125mol
Bo ton O: nO2 1/ 2(2n CO2 n H2O ) 1,1625mol
B2: Tm m
Bo ton khi lng: m mCO2 mH2O mN2 mO2
m 13,35g
p n D
Cu 3
B1: Xc nh CTPT ca X
%m N 15, 73% MX 89g X l H2 N CH2COOCH3
B2: Xc nh cht Y v tnh m
Xt c qu trnh: H2 N CH2COOCH3 CH3OH HCHO(Y)
Li c: 1 mol HCHO to 4 mol Ag

n Ag 4n HCHO 4n X n X 0, 03mol
m 2, 67g
p n B
Cu 4
X + NaOH to 1 cht hu c n chc v cc cht v c
X l C2H5 NH3 NO3
Vy cht hu c Y l C2H5 NH2 c MY = 45 dvC
p n C
Cu 5:
C6H7O2 (OH)3 n 3nHNO3 C6H7O2 (NO3 )3 n 3nH2O
3n (mol) 297n (g)
300 mol 29,7 kg = 29700 g
m HNO3 18900g mddHNO3 19687,5g
VddHNO3 12952ml12,952lit
p n D
Cu 6: p n D
Cu 7:
Du luyn l hidrocacbon
p n A
Cu 8:
Phng php: Tm CT da vo t l mol cc nguyn t c trong hp cht.
B1: Tm CTTQ ca este:
%mC : %m H : %mO 40 : 6, 66 : 53,34
n C : n H : n O 3,33: 6, 66 : 3,33 1: 2 :1
X c CTQT l (CH 2O)n
B2: Bin lun c CTPT ph hp ca este
Nu este n chc n 2 C2H4O2
Ch c 1 este duy nht l HCOOCH3 metyl fomat
p n C
Cu 9: p n C
Cu 10:
C6 H5 NH 2 c tn l anilin
p n A
Cu 11
Phng php: Bo ton khi lng; Bo ton nguyn t; tng quan v s mol sn phm trong phn ng
chy ca este no n chc mch h.
B1: Xc nh s mol cc cht sn phm (CO2 , H 2O)
C: mCO2 mH2O meste mO2 1,62 32.0,085 4,34g
V este no n chc mch h nCO2 n H2O 0,07mol
B2: Xc nh Mtrung bnh ca cc este
Bo ton O: nO(este) 2nCO2 n H2O 2nO2 0,04mol
neste 1/ 2nO(este) 0,02mol
Meste trung bnh =81
2 este lin tip tha mn l C2H 4O2 (M 60) v C3H6O2 (M 74)
p n C
Cu 12:
ng phaann l cc cht c cng M nhng cng thc cu to khc nhau

Tinh bt v xenlulozo khng c cng M
p n A
Cu 13:
Mantozo c nhm CHO ging glucozo, c nhiu nhm OH k nhau, c to thnh t 2 phn t glucozo
p n C
Cu 14:
Protein hnh si hon ton khng tan trong nc, cn protein hnh cu th tan trong nc to dung dch keo.
p n D
Cu 15:
Este phn ng c vi AgNO3 NH3 th cn phn c nhm HCOO-
Cc CTPT ph hp:
HCOO CH 2CH 2CH3
HCOO CH(CH3 )2
p n C
Cu 16:
B1: Xc nh cng thc cu to ca X v kh Y
n X 0,1mol
n NaOH 0,3mol n Y 0, 2mol
X + NaOH Kh Y lm xanh qu tm m
X l (COONH4 )2
Vy kh Y l NH 3
B2: Xc nh cc cht trong cht rn khan v tnh m
Cht rn gm: 01 mol 0,1mol(COONa)2 v 0,1 mol NaOH
mrn = 17,4 g
p n B
Cu 17:
S hon chnh:
CH4 C2H2 CH3CHO C2H5OH CH3COOH CH3COOH CH2
p n D
Cu 18:
Cc tripeptit tr ln mi c phn ng biure vi Cu OH 2 lm xut hin mu tm c trng
p n A
Cu 19:
Axit linoleic: (C17 H31COO)3 C3H5
Axit stearic: (C17 H35COO)3 C3H5
p n B
Cu 20:
Anilin kh tan trong nc, khng mu
p n B
Cu 21:
Dipeptit l: Gly-Ala hoc Ala-Gly
n peptit 0,1mol
n HCl 2n peptit 0, 2mol
VddHCl 0, 2lit
p n B
Cu 22:
Phng php: Bi tp hiu sut: Vi ch sn phm: mthc t = ml thuyt . H%
Mtinh bt = 1000.20% = 200g
PT: (C6H10O5 )n nH2O nC6H12O6
(g) 162n 180n
(g) 200 222,2
V hiu sut phn ng l 75% mglucozo thc 222, 2.75% 166, 6g
p n B
Cu 23:
X + NaOH to 2Z v Y (u l 2 cht hu co) X l este
Oxi ha 1 mol Y cn 2 mol CuO Y c 2 nhm OH Y c t nht 2 cacbon
Vy X l : (HCOO)2 C2H4
Y : C2H4 (OH)2 T : (CHO)2 c MT 58g
p n C
Cu 24:
Phng php: Quy i; bo ton khi lng
B1: Quy i cc amino axit v thnh cc peptit di:
A : 2a aA A aH 2O

B : 3a aB B B 2aH 2O a.X n 9aH 2O
C : 5a aC C C C C 4aH 2O
(V A A B B B A A B B B H 2O...) *
(X l amino axit mt xch trung bnh).
B2: Tnh s mol peptit tng hp da trn s mol cc amino axit
C: nGly 0,8 mol; n Ala 0,9 mol; n Val 1,0 mol
V s lin kt peptit trong C, B, A theo th t to nn 1 cp s cng c tng l 6
s lin kt peptit trong C; B; A ln lt l 1; 2; 3
V trn ta quy CT peptit l A A B B B C C C C C(X n )
S amino axit 2.(3 1) 3.(2 1) 5.(1 1) 27
Li c: n X 2,7mol n Xn 0,1mol
B3: Tm m
Nu c phn ng: A A B B B C C C C C 26H2O amino axit **
m mXn mH2O(*) (mamino axit mH2O(*) 257,1 26.0,1.18 9.0,1.18
m 226,5g
p n D
Cu 25:
Glucozo l monosaccarit nn khng c phn ng thy phn.
p n D
Cu 26: p n A
Cu 27:
Saccarozo khng phn ng vi Cu(OH)2 / OH
p n A
Cu 28:
1 mol mantozo thy phn to 2 mol glucozo
V hiu sut phn ng ch l 80%
nglucozo 0, 24mol;n mantozo 0,3mol
Khi phn ng vi AgNO3 / NH3 :
1 mol Glucozo 2 mol Ag
1 mol Mantozo 2 mol Ag
n Ag 2n glucozo 2n mantozo 0,54mol
m Ag 58,32g
p n B
Cu 29:

Cc cht c s nhm NH 2 > s nhm COOH th s phn hy trong nc to mi trng bazo.
p n B
Cu 30:
Phng php: Bi tp tnh hiu sut phn ng (nguyn tc: tnh theo cht tham gia thiu)
CH3COOH C2H5OH CH3COOC2H5 H2O
nC2H5OH 0,5mol nCH3COOH 0, 4mol v t l mol cc cht phn ng l 1:1
Tnh hiu sut theo cht c t s mol hn
n este 0, 4.60% 0, 24mol
meste 21,12g
p n C
Cu 31: p n D
Cu 32:
Cc tnh cht ng vi mi loi lipit l: (3); (5); (6)
p n B
Cu 33:
Nh dung dch Iod vo tinh bt s xut hin mu xanh tm
p n C
Cu 34: p n D
Cu 35:
Phng php: Bo ton khi lng; bo ton nguyn t; Tm CTPT da vo lng cc nguyn t c trong
phn t.
B1: Tm s mol O 2
Bo ton khi lng:
m X mO2 mCO2 m H 2O
n O2 0, 7mol
B2: Xc nh s mol O trong phn t X
Bo ton nguyn t: nO(X) 2nCO2 n H2O 2nO2 0, 4mol
B3: Xc nh CTPT ca X:
C n C : n H : n O 0, 6 :1, 2 : 0, 4 3: 6 : 2
X c CTTQ l (C3H6O2 )n
V: s H 2. S C + 2 6n 4n 2 n 1 n 1
Vy X l C3H6O2
p n D
Cu 36: p n A
Cu 37: p n A
Cu 38:Phng php: Tm CTPT da vo t l mol cc nguyn t v M
B1: Xc nh CTTQ:
%n C : %n H : %n O : %n N 40, 45 : 7,86 : 35,96 :15, 73
n C : n H : n O : n CN 3,37 : 7,86 : 2, 25 :1,12 3: 7 : 2 :1
CTQT ca A l: (C3H7O2 N)n
B2: Xc nh CTPT ca A:
MA 89n 100g n 1,12 n 1
Vy A l C3H7O2 N
B3: Xc nh CTCT ca A
A va tc dng vi NaOH v HCl nn A l amino axit
M A c ngun gc t thin nhin A l -amino axit
Vy CTCT ph hp: CH3 CH(NH2 ) COOH
p n C
Cu 39:B1: Xc nh dng cu to ca X:

X + NaOH 2 mui hu c + C2H4 (OH)2
X c CT: (R1COO)(R 2COO)C2H4
B2: Xc nh CTCT ca X
n R1COONa n R 2COONa 0,1mol
m muoi 0,1.(R1 67) 0,1.(R 2 67) 15
R1 R 2 16
R1 1; R 2 15
X l : HCOOC2H4OOCH3C
X c kh nng phn ng trng bc nh gc HCOO-
p n A
Cu 40: p n A

S GD T TP.HCM THI TH LN 1 THPT QUC GIA NM 2017
THPT VNH VIN Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Tn hp cht c cng thc cu to (C17H33COO)3C3H5 l:

A. triolein B. tristearin C. trilinolein D. tripanmitin
Cu 2: Thy phn 0,01 mol este X cn 0,03 mol NaOH thu c 0,92g mt ancol, 0,01 mol
CH3COONa; 0,02 mol HCOONa. CTPT ca este l:
Cu 3: Cho cc cht: phenol; axit axetic; etyl axetat; ancol etylic; tripanmitin. S cht phn ng vi
NaOH l:
A. 4 B. 3 C. 2 D. 5
Cu 4: Phng php chuyn ha triglixerit lng thnh triglixerit rn (to b nhn to) l:
A. H nhit tht nhanh ha rn triglixerit
B. Thy phn cht bo trong mi trng axit
C. Thy phn cht bo trong mi trng kim
D. Hidro ha trglixerit lng thnh triglixerit rn
Cu 5: S cht c CTPT C4H8O2 c phn ng vi NaOH l:
A. 5 B. 3 C. 6 D. 4
Cu 6: Thy phn xenlulozo, sn phm thu c l:
A. mantozo B. glucozo C. saccarozo D. fructozo
Cu 7: Amin c cu to CH3CH2CHNH2CH3 l amin:
A. bc 3 B. bc 2 C. bc 1 D. bc 4
Cu 8: Cho cc cht: CH3NH2 (1); NH3 (2); C6H5NH2 (3); (CH3)2NH (4); (C6H5)2NH (5). Kt qu so
snh lc bazo gia cc cht hp l l:
A. (5)<(3)<(1)<(4)<(2) B. (5)<(3)<(2)<(1)<(4)
C. (2)<(3)<(5)<(1)<(4) D. (1)<(2)<(3)<(4)<(5)
Cu 9: Este C4H8O2 tc dng vi NaOH to ancol metylic. Este l:
A. HCOOC3H7 B. CH3COOC2H5 C. C2H5COOCH3 D. HCOOC3H5
Cu 10: ra mi tanh ca c m (mi tanh ca amin), ngi ta c th dng:
A. H2SO4 B. HCl C. CH3COOH D. HNO3
Cu 11: C4H8O2 c s ng phn este l:
A. 5 B. 7 C. 6 D. 4
Cu 12: Hp cht CH3CH2COOCH3 c tn l:
A. etyl axetat B. propyl axetat C. metyl axetat D. metyl propionat
Cu 13: Cho cc tnh cht sau: (1) tan d dng trong nc lnh; (2) thy phn trong dung dch axit un
nng; (3) tc dng vi Iot to xanh tm. Tinh bt c cc tnh cht sau:
A. (1), (3) B. (2), (3) C. (1), (2), (3) D. (1), (2)
1/ glucozo v fructozo u tc dng vi Cu(OH)2 to dung dch xanh lam
2/ saccarozo v antozo thy phn u cho 2 phn t mnaccarit
3/ tinh bt v xenlulozo c CTPT dng (C6H10O5)n v l ng phn ca nhau
4/ cht bo cn c gi l triglixerit
5/ gc hidrocacbon ca axit bo trong triglixerit c ngun gc t thc vt l gc khng no
S pht biu ng l:
A. 2 B. 5 C. 4 D. 3
Cu 15: X phng ha tristearin trong dung dch NaOH thu c C3H5(OH)3 v:
A. C17H31COONa B. C17H35COONa C. C15H31COONa D. C17H33COONa

Cu 16: Thc hin ln men ancol t glucozo (H = 80%) c etanol v kh CO2. Dn kh thu c vo
dung dch nc vi trong d thu c 40g kt ta. Lng glucozo ban u l:
A. 45g B. 36g C. 28,8g D. 43,2g
Cu 17: Vinyl fomat c cng thc phn t l:
Cu 18: S nhm OH trong phn t glucozo l:
A. 5 B. 6 C. 3 D. 4
Cu 19: Cho cc cht sau: etylamin; anilin; dimetylamin; trimetylamin. S cht amin bc 2 l
A. 4 B. 2 C. 1 D. 3
Cu 20: Saccarozo khng tham gia phn ng:
A. Thy phn vi xc tc enzym B. Thy phn nh xc tc axit
C. vi Cu(OH)2 to dung dch xanh lam D. Trng bc
Cu 21: Tinh bt c to thnh cy xanh nh phn ng
A. Thy phn B. Quang hp C. Ha hp D. Phn hy
Cu 22: Saccarozo v glucozo u tham gia:
A. vi Cu(OH)2 to dung dch xanh lam B. Thy phn trong mi trng axit
C. vi dung dch NaCl D. vi AgNO3 trong NH3 un nng
Cu 23: Cho cc cht: glucozo; saccarozo; tinh bt; metyl fomat; xenlulozo; fructozo. S cht tham gia
phn ng thy phn trong mi trng axit to sn phm tc dng vi Cu(OH)2 v trng bc l:
A. 2 B. 4 C. 3 D. 5
Cu 24: Glucozo khng tham gia v phn ng:
A. thy phn B. vi Cu(OH)2 to dung dch xanh lam
C. ln men ancol D. trng bc
Cu 25: ng vi CTPT C3H9N s c s ng phn l:
A. 5 B. 4 C. 2 D. 3
Cu 26: Cho cc tnh cht sau: (1) dng si; (2) tan trong nc; (3) tan trong dung dch svayde; (4) tc
dng vi dung dch HNO3/ H2SO4; (5) trng bc; (6) thy phn. Xenlulozo c cc tnh cht sau:
A. (1),(3),(4),(5) B. (1),(3),(4),(6) C. (2),(3),(4),(6) D. (1),(2),(3),(6)
Cu 27: este no n ch mch h c cng thc chung l:
A. CnH2nO2 B. CnH2n-2O2 C. CnH2n+nO2 D. CnH2nO
Cu 28: X phng ha hon ton 4,4g este C4H8O2 bng dung dch NaOH thu c 4,1h mui. Este l:
A. C2H5COOCH3 B. CH3COOC2H5 C. HCOOCH2CH2CH3 D. HCOOCH(CH3)2
Cu 29: CO2 X Y Z (+enzym) CH3COOH. X, Y, Z ph hp:
A. tinh bt, fructozo, etanol B. tinh bt, glucozo, etanal
C. xenlulozo, glucozo, andehit axetic D. tinh bt, glucozo, etanol
Cu 30: Cht X cha (C,H,N). Bit % khi lng N trong X l 45,16%. Khi em X tc dng vi HCl ch
to mui c dng RNH3Cl. X l:
A. C3H9N B. C2H7N C. CH5N D. C3H7N
Cu 31: Amin c cu to CH3CH2NHCH3 c tn l:
A. etanmetanamin B. propanamin C. etylmetylamin D. propylamin
Cu 32: X phng ha hon ton mt lng triglixerit cn V ml dung dch NaOH 1M s thu c 9,2g
glixerol. Gi tr ca V l:
A. 100 B. 150 C. 200 D. 300
Cu 33: Cht phn ng vi dung dch FeCl3 to kt ta l:
A. CH3OH B. CH3COOH C. CH3NH2 D. CH3COOCH3
Cu 34: So snh nhit si gia cc cht, trng hp no sau y hp l:
A. C3H7OH < C2H5COOH < CH3COOCH3
B. C2H5COOH < C3H7OH < CH3COOCH3
C. CH3COOCH3 < C2H5COOH < C3H7OH
D. CH3COOCH3 < C3H7OH < C2H5COOH
Cu 35: t ht 2 amin n no bc 1 ng ng k tip thu c nCO2 : nH2O = 1 : 2.
CTPT ca 2 amin l:
A. CH3NH2, C2H5NH2 B. C2H5NH2, C3H7NH2
C. C4H9NH2, C5H11NH2 D. C2H7NH2, C4H9NH2

Cu 36: X phng ha hon ton 11,1g hn hp 2 este HCOOC2H5 v CH3COOCH3 bng dung dch
NaOH 1M. Th tch dung dch NaOH ti thiu l:
A. 200 ml B. 150 ml C. 100 ml D. 300 ml
Cu 37: Dy cc cht u lm qu tm m ha xanh l:
A. natri hidroxit, amoni clorua, metylamin
B. amoniac, natri hidroxit, anilin
C. ammoniac, metylamin, anilin
D. metylamin, amoniac, natri axetat
Cu 38: Glucozo cn c gi l:
A. ng nho B. ng mt ong C. ng mch nha D. ng ma
Cu 39: t chy hon ton hn hp X (gm CH3COOC2H3; C2H3COOCH3 v (CH3COO)3C3H5 ) cn
17,808 l O2 (ktc) thu dc 30,36g CO2 v 10, 26g H2O. Lng X trn phn ng ti a vi s mol
NaOH l:
A. 0,18 B. 0,16 C. 0,12 D. 0,2
Cu 40: em 18g mt amin n no A trung ha vi dung dch HCl 2M thu c 32,6g mui. CTPT
ca A v th tch dung dch axit cn l:
A. C3H9N v 200 ml B. CH5N v 200 ml C. C2H7N v 100 ml D. C2H7N v 200 ml
p n
1-A 6-B 11-D 16-A 21-B 26-B 31-C 36-N
2-C 7-C 12-D 17-D 22-A 27-A 32-D 37-D
3-A 8-B 13-B 18-A 23-B 28-B 33-C 38-A
4-D 9-C 14-C 19-C 24-A 29-D 34-D 39-A
5-C 10-C 15-B 20-D 25-B 30-C 35-A 40-D
Cu 1. A
Cu 2.
Bo ton khi lng: mX + mNaOH = mmui + mancol
mX = 1,9g
MX = 190g
V: nNaOH = 3neste; sn phm mui ch c ca axit hu c
X l Trieste; nHCOONa = 2nCH3COONa
X c dng: (HCOO)2(CH3COO)R
R = 41 (C3H5)
X l C7H10O6
C
Cu 3.
Cc cht phn ng c vi NaOH l: phenol; axit axetic; etyl axetat; tripanmitin
A
Cu 4. D
Cu 5.
C4H8O2 c (pi + vng) = 1
phn ng vi NaOH th phi l axit hoc este
Cc cng thc tha mn:
+) Axit: CH3CH2CH2COOH; (CH3)2CHCOOH
+) Este: C2H5COOCH3; CH3COOC2H5; HCOOCH2CH2CH3; HCOOCH(CH3)2
C 6 cht tha mn
C
Cu 6. B
Cu 7.
Bc ca amin bng s nhm th gn trc tip vo nguyn t Nito
C
Cu 8.
Cc nhm ht e (C6H5;) lm gim lc bazo
Cc nhm y e (R no;) lm tng lc bazo
Lc bazo: (C6H5)2NH < C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH
B
Cu 9. C
Cu 10.
Mi tanh ca c l do cc amin to nn
Dng cc cht c tnh axit nh trung ha amin v to mui d dng ra tri; ng thi khng gy nh
hng n cht lng tht c
C
Cu 11.
Cc ng phn este:
HCOOCH2CH2CH3; HCOOCH(CH3)2
CH3COOC2H5; C2H5COOCH3
D
Cu 12. D
Cu 13. B
Cu 14.
(3) sai v tinh bt v xenlulozo khng cng phn t khi nn khng th l ng phn ca nhau.
C 4 cu ng
C
Cu 15. B
Cu 16.
C6H12O6 2CO2 + 2C2H5OH
CO2 + Ca(OH)2 CaCO3 + H2O
nCO2 = nCaCO3 = 0,4 mol nglucozo(PT) = 0,2 mol
nglucozo phi dng = 0,2.100/80 = 0,25 mol
mglucozo = 45g
A
Cu 17.
Vinyl fomat: HCOOCH=CH2
D
Cu 18. A
Cu 19.
Cc cht tha mn: dimetylamin (CH3NHCH3)
C
Cu 20.
Saccarozo khng c nhm CHO nn khng c phn ng trng bc
D
Cu 21. B
Cu 22.
C saccarozo v glucozo u c nhiu nhm OH k nhau
A
Cu 23.
Saccarozo Glucozo + Fructozo
Tinh bt glucozo
Metyl fomat (HCOOCH3) HCOOH + CH3OH
Xenlulozo Glucozo
Cc sn phm: glucozo; HCOOH; fructozo u tha mn yu cu bi
B
Cu 24.
Glucozo l monosaccarit nn khng c phn ng thy phn
A
Cu 25.
Cc ng phn:

+) CH3CH2CH2NH2; (CH3)2CHNH2
+) CH3CH2NHCH3
+) N(CH3)3
B
Cu 26. B
Cu 27. A
Cu 28.
X phng ha: RCOOR1 RCOONa
C neste = nmui = 0,05 mol Mmui = 82g
R = 15 (CH3)
este l CH3COOC2H5
B
Cu 29.
S : CO2 Tinh bt glucozo etanol CH3COOH
+) CO2 + H2O (C6H10O5)n [Qung hp]
+) (C6H10O5)n + nH2O nC6H12)6
+) C6H12O6 2 CO2 + 2C2H5OH
+) C2H5OH + O2 CH3COOH + H2O
D
Cu 30.
X + HCl RNH3Cl X l amin n chc bc 1
%mN(X) = 45,16% MX = 31g CH3NH2(CH5N)
=> C
Cu 31. C
Cu 32.
Triglixerit + 3NaOH glixerol + 3RCOONa
nNaOH = 3nglixerol = 0,3 mol
V = 0,3 lt = 300 ml
D
Cu 33.
V CH3NH2 c tnh bazo mnh mi trng OH- to Fe(OH)3
C
Cu 34.
Cc cht c M gn nh nhau th da vo kh nng to lin kt Kidro vi nc tt hn s c nhit si cao
hn v ngc li
Axit C2H5COOH ancol C3H7OH CH3COOCH3
D
Cu 35. Cng thc amin trung bnh: CnH2n+3N
C: nCO2 : nH2O = 1 : 2 nC : nH = 1 : 4 = n : (2n+3)
n = 1,5
2 amin l: CH3NH2 v C2H5NH2
A
Cu 36.
2 este c M bng nhau
Dng tng qut ca phn ng x phng ha l:
RCOOR + NaOH RCOONa + ROH
nNaOH = neste = 0,15 ol
VNaOH = 0,15 lt = 150 ml
B
Cu 37. D
Cu 38. A
Cu 39.
X quy v gm: x mol C4H6O2 v y mol C9H14O6
nO2 = 0,795 mol; nCO2 = 0,69 mol; nH2O = 0,57 mol
Bo ton O: 2x + 6y = 2nCO2 + nH2O 2nO2 = 0,36 mol

nNaOH = nCOO = nO(X) = x + 3y = 0,18 mol
A
Cu 40.
Cng thc ca A:
RN + HCl RNHCl
(R+14) (R+50,5)
18g 32,6g
32,6.(R + 14) = 18.(R + 50,5)
R = 31 (C2H7N)
nHCl = namin = 0,4 mol
VHCl = 0,2 lt = 200 ml
D

S GD T LO CAI THI TH LN 1 THPT QUC GIA NM 2017
THPT VN BN Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: T nilon-6,6 c tnh dai, bn, mm mi, ng mt c dng dt vi may mc, thuc loi:
A. t poliamit. B. t visco. C. t axetat D. t polieste.
Cu 2: ng vi cng thc phn t C4H9NO2 c bao nhiu amino axit l ng phn cu to ca nhau?
A. 3. B. 4. C. 5. D. 6.
Cu 3: Cu no sau y khng ng:
A. Peptit c th b thy phn khng hon ton thnh cc peptit ngn hn.
B. Khi cho Cu(OH)2 vo lng trng trng thy xut hin mu tm c trng.
C. Ha tan lng trng trng vo nc, sau un si, lng trng trng s ng t li.
D. Hp cht NH2 - CH - CH -CONH-CH2COOH thuc loi ipeptit
Cu 4: Tin hnh bn th nghim sau:
- Th nghim (1): Nhng thanh Fe vo dung dch FeCl3;
- Th nghim (2): Nhng thanh Fe vo dung dch CuSO4;
- Th nghim (3): Nhng thanh Cu trong dung dch Fe2(SO4)3 c nh vi git dung dch H2SO4 long;
- Th nghim (4): Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl.
Cc th nghim xut hin n mn in ho l:
A. (3), (4). B. (2), (4). C. (1), (2). D. (2), (3).
Cu 5: Cu hnh electron lp ngoi cng ca kim loi kim th l (n l lp electron ngoi cng):
A. ns2np1. B. ns1. C. ns2np2. D. ns2.
Cu 6: Cho cu hnh electron nguyn t ( trng thi c bn) cc nguyn t nh sau:
(1) 1s22s22p63s23p64s1 (2) 1s22s22p63s23p3 (3) 1s22s22p63s23p1
(4) 1s22s22p3 (5) 1s22s22p63s2 (6) 1s22s22p63s1
Cc cu hnh electron khng phi ca kim loi l:
A. (2), (3), (4). B. (2), (4). C. (1), (2), (3), (4). D. (2), (4), (5), (6).
Cu 7: Cho bt Fe vo dung dch AgNO3 d, sau khi phn ng xy ra hon ton, thu c dung dch
gm cc cht (bit trong dy in ha ca kim loi, cp oxi ha - kh: Fe3 + / Fe2 + ng trc cp: Ag+ /
Ag ):
A. Fe(NO3)2, AgNO3. B. Fe(NO3)2, Fe(NO3)3.
C. Fe(NO3)2,AgNO3,Fe(NO3)3. D.Fe(NO3)3, AgNO3.
Cu 8: Trong cc th nghim sau, th nghim no khi kt thc phn ng thu c kt ta Al(OH)3 ?

A. Cho t t dung dch Ca(OH)2 n d vo dung dch AlCl3.
B. Cho t t dung dch HCl n d vo dung dch Al(OH)3.
C. Cho t t dung dch NH3 n d vo dung dch AlCl3.
D. Cho t t dung dch H2SO4 n d vo dung dch Al(OH)3.
Cu 9: Thc hin cc th nghim sau:
(a) Cho glucoz tc dng vi Cu(OH)2 iu kin thng.
(b) Cho glucoz tc dng vi dung dch AgNO3 trong NH3 d, un nng.
(c) Cho glucoz tc dng vi H, Ni, un nng.
(d) un nng dung dch saccaroz c axit v c lm xc tc.
S th nghim xy ra phn ng oxi ha - kh l:
A. 2. B.1. C. 3. D. 4.
Cu 10: Mt este X c cng thc phn t l C4H8O2. Khi thy phn X trong mi trng axit thu c
axit propionic. Cng thc cu to thu gn ca X l:
A. CH = CHCOOCH3 B. CH3 COOC2 H5. C. CH3 CH2 COOC2 H5. D. CH3 CH2 COOCH3.
Cu 11: Cht no sau y l monosaccarit?
A. Glucoz. B. Tinh bt. C. Xenluloz. D. Saccaroz.
Cu 12: Thy phn 119,7 gam saccaroz trong mi trng axit vi hiu sut 92%, thu c sn phm
cha m gam glucoz. Gi tr ca m l: (cho H = 1, C = 12, O = 16)
A. 57,96. B. 59,76. C. 63,00. D. 68,48.
Cu 13: Cho s chuyn ha:
O2 ,t 0
CO,t0
dung dch FeCl 3 ( T)
Fe X Y dung dch Z Fe(NO3 )3.
Cc cht Y v T c th ln lt l:
A. Fe3 O4 ;NaNO3. B. Fe; Cu(NO3)2. C. Fe; AgNO3. D.Fe2 O3 ;HNO3.
Cu 14: Cc s oxi ho thng gp ca st l:
A. +2, +4. B. +2, +6. C. +2, +3. D. +3, +6.
Cu 15: Phn ng gia dung dch HNO3 long, d v Fe3 O4 to ra kh NO (sn phm kh duy nht).
Tng cc h s (nguyn, ti gin) trong phng trnh ca phn ng oxi - ha kh ny bng:
A. 55. B. 17. C. 13. D. 20.
Cu 16: T m kg qung hematit (cha 75% Fe2 O3 cn li l tp cht khng cha st) sn xut c 140
kg gang cha 96% st. Bit hiu sut ca ton b qu trnh sn xut l 80 %. Gi tr ca m l (cho Fe =
56, O =16):
A. 256. B. 320. C. 512. D. 640.
Cu 17: Pht biu no sau y sai?
A. Ngoi fructoz, trong mt ong cng cha nhiu glucoz.
B. T visco thuc loi t bn tng hp.
C. H2 NCH2COOH l cht rn iu kin thng.

D. Dung dch lysin l qu tm ha hng.
Cu 18: Cho 7,8 gam kim loi crom phn ng va vi V lt kh Cl2 (trong iu kin thch hp). Gi
tr ca V (ktc) l (cho Cr = 52):
A. 3,36. B. 10,08. C. 5,04. D. 4,48.
Cu 19: Asen l mt nguyn t ha hc c k hiu As (cng nhm vi nguyn t photpho, c s hiu l
33), l mt kim gy ng c kht ting, ng c asen s dn n ung th da, ung th phi, ung th
thn v bng quang; tuy nhin asen hu c li t c hn asen v c (thch tn) rt nhiu (asen hu c
khng tng tc vi c th ngi v thi ra theo ng bi tit t 1-2 ngy), c bin v hi sn lun c
lng asen hu c trong c th v th trong nc mm sn xut truyn thng (ln men c) lun c lng
asen hu c nht nh (t gy nguy him). Cng thc no di y l asen hu c?
A. AsCl3. B. H3AsO4.
C. As2 S3. D. H2N C6H4 - AsO(OH)2.
Cu 20: Xenluloz c cu to mch khng phn nhnh, mi gc C6 H10 O5 c 3 nhm OH, nn c th
vit l:
A. [C6H7O3(OH)2]n. B. [C6H7O2(OH)3]n. C. C6H5O2(OH)3]n D. [C6H8O2(OH)3]n.
Cu 21: Dy no sau y gm cc cht c sp xp theo th t gim dn lc baz ?
A. CH3NH2, NH3, C2H5NH2. B. CH3NH2, C2H5NH2, NH3.
C. NH3,C6H5NH2,CH3NH2. D. C6H5NH2 ,CH3NH2,NH3.
Cu 22: Cht phn ng vi dung dch NaOH to CH3COONa v C2 H5OH:
A. HCOOCH3. B. CH3 COOCH3. C. HCOOC2 H5. D. CH3 COOC2 H5.
Cu 23: Cht tc dng vi Cu(OH)2 cho hp cht c mu tm l:
A. Ala-Gly-Val. B. Ala-Gly. C. Gly-Ala. D. Val-Gly.
Cu 24: C bao nhiu tripeptit m phn t cha 3 gc -aminoaxit khc nhau?
6 cht. B. 8 cht. C. 5 cht. D. 3 cht.
Cu 25: Cht X c cng thc phn t C4H8O2. Khi X tc dng vi dung dch NaOH sinh ra cht Y c
cng thcC3H5O3Na. Cng thc cu to ca X l:
A. HCOOC3H7. B. CH3COOC2H5. C. C2H5COOCH3. D. HCOOC3H5.
Cu 26: Cho 5 gam hn hp bt Cu v Al vo dung dch HCl d, phn ng xong thu c 3,36 lt H
ktc. % khi lng ca Al trong hn hp ban u l:
A. 64%. B. 54%. C. 51%. D. 27%.
Cu 27: Cho kh CO d i qua hn hp gm CuO, Al2O3, MgO (nung nng). Sau khi cc phn ng xy
ra hon ton cht rn thu c gm:
A. Cu, Al, MgO B. Cu,Al2O3, MgO C. Cu, Al, Mg D. Cu,Al2O3,Mg
Cu 28: Dy cation kim loi c xp theo chiu tng dn tnh oxi ho t tri sang phi l:
A. Cu2+ ,Mg2+ ,Fe2+. B. Mg2+ ,Fe2+ ,Cu2+. C. Mg2+ ,Cu2+ ,Fe2+. D. Cu2+ ,Fe2+ ,Mg2+.
Cu 29: Cho mt mu Na vo dung dch CuSO4, hin tng xy ra l:
A. c kh thot ra, xut hin kt ta xanh, sau kt ta tan.

B. c kh thot ra, xut hin kt ta xanh, kt ta khng tan.
C. dung dch mt mu xanh, xut hin Cu mu .
D. dung dch c mu xanh, xut hin Cu mu .
Cu 30: Cho m(g) hn hp 2 aminoaxit (phn t ch cha 1 nhm - COOH v 1 nhm - NH2) tc dng
vi 100ml dung dch HCl 2M c dung dch X. phn ng va ht vi cc cht trong X cn dng
200(g) dung dch NaOH 8,4% c dung dch Y. C cn Y c 34,37(g) cht rn khan. Gi tr m l:
A. 13,87. B. 19,8. C. 17,47. D. 17,83.
Cu 31: t chy hon ton m gam hn hp gm hai amin (l ng ng) v hai anken cn va
0.2775 mol O2, thu c tng khi lng CO2 v H2O bng 11,43 gam. Gi tr ln nht ca m l:
A. 2,55. B. 2,97. C. 2,69. D. 3,25.
Cu 32: Mt dung dch X c cha cc ion: x mol H+, y mol Al3+, z mol SO2- v 0,1 mol Cl-. Khi nh t
t n d dung dch NaOH vo dung dch X, kt qu th nghim c biu din trn th sau:
Cho 300 ml dung dch Ba(OH)2 0,9M tc dng vi dung dch X thu c kt ta Y v dung dch Z.
Khi lng kt ta Y l (cc phn ng xy ra hon ton):
A. 62,91gam. B. 49,72gam. C. 46,60 gam. D. 51,28 gam.
Cu 33: Ha tan hon ton hn hp X gm Cu, CuO, Cu(NO3)2 (trong s mol Cu bng s mol CuO)
vo 350 ml dung dch H2SO4 2M (long), thu c dung dch X ch cha mt cht tan duy nht, v c
kh NO thot ra. Phn trm khi lng Cu trong X c gi tr gn nht vi gi tr no sau y?
A. 23,8 %. B. 30,97%. C. 26,90%. D. 19,28%.
Cu 34: Thy phn hon ton cht bo X trong mi trng axit, thu c glixerol v hn hp hai axit
bo gm axit oleic v axit linoleic (C17H31COOH). t chy m gam X cn va 76,32 gam O2, thu
c 75,24 gam CO. Mt khc, m gam X tc dng ti a vi V ml dung dch 1M. Gi tr ca V l:
A. 120. B. 150. C.180. D. 210.
Cu 35: Hn hp X gm CuSO4, Fe2(SO4)3, MgSO4, trong X oxi chim 47,76% khi lng. Ha tan ht
26,8 gam hn hp X vo nc c dung dch Y, cho dung dch Ba(OH)2 d vo dung dch Y thy xut
hin m gam kt ta. Gi tr ca m l:
A. 46,6. B. 55,9. C.57,6. D. 61,0.
Cu 36: Ha tan ht 8,72 gam hn hp FeS2, FeS v Cu vo 400 ml dung dch HNO3 4M, sn phm thu
c gm dung dch X v mt cht kh thot ra. Nu cho dung dch BaCl2 d vo dung dch X th thu
c 27,96 gam kt ta, cn nu cho dung dch Ba(OH)2 d vo dung dch X th thu c 36,92 gam
kt ta. Mt khc, dung dch X c kh nng ha tan ti a m gam Cu. Bit trong cc qu trnh trn, sn

phm kh duy nht ca N5+ u l NO. Gi tr ca m l:
A. 32,96. B. 9,92. C. 30,72. D. 15,68.
Cu 37: Cho glixerol phn ng vi mt axit cacboxylic n chc thu c cht hu c mch h X. t
chy hon ton a mol X thu c b mol CO2 v c mol H2O (bit b = c + 3a). Mt khc, hiro ha hon
ton a mol X cn 0,3 mol H2, thu c cht hu c Y. Cho ton b lng Y phn ng ht vi 400 ml
dung dch NaOH 1M, c cn dung dch sau phn ng c 32,8 gam cht rn. Phn trm khi lng oxi
trong X l:
A. 40,00%. B. 39,22%. C. 32,00%. D. 36,92%.
Cu 38: Tripeptit X v tetrapeptit Y u mch h (c to nn t cc -amino axit c cng thc dng
H2N CxHy COOH). Tng phn trm khi lng oxi v nit trong X l 45,88%; trong Y l 55,28%.
Thy phn hon ton 32,3 gam hn hp X v Y cn va 400 ml dung dch KOH 1,25M, sau phn
ng thu c dung dch Z cha ba mui. Khi lng mui ca - aminoaxit c phn t khi nh nht
trong Z l:
A. 45,2 gam. B. 48,97 gam. C. 38,8 gam. D. 42,03 gam.
Cu 39: Cao su buna - N (hay cao su nitrile; NBR) l loi cao su tng hp, c tnh chu du cao, c
dng trong ng dn nhin liu; sn xut gng tay chuyn dng,.... xc nh t l mc xch butaien (
CH = CH - CH = CH) v acrilonitrin (CH = CH - CN) trong cao su nitrile, ngi ta t mu cao su ny
trong lng khng kh va (xem khng kh cha 20% O2 v 80% N2 v th tch); thu c hn hp
kh v hi gm CO2, N2, H2O (trong CO chim 14,222% v th tch). T l mc xch butaien v
acrilonitrin trong cao su nitrile l:
A. 4 : 3. B. 3 : 4. C. 5 : 4. D. 1 : 3.
Cu 40: X, Y l hai axit cacboxylic no, n chc, mch h, ng ng k tip nhau (Mx < MY), T l
este to bi X, Y v ancol hai chc Z. t chy hon ton 7,48 gam hn hp E gm X, Y, Z, T cn dng
va 6,048 lt O2 (ktc), thu c m gam hn hp kh v hi. Dn ht hn hp kh v hi thu c
vo bnh cha H2SO4 c, d thy c 0,71m gam kh khng b hp th. Mt khc 7,48 gam hn hp E
trn phn ng ti a vi 100 ml dung dch KOH 1M (un nng).
Cho cc pht biu sau v X, Y, Z, T.
- Phn trm khi lng ca Y trong E l 19,25%.
- Phn trm s mol ca X trong E l 12%.
- X khng lm mt mu dung dch Br2.
- Tng s nguyn t cacbon trong phn t T l 5.
- Z l ancol c cng thc C3H6(OH)2.
S pht biu ng l:
A. 1. B.2. C. 3. D. 4.

P N
1 A 11 A 21 A 31 B
2 C 12 A 22 D 32 D
3 D 13 C 23 A 33 B
4 B 14 C 24 A 34 A
5 D 15 A 25 C 35 D
6 B 16 B 26 B 36 A
7 D 17 D 27 B 37 A
8 C 18 C 28 B 38 B
9 A 19 D 29 B 39 C
10 D 20 B 30 D 40 A
Cu 1: p n A
T nilon-6,6 c tnh dai, bn, mm mi, ng mt c dng dt vi may mc, thuc loi t poliamit.
Cu 2: p n C
Cc ng phn cu to l amino axit ng vi CTPT C4H9NO2:
H2NCH2CH2CH2COOH; CH3CH(NH2)CH2COOH; CH3CH2CH(NH2)COOH; CH3C(NH2)(CH3)COOH;
H2NC(CH3)2COOH .
Cu 3: p n D
Phn tch : Ta thy cc p n A, B, C u ng. Duy ch c D sai v hp cht khng c cu to nn t
hai -aminoaxit nn khng th l ipeptit c.
Ch : -aminoaxit l cc aminoaxit c gc -NH2 cm trc tip vo C lin kt vi nhm -COOH.
Cu 4: p n B
Phn tch : n mn in ha khng th xy ra th nghim (1) v (3) v TN1 v TN3 cha 2 in
cc khc nhau v bn cht (TN1 ch c Fe, TN3 ch c Cu).
Ch : iu kin xy ra n mn in ha l
Cc in cc phi khc nhau v bn cht, c th l cp 2 kim loi khc nhau hoc cp kim loi vi
phi kim,...
Cc in cc phi tip xc trc tip hoc gin tip nhau qua dy dn.
Cc in cc cng tip xc vi mt dung dch cht in l.
Cu 5: p n D
Phn tch : Cc kim loi kim th thuc nhm IIA nn cu hnh e lp ngoi cng ca chng l ns2
Cu 6: p n B
Phn tch: Nguyn t ca hu ht cc nguyn t kim loi c t e lp ngoi cng (1, 2 hoc 3e) nn ta
c th d dng loi cu hnh e ca (2) v (4).
Vy cc cu hnh e khng phi l ca kim loi l : (2) v (4). '
Cu 7: p n D
Phn tch : Theo dy in ha ca kim loi ta c
Fe2 Fe3 Ag
Fe Fe2 Ag
2
u tin, ta c : Fe 2Ag Fe 2Ag V d nn tip tc c phn ng :
Fe2 Ag Fe3 Ag Vy dung dch sau phn ng gm Fe(NO3)3 v AgNO3 d.
Cu 8: p n C
Phn tch :
A. Khi m d th ta lun lun khng thu c kt ta Al(OH)3
B. V lng HCl d nn lng kt ta to thnh lc ban u s b ha tan ht.
C. Lun lun to kt ta Al(OH)3 v NH3 khng c kh nng ha tan kt ta.
D. Ging vi phn ng B, ta lun c lng kt ta to thnh lc ban u s b ha tan ht.
Vy kt thc th nghim C ta thu c kt ta Al(OH)3 .
Cu 9: p n A
Phn tch : Th nghim xy ra phn ng oxi ha-kh l b) Glucoz b oxi ha bi dung dch AgNO3
trong NH3, un nng to kt ta Ag; c)Kh glucoz bng H2 to sobitol.
Ch : Glucoz b oxi ha bi Cu(OH)2 trong mi trng kim.
Cu 10: p n D
nC4H8O2 1
Phn tch: Ta tnh nhanh c . M khi thy phn este C4H8O2 ta thu c axit propionic nn
CTCT thu gn ca X l : CH3CH2COOCH3 .
Cu 11: p n A
Phn tch : Ta d dng nhn thy glucoz l monosaccarit cn saccaroz l isaccarit; tinh bt,
xenluloz l polisaccarit.
Cu 12: p n A
nsaccaroz 0,35mol
Phn tch :
nglucoz 0,92.0,35 0,322mol
Khi thy phn saccaroz ta thu c glucoz v fructoz nn .
Vy khi lng glucoz c to thnh sau phn ng thy phn l : m = 57,96gam.
Cu 13: p n C
Phn tch : Khi t chy Fe, ta thu c X l mt oxit ca Fe. Tip tc kh X bng CO, ta thu c Y
phi l Fe th Y mi tc dng c vi dung dch FeCl3 to ra dung dch Z s l FeCl2 .
Khi , to ra Fe(NO3)3 th T phi l AgNO3.
Vy Y v T c th l Fe; AgNO3 .
Cu 14: p n C
Phn tch : Cc s oxi ha thng gp ca st l +2 v +3.
Cu 15: p n A
Phn tch: ta vit qu trnh oxi-ha kh cn bng phng trnh

8

Fe3 3Fe3 e x3
N 5 3e N 2 x1
3Fe3O4 28HNO3 9Fe NO3 3 NO 14H2O
Vy tng h s trong phng trnh ca phn ng oxi ha-kh ny l 55.

Cu 16: p n B
140.103.0,96
nFe 2400 mol
Ta c : 56
nFe 1 1200
nFe2O3 1500 mol
2 H % 0,8
1500.160
mmanhetit 320 mol
75%
Vy khi lng qung hemantit l 320kg.
Cu 17: p n D
Phn tch : Ta c cng thc ca dung dch lysin l H2N-[CH2]4-CH(NH2)-COOH nn lysin lm qu tm
ha xanh ch khng phi l hng.
Cu 18: p n C
7,8
nCr 0,15 mol nCrCl3 0,15mol
52
3
nCl2 .nCrCl3 0,255 mol
2
Vy V = 5,04l
Cu 19: p n D
Phn tch: d dng nhn thy cng thc ca asen hu c l H2N-C6H4-AsO(OH)2 .
Cu 20: p n B
Phn tch : Xenluloz ((C6H10O5)n) c th vit l [C6H7O2(OH)3]n .
Cu 21: p n A
Phn tch: Nhn thy ngay dy A. CH3NH2, NH3, C6H5NH2 l dy gm cc cht c sp xp theo th t
gim dn lc baz.
Cu 22: p n D
Phn tch : Ta thy tc dng vi NaOH m to CH3COONa v C2H5OH th cht l este
CH3COOC2H5 .
Cu 23: p n A
Phn tch : Nu khng nh phn kin thc Trong mi trng kim, peptit tc dng vi Cu(OH)2 cho
hp cht mu tm. l mu ca hp cht phc gia peptit c t 2 lin kt peptit tr ln vi ion ng
(Phn I.2- SGK c bn Ha 12-tr.51) th ta c th loi ngay cc p n B, C, D v chng cng l ipepptit
c bn cht ging nhau.
Cu 24: p n A

Phn tch : Gi cc -aminoaxit ln lt l A, B v C.
Ta thy c mi-aminoaxit (hoc A, hoc B, hoc C) ng gia th khi thay i v tr cc- aminoaxit
cn li th ta thu c hai peptit khc nhau. Nn vi 3-aminoaxit th ta thu c 2.3 = 6 tripeptit cha 3
gc- aminoaxit khc nhau.
Cc tripeptit l : A-B-C, C-A-B, A-C-B, B-C-A,B-A-C, C-A-B.
Cu 25: p n C
Phn tch : Mui Y c CTCT CH3CH2COONa l nn X s c CTCT l C2H5COOCH3 .
Cu 26: p n B
Phn tch : Ta thy ch c Al tc dng vi dung dch HCl cn Cu th khng nn nAl nH2 :1,5 0,1 mol
% khi lng Al trong hn hp ban u l 54%.
Cu 27: p n B
Phn tch : Nhng kim loi c hot ng trung bnh nh Zn, Fe, Sn, Pb,... thng c iu ch bng
phng php nhit luyt, ngha l kh ion kim loi trong hp cht bng cc cht kh nh C, CO, H2 hoc
cc kim loi hot ng.
Nn khi cho kh CO d i qua hn hp gm CuO, Al2O3, MgO ( nung nng ), sau phn ng xy ra hon
ton cht rn thu c gm : Cu, Al2O3, MgO.
Cu 28: p n B
Phn tch : Dy cc kim loi c sp xp theo chiu tng dn tnh oxi ha t tri sang phi l Mg2+,
Fe2+, Cu2+.
Cu 29: p n B
Phn tch : Nhn thy ngay, khi cho mu Na vo dung dch CuSO4 th Na tc dng vi H2O sinh ra kh
H2 . Sau , dung dch NaOH tc dng vi CuSO4 to kt ta mu xanh (Cu(OH)2), kt ta ny khng
tan.
PTHH : 2Na 2H2O 2NaOH H2
2NaOH CuSO4 Cu OH 2 Na2SO4
Cu 30: p n D
200.8,4%
nNaOH 0,42 mol ; nHCl 0,2 mol
40
nNaOH t / d a min oaxit 0,42 0,2 0,22 mol
Dung dch Y gm NaCl (0,2mol) v mui Na ca aminoaxit (0,22mol)

mmui Na ca aminoaxit 34,37 0,2.58,5 22,67g
aminoaxit NaOH mui H2O

Ta c : 0,22 0,22
Bo ton khi lng, c :

maminoaxit mNaOH mmui mH2O maminoaxit 22,67 0,22.18 0,22.40
Vy khi lng 2 aminoaxit l m = 17,83gam.

Cu 31: p n B
nCO2 a, nH2 O b
Phn tch : ta t
44a 18b 11,43

a 0,18

2a b 0,555 Bo ton n.t O b 0,195
Ta c :
nH2O nCO2 0,015
Ta c :
S chnh lch ny l do t chy amin nn hai amin ny no, mch h.
Cn H2n2 x NH2 x
t CT chung ca hai amin l .
x
Cn H2n 2 x NH2 x
O2
nCO2 (n 1 0,5x) H2O N2
2
nH2O nCO2 0,015 (1 0,5x) nN2 0,5x.namin 0,015 mnit 0,42
Ta c
Bo ton khi lng, ta c :
mhn h p mO2 mCO2 mH2O mN2
m 11,43 mN2 8,88 2,97
Vy khi lng ln nht ca m l 2,97g.

Cu 32: p n D
Phn tch : Ban u, NaOH mt mt lng trung ha lng H+ , sau mi bt u to kt ta v ha
tan kt ta.
Khi nh mt lng 0,35 mol NaOH, ta c:

0,35 x 0,05.3 x 0,2
Lng NaOH cn dng to kt ta cc i l :
x 3nAl 3 x 3y
Khi nh mt lng 0,55 mol NaOH, ta c qu trnh ha tan khi kt ta t cc i xung cn 0,05 mol
kt ta l :
Al (OH )3 OH AlO2 2H2O
0,55 x 3y

0,05 0,55 x 3y y 0,1
Khi :
H 0,2mol
3
Al 0,1mol
2
SO4 0,2mol
Cl 0,1mol
Suy ra dung dch X gm:
Khi nh Ba(OH)2 vo dung dch X th mt 0,1mol Ba(OH)2 trung ha lng H+, cn li 0,17mol
Ba(OH)2 tc dng vi Al3+.
nAl OH a; nAlO b
Gi 3 2
a b nAl 3 y 0,1
a 0,06

3a 4b nOH 0,17.2 0,34 b 0,04
Ta c :
Ta c :
Al 3 3OH Al (OH )3 ; Al 3 4OH AlO2 2H2O
(V )
Vy khi lng kt ta to thnh l :
mAl (OH )3 mBaSO4 0,06.78 0,2.233 51,28g
Cu 33: p n B
nCu nCuO a; nCu( NO3 ) b.
Phn tch : t
Khi cho X tan hon ton trong dung dch H2SO4 th ta ch thu c dung dch ch cha mt cht tan duy
NO3
nht nn sau phn ng th ht v mui thu c l CuSO4 .
CuO 2H Cu2 H2O
Ta c :
3Cu2 8H 2NO 3Cu2 2NO 4H2O
8
a a 2b
3
8
2a a nH 2nH2SO4 1,4 a 3
3
2
2b a b 0,1
M 3
0,3.64
30,97%
Vy khi lng Cu trong X l : 0,3.(64 80) 0,1.188
Cu 34: p n A
Phn tch : Ta thy axit oleic (C18H34O2) v axit linoleic (C18H32O2) l nhng axit c 2 v 3 .
Vy nn khi to este vi glixerol th

X 7 ( nu c 2 axit oleic v 1 axit linoleic) hoc X 8 ( nu c
1 axit oleic v 2 axit linoleic).

nO2 2,385mol ; nCO2 1,71mol
Bo ton nguyn t O, ta c:
nO X 2nO2 2nCO2 nH2O 6nX 4,77 3,42 nH2O I
nCO nH2O 6nX 1,71 nH2O 6nX

nCO2 nH2O ( X 1)nX 2 ( II )

nCO2 nH2O 7nX
1,71 nH2O 7nX
Li c :
Gi (I) v (II), c:
nX 0,03
nH2O 1,53
n 9
X 325
1971
nH2O
1300
nBr 2 0,03.4 0,12mol V 120ml
Vi nX = 0,03 mol th trong gc C ca cht bo c 4 nn .
n y ta chn lun p n A.
Cu 35: p n D
Phn tch : Khi cho CuSO4, Fe2(SO4)3, MgSO4 vo dung dch Ba(OH)2 th cc kt ta to thnh gm
BaSO4, Cu(OH)2, Fe(OH)3, Mg(OH)2.
Ta thy:
26,8.47,76%
nO 4nSO2 0,8mol
4
16
nSO2 0,2 nBaSO4 0,2mol
mol
4
nOH 2nSO2 0,4mol

4
26,8 mkim loi nSO2

C: 4
mkim lo i 26,8 0,2.96 7,6g
m mBaSO4 mkim loi mOH 0,2.233 7,6 0,4.17 61gam
Ch : Ta thng qun mt lng hidroxit ca cc kim loi cng l kt ta. V d nh bi ny khi qun
tnh lng th ta s b nhm l p n A.
Cu 36: p n A
nFes2 a, nFes b, nCu c
t
nS 0,12 2a b (1)
Khi cho BaCl2 vo dung dch X, ta c :
Khi cho Ba(OH)2 d vo dung dch X, ta c khi lng cc hidroxit to thnh l :
36,92 27,96 a b .107 98c(2)
Li c : 8,72 120a 88b 64c (3)
Gii (1), (2), (3), ta c a 0,05; b 0,02; c 0,015.

Qu trnh nhng-nhn e:

FeS2 Fe3 2S6 15e N 5 3e N 2
0,05 0,75
FeS Fe3 s6 9e Cu Cu2 2e
0,02 0,18 0,015 0, 03
nHNO3 0,32mol nHNO3d 1,6 0,32 1,28mol
p dng pp bo ton e, ta c: Suy ra
Khi , dung dch X gm HNO3 d 1,28mol v Fe2(SO4)3 0,035mol v CuSO4 0,015mol
Suy ra s mol Cu b ha tan ti a l :
nFe33 0,035.2 3
nHNO3 d .1,28 0,515mol
2 8 2 8
Vy khi lng Cu m X c kh nng ha tan ti a l 32,96gam.
Cu 37: p n A
Phn tch : Ta c th tm tt qu trnh phn ng nh sau Glixerol+1axhc n chc cht hu
H 0,3mol
NaOH 0,4 mol
c X Y 32,8gam cht rn
2
n nH2O 3nX
Nhn thy b c 3a hay CO2 nn trong X c 4 lin kt pi.
Do CTCT ca X l :
CnH2n-1COO-CH2-CH(OOCC nH2n-1)-CH2OH Ta thy H2 ch cng vo gc R khng no.
nH2 2nX 0,3mo1 nX 0,15mo1
Khi cho NaOH vo Y, ta c:

Cn H2n1COO CH2 CH OOCCn H2n1 CH2OH 2NaOH C3H8O3 2Cn H2n1COONa
Khi cho X tc dng vi NaOH 0,4mol th thu c 32,8g cht rn gm 0,1mol NaOH d v 0,3mol
mui CnH2n+1COONa
28,8
mmui 32,8 0,1.40 28,8g Mmui 96
0,3
CTCT ca mui l C2H5COONa hay n = 2
CTCT ca X l :
C2 H3COO CH2 CH OOCC2 H3 CH2OH
5.16
%O( X) 40%
200
Cu 38: p n B
Phn tch : C CTCT ca -aminoaxit l H 2 N-CxHy-COOH, suy ra X v Y ln lt l:
2 H2O
3H2N Cx Hy COOH X
3H2O
4H2N Cx Hy COOH Y

16.4 14.3
45,88% M X 231
MX
231 18.2
M -aminoaxit 89
Ta c: 3
Suy ra X c th l : Val-Val-Val Tng t c MY 246

246 18.3
M -aminoaxit 75
4
Y phi l Gly-Gly-Gly-Gly
V thy phn hon ton X,Y to hn hp 3 mui nn X khng th l Val-Val-Val.
Suy ra X s l Gly-Ala-B vi B l -aminoaxit c CTCT nh sau : CH 3-CH2-CH(NH2)COOH
(M=103)
Gly vn l-aminoaxit c mui m phn t khi nh nht trong dung dch Z.
nX a, nY b
t .
1
3a 4b nKOH 0,5 a
30
231a 246b 32,3 b 0,1
Ta c:
1
nGly a 4b 0,4
30
Gly l -aminoaxit c mui m phn t khi nh nht trong dung dch Z.
1
mmui gly 113. 0,4 48,97gam
30
Cu 39: p n C
Phn tch : t CT ca cao su buna -N l : (C 4H6)a(C3H3N)b Ta c:
C4H6 a C3H3N b 5,5a 3,75b O2 4a 3b CO2 3a 1,5b H2O 0,5bN2

nCO2
14,222%
nN2 d nN2 sinh ra nCO2 nH2O
nCO2
0,14222
4nO2 d nN2 sinh ra nCO2 nH2O
4a 3b
0,14222
4(5,5a 3,75b) 0,5b (4a 3b) (3a 1,5b)
4a 3b a 5
0,14222
29a 20b b 4
Vy t l mc xch butaien v acrilonitrin trong cao su nitrile l 5:4 .
Cu 40: p n A
Phn tch : Ta d dng nhn ra khi t chy hn hp E th c

nCO2 mCO2 : 44 0,71m : 44
1
nH2O mH2O :18 0,29m :18
M E gm hai axit X, Y no, mch h, n chc l ng ng k tip nhau khi t chy lun to
nCO2 nH2O
ra
Suy ra Z l ancol hai chc, no , mch h v nZ nT .

nO 0,27mol 7,48 mO2 mCO2 mH2O nCO2 .(44 18)
Ta c , bo ton khi lng ta c : ^ ncO2 =
n
H2 O = 0,26mo1 Bo ton nguyn t O, ta c:
2nX 2nY 2nZ 4nT 0,27.2 0,26.3 2nX 2nY 6nT 0,24
Li c nKOH nX nY 2nT 0,1 Suy ra nX nY 0,06; nT nZ 0,02
t CT chung ca X, Y l

Cn H2nO2 n 1
CTPT ca Z, T ln lt l C mH2m+2 O2 v CxH2x-2O4 ( m 2; x 5 )
nCO2 0,06n 0,02. m x 0,26 0,06n 0,02. m x 13 3n m x
Ta c :
M m 2; x 5 nn n 2
Li c n 1 nn hai axit X, Y ln lt l HCOOH v CH 3 COOH. Khi cng thc phn t ca T

s l Cm+3H2m+4O4 .
nHCOOH a nCH3COOH 0,06 a
Lc ny, ta t th
nCO2 a (0,06 a).2 0,02. m m 3 0,26 0,18 a 0,04m 2 25a m
Ta c :
M a 0,06 nn m 3,5
m khng th bng 2 v khi a 0 nn m 3
Khi a 0,04mol v Z, T ln lt l C3 H8 O2 , C6 H10 O4 .

Th li, ta c:
mHCOOH mCH3COOH mC3H8O2 mC6H10O4 0,04.46 0,02.60 0,02.76 0,02.146 7,48gam
Vy
HCOOH X 0,04mol

CH3COOH Y 0,02mol

C3 H6 OH 2 ( Z) 0,02mol

C H O T 0,02mol
hn hp E gm: 6 10 4
0,02.60
%mY( E) 16,04%
7,48
0,04
%mX( E) 40%
0,1
-X l HCOOH c lm mt mu dung dch Br2 -Tng s nguyn t C trong T l 6

-Z l ancol a chc C3H6(OH)2
Vy vi cc pht biu bi cho ch c duy nht pht biu cui l ng.
Ch : Trong cc axit cacboxylic no, n chc, mch h c duy nht HCOOH lm mt mu nc Br2.

THPT TRN HNG O Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: C bao nhiu amin bc 2 c cng cng thc phn t C4 H11 N?

A. 3 B. 8 C. 4 D. 1
Cu 2: Cho mt ipeptit Y c cng thc phn t C6 H12 N2 O3 . S ng phn peptit ca Y (ch cha gc
a-aminoaxit) mch h l:
A. 5 B. 4 C. 7 D. 6
Cu 3: Cho cc nhn nh sau:
(1) Alanin lm qu tm ha xanh.
(2) Axit glutamic lm qu tm ha .
(3) Lysin lm qu tm ha xanh.
(4) Axit aipic v hexametyleniamin l nguyn liu sn xut t nilon-6,6
(5) Methionin l thuc b thn.
S nhn nh ng l:
A. 2 B. 5 C. 3 D. 4
Cu 4: Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2 = C(CH3) - CH = CH2, C6H5CH = CH2 B. CH2 = CH - CH = CH2, C6H5CH = CH2
C. CH2 = CH - CH = CH2, lu hunh D. CH2 = CH - CH = CH2 , CH3 - CH = CH2
Cu 5: Cho cc cht sau
(I) H2 N-CH2 -CH2 -CO-NH-CH2 -CO-NH-CH2 -CH2 -COOH
(II) H2 N-CH2 CO-NH-CH2 -CO-NH-CH2 -COOH
(III) H2 N-CH(CH3 )-CO-NH-CH2 -CO-NH-CH2 -CO-NH-CH2 -COOH
Cht no l tripeptit?
A. III B. I C. II D. I,II
Cu 6: Cc dung dch u tc dng c vi Cu(OH) 2 l:
A. glucoz, xenluloz, glixerol B. fructoz, saccaroz, tinh bt.
C. glucoz, glixerol, tinh bt D. fructoz, saccaroz, glixerol
Cu 7: Poli (vinyl clorua) (PVC) c iu ch t kh thin nhin (cha 95% th tch kh metan) theo
s chuyn ha v hiu sut mi giai on nh sau:
Metan
hs15%
Axetilen
hs95%
Vinylclorua
hs90%
PVC

Mun tng hp 3,125 tn PVC th cn bao nhiu m3 kh thin nhin (o ktc)?
(H=1, C=12, O=16, Cl=35,5)
A. 17466 m3 B. 18385 m3 C. 2358 m3 D. 5580 m3
Cu 8: Thy phn este C4 H6 O2 trong mi trng axit th ta thu c mt hn hp cc cht u c
phn ng trng
gng. Vy cng thc cu to ca este c th l p n no sau y?
A. H-COO-CH=CH-CH3 B. CH2=CH-COO-CH3
C. CH3-COO-CH=CH2 D. H-COO-CH2-CH=CH2
Cu 9: trung ha 200 ml dung dch aminoaxit 0,5M cn 100 g dung dch NaOH 8%, c cn dung
dch c 16,3 g mui khan. X c cng thc cu to (cho H=1; C=12; N=14; O=16; Na=23):
A. (H2 N)2 CH-COOH B. H2 N-CH2 -CH(COOH) 2
C. H2NCH(COOH)2 D. H2 N-CH2 -CH2 -COOH
Cu 10: Cho cc pht biu sau v cacbohirat:
(a) Glucoz v saccaroz u l cht rn, mu trng, c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam.
(d) Khi thu phn hon ton hn hp gm tinh bt v xenluloz trong mi trng axit, ch thu c mt
loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3trong NH3 thu c Ag.
(f) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l
A. 5. B. 6. C. 4. D. 3.
Cu 11: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo
phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5)
A. 6. B. 3. C. 4. D. 5.
Cu 12: phn bit glucoz vi etanal ta dng cch no sau y?

A. tc dng vi Cu(OH)2 nhit cao B. tc dng vi Cu(OH)2 nhit phng
C. thc hin phn ng trng gng D. dng dung dch B2
Cu 13: Cho m gam glucoz ln men thnh ancol etylic vi H= 75%. Ton b kh CO2 sinh ra c hp
th ht vo dung dch Ca(OH)2 ly d to ra 500g kt ta. Gi tr ca m l: (C=12; H=1, O=16; Ca=40)
A. 720 B. 540 C. 1080 D. 600
Cu 14: Chn Cu sai:
A. xenluloz v tinh bt khng phn ng c vi dung dch AgNO3/NH3
B. tinh bt v xenluloz c tnh cht ca ancol a chc, tc dng vi Cu(OH)2, to thnh dung dch
phc cht mu xanh lam
C. tinh bt v xenluloz l nhng polime thin nhin c khi lng phn t rt ln
D. iu kin thng, tinh bt v xenluloz l nhng cht rn mu trng khng tan trong nc
Cu 15: Fructoz khng phn ng c vi:
A. dung dch Br2. B. H2/M, to.
C. dung dch AgNO3/NH3. D. Cu(OH)2.
Cu 16: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng
hp l A. 5. B. 3. C. 4. D. 2.
Cu 17: Nhm cc vt liu c ch to t polime trng ngng l
A. t axetat, nilon-6,6, poli(vinylclorua) B. cao su, nilon-6,6; t nitron
C. nilon-6,6; t lapsan; thy tinh Plexiglas D. nilon-6,6; t lapsan; nilon-6
Cu 18: un nng x gam hn hp A gm 2a mol tetra peptit mch h X v a mol tri peptit mch h Y
vi 550 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c
45,5 gam mui khan ca cc amino axit u c 1-COOH v 1-NH2 trong phn t. Mt khc thu phn
hon ton x gam hn hp A trn bng dung dch HCl d thu c m gam mui. Gi tr ca m l? (cho
C=12; H=1; O=16, N=14 , Na=23)
A. 56,125 B. 56,175 C. 46,275 D. 53,475
Cu 19: Cc este c cng thc C4H6O2 c to ra t axit v ancol tng ng c th c cng thc cu
to nh th no?
A. CH2=CH-COO-CH3; H- COO- CH2-CH= CH2; H-COO- CH=CH- CH3
B. CH2=CH-COO-CH3; CH3COO-CH= CH2; H- COO- CH2-CH= CH2
C. CH2=CH-COO-CH3; H- COO- CH2-CH= CH2
D. CH2=CH-COO-CH3; CH3COO-CH=CH2; H-COO-CH2-CH=CH2; H-COO-C(CH3)=CH2.
Cu 20: Trong cc cht di y, cht no l glyxin?
A. H2N-CH2-COOH B. CH3-CH(NH2)-COOH
C. HOOC-CH2CH(NH2)COOH D. H2N-CH2-CH2-COOH
Cu 21: Cho 0,1 mol H2NC3H5(COOH)2(axit glutamic) vo 150 ml dung dch HCl 2M, thu c dung
dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn
ng l (cho H=1; C=12; N=14; O=16 ,Na=23):

A. 0,55. B. 0,70. C. 0,65. D. 0,50.
Cu 22: Trong s cc cht: phenylamoni clorua, natri phenolat, ancol etylic, phenyl benzoat, t nilon-6,
ancol benzylic, alanin, tripeptit Gly-Gly-Val, m-crezol, phenol, anilin, triolein, cumen . S cht phn
ng c vi dung dch NaOH long, un nng l:
A. 10 B. 7 C. 8 D. 9
Cu 23: Bnh nhn phi tip ng (tim hoc truyn dung dch ng vo tnh mch), l loi
ng no?
A. Glucoz B. Fructoz C. Mantoz D. Saccaroz
Cu 24: Cht no di y khng phi l este?
A. CH3COOH B. CH3COOCH3 C. HCOOCH3 D. HCOOC6H5
Cu 25: Mt este c cng thc phn t l C3H6O2 c phn ng trng gng vi dung dch AgNO3 trong
NH3. Cng thc cu to ca este l cng thc no?
A. HCOOC3H7 B. HCOOC2H5 C. C2H5COOCH3 D. CH3COOCH3
Cu 26: Hp cht X c cng thc cu to CH3CH2 - COO - C2H5. Tn gi ca X l:
A. vinyl axetat B. metyl propionat
C. etyl propionat D. metyl metacrylat
Cu 27: Cho cc polime sau : si bng (1), t tm (2), si ay (3), t enang (4), t visco (5), t axetat
(6), nilon-6,6 (7). Loi t c ngun gc xenluloz l?
A. 1, 2, 3, 5, 6 B. 5, 6, 7 C.1, 2, 5, 7 D. 1, 3, 5, 6
Cu 28: T no di y l t nhn to?
A. T nitron B. T xenluloz axetat. C. T tm. D. T capron.
Cu 29: Lm bay hi 3,7 gam este n chim th tch bng th tch ca 1,6 gam O2 trong cng iu kin.
Este trn c s ng phn l: (cho C=12; H=1; O=16)
A. 3 B. 2 C. 4 D. 1
Cu 30: t chy hon ton a mol mt peptit X (c to ra t aminoaxit no, mch h trong phn t c
1- NH2 v 1-COOH) thu c b mol CO2 v c mol H2O v d mol N2. Bit b - c = a. Thu phn hon
ton 0,2 mol X bng dung dch NaOH (ly gp i so vi lng cn thit phn ng) ri c cn dung
dch sau phn ng th thu c cht rn c khi lng tng m gam so vi peptit ban u. Gi tr ca m
l? (cho C=12; H=1; O=16, N=14, Na=23)
A. 60,4 B. 76,4 C. 30,2 D. 28,4
Cu 31: Este C4H8O2 c to bi ancol metylic th c cng thc cu to l:
A. HCOOC3H7. B. CH3COOC2H5. C. C2H5COOCH3. D. C2H3COOCH3.
Cu 32: T nilon-6,6 l
A. hexacloxiclohexan B. poliamit ca axit aipic v exametyleniamin
C. poli amit ca axit s - aminocaproic D. polieste ca axit aipic v etylenglicol
Cu 33: Cho 3,52 gam cht A C4H8O2 tc dng vi 0,6 lt dung dch NaOH 0,1M. Sau phn ng c cn
dung dch thu c 4,08 gam cht rn. Cng thc ca A l:

A. C2H5COOCH3 B. HCOOC3H7 C. CH3COOC2H5 D. C3H7COOH
Cu 34: Polime no di y c cng cu trc mch polime vi nha bakelit?
A. cao su lu ha B. amiloz C. xenluloz D. Glicogen
Cu 35: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO2 hp th
vo dung dch nc vi trong thu c 275g kt ta v dung dch Y. un k dung dch Y thu thm 150g
kt ta na. Khi lng m l? (cho H = 1, C =12, O = 16, Ca=40)
A. 375g B. 750g C. 450g D. 575g
Cu 36: C4H8O2 c bao nhiu ng phn mch h phn ng c vi dung dch NaOH?
A. 5 B. 7 C. 6 D. 8
Cu 37: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t
thuc loi t poliamit?
A. 4 B. 1 C. 2 D. 3
Cu 38: Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg
xenluloz trinitrat (hiu sut 80%) l? (Cho H = 1;C =12; O = 16; N=14)
A. 34,29 lt. B. 42,34 lt. C. 53,57 lt. D. 42,86 lt.
Cu 39: Thy phn hon ton hn hp E gm 2 este X, Y n chc, ng phn, mch h, bng mt
lng dung dch NaOH va thu c 13,2 gam hn hp 2 mui (Z) v 7,8 gam hn hp 2 ancol (ch
hn km nhau 1 nguyn t C trong phn t). Nung Z thu 0,075 mol Na2CO3. Xc nh CTCT thu gn
ca X v Y: (Cho H = 1; C =12; O = 16; Na=23)
A. CH2 = CHCOOC2 H5 v CH3 COOCH = CHCH3
B. HCOOCH2 CH = CHCH3 v CH3 COOCH2 CH = CH2
C. C2 H5 COOCH2 CH = CH2 v CH3 CH = CHCOOC2 H5
D. CH3 COOCH2 CH = CH2 v CH2 = CHCOOC2 H5
(a) C th dng nc brom phn bit glucoz v fructoz.
(b) Trong mi trng baz, glucoz v fructoz c th chuyn ho ln nhau.
(c) Tinh bt v xenluloz l ng phn cu to ca nhau
(d) Khi un nng glucoz b kh bi dung dch AgNO3 trong NH3 to ra Ag.
(e) Trong dung dch, glucoz v fructoz u ho tan Cu(OH) 2 nhit cao cho dung dch mu xanh
lam.
(f) Trong dung dch, fructoz tn ti ch yu dng vng 5 cnh a - fructoz v 3-fructoz.
S pht biu ng l:
A. 4. B.5. C. 3. D. 2
P N

1 A 11 B 21 D 31 C
2 A 12 B 22 C 32 B
3 C 13 D 23 A 33 C
4 B 14 B 24 A 34 A
5 C 15 A 25 B 35 D
6 D 16 B 26 C 36 C
7 B 17 D 27 D 37 C
8 A 18 D 28 B 38 C
9 C 19 C 29 B 39 D
10 C 20 A 30 A 40 C
Cu 1: p n A
Cc amin bc 2 c cng cng thc phn t C4H11N l : CH3NHCH2CH2CH3, CH3NHCH(CH3)CH3;
CH 3CH 2 NHCH 2CH 3 .
Ch : Bc ca amin khc vi bc ca ancol.
Cu 2: p n A
Phn tch: Cc -aminaxit to nn ipeptit Y c th l :
A: H2N-CH2-COOH;B: CH3-CH2-CH(NH2)-COOH;
C: (CH3)2C(NH2)COOH;D: CH3-CH(NH2)-COOH
Cc ng phn ipeptit ca Y(C6H12N3O2) l:
A-B; B-A A-C; C-A v D-D.
Cu 3: p n C
Phn tch : Cc nhn nh ng l : 2, 3, 4.
Nhn nh 1 sai v Alanin c CTCT l CH3-CH(NH2)- COOH nn khng lm qu tm ha xanh.
Nhn nh 5 sai v methionin l thuc b gan.
Cu 4: p n B
Cc cht dng tng hp Cao su buna-S l : stiren ( C6H5CH=CH2) v buta-1,3-ien vi xc tc Na.
Cu 5: p n C Cht l tripeptit l : III
Ch : Ta cn xem xt k cc aminoaxit to nn peptit c phi l -aminaxit khng.
Cu 6: p n D
Phn tch: D thy p n A ta loi xenluloz, p n B v C loi tinh bt.
Vy cc dung dch u tc dng c vi Cu(OH)2 l fructoz, saccaroz, glixerol.
Cu 7: p n B
Phn tch : Ta c th tm tt ton b qu trnh phn ng nh sau
2nCH4
15%

nC2 H2
95%

nCH2CHCl
90%

(CH2 CHCl )n
3,125.106
nPVC 5.104 mol
62,5
Cu 8: p n A
Phn tch: D dng tnh nhanh c nC4H6O2 = 2. Este ny khi thy phn trong mi trng axit thu c
mt hn hp cc cht u c phn ng trng gng nn CTCT ca n l COO-CH=CH-CH3.

Cu 9: p n C
Phn tch: naminoaxit 0,5.0,2 0,1; nNaOH 0,2mol .

aminoaxit c hai nhm-COOH trong phn t .
16,3
Mmui 163
Ta c 0,1
Suy ra CTCT ca mui l H2N-CH-(COONa)2 Vy CTCT ca aminoaxit l H2N-CH-(COOH)2 Cu 10:

p n C
Phn tch: Ta nhn thy cc pht biu ng l b, c, d, e. Pht biu a sai v glucoz v saccaroz l cc
cht rn khng mu ch khng phi l mu trng. Pht biu f sai v saccaroz khi tc dng vi H2 khng
to ra sobitol, ch c glucoz .
Cu 11: p n B
k(C2 H3Cl ) CI 2 C2k H3k1Cl( k1) HCl
Theo bi, c :
(k 1).35,5
63,96% k3
12.2k 3k 1 (k 1).35,5
Cu 12: p n B
Phn tch: Khi cho glixerol v etanal tc dng vi Cu(OH)2 nhit phng th ch c glixerol to dung
dch mu xanh lm cn etanal khng c hin tng g.
Cu 13: p n D
nCaCO3 nCO2 5mol
Phn tch:
nCO2 1 5 1 10
nGlu . .
2 H% 2 0,75 3
10
mGlu 600gam
3.180
Vy khi lng Gluocoz l 600 gam.
Cu 14: p n B
Phn tch: Nhn thy ngay p n sai l B. Tinh bt v xenluloz khng c tnh cht cu ancol a chc,
tc dng vi Cu(OH)=
Cu 15: p n A
Phn tch: Fructoz khng phn ng c vi dung dch Br2.
Cu 16: p n B
Phn tch: Cc t tng hp l t nilon-6,6; t nitron(hay olon), t capron.
Cu 17: p n D
Phn tch: Cc vt liu c ch to t polime trng ngng l nilon-6,6; t lapsan; nilon-6.
Cu 18: p n D
nNaOH 2a.4 a.3 0,55 a 0,05
Phn tch: Ta c Khi cho peptit tc dng vi NaOH ta lun c
nH2Osinh ra npeptit
nH2O 2aa a 0,15

mA mNaOH mmui mH 2O
mA 45,5 0,15.18 0,55.40 26,2gam
Khi cho peptit tc dng vi HCl th nHC1 nNaOH 0,55mol

tetrapeptit X 4HCl 3H2O Mui
C : 0,1 0,4 0,3
tripeptit Y 3HCl 2H2O Mui

0,05 0,15 0,1
mA mHCl mH 2 O mmui
mmui 26,2 0,55.36,5 0,4.18 53,475gam
Vy khi lng mui thu c l 53,475gam.
Cu 19: p n C
Phn tch: Cc este c CT C4H6O2 c to ra t axit v ancol tng ng c th c CTCT l: CH2=CH-
COO-CH3; H-COO-CH2-CH=CH2 .
Cu 20: p n A
Phn tch: Glyxin c CTCT l H2N-CH2-COOH.
Cu 21: p n D
Phn tch: Ta coi NaOH tc dng ring vi HCl v axit glutamic
nNaOH nH 2nGlutamic nHCl 0,5mol
Vy s mol NaOH phn ng l 0,5mol.

Cu 22: p n C
Phn tch: Cc cht tc dng vi dung dch NaOH long, un nng l phenylamoni clorua, phenyl
benzoat, t nilon-6, alanin, tripeptit Gly-Gly-Ala, m-crezol, phenol, triolein.
Cu 23: p n A
Phn tch: Bnh nhn phi tip ng Glucoz (tim hoc truyn dung dch ng vo tnh mch).
Cu 24: p n A
Phn tch: D dng nhn thy CH3COOH l axit ch khng phi este.
Cu 25: p n B
nC3H6O2 1
Phn tch: D dng tnh nhanh c nn este X c kh nng tham gia phn ng trng
gng th X l este ca axit fomic. Vy CTCT ca X l HCOOC2H5 .
Cu 26: p n C
Phn tch: Hp cht X c CTCT CH3CH2-COO-C2H5 nn X c tn l etyl propionat.
Cu 27: p n D

Phn tch: Nhng loi t c ngun gc t xenluloz l : si bng(1), si ay(3), t visco(5), t axetat(6).
Cu 28: p n B
Phn tch: Ta c t nitron v t capron l t tng hp; t tm l t thin nhin; t xenluloz axetat l t
nhn to.
Cu 29: p n B
neste nO2 0,05mol
Phn tch:
3,7
Meste 74
0,05
Vy este trn c cc ng phn l HCOOC2H5, CH3COOCH3 .
Cu 30: p n A
Phn tch: Ta t cng thc ca peptit l CnH2n+2-xOx+1Nx v a = 1
nCO2 b n; nH2O c n 1 0,5x
M b - c = a nn n (n 1 0,5x) 1 x 4
Suy ra X l tetra peptit.
X 4NaOH Mui H2O
Ta c :
mrn mNaOH mH2O 0,2.4.2.40 0,2.18 60,4gam
Suy ra
Ch : Nu khng c k l lng NaOH ly gp i so vi lng cn thit th ta s tnh thiu lng
NaOH d sau phn ng cng l cht rn. V d bi ny nu tnh thiu th ta s khoanh ln p n D.
Cu 31: p n C
Phn tch: Este C4H8O2 c to bi ancol metylic th c CTCT l C2H5COOCH3
Cu 32: p n B
Phn tch: T nilon-6,6 l poliamit ca axit aipic v hexametyleniamin
PTHH:

nH2N CH2 6 NH2 nHOOC CH2 4 COOH NH CH2 6 NH CO CH2 4 CO 2nH2O n
Cu 33: p n C
3,52
nC4 H8O2 0,04mol ;
88
4,08 mNaOH d mmui 0,02.40 mmui
mmui 3,28gam Mmui 82
Ta c
CTCT ca mui l CH3COONa CTCT ca A l CH3COOC2H5
Cu 34: p n A
Phn tch: Cao su lu ha c cng cu trc mch polime vi nha bakelit(mch khng gian).
Cu 35: p n D
Phn tch:
Ta c nCO 2
3
1,5.2 2,75 5,75mol

5,75 1
mtinh bt . .162 575gam
2 81%
Vy khi lng tinh bt l 575 gam
Cu 36: p n C
nC4H8O2 1
Phn tch: D dng tnh nhanh c . Cc ng phn l este hoc axit ca C4H8O2 s tc dng
c vi dung dch NaOH. 6 ng phn 2 axit v 4 este) l :
CH3CH2CH2COOH, CH3CH(CH3)COOH, HCOOCH2CH2CH3,
HCOOCH(CH3)CH3, CH3COOCH2CH3, CH3CH2COOCH3 .
Cu 37: p n C
Phn tch: Cc t thuc loi t poliamit l t capron, t nilon-6,6.
Ch : Khi c qu nhanh ta c th nhm t nitron cng thuc loi t poliamit.
Cu 38: p n C
59,4
nxenluloz trinitrat 0,2mol
297
[ C6 H7O2 (OH )3 ] n 3nHNO3 [ C6 H7O2 (ONO2 )3 ] n 3nH2O
0,2.3
nHNO3 0,75mol
80%
mHNO3 47,25gam
C mHNO3 D.VHNO3
1 mHNO3
Vdung dch . 53,57lt
63% D
Cu 39: p n D
nNaOH 2nNa 2 CO3 0,15mo1
Phn tch: D dng tnh c
nancol nmui neste nNaOH 0,15
7,8
M ancol 5,2
0,15
Hai ancol c C2H5OH(M=46) v C3HxO. Da vo 4 p n ta suy ra c ngay ancol cn li phi l
CH2=CH-CH2OH hay C3H6O. Loi p n A v B
nC2H6O a; nC3H6O b
t
a b 0,15
a b 0,075
Ta c : 46a 58b 7,8
meste mmui mancol mNaOH 15g

Ta c (bo ton khi lng)
t cng thc este l RCOOC2H5 v R'COOC3H5.
0,075. R 67 0,075( R' 67) 13, 2R R' 42
Th p n C v D, ta thy p n D tha mn vi R' l gc CH3-(M=15) v R l gc CH2=CH(M=27).

Cu 40: p n C
Phn tch: Nhn thy ngay pht biu C sai v glucoz v fructoz khng phi l ng phn cu to ca
nhau ; pht biu d sai v glucoz b oxi ha bi dung dch AgNO3 trong NH3 to ra Ag ch khng phi b
kh. Pht biu e sai v khi cho Cu(OH)2 tc dng vi glucoz v fructoz nhit cao th cho cht rn
mu gch(Cu2O) ch khng phi dung dch mu xanh lam. Ba pht biu cn li ng.

THPT TRN HNG O Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Mt dung dch c cc tnh cht:

- Ha tan Cu(OH)2 cho phc ng mu xanh lam
- B thy phn khi c mt xc tc axit hoc enzim.
- Khng kh c dung dch AgNO3/NH3 v Cu(HO)2 khi un nng.
Dung dch l:
A. Mantozo B. Fructozo C. Saccarozo D. Glucozo
Cu 2: Cho dy cc cht sau: Saccarozo, glucozo, xenlulozo, fructozo. S cht tham gia phn ng trng
gng l:
A. 1 B. 3 C. 4 D. 2
Glucozo XYCH3COOH. Hai cht X, Y ln lt l
A. CH3CHO v CH3CH2OH B. CH3CH2OH v CH3CHO
C. CH3CH2OH v CH2=CH2 D. CH3CH(OH)COOH v CH3CHO
Cu 4: Saccarozo c th tc dng vi cc cht no sau y?
A. H2O/H+, to ; Cu(HO)2, to thng B. Cu(HO)2, to thng ; dd AgNO3/NH3
C. Cu(HO)2, un nng; dd AgNO3/NH3 D. Ln men; Cu(HO)2, un nng
Cu 5: X l mt este no n chc, c t khi hi so vi He l 22. Nu em un 4,4 gam este X vi dd NaOH
d, thu c 4,1 gam mui. Cng thc cu to thu gn ca X l (He=4, C=12, H=1, O=16)
A. C2H5COOCH3 B. CH3COOC2H5 C. HCOOCH(CH3)2 D. HCOOCH2CH2CH3
Cu 6: Khi t chy hon ton 1 amin n chc X, ngi ta thu c 12,6 g H2O, 8,96 lt kh CO2 v
2,24 lt N2 (cc th tch kh o c ktc). X c cng thc phn t l (N=14, C=12, H=1, O=16):
A. C3H9N B. C2H7N C. C4H11N D. C5H13N
Cu 7: Trung ha hon ton 4,44 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit
HCl, to ra 8,82 gam mui. Amin c cng thc l (N=14, C=12, H=1)
A. H2NCH2CH2CH2CH2NH2 B. CH3CH2CH2NH2
C. H2NCH2CH2NH2 D. H2NCH2CH2CH2NH2
Cu 8: Khi t chy hon ton este no n chc, mch h th s mol CO2 sinh ra bng s mol O2
phn ng. Tn gi ca este l:
A. metyl fomiat B. propyl axetat C. metyl axetat D. etyl axetat
Cu 9: Thy phn hon ton 150 gam dung dch saccarozo 10,26% trong mi trng axit va ta thu
c dung dch X. Cho dung dch AgNO3 trong NH3 vo dung dch X v un nh th khi lng Ag thu
c l (H=1, c=12, O=16, Ag=108)
A. 36,94 g B. 19,44 g C. 15,50 g D. 9,72 g
Cu 10: Cho 27,2 g hn hp gm pheylaxetat v metylbenzoat (c t l mol l 1:1) tc dng vi 800 ml
dd NaOH 0,5M thu c dd X. C cn dd X th khi lng cht rn thu c l (C=12, H=1, O=16,
Na=23)
A. 36,4 B. 40,7 C. 38,2 D. 33,2
Cu 11: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5-
l gc phenyl). Dy cc cht sp xp heo th t lc bazo gim dn l:
A. (4), (1), (5), (2), (3) B. (3), (1), (5), (2), (4)
C. (4), (2), (3), (1), (5) D. (4), (2), (5), (1), (3)
Cu 12: Nhng phn ng ha hc no chng minh rng glucozo c cha 5 nhm hydroxyl trong phn t:
A. Phn ng to 5 chc este trong phn t
B. Phn ng trng gng v phn ng ln men ru

C. Phn ng to kt ta gch vi Cu(OH)2 khi un nng v phn ng ln men ru
D. Phn ng cho dung dch mu xanh lam nhit phng vi Cu(OH)2
Cu 13: Hp cht hu c X c CTPT C9H10O2. ung nng X vi dd NaOH d thu c hn hp 2 mui.
CTCT ca X l:
A. CH3CH2COOC6H5 B. CH3-COOCH2C6H5
C. HCOOCH2CH2C6H5 D. HCOOCH2C6H4CH3
Cu 14: Thy phn hon ton hn hp gm hai este n chc X, Y l ng phn cu to ca nhau cn
100 ml dd NaOH 1M, thu c 7,85 g hn hp mui ca hai axit l ng ng k tip nhau v 4,95 g hai
ancol bc I. CTCT v % khi lng ca 2 este l (Na=23, O=16, C=12)
A. HCOOC2H5, 45%; CH3COOCH3, 55%
B. HCOOCH2CH2CH3, 75%; CH3COOC2H5, 25%
C. HCOOCH2CH2CH3, 25%; CH3COOC2H5, 75%
D. HCOOC2H5, 55%; CH3COOCH3, 45%
Cu 15: Este c CTPT C4H8O2, tham gia phn ng trng bc c tn l: (1) Etylfomat; (2) metylxetat; (3)
propylfomat; (4) isopropylfomat; (5) etylaxetat
A. 1, 3, 4 B. 3, 4 C. 2, 3, 4 D. 1, 3, 5
Cu 16: Ancol etylicc c iu ch t tinh bn bng phng php ln men vi hiu sut ton b qu
trnh l 90%, hp th ton b lng CO2, sinh ra khi ln men m gam tinh bt vo dung dch Ba(OH)2 d,
thu c 400 gam kt ta v dung gijch X. Bit khi lng X giarm i so vi khi lng dung dch ban
u l 259,2 gam. Gi tr ca m l (H=1, C=12, O=16, Ca=40)
A. 405 B. 324 C. 360 D. 288
Cu 17: Cho dy cc cht: stiren. Phenol, toluene, anilin, metyl amin. S cht trong dy tc dng c
vi dung dch brom l
A. 5 B. 3 C. 4 D. 2
Cu 18: un nng este: CH2=CHCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c
l:
A. CH3COONa v CH3CHO B. C2H5COONa v CH3OH
C. CH3COONa v CH2=CHOH D. CH2=CHCOONa v CH3OH
Cu 19: Nhn xt no sau y ng?
A. Glucozo tc dng c vi sudng dujch nc brom to thnh mui amoni gluconat
B. Glucozo c rt nhiu trong mt ong (khong 40%)
C. Xenlulozo tan c trong dung dch Cu(OH)2/NaOH to dung dch xanh lam v trong mi mt xch
ca xenlulozo c 3 nhm OH t do
D. t chy saccarozo thu c s mol CO2 ln hn s mol H2O
Cu 20: phn bit tinh bt v xenlulozo ta dng:
A. phn ng mu vi dung dch I2
B. phn ng vi Cu(OH)2 nhit phng
C. phn ng trng bc
D. phn ng thy phn
Cu 21: Cho m gam glucozo ln men thnh ancol etylic vi hiu sut 60%. Hp th hon ton kh CO2
sinh ra vo nc vi trong d thu c 30 gam kt ta. Gi tr ca m l (H=1; O=16; Ca=40; C=12)
A. 45 B. 22,5 C. 11,25 D. 14,4
Cu 22: Pht biu no di y ng?
A. thy phn tinh bt thu c fructozo v glucozo
B. c xenlulozo v tinh bt u c phn ng trng bc
C. thy phn xenlulozo thu c glucozo
D. fructozo c phn ng trng bc, chng t trong phn t fructozo c nhm chc CHO
Cu 23: B l este c CTPT C8H8O2, c iu ch t axit v ancol tng ng v khng tham gia phn
ng trng gng. CTPT ca B l:
A. C6H5COOCH3 B. HCOOC6H4CH3 C. HCOOCH2C6H5 D. CH3COOC6H5
Cu 24: Metyl fomat c CTPT l:
A. CH3COOCH3 B. CH3COOC2H5 C. HCOOC2H5 D. HCOOCH3
Cu 25: Cht no di y khng phi l este
A. CH3COOCH3 B. HCOOCH3 C. HCOOC6H5 D. CH3COOH
Cu 26: Hp cht X c cng thc cu to CH3CH2 COO CH3. Tn gi ca X l

A. vinyl axetat B. etyl propionat C. metyl propionat D. metyl metacrylat
Cu 27: S ng phn amin bc 1 c cng cng thc phn t C5H13N l
A. 6 B. 9 C. 7 D. 8
Cu 28: Cho este c cng thc cu to: CH2=C(CH3)COOCH3. Tn gi ca este l
A. Metyl metacrylic B. Metyl acrylat C. Metylacrylic D. Metyl metacrylat
Cu 29: Bng di y ghi li hin tng khi lm th nghim vi cc cht sau dng dung dch X, Y, Z,
T
Cht X Y Z T
Thuc th
Dd AgNO3/NH3, to Kt ta bc Khng hin Kt ta bc Kt ta bc
tng
Dd nc brom Mt mu Khng hin Khng hin Mt mu
tng tng
Thy phn Khng b thy B thy phn Khng b thy B thy phn
phn phn
Cht X,Y,Z,T ln lt l
A. fructozo, xenlulozo, glucozo v saccarozo
B. mantozo, saccarozo, fructozo, glucozo
C. glucozo, saccarozo, fructozo, mantozo
D. saccarozo, glucozo , mantozo , fructozo
Cu 30: Ln men 162 gam bt np (cha 80% tinh bt). Hiu sut qu trnh ln men l 55%. Lng
ancol etylic thu c em pha long thnh V (lt) ancol 230. Bit khi lng ring cu ancol nguyn cht
l 0,8g/ml. Gi tr V l (H=1; C=12; O=16)
A. 220 B. 275 C. 0,220 D. 0,275
Cu 31: S ng phn este ng vi CTPT C4H8O2 l
A. 4 B. 5 C. 3 D. 6
Cu 32: Cht no sau y thuc loi amin bc 1?
A. (CH3)3N B. CH3NHCH3 C. CH3NH2 D. CH3CH2NHCH3
Cu 33: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c
X,Y. T X c th iu ch trc tip xa Y. Vy cht X l:
A. axit fomic B. etyl axetat C. ancol etylic D. ancol metylic
Cu 34: Pht biu no sau y ng?
A. Tt c cc amin u lm qu tm m chuyn mu xanh
B. ra sch ng nghim c dnh anilin, c th dng HCl
C. nhit thng, tt c cc amin u tan nhiu trong nc
D. Cc amin u khng c, c s dng trong ch bin thc phm
Cu 35: Cho bit cht no sau y thuc monosacarit
A. saccarozo B. glucozo C. xenlulozo D. tinh bt
Cu 36: ng vi cc cng thc phn t C5H10O2 c bao nhiu este ng phn ca nhau tham gia phn
ng trng bc?
A. 2 B. 9 C. 4 D. 5
Cu 37: Cho 27,9g anilin tc dng vi dung dch brom, phn ng xy ra hon ton to 49,5g kt ta.
Khi lng brom trong dung dch brom ban u l (N=14; C=12; H=1; Br=80)
A. 72g B. 24g C. 48g D. 144g
Cu 38: t chy m gam hn hp X gm etyl axetat. Axit acrylic v andehit axetic ri cho ton b sn
phm chy hp th ht vo bnh ng nc vi trong d thu c 45 gam kt ta v khi lng bnh
nc vi trong tng 27 gam. S mol axit acrylic c trong m gam hn hp X l(cho Ca=40; C=12; O=16,
H=1)
A. 0,050 B. 0,025 C. 0,150 D. 0,100
Cu 39: Mt cht hu c A c CTPT C3H6O2 tha mn: A tc dng c dd NaOH un nng v dd
AgNO3/NH3, to. Vy A c CTCT l:
A. HOC CH2 CH2OH B. H COO C2H5
C. CH3 COO CH3 D. C2H5COOH
(a) Cht bo c gi chung l triglixerit hay triaxyglixerol

(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong cc dung mi hu c
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch
(d) Tristearin, triolein c CT ln lt l (C17H33COO)3C3H5, (C17H35COO)3C3H5
(e) Triolein c kh nng tham gia phn ng cng hidro khi un nng c xc tc Ni
(f) Cht bo b thy phn khi un nng trong dd kim
S pht biu ng l:
A. 3 B. 5 C. 4 D. 6
p n
1-C 6-B 11-D 16-D 21-A 26-C 31-A 36-C
2-D 7-D 12-A 17-B 22-C 27-D 32-C 37-A
3-B 8-A 13-A 18-D 23-A 28-D 33-C 38-A
4-A 9-B 14-C 19-D 24-D 29-C 34-B 39-B
5-B 10-C 15-B 20-A 25-D 30-C 35-B 40-B
Cu 1.
Fructozo l glucozo khng c phn ng thy phn
Mantozo kh c AgNO3/NH3 v Cu(OH)2 khi un nng
C
Cu 2.
Cc cht tha mn: glucozo, fructozo
D
Cu 3.
S hon chnh: glucozo CH3CH2OH CH3CHO CH3COOH
Cc phng trnh phn ng:
C6H12O6 2C2H5OH + 2CO2
C2H5OH + CuO(t0C) CH3CHO + Cu + H2O
CH3CHO + [O] (t0C) CH3COOH
B
Cu 4. A
Cu 5. MX = 22.NHe = 88g nX = 0,05 mol
Phng trnh tng qut: RCOOR + NaOH RCOONa + ROH
nRCOONa= nX = 0,05 mol MRCOONa = 82g
R = 15 (CH3)
X l CH3COOC2H5
B
Cu 6.
X l amin n chc nn ch c thnh phn: C; H; N
Bo ton nguyn t:
nC = nCO2 = 0,4 mol; nH = 2nH2O = 1,4 mol; nN = 2nN2 = 0,2 mol
nC : nH : nO = 0,4 : 1,4 : 0,2 = 2 : 7 : 1
Amin tha mn l: C2H7N
B
Cu 7.
V amin bc 1 kkhoong phn nhnh amin ti a ch c 2 nhm NH2
Tng qut amin bc 1:
R(NH2)n + nHCl R(NH3Cl)n
(R+16n) (R+52,5n)
4,44g 8,82g
4,44.(R + 52,5n) = 8,82.(R + 16n)
R = 21n
Nu n = 1 R = 21 Khng c trng hp tha mn

Nu n = 2 R = 42 -CH2-CH2-CH2-
Amin l H2N-CH2-CH2-CH2-NH2
D
Cu 8.
Este no mch h th trong phn t ch c 1 lin kt pi CnH2nO2
CnH2nO2 + (1,5n 1)O2 nCO2 + nH2O
Theo bi: nO2= nCO2 n = 1,5n 1 n =2
Este l C2H4O2 : HCOOCH3
A
Cu 9.
nsaccarozo = 0,045 mol
Saccarozo glucozo + fructozo
C glucozo v fructozo u phn ng vi AgNO3
Glucozo/Fructozo 2Ag
nAg = 2nglucozo + 2nfructozo = 4nsaccarozo = 0,18 mol
mAg = 19,44g
B
Cu 10.
nNaOH = 0,4 mol
Trong hn hp c: CH3COOC6H5 v C6H5COOCH3 vi cng s mol l 0,1 mol
CH3COOC6H5 + 2NaOH CH3COONa + C6H5ONa + H2O
C6H5COOCH3 + NaOH C6H5COONa + CH3OH
Sau phn ng cht rn gm: 0,1 mol CH3COONa; 0,1 mol C6H5ONa; 0,1 mol C6H5COONa; 0,1 mol NaOH
d
mrn = 38,2g
C
Cu 11.
Cc nhm ht e (C6H5;) lm gim lc bazo
Cc nhm y e (R no;) lm tng lc bazo
Lc bazo: (C6H5)2NH < C6H5NH2 < NH3 < C2H5NH2 < (C2H5)2NH
D
Cu 12. A
Cu 13.
X c s (pi + vng) = 5. V X ch c 2O 1 nhm COO
X + NaOH to mui th X phi l este ca phenol
Ch c CH3CH2COOC6H5 tha mn
A
Cu 14.
Bo ton khi lng: meste = mmui + mancol - mNaOH = 8,8g
nNaOH = neste = naxit = 0,1 mol (v este n chc)
Meste = 88g (C4H8O2)
Mtb(mui) = 78,5g 2 axit ng ng k tip l: HCOOH v CH3COOH
2 este l HCOOCH2CH2CH3 v CH3COOCH2CH3 vi s mol l x v y
x + y = 0,1 mol; mmui = 68x + 74y = 7,85g
x = 0,025; y = 0,075 mol
%mHCOOC3H7 = 25%; %mCH3COOC2H5 = 75%
C
Cu 15.
C4H8O2 ch c 3 cht 3, 4, 5. Trong ch c 3 v 4 l c phn ng trng bc nh c nhm CHO (gc
HCOO-)
B
Cu 16.
Ba(OH)2 + CO2 BaCO3 + H2O
Ba(OH)2 + 2CO2 Ba(HCP3)2
mX gim so vi ban u = mBaCO3 mCO2 = 140,8g

nCO2 = 3,2 mol
(C6H10O5)n nC6H10O6 2nCO2
ntinh bt = 288g
D
Cu 17.
Cc cht tha mn: stiren; phenol; anilin
B
Cu 18. D
Cu 19.
A sai v: Glucozo + nc Brom to axit gluconic
B sai v: Fructozo mi c nhiu trong mt ong
C sai v: Xenlulozo khng tan trong dung dch Cu(OH)2/NaOH
D
Cu 20.
Tinh bt mi c phn ng vi I2 cn xenlulozo th khng
A
Cu 21.
nCO2 = nCaCO3 = 0,3 mol
C6H12O6 2CO2
nC6H12O6 = 0,15 mol Thc t cn dng: n = 0,15.100/60 = 0,25 mol
m =45g
A
Cu 22.
A sai v: thy phn tinh bt ch to glucozo
B sai v: c xenlulozo v tinh bt u khng c phn ng trng bc
D sai v: fructozo khng c nhm CHO nhng trong mi trng bazo th fructozo chuyn thnh glucozo
C
Cu 23.
B iu ch t ancol khng th l este ca phenol
B khng c phn ng trng bc khng c gc HCOO
A
Cu 24. D
Cu 25. D
Cu 26. C
Cy 27.
C5H13N c cc ng phn bc 1:
C C C C C NH2
C C C C(CH3) NH2
C C C(CH3) C NH2
C C(CH3) C C NH2
C C C(CH3)2 NH2
(CH3)3C C NH2
(C2H5)2C NH2
C C(CH3) C(CH3) NH2
D
Cu 28. D
Cu 29.
X khng b thy phn loi mantozo v saccarozo
X lm mt mu nc brom loi fructozo
C
Cu 30.
(C6H10O5)n nC6H12O6 2nX2H5OH
nC2H5OH = (2n).ntinh bt.H% = 0,88 mol
VC2H5OH = m/D = 0,88.46/0,8 = 50,6 ml
Vru = 50,6.100/23 = 220 ml = 0,22 lt

C
Cu 31.
Cc ng phn este:
HCOOCH2CH2CH3; HCOOCH(CH3)2
CH3COOC2H5; C2H5COOCH3
A
Cu 33.
Bc ca amin = s nhm hidrocacbon gn vo N
C
Cu 33.
X : C2H5OH; Y : CH3COOH
Este: CH3COOC2H5
C2H5OH + 2[O] CH3COOH + H2O
C
Cu 34.
A sai v: cc amin c nhm ht e nh C6H5NH2 khng lm i mu qu tm
C sai v: nhit thng, anilin khng tan trong nc
D sai v: C6H5NH2 l 1 cht c
B
Cu 35. B
Cu 36.
Este khng tham gia phn ng trng bc phi c nhm HCOO- :
HCOO-C-C-C-C; HCOO-C(CH3)-C-C; HCOO-C-C(CH3)-C; HCOO-C(CH3)3
C
Cu 37.
C6H5NH2 + 3Br2 H2NC6H2Br3 + 3HBr
nkt ta = 0,15 mol < nanilin = 0,3 mol anilin d
nBr2 = 0,45 mol mBr2 = 72g
A
Cu 38.
X gm: CH3COOC2H5(C4H8O2); C2H3COOH(C3H4O2); CH3CHO(C2H4O)
Quy hn hp v: x mol C2H4O v y mol C3H4O2
Sau hi t chat: mbnh tng = mspc = 27g
nCO2 = nCaCO3 = 0,45 mol nH2O = 0,4 mol
nCO2 = 2x + 3y = 0,45; nH2O = 2x + 2y = 0,4
x = 0,15; y = 0,05 mol
A
Cu 39. B
Cu 40.
(d) sai v: tristearin, triolein c CT ln lt l (C17H35COO)3C3H5, (C17H33COO)3C3H5
B

THPT THUN THNH I Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Thy phn hon ton m gam triolein trong dung dch NaOH d, un nng. Sau phn ng hon
ton thu c 22,8 gam mui (x phng). Gi tr ca m l:
A. 21,5 B. 22,4 C. 21,8 D. 22,1
(a) Cho Mg vo dung dch Fe2 (SO4)3 d
(b) Sc kh Cl2vo dung dch FeCl2
(c) Dn kh H2 d qua bt CuO nung nng
(d) Cho Na vo dung dch CuSO4 d
(e) Nhit phn AgNO3
(g) t FeS2 trong khng kh
(h) in phn dung dch CuSO4 vi in cc tr.
Sau khi kt thc cc phn ng. S th nghim thu c kim loi l:
A. 4 B. 5 C. 2 D. 3
Cu 3: : Nung hn hp X gm Al v Fe3O4 c t l khi lng 1:1, sau khi cc phn ng hon ton thu
c cht rn Y Thnh phn ca cht rn Y
A. Al2O3, Fe, Al B. Al2O3, Fe, Fe3O4 C. Al2O3, FeO, A D. Al2O3, Fe
Cu 4: Cho hn hp bt gm Al, Cu vo dung dch cha AgNO3 v Fe(NO3)3 sau phn ng hon ton
thu c cht rn X gm hai kim loi v dung dch Y cha 3 mui. Cc cation trong dung dch Y l:
A. Fe3+, Ag+, Cu2+ B. Al3+, Fe2+, Cu2+ C. Al3+, Fe3+, Cu2+ D. Al3+,Fe3+,Fe2+
Cu 5: : in phn (vi in cc tr v mng ngn) dung dch cha 0,05 mol CuSO4 v x mol KCl bng
dng in c cng 5A, sau mt thi gian, thy khi lng dung dch gim 9,475 gam. Dung dch thu
c tc dng vi Al d, phn ng gii phng 1,68 lt kh H2(ktc). Thi gian in phn l:
A. 2895 giy B. 3860 giy C. 5790 giy D. 4825 giy
Cu 6: : Trong dy kim loi: Al, Cu, Au, Fe. Kim loi c tnh do ln nht l
A. Fe B. A C. Au D. Cu
Cu 7: Cho cc ng dng:
1) Dng lm dung mi
2) Dng trng gng
3) Dng lm nguyn liu sn xut cht do, dng lm dc phm
4) Dng trong cng nghip thc phm Nhng ng dng no l ca este.
A. 1, 2, 3 B. . 1, 2, 4 C. 1, 3, 4 D. 2, 3, 4
Cu 8: : Ln men m gam glucoz thu c etanol v kh CO2 (hiu sut t 72%). Hp th ht kh CO2
bng nc vi trong thu c 40 gam kt ta v khi lng dung dch gim 4,8 gam. Gi tr ca m l:
A. 135,0 B. 90,0 C. 100,0 D. 120,0
Cu 9: : Cht no sau y khng to kt ta khi cho vo dung dch AgNO3?
A. HCl B. H3PO4 C. . H2S D. HBr
Cu 10: : Nhm chc no sau y c trong tristearin?
A. . este B. anehit C. anco D. axit
Cu 11: Cho cc dung dch sau: Ba(HCO3 )2,NaOH,AlCl3,KHSO4 c nh s ngu nhin l X, Y, Z,
T. Tin hnh cc th nghim sau:
Ha cht X Y Z T
Qu tm xanh xanh
Dung dch HCl Kh bay ra ng nht ng nht ng nht

Dung dch Kt ta trng,
Kt ta trng Kt ta trng ng nht
Ba(OH)2 sau tan
Dung dch cht Y l
A. KHSO4 B. . NaOH C. AlCl3 D. Ba(HCO3 )2
Cu 12: Cho ming hp kim Fe-C vo dung dch HCl long, khi xy ra qu trnh n mn in ha hc
ng vi s to thnh pin in. Ti cc dng xy ra qu trnh:
A. Fe 2 2e Fe B .Fe Fe 2 2e
C. 2 H 2O 4 H O2 4e D. 2 H 2e H 2
Cu 13: Cht no sau y i mu qu tm sang xanh?
A. anilin B. etylamin C. alanin D. glyxin
Cu 14: Amino axit X no, mch h c cng thc phn t CmHmO4N. Mi quan h gia m vi n l:
A. m 2n 1 B. m 2n 2 C. m 2n 1 D. m 2n
Cu 15: Pht biu no sau y khng ng?
A. . Cc cht bo thng khng tan trong nc v nh hn nc
B. Cht bo l este ca etilenglicol vi cc axit bo
C. Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni
D. Cht bo b thy phn khi un nng trong dung dch kim
Cu 16: Cht no sau y i mu qu tm sang xanh?
A. anilin B. etylamin C. alanin D. glyxin
Cu 17: : Cho dy cc kim loi: Na, Ba, Al, K, Mg. S kim loi trong dy phn ng vi lng d dung
dch FeCl3 thu c kt ta l:
A. 5 B. 3 C. 2 D. 4
Cu 18: Cho 1,37 gam Ba vo 100,0 ml dung dch Al2(SO4)3 0,03M thu c cht rn c khi lng l:
A. 2,205 B. 2,565 C. 2,409 D. 2,259
Cu 19: Cho 0,1 mol amino axit X c cng thc dng R(NH2)(COOH)2 vo dung dch H2SO4 1,5M thu
c dung dch Y. tc dng ht vi cht tan trong dung dch Y cn dng dung dch NaOH 1M v
KOH 1,5M, sau phn ng thu c dung dch cha 43,8 gam hn hp mui. Cng thc ca X l
A. C4H7(NH2)(COOH)2 B. C5H9(NH2)(COOH)2
C. C3H5(NH2)(COOH)2 D. C2H3(NH2)(COOH)2
Cu 20: T visco thuc loi:
A. T bn tng hp B. T thin nhin C. T tng hp D. T poliamit
Cu 21: Ha tan hon ton mt loi qung trong s cc qung hematit, manhetit, xierit, pirit, Trong
dung dch HNO3 c, d un nng thu c kh NO2 (kh duy nht thot ra) v dung dch X. Cho dung
dch BaCl2 d vo dung dch X, khng thy xut hin kt ta. Qung ha tan l:
A. Pirit B. Manhetit C. Xierit D. Hematit
Cu 22: Ha cht no sau y c th s dng lm mm nc cng cha nhiu Ca2+ v Cl- ?
A. Ca(OH)2 B. . NaOH C. HCl D. Na2CO3
Cu 23: Thuc th phn bit trc tip cc dung dch: HCl, H2SO4, NaOH l:
A. dung dch BaCl2 B. bt nhm
C. dung dch Ba(HCO3 )2 D. dung dch NaHCO
Cu 24: Tu bin vi lp v thp d b n mn bi mi trng khng kh v nc bin. bo v cc
tu thp ngoi vic sn bo v, ngi ta cn gn vo v tu mt s tm kim loi. Tm kim loi l:
A. thic B. ng C. ch D. km
Cu 25: : Cht X c cng thc phn t l C4H8O2N. Cho 10,3 gam X tc dng va vi NaOH th thu
c 9,7 gam mui. Cng thc ca X l:
A. CH2 = CH COONH3 CH3 B. H2N C3H6 COOH
C.H2N CH2 COO C2H5 D. H2N C2H4
COO CH3
Cu 26: : Nh t t V lt dung dch cha Ba(OH)2 0,5 M vo
dung dch cha x mol NaHCO3 v y mol BaCl2. th sau y
biu din s ph thuc gia lng kt ta v th tch dung dch
Ba(OH)2 nh sau:
Gi tr ca x v y tng ng l:
A. 0,1 v 0,05 B. 0,2 v 0,05 C.C. 0,4 v 0,05 D. 0,2 v 0,10

Cu 27: Cho 33,2 gam hn hp X gm Fe, Fe3O4, Cu, CuO vo 500 ml dung dch HCl 2M, thu c 1,6
gam cht rn, 2,24 lt kh H2 (ktc) v dung dch Y. Cho dung dch AgNO3 d vo dung dch Y, thu c
0,56 lt kh NO (ktc) v m gam kt ta. Gi tr ca m l:
Cu 28: Cho 40 gam hn hp X gm Fe3O4 v Cu vo dung dch HCl thu c dung dch Y cha hai
cht tan v cn li 16,32 gam cht rn. Cho dung dch AgNO3 d vo dung dch Y thu c m gam cht
rn. Cc phn ng xy ra hon ton. Gi tr ca m gn nht vi gi tr no sau y?
A. 124 B. 118 C. 108 D. 112
Cu 29: : Cho cc pht biu sau:
(1) Trong cc phn t amin, nht thit phi cha nghuyn t nit.
(2) Cc amin cha t 1C n 4C u l cht kh iu kin thng.
(3) Trong phn t ipeptit mch h c cha hai lin kt peptit.
(4) Trong phn t metylamoni clorua, cng ha tr cu nit l IV.
(5) Dung dch anilin lm mt mu nc brom.
Nhng pht biu ng l:
A. (1), (3), (5) B. (1), (2), (3) C. (2), (4), (5) D. (1), (4), (5)
Cu 30: Thy phn tetrapeptit X mch h thu c hn hp cc -amino axit (no, mch h, phn t u
cha 1 nhm NH2 v 1 nhm COOH). Mt khc, t chy hon ton m gam X bng CuO d, un
nng thy khi lng CuO gim 3,84 gam. Cho hn hp kh v hi sau phn ng vo dung dch NaOH
c, d thy thot ra 448 ml kh N2 (ktc). Thy phn hon ton m gam X trong dung dch HCl d, un
nng thu c mui c khi lng l:
A. 5,12 B. 4,74 C. 4,84 D.4,52
Cu 31: : Phn ng no sau y thu c sn phm l este?
A. (CH3CO)2O + C6H5OH (phenol) B. C H OH HCHO/OH-, t0
C. CH3COOH + CH3NH2 D. C6H5OH + HNO3 c/ xt H2SO4 c
Cu 32: Cho 14,7 gam axit glutamic vo dung dch H2SO4 0,5M v HCl 1M, thu c dung dch X cha
19,83 gam cht tan. Th tch dung dch NaOH 1M v KOH 0,6M cn ly phn ng va vi cht tan
trong dung dch X l:
A. 200,0 ml B. 225,0 ml C. 160,0 ml D. . 180,0 ml
Cu 33: Th tch dung dch NaOH 1M cn cho vo dung dch cha 0,15 mol Ba(HCO3)2 v 0,1 mol BaCl2
thu c kt ta c khi lng ln nht l:
A. 300 ml B. 150 ml C. 250 ml D. 200 ml
Cu 34: Dung dch X cha 0,15 mol H2SO4 v 0,1 mol Al2(SO4)3. Cho V ml dung dch NaOH 1M vo
dung dch X, thu c m gam kt ta. Thm tip 450 ml dung dch NaOH 1M vo, sau khi cc phn ng
xy ra hon ton thu c 0,5m gam kt ta. Gi tr ca 1 V l:
A. 550,0 ml B. 500,0 ml C. 600,0 ml D. 450,0 ml
Cu 35: Hn hp X gm 2 este mch h (ch cha chc este). Thy phn hon ton hn hp X trong
dung dch NaOH un nng, sau phn ng thu c m gam mui natri axetat v 10,8 gam hn hp Y gm
2 ancol no, mch h c cng s nguyn t cacbon. t chy hon ton 10,8 gam hn hp Y thu c
8,96 lt kh CO2 (ktc) v 10,8 gam H2O. Gi
A. 20,5 B. 32,8 C. 16,4 D. 24,6
Cu 36: Cho dy cc cht sau: etyl axetat, triolein, t visco, saccaroz, xenluloz, fructoz. S cht
trong dy thy phn trong dung dch axit l:
A. 4 B. 3 C. 6 D. 5
Cu 37: Cho m gam X gm Na, Na2O, Al, Al2O3 vo nc d thy tan hon ton, thu c dung dch Y
cha mt cht tan v thy thot ra 4,48 lt kh H2 (ktc). Sc kh CO2 d vo dung dch Y, thu c 15,6
gam cht rn X. Gi tr ca m l:
A. . 14,2 B. 12,2 C. . 13,2 D. 11,2
Cu 38: Cho m gam bt st vo 200 ml dung dch CuSO4 1M, sau phn ng hon ton thu c cht rn
X. Chia X thnh 2 phn khng bng nhau: Phn 1: cho tc dng vi dung dch HCl d thy thot ra 2,24
lt kh H2 (ktc). Phn 2: cho tc dng vi dung dch HNO3 long d, thu c 6,72 lt kh NO (ktc). No
l sn phm kh duy nht ca HNO3.
Gi tr ca m gn vi gi tr no nht?
A. 24,0 B. 30,8 C. 28,2 D. 26,4

Cu 39: : Geranyl axetat l mt este n chc, mch h c mi hoa hng. X tc dng vi Br2 trong CCl4
theo t l mol 1:2. Trong phn t X, cacbon chim 73,47% theo khi lng. Tng s nguyn t c trong
phn t geranyl axetat l:
A. 34 B. 32 C. 28 D. 30
Cu 40: Dung dch X cha 19,5 gam hn hp etylamin v glyxin tc dng va vi 200 ml dung dch
KOH 1M. Hy cho bit dung dch X tc dng va vi bao nhiu ml dung dch HCl 1M?
A. 200ml B. 300ml C. 350ml D. 250ml
p n
1- 6- 11- 16- 21- 26- 31- 36- 41- 46-
2- 7- 12- 17- 22- 27- 32- 37- 42- 47-
3- 8- 13- 18- 23- 28- 33- 38- 43- 48-
4- 9- 14- 19- 24- 29- 34- 39- 44- 49-
5- 10- 15- 20- 25- 30- 35- 40- 45- 50-
Cu 1: p n D
PTHH : C17 H 33COO 3 C3 H 5 3NaOH
t0
3C17 H 33COONa C3 H 5 OH 3
22,8 n
nmuoi 0, 075 mol mtriolein muoi .884 0,075 3.884 22,1 gam
304 3
Vy m = 22,1 (gam)
Cu 2: p n D
Phn tch: a)Khi sc Mg vo dung dch Fe2(SO4)3 d ta ch c duy nht mt phn ng xy ra:
Mg Fe2 SO4 3 MgSO4 2FeSO4
- Nu l trng hp sc Mg d vo dung dch Fe2(SO4)3 th sau khi xy ra phn ng trn, Mg tip tc tc
dng vi mui FeSO4 sinh ra kim loi Fe theo phng trnh Mg FeSO4 MgSO4 Fe . Kt thc phn
ng ta thu c hai kim loi l Fe v Mg d
b) Mui st(II) d b oxi ha thnh mui st(III) bi cc cht oxi ha :
Cl2 2 FeCl2 2FeCl3
c) Khi un nng, CuO d b H2 , CO, C kh thnh ng kim loi:
H 2 CuO H 2O Cu
0
t
d) Khi cho Na vo dung dch CuSO4 d,ta c

1
1 Na H 2O NaOH H 2 2 2NaOH CuSO4 Na2 SO4 Cu OH 2
2
e) Nhit phn AgNO3 ,ta c PTHH
1
AgNO3 t0
Ag NO2 O2
2
f) Khi t FeS2 trong khng kh, ta c : 4 FeS2 11O2
t0
2 Fe2O3 8SO2
1
g) in phn CuSO4 vi in cc tr : CuSO4 H 2O Cu O2 H 2 SO4
2
Vy cc th nghim thu c kim loi sau khi kt thc phn ng l : c, e v g.
Cu 3: p n A
Phn tch:
t mAl mFe3O4 232 gam
PTHH: 8Al+ 3Fe3O4 t 0 4Al2O3 + 9Fe
232
Ban u mol 1mol
27
72
Phn ng mol 1mol
27
Suy ra sau phn ng Al d.
Vy hn hp cht rn Y sau phn ng thu c l Al , Al2O3 v Fe .

Ch : xc nh cc cht sau phn ng trong phn ng nhit nhm, ta vit phng trnh v tnh s mol
trc v sau phn ng
Cu 4: p n B
Al AgNO3 Ran X(2 kim loai )
C :
Cu Fe NO3 3 Dung dch Y(3 muo i)
Al 3 Fe2 Cu 2 Fe3 Ag
Dy in ha ca kim loi:
Al Fe Cu Fe2 Ag
X chc chn c Ag v mt kim loi na trong ba kim loi Al, Fe, Cu. Khi th bt k l kim loi no trong
ba kim loi cng s y ht mui Fe3+ thnh mui Fe2+ nn trong dung dch Y khng tn ti cation Fe3+.
n y, ta thy ch duy nht p n B tha mn.
Cu 5: p n D
Phn tch:
1, 68
nH 2 0, 075 mol
22, 4
Ta c :
Ti cc + : , ,
+
2x x 2x
+ + +
2a a 4a 4a
Ti cc (-) : +, , +
+ +
0,05 0,1 0,05
+ +
2b 2b b 2b
Dung dch thu c sau in phn tc dng vi Al d, gii phng kh H2 chng t n phi cha KOH
hoc H2SO4.
TH1: H+ d
Ta c
3
nH nOH 2nH 2 0,15 v 3H Al Al 3 H 2 4a 2b 0,15 1
2
p dng phng php bo ton e, ta c : 2 x 4a 0,1 2b 2
Ta c khi lng dung dch gim l : mCu mCl2 mH 2 mO2 9, 475
71x 2b 32a 6, 275 3
T (1), (2) v (3) ta c h:
4a 2b 0,15 a 0, 025

4a 2b 2 x 0,1 b 0, 075
32a 2b 71x 6, 275 x 0, 075

t F 0, 25.96500
Ta c : ne I . t ne . 4825 s .
F I 5
Cu 6: p n C
Tnh do ca kim loi : Au Al Cu Ag Sn ...
Cu 7: p n C
Phn tch: Cc ng dng ca este l
(1) Do c kh nng ha tan tt nhiu cht nn mt s este c dng lm dung mi tch, chit cht hu
c ( etyl axetat ), pha sn ( butyl axetat ) ,...
(3) Mt s polime ca este c dng sn xut cht do.
(4) Mt s este c mi thm, khng c, c dng lm cht to hng trong cng nghip thc phm , m
phm ,...
Cu 8: p n C

Khi lng dung dch gim l: mCaCO3 mCO2 4,8
mCO2 40 4,8 35, 2 g nCO2 0,8 mol
nCO2 1 5 5
Ta c nGlucozo . mol mGlu .180 100 gam
2 H% 9 9
Vy m = 100 gam.
Cu 9: p n B
Phn tch:
A.AgNO3 + HCl HNO3 + AgCl (trng)
B.3AgNO3 + H3PO4 3HNO3 + Ag3PO4 . Nhng sau , Ag3PO4 tan trong axit HNO3 .
C.2AgNO3 + H2S 2HNO3 + Ag2S (en)
D.AgNO3 + HBr HNO3 + AgBr (vng nht)
Cu 10: p n A
Tristearin l este ca axit stearic vi ancol glixerol.
Cu 11: p n A
Phn tch: Y lm qu tm ha nn Y c tnh axit nn loi ngay c p n B v D. Y to dung dch ng
nht khi tc dng vi HCl v to kt ta trng khi tc dng vi Ba(OH)2 nn Y ch c th l KHSO4 v khi
AlCl3 khi tc dng vi Ba(OH)2 s to kt ta v ri kt ta li tan.
PTHH: KHSO4 +HCl KCl + H2SO4
KHSO4 +Ba(OH)2 BaSO4 + KOH +H2O
Cu 12: p n D
Phn tch: Cho ming hp kim Fe-C vo dung dch HCl long, khi xy ra qu trnh n mn in ha hc
ng vi s hnh thnh pin in. Ti catot( cc dng), ion H+ ca dung dch HCl nhn electron bin thnh
nguyn t H ri thnh phn t H2 thot ra :2H+ + 2e H2.
Cu 13: p n B
Etylamin(C2H5NH2) lm i mu qu tm sang xanh.
Cu 14: p n A
Phn tch: Amino axit no, mch h c cng thc CnHmO4N nn amino axit ny c 2 nhm COOH v 1
nhm NH2. t cng thc cu to ca n l NH2CaH2a-1(COOH)2
Suy ra , n a 2v m 2 2a 1 2 2a 3 m 2n 1
Cu 15: p n B
Phn tch: Cht bo l este ca etilenglicol v cc axit bo l Sai Cht bo l este ca glixerol v cc axit
bo.
Cu 16: p n A
Phn tch: Fructoz , Glucoz : monosacarit.
Mantoz, Saccaroz : isacarit.
Tinh bt v Xenluloz : polisacarit.
Cu 17: p n B
Phn tch: Cc kim loi phn ng c vi lng d FeCl3 thu c kt ta l nhng kim loi to hidroxit:
Na, Ba,Mg. Khi kt ta sinh ra l Fe(OH)3.
Cu 18: p n C
nBa 0, 01 mol; nAl2 SO4 0, 003 mol
3
nBaOH 0, 01 mol nOH 0, 02 mol

2
nOH 0, 02
Ta c : 3 4
nAl 3 0, 003.2
Nn sau phn ng to ra kt ta Al(OH)3 v Ba(AlO2 )2
Ta c: Al 3 3OH Al OH 3
x 3x x
3
Al 4OH AlO2 2 H 2O
y 4y y

nOH 3 x 4 y 0, 02
x 0, 004
nAl OH x 0, 004
n 3 x y 0, 006 y 0, 002
Al
3
Li c nBaSO4 nSO 2 0,009 mol

4
v n
Ba 2
nSO 2
4

Vy khi lng kt ta sau phn ng l : mAl OH mBaSO4 2, 409 gam.
3
Cu 19: p n D
Phn tch: Ta coi c qu trnh l cho NaOH tc dng vi axit v tc dng vi c amino axit.
Nn gp c hai qu trnh lm mt:
RNH 2 COOH 2 H 2 SO4 NaOH KOH
0,1 mol 0,15 mol
43,8 g ho i H 2O
n hp muo
Ta c : nH 2nX 2nH2SO4 0,5 mol
(H2O c to ra t phn ng trung ha axit v baz) S dng phng php trung bnh, t cng thc chung
ca NaOH v KOH l XOH, ta c
40.1 56.1,5
MX 17 32, 6
1 1,5
p dng phng php bo ton khi lng, ta c:
mX mH 2 SO4 mXOH 43,8 mH 2O
0,1. MR 106 0,15.98 0,5. 32,6 17 43,8 0,5.18 M R 27 R l C2 H 3
Vy X c cng thc cu to l C2H3NH2 (COOH)2 .
Cu 20: p n A
T visco l t bn tng hp ( t nhn to ).
Cu 21: p n B
Phn tch:
Cu 22: p n D

NO2 ( kh duy nha t thoa
t ra)
Qua
ng sat+HNO3 t0
BaCl2
dung dch X kho
ng tao
Qung manhetit (Fe3O4), qung Hemantit (Fe2O3), qung Hemantit nu (Fe2O3.nH2O), qung xierit(
FeCO3), qung pirit ( FeS2).
Vy qung st ha tan l qung manhetit (Fe3O4).
Cu 23: p n D
Ha cht c th lm mm nc cng cha nhiu Ca2+ v Cl l Na2CO3 .
Cu 24: p n D
Phn tch: Ngi ta dng cc mu km (Zn) gn ln v tu bin bo v cc tu thp. Trong nc bin c
dung dch NaCl lm cht in li, s hnh thnh 2 cp in cc vi Fe l cc dng , Zn l cc m. Hin
tng n mn in ha xy ra, Zn l cc m nn b n mn, cn Fe l cc dng nn khng b n mn.
Cu 25: p n C
10,3
nX 0,1 mol M muoi 9, 7 0,1 97 gam / mol
103
Mui c cng thc phn t l NH2CH2COONa
Cng thc cu to ca X l NH2CH2COOC2H5
Cu 26: p n A
Phn tch: - Ta nhn thy ngay khi cho 0,15 mol Ba(OH)2 vo dung dch th kt ta t cc i vi s mol
ca BaCO3 l 0,2 mol
nBaCO3 nBaOH nBaCl2 0, 2 0,15 y y 0, 05 mol
2
Khi nh t t 0,05 mol Ba(OH)2 vo dung dch th xut hin 0,1 mol kt ta BaCO3 v kt ta tip tc tng
khi tip Ba(OH)2 nn
nBaCO3 nCO 2 nNaHCO3 x 0,1 mol
3
Cu 27: p n A

Phn tch: Fe, Fe3O4 , Cu, CuO HCl 1mol
33,2 gam

1, 6 g cha n Cu
t ra

H 2 0,1mol

Dung dch Y m gam
AgNO 3, d

0, 025 mol NO
1, 6
nCu d 0, 025 mol ; nH2 nFe 0,1 mol
64
t s mol ca Fe3O4 l a(mol) v s mol CuO l b(mol)
Ta c: Fe3O4 + 8HCl FeCl2 +2FeCl3
A 8a a 2a
Cu +2FeCl3 CuCl2 + 2FeCl3
a 2a
Suy ra trong 33,2g hn hp X c
nCu a 0,025 mol 33,2 = 0,1.56+ 232. a +(a + 0,025). 64 + 80b 296a +80b = 26(1)
V khi cho AgNO3 d vo dung dch Y thy thot ra kh NO nn HCl chc chn cn d
nHCl d 1 2nH 2 8nFe3O4 2nCuO 1 0, 2 8a 2b 0,8 8a 2b
Ta c:
3Fe2+ + 4H+ + NO3 3Fe3+ +NO + 4H2O (I)
0,075 0,1 0,025
nHCl d = 0,1(mol) 8a+ 2b = 0,7 (2)
1 1
1 v 2 ta c a mol v b mol
12 60
HCl d 0,1 mol

Suy ra dung dch Y gm FeCl2 0,35 mol
CuCl 0,1 mol
2
T phng trnh (I), ta thy FeCl2 d 0,275 mol nn ta c thm phn ng :

Ag Fe2 Fe3 Ag nAg 0, 275 mol v nAgCl nCl nHCl ban au 1 mol
0, 275.108 1. 108 35,5 173, 2 gam
Vy m=173,2 gam.
Ch : Ta thng qun phn ng + + 2+ 3+ + nn tnh thiu lng kt ta Ag.
Cu 28: p n B
Phn tch: Fe3O4 , Cu HCl
40 gam
Dd Y 2 cha
t tan m g cha
AgNO 3 d
t ra
n

16,32 gam cha t ra
n
t nFe3O4 x mol
16,32
16,32 gam cht rn l Cu: nCu 0, 255 mol
64
Dung dch Y cha 2 cht tan s l CuCl2 v FeCl2 ( v Cu d nn mui Fe3+ b y xung ht thnh mui
Fe2+ ).
Ta c : Fe3O4 8HCl FeCl2 2FeCl3 4H 2O
x x x
Cu+ 2FeCl3 CuCl2+2FeCl2
x 2x x 2x

40 mCu mFe3O4 64. x 0, 255 232 x x 0,08
Dung dch Y gm:
nFeCl2 x 2 x 0, 24 mol ; nCuCl2 x 0, 08 mol
nCl (0, 08 0, 24).2 0, 64 mol nAgCl 0, 64 mAgCl 91, 84 gam
Ta c Ag Fe2 Fe3 Ag nAg nFe2 0, 24 mol mAg 25,92 gam
Vy m 25,92 91,84 117,76 gam
Ch : Ta thng qun phn ng + + 2+ 3+ + nn tnh thiu lng kt ta Ag.
Cu 29: p n D
Phn tch: (2) sai v cc amin l cht kh iu kin thng ch gm metylamin, imetylamin, trimetylamin
v etylamin
(3) sai v trong phn t ipeptit mch h c cha mt lin kt peptit.
Cu 30: p n C
Phn tch: t cng thc trung bnh ca amino axit to nn peptit X l Cn H 2 n 1 NO2
3 H2O
Cng thc ca tetrapeptit X l 4H 2n1 NO2 C4n H8n2 N4O5
4
Ta c nN2 nX . 0, 02 nX 0, 01 mol
2
Ging vi phn ng t chy ancol bng CuO, ta c:
C4 n H8n2 N 4O5 CuO
t0

4nCO2 4n 1 H 2O Cu 2 N 2 I
0,01 4n. 0,01 (4n1).0,01
3,84
Khi lng CuO gim chnh l khi lng O trong CuO nO nCuO 0, 24 mol
16
Bo ton nguyn t O cho phng trnh (I), ta c :
5nX + nCuO = 2nCO2 + nH2O 5.0,01 +0,24 = 8n. 0,01 + (4n 1). 0,01 n = 2,5
Suy ra X c cng thc l : C10H18N4O5
Ta c : C10H18N4O5 +4HCl +3H2O Mui
mmui = mX + mHCl + mH2O = nX.284 + 4nX.36,5+3nX. 18= 0,01.484 = 4,84 (gam)
Ch : lm cc bi tp v peptit ta thng t cng thc chung ca chng. Vi cc phn ng cho peptit
tc dng vi HCl, ta p dng phng php bo ton khi lng theo phng trnh : Peptit X(c n lin kt
peptit) + (n+1)HCl + nH2O Mui
Cu 31: p n A
C6H5OH + (CH3CO)2O C6H5OOCCH3 + CH3COOH
Cu 32: p n A
Phn tch: Glutamic: HOOC-CH(NH2)-CH2-CH2-COOH
14, 7
nGlu 0,1 mol
147
Ta c Glu + (HCl,H2SO4 ) Mui
Bo ton khi lng ta c : 19,83 mHCl mH 2 SO4 mGlu
mHCl mH2SO4 19,83 14,7 5,13 gam
n 1
Li c: HCl 2 nn ta c nHCl 0, 06mol v nH SO 0, 03mol
nH 2 SO4 0, 5 2 4
nH 2nGlu nHCl nH 2 SO4 = 2.0,1 +0,06+ 2.0,03 = 0,32mol

Suy ra s mol OH cn phn ng vi s cht tan trong dung dch X cng l s mol OH phn ng vi
tng s mol H+
0,32
nOH 0,32 mol V 200 ml .
1 0, 6
Ch : Nu bi cho khi lng mt s cht trc v sau phn ng th ta s dng phng php bo ton
khi lng kt hp vi cc gi thit khc lm bi.

Cu 33: p n C
Ta c nBa2 nBa HCO3 nBaCL2 0,15 0,1 0, 25mol
2
nHCO3 2nBa HCO3 2.0,15 0,3 mol

2
Suy ra s mol BaCO3 cc i s tnh theo s mol Ba2+ khi ta cho thm NaOH vo dung dch. Khi kt
ta t cc i cn thm 0,25 mol NaOH VNaOH = 250ml.
Cu 34: p n C

H 2 SO4 0,15 mol
Phn tch: X NaOH V1mol
m g
NaOH 0,45 mol
0,5m g
Al
2 SO
4 3 0,1 mol
Ta thy sau khi cho thm 0,45 mol NaOH th khi lng kt ta thu c t hn so vi lng kt ta thu
c ban u nn khi cho 0,45 mol vo th xy ra qu trnh
Al OH 3 OH AlO2 2H 2O
S mol OH dng to m(g) kt ta l : V1 0,15.2 = V1 - 0,3 (mol)
S mol OH dng to 0,5m(g) kt ta l : V1+ 0,45 0,15.2 = V1 +0,15 (mol)
Ta c nAl3 0, 2 mol nn nAl OH max 0, 2 mol
3
ha tan ht ton b lng Al(OH)3 cn 0,2 mol OH Nn khi cho thm 0,45 mol NaOH vo m(g) kt
ta, vn thu c 0,5m(g) kt ta th ln u tin, lng kt ta cha b ha tan mt phn
Ta c : Al3+ + 3OH Al(OH)3 (1)
0,2 0,6 0,2
Al(OH)3 + OH
0,2- (V1 + 0,15 0,6) (V1 + 0,15 0,6)
AlO2 + 2H2O (2)
-
nOH V 0,3
m 78. 78. 1
3 3 6[0,2 (V1 + 0,15 0,6)] = V1 0,3 V1 = 0,6
0,5m 78. 0, 2 V 0,15 0, 6
1
Vy V1= 600 ml.
Cu 35: p n D
Phn tch: Khi t chy 2 ancol Y thu c:
nCO2 0, 4
nCO2 0, 4 mol ; nH 2O 0, 6 mol nC nCO2 2
nH2O 0, 6 0, 4
Do Y gm 2 ancol no, mch h, c cng s nguyn t Cacbon nn Y gm C2H5OH v C2H4 (OH)2 Gi s
mol C2H5OH v C2H4 (OH)2 ln lt l x, y mol.
nCO 2 x 2 y 0, 4 x 0,1
Ta c 2
m 46 x 62 y 10,8 y 0,1
V khi thy phn este trong NaOH ch thu c mui natri axetat nn cng thc ca 2 este l CH3COOC2H5
v (CH3COO)2C2H4 .
p dng nh lut bo ton nguyn t ta c:
nCH3COONa nCH3COO nCH3COOC2 H5 2nCH3COO C2 H4
2
= 0,1+ 0,1.2 = 0,3 mCH3COONa 82.0,3 24, 6 g

Cu 36: p n D
Cc cht thy phn trong mi trng axit l : etyl axetat, triolein, t visco, saccaroz, xenluloz.
Cu 37: p n C
Phn tch: Quy i hn hp X v Al, Na v O
Al 0, 2 mol

Ta c X Na 0, 2 mol H 2O : 0, 2mol Y : NaAlO2 (0, 2 mol ) H 2 (0, 2 mol )(1)
O x mol

4, 48
nH 2O nH 2 0, 2 mol.
22, 4

V sau phn ng dung dch Y ch cha 1 mui tan duy nht nn Y ch c NaAlO2 .
Cho CO2 vo Y ta c: CO2 + NaAlO2 + 2H2O NaHCO3 + Al(OH)3
15, 6
nNaAlO2 nAl OH 0, 2mol
3
78
p dng nh lut bo ton nguyn t vo (1), ta c:
Trong X c : nNa nAl nNaAlO2 0, 2mol.
p dng nh lut bo ton nguyn t O vo (1) ta c:
nO X nO H2O 2nO NaAlO2 x 0, 2 0, 2.2 x = 0,2.
Vy khi lng ca X l: mX = mNa + mAl + mO = 13,2g
Cu 38: p n A
Phn tch:
Fe + CuSO4 FeSO4 +Cu (1)
0,2 0,2 0,2
V phn ng xy ra hon ton, sau phn ng cht rn X c kh nng ha tan HCl to kh H2 nn sau phn
ng (1) Fe d. Do cht rn X chia lm 2 phn khng bng nhau nn ta gi P1=kP2
P1: Fe+2HCl FeCl2 + H2
2, 24
nFe nH 2 0,1 mol
22, 4
Fe
P2 : HNO3 dd Y NO H 2O 2
Cu
6, 72 nFe phan 1 0,1
nNO 0,3 mol , nFe phan 2 mol
22, 4 k k
0, 2
Ta li c P1 = kP2 nn nCu P2 mol
k 1
+ + + + +2
+ +
p dng nh lut bo ton e P2 ta c:
0,1 0, 2
3nFe + 2nCu = 3nNO 3. 2. 0,3.3
k k 1
7
k n
0,1 9
mol nFe X 0,1
9
mol
9 Fe P2
k 70 70
3
nFe ban au nFe1 nFe X mFe 24 g
7
Cu 39: p n A
Phn tch: X l este n chc mch h, X tc dng vi Br2/CCl4 theo t l 1:2, chng t X l este c cha 2
lin kt trong mch Cacbon CT ca X l CnH2n4O2 .
12n
%mC 0, 7347 n 12. Vy CT ca X l C12H20O2 .
12n 2n 4 16.2
Tng s nguyn t c trong phn t X l: 12+20+2=34.
Cu 40: p n B
H2NCH2COOH +KOH H2NCH2COOK+H2O
Khi cho hn hp X tc dng vi KOH ch c Glyxin phn ng vi KOH
nGly = nKOH = 0,2 mol mGly=75.0,2=15g
4,5
metylamin 19,5 15 4,5 g netylamin 0,1 mol
45
Khi cho X tc dng vi HCl th c 2 u tc dng theo t l mol 1:1.
nHCl = nGly + netylamin = 0,2 +0,1 = 0,3 mol VHCl = 300ml

S GD T THANH HA THI TH LN 1 THPT QUC GIA NM 2017
THPT QUNG XNG I Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Ha tan ht m gam bt nhm kim loi bng dung dch HNO3 thu c dung dch A khng
cha mui amoni v 1,12 lt kh N2 ktc. Khi lng ban u m c gi tr:
A. 4,5g B. 4,32g C. 1,89g D. 2,16g
Cu 2: Cho cc cht C6H5OH (X); C6H5NH2 (Y); CH3NH2 (Z) v HCOOCH3 (T). Cht khng lm i
mu qu tm l:
A. X, Y B. X, Y, Z C. X, Y, T D. Y v T
Cu 3: Thy phn este c cng thc phn t C4H8O2 trong mi trng axit thu c 2 sn phm hu c
X v Y (cha C, H, O). Bit Y c th c to ra t qu trnh oxi ha X iu kin thch hp. Cu to
ca X l:
A. C2H5OH B. CH3COOC2H5 C. C2H5COOCH3 D. CH3COOH.
Cu 4: Hai cht no sau y u tan tt trong nc
A. CH3COOH v CH3NH2 B. CH3COOCH3 v CH3OH
C. HCOOH v Tinh bt D. C6H5NH2 v CH3COOH
Cu 5: Phn ng khng lm gii phng kh l:
to
A. Na CH 3OH B. CH 3 NH 3Cl NaOH
C. CH 3COOC2 H 5 KOH D. CH 3COOH NaHCO3
Cu 6: C bao nhiu phn ng ha hc c th xy ra khi cho cc ng phn n chc ca C2H4O2 tc
dng ln lt vi tng cht: Na, NaOH, NaHCO3?
A. 2 B. 3 C. 4 D. 5
Cu 7: un nng X vi dung dch NaOH d thu c mui v ancol a chc. Cng thc cu to ca X
l
A. CH3COOCH(CH3)2 B. CH3COOCH2CH2-OOCH.
C.CH3OOC-COOCH2CH3 D. CH3COOCH=CH2
Cu 8: Cho hn hp bt X gm 3 kim loi: Fe, Cu, Ag. tch nhanh Ag ra khi X m khng lm thay
i khi lng cc cht cn dng ha cht no?
A. Dung dch AgNO3 d B. Dung dch HCl c
C. Dung dch FeCl3 d D. Dung dch HNO3 d
Cu 9: Phng php iu ch NaOH trong cng nghip l:
A. in phn dung dch NaCl bng dng din mt chiu c mng ngn
B. Cho Na vo H2O
C. Cho Na2O vo nc.
D. Cho dung dch Na2CO3 tc dng vi dung dch Ba(OH)2.
Cu 10: Ly m gam mt axit hu c n chc X cho tc dng vi NaHCO3 d thy gii phng 2,2g kh.
Mt khc, cho m gam X vo C2H5OH ly d trong H2SO4 c (H = 80%) th thu c 3,52g este. Gi tr
ca m l:
A. 2,4g B. 2,96g C. 3,0g D. 3,7g

Cu 11: C 4 l dung dch ring bit X, Y, Z v T cha cc cht khc nhau trong s bn cht:
(NH4)2CO3,KHCO3, NaNO3, NH4NO3. Bng cch dng dung dch Ca(OH)2 cho ln lt vo tng dung
dch, thu c kt qu sau:
Cht
Thuc th
X Y Z T
Dung dch Khng c hin Kt ta trng, c
Kt ta trng Kh mi khai
Ca(OH)2 tng kh mi khai
Nhn xt no sau y ng?
A. X l dung dch NaNO3. B. T l dung dch (NH4)2CO3
C. Y l dung dch KHCO3 D. Z l dung dch NH4NO3.
Cu 12: Cho 6,4g hn hp 2 kim loi k tip thuc nhm IIA ca bng tun hon tc dng vi dung dch
H2SO4 long d thu c 4,48 lt H2 (ktc). Hai kim loi l:
A. Be v Mg B. Mg v Ca C. Ca v Sr(88) D. Sr v Ba
Cu 13: Kim loi khng tc dng vi dung dch Fe2(SO4)3 l :
A. Fe. B. Cu C. Ag D. Al
Cu 14: Cho cc phng trnh ion rt gn sau:
a) Cu 2 Fe Fe 2 Cu ; b) Cu + 2Fe3+ 2Fe2+ + Cu2+; c) Fe2+ + Mg Mg2+ + Fe
Nhn xt ng l:
A. Tnh kh ca: Mg > Fe > Fe2+ > Cu
B. Tnh kh ca: Mg > Fe2+ > Cu > Fe
C. Tnh oxi ha ca: Cu2+ > Fe3+ > Fe2+ > Mg2+
D. Tnh oxi ha ca: Fe3 Cu 2 Fe2 Mg 2
Cu 15: C cc dung dch mt nhn sau: axit axetic, glixerol, etanol, glucozo. Thuc th dng nhn
bit cc dung dch ny l:
A. Qu tm B. dd AgNO3/NH3
C.CuO D. Qu tm, AgNO3/NH3, Cu(OH)2
Cu 16: Nung nng mt hn hp gm 0,2 mol Fe(OH)2 v 0,1 mol BaSO4 ngoi khng kh ti khi
lng khng i , th s gam cht rn cn li l
A. 39,3 gam B. 16 gam C. 37,7 gam D. 23,3gam
Cu 17: Trong s cc polime: Xenlulozo, PVC, amilopectin. Cht c mch phn nhnh l:
A. amilopectin B. PVC
C. Xenlulozo D. Xenlulozo v amilopectin
Cu 18: Thy phn hon ton 0,01 mol saccarozo trong mi trng axit, vi hiu sut l 60%, thu c
dung dch X. Trung ha dung dch X thu c dung dch Y, em dung dch Y ton b tc dng vi lng
d dung dch AgNO3/NH3 thu c m gam Ag. Gi tr ca m l:
A. 6,48g B. 2,592g C. 0,648g D. 1,296g
Cu 19: Cho hn hp X gm Al, Fe, Cu. Dung dch no sau y khi ly d khng th ha tan ht X?
A. HNO3 long B. NaNO3 trong HCl C. H2SO4 c nng D. H2SO4 long
Cu 20: Hp cht hu c A c t khi hi so vi H2 l 30. t chy hon ton 0,3g A ch thu c 224
ml CO2 v 0,18g H2O. Cht A phn ng c vi Na to H2 v c phn ng trng bc. Vy A l:
A. CH 3COOH B. HO CH 2 CHO C. CH 3OCHO D. HOOC CHO
Cu 21: Ha tan 9,14g hn hp Cu, Mg, Al bng dung dch HCl va thu c 7,84 lt kh X(ktc);
dung dch Z v 2,54g cht rn Y. Lc b cht rn Y, c cn dung dch Z thu c khi lng mui khan
l:
A. 19,025g B. 31,45g C. 33,99g D. 56,3g
Cu 22: Cc kim loi ch tc dng vi dung dch H2SO4 long m khng tc dng vi dung dch H2SO4
c ngui l
A. Cu v Fe B. Fe v Al C. Mg v Al D. Mg v Cu
Cu 23: Cho kh CO i qua m gam Fe2O3 nung nng th thu c 10,68g cht rn A v kh B. Cho ton
b kh B hp th vo ducg dch Ca(OH)2 d th thy to ra 3 gam kt ta. Gi tr ca m l:
A. 11,16g B. 11,58g C. 12,0g D. 12,2g

Cu 24: Ha tan hon ton 20g hn hp A gm Mg v Fe2O3 bng dung dch HNO3 c d thu c
dung dch B v V lt kh NO2 (ktc) l sn phm kh duy nht. Thm NaOH d vo dung dch B. Kt
thc th nghim, lc ly kt ta em nung trong khng kh n khi lng khng i thu c 28g cht
rn. Gi tr ca V l:
A. 44,8 lt B. 33,6 lt C. 22,4 lt D. 11,2 lt
Cu 25: Ha tan hon ton Fe vo dung dch H2SO4 long va thu c 4,48 lt H2(ktc). C cn
dung dch trong iu kin khng c oxi thu c m gam mui khan. Gi tr ca m l
A. 30,4 B. 15,2 C. 22,8 D. 20,3
Cu 26: Cho mt lng hn hp gm CuO, Fe2O3 tan ht trong dung dch HCl thu c 2 mui c t l
mol l 1:1. Phn trm khi lng CuO v Fe2O3 trong hn hp ln lt l:
A. 45,38% v 54,62% B. 50% v 50% C. 54,63% v 45,38% D. 33,33% v 66,67%
Cu 27: Ha tan 1,8g mui sunfat khan ca mt kim loi ha tr II trong nc, ri thm nc cho 50
ml dung dch. phn ng vi 10 ml dung dch cn va 20 ml dung dch BaCl2 0,15M. Cng thc
ha hc ca mui sunfat l:
A. CuSO4 B. FeSO4 C. MgSO4 D. ZnSO4
Cu 28: X l hp cht hu c va tc dng vi AgNO3/NH3, va tc dng vi NaOH nhng khng lm
qu tm i mu. X l
A. axit fomic B. etyl axetat C. metyl fomat D. axit axetic
Cu 29: Trong s nhng hp cht HCOOH; CH3COOCH3; ClNH3CH2COOH; HOCH2C6H4OH;
CH3COOC6H5. S hp cht tc dng vi NaOH theo t l 1:2 v s mol l
A. 1 B. 3 C. 2 D. 4
Cu 30: Cho 10 ml dung dch mui Canxi tc dng vi lng d dung dch Na2CO3, lc ly kt ta nung
n khi lng khng i thu c 0,28g cht rn. Nng mol ca ion canxi trong dung dch ban u
l:
A. 0,5M B. 0,05M C. 0,70M D. 0,28M
Cu 31: Sp xp theo chiu tng dn tnh axit ca cc cht: HCOOH (1), CH3COOH (2), C6H5OH
(phenol), (3) ln lt l
A. 3 2 1 B. 3 1 2 C. 2 1 3 D. 2 3 1
Cu 32: Phn ng no sau y l khng ng?
A. 2 Na 2 H 2O 2 NaOH H 2 B. 2 Al 3Cl2 2 AlCl3
C. FeCl2 Na2 SO4 FeSO4 2 NaCl D. BaO CO2 BaCO3
Cu 33: Cho 13,5 gam hn hp gm 3 amin no, n chc, mch h tc dng va vi 300 ml dung
dch HCl xM, thu c dung dch cha 24,45 gam hn hp mui. Gi tr ca x l
A. 0,5 B. 1,4 C. 2,0 D. 1,0
Cu 34: T 3 -amino axit: glyxin, alanin, valin c th to ra my tripeptit mch h trong c c 3 -
amino axit ?
A. 4 B. 6 C. 3 D. 2
Cu 35: sn xut 10 lt C2H5OH 46 (d= 0,8 gam/ml) cn dng bao nhiu kg tinh bt bit hiu sut ca
c qu trnh sn xut l 80%?
A. 16,2kg B. 8,62kg C. 8,1kg D. 10,125kg
Cu 36: Este no, n chc, mch h c cng thc phn t chung l:
A. Cn H 2nO n 3 B. Cn H 2n 2O2 n 2
C. Cn H 2n 2O n 3 D. Cn H 2nO2 n 2 .
Cu 37: Dung dch X c cha AgNO3 v Cu(NO3)2 c cng nng mol. Thm 1 hn hp gm 0,03
mol Al v 0,05 mol Fe vo 100 ml dung dch X cho ti khi phn ng kt thc thu c cht rn Y gm 3
kim loi. Cho m gam Y vo HCl d gii phng 0,07g kh. Nng ca 2 mui ban u l:
A. 0,3M B. 0,4M C. 0,42M D. 0,45M
Cu 38: Cho hn hp A gm hai cht hu c mch h X, Y (ch cha C, H, O m MX < MY) tc dng
va vi 200 ml dung dch NaOH 1M, thu c 0,2 mol mt ancol n chc v 2 mui ca hai axit
hu c n chc, k tip nhau trong dy ng ng. Mt khc t chy 20,56 gam A cn 1,26 mol O2 thu
c CO2 v 0,84 mol H2O. Phn trm s mol ca X trong A l:

A. 20% B. 80% C. 40% D. 75%
Cu 39: Cho hn hp M gm hai axit cacboxylic X, Y (cng dy ng ng, c s mol bng nhau MX <
MY) v mt amino axit Z (phn t c mt nhm -NH2). t chy hon ton 0,4 mol hn hp M thu c
kh N2; 14,56 lt CO2 ( ktc) v 12,6 gam H2O. Cho 0,3 mol M phn ng va vi dung dch x mol
HCl. Nhn xt no sau y khng ng?
A. Gi tr ca x l 0,075
B. X c phn ng trng bc
C. Phn trm khi lng ca Y trong M l 40%.
D. Phn trm khi lng ca Z trong M l 32,05%.
Cu 40: Hn hp M gm hai peptit X v Y, chng cu to t mt amino axit v c tng s nhm -CO-
NH- trong 2 phn t l 5 vi t l mol nX: nY=1:2. Thy phn hon ton m gam M thu c 12 gam glixin
v 5,34gam alanin. Gi tr ca m:
A. 16,46 B. 15,56 C. 14,36 D. 14,46
p n
1-A 6-C 11-B 16-A 21-B 26-B 31-A 36-D
2-C 7-B 12-B 17-A 22-B 27-C 32-C 37-
3-A 8-C 13-C 18-B 23-A 28-C 33-D 38-
4-A 9-A 14-D 19-D 24-C 29-C 34-B 39-
5-C 10-C 15-D 20-B 25-A 30-A 35-C 40-
Cu 1:p n A
Phn tch : tnh nhanh, ta s dng phng trnh ion biu din qu trnh nhng-nhn e.
1,12
nN 2 = 0, 05 mol
22, 4
Al Al 3 3e ,
2 N 5 10e N 2
0,5 0,05
0,5
Bo ton e, ta c : nAl mAL 4,5( gam)
3
Cu 2:p n C
Phn tch : Cc cht khng lm qu tm i mu l C6H5OH(X), C6H5NH2(Y), HCOOCH3(T). Ch c cht
CH3NH2 lm qu tm ha xanh.
Cu 3:p n A
Phn tch : Y c th to ra t qu tnh oxi ha X nn s C trong X v Y l nh nhau.
Suy ra cu to ca este l :l : C2H5OH
Cu 4:p n A
Phn tch : Hai cht tan tt trong nc l CH3COOH v CH3NH2 ( c lin kt H linh ng).
Cu 5:p n C
Phn tch :
A. 2Na + 2CH3OH 2CH3ONa + H2
B. CH 3 NH 3Cl NaOH t CH 3 NH 2 NaCl H 2O
C. CH 3COOC2 H 5 KOH CH 3COOK C2 H 5OH
D. CH 3COOH NaHCO3 CO2 CH 3COONa H 2O
Cu 6:p n C
Phn tch : Cc ng phn cu to, n chc ca C2H4O2 l : CH3COOH, HCOOCH3
CH3COOH HCOOCH3
Na CH3COONa+ H2 -
NaOH CH3COONa + H2O HCOONa + CH3OH
NaHCO3 CO2 + H2O+ CH3COONa -

Cu 7:p n B
CH3COOCH2CH2OOCH + NaOH CH3COONa + HCOONa + OHCH2CH2OH
Cu 8: p n C
Phn tch : tch Ag ra khi hn hp X(Fe,Cu, Ag) m khng lm thay i khi lng cc cht cn dng
ha cht tc dng c vi Fe, Cu m khng sinh ra Ag v ha cht khng tc dng vi Ag. Suy ra l
dung dch FeCl3.
PTHH :
Cu 2FeCl3 CuCl2 2FeCl2
Fe 2 FeCl3 3FeCl2
Cu 9: p n A
Phn tch : Phng php iu ch NaOH trong cng nghip l in phn dung dch NaCl bng dng in
mt chiu c mng ngn.
Cu 10: p n C
Ta c X + NaHCO3 Mui +H2O + CO2
2, 2
nX nCO 2 0, 05mol
44
Khi cho X tc dng vi C2H5OH , ta c H 80% th meste 3,52 gam
4, 4
Ta c: neste nX 0, 05 M este 88
0, 05
Este : CH3COOCH3 mx 0,05.60 3 gam Vy m 3 gam
Cu 11: p n B
Phn tch : X Ca OH 2 Kt ta trng X l KHCO3
Y Ca OH 2 Kh mi khai Y l NH4NO3
Z Ca OH 2 Khng c hin tng Z l NaNO3
T Ca OH 2 Kt ta trng, kh mi khai T l (NH4)2CO3
Cu 12: p n B
4, 48 6, 4
Ta c : nH 2 0, 2 nkim loai 0, 2 M kim loai 32
22, 4 0, 2
Suy ra hai kim loi l Mg(24) v Ca(40).
Cu 13:p n C
Phn tch : Kim loi khng tc dng c vi dung dch Fe2(SO4)3 l Ag v :
Al 3 Fe2 Cu 2 Fe3 Ag 2
Al Fe Cu Fe2 Ag
Cu 14: p n D
Phn tch :
Fe2 Cu 2
T phn ng a) ta c :
Fe Cu
Cu 2 Fe3
T phn ng b) ta c :
Cu Fe2
Mg 2 Fe2
T phn ng c) ta c :
Mg Fe
2
Mg Fe2 Cu 2 Fe3
Suy ra c sp xp sau :
Mg Fe Cu Fe2
Tnh kh : Mg Fe Cu Fe2
Tnh oxi ha : Mg 2 Fe2Cu 2 Fe3 Vy nhn xt ng l D.
Cu 15: p n D
Phn tch :

- Dng qu tm, ta nhn ra : axit axetic lm qu tm ha .
- Dng AgNO3/NH3 , ta nhn ra : glucozo c phn ng to kt ta trng (Ag).
- Dng Cu(OH)2 ta nhn ra : glixerol to dung dch mu xanh lam.
- Cht cn li l etanol.
Cu 16: p n A
Phn tch : Khi nung nng hn hp Fe(OH)2 v BaSO4 ngoi khng kh th cht rn thu c l : Fe2O3 v
BaSO4
Ta c : 4 Fe(OH )2 O2 2Fe2O3 4H 2O
m mFe2O3 mBaSO4 0,1.160 0,1.233 39,3 gam
Ch : Khi nung ngoi khng kh th Fe(OH)2 s sinh ra Fe2O3 v c phn ng gia FeO vi O2 .
Cu 17: p n A
Amilopectin : mch phn nhnh
Cu 18: p n B
H ,T 0
Saccaroz + H2O Glucoz + Fructoz
Sau phn ng, ta c :
nGlu nFruc 0,01.60% 0,006 mol
nAg 2nGlu 2nFruc 2.(0, 006 0, 006) = 0,012 mol mAg = 0,012.108 = 2,592 gam
Ch : Saccaroz khng tc dng vi AgNO3 /NH3 .
Cu 19: p n D
Phn tch :
- Khi cho X(Al,Fe,Cu) vo HNO3 long, NaNO3 trong HCl hay H2SO4 c, nng th Al v Fe th c ba cht
trong X u phn ng theo kiu phn ng oxi ho kh nn X b ha tan ht.
- Nu cho X(Al,Fe,Cu) vo H2SO4 long th ch c Al v Fe phn ng. V ch sinh ra mui Fe(II) nn khng
th ha tan c Cu.
Cu 20: p n B
0,3
nA 0, 005mol ; nCO 0, 01mol ; nH O 0, 01 mol A : C2 H 4O2
30.2 2 2
V A phn ng vi Na to H2 v c phn ng trng bc nn A c cng thc cu to l HO CH 2 CHO .

Cu 21:p n B
7,84
nH 2 0,35mol
22, 4
H 2 0,35 mol

Cu , Mg , Al HCl (va ) Dung dch Z
Ra
n Y : 2,54 g
9,14 gam
Cht rn Y l Cu
mZ mMg , Al mCl (9,14 2,54) 2nH . 35,5 = 6,6 + 0,35.71 = 31,45 (gam).

2
Cu 22: p n B
Phn tch : Cc kim loi tc dng c vi H2SO4 long m khng tc dng c vi H2SO4 c, ngui l :
Fe v Al.
Cu 23: p n A
Phn tch: Ta c th tm tt ton b qu trnh phn ng nh sau
Ra n A (10,68g)
Fe2O3 Ca ( OH ) 2 , d
m ( gam ) Kh B 3( g )
nB (CO2 ) nCaCO3 0, 03 mol nCO = nCO2 =0, 03 mol
mFe2O3 mCO mA mCO2 m 0, 03.28 10, 68 0, 03.44 m 11,16 gam
Cu 24: p n C

mMg mFe 2O 3 20 gam 28 20
Ta c : nMg 0,5mol
mMgO mFe 2O 3 28( gam) 16
Bo ton e nNO2 = 2nMg = 1 mol V = 22,4 lt
Cu 25: p n A
Fe + H2SO4 FeSO4 + H2 nFeSO4 = nH2 = 0,2 mol mFeSO4 = 30,4(gam)
Cu 26: p n B
nFeCl3 2nFe2O3 1 nFe O 1 80.3
Ta c: 2 3 %CuO 50%
nCuCl2 nCuO 2 nCuO 2 80.2 160
%Fe2O3 50%
Cu 27: p n C
Phn tch : phn ng vi 50ml dung dch cn va BaCl2(0,015mol)
nmui sunfat = 0,015 mol Mmui = 120
Vy cng thc ha hc ca mui sunfat l MgSO4.
Cu 28: p n C
Phn tch :
A sai v axit fomic va tc dng vi AgNO3/NH3, va lm qu tm ha .
B sai v etyl axetat(HCOOC2H5) tc dng vi AgNO3/NH3
D sai v axit axetic lm qu tm ha .
Cu 29: p n C
Phn tch : Cc cht tc dng vi NaOH theo t l 1:2 l : ClNH3CH2COOH, CH3COOC6H5
Cu 30: p n A
1
CaCO3 t0
t Ca CO2 O2
2
0, 28 0, 0007
nCaCO3 nCa 0, 007mol CM CaCO 0.7 M
40 3
0, 01
Cu 31: p n A
Phn tch : Tnh axit : C6H5OH(3)<CH3COOH(2)<HCOOH (1)
Cu 32: p n C
Phn tch : Phn ng C sai v khng to kt ta hay cht kh khi cho hai mui tc dng vi nhau.
Cu 33: p n D
Phn tch: Bo ton khi lng, ta c
0,3
mHCl mmuoi mamin 24, 45 13,5 10,95 nHCl 0,3mol x 1M
0,3
Cu 34: p n B
Gly-Ala-Val; Gly-Val-Ala; Ala-Gly-Val; Ala-Val-Gly; Val-Gly-Ala; Val-Ala-Gly.
Cu 35:p n C
C6 H10O5 n H ,t 0
nC6 H12O6 enzim
2C2 H 5OH
mC2 H5OH 10.103..46%.0,8
Ta c nC2 H5OH 80mol
46 46
80
ntinh bot= 50mol mtinh bot 8,1kg
2.80%
Cu 36: p n D
Phn tch : Este no, n chc, mch h c cng thc phn t chung l CnH2nO2 ( n 2).
Cu 37: p n B
AgNO3 , x mol Al 0, 03mol
X Ra n Y 3 kim loai
HCld
H 2 0,035mol
Cu NO3 , x Fe0, 05mol
mol
Cht rn Y gm 3 kim loi nn Fe d v Y gm Fe d, Ag, Cu.

Gi s mol Fe phn ng phn ng u l ymol
Ta c: nenhan nAg + 2nCu2 3x
ne nhng = 3nAl 2.nFephan ng 3.0,03 2 y
Bo ton e, c : 3x 0, 09 2 y .
Li c: nFe d =nH2 =0,035( ch c Fe phn ng vi HCl sinh ra H2 )
y=0,050,035=0,015x=0,04mol
Vy nng ca 2 mui ban u l 0,4M.
Cu 38: p n B
Phn tch : Ta c th tm tt ton b qu trnh phn ng nh sau
1 ancol n ch c 0,2mol
X NaOH v mol
A : ( M X M Y ) a u
,0,2
2 muo i cu
a 2 axit h
u c n ch
c
Y ketie
p nhau trong day o
ng ang
X,Y l 2 este n chc to bi mt ancol v hai axit k tip nhau trong dy ng ng.
Ta c: X , Y O2 CO2 H 2O
20,56g 1,26g 0,84g
Bo ton khi lng, c:
mX,Y + mO2 = mCO2 + mH2O
mCO2 = 45,76(gam) nCO2 = 1,04 mol
Bo ton nguyn t O, ta c:
nO ( X ) 2. nO2 2nCO2 nH 2O
0, 4
nO ( X ) 1, 26.2 1, 04.2 0,84 nO ( X ) 0, 4 nX 0, 2mol
2
nCO2 nH 2O1, 04 0,84
Ta thy: 1
nX 0, 2
nn X, Y l hai este c 1 lin kt trong mch Cacbon.
20,56
Ta c : M X ,Y 102,8 X: C5H8O2(M = 100) v Y: C6H10O2(M = 114)
0, 2
t s mol ca X, Y ln lt l a, b
5a 6b nCO 2 1, 04 a 0,16 0,16
%nX ( A) 80%
100a 114b 20,56 b 0, 04 0,16 0, 04
Vy phn trm s mol X trong hn hp A l 80%.
Cu 39: p n C
Phn tch : nCO 0,65mol ; nH2 O 0,7mol
0.65 0, 7.2
Ta c :, C 1, 625 , H 3,5
0, 4 0, 4
Suy ra X l HCOOH v Y l CaH2aO2.
V nCO2 < nH2O nn amino axit no, n chc, mch h. t cng thc ca amino axit l Cn H 2 n 1O2 N .
naminoaxixt 0,1 nX = nY 0,15 Ta c : 0,1n 0,15a 0,15.1 0, 65
2n 3a 10 a n 2
CTPT ca aminoaxit l C2H5O2N v Y l CH3COOH
HCOOH X 0,1125mol

Trong 0,3mol M c: CH 3COOH Y 0,1125mol

C2 H 5O2 N Z 0, 075
mol
Suy ra x nHCl 0,075mol ; X(HCOOH) c kh nng trng bc l nhn nh ng.

0,1125.60 0, 075.75
%Y ( M ) 38, 46% % Z ( M ) 32, 05%
17,55 17,55
Vy nhn nh sai l C.
Cu 40: p n D
12 5,34 nGlyxin 8
nGlyxin 0,16mol ; nAlanin 0, 06mol (1)
75 89 nAlanin 3
Gi cng thc cu to X l Glya Alab v cng thc cu to Y l Glyc Alad.
( a b ) (c d ) 5 1 1 7
n 1
Ta c : X (2)
nY 2
T (1) v (2), ta c :
a.nX c.2nX 8 a 2c 8
3a 6c 8b 16d
b.nX d.2nX 3 b 2d 3
3(7 b d ) 3c 8b 16d 21 3c 11b 19d Ta c 11b 19d 30
21 3c 30 M c 4 (v tng s amino axit to nn 2 peptit l 7) nn c 3 .
Khi 11b 19d 30 , v suy ra b d 1 a 2 .
Cng thc cu to ca X l : Gly2 Ala
Cng thc cu to ca Y l: Gly3 Ala
Ta c : a.nX c.2nX nGly 0,16 0,16 2nX 3.2nX
0,16 2nX 3, 2nX nX 0,02mol nY 0,04mol
m 0, 02.(2.75 89 2.18) 0, 04.(3.75 89 2.18) 14.46( gam)
Vy : m 14, 46 gam
Ch : S lin kt peptit trong 1 peptit=s amino axit to nn peptit-1

S GD T THANH HA THI TH LN 1 THPT QUC GIA NM 2017
THPT NNG CNG I Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: un nng dung dch cha 27 gam glucoz vi AgNO3/NH3, gi s hiu sut phn ng l 75%
thy Ag kim loi tch ra. Khi lng Ag kim loi thu c l:
A. 16,2 gam B. 21,6 gam. C. 24,3 gam D. 32,4 gam
Cu 2: phn bit cc dung dch ring bit: Al(NO3)3, FeCl3, KCl, MgCl2, c th dng dung dch:
A. HCl. B. HNO3. C. Na2SO4. D. NaOH.
Cu 3: thu c kim loi Fe t dung dch Fe(NO3)2 theo phng php thu luyn, c th dng
kim loi no sau y:
A. Zn. B. Fe. C. Na. D. Ca.
Cu 4: Cho t t n d kim loi Na vo dung dch c cha mui FeCl3. S phn ng xy ra l:
A. 4 B. 2 C. 3 D. 5
Cu 5: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung
dch Fe(NO3)3. Hai kim loi X, Y ln lt l:
A. Ag, Mg B. Cu, Fe C. Fe, Cu D. Mg, Ag
Cu 6: Cho cc cht sau : Ba(HSO3)2 ; Cr(OH)2; Sn(OH)2; NaHS; NaHSO4; NH4Cl; CH3COONH4;
C6H5ONa; ClH3NCH2COOH. S cht va tc dng vi NaOH va tc dng vi HCl l:
A. 4 B. 5 C. 7 D. 6
Cu 7: Cho cc dung dch: X1: dung dch HCl X2: dung dch KNO3 X3: dung dch Fe2(SO4)3.
Dung dch no c th ho tan c bt Cu:
A. X2,X3 B. X1,X2,X3 C. X1, X2 D. X3
Cu 8: Cho cc cht: Metyl amin, Sobitol, glucoz, Etyl axetat v axit fomic. S cht tc dng c vi
Cu(OH)2 l:
A. 3 B. 4 C. 2 D. 5
Cu 9: Cho 20 gam hn hp 3 amin: Metyl amin, etyl amin, propyl amin tc dng va vi V ml dung
dch HCl 1M. Sau phn ng c cn dung dch thu c 31,68 g mui khan. Gi tr ca V l:
A. 240ml B. 320 ml C. 120ml D. 160ml

Cu 10: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn:
A. St ng vai tr catot v b oxi ho. B. Km ng vai tr catot v b oxi ho.
C. Km ng vai tr anot v b oxi ho. D. St ng vai tr anot v b oxi ho.
Cu 11: Polime no d b thu phn trong mi trng kim:
A. ( CH2-CH=CH-CH2 )n B. ( CH2-CH2-O )n
C. ( CH2-CH2 )n D. ( HN-CH2-CO )n
Cu 12: Cho dy cc cht: Al, Al2O3, AlCl3, Al(OH)3. S cht trong dy va phn ng c vi dung
dch NaOH, va phn ng c vi dung dch HCl l:
A. 2. B. 4. C. 1. D. 3.
Cu 13: Cho s bin ha sau (mi mi tn l 1 phn ng):
X G T metan
E
Y + HCl axit metacrylic F polimetyl metacrylic
Trong s cc cng thc cu to sau y:

(1) CH2 = C(CH3)COOC2H5. (2) CH2 = C(CH3)COOCH3.
(3) . CH2 = C(CH3)OOCC2H5. (4) . CH3COOC(CH3) = CH2.
(5) CH2 = C(CH3)COOCH2C2H5.
C bao nhiu cng thc cu to ph hp vi E:
A. 4. B. 1. C. 3. D. 2.
Cu 14: Ho cht no sau y c th s dng phn bit 3 dung dch sau: NaCl, ZnCl2 v AlCl3.
A. Dung dch Na2SO4 B. Dung dch NH3
C. Dung dch NaOH D. Dung dch H2SO4 long
Cu 15: Cng thc tng qut ca aminoaxit no cha hai nhm amino v mt nhm cacboxyl, mch h
l:
A. CnH2n+2O2N2 B. CnH2n+O2N2 C. Cn+H2n+O2N2 D. CnH2n+3O2N2
Cu 16: Cacbon monoxit (CO) c trong thnh phn chnh ca loi kh no sau y:
A. Kh m du B. Kh thin nhin C. Khng kh D. Kh l cao
Cu 17: un nng 6 gam CH3COOH vi 6 gam C2H5OH (c H2SO4 c lm xc tc) hiu sut phn ng
este ha bng 50%. Khi lng este to thnh l:
A. 5,2 gam B. 8,8 gam C. 6 gam D. 4,4 gam
Cu 18: Trng hp khng xy ra phn ng ho hc l:
A. Fe + dung dch FeCl3. B. Fe + dung dch HCl.
C. Cu + dung dch FeCl3. D. Cu + dung dch FeCl2.
Cu 19: Cht khng c phn ng thy phn l :
A. Etyl axetat. B. Gly-Ala. C. saccaroz D. Fructozo.
Cu 20: Ho tan 7,8 gam hn hp gm Al v Mg bng dung dch HCl d. Sau phn ng khi lng dung
dch axit tng thm 7 gam. Khi lng Al v Mg trong hn hp ban u l:
A. 1,2 gam v 6,6 gam B. 5,4 gam v 2,4 gam
C. 1,7 gam v 3,1 gam D. 2,7 gam v 5,1 gam
Cu 21: Cho hn hp X gm Fe3O4, Cu vo dung dch HCl d thy cn mt phn cht rn cha tan. Vy
cc cht tan trong dung dch sau phn ng l:
A. FeCl3, FeCl2, CuCl2 B. FeCl2, CuCl2, HCl C. FeCl3, CuCl2, HCl D. FeCl3, FeCl2, HCl
Cu 22: Cho hai mui X, Y tha mn iu kin sau:
X + Y khng xy ra phn ng X + Cu khng xy ra phn ng
Y + Cu khng xy ra phn ng X + Y + Cu xy ra phn ng

X, Y l mui no di y :
A. Fe(NO3)3 v NaHSO4. B. NaNO3 v NaHCO3.
C. NaNO3 v NaHSO4. D. Mg(NO3)2 v KNO3.
Cu 23: Cho m gam Mg vo dung dch c cha 0,8 mol Fe(NO3)3 v 0,05 mol Cu(NO3)2, n phn ng
hon ton thu c 14,4 gam cht rn.Gi tr ca m l:
A. 15,6 gam. B. 24 gam C. 8,4 gam. D. 6 gam.
Cu 24: Kt qu th nghim ca cc dung dch X, Y, Z, T vi thuc th c ghi bng sau:
Mu th Thuc th Hin tng
X, T Qu tm Qu tm chuyn mu xanh
Y Dung dch AgNO3 trong NH3 un nng Kt ta Ag trng sng
Y, Z Cu(OH)2 Dung dch xanh lam
X,T Dung dch FeCl3 Kt ta nu
X, Y, Z, T ln lt l:
A. Etylamin, glucoz, saccaroz, trimetylamin. B. Etylamin, saccaroz, glucoz, anilin.
C. Anilin, etylamin, saccaroz, glucoz. D. Etylamin, glucoz, mantoz, trimetylamin.
Cu 25: Thuc th duy nht phn bit 4 dung dch BaCl2, H2SO4, HCl, NaCl b mt nhn l
A. BaCl2 B. Qu tm C. HCl D. Ba(OH)2
Cu 26: S ng phn n chc, mch h, tc dng vi NaOH m khng tc dng vi Na c cng
thc phn t C4H8O2 l:
A. 2. B. 3. C. 6. D. 4.
Cu 27: Ho tan ht m gam Fe bng 400 ml dung dch HNO3 1M. Sau khi phn ng xy ra hon ton thu
c dung dch cha 26,44 gam cht tan v kh NO (sn phm kh duy nht). Gi tr ca m l:

A. 5,60. B. 12,24. C. 6,12. D. 7,84.
Cu 28: Mnh no sau y khng ng:
A. m in ca cc kim loi kim gim dn t Li n Cs.
B. Cc nguyn t kim loi kim th u tc dng vi nc gii phng H2.
C. Cc kim loi Na, K, Ba u tc dng vi dung dch HCl gii phng H2.
D. Nng lng ion ha I1 ca kim loi kim gim dn t Li n Cs.
NH3 X Y Z
CH I
3 2 HNO
CuO
Cu 29: Cho s phn ng: (1:1) t0 . Bit Z c kh nng tham gia phn
ng trng gng. Hai cht Y v Z ln lt l :
A. CH3OH, HCHO. B. C2H5OH, CH3CHO. C. CH3OH, HCOOH. D. C2H5OH, HCHO.
Cu 30: Cho 5 gam bt Mg vo dung dch hn hp KNO3 v H2SO4, un nh, trong iu kin thch hp,
n khi phn ng xy ra hon ton thu c dung dch A cha m gam mui; 1,792 lt hn hp kh B
(ktc) gm hai kh khng mu, trong c mt kh ha nu ngoi khng kh v cn li 0,44 gam cht rn
khng tan. Bit t khi hi ca B i vi H2 l 11,5. Gi tr ca m l:
A. 31,08 B. 29,34. C. 27,96. D. 36,04.
Cu 31: t chy hon ton 29,2 gam hn hp X gm anehit acrylic, metyl axetat, anehit axetic
v etylen glicol thu c 1,15 mol CO2 v 23,4 gam H2O. Mt khc, khi cho 36,5 gam hn hp X
trn tc dng ht vi dung dch AgNO3 trong NH3 th thu c ti a m gam Ag. Gi tr gn nht
ca m l:
A. 64,8 B. 43,5 C. 53,9 D. 81,9
Cu 32: t chy hon ton a mol cht bo A thu c b mol CO2 v c mol nc, bit b-c= 5a. Khi
hidro ha hon ton m gam A cn va 2,688 lt H2 (ktc) thu c 35,6 gam sn phm B. Mt khc
thy phn hon ton m gam A trung tnh bng mt lng dung dch NaOH va , ri c cn thu c x
gam x phng. Gi tr ca x l:
A. 36,24. B. 12,16. C. 12,08. D. 36,48.
Cu 33: Hn hp A gm ba peptit mch h X, Y, Z c t l mol tng ng l 2 : 3 : 4. Thy phn hon
ton m gam A thu c hn hp sn phm gm 21,75 gam Glyxin v 16,02 gam Alanin. Bit s lin kt
peptit trong phn t X nhiu hn trong Z v tng s lin kt peptit trong ba phn t X, Y, Z nh hn 17.
Gi tr ca m l:
A. 30,93. B. 31,29. C. 30,57. D. 30,21.
Cu 34: Chn pht biu ng:
A. Trong 4 kim loi : Ba, Sn, Cr, Cu ch c 2 kim loi c th c iu ch bng phn ng nhit nhm
B. Nhng mt thanh Sn vo dung dch NiCl2 thy xut hin n mn in ha
C. Kim loi dn in tt hn c l Ag, kim loi c tnh do nht l Au
D. Kim loi Be c mng tinh th lp phng tm din

Cu 35: T glucozo bng mt phng trnh phn ng trc tip c th iu ch c:
A. HCOOH. B. CH3-CH(OH)-COOH.
C. CH3COOH. D. C3H7OH.
Cu 36: Cht hu c A khng tc dng vi Na. un nng A trong dung dch NaOH ch to ra mt mui
ca -aminoaxit c mch cacbon khng nhnh, cha mt nhm amino vi hai nhm cacboxyl v mt
ancol n chc. Thu phn hon ton mt lng cht A trong 100 ml dung dch NaOH 1M ri em c
cn, thu c 1,84 gam ancol B v 6,22 gam cht rn khan D. un nng lng ancol B trn vi H2SO4
c 170oC thu c 0,672 lt olefin (ktc) vi hiu sut l 75%. Cho ton b cht rn D tc dng vi
dung dch HCl d ri c cn th thu c cht rn khan E (khi c cn khng xy ra phn ng). Khi
lng cht rn E gn nht:
A. 8,4 B. 8,7 C. 10.2 D. 9,5
Cu 37: Cho kim loi M tc dng vi Cl2 thu c mui X. Mt khc, cho kim loi M tc dng vi dung
dch HCl thu c mui Y. Cho mui Y tc dng vi Cl2 li thu c mui X. Vy M c th ng vi kim
loi no sau y:
A. Fe B. Cu C. Ni D. Ba
Cu 38: x mol CO2 vo dung dch a mol Ba(OH)2 v b mol NaOH sinh ra c mol kt ta. kt qu ta c
th sau
Gi tr ca a l:
A.0,1 B. 0,15 C.0,2 D.0,25
Cu 39: Cho m gam Fe vo dung dch AgNO3 c hn hp X gm 2 kim loi. Chia X lm 2 phn.
- Phn 1: c khi lng m1 gam, cho tc dng vi dung dch HCl d, c 0,1 mol kh H2.
- Phn 2: c khi lng m2 gam, cho tc dng ht vi dung dch HNO3 long d, c 0,4 mol kh NO.
Bit m2 m1 = 32,8. Gi tr ca m bng:
A. 1,74 gam hoc 6,33 gam B. 33,6 gam hoc 47,1 gam
C. 17,4 gam hoc 63,3 gam D. 3,36 gam hoc 4,71 gam
Cu 40: Cho 13,35 gam hn hp X gm (CH2NH2CH2COOH v CH3CHNH2COOH) tc dng vi V ml
dung dch NaOH 1 M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch
HCl 1M . Gi tr ca V l
A. 200 ml B. 250 ml C. 100 ml D. 150 ml
------------------- Ht -------------------

P N V HNG DN GII
Cu 1: un nng dung dch cha 27 gam glucoz vi AgNO3/NH3, gi s hiu sut phn ng l 75%
thy Ag kim loi tch ra. Khi lng Ag kim loi thu c l:
HD: nAg = 2.nglucoz (p) = 2. (27/180).0,75 = 0,225 mol 24,3 gam
Cu 2: phn bit cc dung dch ring bit: Al(NO3)3, FeCl3, KCl, MgCl2, c th dng dung dch:
A. HCl. B. HNO3. C. Na2SO4. D. NaOH.
Cu 3: thu c kim loi Fe t dung dch Fe(NO3)2 theo phng php thu luyn, c th dng
kim loi no sau y:
A. Zn. B. Fe. C. Na. D. Ca.
Cu 4: Cho t t n d kim loi Na vo dung dch c cha mui FeCl3. S phn ng xy ra l:
A. 4 B. 2 C. 3 D. 5
HD : 2Na + 2H2O 2Na+ + 2OH- + H2
Fe3+ + 3OH- Fe(OH)3
Cu 5: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung
dch Fe(NO3)3. Hai kim loi X, Y ln lt l:
A. Ag, Mg B. Cu, Fe C. Fe, Cu D. Mg, Ag
Cu 6: Cho cc cht sau : Ba(HSO3)2 ; Cr(OH)2; NaHS; NaHSO4; NH4Cl; CH3COONH4; C6H5ONa;
ClH3NCH2COOH. S cht va tc dng vi NaOH va tc dng vi HCl l:
A. 4 B. 5 C. 2 D. 3
Cu 7: Cho cc dung dch: X1: dung dch HCl X2: dung dch KNO3 X3: dung dch Fe2(SO4)3.
Dung dch no c th ho tan c bt Cu:
A. X2,X3 B. X1,X2,X3 C. X1, X2 D. X3
Cu 8: Cho cc cht: Metyl amin, Sobitol, glucoz, Etyl axetat v axit fomic. S cht tc dng c vi
Cu(OH)2 l:
A. 3 B. 4 C. 2 D. 5
Cu 9: Cho 20 gam hn hp 3 amin: Metyl amin, etyl amin, propyl amin tc dng va vi V ml
dung dch HCl 1M. Sau phn ng c cn dung dch thu c 31,68 g mui khan. Gi tr ca V l:

A. 240ml B. 320 ml C. 120ml D. 160ml
HD: p dng BTKL ta c m(HCl) = mmui - mamin = 11,68 gam 0,32 mol => V = 0,32 lt
Cu 10: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn:
A. St ng vai tr catot v b oxi ho. B. Km ng vai tr catot v b oxi ho.
C. Km ng vai tr anot v b oxi ho. D. St ng vai tr anot v b oxi ho.
Cu 11: Polime no d b thu phn trong mi trng kim:
A. ( CH2-CH=CH-CH2 )n B. ( CH2-CH2-O )n
C. ( CH2-CH2 )n D. ( HN-CH2-CO )n
Cu 12: Cho dy cc cht: Al, Al2O3, AlCl3, Al(OH)3. S cht trong dy va phn ng c vi dung
dch NaOH, va phn ng c vi dung dch HCl l:
A. 2. B. 4. C. 1. D. 3.
Cu 13: Cho s bin ha sau (mi mi tn l 1 phn ng):
X G T metan
E
Y + HCl axit metacrylic F polimetyl metacrylic
Trong s cc cng thc cu to sau y:

(1) CH2 = C(CH3)COOC2H5. (2) CH2 = C(CH3)COOCH3.
(3) . CH2 = C(CH3)OOCC2H5. (4) . CH3COOC(CH3) = CH2.
(5) CH2 = C(CH3)COOCH2C2H5.
C bao nhiu cng thc cu to ph hp vi E:
A. 4. B. 1. C. 3. D. 2.
Cu 14: Ho cht no sau y c th s dng phn bit 3 dung dch sau: NaCl, ZnCl2 v AlCl3.
A. Dung dch Na2SO4 B. Dung dch NH3
C. Dung dch NaOH D. Dung dch H2SO4 long
Cu 15: Cng thc tng qut ca aminoaxit no cha hai nhm amino v mt nhm cacboxyl, mch h
l:
A. CnH2n+2O2N2 B. CnH2n+O2N2 C. Cn+H2n+O2N2 D. CnH2n+3O2N2
Cu 16: Cacbon monoxit (CO) c trong thnh phn chnh ca loi kh no sau y:
A. Kh m du B. Kh thin nhin C. Khng kh D. Kh l cao
Cu 17: un nng 6 gam CH3COOH vi 6 gam C2H5OH (c H2SO4 c lm xc tc) hiu sut phn ng
este ha bng 50%. Khi lng este to thnh l:
HD : Do n(CH3COOH) < n(C2H5OH) nn Hiu sut tnh theo CH3COOH

neste = (6/60).0,5 = 0,05 mol 4,4 gam
Cu 18: Trng hp khng xy ra phn ng ho hc l:
A. Fe + dung dch FeCl3. B. Fe + dung dch HCl.
C. Cu + dung dch FeCl3. D. Cu + dung dch FeCl2.
Cu 19: Cht khng c phn ng thy phn l :
A. Etyl axetat. B. Gly-Ala. C. saccaroz D. Fructozo.
Cu 20: Ho tan 7,8 gam hn hp gm Al v Mg bng dung dch HCl d. Sau phn ng khi lng dung
dch axit tng thm 7 gam. Khi lng Al v Mg trong hn hp ban u l:
A. 1,2 gam v 6,6 gam B. 5,4 gam v 2,4 gam
C. 1,7 gam v 3,1 gam D. 2,7 gam v 5,1 gam
Cu 21: Cho hn hp X gm Fe3O4, Cu vo dung dch HCl d thy cn mt phn cht rn cha tan. Vy
cc cht tan trong dung dch sau phn ng l:
A. FeCl3, FeCl2, CuCl2 B. FeCl2, CuCl2, HCl C. FeCl3, CuCl2, HCl D. FeCl3, FeCl2, HCl
Cu 22: Cho hai mui X, Y tha mn iu kin sau:
X + Y khng xy ra phn ng X + Cu khng xy ra phn ng
Y + Cu khng xy ra phn ng X + Y + Cu xy ra phn ng

X, Y l mui no di y :
A. Fe(NO3)3 v NaHSO4. B. NaNO3 v NaHCO3.
C. NaNO3 v NaHSO4. D. Mg(NO3)2 v KNO3.
Cu 23: Cho m gam Mg vo dung dch c cha 0,8 mol Fe(NO3)3 v 0,05 mol Cu(NO3)2, n phn ng
hon ton thu c 14,4 gam cht rn.Gi tr ca m l:
A. 15,6 gam. B. 24 gam C. 8,4 gam. D. 6 gam.
HD : Cht rn sau phn ng gm : Cu ( 0,05 mol 3,2 gam ) v Fe ( 11,2 gam 0,2 mol )
dung dch sau phn ng cha : Mg2+ ; Fe2+ ( 0,6 mol ) v NO3- ( 2,5 mol)
Theo BTT : n(Mg2+) = 0,65 mol => m(Mg) = 15,6 gam
X, T Qu tm Qu tm chuyn mu xanh
Y, Z Cu(OH)2 Dung dch xanh lam
X,T Dung dch FeCl3 Kt ta nu
X, Y, Z, T ln lt l:
A. Etylamin, glucoz, saccaroz, trimetylamin. B. Etylamin, saccaroz, glucoz, anilin.

C. Anilin, etylamin, saccaroz, glucoz. D. Etylamin, glucoz, mantoz, trimetylamin.
Cu 25: Thuc th duy nht phn bit 4 dung dch BaCl2, H2SO4, HCl, NaCl b mt nhn l
A. BaCl2 B. Qu tm C. HCl D. Ba(OH)2
Cu 26: S ng phn n chc, mch h, tc dng vi NaOH m khng tc dng vi Na c cng
thc phn t C4H8O2 l:
A. 2. B. 3. C. 6. D. 4.
HD : vit cc ng phn este
Cu 27: Ho tan ht m gam Fe bng 400 ml dung dch HNO3 1M. Sau khi phn ng xy ra hon ton thu
c dung dch cha 26,44 gam cht tan v kh NO (sn phm kh duy nht). Gi tr ca m l:
A. 5,60. B. 12,24. C. 6,12. D. 7,84.
HD : - Nu HNO3 d th cht tan thu c cha Fe(NO3)3 v HNO3 d
Gi a l s mol HNO3 phn ng => n(NO) = n(Fe) = a/4
242.a/4 + (0,4 a) 63 = 26,44 => a <0 ( loi)
Vy HNO3 ht, cht tan ch cha mui : n(NO) = n(HNO3) = 0,1 mol
=> n(NO3-)mui = 0,3 mol => m + 0,3.62 = 26,44 => m = 7,84 gam
Cu 28: Mnh no sau y khng ng:
A. m in ca cc kim loi kim gim dn t Li n Cs.
B. Cc nguyn t kim loi kim th u tc dng vi nc gii phng H2.
C. Cc kim loi Na, K, Ba u tc dng vi dung dch HCl gii phng H2.
D. Nng lng ion ha I1 ca kim loi kim gim dn t Li n Cs.
NH3 X Y Z
CH I
3 HNO
2 CuO
Cu 29: Cho s phn ng: (1:1) t0 . Bit Z c kh nng tham gia phn
ng trng gng. Hai cht Y v Z ln lt l :
A. CH3OH, HCHO. B. C2H5OH, CH3CHO. C. CH3OH, HCOOH. D. C2H5OH, HCHO.
Cu 30: Cho 5 gam bt Mg vo dung dch hn hp KNO3 v H2SO4, un nh, trong iu kin thch hp,
n khi phn ng xy ra hon ton thu c dung dch A cha m gam mui; 1,792 lt hn hp kh B
(ktc) gm hai kh khng mu, trong c mt kh ha nu ngoi khng kh v cn li 0,44 gam cht rn
khng tan. Bit t khi hi ca B i vi H2 l 11,5. Gi tr ca m l:
A. 31,08 B. 29,34. C. 27,96. D. 36,04.
HD : Kh B gm NO ( 0,06 mol ) v H2 ( 0,02 mol ) ; nMg (p) = 0,19 mol
Theo nh lut bo ton electron : n(NH4+) = (0,19.2 0,06.3 - 0,02.2)/8 = 0,02 mol
Do to H2 nn NO3- ht nn : n(KNO3) = 0,06 + 0,02 = 0,08 mol
Dung dch A cha : Mg2+( 0,19 mol) ; K+ (0,08 mol); NH4+ ( 0,02 mol ) v SO42- ( 0,24 mol )
m = 31,08 gam

Cu 31: t chy hon ton 29,2 gam hn hp X gm anehit acrylic, metyl axetat, anehit axetic
v etylen glicol thu c 1,15 mol CO2 v 23,4 gam H2O. Mt khc, khi cho 36,5 gam hn hp X
trn tc dng ht vi dung dch AgNO3 trong NH3 th thu c ti a m gam Ag. Gi tr gn nht
ca m l:
A. 64,8 B. 43,5 C. 53,9 D. 81,9
HD : Cc hp cht trong X gm C3H4O; C3H6O2; C2H4O v C2H6O2
Trong 29,2 gam hn hp X : m(O) = 29,2 1,15.12 1,3.2 = 12,8 gam 0,8 mol
t : n(C3H4O) + n(C2H4O) = a mol ; n(C3H6O2) + n(C2H6O2) = b mol
a + 2b = 0,8 v n(H2O) = 2a + 3b = 1,3 => a = 0,2 ; b = 0,3
Trong 36,5 gam X : nandehit = 0,25 mol => nAg = 0,5 mol 54 gam
Cu 32: t chy hon ton a mol cht bo A thu c b mol CO2 v c mol nc, bit b-c= 5a. Khi
hidro ha hon ton m gam A cn va 2,688 lt H2 (ktc) thu c 35,6 gam sn phm B. Mt khc
thy phn hon ton m gam A trung tnh bng mt lng dung dch NaOH va , ri c cn thu c x
gam x phng. Gi tr ca x l:
A. 36,24. B. 12,16. C. 12,08. D. 36,48.
HD : Trong A c s lin kt l 6 => 3 c kh nng cng c H2 ( cc gc hidrocacbon)
n(A) = 0,12/3 = 0,04 mol v m = 35,6 0,12.2 = 35,36 gam
Khi thy phn : n(NaOH)p = 0,12 mol ; nglixerol = 0,04 mol
Theo BTKL : x = 35,36 + 0,12.40 0,04.92 = 36,48 gam
Cu 33: Hn hp A gm ba peptit mch h X, Y, Z c t l mol tng ng l 2 : 3 : 4. Thy phn hon
ton m gam A thu c hn hp sn phm gm 21,75 gam Glyxin v 16,02 gam Alanin. Bit s lin kt
peptit trong phn t X nhiu hn trong Z v tng s lin kt peptit trong ba phn t X, Y, Z nh hn 17.
Gi tr ca m l:
A. 30,93. B. 31,29. C. 30,57. D. 30,21.
HD : Ta c Gly : Ala = 29 : 18 tng s mt xch ca T l bi s ca ( 29 + 18 )k = 47k ( vi k l s
nguyn dng)
Tng s lin kt peptit l 16 k t max khi Z cha 15 mt xch ( ng vi 14 lin kt peptit) , Y
cha 2 mt xch ( ng vi 1 lin kt peptit), X cha 2 mt xch (( ng vi 1 lin kt peptit) 47k
2.2 + 2. 3 + 4. 15 k 1,48 k = 1
Quy i 3 peptit X, Y, Z thnh mt peptit G cha 47 mt xch gm 29 Gly v 18 Ala, ng thi gii
phng ra 8 phn t H2O.
C nG = 0,29 : 29 = 0,01 mol
2X + 3Y + 4Z 29Gly-18Ala + 8H2O
m=mG + mH2O = 0,01. (29. 75 + 18. 89-46.18) +0,08. 18 = 30,93 gam.
Cu 34: Chn pht biu ng:

A. Trong 4 kim loi : Ba, Sn, Cr, Cu ch c 2 kim loi c th c iu ch bng phn ng nhit nhm
B. Nhng mt thanh Sn vo dung dch NiCl2 thy xut hin n mn in ha
C. Kim loi dn in tt hn c l Ag, kim loi c tnh do nht l Au
D. Kim loi Be c mng tinh th lp phng tm din
Cu 35: T glucozo bng mt phng trnh phn ng trc tip c th iu ch c:
A. HCOOH. B. CH3-CH(OH)-COOH.
C. CH3COOH. D. C3H7OH.
Cu 36: Cht hu c A khng tc dng vi Na. un nng A trong dung dch NaOH ch to ra mt mui
ca -aminoaxit c mch cacbon khng nhnh, cha mt nhm amino vi hai nhm cacboxyl v mt
ancol n chc. Thu phn hon ton mt lng cht A trong 100 ml dung dch NaOH 1M ri em c
cn, thu c 1,84 gam ancol B v 6,22 gam cht rn khan D. un nng lng ancol B trn vi H2SO4
c 170oC thu c 0,672 lt olefin (ktc) vi hiu sut l 75%. Cho ton b cht rn D tc dng vi
dung dch HCl d ri c cn th thu c cht rn khan E (khi c cn khng xy ra phn ng). Khi
lng cht rn E gn nht:
A. 8,4 B. 8,7 C. 10.2 D. 9,5
HD : nancol = 0,03.100/75 = 0,04 mol => NaOH phn ng = 0,04 mol , nmui = 0,02 mol
Cht rn D gm : NaOH d ( 0,06 mol) v mui => mmui = 3,82 gam => Mmui = 191
Maminoaxit = 191 44 = 147 : H2NC3H5(COOH)2
Khi cho D + HCl thu c : ClH3NC3H5(COOH)2 ( 0,02 mol ) v NaCl ( 0,1 mol)
m(E) = 9,52 gam
Cu 37: Cho kim loi M tc dng vi Cl2 thu c mui X. Mt khc, cho kim loi M tc dng vi dung
dch HCl thu c mui Y. Cho mui Y tc dng vi Cl2 li thu c mui X. Vy M c th ng vi kim
loi no sau y:
A. Fe B. Cu C. Ni D. Ba
Cu 38: x mol CO2 vo dung dch a mol Ba(OH)2 v b mol NaOH sinh ra c mol kt ta. kt qu ta c
th sau
Gi tr ca a l:
A.0,1 B. 0,15 C.0,2 D.0,25
HD : Khi n(CO2) = 0,4 mol th nkt = 0,05 mol => 0,05 = 2a + b 0,4 => 2a + b = 0,45
on th i ngang coi nh CO2 tc dng vi NaOH to NaHCO3 => b = 0,25 mol => a = 0,1

Cu 39: Cho m gam Fe vo dung dch AgNO3 c hn hp X gm 2 kim loi. Chia X lm 2 phn.
- Phn 1: c khi lng m1 gam, cho tc dng vi dung dch HCl d, c 0,1 mol kh H2.
- Phn 2: c khi lng m2 gam, cho tc dng ht vi dung dch HNO3 long d, c 0,4 mol kh NO.
Bit m2 m1 = 32,8. Gi tr ca m bng:
A. 1,74 gam hoc 6,33 gam B. 33,6 gam hoc 47,1 gam
C. 17,4 gam hoc 63,3 gam D. 3,36 gam hoc 4,71 gam
HD : Phn 1 : n(Fe) = 0,1 mol , nAg = a mol
Phn 2 : nFe = 0,1n mol v nAg = a.n mol
Ta c : m2 m1 = 5,6n + 108a.n 5,6 108.a = 32,8 => 5,6.n + 108.a.n 108 a = 38,4
Mt khc : Bo ton electron ta c 0,3.n + a.n = 1,2
n = 3 hoc n = 108/67
- Khi n = 3 =>a = 0,1 => Trong X : nFe = 0,4 mol v nAg = 0,4 mol
=> nFe b = 0,4 + 0,2 = 0,6 mol 33,6 gam
- Khi n = 108/67 => a = 4/9 => Trong X : Fe ( 35/134 mol) , Ag ( 700/603)
=> Fe(b) = 1015/1206 mol 47,131 gam
Cu 40: Cho 13,35 gam hn hp X gm (CH2NH2CH2COOH v CH3CHNH2COOH) tc dng vi V ml
dung dch NaOH 1 M thu c dung dch Y. Bit dung dch Y tc dng va vi 250 ml dung dch
HCl 1M . Gi tr ca V l
A. 200 ml B. 250 ml C. 100 ml D. 150 ml
HD : nX = 13,35 : 89 = 0,15 mol . X cha cc cht c 1 nhm NH2 nn ta c
n(HCl) = n(NaOH) + nX => n(NaOH) = 0,25 0,15 = 0,1 mol => V = 0,1 lt = 100 ml
------------------- Ht -------------------

THPT HONG HOA THM Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Dn 8,96 lt CO2 ( ktc) vo 600 ml dung dch Ca(OH)2 0,5M. Phn ng kt thc thu c m
gam kt ta. Ga tr ca m l
A. 40 B. 30 C. 25 D. 20
Cu 2: C 4 dd ng trong 4 l ha cht mt nhn l (NH4)2SO4, K2SO4, NH4NO3, KOH, nhn bit 4
cht lng trn, ch cn dng dung dch
A. BaCl2. B. NaOH. C. Ba(OH)2. D. AgNO3
Cu 3: Hp cht no sau y tc dng c vi vng kim loi?
A. Khng c cht no. B. Axit HNO3 c nng.
C. Dung dch H2SO4 c nng. D. Hn hp axit HNO3 v HCl c t l s mol 1:3.
Cu 4: in phn 200 ml dung dch mui CuSO4 trong thi gian, thy khi lng dung dch gim 8 gam.
Dung dch sau in phn cho tc dng vi dd H2S d thu c 9,6g kt ta en. Nng mol ca dung
dch CuSO4 ban u l
A. 2M B. 1,125M C. 0,5M D. 1M
Cu 5: Cho kh CO d i qua hn hp gm CuO, Al2O3, MgO (nung nng). Khi phn ng xy ra hon
ton thu c cht rn gm
A. Cu, Al2O3, Mg. B. Cu, Al, MgO. C. Cu, Al, Mg. D. Cu, Al2O3, MgO
Cu 6: in phn hon ton 200ml dung dch AgNO3 vi 2 in cc tr thu c mt dung dch c
pH=2. Xem th tch dung dch thay i khng ng k th lng Ag bm catot l
Cu 7: C cc dung dch Al(NO3)3, NaNO3, Mg(NO3)2, H2SO4. Thuc th phn bit cc dd l
A. dd BaCl2. B. dd NaOH. C. dd CH3COOAg. D. qi tm.
Cu 8: Nguyn liu chnh dng sn xut nhm l
A. qung lmit B. qung boxit. C. qung manhetit. D. qung pirit.
Cu 9: Cc nguyn t thuc nhm IIA c cu hnh electron lp ngoi cng l
A. ns1np 2 B. ns 2 C. np 2 D. ns1sp1
Cu 10: Cho 8,40 gam st vo 300 ml dung dch AgNO3 1,3 M. Lc k cho phn ng xy ra hon ton
thu c m gam cht rn. Gi tr ca m l
A. 16,20 B. 42,12 C. 32,40 D. 48,60
Cu 11: Cho dy chuyn ho sau: Fe FeCl3 FeCl2 Fe NO3 3 . X, Y, Z ln lt l:
X Y Z
A. Cl2, Fe, HNO3. B. Cl2, Cu, HNO3. C. Cl2, Fe, AgNO3. D. HCl, Cl2, AgNO3.
Cu 12: Ch dng mt thuc th duy nht no sau y phn bit hai kh SO2 v CO2?
A. dd Ba(OH)2. B. H2O. C. dd Br2. D. dd NaOH.
Cu 13: Hn hp X gm Fe v Cu, trong Cu chim 43,24% khi lng. Cho 14,8 gam X tc dng ht
vi dung dch HCl thy c V lt kh (ktc) bay ra. Gi tr ca V l
A. 1,12 B. 3,36 C. 2,24 D. 4,48
Cu 14: C 5 l ng ring bit cc kh sau: N2, NH3, Cl2, CO2, O2. xc nh l ng kh NH3 v Cl2
ch cn dng thuc th duy nht l
A. dung dch BaCl2. B. qu tm m. C. dd Ca(OH)2. D. dung dch HCl.
Cu 15: Cho dung dch NaOH (d) vo dung dch cha hn hp FeCl2 v CrCl3, thu c kt ta X.
Nung X trong khng kh n khi lng khng i thu c cht rn Y. Vy Y l
A. Fe2O3. B. CrO3. C. FeO. D. Fe2O3 v Cr2O3.
Cu 16: Ho tan 5,6 gam Fe bng dung dch HNO3 long (d), sinh ra V lt kh NO (sn phm kh duy
nht, ktc). Gi tr ca V l

A. 2,24 B. 3,36 C. 4,48 D. 6,72
Cu 17: Hai kim loi u phn ng vi dung dch Cu(NO3)2 gii phng kim loi Cu l
A. Fe v Au. B. Al v Ag. C. Cr v Hg. D. Al v Fe.
Cu 18: Cu hnh electron no di y c vit ng?
A. 26 Fe2 Ar 3d 4 4s 2 B. 26 Fe3 Ar 3d 5 C. 26 Fe2 Ar 4s 2 3d 4 D. 26 Fe Ar 4s1 3d 7
Cu 19: Cho cc kim loi: Ni, Fe, Cu, Zn; s kim loi tc dng vi dung dch Pb(NO3)2 l
A. 4 B. 3 C. 2 D. 1
Cu 20: Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch
cht in li th cc hp kim m trong Fe u b n mn trc l:
A. II, III v IV. B. I, III v IV. C. I, II v III. D. I, II v IV.
Cu 21: Dung dch cht no sau y lm qu tm ha xanh?
A. Alanin. B. Anilin. C. Metylamin. D. Glyxin.
Cu 22: Cho cc hp kim sau: Al Zn (1); Fe Zn (2); Zn Cu (3); Mg Zn (4). Khi tip xc vi dung
dch axit H2SO4 long th cc hp kim m trong Zn b n mn in ha hc l
A. (2), (3) v (4). B. (3) v (4). C. (1), (2) v (3). D. (2) v (3).
Cu 23: Mt loi nc cng khi un si th mt tnh cng. Trong loi nc cng ny c ha tan nhng
cht no sau y?
A. Ca(HCO3)2, MgCl2. B. Mg(HCO3)2, CaCl2.
C. Ca(HCO3)2, Mg(HCO3)2. D. CaSO4, MgCl2.
Cu 24: C cc th nghim sau
(a) Cho kim loi Na vo dung dch CuSO4;
(b) Sc CO2 n d vo dung dch Ca(OH)2;
(c) Cho t t dung dch NaOH n d vo dung dch Al2(SO4)3;
(d) Cho t t dung dch NaOH n d vo dung dch FeCl3;
Sau khi kt thc cc phn ng, s th nghim thu c kt ta l
A. 1 B. 4 C. 3 D. 2
Cu 25: Cht khng c kh nng ha tan c Cu(OH)2 l
A. axit axetic. B. Ala-Ala-Gly. C. glucoz. D. Phenol.
Cu 26: Tripeptit l hp cht m phn t c
A. hai lin kt peptit, ba gc -aminoaxit. B. hai lin kt peptit, ba gc -aminoaxit.
C. ba lin kt peptit, hai gc -aminoaxit. D. ba lin kt peptit, ba gc -aminoaxit.
Cu 27: Trong ht nhn nguyn t, ht mang in l
A. proton v electron. B. electron. C. proton. D. proton v notron.
Cu 28: Xenluloz c cu to mch khng phn nhnh, mi gc C6H10O5 c 3 nhm -OH, nn c th
vit
A. [C6H7O3(OH)2]n. B. [C6H5O2(OH)3]n. C. [C6H7O2(OH)3]n. D. [C6H8O2(OH)3]n.
Cu 29: Polime c iu ch bng phn ng trng ngng l
A. nilon-6,6. B. polietilen.
C. poli(metyl metacrylat). D. poli(vinyl clorua).
Cu 30: X phng ha hon ton 2,96 gam HCOOC2H5 bng mt lng dung dch KOH va . C cn
dung dch sau phn ng, thu c m gam mui khan. Gi tr ca m l
A. 3,36. B. 2,52 C. 4,20 D. 2,72
Cu 31: t chy hon ton 8,96 lt (ktc) hn hp M gm 2 anken ng ng lin tip X; Y (MX < MY)
ri dn ton b sn phm chy ln lt qua bnh I ng P2O5 d v bnh II ng dung dch Ca(OH)2 d
thy khi lng bnh I tng m gam v khi lng bnh II tng (m + 39) gam. Phn trm th tch anken Y
trong M l
A. 80,00. B. 75,00. C. 33,33. D. 40,00.
Cu 32: Ha tan hon ton 3,92 gam hn hp X gm Al, Na v Al2O3 vo nc (d) thu c dung dch
Y v kh H2. Cho 0,06 mol HCl vo X th thu c m gam kt ta. Nu cho 0,13 mol HCl vo X th thu
c (m 0,78) gam kt ta. Phn trm khi lng Na c trong X l
A. 44,01 B. 41,07 C. 46,94 D. 35,20
Cu 33: Cho t t n d dung dch Ba(OH)2 vo cc dung dch sau:
(1) Dung dch NaHCO3. (2) Dung dch Ca(HCO3)2. (3) Dung dch MgCl2.
(4) Dung dch Na2SO4. (5) Dung dch Al2(SO4)3. (6) Dung dch FeCl3.

(7) Dung dch ZnCl2. (8) Dung dch NH4HCO3.
Sau khi kt thc cc phn ng, s trng hp thu c kt ta l
A. 6 B. 5 C. 8 D. 7
Cu 34: Cho 50,0 gam hn hp X gm Fe3O4 v Cu vo dung dch HCl d. Kt thc phn ng cn li
20,4 gam cht rn khng tan. Phn trm khi lng ca Cu trong hn hp X l
A. 40,8 B. 53,6 C. 20,4 D. 40,0
Cu 35: Hn hp X gm C3H8, C2H4(OH)2 v mt s ancol no, n chc, mch h (C3H8 v C2H4(OH)2
c s mol bng nhau). t chy hon ton 5,444 gam X ri hp th ton b sn phm chy vo dung dch
Ba(OH)2 d thy khi lng bnh tng ln 16,58 gam v xut hin m gam kt ta. Gi tr ca m l
A. 47,477. B. 43,931. C. 42,158. D. 45,704.
Cu 36: Ha tan ht 27,2 gam hn hp rn X gm Fe3O4, Fe2O3 v Cu trong dung dch cha 0,9 mol HCl
(dng d), thu c dung dch Y c cha 13,0 gam FeCl3. Tin hnh in phn dung dch Y bng in
cc tr n khi catot bt u c kh thot ra th dng in phn, thy khi lng dung dch gim 13,64
gam. Cho dung dch AgNO3 d vo dung dch sau in phn, kt thc phn ng thy kh NO thot ra (sn
phm kh duy nht); ng thi thu c m gam kt ta. Gi tr ca m gn nht vi gi tr no sau y?
A. 116,89. B. 118,64. C. 116,31. D. 117,39.
Cu 37: Hn hp E gm este X n chc v axit cacboxylic Y hai chc (u mch h, khng no c mt
lin kt i C=C trong phn t). t chy hon ton mt lng E thu c 0,43 mol kh CO2 v 0,32 mol
hi nc. Mt khc, thy phn 46,6 gam E bng 200 gam dung dch NaOH 12% ri c cn dung dch thu
c phn hi Z c cha cht hu c T. Dn ton b Z vo bnh ng Na, sau phn ng khi lng bnh
tng 188,85 gam ng thi thot ra 6,16 lt kh H2 (ktc). Bit t khi ca T so vi H2 l 16. Phn trm
khi lng ca Y trong hn hp E c gi tr gn nht vi gi tr no sau y?
A. 41,3%. B. 43,5% C. 48,0%. D. 46,3%.
Cu 38: Thu phn hon ton m gam tetrapeptit X mch h thu c hn hp Y gm 2 amino axit (no,
phn t cha 1 nhm -COOH, 1 nhm -NH2) l ng ng k tip. t chy hon ton hn hp Y cn
va 58,8 lt khng kh (cha 20% O2 v th tch, cn li l N2) thu c CO2, H2O v 49,28 lt N2 (cc
kh o ktc). S cng thc cu to tho mn ca X l
A. 8 B. 12 C. 4 D. 6
Cu 39: Hn hp X gm glixerol, metan, ancol etylic v axit no, n chc mch h Y, trong s mol
metan gp hai ln s mol glixerol. t chy ht m gam X cn 6,832 lt O2 (ktc), thu c 6,944 lt CO2
(ktc).Nu cho m gam hn hp X tc dng vi 80 ml dung dch NaOH 2,5M, ri c cn dung dch sau
phn ng ththu c a gam cht rn khan. Gi tr ca a l
A. 10,88. B. 14,72. C. 12,48. D. 13,12.
Cu 40: Hn hp X gm Al, Al2O3, Fe v cc oxit ca st trong O chim 18,49% v khi lng. Ha
tan ht 12,98 gam X cn va 627,5 ml dung dch HNO3 1M thu c dung dch Y v 0,448 lt hn
hp Z (ktc) gm NO v N2 c t l mol tng ng l 1:1. Lm bay hi dung dch Y thu c m gam
mui. Gi tr ca m l
A. 60,272. B. 51,242. C. 46,888. D. 62,124.
Chobitnguyntkhicaccnguynt:
H =1, Li= 7, Be =9, C = 12, N = 14, O = 16, F =19, Na = 23, Mg = 24, Al = 27, S =32, Cl =
35,5, K = 39, Ca = 40, Cr = 52 ; Mn =55, Fe = 56, Cu = 64, Zn = 65, Br =80, Sr = 88, Ag = 108; I =127,
Ba=137, Pb =208.

P N V HNG DN GII CHI TIT
1-D 6-C 11-D 16-A 21-C 26-B 31-B 36-A
2-C 7-B 12-C 17-D 22-D 27-C 32-B 37-D
3-D 8-B 13-B 18-B 23-C 28-C 33-D 38-C
4-D 9-B 14-B 19-B 24-D 29-A 34-B 39-C
5-D 10-B 15-A 20-B 25-D 30-A 35-D 40-C
Cu 1
nCO2 0, 4mol ; nOH 0, 6mol
C: nCO2 nOH 2nCO2 phn ng to 2 mui
nCO3 nOH nCO2 0, 2 mol nCa2 0,3mol
=> Sau phn ng c lng kt ta l : 0,2 mol CaCO3
=> mCaCO3 20 g
=> D
Cu 2
Khi dng Ba(OH)2 th:
+) (NH4)2SO4: C kt ta trng v si bt kh
NH4 2 SO4 Ba OH 2 2NH3 BaSO4 2H 2O
K2 SO4 Ba OH 2 2NH3 Ba NO3 2 2H 2O
+) NH4NO3: c si bt kh
2 NH 4 NO3 Ba OH 2 2NH3 Ba NO3 2 2H 2O
+) KOH: khng hin tng (khng phn ng vi Ba(OH)2)
=> C
Cu 3
Vng c th tan trong nc cng toan vi thnh phn gm HNO3 v HCl vi t l mol tng ng l 1:3
=> p n D
Cu 4
Qu trnh in phn c th xy ra cc phn ng:
Catot (-): Cu 2 2e Cu
2H 2O 2e H 2 2OH *
Anot(+): 2 H 2O 4 H O2 4e
Sau in phn: Cu 2 S 2 CuS (en) nCu 2 d = nCuS 0,1 mol
=> Chng t Cu 2 d => cha c qu trnh (*)
Gi s mol Cu 2 b in phn l x mol nO2 0,5 x mol
mdd giam mCu mO2 64 x 32.0,5 x 8 g x 0,1 mol
nCu2 bd nCu2 du nCu 2 dp 0, 2 mol
CM CuSO4 1M
=> p n D
Cu 5
CO ch kh c oxit ca kim loi ng sau Al trong dy in ha
=> p n D
Cu 6
Dung dch sau in phn c pH 2 c H+
Vy cc qu trnh din ra khi in phn l:
Catot(-): Ag 1e Ag
Anot(+): 2 H 2O 4 H O2 4e
CM 10 pH 0, 01M nH 0, 002 mol
H


Bo ton e: nAg nH 0, 002 mol
mAg 0, 216 g
=> p n C
Cu 7
Khi dng NaOH th:
+) Al(NO3)2: c kt ta keo trng, sau kt ta tan ra
Al NO3 2 3NaOH Al OH 3 3NaNO3
Al OH 3 NaOH NaAlO2 2H 2O
+) NaNO3: Khng c hin tng g (khng c phn ng)
+) Mg(NO3)2: c kt ta trng
Mg NO3 2 2 NaOH Mg OH 2 2NaNO3
+) H2SO4: khng c hin tng g (c phn ng)
Vi 2 cht NaNO3 v H2SO4. Sau khi thu c kt ta trng t bnh Mg(NO3)2
Nh 2 cht trn vo kt ta nu kt ta tan th l H2SO4.
Mg OH 2 H 2 SO4 MgSO4 2H 2O
=> p n B
Cu 8: p n B
Cu 9: p n B
Cu 10:
nFe 0,15 mol ; nAgNO3 0,39 mol
Fe 2 AgNO3 Fe NO3 2 2 Ag
0,15 ->0,3 -> 0,15mol
Fe NO3 2 AgNO3 Fe NO3 3 Ag
0,09 <- 0,09 mol
nAg 0,39 mol
mAg 42,12 g
=> p n B
Cu 11
Cc phn ng
Fe 3 / 2Cl2 FeCl3
2 FeCl3 Fe 3FeCl2
2 FeCl3 Cu 2FeCl2 CuCl2
FeCl2 HNO3 Fe NO3 3 FeCl3 H 2O N xOy
FeCl2 3 AgNO3 Fe NO3 3 2 AgCl Ag
=> p n D
Cu 12:
SO2 mi c th lm mt mu nc Brom theo phn ng:
SO2 Br2 2H 2O H 2 SO4 2HBr
=> p n C
Cu 13:
Trong X c: nFe = 0,15 mol (ch c Fe phn ng vi HCl)
Fe 2 HCl FeCl2 H 2
nH 2 0,15 mol VH 2 3,36 lit
=> p n B
Cu 14:
Vi qu tm m:
+) NH3: lm qu tm m ha xanh
+) Cl2: lm qu tm m ha sau mt mu
=> p n B
Cu 15
FeCl2 2 NaOH Fe OH 2 2 NaCl
CrCl3 3 NaOH Cr OH 3 3NaCl
Cr OH 3 NaOH NaCrO2 2 H 2O
Ch thu c kt ta Fe OH 2 . Sau nung ln:
1 1
Fe OH 2 O2 H 2O Fe OH 3
4 2
2Fe OH 3 Fe2O3 3H 2O
=> p n A
Cu 16
Bo ton e: 3.nFe 3.nNO nNO 0,1mol
VNO 2, 24 lit
=> p n A
Cu 17:
Cc kim loi ng trc Cu u c th y Cu 2 ra khi mui ca n.
=> p n D
Cu 18: p n B
Cu 19
Cc kim loi ng trc Pb u c th y Pb 2 ra khi mui ca n.
l: Ni, Fe, Zn
=> p n B
Cu 20
Trong mt pin in ha, Anot(-) xy ra s oxi ha
Fe b n mn trcc th Fe phi l Anot(-) [c th in cc m hn hay tnh kh mnh hn]=> p n
B
Cu 21
Metylamin(CH3NH2) l mt cht c tnh bazo mnh
=> p n C
Cu 22
Trong mt pin in ha, Anot(-) x ra s oxi ha
Zn b n mn trc th Zn phi l Anot(-) [c th in cc m hn hay tnh kh mnh hn]=> p n
D
Cu 23
Loi nc cng khi un si th mt tnh cng => Nc cng tm thi
Ch c Ca 2 ; Mg 2 ; HCO3
=> p n C
Cu 24
1
(a) Na H 2O NaOH H 2
2
2NaOH CuSO4 Cu OH 2 Na2 SO4
(b) CO2 Ca OH 2 Ca HCO3 2
(c) 6 NaOH Al2 SO4 3 3Na2 SO4 2 Al OH 3
Al OH 3 NaOH NaAlO2 2H 2O
(d) 3NaOH FeCl3 Fe OH 3 3NaCl
Ch c (a) v (d)
=> p n D
Cu 25: p n D
Cu 26: p n B
Cu 27: p n C
Cu 28: p n C
Cu 29: p n A
Cu 30:
HCOOC2 H5 KOH HCOOK C2 H5OH
0,04 mol -> 0,04 mol
=> mmui = 3,36g
=> p n A
Cu 31
Khi t chy anken th nCO2 nH 2O a mol
m I tng = mH2O ; mII tng = mCO2
mII mI 44a 18a 39 g a 1,5 mol
nanken 0, 4 mol S C trung bnh = 3,75
=> 2 anken l C3H6 v C4H8 vi s mol ln lt l x v y
x y 0, 4; nCO2 3 x 4 y 1,5
x 0,1; y 0,3
% VY 75%
=> p n B
Cu 32:
X + H2O d khng thy c kt ta => Al v Al2O3 tan kt
1
Na H 2O NaOH H 2
2
3
NaOH Al H 2O NaAlO2 H 2
2
2 NaOH Al2O3 2 NaAlO2 H 2O
Khi thm HCl, c th c:
NaOH HCl NaCl2 H 2O
NaAlO2 HCl H2O Al OH 3 NaCl
Al OH 3 3HCl AlCl3 3H 2O
thm 0,07 mol HCl th ch lm tan 0,01 mol kt ta
=> chng t khi thm 0,06 mol HCl th NaAlO2 vn cn d
Gi s mol NaOH d = a; s mol NaAlO2 vn cn d
+) nHCl 0,06 mol; nHCl AlO2 0,06 a mol b a b 0,06mol
=> nkt ta = 0,06 a mol m / 78
+) nHCl 0,13 mol nHCl 4nNaAlO2 3nAl OH nNaOH d
3
0,13 4b 3. 0, 06 a 0, 01 a
0, 28 4b 4a
a b 0,07 mol nNa X
%mNa X 41,07%
=> p n B
Cu 33
Cc trng hp c kt ta l: (1), (2), (3), (4), (5), (6), (8)
=> p n D
Cu 34
Fe3O4 8HCl FeCl2 2FeCl3 4H 2O
x -> 2x
Cu 2FeCl3 CuCl2 2FeCl2

x <- 2x
Cht rn cn li chc chn l Cu
=> mphn ng 232 x 64 x 50 20, 4
x 0,1 mol
mCu X 50 232.0,1 26,8g
m%Cu X 53,6%
=> p n B
Cu 35
S mol C3H8 v C2H6O2 bng nhau
=> Qui v C3H8O v C2H6O
Cc cht trong X u c dng Cn H 2 n 2O
Bo ton khi lng: mX mO2 mCO2 mH 2O mbnh tng
nO2 0,348
Cn H2n2O 1,5nO2 nCO2 n 1 H 2O
0,348 -> 0,232 mol
nBaCO3 nCO2 0, 232 mol
m 45, 704 g
=> p n D
Cu 36
Qui hn hp u v: Fe2O3; x mol FeO; y mol Cu
X + HCl d v khng c kt ta sau => Cu phn ng ht
2 FeCl3 Cu 2FeCl2 CuCl2
Y gm 0,08 mol FeCl3; x 2 y mol FeCl2; y mol CuCl2; HCl
0,08.3 2 x 2 y 0,9
Hn hp u gm: 0,04 y mol Fe2O3; x mol FeO; y mol Cu
27, 2 160. 0,04 y 72 x 64 y 1
Khi in phn:
Catot(-): th t c th xy ra
Fe3 1e Fe 2
Cu 2 2e Cu
2H 2e H 2 *
Fe 2 2e Fe
Anot(+):
2Cl Cl2 2e
V ngng in phn khi catot c kh => dng trc qu trnh (*)
1
Bo ton e: nCl2 0, 08 2 y 0, 04 y mol
2
=> mgim mCu mCl2 y.64 0,04 y .71 13,64 g
y 0, 08 mol . T 1 x 0,04 mol
=> Sau in phn cn: nHCl d = 0,1 mol; nFeCl2 0,16 0, 04 0, 08 0, 28 mol
3Fe2 4 H NO3 3Fe3 NO 2 H 2O
0,075 <- 0,1 mol
Fe2 Ag Fe3 Ag
Ag Cl AgCl
=> Kt ta gm: 0,205 mol Ag; 0,66 mol AgCl
m 116,85 g

=> p n A
Cu 37
T c M T 32 CH 3OH
Z gm CH3OH v H2O
E gm: a mol X Cn H 2n2O2 v b mol Y Cm H 2m4O4 u c 1 C=C n 4;m 4
t chy:
Cn H 2n2O2 O2 nCO2 n 1 H 2O
Cm H 2m4O4 O2 mCO2 m 2 H 2O
Khi phn ng vi NaOH
Cn H 2 n 2O2 NaOH mui + ancol
Cm H 2 m4O4 2 NaOH Mui + H2O
=> Ta thy: nCO nH O nX 2nY nNaOH nCOO 0,11 mol
2 2
Bo ton nguyn t: mE mC mH mO 9,32 g

=> Vi 46,6g E th nNaOH p = 0,55 mol => nNaOH d 0,05 mol
=> mbnh tng mH 2 mCH3OH mH 2O 188,85 2.0, 275 189, 4 g
1
H 2 O Na NaOH H2
2
1
CH 3OH Na CH 3ONa H2
2
(Na s thiu)
Bo ton khi lng: mE + mdd NaOH = mrn + mZ
=> mrn = 57,2g
mZ mH2O dd NaOH mH2O Puvoi axit mCH3OH
mH2O Pu voi axit mCH3OH 13, 4 g
nNaOH pu nH 2O nCH 3OH 0,55 mol
mH2O axit 0,3 naxitY 0,15mol; nCH3OH nX 0, 25 mol
46,6 g mE 0, 25. 14n 30 0,15. 14m 60
5n 3m 43
m 5; m 6 tha mn
Y l C6 H8O4 %mY E 46,35%
=> p n D
Cu 38
Trong khng kh c: n O2 0,525 mol; nN2 2,1 mol
nN2 sau phn ng = 2,2 mol => nto ra = 0,1 mol
Hn hp 2 amin no n chc ng ng k tip c cng thc chung l:
Cn H 2n1O2 N 1,5n 0,75 O2 nCO2 n 0,5 H 2O 0,5N2
0,525 mol 0,1 mol
0,525.0,5 0,1. 1,5n 0,75
n 2, 25
=> 2 amino axit l H2NCH2COOH(Gly) v CH3CH(NH2)-COOH(Ala) vi s mol ln lt l x
x y 2nN2 0, 2 mol
nO2 2, 25 x 3, 75 y 0,525
x 0,15; y 0, 05 mol
x : y 3 :1
Vy tetrapeptit c 3Gly v 1Ala
=> S peptit tha mn l: 4

=> p n C
Cu 39
X gm: CH4, C2H6O; C3H8O3; CnH2nO2
nCH 4 2nC3 H8O3 => Qui v CH4O; C3H8O
nCO2 0,31 mol ; nO2 0,305 mol
Coi hn hp gm: Cm H 2 m 2O : c mol ; Cn H 2 nO2 : b mol
nH 2O nCO2 nancol 0,31 c
Bo ton O: nO X 2nO2 2nCO2 nH2O
c 2b 0,305.2 0,31.2 0,31 c
b 0,16 mol
nX 0,16 mol
S C trung bnh nCO2 / b 1,9375
=> axit c 1 C (hn hp ancol c C1 : C2 : C3 )
HCOOH , nNaOH 0, 2 mol
=> cht rn gm: 0,16 mol HCOONa; 0,14 mol NaOH d
a 12, 48 g
=> p n C
Cu 40
Qui hn hp X v Al; Fe; O nO 0,15 mol
nHNO3 0, 6275 mol
nNO nN2 0, 01mol
C nHNO3 2nO 4nNO 12nN2 10nNH 4 NO3
nNH 4 NO3 0, 01675 mol
nNO3 muoi KL 2nO 3nNO 10nN 2 8nNH 4 NO3 0,564 mol
=> mmui = mKL + mNO3 mui KL + mNH 4 NO3 = 46,888g
=> p n C

THPT HN THUYN Mn: KHOA HC T NHIN HA HC

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu tm ha xanh. Trn ln
hai dung dch trn thu c kt ta. Hai cht X v Y tng ng l
A. KNO3 v Na2CO3. B. Ba(NO3)2 v Na2CO3.
C. Ba(NO )
3 2 v K2 SO4 D. Na2SO4 v BaCl2.
Cu 2: Axit no sau y l axit bo?
A. Axit aipic B. Axit glutamic C. Axit stearic D. Axit axetic
Cu 3: Fructoz khng phn ng c vi cht no sau y?
A. Cu(OH)2 nhit thng B. H2 (xc tc Ni, to)
C. nc Br .
2 D. dung dch AgNO3/NH3, to
Cu 4: Ha cht no sau y khng c dng khi sn xut saccaroz trong cng nghip t cy ma?
A Vi sa. B. Kh sunfur. C. Kh cacbonic. D. Phn chua.
Cu 5: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt
phn ng c th chuyn ho X thnh Y. Cht Z khng th l.
A. metyl propionat B. etyl axetat. C. vinyl axetat D. metyl axetat.
Cu 6: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc
dng vi: Na, dung dch NaOH, dung dch NaHCO3, dung dch AgNO3/NH3, to. S phn ng xy ra l
A. 3 B. 5 C. 6 D. 4
Cu 7: Cht kh no sau y c to ra t bnh cha chy v dng sn xut thuc gim au d dy?
A. CO2. B. CO C. CH4 D. N2.
Cu 8: Hai cht ng phn ca nhau l
A. amiloz v amilopectin. B. xenluloz v tinh bt
C. saccaroz v glucoz. D. fructoz v glucoz.
Cu 9: Trong phn t ca cc cacbohyrat lun c
A. nhm chc xetn B. nhm chc axit. C. nhm chc anehit D. nhm chc ancol.
Cu 10: Cho 0,1 mol tristearin tc dng hon ton vi dung dch NaOH d, un nng, thu c m gam
glixerol. Gi tr ca m l
A. 9,2. B. 14,4. C. 4,6. D. 27,6.
Cu 11: iu kin thng, cacbohirat no sau y khng ha tan c Cu(OH)2 .
A. saccaroz B. fructoz C. glucoz D. xenluloz
Cu 12: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste
c to ra ti a l
A. 3 B. 5 C. 6 D. 4
Cu 13: Sn phm ca phn ng nhit phn hon ton AgNO3 l:
A. Ag2O, NO2, O2 B. Ag, NO2, O2 C. Ag2O, NO, O2. D. Ag, NO, O2
Cu 14: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3 0,2M
v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A. 0,015 B. 0,020 C. 0,010 D. 0,030.
Cu 15: : Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh th KNO3 to
thnh kh Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to thnh kh Z. Cc kh X, Y v Z ln
lt l
A. SO2, O2 v Cl2 B. Cl2, O2 v H2S. C. H2, O2 v Cl2. D. H2, NO2 v Cl2.
Cu 16: C th phn bit 3 dung dch: KOH, HCl, H 2 SO4 (long) bng mt thuc th l
A. giy qu tm B. BaCO3. C. Al D. Zn
Cu 17: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 1,80gam B. 2,25gam C. 1,82gam D. 1,44gam
Cu 18: C th dng NaOH ( th rn) lm kh cc cht kh
A. NH3, SO2, CO, Cl2. B. N2, Cl2, O2, CO2, H2.
N
C. 2 , NO2 , CO 2 , CH4 , H2 D. NH3, O2, N2, CH4, H2
Cu 19: Isoamyl axetat l este c mi chui chn c khi lng phn t l
A. 116 B. 144 C. 102 D. 130
Cu 20: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) vo
4 dung dch trn, thm tip dung dch NH3 c (d) vo th sau khi kt thc cc phn ng s cht kt ta
thu c l
A. 3 B. 2 C. 4 D. 1
Cu 21: Trong cc th nghim sau:
(1) Cho SiO2 tc dng vi axit HF.
(2) Cho kh SO2tc dng vi kh H2S.
(3) Cho kh NH3 tc dng vi CuO un nng.
(4) Cho CaOCl2 tc dng vi dung dch HCl c.
(5) Cho Si n cht tc dng vi dung dch NaOH.
(6) Cho kh O3 tc dng vi Ag.
(7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng
S th nghim to ra n cht l
A. 4 B. 5 C. 6 D. 7
Cu 22: Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz B. mt gc -glucoz v mt gc -fructoz C. mt gc
-glucoz v mt gc -fructoz D. hai gc -glucoz
Cu 23: Tc nhn ch yu gy ma axit l
A. SO2 v NO2 B. CH4 v NH3 C. CO v CH4 D. CO v CO2.
Cu 24: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu
vi dung dch HNO3 c, nng l
A. 8 B. 10 C. 11 D. 9
Cu 25: iu kin thch hp xy ra cc phn ng sau:
(a) 2C + Ca CaC2. (b) C + 2H2 CH4.
(c) C + CO2 2CO. (d) 3C + 4Al Al4C3.
Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng
A. (a) B. (b) C. (c) D. (d)
Cu 26: : Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc Br2?
A. CH3CH2CH2OH B. CH3CH2COOH C. CH2=CHCOOH D. CH3COOCH3.
Cu 27: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5%
(D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l
A. 36 B. 60 C. 24 D. 40
Cu 28: Cacbohirat no sau y thuc loi isaccarit?
A. Xenluloz B. Glucoz C. Saccaroz D. Amiloz
Cu 29: t chy 24,48 gam hn hp X gm glucoz v saccacroz cn dng 0,84 mol O2. Mt khc
un nng 24,48 gam X trong mi trng axit, thu c hn hp Y gm cc hp cht hu c. Cho ton b
Y tc dng vi lng d dung dch AgNO3/NH3 un nng, thu c m gam Ag
Cc phn ng xy ra hon ton. Gi tr ca m l
Cu 30: un nng 14,64 gam este X (C7H6O2) cn dng 120 gam dung dch NaOH 8%. C cn dung
dch thu c lng mui khan l
Cu 31: Ha tan ht m gam kim loi M cn dng 136 gam dung dch HNO3 31,5%. Sau khi kt thc phn
ng thu c dung dch X v 0,12 mol kh NO duy nht. C cn dung dch X thu c (2,5m + 8,49) gam
mui khan. Kim loi M l
A. Ca B. Mg C. Zn D. Cu

Cu 32: Hn hp X gm OHC-CC-CHO; HOOC-CC-COOH, OHC-CC-COOH. Cho m gam hn
hp X tc dng vi dd AgNO3 trong nc amoniac d (un nng nh) thu c 43,2 gam Ag. Mt khc
m gam hn hp X tc dng vi NaHCO3 d thu c 11,648 lt CO2 (ktc). Thm m gam glucoz vo
m gam hn hp X sau em t cn 60,032 lt O2 (ktc), sn phm sinh ra c hp th vo dung dch
Ba(OH)2 d thu c 614,64 gam kt ta. Gi tr ca (m+ m) l
A. 94,28 B. 88,24 C. 96,14 D. 86,42
Cu 33: X, Y, Z, T l mt trong s cc dung dch sau: glucoz; fructoz; glixerol; phenol. Thc
hin cc th nghim nhn bit chng v c kt qu nh sau:
Cht Y Z X T
Dung dch Xut hin kt Xut hin kt ta
AgNO3/NH3, un nh ta bc trng bc trng
Nc Br2 Nht mu Xut hin kt ta
trng
Cc dung dch X, Y, Z, T ln lt l.
A. fructoz, glucoz, glixerol, phenol B. phenol, glucoz, glixerol, fructoz
C. glucoz, fructoz, phenol, glixerol D. fructoz, glucoz, phenol, glixerol
Cu 34: t chy hon ton 10,58 gam hn hp X cha ba este u n chc, mch h bng lng oxi
va , thu c 8,96 lt kh CO2 (ktc). Mt khc, hiro ha hon ton 10,58 gam X cn dng 0,07 mol
H2 (xc tc, to) thu c hn hp Y. un nng ton b Y vi 250 ml dung dch NaOH 1M, c cn dung
dch sau phn ng, thu c mt ancol Z duy nht v m gam rn khan. Gi tr ca m l
A. 15,60 B. 15,46 C. 13,36 D. 15,45
Cu 35: Thy phn hon ton cht bo X trong mi trng axit, thu c axit oleic v axit stearic c t l
mol tng ng 1:2. Khi lng phn t ca X l
A. 886 B. 890 C. 884 D. 888
Cu 36: t chy X cng nh Y vi lng oxi va , lun thu c CO 2 c s mol bng s mol O2
phn ng. Bit rng X, Y (MX < MY) l hai este u mch h, khng phn nhnh v khng cha nhm
chc khc. un nng 30,24 gam hn hp E cha X, Y (s mol ca X gp 1,5 ln s mol Y) cn dng 400
ml dung dch KOH 1M, thu c hn hp F cha 2 ancol v hn hp cha 2 mui. Dn ton b F qua
bnh ng Na d thy khi lng bnh tng 15,2 gam. t chy hon ton hn hp mui cn dng 0,42
mol O2. Tng s nguyn t c trong Y l
A. 21 B. 20 C. 22 D. 19
A. Hiro ha hon ton glucoz (xc tc Ni, un nng) to ra sorbitol
B. Xenluloz tan tt trong nc v etanol
C. Saccaroz c kh nng tham gia phn ng trng bc.
D. Thy phn hon ton tinh bt trong dung dch H2SO4, un nng, to ra fructoz
Cu 38: T m gam tinh bt iu ch ancol etylic bng phng php ln men vi hiu sut ca c qu
trnh l 75%. Lng CO2 sinh ra t qu trnh trn c hp th hon ton vo dung dch Ca(OH)2 thu
c 50 gam kt ta v dung dch X. Thm dung dch NaOH 1M vo X, lng kt ta thu c l ln
nht th cn ti thiu 100 ml dung dch NaOH 1M. Gi tr ca m l
A. . 75,6 gam B. 64,8 gam C. 84,0 gam D. 59,4 gam
Cu 39: Ha tan 8,4 gam Fe vo 500 ml dung dch X gm HCl 0,2M v H2SO4 0,1M. C cn dung dch
thu c sau phn ng th thu c bao nhiu gam mui khan?
Cu 40: C bn dung dch ring bit c nh s: (1) H2SO4 1M, (2)HCl 1M; (3)KNO3 1M v
(4)HNO3 1M. Ly ba trong bn dung dch trn c cng th tch trn vi nhau, ri thm bt Cu d vo,
un nh, thu c V lt kh NO (ktc). Hi trn vi t hp no sau y th th tch kh NO l ln nht?
A. (1), (2) v (3) B. (1), (2) v (4) C. (1), (3) v (4) D. (2), (3) v (4)

p n
1 B 11 D 21 C 31 C
2 C 12 C 22 B 32 B
3 C 13 B 23 A 33 A
4 D 14 C 24 B 34 A
5 A 15 C 25 C 35 D
6 C 16 B 26 C 36 A
7 A 17 B 27 D 37 A
8 D 18 D 28 C 38 A
9 D 19 D 29 D 39 D
10 A 20 D 30 A 40 B
HNG DN GII
Cu 1: Chn B
Ta c dung dch Y lm qu tm ha xanh loi p n C,D v K2SO4 v BaCl2 khng lm i mu qu
tm. Trn dung dch X v Y li vi nhau thu c kt ta loi A, chn B
PTHH: Ba(NO3)2 + Na2CO3 BaCO3 +2NaNO3
Cu 2: Chn C
Axit Stearic l axit bo, c cng thc l C17H35COOH. Ch : Axit bo l axit n chc, c mch
Cacbon khng phn nhnh v s nguyn t C chn (C12 C24).
Cu 3: Chn C
Fructoz khng phn ng c vi nc Brom.
Ch : Fructoz c tnh cht ca 1 ancol a chc nn n tc dng c vi dung dch Cu(OH)2 , c tnh
cht ca xeton nn tc dng vi H2 to thnh Sobitol. Mc d n khng c nhm CHO nhng vn c
phn ng trng gng v tc dng vi Cu(OH)2/OH, t0 v trong mi trng baz tn ti cn bng:
OH

Fructozo Glucozo

Cu 4: Chn D
Trong qu trnh sn xut ma t saccaroz khng dng n phn chua. Ngi ta dng vi sa loi b
tp cht, dng kh cabonic lc b CaCO3, dng kh sunfur ty mu.
Cu 5: Chn A
Phn tch: Thy phn este Z trong mi trng axit thu c 2 cht hu c X, Y trong MX < MY nn
Y l axit hu c, cn X l ancol hoc anehit, xeton. Bng 1 phn ng c th chuyn ha X thnh Y vy
ta c:
A. Metyl propionat

CH3CH 2COOCH3
H
CH3CH 2COOH CH3OH
T CH3OH khng th chuyn ha thnh CH3CH2COOH bng 1 phn ng.
B. Etyl axetat
H

CH3COOCH 2CH3 CH3COOH C2 H5OH
C2 H 5OH O2
men giam
CH 3COOH H 2O
C. Vinyl axetat

CH3COOCH CH 2 H
CH 3COOH CH 3CHO H 2O
1 Mn 2
CH 3CHO O2 to
CH 3COOH
2
D. Metyl axetat
H

CH 3COOCH 3 CH 3COOH CH 3OH
CH3OH CO CH 3COOH
o
t
Cu 6: Chn C
Cc ng phn n chc, mch h c cng thc phn t l C2H4O2 l CH3COOH, HCOOCH3

CH3COOH l axit nn c th tc dng vi Na, NaOH, NaHCO3, AgNO3/NH3
1
CH 3COOH Na CH 3COONa H 2 ; CH 3COOH NaOH CH 3COONa H 2O
2
CH 3COOH NaHCO3 CH 3COONa CO2 H 2O ;
CH 3COOH NH 3 CH 3COONH 4
HCOOCH3 c phn ng trng bc v NaOH
Ch : Nhiu em s khng chn c p n v ng phn ca C2H4O2 cn c OH CH2 CHO.
Nhng cc em qun rng OH CH2 CHO l tp chc trong khi bi yu cu l n chc.
Hoc l cc em s qun 1 ch quan trng l cc axit tr HCOOH s khng tham gia phn ng trng
gng nhng s xy ra phn ng axit vi baz
Cu 7: Chn A
Cht kh c to ra t bnh cha chy v dng sn xut thuc gim au d dy l CO2 . V CO2 c
khn nng dp tt m chy v n iu ch c NaHCO3 l cht lm gim au d dy.
Cu 8: Chn D
Hai cht l ng phn ca nhau l Glucoz v Fructoz, u c cng thc l C6H12O6
Ch : Nhiu em s chn p n B l xenluloz v tinh bt l ng phn ca nhau v cng c cng thc
l (C6H10O5)n nhng qun mt rng ch s n c th khc nhau.
Cu 9: Chn D
Trong phn t ca cacbohyrat lun c nhm ancol.
Cu 10: Chn A
(C17 H 35COO)3 C3 H 5 3NaOH 3C17 H 35COONa C3 H 5 (OH )3
0,1 0,1
Ta c: nglixerol ntristearin 0,1 mol mglixerol 0,1.92 9, 2 g
Cu 11: Chn D
iu kin thng xenluloz khng ha tan c Cu(OH)2
Cu 12: Chn C
S trieste c to thnh khi cho glixerol tc dng vi 2 axit bo l 6
C17 H 35COO 3 C3 H 5 ; C15 H 31COO 3 C3 H 5 ; C17 H 35COO,C17 H 35COO, C15 H 31COO C3H 5 ;
(C17 H 35COO, C15 H 31COO, C17 H 35COO )C3 H 5 ; Cu 13:
(C15 H 31COO, C15 H 31COO, C17 H 35COO )C3 H 5 ; (C15 H 31COO, C17 H 35COO, C15 H 31COO )C3H 5 ;
Chn B
1
Khi nhit phn hon ton AgNO3 l AgNO3 to
Ag NO2 O2
2
Cu 14: Chn C
Nh t t 0,03 mol HCl vo 0,02 mol Na2CO3 v 0,02 mol NaHCO3 th trc tin c phn ng:
H CO32 HCO (1)
0, 02 0, 02 0, 02
H HCO3 CO2 H 2O (2)
0,01 0,04 0,01
T (1) suy ra: nH (1) nCO2 0, 02mol nHCl (con lai) 0, 03 0, 02 0, 01mol
3
nHCO 0,02 0,02 0,04

3
T (2) suy ra sau phn ng (2) HCO3 d, H ht nn s mol CO2 tnh theo
HCl nCO2 nHCl 0, 01mol
Cu 15: Chn C
Fe H 2 SO4 FeSO4 H 2 ( X )
1
Nhit phn KNO3: KNO3 KNO2 O2 Y
o
t

5
KMnO4 8HCl KCl MnCl2 Cl2 ( Z ) 4 H 2O
2
Vy cc kh X,Y,Z ln lt l H2, O2, Cl2.
Cu 16: Chn B
Ta cho BaCO3 ln lt vo cc dung dch KOH, HCl, H2SO4 ta thy hin tng sau:
Mu no va c kh thot ra va c kt ta xut hin th l mu H2SO4.
BaCO3 H 2 SO4 BaSO4 CO2 H 2O
Mu no ch c kh thot ra th mu l HCl
BaCO3 2 HCl BaCl2 CO2 H 2O
Mu cn li khng c hin tng g l mu KOH.
Cu 17: Chn B
OH CH2 [(OH) CH]4CHO + H2 OH CH2 [(OH) CH ]4CH2OH (Sobitol)
1,82
nGlucoz = nsobitol = = 0,01mol
182
0, 01.180
Vi hiu sut 80% th lng Glucoz cn dng l: 2, 25 g
80%
Cu 18: Chn D
Ch : lm kh cc kh th cc kh khng phn ng vi cht cn dng. Vy y ta c th dng
NaOH lm kh cc kh m khng phn ng vi NaOH.
A. Loi v c SO2 , Cl2 tc dng c vi NaOH
B. Loi v c CO2 , Cl2 tc dng c vi NaOH
C. Loi v c CO2 ,NO2 tc dng c vi NaOH
Cu 19: Chn D
Este Isoamyl axetat c cng thc l: CH3COOCH2CH2CH(CH3)2 C7H14O2
Vy phn t khi ca Isoamyl axetat l 130 g/mol.
Cu 20: Chn D
Cho KOH d ln lt vo cc cht, sau li thm NH3 d vo, ta c PTHH
1. CuCl2 KOH + CuCl2 Cu(OH)2 +2KCl
Cu(OH)2 + 4NH3 [Cu(NH3 )4 ](OH)2
2. ZnCl2 KOH + ZnCl2 Zn(OH)2 +2KCl
Zn(OH)2 + 4NH3 [Zn(NH3 )4 ](OH)2
3. FeCl3 KOH + FeCl3 Fe(OH)3 +3KCl
4. AlCl3 KOH + AlCl3 Al(OH)3 +3KCl
KOH + Al(OH)3 KAlO2 + 2H2O
Vy cui cng ch c FeCl3 l to kt ta
Cu 21: Chn C
(a) Cho SiO2 tc dng vi axit HF: SiO2 + 4HF SiF4 + 2H2O
(b) Cho SO2 tc dng vi H2S: SO2 + 2H2S 3S +2H2O
(c) Cho NH3 tc dng vi CuO: 2NH3 + 3CuO 3Cu + N2 + 3H2O
(d) Cho CaOCl2 tc dng vi HClc: CaOCl2 + 2HClc CaCl2 + Cl2 + H2O
(e) Cho Si tc dng vi NaOH Si + 2NaOH+ H2O Na2SiO3 + 2H2
(f) Cho O3 tc dng vi Ag: O3 + 2Ag Ag2O +O2
(g) Cho NH4Cl tc dng vi NaNO2 un nng:NH4Cl + NaNO2 NaCl+ N2 +2H2O
Vy s n cht c to thnh l: 6
Cu 22: Chn B
Mt phn t saccaroz c 1 gc -glucoz v 1 gc - fructoz lin kt vi nhau.
Cu 23: Chn A
Tc nhn ch yu gy ma axit l: SO2 v NO2
Cu 24: Chn B
Cu+ 4HNO3 c nng Cu(NO3 )2 +2NO2 + 2H2O
Tng h s tt c cc cht trong phng trnh l: 1+4+1+2+2=10
Cu 25: Chn C
Tnh kh ca Cacbon l s tng s oxi ha ca Cacbon

(a) 2C 0 Ca CaC21 loi
(b) C 0 2 H 2 C 4 H 4 loi
(c) C 0 C 4O2 C 2O Chn
(d) 3C 0 4 Al Al4C34 loi
Cu 26: Chn C
Cht va tc dng c vi NaOH, va tc dng c vi Br2 th l este hoc axit khng no. Vy
chnh l CH2 = CH COOH
Cu 27: Chn D
C6 H 7O2 OH 3 n 3nHNO3
H 2 SO4
C6 H 7O2 ONO2 3 n xenlulozo trinitrat 3nH 2O
540 180
53460
nxenlulozo trinitrat 180 mol .
297
V hiu sut l 60% nn s mol HNO3 cn dng l:
180 56700
.3 900mol mHNO3 900.63 56700 g mdd 60000 g
60% 94,5%
m 60000
Ta c mdd=V.D V dd = = 40000ml =40 l
D 1,5
Cu 28: Chn C
Cacbohirat thuc loi isaccarit l Saccaroz.
Ch : Nhm isaccarit l nhng cht khi thy phn thu c 2 monosaccarit gm Saccaroz v
Mantoz.
Cu 29: Chn D
Gi s mol Glucoz v Saccaroz ln lt l x,y mol
C6H12O6 +6O2 6CO2 + 6H2O
C12H22O11 + 12O2 12CO2 + 11H2O
m 180 x 342 y 24, 48 x 0, 06

nO2 6 x 12 0,84 y 0, 04
Khi thy phn X ch c Saccaroz b thy phn:
Saccaroz Glucoz+Fructoz
0,04 0,04 0,04
Sau khi thy phn : nglucoz = 0,06+ 0,04 = 0,1; nfructoz = 0,04
Glucozo
AgNO3 / NH 3
2 Ag Fructozo AgNO3 / NH 3
2 Ag
Ta c:
0,1 0, 2 0, 04 0, 08
Vy tng s mol Ag l: 0,2+0,08=0,28 mol. mAg = 0,28.108 = 30,24g
Cu 30: Chn A
14, 64 120.8%
nX 0,12mol , nNaOH 0, 24
122 40
X tc dng vi NaOH theo t l 1:2 , m X c CT l C7H6O2 nn X c dng HCOOC6H5
HCOOC6 H 5 2 NaOH HCOONa C6 H 5ONa H 2O
0,12 0, 24 0,12 0,12
C cn dung dch thu c m gam mui khan.
Vy m = mHCOONa + m C6 H 5ONa = 0,12.68 +0,12.116 = 22,08g
Cu 31: Chn C
n 0,56 2 x
M : n

M HNO3 ;0, 68 NO3 : 0,56 x NO : 0,12 H 2O

NH 4 : x


136.31,5%
nHNO3 0, 68mol Gi s mol NH 4 l x mol
63
p dng nh lut bo ton nguyn t N ta c:
nHNO3 nNO nNH nNO nNO 0,68 0,12 x 0,56 x
3 4 3
p dng nh lut bo ton in tch cho dung dch X ta c:

0,56 2 x
n.nM n nNH nNO nM n
4 3
n
n
M M ne N 5 3e N 2
N 5 8e N 3
p dng nh lut bo ton e ta c:
0,56 2 x
.n 0,12.3 8 x x 0, 02
n
Ta c: mX mM mNO mNH m (0,56 0,02).62 0,02.18 2,5m 8, 49 m 16,9 g
3 4
0,52 0,52 M 65
Ta c: nM mM .M 16,9 M : Zn
n n n 2
Cu 32: Chn B
Hn hp X ta c th quy i v CHO, COOH v C
CHO : 0, 2
COOH : 0,52

O2 : 2, 68 CO2 : 3,12 H 2O : 0,36 6b(1)
C : a
C6 H12O6 : b
1 1 43, 2
Ta c nCHO 2nAg nCHO nAg . 0, 2
2 2 108
11, 648
nCOOH nNaHCO3 nCO2 0,52
22, 4
Gi s mol C v C6H12O6 ln lt l a,b mol.
Sau khi thm m gam C6H12O6 vo m gam X ri t chy ta c:
614,64
nCO2 (1) nBaCO3 3,12 0, 2 0,52 a 6b a 6b 2, 4 2
197
p dng nh lut bo ton H vo (1), ta c:
60,032
nH 2O 1 2 nCHO nCOOH 6b 0,36 6b; nO2 1 2,68
22, 4
T (1) ta c: nCO2 ( X ) nCO2 (1) nCO2 ( C6 H12O6 ) 3,12 6b ; nH 2O ( X ) 0,36
Ta c X u c dng C4H2On nn khi t chy s cho t l mol
CO2 : H 2O 4 : 1 3,12 6b 0,36.4 b 0, 28.
T (2) suy ra a=0,72
Vy m + m = 0,2.29 +0.52.45 +0,72.12 + 0,28.180 = 88,24g
Cu 33: Chn A
Y va c phn ng trng bc va lm nht mu nc Brom vy Y l Glucoz.
Z va khng tham gia phn ng trng bc, va khng lm nht mu nc Brom vy Z l Glixerol.
T khng tham gia trng bc nhng khi tc dng vi nc Brom li xut hin kt ta trng, vy T l
Phenol.
X c tham gia phn ng trng bc nhng khng tc dng vi dung dch Brom, vy X l Fructoz.
Cu 34: Chn A
t chy 10,58g hn hp X gm 3 este n chc, mch h ta c: nCO2 = 0,4 mol.
Mt khc hiro ha hon ton 10,58g hn hp X cn 0,07 mol H2. Vy 0,07 mol H2 chnh l s mol lin
kt trong mch Cacbon ca 3 este.
nCO2 nH 2O 0, 07 nH 2O 0, 4 0, 07 0,33
p dng nh lut bo ton khi lng cho phn ng t chy ta c:
mX mO2 mCO2 mH 2O mO2 0, 4.44 0,33.18 10,58 12,96 g nO2 0, 405 p dng
nh lut bo ton nguyn t O ta c:
0, 4
2nX 2nO2 2nCO2 nH 2O nX 0,16 mol nC 2,5
0,16
Vy phi c 1 este c 2C. Vy este phi l HCOOCH3 .
Theo bi ta thy thy phn Y trong NaOH ch thu c 1 ancol duy nht, vy ancol l CH3OH.
Vy CT trung bnh cu 3 este sau khi hiro ha l RCOOCH3(Y)
mY mX mH 2 10,58 0, 07.2 10, 72 g
RCOOCH3 + NaOH RCOONa + CH3OH
O,16 0,25 0,16
mY mNaOH m mCH3OH m 10, 72 0, 25.40 0,16.32 15, 6 g
Cu 35: Chn D
Ta c: Axit oleic l: C17H33COOH, axit stearic l C17H35COOH
Khi thy phn cht bo X thu c axit oleic v axit stearic c t l mol 1:2 nn trong X c 1 nhm
C17H33COO
V 2 nhm C17H35COO . Cht bo lun c dng (RCOO)3C3H5 .
Vy khi lng phn t X l: (281 2.283) 41 888
Cu 36: Chn A
2 Este + KOH 2 mui v 2 ancol (1)
nKOH = 0,4 mol. Vy suy ra khi ancol phn ng vi Na thu c kh H 2 nH 2 0,5nOH 0, 2 mol .
Khi cho ancol tc dng vi Na d thy khi lng bnh tng
15, 2 g mancol mH 2 15, 2 mancol 15, 6 g
p dng nh lut bo ton khi lng cho (1) ta c:
meste mKOH mmuoi mancol mmuoi 30, 24 0, 4.56 15,6 37,04 g
Gi Cng thc chung ca 2 mui l CxHyCOOK
Khi t chy mui cn 0,42 mol O2:
CxHyCOOK: 0, 4 O2 : 0, 42 CO2 K2CO3 : 0, 2 H2O 2
p dng nh lut bo ton nguyn t K, ta c nCx H yCOOK 2nK2CO3 nK2CO3 0, 2
Gi s mol CO2 v H2O ln lt l a, b mol.
p dng nh lut bo ton O vo (2) ta c :
2a b 0, 4.2 0, 42.2 0, 2.3 1,04 3
p dng nh lut bo ton khi lng vo (2) ta c:
mCO2 mH2O 37,04 0, 42.32 0, 2.138 22,88 44a 18b 4
T (3) v (4) suy ra a=0,52 v b=0
T ta suy ra trong c hai mui u khng c H
Gi cng thc mui ca X l KOOC Ca COOK: x mol
Gi cng thc mui ca Y l KOOC Cb COOK: y mol
p dng nh lut bo ton K ta c: 2 x 2 y 0, 4 5
Theo bi ra ta c: x 1,5 y 0 6
T (5) v (6) ta c: x 0,12 v y 0, 08
mmuoi 0,12. 83.2 12a 0,08. 83.2 12b 37,04 3a 2b 8
Este mch h nn c 2 ancol u phi l ancol n chc. Khi t este c s mol CO2 bng s mol O2
phn ng m este 2 chc nn c 2 este u c 8H, cc gc axit khng c H nn tng s H trong 2 gc
ancol ca mi este u l 8H.
Mt khc nF nKOH 0, 4 .
Theo ta tnh trn mancol 15, 6 g MOH 39 2 ancol chnh l CH3OH v C2H5OH.
V MX < MY nn a = 0, b = 4 l nghim duy nht tha mn.

Vy cng thc 2 este l:
X: CH3OOC COOC2H5 v Y: CH3 OOC C C C C COO C2H5
Vy trong Y c 21 nguyn t.
Cu 37: Chn A
B. Sai v Xenluloz khng tan trong nc, khng tan trong cc dung mi hu c.
C. Sai v Saccaroz khng c khn nng trng bc.
D. Sai v khi thy phn hon ton tinh bt trong dung dch H2SO4 , un nng to ra glucoz.
Cu 38: Chn A
(C6H10O5 )n nC6H12O6 2C2H5OH + 2CO2 (1)
Phn tch: Khi cho cho hp thu CO2 vo Ca(OH)2 thu c dung dch X. Cho dung dch NaOH vo X
li thy xut hin kt ta, chng t trong X c Ca(HCO3)2 .
CO2 + Ca(OH)2 CaCO3 + H2O
2CO2 + Ca(OH)2 Ca(HCO3)2
thu c kt ta ln nht khi cho NaOH vo X ta c PTHH:
NaOH +Ca(HCO3)2 CaCO3 + NaHCO3 + H2O
50
nCa HCO3 nNaOH 0,1 mol , nCaCO3 0,5
2
100
nCO2 2nCa HCO3 nCaCO3 0,1.2 0,5 0,7
2
1
T (1) suy ra: ntinh bt nCO2 0,35 mol
2
0,35.162
V hiu sut ca ca qu trnh l 75% nn ta c khi lng tinh bt cn dng l: = 75, 6 g
75%
Cu 39: Chn D
8, 4
nFe 0,15, nHCl 0,5.0, 2 0,1, nH 2 SO4 0,05
56
n H = 0,1 0,05.2 0, 2 mol
Fe 2 H Fe 2 H 2
0,15 0,2 0,1
Vy sau phn ng Fe d , H ht.
1
nFe2 n 0,1 mol
2 H
C cn dung dch sau phn ng s gm Fe2 , Cl , SO4 2 .
Vy khi lng mui khan l: 0,1.56 0,1.35,5 0, 05.96 13,95g
Cu 40: Chn B
Phn tch:
t nH 2 SO4 nHCl nKNO3 nHNO3 1 mol
- Xt trng hp trn H2SO4(1) vi HCl(2) v KNO3(3):
nH 3
nNO3 1
3Cu 8H 2 NO3 3Cu 2 2 NO 4 H 2O
B 3 1
SP 0 0,25 0,75
- Xt trng hp trn H2SO4(1) vi HCl(2) v HNO3(4):
nH 4
nNO3 1
3Cu 8H 2 NO3 3Cu 2 2 NO 4 H 2O
B 4 1
SP 0 0 1
- Xt trng hp trn H2SO4(1) vi KNO3(3) v HNO3(4) :
nH 3

nNO3 2
3Cu 8H 2 NO3 3Cu 2 2 NO 4 H 2O
B 3 2
SP 0 1,75 0,75
- Xt trng hp trn HCl (1)vi KNO3 (3)v HNO3(4)
nH 2

nNO3 2
3Cu 8H 2 NO3 3Cu 2 2 NO 4 H 2O
B 2 2
SP 0 1,875 0,125
Vy khi trn H2SO4(1) vi HCl(2) v HNO3(4) ta s thu c th tch NO l ln nht nu cho hn hp
tc dng vi Cu.

M : 135
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.

Cu 2: Vinyl axetat c cng thc cu to thu gn l:
A. CH3COOCH2-CH3 B. CH3COOCH3
C. CH3COOCH=CH2 D. CH2=CH-COOCH3
Cu 3: Trong iu kin thng, X l cht rn, dng si mu trng. Phn t X c cu trc mch khng
phn nhnh, khng xon. Thy phn X trong mi axit, thu c glucoz.Tn gi ca X l:
A. Fructoz B. Amilopectin C. Xenluloz D. Saccaroz
Cu 7: Glucoz ln men thnh ancol etylic theo phn ng sau:
C6H12O6 men
3035 C0 2C 2 H 5OH 2CO 2
thu c 92 gam C 2H5OH cn dng m gam glucoz. Bit hiu sut ca qu trnh ln men l 60%.
Gi tr m l:
A. 360 B. 108 C. 300 D. 270
Cu 8: un nng 14,6 gam Gly-Ala vi lng d dung dch NaOH. Sau khi phn ng xy ra hon
ton, thu c dung dch cha m gam mui. Gi tr m l:
A. 22,6 B. 18,6 C. 20,8 D. 16,8
Cu 9: Hp cht no di y thuc loi amino axit ?
A. CH3COOC2H5 B. HCOONH4 C. C2H5NH2 D. H2NCH2COOH
Cu 10: Thy phn 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy
ra hon ton, c cn dung dch, thu c m gam cht rn khan. Ga tr ca m l:
A. 8,20 B. 10,40 C. 8,56 D. 3,28
Cu 11: Cho m gam hn hp kim loi Zn, Cu vo dung dch HCl (d). Sau khi cc phn ng xy ra
hon ton, thu c 4,48 lt H 2 (ktc) v 2,0 gam kim loi khng tan. Ga tr ca m l:
A. 8,5 B. 18,0 C. 15,0 D. 16,0
Cu 12: X phng ha tristearin bng NaOH, thu c glixerol v cht X. Cht X l:
A. CH3[CH2]16(COOH)3 B. CH3[CH2]16COOH
C. CH3[CH2]16(COONa)3 D. CH3[CH2]16COONa

Cu 13: Cho dy cc kim loi: Na, Ca, Cu, Fe, K. S kim loi trong dy tc dng vi H 2O to dung
dch baz l:
A. 2 B. 4 C. 3 D. 1
Cu 14: Polime no sau y l polime thin nhin ?
A. Amiloz B. Nilon-6,6 C. Cao su isopren D. Cao su buna
Cu 15: ng fructoz c nhiu trong mt ong, ngoi ra cn c trong cc loi hoa qu v rau xanh
nh i, cam, xoi, rau dip xon, c chuart tt cho sc khe. Cng thc phn t ca fructoz l:
A. C12H22O11 B. C6H12O6 C. C6H10O5 D. CH3COOH
Cu 16: Polime no sau y c cu trc mch phn nhnh ?
A. Amilopectin B. Xenluloz C. Cao su isopren D. PVC
Cu 17: iu kin thng, amin X l cht lng, d b oxi ha khi ngoi khng kh. Dung dch X
khng lm i mu qu tm nhng tc dng vi nc brom to kt ta trng. Amin X l:
A. anilin B. metylamin C. imetylamin D. benzylamin
Cu 18: Cho 9,0 gam glucoz phn ng hon ton vi lng d dung dch AgNO 3 trong NH3 (un
nng), thu c m gam Ag.Ga tr ca m l :
A. 16,2 B. 21,6 C. 5,4 D. 10,8
Cu 19: Hai cht no sau y u tham gia phn ng trng hp to ra polime ?
A. Vinyl clorua v caprolactam B. Axit aminoaxetic v protein
C. Etan v propilen D. Butan-1,3-ien v alanin
Cu 20: Tin hnh phn ng kh oxit X thnh kim loi bng kh CO (d) theo s hnh v:
Oxit X l:
A. Al2O3 B. K2O C. CuO D. MgO
Cu 21: Mt on mch PVC c 1000 mt xch. Khi lng ca on mch l:
A. 12500 vC B. 62500 vC C. 25000 vC D. 62550 vC
Cu 22: Cho C2H4(OH)2 phn ng vi hn hp gm CH 3COOH v HCOOH trong mi trng axit
(H2SO4), thu c ti a s este thun chc l:
A. 3 B. 2 C. 4 D. 1
Cu 23: Ba dung dch: glucoz, saccaroz v fructoz c tnh cht chung no sau y ?
A. un nng vi Cu(OH) 2 c kt ta gch.
B. Ha tan Cu(OH)2 cho dung dch mu xanh lam.
C. u tc dng vi dung AgNO 3/NH3 to kt ta Ag.
D. u tham gia phn ng thy phn.
Cu 24: Cht trng thi lng iu kin thng l:
A. Natri axetat B. Tripanmetin C. Triolein D. Natri fomat
Cu 25: Hn hp X gm Fe2O3, FeO v Cu (trong st chim 52,5% v khi lng). Cho m gam X
tc dng vi 420 ml dung dch HCl 2M d, thu c dung dch Y v cn li 0,2 m gam cht rn
khng tan. Cho dung dch AgNO3 d vo Y thu c kh NO v 141,6 gam kt ta. Bit cc phn
ng xy ra hon ton. Gi tr ca m l:
A. 20 B. 32 C. 36 D. 24
axit, tng s nhm CO-NH- trong 2 phn t l 5 ) vi t l mol X : Y=1 : 3. Khi thy phn hon ton
m gam M thu c 81 gam glyxin v 42,72 gam alanin. Gi tr ca m l:
A. 116,28 B. 109,5 C. 104,28 D. 110,28
Cu 27: Cho 34 gam hn hp X gm 2 este n chc mch h u thuc hp cht thm (t khi hi
ca X so vi O2 lun bng 4,25 vi mi t l mol ca 2 este). Cho X tc dng va vi 175 ml dung

dch NaOH 2M. C cn dung dch sau phn ng thu c hn hp Y gm hai mui khan. Thnh phn
phn trm v khi lng ca 2 mui trong Y l:
A. 46,58% v 53,42% B. 56,67% v 43,33% C. 55,43% v 55,57% D. 35,6% v 64,4%
(a) Thy phn hon ton vinyl axetat bng NaOH thu c natri axetat v andehit fomic.
(b) Polietilen c iu ch bng phn ng trng ngng.
(c) iu kin thng anilin l cht kh.
(d) Tinh bt thuc loi polisaccarit.
(e) iu kin thch hp triolein tham gia phn ng cng hp H 2.
S pht biu ng l:
A. 2 B. 4 C. 5 D. 3
Cu 29: Cho 0,05 mol hn hp 2 este n chc X v Y phn ng va vi dung dch NaOH thu
c hn hp cc cht hu c Z. t chy hon ton Z thu c 0,12 mol CO2 v 0,03 mol Na2CO3
.Nu lm bay hi hn hp Z thu c m gam cht rn khan .Gi tr ca m l:
A. 3,48 B. 2,34 C. 4,56 D. 5,64
Cu 30: Cho cc cht sau: amiloz, amilopectin, saccaroz, xenluloz, fructoz, glucoz. S cht
trong dy b thy phn khi un nng vi dung dch axit v c l:
A. 3 B. 5 C. 6 D. 4
Cu 31: Hn hp no sau y thuc loi ipeptit ?
A. H2 N CH2 CO NH CH(CH3 ) COOH
B. H 2 N CH 2 CH 2 CO CH 2 COOH
C. H 2 N CH 2 CO NH CH 2 CO NH CH 2 COOH
D. H 2 N CH 2 CH 2 CO NH CH 2 CH 2 COOH
Cu 32: ha tan hon ton hn hp X gm 11,2 gam Fe v 4,8 gam Fe 2O3 cn dng ti thiu V
ml dung dch HCl 2M, thu c dung dch Y .Cho dung dch AgNO 3 vo d vo Y thu c m gam
kt ta . Gi tr ca V v m ln lt l:
A. 290 v 83,23 B. 260 v 102,7 C. 290 v 104,83 D. 260 v 74,62
Cu 33: X phng ha hon ton m gam triglixerit X bng lng va NaOH thu c 0,5 mol
gilixerol v 459 gam mui khan. Gi tr ca m l:
A. 444 B. 442 C. 443 D. 445
Cu 34: Cho hn hp X gm 0,56 gam Fe v Mg tc dng vi 250 ml dung dch CuSO4. Sau khi cc
phn ng xy ra hon ton, thu c 0,92 gam kim loi. Nng mol/l ca dung dch CuSO 4 l:
A. 0,02M B. 0,04M C. 0,05M D. 0,10M
Cu 36: Cho 86,3 gam hn hp X gm Na, K, Ba v Al 2O3 (trong oxi chim 19,47% v khi
lng) tan ht vo nc, thu c dung dch Y v 13,44 lt kh H2 (ktc). Cho 3,2 lt dung dch HCl
0,75M vo dung dch Y. Sau khi cc phn ng xy ra hon ton, thu c m gam kt ta. Gi tr ca
m l:
A. 10,4 B. 27,3 C. 54,6 D. 23,4
Cu 37: X phng ha cht bo X, thu c glixerol v hn hp hai mui l natriolat, natri panmitat
c t l mol 1:2. Hy cho bit cht X c bao nhiu cng thc cu to ?
A. 3 B. 4 C. 1 D. 2
A. Tripeptit Gly-Ala-Gly c phn ng mu biure.
B. Lin kt peptit l lin kt CO-NH- gia hai n v -amino axit.
C. Cc dung dch Glyxin, Alanin, Lysin u khng lm i mu qu tm.
D. Polipeptit b thy phn trong mi trng axit hoc kim.

A. 5,92 B. 4,68 C. 2,26 D. 3,46
Cu 40: Thc hin phn ng chuyn ha PVC thnh t clorin bng cch cho Clo tc dng vi PVC.
Trong t clorin, Clo chim 66,67% v khi lng. S mc xch trung bnh ca PVC phn ng vi
1 phn t Clo l:
A. 2 B. 3 C. 4 D. 1
----------HT----------

PHN TCH HNG DN GII
Cu 1: Chn B.
Cu 2: Chn C.
Cng thc cu to CH3COOC2H5 CH3COOCH3 CH3COOCH=CH2 CH2=CH-COOCH3
Tn gi Etyl axetat Metyl axetat Vinyl axetat Metyl acrylat
Cu 3: Chn C.
- Fructoz v saccaroz iu kin thng tn ti dng tinh th mu trng.
- Amilopectin l mt on mch ca tinh bt c mch phn nhnh, l cht rn v nh hnh khng tan
trong nc ngui, trong nc nng (khong 65 oC) to thnh dung dch keo (gi l h dn).
- Xenluloz iu kin thng l cht rn, dng si mu trng, phn t c cu trc mch khng phn
nhnh, khng xon v c cu to t cc mc xch glucoz nn khi thy phn trong mi trng
axit thu c glucoz.
Vy cht rn X cn tm l xenluloz.
Cu 4: Chn D.
xt,p,t o
Cu 5: Chn B.
Cu 6: Chn B.
Cu 7: Chn C.
n C2H5OH 5
- Ta c: n C6H12O6 m C6 H12O6 300 (g)
2.H% 3
Cu 8: Chn C.
14,6
- Ta c: nGlyNa nAlaNa nGly Ala 0,1mol mmui 97nGlyNa 111nAlaNa 20,8(g)
146
Cu 9: Chn D.
- Amino axit l nhng hp cht hu c tp chc phn t cha ng thi nhm amino ( -NH2) v nhm
cacboxyl (-COOH).
Cu 10: Chn D.
0
- Phn ng : CH 3COOC 2 H 5 NaOH
t
CH 3COONa C2 H 5OH
0,1mol 0,04 mol 0,04 mol
m CH 3COONa 3, 28(g)
Cu 11: Chn C.
BT:e
nZn nH2 0,2mol m 65nZn mCu(rn khng tan) 15(g)

Cu 12: Chn D.
0
Cu 13: Chn C.
- Cu khng tc dng vi H 2O trong khi Fe tc dng vi nc nhit cao to thnh cc oxit st
tng ng.
Vy c 3 kim loi Na, Ca v K trong dy tc dng vi nc nhit thng to dung dch baz
ln lt l NaOH, Ca(OH) 2 v KOH.
Cu 14: Chn A.
Polime thin nhin Polime tng hp
amiloz Nilon-6,6, cao su isopren, cao su buna
Cu 15: Chn B.
Cng thc C12H22O11 C6H12O6 (C6H10O5)n CH3COOH
Tn gi Saccaroz Glucoz Tinh bt Axit axetic
Mantoz Fructoz Xenluloz
Cu 16: Chn A.
- Cc polime mch phn nhnh thng gp l amilopectin v glicozen
- Cc polime mch khng gian thng gp l cao su lu ha v nha rezit.
- Cn li l cc polime mch phn nhnh.
Cu 17: Chn A.
- Cht X l anilin (C6H5NH2) khi ngoi khng kh th b oxi trong khng kh oxi ha thnh mu
nu en. Dung dch anilin khng lm i mu qu tm nhng tc dng vi nc brom to kt ta
trng theo phng trnh sau :
Cu 18: Chn D.
- Ta c : nAg 2nC6H12O6 0,1.108 10,8(g)
Cu 19: Chn A.
- Trng hp caprolactam to t capron
CH2 CH2 C O
n CH2 to N (CH2)5 C
CH2 CH2 C N n
H O
- Trng hp vinyl clorua to t poli(vinyl clorua)
n CH2 to, p, xt
CH CH2 CH
Cl Cl n
Cu 20: Chn C.
Vy oxit X l CuO.
Cu 21: Chn B.
- Ta c n = 1000, vy M (CH2 CH(Cl))1000 1000M C2H3Cl 62500
Cu 22: Chn A.
- C 3 este thun cha thu c l: C 2H4(OOCCH3)2, C2H4(OOCH)2 v HCOOCH2CH2OOCCH3.
- Lu : Este thun chc l este m trong phn t ch cha chc este m khng cha cc nhm chc
khc.
Cu 23: Chn B.
A. Sai, Ch c glucoz v fructoz un nng vi Cu(OH) 2 c kt ta gch.
B. ng, Tt c cc cht trn u ha tan Cu(OH) 2 cho dung dch c mu xanh lam.
C. Sai, Ch c glucoz v fructoz tc dng vi dung dch AgNO3/NH3 to kt ta Ag.
D. ng, Ch c saccaroz tham gia phn ng thy phn.
Cu 24: Chn C.
- Cc cht bo c to thnh t cc gc axt bo no thng trng thi rn cn cc cht bo c
to thnh t cc gc axt bo khng no thng trng thi lng.

Cu 25: Chn B.
amol bmol Cu(d ) :0,2m(g)
HCl(d )
- Qu trnh: Fe2O3 ,FeO,Cu
Fe2 ,Cu2 ,Cl ,H (d )
AgNO3
Ag,AgCl NO
m(g) cmol
dung dch Y 141,6(g)
m 143,5nAgCl
BT:Cl
nAgCl nHCl 0,84mol nAg 0,195mol
108
- Khi cho X tc dng vi HCl v dung dch Y tc dng vi AgNO 3 th ta c h sau :
160nFe2O3 72nFeO 64nCu(p ) m m rn 160a 72b 64a 0,8m
a 0, 05
m 56.2a 56b b 0,2

Theo ta c Fe
0,525
0,525
mX m
c 0,035

BT:e
nFeO 2nCu(p ) 3nNO nAg b 2a 3c 0,195
m 32
nHCl 6nFe2O3 2nFeO 4nNO 6a 2b 4c 0,84
Cu 26: Chn C.
XY3 3H 2O
nGly 1,08 9
nAla 0,48 4
(52).nX 9k 4k (52).nZ

mM 57nC2H 3ON 14nCH 2 18nH 2O 104,28(g)
Cu 27: Chn A.
nNaOH
- Nhn thy rng 1 2 , nn trong hn hp este c 1 este c to thnh t phenol (hoc
neste
ng ng). Theo d kin bi ta c M X = 136 (C8H8O2), mc khc dung dch Y ch cha hai mui
khan nn hn hp X cha HCOOCH2C6H5(A) v HCOOC6H4CH3 (B) .
- Khi cho X tc dng vi NaOH th:
2nA nB nNaOH 2nA nB 0,35 nB 0,15mol
mmui 68nHCOONa 116nCH 3C6H 4ONa 36,5(g) %mHCOONa 46,58 v %mCH3C6H 4ONa 53,42
Cu 28: Chn A.
0
(a) Sai, Phn ng: CH3COOCH=CH2 + NaOH
t
CH3COONa + CH3CHO (andehit axetic)
xt,t o ,p
(b) Sai, Polietilen c iu ch bng phn ng trng hp: CH2 CH2 ( CH2 CH2 ) .
(c) Sai, iu kin thng anilin l cht lng.
(d) ng, Tinh bt v xenluloz thuc loi polisaccarit.
Ni, t 0
(e) ng, Phn ng: (C17 H33COO)3 C3H5 3H 2 (C17 H35COO)3 C3H5
triolein tristearin
Vy c 2 pht biu ng l (d) v (e)
Cu 29: Chn C.

nNaOH
- Nhn thy rng 1 2 , nn trong hn hp este c cha este c to thnh t phenol (hoc
neste
ng ng). Gi 2 este l A v B (vi CA 2 v C B 7)
nA nB 0,05 nA 0,04mol
- Este tc dng vi NaOH th :
nA 2nB nNaOH 0,06 nB 0,01mol
- Khi t hn hp Z th :
BT:C CA 2(HCOOCH 3 )
nA .CA nB.CB nNa2CO3 nCO2 0,04CA 0,01CB 0,15
CB 7(HCOOC6 H 5 )
mmui 68nHCOONa 116nC6H 5ONa 4,56(g)
Cu 30: Chn D.
- C 4 cht trong dy khi thy phn khi un nng vi dung dch axit v c l: amiloz, amilopectin,
saccaroz v xenluloz.
Cu 31: Chn A.
- ipeptit c to thnh t 2 n v - amino axit c s lin kt peptit l 1.
- Lu : cu B, D cht ban u khng c to thnh t cc - amino axit nn khng c gi l
peptit.
Cu 32: Chn B.
0,52
- Ho tan hon ton X th: nHCl(ti thiu) 2nFeCl 2 2(nFe 2nFe2O3 ) 0,52mol VHCl 0,26(l)
2

BT:e
nAg nFeCl 2 0,26mol
- Khi cho dung dch Y tc dng vi AgNO3 th:
nAgCl nHCl(ti thiu) 0,52mol
- Khi : m 108nAg 143,5nAgCl 102,7(g)
Cu 33: Chn D.
- Ta c: nNaOH(p ) 3nC3H 5(OH)3 1,5mol
BTKL
mx phng mmui 40nNaOH 92nC3H5(OH)3 445(g)
Cu 34: Chn B.
TGKL
BT:e

Cu 35: Chn A.
m mamin
nHCl mui
BTKL
36,5
Cu 36: Chn D.
n O(trong X) 86,3.0,1947
- Theo ta c : n Al2O3 0,35mol
3 16.3
- Khi ha tan hn hp X bng nc. Xt dung dch Y ta c:
+ n AlO2 2n Al2O3 0, 7 mol BTDT
n OH 2n H 2 2n AlO 2 0,5 mol
- Khi cho dung dch Y tc dng vi 2,4 mol HCl, v: n AlO2 n n H 4n AlO2 n
OH OH
4n AlO2 (n H n OH )
n Al(OH)3 0,3mol m Al(OH)3 23, 4(g)
3
Cu 37: Chn D.

- Gi A l gc C17H33COO- (oleat) v B l gc C15H31COO- (panmitat)
- X c hai cng thc cu to tha mn vi cc gc sau: A B B v B A B.
Cu 38: Chn C.
A. ng, Cc peptit c 2 lin kt CONH tr ln u tham gia phn ng mu biure.
B. ng, Lin kt peptit l lin kt CO-NH gia hai n v -amino axit.
C. Sai, Ch c lysin lm qu tm ha xanh, cn glyxin v alanin khng lm i mu qu tm.
D. ng, Tt c cc polipeptit b thy phn trong mi trng axit hoc kim.
Cu 39: Chn D.
t0
amol amol amol amol
t0
bmol 2bmol bmol
a 2b 0,05 a 0,01mol
a 0,01 b 0,02mol
Cu 40: Chn A.
- Phn ng: (C2H3Cl)n + Cl2 C2nH3n-1Cln+1 + HCl
35,5(n 1)
- Ta c: %Cl 0,6667 n 2
12.2n 3n 1 35,5(n 1)

S GD V T THANH HO THI TH THPT QUC GIA LN I
TRNG THPT BM SN NM HC 2016-2017
( thi gm c 4 trang) Mn: HO HC
M 065
H v tn th sinh:.......................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t ca cc nguyn t: H=1; C=12; N=14; O=16; Na=23; Mg=24; Al=27;
S=32; Cl=35,5; K=39; Ca=40; Fe=56; Cu=64; Zn=65; Ba=137; Ag =108; Br=80.
Cu 1: Ancol v amin no sau y cng bc?

A. (CH3)3COH v (CH3)2NH. B. (CH3)2CHCH2OH v CH3NHCH(CH3)2.
C. CH3CH(NH2)CH3 v CH3CH2OH. D. (CH3)2CHOH v (CH3)2CHNH2.
Cu 2: Cho s hiu nguyn t ca cc nguyn t sau: Na(Z=11); K(Z=19); Ca(Z=20); Cl(Z=17). Ion no
sau y c cu hnh electron 1s22s22p6?
A. Na+. B. Ca2+. C. K+. D. Cl-.
Cu 3: Trong cc cp cht di y, cp cht no khng cng tn ti trong dung dch?
A. NaCl v Ba(NO3)2. B. AlCl3 v CuSO4.
C. Na2CO3 v KOH. D. NaOH v NaHCO3.
Cu 4: trng thi c bn, cu hnh electron ca nguyn t Mg (Z = 12) l
A. 1s32s22p63s1. B. 1s22s22p63s2. C. 1s22s32p63s2. D. 1s22s22p63s1.
Cu 5: nhn bit ion NO 3 trong dung dch c th dng thuc th no sau y?

A. Dung dch HCl. B. Dung dch NaOH.
C. Dung dch BaCl2. D. Cu v dung dch H2SO4 long.
Cu 6: Nng phn trm ca dung dch to thnh khi ha tan 23 gam natri kim loi vo 178 gam nc
l kt qu no sau y?
A. 22,47%. B. 20,21%. C. 19,90%. D. 20,00%.
Cu 7: S nguyn t H c trong phn t vinyl axetat l
A. 6. B. 10. C. 8. D. 4.
Cu 8: Th nghim no sau y chng t trong phn t glucoz c nhiu nhm OH k nhau?
A. Thc hin phn ng trng bc.
B. Kh hon ton glucoz thnh hexan.
C. Tin hnh phn ng to este ca glucoz vi anhirit axetic.
D. Cho glucoz tc dng vi Cu(OH)2 to dung dch c mu xanh lam.

Cu 9: nh hng ca gc C6H5 n nhm NH2 trong phn t anilin th hin qua phn ng gia anilin
vi cht no sau y?
A. Qu tm (khng i mu). B. Dung dch HCl.
C. Nc brom. D. Dung dch H2SO4.
Cu 10: Hp cht no sau y khng thuc loi ipeptit ?
A. H2N-CH(CH3)CONH-CH2COOH. B. H2N-CH2CH2CONH-CH2-CH2COOH.
C. H2N-CH2CONH-CH2COOH. D. H2N-CH2CONH-CH(CH3)-COOH.
Cu 11: Kim loi no sau y khng kh c ion Cu2+ trong dung dch CuSO4 thnh Cu?
A. Al. B. Mg. C. Fe. D. K.
HCl NaOH
Cu 12: Cho s chuyn ha sau: Alanin X Y
Cht Y l cht no sau y?
A. H2N-CH2-CH2-COOH. B. CH3-CH(NH3Cl)-COONa.
C. CH3-CH(NH3Cl)-COOH. D. CH3-CH(NH2)-COONa.
Cu 13: Hp cht hu c X c cng thc: H2N CH2 COOH. X c tn gi l
A. Glyxin. B. Lysin. C. Valin. D. Alanin.
Cu 14: Trong cc phn ng gia cc cp cht sau, phn ng no thuc loi phn ng tng mach polime?
OH ; t 0
A. Nha Rezol B. poli(vinyl axetat) + H2O
o
t
0 0
C. poli(vinyl clorua) + Cl2
t
D. Poliisopren + HCl
t

Cu 15: Dung dch H2SO4 long phn ng c vi kim loi no sau y?
A. Ag. B. Cu. C. Fe. D. Au.
Cu 16: Cht no sau y khng b thy phn?
A. Tinh bt. B. Fructoz. C. Xenluloz. D. Saccaroz.
Cu 17: Cho s hiu nguyn t ca cc nguyn t sau: Na(Z=11); Mg(Z=12); Al(Z=13); K(Z=19). Dy
no sau y c sp xp theo th t tnh kim loi gim dn?
A. K; Mg; Al; Na. B. Al; Mg; Na; K. C. K; Na; Mg; Al. D. Al; Na; Mg; K.
Cu 18: Phng trnh ha hc no sau y vit sai?
A. Cu + 2FeCl3 CuCl2 + 2FeCl2. B. Cu + 2AgNO3 Cu(NO3)2 + 2Ag.
C. Fe + CuCl2 FeCl2 + Cu. D. Cu + 2HNO3 Cu(NO3)2 + H2.
Cu 19: Este (X) c to thnh t axit axetic v ancol metylic c cng thc phn t l
A. C3H6O2. B. C4H8O2. C. C2H4O2. D. C4H10O2.
Cu 20: Sn phm hu c ca phn ng no sau y c dng ch to t tng hp?
A. Trng hp metyl metacrylat. B. Trng hp polietilen.
C. Trng hp vinyl xianua. D. Trng hp vinyl clorua.

(1) Cho dung dch NaOH vo dung dch Ca(HCO3)2.
(2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(3) Sc kh H2S vo dung dch FeCl3.
(4) Sc kh NH3 ti d vo dung dch AlCl3.
(5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 3. B. 5. C. 4. D. 2.
Cu 22: un nng 45,54 gam hn hp E gm hexapeptit X v tetrapeptit Y cn dng 580 ml dung dch
NaOH 1M ch thu c dung dch cha mui natri ca glyxin v valin. Mt khc, t chy cng lng E
trn trong oxi va thu c hn hp CO2, H2O, N2, trong tng khi lng ca CO2 v H2O l
115,18 gam. Cng thc phn t ca peptit Y l
A. C14H26N4O5. B. C17H32N4O5. C. C11H20N4O5. D. C18H32N4O5.
Cu 23: Cho dy cc cht: benzyl axetat, anlyl axetat, vinyl fomat, etyl fomat, tripanmitin. S cht trong
dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l
A. 5. B. 4. C. 3. D. 2.
Cu 24: Cho hn hp gm Fe v Mg vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu
c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong dung dch X l
A. Mg(NO3)2 Fe(NO3)3. B. Mg(NO3)2 v Fe(NO3)2.
C. Fe(NO3)2 v AgNO3. D. Mg(NO3)2 v AgNO3.
(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu
c mt loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag.
(g) Glucoz v fructoz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l
A. 5. B. 3. C. 6. D. 4.
Cu 26: X phng ho hon ton m gam cht bo trung tnh bng dung dch KOH d th thu c 18,77
gam x phng. Nu thay dung dch KOH bng dung dch NaOH d th ch thu c 17,81 gam x phng.
Gi tr ca m l
A. 18,36. B. 17,25. C. 17,65. D. 36,58.
Cu 27: Cho 2 phng trnh ion rt gn
1) R2+ + X R + X2+; 2) R + 2X3+ R2+ + 2X2+
Nhn xt no sau y l ng?
A. Tnh kh: X2+ > R > X. B. Tnh oxi ha: X3+ > R2+ > X2+.
C. Tnh kh: X > X2+ >R. D. Tnh oxi ha: R2+ > X3+> X2+.
Cu 28: Phn ng gia cc cht no sau y khng to ra hai mui?
A. NO2 v dung dch NaOH d. B. Ba(HCO3)2 v dung dch KOH d.
C. Fe3O4 v dung dch HNO3 d. D. Fe3O4 v dung dch HCl d.
Cu 29: Cho 12,55 gam hn hp rn X gm FeCO3, MgCO3 v Al2O3 tc dng hon ton vi dung dch
H2SO4 v NaNO3 (trong t l mol ca H2SO4 v NaNO3 tng ng l 19:1) thu c dung dch Y
(khng cha ion NO 3 ) v 2,464 lt kh Z (ktc) gm NO, CO2, NO2 c t khi hi so vi H2 l 239/11.
Cho dung dch Y tc dng vi dung dch NaOH n khi thu c kt ta cc i thy c 0,37 mol NaOH
tham gia phn ng. Mt khc, khi cho dung dch Y tc dng dung dch NaOH d un nng khng thy
kh bay ra. Phn trm v khi lng ca FeCO3 trong hn hp X c gi tr gn nht vi gi tr no sau
y?
A. 46,2 %. B. 40,63 %. C. 20,3 %. D. 12,19 %.
Cu 30: Hn hp X gm Ba, BaO, Na, Na2O v K. Cho m gam hn hp X vo nc d thu c 3,136
lt H2 (ktc); dung dch Y cha 7,2 gam NaOH; 0,93m gam Ba(OH)2 v 0,044m gam KOH. Hp th
7,7952 lt CO2 (ktc) vo dung dch Y thu c a gam kt ta. Gi tr ca a gn nht vi gi tr no sau
y?
A. 25,5. B. 24,7. C. 28,2. D. 27,9.
Cu 31: Nung nng 30,005 gam hn hp X gm KMnO4, KClO3 v MnO2, sau mt thi gian thu c
kh oxi v 24,405 gam cht rn Y gm K2MnO4, MnO2, KMnO4, KCl. phn ng hon ton Y cn va
2,0 lt dung dch cha HCl 0,4M thu c 4,844 lt kh Cl2 (ktc). Phn trm KMnO4 b nhit phn l
A. 75,72 %. B. 52,66 %. C. 72,92 %. D. 63,19 %.
Cu 32: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c
cht rn Y v cht hu c Z. Cho Z tc dng vi dung dch AgNO3 trong NH3 thu c cht hu c T.
Cho T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l cht no trong s cc cht
sau?
A. CH3COOCH=CH-CH3. B. HCOOCH=CH2.
C. CH3COOCH=CH2. D. HCOOCH3.
Cu 33: Cho X, Y l hai cht thuc dy ng ng ca axit acrylic (MX < MY); cho Z l ancol c cng s
nguyn t cacbon vi X; T l este hai chc to bi X, Y v Z. t chy hon ton 11,16 gam hn hp E
gm X, Y, Z, T cn va 13,216 lt kh O2 (ktc), thu c kh CO2 v 9,36 gam nc. Mt khc 11,16
gam E tc dng ti a vi dung dch cha 0,04 mol Br2. Khi lng mui thu c khi cho cng lng E
trn tc dng vi NaOH d l
Cu 34: t chy hon ton 1 mol cht bo trung tnh, thu c lng CO2 v H2O hn km nhau 6 mol.
Mt khc a mol cht bo trn tc dng ti a vi 600 ml dung dch Br2 1M. Gi tr ca a l
A. 0,30. B. 0,18. C. 0,20. D. 0,15.
Cu 35: Tin hnh 2 th nghim sau:
Th nghim 1: Cho m gam bt Fe (d) vo V1 lit dung dch Cu(NO3)2 0,2M.
Th nghim 2: Cho m gam bt Fe (d) vo V2 lit dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c 2 th nghim u bng nhau.
Biu thc lin h gia V1 v V2 l
A. V1 = 5V2. B. V1 = 2V2. C. V1 = 10V2. D. 10V1 = V2.
Cu 36: Thy phn hon ton 1 mol pentapeptit X th thu c 3 mol glyxin, 1 mol alanin v 1 mol
valin. Khi thy phn khng hon ton X trong hn hp sn phm thy c cc ipeptit Gly-Gly; Ala-Gly;
v tripeptit Gly-Val-Gly. Amino axit u N, amino axit u C ca X l
A. Gly, Val. B. Ala, Gly. C. Ala, Val. D. Gly, Gly.
Cu 37: Cho m (gam) hn hp Na v Ca vo mt lng nc d thu c dung dch X v V lit kh
(ktc). Sc t t n d kh CO2 vo dung dch X, kt qu th nghim c biu din trn th sau:
S mol CaCO3
0,1
0,0
5
S mol CO2
0,05 0,1 0,35 0,4
Gi tr ca V l
A. 3,36. B. 4,48. C. 2,24. D. 5,6.
Cu 38: Cht X c cng thc phn t C6H8O4. Cho 1 mol X phn ng ht vi dung dch NaOH, thu c
cht Y v 2 mol cht Z. un Z vi dung dch H2SO4 c, thu c imetyl ete. Cht Y phn ng vi
dung dch H2SO4 long (d), thu c cht T. Cho T phn ng vi HBr, thu c hai sn phm l ng
phn cu to ca nhau. Pht biu no sau y khng ng?
A. Cht Z khng lm mt mu nc brom.
B. Cht Y c cng thc phn t C4H4O4Na2.
C. Cht T khng c ng phn hnh hc.
D. Cht X phn ng vi H2 (Ni, t0) theo t l mol 1 : 1.
Cu 39: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn
amin bc 2 ca X l
A. 5. B. 2. C. 4. D. 3.
Cu 40: un nng dung dch cha 18 gam glucoz vi lng va dung dch bac nitrat trong amoniac
n phn ng hon ton. Khi lng bc sinh ra l

-----------------------------------------------
----------- HT ----------
Ch : Hc sinh khng c s dng bng tun hon cc nguyn t ha hc.

p n:
Cu 1 2 3 4 5 6 7 8 9 10
p
C A D B D D A D A B
n
Cu 11 12 13 14 15 16 17 18 19 20
p
D D A A C B C D A C
n
Cu 21 22 23 24 25 26 27 28 29 30
p
C C B B A B B C A A
n
Cu 31 32 33 34 35 36 37 38 39 40
p
C C D D A B B B D C
n
Bi gii chi tit:

Cu 1: CH3CH(NH2)CH3 l amin bc 1 v CH3CH2OH l ancol bc 1. p n C
Cu 2: Cu hnh e ca cc ion: Na+: 1s22s22p6;
Cl-; Ca2+ v K+ u c cu hnh e: 1s22s22p63s23p6;
p n A.
Cu 3: Cc cp cht: NaCl v Ba(NO3)2; AlCl3 v CuSO4; Na2CO3 v KOH; u khng c phn ng.
Cp cht NaOH v NaHCO3 c phn ng nn khng th cng tn ti trong dung dch:
NaOH + NaHCO3 Na2CO3 + H2O; p n D.
Cu 4: Cu hnh e ca nguyn t Mg (Z = 12) l: 1s22s22p63s2. p n B.
Cu 5: nhn bit ion NO 3 trong dung dch c th dng thuc th l Cu v dd H2SO4 long v c hin
tng Cu tan to kh khng mu ha nu trong khng kh:
3Cu + 8H+ + 2NO 3 3Cu2+ + 2NO + 4H2O;
2NO + O2 2NO2 (kh mu nu ); p n D.

Cu 6: Ta c: nNa = nNaOH = 1 mol; n H2 = 0,5 mol;
Khi lng dd sau p: mdds = mNa + m H2O - m H2 = 23 + 178 0,52 = 200(g);
40
C%(NaOH) = 100% = 20%; p n D.
200
Cu 7: Cng thc ca vinyl axetat l: CH3COOCH = CH2; c 6 nguyn t H; p n A.
Cu 8: p n D

Cu 9: Gc C6H5 ht e lm cho mt e trn nguyn t N gim; Tnh baz gim nn qu tm khng
i mu; p n A.
Cu 10: Hp cht H2N-CH2CH2CONH-CH2-CH2COOH c 1 lin kt CO-NH nhng khng phi lin kt
gia cc n v -aminoaxit nn khng phi i peptit; p n B
Cu 11: Trong dd K kh H2O nn khng kh c ion Cu2+ thnh Cu; p n D.
Cu 12: Cc phn ng: CH3 CH(NH2) COOH + HCl CH3 CH(NH3Cl) COOH;
CH3 CH(NH3Cl) COOH + NaOH CH3-CH(NH2)-COONa + NaCl + H2O;
p n D.
Cu 13: p n A
0
Cu 14: Nha Rezol
t
Nha Rezit (cu trc mng khng gian, lm tng mch polime).
p n A.
Cu 15: dd H2SO4 long p vi Fe: H2SO4 + Fe FeSO4 + H2. p n C.
Cu 16: Fructoz thuc loi monosacarit nn khng b thy phn. p n B.
Cu 17: Trong cc kim loi cho:
- Cc kim loi Na, Mg, Al cng thuc chu k III tnh kim loi gim dn nn: Na>Mg>Al.
- Cc kim loi Na v K cng thuc nhm IA tnh kim loi tng dn nn: Na<K.
Vy tnh kim loi gim dn theo dy: K; Na; Mg; Al. p n C.
Cu 18: Phn ng ca Cu v HNO3 khng to sn phm l H2 v ion H+ khng oxi ha c Cu. p
n D.
Cu 19: Este (X) c to thnh t axit axetic v ancol metylic c CT l: CH3COOCH3.
CTPT: C3H6O2. p n A.
Cu 20: Trng hp vinyl xianua (thng c gi l acrilonitrin) thu c polime l poliacrilonitrin
dng sn xut t nitron hay t olon. p n C.
Cu 21: C 4 th nghim thu c kt ta l:
(1) Cho dung dch NaOH vo dung dch Ca(HCO3)2:
OH- + HCO 3 CO 32 + H2O; CO 32 + Ca2+ CaCO3.
(3) Sc kh H2S vo dung dch FeCl3: H2S + 2Fe3+ 2Fe2+ + S + 2H+.

(4) Sc kh NH3 ti d vo dung dch AlCl3: 3NH3 + 3H2O + Al3+ Al(OH)3 + 3NH 4 .
(5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]):
CO2 + 2H2O + AlO 2 Al(OH)3 + HCO 3 .
p n C.
Cn H 2n - 1ON(0,58 mol) + O2
Cu 22: hh E
Quy i
CO2 + H 2O N 2 .
x mol H 2O (x mol) 115,18 gam
45,54 gam

Theo bi ra ta c phng trnh: 0,58(14n + 29) + 18x = 45,54;
Theo bo ton nguyn t C, H: 0,58n 44 + 18(0,58n 0,29) + 18x = 115,18;
Gii h 2 pt trn ta c: n = 191/58; x = 0,11;
Gi CT ca peptit X l: (Gly)n(Val)6-n; Y l: (Gly)m(Val)4-m;
X + 6NaOH nX + nY = 0,11 nX = 0,07

Ta c:
mui + H 2O ; ; ;
Y + 4NaOH 6nX + 4nY = nNaOH = 0,58 nY = 0,04
191
Theo bo ton mol C: 0,07(30 3n) + 0,04(20 3m) = 0,58. = 1,91;
58
7n + 4m = 33; n = 3; m = 3;
Vy CT phn t ca peptit Y l: (C2H3ON)3(C5H9ON)H2O; hay C11H20N4O5.
p n C.
Cu 23: C 4 cht khi thy phn trong dd NaOH d un nng sinh ra ancol l:
- Benzyl axetat sinh ra ancol l C6H5CH2OH:
CH3COOCH2-C6H5 + NaOH CH3COONa + C6H5CH2OH.
- Anlyl axetat sinh ra ancol l CH2 = CH CH2OH
CH3COOCH2-CH = CH2 + NaOH CH3COONa + CH2 = CH
CH2OH.
- Etyl fomat sinh ra ancol l C2H5OH
HCOOC2H5 + NaOH HCOONa + C2H5OH.
- Tripanmitin sinh ra ancol l C3H5(OH)3
(C15H31COO)3C3H5 + 3NaOH 3C15H31COONa + C3H5(OH)3.
p n B.
Cu 24: Khi cho hn hp Fe v Mg vo dd AgNO3 cc phn ng xy ra theo th t:
Mg + 2Ag+ Mg2+ + 2Ag; Fe + 2Ag+ Fe2+ + 2Ag;
Sau khi p xy ra hon ton thu c cht rn Y gm 2 kim loi l Ag v Fe cn d.
ion Ag+ p ht. Vy 2 mui trong dd X l Mg(NO3)2 v Fe(NO3)2; p n B.
Cu 25: Trong cc pht biu cho v cacbohirat:
- Cc pht biu ng l: (a), (b), (c), (e), (g);
- Pht biu (d) sai v thy phn saccaroz thu c 2 loi monosaccarit l glucoz v fructoz.
p n A.
Cu 26: Ta c p x phng ha: (RCOO)3C3H5 + 3XOH 3RCOONa + C3H5(OH)3.
Theo pt ta thy:
C 3 mol XOH p th khi lng x phng to thnh chnh lch 3.(39 23) = 48 gam.
0,06 mol (18,77 17,81) = 0,96 gam.
Vy s mol glixerol to thnh = 0,02
Theo bo ton khi lng: mcht bo = 18,77 + 0,02 . 92 0,06 . 56 = 17,25 gam.

p n B.
Cu 27:
Tnh kh: X > R
T pt (1): R2+ + X R + X2+; 2 2
Tnh oxi ha: R > X
Tnh kh: R > X 2
T pt (2): R + 2X3+ R2+ + 2X2+ 3 2
Tnh oxi ha: X > R
Vy: Tnh oxi ha: X3+ > R2+ > X2+; p n B.

Cu 28: Phn ng gia NO2 v dung dch NaOH d to 2 mui l NaNO3 v NaNO2.
Phn ng gia Ba(HCO3)2 v dung dch KOH d to 2 mui l BaCO3 v K2CO3.
Phn ng gia Fe3O4 v dung dch HNO3 d ch to 1 mui l Fe(NO3)3.
Phn ng gia Fe3O4 v dung dch HCl d to 2 mui l FeCl2 v FeCl3.
p n C.
FeCO3: x mol
H2SO4 ; NaNO3 + KhZ (NO; CO2 ; NO2 )
Cu 29: hh X MgCO3: y mol
(tlmol 19:1)
2 3 2
;
Al O : z mol dd Y ( Mg ; Al ; Fe; SO4 )
2 3
12,55 gam
kt ta cc i
dd Y
NaOH (0,37 mol)
; Gi s mol NaNO3 l a; s mol H2SO4 l 19a.
+ dd Na2SO4
1
Theo bo ton mol Na: n Na2SO4 = n H2SO4 = (nNaOH + n NaNO3 ); 38a = 0,37 + a; a = 0,01;
2
Ta c: nkh Z = 0,11 mol; Bo ton N: nNO + n NO2 = n NO = 0,01; n CO2 = 0,1;
3
239 2
mkh Z = 0,11 = 4,78 (g); mNO + m NO2 = 0,38; 30nNO + 46n NO2 = 0,38;
11
nNO = n NO2 = 0,005; Theo bo ton mol e: ne nhn = ne cho = 30,005 + 0,005 = 0,02;
n FeCO3 (oxi ha kh) = n Fe3 = 0,02; 32z + 2y + 30,02 + 2(x 0,02) = nNaOH = 0,37;
6z + 2y + 2x = 0,35; Theo bi ra: x + y = n CO2 = 0,1; z = 0,025;
x + y = 0,1
T ta c h pt: x = y = 0,05; %m FeCO3 = 46,22%; p n A.
116x + 84y = 10
Cu 30: Dng pp quy i.
hh X c: nBa = x; nK = y; nO = z; nNa = nNaOH = 0,18; n H2 = 0,14; n CO2 = 0,348;
0,93m 0,31m 0,044m 0,011m

x= ;y= = ;
171 57 56 14
Theo bo ton mol e: 2x + 0,18 + y = 2z + 20,14 = 2z + 0,28;
y 0,31m 0,011m
z=x+ - 0,05 = + - 0,05 ; Theo bi ra ta c pt:
2 57 28

0,31m 0,011m 0,31m 0,011m
137 + 39 + 16( + - 0,05) + 0,18 23 = m; m = 25,5 (g).
57 14 57 28
0,31 25,5 0,011 25,5
Ta c: n OH (dd Y) = 0,18 + 2 + = 0,4774 (mol);
57 14
Khi hp th CO2 vo dd Y: to ra a mol HCO 3 ; b mol CO 32 ta c h pt:
a + b = 0,348 a = 0,2186
Ba2+ d; n BaCO3 = n CO2 = 0,1294; m BaCO3 = 25,9418 (g);
a + 2b = 0,4774 b = 0,1294 3
p n A.
Cu 31: S qu trnh phn ng:
KMnO4 (x mol) KMnO4
O2 HCl MnCl 2
hh X KClO3 (y mol) hh Y K 2 MnO4
0,8 mol + Cl 2 + H2O;
MnO (z mol) MnO ; KCl KCl
2 2 0,21625 mol
30,005 gam 24,405 gam
Theo bo ton khi lng: m O2 = 30,005 24,405 = 5,6 (g); n O2 = 0,175 mol;
Bo ton e: 5x + 6y + 2z = 0,1754 + 0,216252 = 1,1325;

1
Bo ton H: n H 2O = nHCl = 0,4 mol;
2
Bo ton O: 4x + 3y + 2z = 0,1752 + 0,4 = 0,75;
158x + 122,5y + 87z = 30,005 x = 0,12

Theo bi ra ta c h pt: 5x + 6y + 2z = 1,1325 y = 0,0875 ;
4x + 3y + 2z = 0,75 z = 0,00375

Ta thy: 0,0875 mol KClO3 b nhit phn hon ton sinh 0,13125 mol O2
cn 0,04375 mol O2 na l do 0,0875 mol KMnO4;
0,0875
%(KMnO4 b nhit phn) = 100% = 72,92%. p n C.
0,12
Cu 32: Ta thy:
CH 3COOCH = CH 2 + NaOH CH 3COONa + CH 3CHO ;
X Y Z
CH3CHO + AgNO3 + NH3 CH 3COONH 4 ;

T
CH3COONH4 + NaOH CH3COONa + NH3 + H2O; p n C.

Cu 33: n O2 = 0,59 mol;
Theo bo ton khi lng: 11,16 + 0,59 32 = m CO2 + 9,36; n CO2 = 0,47; n H2O = 0,52;
Z l ancol no 2 chc;
mO(trong E) = 11,16 0,47 12 0,52 2 = 4,48 (g); n Otrong E = 0,28 mol;

axit: x mol

2x + 4y + 2z = 0,28
BTNT O
Xt hh E: este: y mol Ta c: BTLK z = 0,1;
ancol: z mol
x + 2y = 0,04

ancol c 3C v hai axit c 3C v 4C
Axit X: C3H4O2 (a mol); Axit Y: C4H6O2 (b mol);
Este: C10H14O4 (y mol); Ancol: C3H8O2 (0,1 mol); a + b + 2y = 0,04;
Theo BTNT C: 3a + 4b + 10y = 0,47 3 0,1 = 0,17;
Theo bi ra: 72a + 86b + 198y = 11,16 76 0,1 = 3,56;
Gii h 3 pt ta c: a = 0,01; b = 0,01; y = 0,01;
m = 0,01 2(94 + 108) = 4,04 (g). p n D.
Cu 34: Ga s bt bo ha trong phn t cht bo = a. Ta c:
nCO2 nH2O 6
1= = ; a = 7 ; Phn t cht bo c CT: (RCOO)3C3H5;
a- 1 a- 1
C 4 lk gc R. Ngha l 1 mol cht bo tc dng vi ti a 4 mol Br2;
td 0,6 mol Br2 s mol cht bo l 0,15 mol. p n D.
Cu 35: Sau khi cc p xy ra hon ton, khi lng cht rn thu c 2 th nghim bng nhau khi
lng kim loi tng 2 th nghim bng nhau.
Th nghim 1: 1 mol Cu2+ p khi lng kim loi tng 8 gam
0,2V1 mol Cu2+ p lng kim loi tng 80,2V1
(gam).
Th nghim 2: 2 mol Ag+ p khi lng kim loi tng 160 gam.
0,1V2 mol Ag+ p .................................8V2 (gam).
T ta c: 8V2 = 1,6V1; V1 = 5V2; p n A.
Cu 36: Theo bi ra pentapeptit l: Ala-Gly-Val-Gly-Gly. p n B.
Cu 37: T th ta c: nCa = n CaCO3 (max) = 0,1;
Lng kt ta gim l qu trnh CaCO3 Ca(HCO3)2;

Lng kt ta chy ngang (khng i ) l qu trnh NaOH NaHCO3 ;
nNaOH = n CO2 = 0,35 0,05 0,1 = 0,2; n OH = 2nCa + nNa = 0,4;
1
n H2 = n = 0,2 mol; V = 4,48 lit; p n B.
2 OH
Cu 38: Khi un Z vi dd H2SO4 c thu c imetyl ete Z l CH3OH;
Theo bi ra ta c s : C6H8O4 + NaOH Y + 2CH3OH;
Vy CT ca X l: C2H2(COOCH3)2; CT ca Y l: C2H2(COONa)2; p n B.
15 10 10 36,5
Cu 39: Theo bo ton khi lng: namin = nHCl = ; Mamin = = 73;
36,5 5

Vy CTPT ca amin l C4H11N; 3 ng phn amin bc 2; p n D.
Cu 40: nAg = 2nglucoz = 0,2 mol; mAg = 21,6 gam; p n C.

TNH THANH HA Mn: KHOA HC T NHIN HA HC
THPT CHUYN LAM SN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Phn ng thy phn este trong mi trng kim, un nng c gi l phn ng ?

A. X phng ha B. Trng gng C. Este ha D. Hidro ha
Cu 2: Kim loi iu ch c bng phng php thy luyn, nhit luyn v in phn :
A. Mg B. Na C. Al D. Cu
Cu 3: Cho 7,68 gam hn hp Fe 2O3 v Cu tc dng vi HCl d, sau phn ng cn li 3,2 gam Cu.
Khi lng ca Fe2O3 ban u l:
Cu 4: Thy phn este X c CTPT C4H6O2. Khi X tc dng vi dung dch NaOH thu c hn hp 2
cht hu c Y v Z trong Z c t khi hi so vi H 2 l 16. Tn ca X l:
A. Etyl axetat B. Metyl propionat C. Metyl axetat D. Metyl acrylat
Cu 5: Khi in phn NaCl nng chy (in cc tr), ti catot xy ra ?
A. s kh ion Na+ B. s kh ion Cl - C. s oxi ha ion Cl - D. s oxi ha ion Na+
Cu 6: Nung nng mt ng s cha 36,1 gam hn hp gm MgO, CuO, ZnO v Fe 2O3 ri dn hn
hp kh X gm CO v H2 d i qua n khi phn ng xy ra hon ton, thu c 28,1 gam cht rn.
Tng th kh X (ktc) tham gia phn ng kh l :
A. 5,6 lt B. 11,2 lt C. 22,4 lt D. 8,4 lt
Cu 7: Dy kim loi no di y iu ch c bng cch in phn nng chy mui clorua ?
A. Al, Mg, Fe B. Al, Mg, Na. C. Na, Ba, Mg D. Al, Ba, Na
Cu 8: Dung dch cha cht no sau y lm qu tm i thnh mu xanh ?
A. Glutamic B. Anilin C. Glyxin D. Lysin
Cu 9: t chy hon ton hp cht hu c no sau y th thnh phn sn phm thu c khc vi
cht cn li ?
A. Protein B. Cao su thin nhin C. Cht bo D. Tinh bt
Cu 10: T c sn xut t xenluloz ?
A. to tm B. t capron C. t nilon-6,6 D. t visco
Cu 11: Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung
dch cht in li th cc hp kim m trong Fe u b n mn trc l:
A. I, III v IV B. II, III v IV C. I, II v IV D. I, II v III
Cu 12: Cho dy cc cht sau: glucoz, saccaroz, isoamyl axetat, phenylamoni clorua, poli(vinyl
axetat), glyxylvalin (Gly-Val), etilenglicol, triolein. S cht tc dng vi dung dch NaOH un nng
l:
A. 5 B. 7 C. 4 D. 6
Cu 13: Cho s phn ng sau: X + NaOH CH3COONa + cht hu c Y ;
Y + O2 Y1 ; Y1 + NaOH CH3COONa + H2O
S cht X tha mn s trn l:
A. 3 B. 4 C. 2 D. 1
Cu 14: Cht no sau y va phn ng c vi NaOH va phn ng c vi HCl?
A. C2H5OH B. C6H5NH2 C. NH2-CH2-COOH D. CH3COOH
Cu 15: Cho tng cht : NH2-CH2-COOH; CH3COOH; CH3COOCH3 ln lt tc dng vi dung dch
NaOH (un nng) v vi dung dch HCl (un nng). S trng hp xy ra phn ng l:
A. 6 B. 3 C. 5 D. 4
Cu 16: Cho dy cc polime gm: t tm, t capron, nilon 6,6, t nitron, poli(metyl metacrylat),
poli(vinyl clorua), cao su buna, t axetat, poli(etylen terephtalat). S polime c tng hp t phn
ng trng hp l:
A. 6 B. 4 C. 5 D. 7
Cu 17: Cht X c CTPT C2H7NO2 tc dng vi dung dch HCl v dung dch NaOH. Cht X thuc
loi hp cht no sau y ?
A. Mui amoni hoc mui ca amin vi axit cacboxylic.
B. Aminoaxit hoc mui ca amin vi axit cacboxylic.
C. Aminoaxit hoc este ca aminoaxit.
D. Este ca aminoaxit hoc mui amoni.
Cu 18: Metylamin khng phn ng c vi dng dch no sau y ?
A. CH3COOH. B. FeCl3. C. HCl. D. NaOH.
- Th nghim 1: Cho thanh Fe vo dung dch H 2SO4 long.
- Th nghim 2: Nhng thanh Fe vo dung dch H 2SO4 long c thm vi git dung dch CuSO 4.
- Th nghim 3: Nhng thanh Cu vo dung dch FeCl 3.
- Th nghim 4: Nhng thanh Fe vo dung dch FeCl 3.
S trng hp n mn in ha l:
A. 2. B. 1. C. 4. D. 3.
Cu 20: un si hn hp X gm 12 gam axit axetic v 11,5 gam ancol etylic vi xc tc H 2SO4 c.
Kt thc phn ng thu c 11,44 gam este. Hiu sut phn ng este ha l:
A. 50%. B. 66,67%. C. 65,00%. D. 52,00%.
Cu 21: Phn ng trng bc c s dng trong cng nghip sn sut gng, rut phch. Ha cht
c dng thc hin phn ng ny l:
A. Saccaroz. B. Andehit axetic. C. Glucoz. D. Andehit fomic.
Cu 22: Ngm thanh Cu (d) vo dung dch AgNO 3 thu c dung dch X. Sau ngm thanh Fe
(d) vo dung dch X thu c dung dch Y. Bit cc phn ng xy ra hon ton. Dung dch Y c
cha cht tan l:
A. Fe(NO3)3. B. Fe(NO3)2.
C. Fe(NO3)2, Cu(NO3)2. D. Fe(NO3)3, Fe(NO3)2.
Cu 23: kh mi tanh ca c (gy ra do mt s amin) nn ra c vi ?
A. nc mui. B. nc. C. gim n. D. cn.
Cu 24: Dung dch Fe2(SO4)3 khng phn ng vi cht no sau y ?
A. NaOH. B. Ag. C. BaCl2. D. Fe.
Cu 25: Cho 6,675 gam mt amino axit X (phn t c 1 nhm NH2 v 1 nhm COOH) tc dng
va ht vi dung dch NaOH thu c 8,633 gam mui. Phn t khi ca X bng ?
A. 117. B. 89. C. 97. D. 75.
Cu 26: Tnh cht no khng phi l tnh cht vt l chung ca kim loi ?
A. Tnh cng. B. Tnh dn in. C. nh kim. D. Tnh do.
Cu 27: Cht no sau y thuc loi isaccarit?
A. Saccaroz. B. Glucoz. C. Tinh bt. D. Xenluloz.
Cu 28: in phn 10 ml dung dch AgNO 3 0,4M (in cc tr) trong thi gian 10 pht 30 giy vi
dng in c cng I = 2A, thu c m gam Ag. Gi s hiu sut phn ng in phn t 100%.
Gi tr ca m l:
A. Axit glutamic. B. Axit stearic. C. Axit axetic. D. Axit aipic.
Cu 30: Cho lung kh H 2 d qua hn hp cc oxit CuO, Fe 2O3, Al2O3, MgO nung nng nhit
cao. Sau phn ng, hn hp cht rn thu c gm ?
A. Cu, Fe, Al, Mg. B. Cu, FeO, Al2O3, MgO.
C. Cu, Fe, Al2O3, MgO. D. Cu, Fe, Al, MgO.

Cu 31: Cho 0,01 mol mt este tc dng va vi 100ml dung dch NaOH 0,2M, un nng. Sn phm
to thnh gm mt ancol v mt mui c s mol bng nhau v bng s mol este. Mt khc, x phng ha
hon ton 1,29 gam este bng mt lng va 60ml dung dch KOH 0,25M, c cn dung dch sau
phn ng thu c 1,665 gam mui khan. Cng thc ca este l:
A. C2H4(COO)2C4H8 B. C4H8(COO)2C2H4 C. CH2(COO)2C4H8 D. C4H8(COO)C3H6
Cu 32: Hn hp X cha cht A (C5H16O3N2) v cht B (C4H12O4N2) tc dng vi dung dch NaOH va
, un nng cho n khi phn ng xy ra hon ton ri c cn thu c m gam hn hp Y gm 2 mui
D v E (MD < ME) v 4,48 lt (ktc) hn hp Z gm 2 amin no, n chc, ng ng k tip c t khi so
vi H2 bng 18,3. Khi lng ca mui E trong hn hp Y l:
A. 4,24 B. 3,18 C. 5,36 D. 8,04
Cu 33: Hn hp gm 1,3 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 2 mol Ag+ sau phn
ng hon ton, lc b phn dung dch thu c cht rn gm 2 kim loi. Gi tr ca x c th l:
A. 1,8 B. 2 C. 2,2 D. 1,5
Cu 34: Cho cc s phn ng sau:
(a) X + O2 Y; (b) Z + H2O G
(c) Z + Y T (d) T + H2O Y + G.
Bit X, Y, Z, T, G u c phn ng vi dung dch AgNO3 trong NH3 to kt ta v G c 2 nguyn t
cacbon trong phn t. Phn trm khi lng ca nguyn t oxi trong phn t T c gi tr xp x bng ?
A. 37,21%. B. 44,44%. C. 53,33%. D. 43,24%
Cu 35: Cho cc pht biu sau v cacbohidrat :
(c) Trong dung dch glucoz v saccarozo u ha tan Cu(OH) 2 to phc mu xanh lam.
(d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit ch thu
(e) Khi un nng glucoz vi dung dch AgNO 3/NH3 thu c Ag.
(g) Glucoz v saccaroz u tc dng vi H 2 (xc tc Ni, un nng) to sorbitol.
S pht biu ng l:
A. 3 B. 4 C. 5 D. 6
Cu 36: Tin hnh in phn vi in cc tr v mng ngn xp mt dung dch cha m gam hn hp
CuSO4 v NaCl cho n khi nc bt u b in phn c hai in cc th dng li. anot thu
c 0,896 lt kh (kc). Dung dch sau khi in phn c th ha tan ti a 3,2 gam CuO. Gi tr ca
m l:
A. 11,94 B. 9,60 C. 5,97 . D. 6,40
Cu 37: Ha tan hon ton 25,3 gam hn hp X gm Mg, Al v Zn bng dung dch HNO 3. Sau khi
phn ng kt thc thu c dung dch Y v 4,48 lt (kc) kh Z (gm hai hp cht kh khng mu) c
khi lng 7,4 gam. C cn dung dch Y thu c 122,3 gam hn hp mui. S mol HNO 3 tham
gia phn ng gn nht vi gi tr no sau y ?
A. 1,81 mol B. 1,95 mol C. 1,8 mol. D. 1,91 mol
Cu 38: Cho 5,2 gam hn hp gm Al, Mg v Zn tc dng va vi dung dch H 2SO4 10% thu
c dung dch Y v 3,36 lt kh H2 (kc). Khi lng ca dung dch Y l:
A. 152 gam B. 146,7 gam C. 175,2 gam . D. 151,9 gam
Cu 39: Hn hp M gm LysGlyAla, LysAlaLysLysLysGly v AlaGly trong oxi chim
21,3018% v khi lng. Cho 0,16 mol M tc dng va vi dung dch HCl thu c m gam mui.
Gi tr ca m l:
A. 86,16 B. 90,48 C. .83,28 D. 93,26
Cu 40: Hn hp E gm X, Y v Z l 3 peptit u mch h (M X > MY > MZ). t chy 0,16 mol X
hoc Y hoc Z u thu c s mol CO 2 ln hn s mol H2O l 0,16 mol. Nu un nng 69,8 gam
hn hp cha X, Y v 0,16 mol Z vi dung dch NaOH va thu c dung dch cha 101,04 gam
hai mui ca alanin v valin. Bit n X < nY. Phn trm khi lng ca X trong E gn nht vi :
A. 12 B. 95 C. 54 D. 10

----------HT----------

THI TH LN 1 CHUYN LAM SN THANH HA LN 1
Cu 1: Chn A.
Cu 2: Chn D.
- Cc kim loi Na, Mg, Al u c c iu ch bng phng php in phn nng chy.
- Kim loi Cu c iu ch bng c 3 phng php:
Phng php thy luyn: Zn + CuSO4
ZnSO4 + Cu
to
Phng php nhit luyn: CO + CuO Cu + CO2
pdd
Phng php in phn: 2CuSO4 + 2H2O
2Cu + 2H2SO4 + O2
Cu 3: Chn B.
- Phng trnh phn ng :
Fe2O3 + 6HCl 2FeCl3 + 3H2O ; Cu + 2FeCl3 CuCl2 + 2FeCl2
mol: x 2x mol: x 2x
- Ta c: m Fe 2O3 mCu p = 7,68 3,2 160x + 64x = 4,48 x = 0,02 mol m Fe 2O3 3, 2 (g)
Cu 4: Chn D.
- Ta c: M Z 32 Z l CH3OH. Vy este X c cng thc cu to l: CH2 CH COOCH3 c tn
gi l metyl acrylat.
Cu 5: Chn A.
- Cc phn ng xy ra cc in cc:
catot (cc m) xy ra s kh ion Na+ thnh Na: Na+ + e Na
anot (cc dng) xy ra s oxi ha ion Cl- thnh Cl2: 2Cl- Cl2 + 2e
pnc
- Phng trnh in phn: 2NaCl 2Na + Cl2
Cu 6: Chn B.
36,1 28,1
- Ta c: VX (n CO n H 2 ).22, 4 .22, 4 11, 2 (l)
16
Cu 7: Chn C.
- Trong cng nghip, kim loi kim v kim loi kim th c iu ch bng phng php in phn
nng chy mui halogenua tng ng:
pnc
2MCln 2M + nCl2 (M l kim loi)
- Tuy nhin, Al c iu ch bng cch in phn nng chy Al2O3:
2Al2O3 pnc
4Al + 3O2
Cu 8: Chn D.
- Dung dch anilin v cc amin thm ca chng khng lm i mu qu tm.
- Tc dng ln thuc th mu ca cc aminoaxit: (H2N)x R (COOH)y. Khi:
x = y th amino axit trung tnh, qu tm khng i mu.
x > y th amino axit c tnh baz, qu tm ha xanh.
x < y th amino axit c tnh axit, qu tm ha .
Cu 9: Chn A.
- t chy hon ton cao su thin nhin, cht bo, tinh bt th sn phm thu c l CO2 v H2O.
- Khi t chy hon ton protein th ngoi sn phm thu c l CO2 v H2O cn c kh N2 thot ra.
Cu 10: Chn D.
- Cc loi t c sn xut t xenluloz:
T visco: ha tan xenluloz trong NaOH long v CS2 thu c dung dch keo rt nht l t visco.
T axetat: ha tan xenluloz vi anhirit axetic (c H2SO4 c) thu c xenluloz iaxetat v
xenluloz triaxetat.
Cu 11: Chn A.

- Trong cp in cc: kim loi kim loi th kim loi no c tnh kh mnh hn ng vai tr l cc m
(anot) th kim loi b n mn khi tip xc vi dung dch cht in li.
- Trong cp in cc: kim loi phi kim thng hay gp nht l Fe C th kim loi ng vai tr l cc
m v b n mn khi tip xc vi dung dch cht in li.
- Do vy cc cp hp kim tha mn l: I, III, IV.
Cu 12: Chn A.
- Cc cht hu c tc dng vi NaOH thng gp l :
to
Dn xut halogen: R-X + NaOH ROH + NaX
(Ch : C6H5Cl khng tc dng NaOH un nng, phn ng ch xy ra khi c y cc iu kin
xc tc, nhit d v p sut).
Phenol: C6H5OH + NaOH
C6H5ONa + H2O
Axit cacboxylic (-COOH): -COOH + NaOH
-COONa + H2O
to
Este (-COO-): RCOOR + NaOH RCOONa + ROH
Mui ca amin: RNH3Cl + NaOH
RNH2 + NaCl + H2O
Aminoaxit: H2NRCOOH + NaOH
H2NRCOONa + H2O
Mui ca aminoaxit: HOOCRNH3Cl + 2NaOH
NaOOCRNH2 + NaCl + 2H2O
Mui amoni ca axit hu c: RCOONH3R+ NaOH RCOONa + RNH 2 + H2O
Mui amoni ca axit v c: RNH3NO3, (RNH3)2CO3, RNH3HCO3, RNH3HSO4, (RNH3)2SO4.
- Cu to ca cc cht trong dy:
Glucoz Saccaroz Isoamyl axetat Phenylamoni clorua
C6H12O6 C12H22O11 CH3COOCH2CH2CH(CH3)2 C6H5NH3Cl
Poli(vinyl axetat) glyxylvalin Etilenglicol Triolein
( CH[OOCCH3 ] CH2 ) Gly - Val C2H4(OH)2 (C17H33COO)3C3H5
Vy c 5 cht tha mn.
Cu 13: Chn B.
- T cc d kin ca bi ta suy ra c cu to ca X l: CH3COOR v Y1 l: CH3COOH
- Cc cng thc cu to ca Y tha mn phn ng: Y + O2
Y1
men gia
m Mn2
CH3COOH + H2O ; 2CH3CHO (Y) + O2 2CH3COOH
C2H5OH (Y) + O2
Vy c 4 cht X tng ng l: CH3COOC2H5 ; CH3COOCH=CH2 ; CH3COOCH(OH)-CH3 v
CH3COOCH(Cl)-CH3.
Cu 14: Chn C.
A. C2H5OH khng tc dng c vi NaOH v HCl.
B. C6H5NH2 + HCl
C6H5NH3Cl
H 2 NCH 2COOH HCl
ClH 3 NCH 2COOH
C.
H 2 NCH 2COOH NaOH
H 2 NCH 2COONa H 2O
D. CH3COOH + NaOH CH3COONa + H2O
Cu 15: Chn C.
- Cc phn ng xy ra:
to
H 2 NCH 2COOH NaOH H 2 NCH 2COONa H 2O
to
H 2 NCH 2COOH HCl ClH 3 NCH 2COOH
to
CH3COOH + NaOH CH3COONa + H2O

to
CH 3COOCH 3 NaOH CH 3COONa CH 3OH
HCl,t o

CH 3COOCH 3 H 2O
CH 3COOH CH 3OH

Cu 16: Chn C.
- T tm thuc loi t thin nhin.
- T axetat c iu ch t phn ng ca xenluloz vi anhirit axetic (xc tc H 2SO4 c)
H 2SO4 a
c
[C6H7O2(OH)3]n + 3n(CH3CO)2O [C6H7O2(OCOCH3)3]n + 3nCH3COOH
Xenluloz anhirit axetic xenluloz triaxetat axit axetic
- T capron Trng hp caprolactam:
Caprolactam Nilon 6 (t capron)

- T nitron: Trng hp acrilonitrin:
- Cao su buna: Trng hp buta-1,3-ien:
Buta-1,3-ien Polibutaien hay cao su buna

- Poli(metyl metacrylat): Trng hp metyl metacrylat:
- T Nilon6,6: ng trng ngng axit aipic v hexametyleniamin:

o
nH OOC[CH 2 ]4 COOH (X 3 ) nNH 2 [CH 2 ]6 NH 2 (X 4 )
t
( NH[CH 2 ]6 NHCO[CH 2 ]4 CO ) n 2nH 2O
axit aipic hexametyleniamin poli(hexametylen-aipamit) hay t nilon 6,6
- T lapsan: ng trng ngng axit terephtalic v etylen glycol:
to
n(p HOOCC6H 4COOH) n(HOCH 2CH 2OH) ( OC C6H 4 CO OCH 2 CH 2 O) n 2nH2O
Axit terephtalic Etylen glicol Poli (etylenterephtalat) hay t lapsan
Vy c 5 polime c iu ch bng phn ng trng hp l t capron, t nitron, poli(metyl

metacrylat), poli (vinyl clorua), cao su buna.
Cu 17: Chn A.
- Cng thc cu to ca X l: CH3COONH4 (mui amoni) v HCOONH 3CH3 (mui ca amin vi
axit cacboxylic).
Cu 18: Chn D.
A. CH3NH2 + CH3COOH
CH3COONH3CH3
B. 3CH3NH2 + FeCl3 + 3H2O
3CH3NH3Cl + Fe(OH)3 nu
C. CH3NH2 + HCl CH3NH3Cl
D. CH3NH2 + NaOH: khng phn ng
Cu 19: Chn B.
- iu kin xy ra n mn in ha l: (3 iu kin bt buc)

(1) C cc cp in cc khc nhau v bn cht, c th l kim loi kim loi, kim loi phi kim. Kim
loi hot ng mnh hn ng vai tr cc m v b n mn.
(2) Cc cp in cc phi tip xc trc tip hoc gin tip vi nhau thng qua dy dn.
(3) Cc in cc phi cng tip xc vi mt dung dch cht in li.
- th nghim 1: Khng tha mn iu kin (1).
- th nghim 2: Tha mn.
Cu 20: Chn C.
H 2SO4
c

- Phng trnh phn ng: CH 3COOH C2H 5OH CH 3COOC2H 5 H 2O

o
0,2mol 0,25mol t 0,13mol
n CH3COOC2H5
H .100% 65%
n CH3COOH
Cu 21: Chn C
- Trong cng nghip: glucoz dng trng gng, trng rut phch (thay cho anehit v anehit c).
Cu 22: Chn B.
- Cc phn ng xy ra:
Cu(d) + AgNO3 Cu(NO3)2 + Ag Cu(NO3)2 + Fe(d) Fe(NO3)2 + Cu
Vy dung dch Y cha Fe(NO3)2.
Cu 23: Chn C.
- Trong mi tanh ca c l hn hp cc amin (nhiu nht l trimetylamin) v mt s cht khc, chnh v
vy ngi ta dng gim n (thnh phn c cha CH3COOH) kh mi tanh ca c trc khi nu.
Cu 24: Chn B.
A. Fe2(SO4)3 + 6NaOH 2Fe(OH)3 nu + 3Na2SO4
B. Fe2(SO4)3 + Ag: khng xy ra (v khng tun theo quy tc ).
C. Fe2(SO4)3 + 3BaCl2
3BaSO4 trng + 2FeCl3
D. Fe2(SO4)3 + Fe 3FeSO4
Cu 25: Chn D.
TGKL 8, 633 6, 675 6, 675
n X 0, 089 mol M X 75
40 18 0, 089
Cu 26: Chn A.
- Cc tnh cht vt l chung bao gm: tnh do, tnh dn in, dn nhit v nh kim u do cc e t do
trong kim loi gy nn.
Cu 27: Chn A.
- Monosaccarit: glucoz, fructoz. isaccarit: saccaroz, mantoz. Polisaccarit: tinh bt, xenluloz.
Cu 28: Chn C.
Ti catot Ti anot
Ag +
+ e Ag H2O 4H + O2 + 4e
+
0,004 0,004 0,004

H2O + 2e H2 + 2OH-
It
- Ta c ne trao i 0,013mol > ne Ag nhng = 0,004 mol mAg 0,004.108 0,432(g)
96500
Cu 29: Chn B.
A. Axit glutamic B. Axit stearic C. Axit axetic D. Axit aipic
HOOC(CH2)2CH(NH2)-COOH (C17H35COO)3C3H5 CH3COOH HOOC(CH2)4COOH
Cu 30: Chn C.
- Cc tc nhn kh nh H 2, CO ch kh c cc oxit baz ca cc kim loi ng sau nhm trn dy

in ha. Vy cht rn thu c gm Cu, Fe, Al 2O3, MgO.

Cu 31: Chn B.
nNaOH
- Khi cho 0,01 mol este tc dng vi 0,02 mol NaOH th: 2 . Mt khc s mol mui ancol thu
neste
c bng s mol este. Vy este c dng l R(COO)2 R'
t0
R(COO)2 R' 2KOH R(COOK) 2 R'(OH) 2
0,015mol 0,0075mol 0,0075mol
BTKL 0,465
mR'(OH)2 meste 56nKOH mmui khan 0,465(g) M R'(OH)2 62(C2H 4 (OH)2 )
0,0075
1,665
M mui 222 : C4H8(COOK)2 Este l: C4H8(COO)2 C2H 4
0,0075
Cu 32: Chn D.
- Khi cho hn hp X tc dng vi NaOH va th :
t0
(C2H5 NH3 ) 2 CO3 (A) 2NaOH Na 2CO3 (D) 2C2H5 NH 2 2H 2O
t0
(COONH3CH3 ) 2 (B) 2NaOH (COONa) 2 (E) CH3NH 2 2H 2O
- Xt hn hp kh Z ta c :
n C2H5 NH 2 n CH3NH 2 0, 2 n C2H5NH 2 0, 08mol n E 0,5n CH3NH 2 0, 06 mol

45n C2H5 NH 2 31n CH3NH 2 0, 2.18,3.2 n CH3NH 2 0,12 mol m E 0, 06.134 8, 04(g)

Cu 33: Chn D.
- Hn hp kim loi gm Ag v Cu, gi s hn hp gm Mg v Zn tc dng va vi dung dch cha 2
2nCu2 nAg 2nMg
mol Cu2+ v 2 mol Ag+ th : nZn 1,7mol (Khng c p n).
2
- Chng t dung dch sau phn ng cha Mg2+, Zn2+ v Cu2+. V vy nZn 1,7mol
Cu 34: Chn B.
- Cc phn ng xy ra:
2 1
Hg xt
(b) C2H2 (Z) H 2O CH3CHO(G) (a) HCHO(X) O 2 HCOOH(Y)
2
(c) HCOOH(Y) C2H 2 (Z)
HCOOC2H3 (T)

H
(d) HCOOC2 H3 (T) H2O HCOOH(Y) CH3CHO (G)
Vy %O(T) 44, 44
Cu 35: Chn B.
- C 4 nhn nh ng l (a), (b), (c) (e).
(d) Sai, Khi thy phn tinh bt ch thu c glucoz cn khi thy phn saccaroz th thu c c
glucoz v fructoz.
(g) Sai, Ch c glucoz phn ng vi H 2 (Ni. t0) thu c sorbitol, saccaroz th khng tham gia
phn ng hiro ha.
Cu 36: Chn A.
- V dung dch ha tan c CuO nn dung dch sau in phn c cha H + (tc l ti anot nc
in phn). Ta c : nH 2nCuO 0,08mol
Ti catot Ti anot
Cu 2+
+ 2e Cu 2Cl -
Cl2 + 2e
x mol 2x mol x mol 2y mol y mol 2y mol
H2O 4H+ + O2 + 4e
0,08 mol 0,02 mol 0,08 mol

BT:e
2n 2nCl 2 4nO2 2x 2y 0,08 x 0,06mol
Xt hn hp kh ta c: Cu2
nCl 2 nkh nO2
y 0,02 y 0,02mol
m 160nCuSO4 58,5nNaCl 11,94(g)
Cu 37: Chn D.
nNO nN2O 0,2 nNO 0,1mol
30nNO 44nN2O 7,4 nN2O 0,1mol
nNO3 (trong mui) 3nNO 8nN2O 9nNH4 1,1 9x
- Ta c: mmui mkim loi 18nNH4 62nNO3 122,3 25,3 18x 62(1,1 9x) x 0,05mol
nHNO3 10nNH 4 4nNO 10nN 2O 1,9mol
Cu 38: Chn D.
98nH2SO4 .100
- Ta c: nH2SO4 nH2 0,15mol mddH2SO4 147(g)
C%
BTKL
mY mkim loi mddH 2SO4 2nH 2 151,9(g)
Cu 39: Chn B.
- Nhn thy rng hn hp M c dng GlyAla(Lys)x (CTPT ca M l C56x H1012x O3x N22x )
16(3 x)
- Theo ta c: %mO 0,213018 x 1,5
12(5 6x) 16(3 x) 10 12x 14(2 2x)
t0
- Khi cho M tc dng HCl th: GlyAla(Lys)1,5 5HCl 2,5H 2O GlyHCl AlaHCl Lys(HCl)2
BTKL
mmui mM 36,5nHCl 18nH2O 90,48(g)
Cu 40: Chn A.
nCO2 nH 2O 0,16
- Khi t 0,16 mol X th : nX 0,16 k X 4
0,5k X 1 0,5k X 1
- Tng t khi t ln lt 0,16 mol Y v Z th ta c kY = kZ = 4.
- Gi x l s mol ca hn hp E. Khi un nng 69,8 gam E vi NaOH va th :
BTKL
mmui mE 18nH 2O 40nNaOH 101,04 69,8 40.4t 18t t 0,22mol
+ Xt hn hp mui ta c:
111nAlaNa 139nValNa mmui 111nAlaNa 139nValNa 101,04 nAlaNa 0,76

nAlaNa nValNa 4nE nAlaNa nValNa 0,88 nValNa 0,12
- Ta nhn thy rng nZ > nValNa, nn peptit Z trong E l (Ala)4 (0,16 mol)
- Gi x, y ln lt l s mol ca X v Y. Theo ta c X l (Val)a(Ala)4 a v b l (Val)b(Ala)4 b.

BT:Val
xa yb 0,12
xa yb 0,12
BT:Ala xy x 0,02 v y = 0,04
x(4 a) y(4 b) 0,76 4x 4y xa yb 0,76
a,b 4
x y 0,22 0,16 0,06 x y 0,06 a= 4 v b=1

0,02.414
%mX .100% 11,86%
69,8

TNH THI BNH Mn: KHOA HC T NHIN HA HC
THPT CHUYN THI BNH

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: T 1 tn mn ca cha 60% xenlulozo iu ch ancol etylic 700 , hiu sut ca qu trnh l 70%,
khi lng ring ca ancol nguyn cht l 0,8 g/ml. Th tch ancol 700 thu c l :
A. 208,688 lit B. 298,125 lit C. 452,893 lit D. 425,926 lit
Cu 2: Ha tan 30g glyxin trong 60g etanol, ri thm t t 10 ml dung dch H2SO4 c ,sau un nng
1 thi gian. ngui, cho hn hp vo nc lnh, ri trung ha bng NH3 d thu c mt sn phm
hu c c khi lng 33g. Hiu sut ca phn ng l :
A. 75% B. 80% C. 85% D. 60%
Cu 3: Thy phn este C4H6O2 trong mi trng kim thu c hn hp sn phm m cc cht sn phm
u c phn ng trng gng. Cu to c th c ca este l :
A. HCOO-CH=CHCH3 B. CH2=CH-COOCH3
C. HCOO-CH2CH=CH2 D. CH2COOCH=CH2.
Cu 4: Kim loi no trong s cc kim loi : Al , Fe , Ag, Cu c tnh kh mnh nht :
A. Fe B. Ag C. Al D. Cu
Cu 5: Ln men nc qu nho thu c 100,0 lit ru vang 100 (bit hiu sut phn ng ln men t
95,0% v ancol etylic nguyn cht c khi lng ring l 0,8 g/ml). Gi s trong nc qu nho c mt
loi ng l glucozo. Khi lng glucozo c trong lng nc qu nho dng l :
A. 19,565 kg B. 16,476 kg C. 15,652 kg D. 20,595 kg
Cu 6: t chy hon ton m gam hp cht A (thuc dy ng ng ca anilin) thu c 4,62g CO2 , a
gam H2O v 168 cm3 N2 (dktc). Xc nh s cng thc cu to tha mn A?
A. > 4 B. 4 C. 3 D. 2
Cu 7: X l mt hp cht c CTPT C6H10O5 :
X + 2NaOH 2Y + H2O
o
t
Y + HCllong Z + NaCl
Hy cho bit 0,1 mol Z tc dng vi Na d th thu c bao nhiu mol H2 ?
A. 0,1 mol B. 0,15 mol C. 0,05 mol D. 0,2 mol

o H 2 SO4 o
dd, NaOH ,t
NH3 , H 2O Na2 SO3
C2 H5OH , H 2 SO4 ,t
H 2O

A B C CH3-CH(NH3HSO4)-COOC2H5
A l :

A. CH3-CH(NH2)-COONH4 B. CH3-CH(CH3)-COONH4
C. H2N-CH2-CH2-COOH D. CH3-CH(NH2)-COOH
Cu 9: Hp cht A c cng thc phn t C4H6Cl2O2. Cho 0,1 mol A tc dng va vi dung dch cha
0,3 mol NaOH, thu c dung dch hn hp trong c 2 cht hu c gm ancol etylic v cht hu c
X, c cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l :
A. 9,60g B. 23,1g C. 11,4g D. 21,3g
Cu 10: Dung dch no lm xanh qu tm :
A. CH3CH(NH2)COOH B. H2NCH2CH(NH2)COOH
C. ClH3NCH2COOH D. HOOCCH2CH(NH2)COOH
Cu 11: Amino axit l nhng hp cht hu c cha cc nhm chc :
A. cacboxyl v hidroxyl B. hidroxyl v amino
C. cacboxyl v amino D. cacbonyl v amino
Cu 12: Trong dy chuyn ha
H 2O H2 O2 Y
X
C2H2 Y
Z T. Cht T l :
A. CH3COOH B. CH3COOC2H5 C. CH3COOC2H3 D. C2H5COOCH3

Cu 13: Sp xp cc hp cht sau : metyl amin (I) ; dimetylamin(II) ; NH3(III) ; p-metylanilin (IV) ;
anilin (V) theo trnh t tnh bazo gim dn :
A. II > I > III > IV > V B. IV > V > I > II > III
C. I > II > III > IV D. III > IV > II > V > I
Cu 14: bo v v tu ngi ta thng dng phng php no sau y :
A. Dng hp kim khng g B. Dng cht chng n mn
C. M 1 lp kim loi bn ln v tu D. Gn l Zn ln v tu.
Cu 15: Xenlulozo trinitrat l cht d chy v n mnh c u ch t xenlulozo v HNO3. Mun iu
ch 29,7 kg xenlulozo trinitrat (hiu sut 90%) th th tch HNO3 96% (d = 1,52g/ml) cn dng l :
A. 1,439 lit B. 15 lit C. 24,39 lit D. 14,39 lit
Cu 16: Tnh cht bazo ca anilin yu hn NH3 th hin phn ng no :
A. anilin tc dng c vi axit
B. anilin d to kt ta vi dung dch FeCl3
C. anilin tc dng d dng vi nc Brom
D. anilin khng lm i mu qu tm
Cu 17: Nhn nh no di y khng ng v glucozo v fructozo :
A. Glucozo v Fructozo u tc dng c vi hidro to poliancol
B. Glucozo v Fructozo u tc dng c vi Cu(OH)2 to ra dung dch phc ng mu xanh lam.
C. Glucozo c phn ng trng bc v n c tnh cht ca nhm CHO
D. Khc vi glucozo, fructozo khng c phn ng trng bc v dng mch h no khng c nhm
CHO

Cu 18: Cho kh CO i qua ng cha 0,04 mol X gm FeO v Fe2O3 t nng, ta nhn c 4,784g cht
rn Y (gm 4 cht), kh i ra khi ng dn qua dung dch Ba(OH)2 d th thu c 9,062g kt ta. Phn
trm khi lng FeO trong hn hp X l :
A. 24,42% B. 25,15% C. 32,55% D. 13,04%
Cu 19: Cho 1,22g mt este E phn ng va vi 0,02 mol KOH, c cn dung dch thu c 2,16g hn
hp mui F. t chy hon ton mui ny thu c 2,64g CO2 ; 0,54g H2O v a gam K2CO3. ME < 140
vC. Trong F phi cha mui no sau y?
A. CH3C6H4-OK B. C2H5COOK C. CH3COOK D. HCOOK
Cu 20: Trng thi v tnh tan ca cc amino axit l :
A. Cht lng d tan trong nc B. Cht rn d tan trong nc
C. Cht rn khng tan trong nc D. Cht lng khng tan trong nc
Cu 21: Cho cc cp cht: (1) CH3COOH v C2H5CHO ; (2) C6H5OH v CH3COOH ; (3) C6H5OH v
(CH3CO)2O ; (4) CH3COOH v C2H5OH ; (5) CH3COOH v CHCH ; (6) C6H5COOH v C2H5OH.
Nhng cp cht no tham gia phn ng to thnh este iu kin thch hp?
A. (3),(4),(6) B. (1),(2),(3),(4),(5)
C. (3),(4),(5),(6) D. (2),(3),(4),(5),(6)
Cu 22: un nng 0,4 mol hn hp E gm dipeptit X, tripeptit Y v tetrapeptit Z u mch h bng
lng va dung dch NaOH, thu c dung dch cha 0,5 mol mui ca glyxin v 0,4 mol mui ca
alanin v 0,2 mol mui ca valin. Mt khc t chy m gam E trong O2 va ddurr thu c hn hp O2,
H2O v N2, trong tng khi lng ca CO2 v nc l 78,28g. Gi tr ca m gn nht vi gi tr no :
A. 40 B. 50 C. 35 D. 45
Cu 23: Mun tng hp 120 kg metylmetacrylat, hiu sut qu trnh este ha v trng hp ln lt l
60% v 80%, khi lng axit v ancol cn dng ln lt l :
A. 170 kg v 80 kg B. 65 kg v 40 kg
C. 171 kg v 82 kg D. 215 kg v 80 kg
Cu 24: ng dng no sau y ca amino axit l khng ng :
A. Axit glutamic l thuc b thn kinh
B. Mui inatri glutamat dng lm gia v thc n (gi l m chnh hay bt ngt)
C. Amino axit thin nhin (hu ht l a-amino axit) l c s kin to nn cc loi protein ca c th
sng.
D. Cc amino axit c nhm NH2 v tr s 6 tr ln l nguyn liu sn xut t nilon.
Cu 25: Nung hn hp bt gm 15,2g Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton
thu c 23,3g hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl d thy thot ra V lit kh
H2(dktc). Gi tr ca V l :
A. 10,08 B. 4,48 C. 7,84 D. 3,36
Cu 26: c im ca n mn in ha l :
A. Khng pht sinh dng in.

B. C pht sinh dng in
C. Tc n mn ph thuc vo nhit
D. Tc n mn khng ph thuc vo nhit .
Cu 27: C cc nhn nh sau :
1. Cht bo l trieste ca glixerol vi cc axit monocacboxylic c mch C di khng phn nhnh.
2. Lipit gm cc cht bo ,sp, steroid, photpholipit,...
3. Cht bo l cht lng
4. Cht bo cha cc gc axit khng no thng l cht lng nhit thng v c gi l du.
5. Phn ng thy phn cht bo trong mi trng kim l phn ng thun nghch.
6. Cht bo l thnh phn chnh ca du m ng vt, thc vt.
S nhn nh ng :
A. 5 B. 2 C. 4 D. 3
Cu 28: Phn bit 3 dung dch : H2N-CH2-COOH, CH3COOH v C2H5NH2 ch dng mt thuc th l :
A. dung dch HCl B. dung dch NaOH C. Natri kim loi D. Qu tm
Cu 29: Hn hp A gm 2 kim loi Fe Cu. C th dng dung dch no sau y thu c Cu kim
loi?
A. Dung dch Cu(NO3)2 d B. Dung dch MgSO4 d
C. Dung dch Fe(NO3)2 d D. Dung dch FeCl3 d
Cu 30: un nng 20g mt loi cht bo trung tnh vi dung dch cha 0,25 mol NaOH, trung ha
NaOH d cn 0,18 mol HCl. Khi lng x phng 72% sinh ra t 1 tn cht bo trn l :
A. 1434,26 kg B. 1703,33 kg C. 1032,67 kg D. 1344,26 kg
Cu 31: Ly 14,3g hn hp X gm Mg, Al, Zn em t nng trong oxi d, sau khi phn ng xy ra hon
ton th nhn c 22,3g hn hp Y gm 3 oxit. Tnh th tch dung dch HCl 2M ti thiu cn dng
ha tan hn hp Y.
A. 400 ml B. 600 ml C. 500 ml D. 750 ml
Cu 32: Cho cc cht : etyl axetat, etanol, axit acrylic, phenol, phenylamoni clorua, phenyl axetat. Trong
cc cht ny, s cht tc dng c vi dung dch NaOH l :
A. 6 B. 5 C. 4 D. 3
Cu 33: C nhng cp kim loi sau y tip xc vi nhau, khi xy ra s n mn in ha th trong cp
no st khng b n mn :
A. Fe-Sn B. Fe-Zn C. Fe-Cu D. Fe-Pb
Cu 34: Trong s cc loi t sau : t tm, t visco, t nilon-6,6 , t axetat, t capron, t enang, nhng
loi t no thuc loi t nhn to :
A. T nilon-6,6 v t capron B. T visco v t nilon-6,6
C. T visco v t axetat D. T tm v t enang
Cu 35: phn bit du bi trn my vi du thc vt, ngi ta :
A. t chy ri nh lng oxi trong tng cht

B. Cho Cu(OH)2 vo tng cht
C. Ha tan trong benzen
D. un nng vi KOH d, ri cho thm dung dch CuSO4 vo.
Cu 36: Tnh cht no sau y khng phi l tnh cht c trng ca kim loi :
A. Tc dng vi dung dch mui B. Tc dng vi bazo
C. Tc dng vi phi kim D. Tc dng vi axit
Cu 37: Cho 5,6g hn hp X gm Mg, MgO c t l mol tng ng l 5 : 4 tan va trong dung dch
hn hp cha HCl v KNO3. Sau phn ng thu c 0,224 lit kh N2O (dktc) v dung dch Y ch cha
mui clorua. Bit cc phn ng hon ton. C cn dung dch Y cn thn thu c m gam mui. Gi tr
ca m l :
A. 20,51g B. 23,24g C. 24,17g D. 18,25g
Cu 38: Nhn nh no sau y l ng nht :
A. Phn t polime do nhiu n v mt xch to thnh
B. Xenlulozo c th b polime khi c un nng
C. Monome v mt xch trong polime c cu to ging nhau
D. Cao su lu ha l sn phm khi lu ha cao su thin nhin.
Cu 39: Qu trnh thy phn tinh bt bng enzim khng xut hin cht no sau y :
A. Saccarozo B. Dextrin C. Mantozo D. Glucozo
Cu 40: Hp cht X (cha C, H, O, N) c cng thc phn t trng vi cng thc n gin nht, va tc
dng vi axit va tc dng vi kim. Trong X, % khi lng ca nguyn t C, H, N ln lt l 40,449% ;
7,865% ; 15,73%. Khi cho 4,45g X phn ng hon ton vi NaOH (un nng) c 4,85g mui khan.
Nhn nh no v X sau y khng ng :
A. X va tc dng vi dung dch HCl, va tc dng vi dung dch NaOH
B. Phn t X cha 1 nhm este
C. X d tan trong nc hn Alanin
D. X l hp cht no, tp chc.
P N

1.D 11.C 21.C 31.C
2.B 12.B 22.C 32.B
3.A 13.A 23.D 33.B
4.C 14.D 24.B 34.A
5.B 15.D 25.C 35.D
6.B 16.D 26.B 36.B
7.A 17.D 27.D 37.A
8.A 18.D 28.D 38.D
9.D 19.D 29.A 39.A
10.B 20.B 30.A 40.C
LI GII CHI TIT
Cu 1: T 1 tn mn ca cha 60% xenlulozo iu ch ancol etylic 700 , hiu sut ca qu trnh l 70%,
khi lng ring ca ancol nguyn cht l 0,8 g/ml. Th tch ancol 700 thu c l :
A. 208,688 lit B. 298,125 lit C. 452,893 lit D. 425,926 lit
p n : D
Phng php : Tnh lng cht theo hiu sut phn ng
Qu trnh : C6H10O5 -> C6H12O6 -> 2C2H5OH + 2CO2
,mC6H10O5 = 1000.60% = 600 kg => nC6H10O5 = 100/27 kmol
=> nC2H5OH = 2.70%.100/27 = 5,185 kmol
=> VC2H5OH = 5,185.46/0,8 = 298,15 lit
=> Vdd ru = 298,15.100/70 = 425,926 lit
Cu 2: Ha tan 30g glyxin trong 60g etanol, ri thm t t 10 ml dung dch H2SO4 c ,sau un nng
1 thi gian. ngui, cho hn hp vo nc lnh, ri trung ha bng NH3 d thu c mt sn phm
hu c c khi lng 33g. Hiu sut ca phn ng l :
A. 75% B. 80% C. 85% D. 60%
p n : B
Phng php : Tnh hiu sut ca phn ng : tnh theo cht tham gia thiu
H2NCH2COOH + C2H5OH -> H2NCH2COOC2H5 + H2O
Mol 0,4 1,3 0,32 mol
=> Tnh hiu sut theo Glyxin => H% = 0,32/0,4 = 80%
Cu 3: Thy phn este C4H6O2 trong mi trng kim thu c hn hp sn phm m cc cht sn phm
u c phn ng trng gng. Cu to c th c ca este l :
A. HCOO-CH=CHCH3 B. CH2=CH-COOCH3
C. HCOO-CH2CH=CH2 D. CH2COOCH=CH2.
p n : A
Thy phn este m hn hp sn phm c cc cht u c phn ng trng gng
=> Ch c th l HCOO-CH=CHCH3 to ra : HCOONa v CH3CH2CHO
Cu 4: Kim loi no trong s cc kim loi : Al , Fe , Ag, Cu c tnh kh mnh nht :
A. Fe B. Ag C. Al D. Cu
p n : C
Da vo dy in ha : T tri sang phi th tnh kh gim dn
Cu 5: Ln men nc qu nho thu c 100,0 lit ru vang 100 (bit hiu sut phn ng ln men t
95,0% v ancol etylic nguyn cht c khi lng ring l 0,8 g/ml). Gi s trong nc qu nho c mt
loi ng l glucozo. Khi lng glucozo c trong lng nc qu nho dng l :
A. 19,565 kg B. 16,476 kg C. 15,652 kg D. 20,595 kg
p n : B
Phng php : tnh lng cht theo hiu sut
Phn ng : C6H12O6 + H2O -> 2C2H5OH + 2CO2
C : nC2H5OH = 100.10%.0,8/46 = 0,174 kmol
=> Theo phn ng : nC6H12O6 = 0,174.0,5.100/95 = 0,0915 kmol
=> mglucozo = 16,476 kg
Cu 6: t chy hon ton m gam hp cht A (thuc dy ng ng ca anilin) thu c 4,62g CO2 , a
gam H2O v 168 cm3 N2 (dktc). Xc nh s cng thc cu to tha mn A?
A. > 4 B. 4 C. 3 D. 2
p n : B
A thuc dy ng ng ca anilin => A c CTTQ : CnH2n-7NH2
C : nN2 = 0,0075 mol ; nCO2 = 0,105 mol
=> nC : nN = 7 : 1. V A ch c 1 nguyn t N nn A c 7C (n = 7)
=> A l C7H7NH2
Cc CTCT tha mn :
C6H5CH2NH2 ; o,m,p-CH3-C6H4NH2
Vy c 4 CTCT tha mn.
Cu 7: X l mt hp cht c CTPT C6H10O5 :
X + 2NaOH 2Y + H2O
o
t
Y + HCllong Z + NaCl
Hy cho bit 0,1 mol Z tc dng vi Na d th thu c bao nhiu mol H2 ?
p n : A
X l : HO-C2H4-CO-O-CO-C2H4-OH
Y l : HO-C2H4-COONa
Z l : HO-C2H4-COOH
HO-C2H4-COOH + 2Na -> NaO-C2H4-COONa + H2
=> nH2 = nZ = 0,1 mol

o H 2 SO4 o
dd, NaOH ,t
NH3 , H 2O Na2 SO3
C2 H5OH , H 2 SO4 ,t
H 2O

A B C CH3-CH(NH3HSO4)-COOC2H5
A l :
A. CH3-CH(NH2)-COONH4 B. CH3-CH(CH3)-COONH4
C. H2N-CH2-CH2-COOH D. CH3-CH(NH2)-COOH
p n : A
A : CH3-CH(NH2)-COONH4
B : CH3-CH(NH2)-COONa
C : CH3-CH(NH3HSO4)-COOH
Cu 9: Hp cht A c cng thc phn t C4H6Cl2O2. Cho 0,1 mol A tc dng va vi dung dch cha
0,3 mol NaOH, thu c dung dch hn hp trong c 2 cht hu c gm ancol etylic v cht hu c
X, c cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l :
A. 9,60g B. 23,1g C. 11,4g D. 21,3g
p n : D
A + NaOH t l mol 1 : 3 v to 2 cht hu c trong c ancol etylic
=> A l : Cl2CHCOOC2H5
Cl2CHCOOC2H5 + 3NaOH -> OHC-COONa + 2NaCl + C2H5OH + H2O
=> Cht rn gm : 0,1 mol OHC-COONa ; 0,2 mol NaCl
=> m = 21,3g
Cu 10: Dung dch no lm xanh qu tm :
A. CH3CH(NH2)COOH B. H2NCH2CH(NH2)COOH
C. ClH3NCH2COOH D. HOOCCH2CH(NH2)COOH
p n : B
Cc cht c s nhm NH2 > s nhm COOH th l qu tm ha xanh
Cu 11: Amino axit l nhng hp cht hu c cha cc nhm chc :
A. cacboxyl v hidroxyl B. hidroxyl v amino
C. cacboxyl v amino D. cacbonyl v amino
p n : C
Cu 12: Trong dy chuyn ha
H 2O H2 O2 Y
X
C2H2 Y
Z T. Cht T l :
A. CH3COOH B. CH3COOC2H5 C. CH3COOC2H3 D. C2H5COOCH3

p n : B
S ph hp : C2H2 CH3CHO C2H5OH CH3COOH CH3COOC2H5(T)
Cu 13: Sp xp cc hp cht sau : metyl amin (I) ; dimetylamin(II) ; NH3(III) ; p-metylanilin (IV) ;
anilin (V) theo trnh t tnh bazo gim dn :

A. II > I > III > IV > V B. IV > V > I > II > III
C. I > II > III > IV D. III > IV > II > V > I
p n : A
Cc nhm R no nh vo N th lm tng lc bazo
Cc nhm R khng no lm gim lc bazo
Cng nhiu R cng nhm nh vo N th hiu ng cng tng.
Cu 14: bo v v tu ngi ta thng dng phng php no sau y :
A. Dng hp kim khng g B. Dng cht chng n mn
C. M 1 lp kim loi bn ln v tu D. Gn l Zn ln v tu.
p n : D
Khi gn l km ln v tu(Fe) th to pin in vi cc (-) l Zn
=> khi Zn b oxi ha ch khng phi l Fe => bo v c tu thi gian di, chi ph tit kim.
Cu 15: Xenlulozo trinitrat l cht d chy v n mnh c u ch t xenlulozo v HNO3. Mun iu
ch 29,7 kg xenlulozo trinitrat (hiu sut 90%) th th tch HNO3 96% (d = 1,52g/ml) cn dng l :
A. 1,439 lit B. 15 lit C. 24,39 lit D. 14,39 lit
p n : D
Phng php : Tnh lng cht t hiu sut phn ng.
[C6H7O2(OH)3]n + 3nHNO3 -> [C6H7O2(ONO2)3]n + 3nH2O
,nxenlulozo trinitrat = 0,1/n (kmol)
=> nHNO3 = 3n . 0,1/n . 100/90 = 1/3 kmol
=> VHNO3 dd = 14,39 lit
Cu 16: Tnh cht bazo ca anilin yu hn NH3 th hin phn ng no :
A. anilin tc dng c vi axit
B. anilin d to kt ta vi dung dch FeCl3
C. anilin tc dng d dng vi nc Brom
D. anilin khng lm i mu qu tm
p n : D
Cu 17: Nhn nh no di y khng ng v glucozo v fructozo :
A. Glucozo v Fructozo u tc dng c vi hidro to poliancol
B. Glucozo v Fructozo u tc dng c vi Cu(OH)2 to ra dung dch phc ng mu xanh lam.
C. Glucozo c phn ng trng bc v n c tnh cht ca nhm CHO
D. Khc vi glucozo, fructozo khng c phn ng trng bc v dng mch h no khng c nhm
CHO
p n : D
D sai v Fructozo trong mi trng kim chuyn thnh Glucozo nn c phn ng trng bc.

Cu 18: Cho kh CO i qua ng cha 0,04 mol X gm FeO v Fe2O3 t nng, ta nhn c 4,784g cht
rn Y (gm 4 cht), kh i ra khi ng dn qua dung dch Ba(OH)2 d th thu c 9,062g kt ta. Phn
trm khi lng FeO trong hn hp X l :
A. 24,42% B. 25,15% C. 32,55% D. 13,04%
p n : D
Phng php : Bo ton khi lng
Qu trnh : X(FeO,Fe2O3) -> Y(Fe,FeO,Fe2O3,Fe3O4)
=> nCO2 = nBaCO3 = 0,046 mol = nO(p)
Bo ton khi lng : mX = mY + mO(p) = 5,52g = 72nFeO + 160nFe2O3
V : nX = nFeO + nFe2O3 = 0,04 mol
=> nFeO = 0,01 ; nFe2O3 = 0,03 mol
=> %mFeO = 13,04%
Cu 19: Cho 1,22g mt este E phn ng va vi 0,02 mol KOH, c cn dung dch thu c 2,16g hn
hp mui F. t chy hon ton mui ny thu c 2,64g CO2 ; 0,54g H2O v a gam K2CO3. ME < 140
vC. Trong F phi cha mui no sau y?
A. CH3C6H4-OK B. C2H5COOK C. CH3COOK D. HCOOK
p n : D
V : mE + mKOH = 2,34g > mF => c to H2O sau phn ng vi KOH
=> nH2O = 0,01 mol
=> Este c dng : R1COO-C6H4R2
=> F gm : 0,01 mol R1COONa v 0,01 mol R2-C6H4-OK
V nE = 0,01 mol => ME = 122g < 140 vC => R1 + R2 = 2 => R1 = R2 = 1 (H)
Vy trong F buc phi cha mui HCOOK
Cu 20: Trng thi v tnh tan ca cc amino axit l :
A. Cht lng d tan trong nc B. Cht rn d tan trong nc
C. Cht rn khng tan trong nc D. Cht lng khng tan trong nc
p n : B
Cu 21: Cho cc cp cht: (1) CH3COOH v C2H5CHO ; (2) C6H5OH v CH3COOH ; (3) C6H5OH v
(CH3CO)2O ; (4) CH3COOH v C2H5OH ; (5) CH3COOH v CHCH ; (6) C6H5COOH v C2H5OH.
Nhng cp cht no tham gia phn ng to thnh este iu kin thch hp?
A. (3),(4),(6) B. (1),(2),(3),(4),(5)
C. (3),(4),(5),(6) D. (2),(3),(4),(5),(6)
p n : C
Cu 22: un nng 0,4 mol hn hp E gm dipeptit X, tripeptit Y v tetrapeptit Z u mch h bng
lng va dung dch NaOH, thu c dung dch cha 0,5 mol mui ca glyxin v 0,4 mol mui ca
alanin v 0,2 mol mui ca valin. Mt khc t chy m gam E trong O2 va ddurr thu c hn hp O2,
H2O v N2, trong tng khi lng ca CO2 v nc l 78,28g. Gi tr ca m gn nht vi gi tr no :

A. 40 B. 50 C. 35 D. 45
p n : C
Phng php: Qui i hn hp v thnh 1 cht i din, bo ton khi lng.
t : CT amino axit: CnH2n+1O2N
( x 1) H 2O
x CnH2n+1O2N hh E CnH2nO2NNa; mhh mui = 120,7 gam
NaOH
120, 7 32 1,1
Ta c : 14n + 69 = 0, 4 => n = 11 ; x = 0, 4 = 2,75
1,75H 2O O2
2,75 CnH2n+1O2N C2,75n H5,5n 0,75O3,75N2,75 (E) CO2 + H2O + N2
t nE = a (mol)
mCO2 + mH2O = 44.2,75an + 9(5,5n 0,75)a = 78,28 => a = 0,16 mol
32
mhh E = 0,16(38,5. 11 - 0,75 + 16.3,75 + 14.2,75) = 33,56 gam
Cu 23: Mun tng hp 120 kg metylmetacrylat, hiu sut qu trnh este ha v trng hp ln lt l
60% v 80%, khi lng axit v ancol cn dng ln lt l :
A. 170 kg v 80 kg B. 65 kg v 40 kg
C. 171 kg v 82 kg D. 215 kg v 80 kg
p n : D
Phng php : Tnh lng cht theo hiu sut
CH2=C(CH3)COOH + CH3OH -> CH2=C(CH3)COOCH3 -> Trng hp
=> nmt xch = neste = 1,2 kmol
=> nancol = naxit = 1,2 . 100/60 . 100/80 = 2,5 kmol
=> mancol = 80kg ; maxit = 215 kg
Cu 24: ng dng no sau y ca amino axit l khng ng :
A. Axit glutamic l thuc b thn kinh
B. Mui inatri glutamat dng lm gia v thc n (gi l m chnh hay bt ngt)
C. Amino axit thin nhin (hu ht l a-amino axit) l c s kin to nn cc loi protein ca c th
sng.
D. Cc amino axit c nhm NH2 v tr s 6 tr ln l nguyn liu sn xut t nilon.
p n : B
Mui mononatri ca axit glutamic mi lm m chnh
Cu 25: Nung hn hp bt gm 15,2g Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton
thu c 23,3g hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl d thy thot ra V lit kh
H2(dktc). Gi tr ca V l :
A. 10,08 B. 4,48 C. 7,84 D. 3,36
p n : C

Bo ton khi lng : mAl + mCr2O3 = mX => nAl = 0,3 mol ; nCr2O3 = 0,1 mol
Phn ng : 2Al + Cr2O3 -> Al2O3 + 2Cr
Sau phn ng c : nCr = 0,2 mol ; nAl = 0,1 mol l phn ng vi axit to H2
Cr + 2HCl -> CrCl2 + H2
Al + 3HCl -> AlCl3 + 1,5H2
=> nH2 = nCr + nAl.1,5 = 0,35 mol
=> VH2 = 7,84 lit
Cu 26: c im ca n mn in ha l :
A. Khng pht sinh dng in.
B. C pht sinh dng in
C. Tc n mn ph thuc vo nhit
D. Tc n mn khng ph thuc vo nhit .
p n : B
Cu 27: C cc nhn nh sau :
1. Cht bo l trieste ca glixerol vi cc axit monocacboxylic c mch C di khng phn nhnh.
2. Lipit gm cc cht bo ,sp, steroid, photpholipit,...
3. Cht bo l cht lng
4. Cht bo cha cc gc axit khng no thng l cht lng nhit thng v c gi l du.
5. Phn ng thy phn cht bo trong mi trng kim l phn ng thun nghch.
6. Cht bo l thnh phn chnh ca du m ng vt, thc vt.
S nhn nh ng :
A. 5 B. 2 C. 4 D. 3
p n : D
1. Sai, v cht bo l trieste ca axit monocacboxylic c s C chn t 12-24, khng phn nhnh
3. Sai, v cht bo no l cht rn
5. Sai, v phn ng thy phn cht bo trong mi trng kim l phn ng 1 chiu
Vy c 3 ng.
Cu 28: Phn bit 3 dung dch : H2N-CH2-COOH, CH3COOH v C2H5NH2 ch dng mt thuc th l :
A. dung dch HCl B. dung dch NaOH C. Natri kim loi D. Qu tm
p n : D
Nu dng Qu tm :
+) H2N-CH2-COOH : tm
+) CH3COOH :
+) C2H5NH2 : xanh
Cu 29: Hn hp A gm 2 kim loi Fe Cu. C th dng dung dch no sau y thu c Cu kim
loi?
A. Dung dch Cu(NO3)2 d B. Dung dch MgSO4 d

C. Dung dch Fe(NO3)2 d D. Dung dch FeCl3 d
p n : A
Dng Cu(NO3)2 v n ch phn ng vi Fe to Cu kim loi
Cu 30: un nng 20g mt loi cht bo trung tnh vi dung dch cha 0,25 mol NaOH, trung ha
NaOH d cn 0,18 mol HCl. Khi lng x phng 72% sinh ra t 1 tn cht bo trn l :
A. 1434,26 kg B. 1703,33 kg C. 1032,67 kg D. 1344,26 kg
p n : A
nNaOH p = 0,25 0,18 = 0,07 mol
Phn ng tng qut : Cht bo + 3NaOH -> 3.Mui mononatri + C3H5(OH)3
=> nglicerol = 1/3.nNaOH = 0,07/3 mol
=> mMui = 20,653g
Vi 1 tn Cht bo th to mMui = 1032,67 kg
=> mX phng 72% = 1434,26 kg
Cu 31: Ly 14,3g hn hp X gm Mg, Al, Zn em t nng trong oxi d, sau khi phn ng xy ra hon
ton th nhn c 22,3g hn hp Y gm 3 oxit. Tnh th tch dung dch HCl 2M ti thiu cn dng
ha tan hn hp Y.
A. 400 ml B. 600 ml C. 500 ml D. 750 ml
p n : C
Bo ton khi lng : mX + mO (p) = mY => nO(p) = 0,5 mol
Phn ng tng qut : O + 2H+ -> H2O
=> nHCl = 2nO = 1 mol
=> Vdd HCl = 0,5 lit = 500 ml
Cu 32: Cho cc cht : etyl axetat, etanol, axit acrylic, phenol, phenylamoni clorua, phenyl axetat. Trong
cc cht ny, s cht tc dng c vi dung dch NaOH l :
A. 6 B. 5 C. 4 D. 3
p n : B
Cc cht tha mn : etyl axetat, axit acrylic, phenol, phenylamoni clorua, phenyl axetat
Cu 33: C nhng cp kim loi sau y tip xc vi nhau, khi xy ra s n mn in ha th trong cp
no st khng b n mn :
A. Fe-Sn B. Fe-Zn C. Fe-Cu D. Fe-Pb
p n : B
St khng b n mn khi st cc dng
Cu 34: Trong s cc loi t sau : t tm, t visco, t nilon-6,6 , t axetat, t capron, t enang, nhng
loi t no thuc loi t nhn to :
A. T nilon-6,6 v t capron B. T visco v t nilon-6,6
C. T visco v t axetat D. T tm v t enang

p n : A
Cu 35: phn bit du bi trn my vi du thc vt, ngi ta :
A. t chy ri nh lng oxi trong tng cht
B. Cho Cu(OH)2 vo tng cht
C. Ha tan trong benzen
D. un nng vi KOH d, ri cho thm dung dch CuSO4 vo.
p n : D
Khi un nng vi KOH th du thc vt do l trieste ca glicerol nn s phn ng thy phn to
C3H5(OH)3.
Sau cho Cu(OH)2 vo th Cu(OH)2 s tan trong C3H5(OH)3 to phc tan mu xanh.
Du bi trn l hidrocacbon nn khng c hin tng trn.
Cu 36: Tnh cht no sau y khng phi l tnh cht c trng ca kim loi :
A. Tc dng vi dung dch mui B. Tc dng vi bazo
C. Tc dng vi phi kim D. Tc dng vi axit
p n : B
Cu 37: Cho 5,6g hn hp X gm Mg, MgO c t l mol tng ng l 5 : 4 tan va trong dung dch
hn hp cha HCl v KNO3. Sau phn ng thu c 0,224 lit kh N2O (dktc) v dung dch Y ch cha
mui clorua. Bit cc phn ng hon ton. C cn dung dch Y cn thn thu c m gam mui. Gi tr
ca m l :
A. 20,51g B. 23,24g C. 24,17g D. 18,25g
p n : A
Phng php : Bo ton nguyn t, bo ton electron.
,nMg = 0,1 ; nMgO = 0,08 mol ; nN2O = 0,01 mol
Bo ton e : 2nMg = 8nN2O + 8nNH4+ => nNH4+ = 0,015 mol
V dung dch ch cha mui clorua l : MgCl2 ; KCl ; NH4Cl
Bo ton nguyn t : nKNO3 = nKCl = 2nN2O + nNH4+ = 0,035 mol
Vy Y gm : 0,035 mol KCl ; 0,18 mol MgCl2 ; 0,015 mol NH4Cl
=> m = 20,51g
Cu 38: Nhn nh no sau y l ng nht :
A. Phn t polime do nhiu n v mt xch to thnh
B. Xenlulozo c th b polime khi c un nng
C. Monome v mt xch trong polime c cu to ging nhau
D. Cao su lu ha l sn phm khi lu ha cao su thin nhin.
p n : D
A Sai v cc n v mt xch ny phi lp li theo mt qui lut nht nh
B Sai, ch khi un nng vi H+ th xenlulozo mi b thy phn to Glucozo
C Sai, v mt xch c th gm nhiu monome

Cu 39: Qu trnh thy phn tinh bt bng enzim khng xut hin cht no sau y :
A. Saccarozo B. Dextrin C. Mantozo D. Glucozo
p n : A
Cu 40: Hp cht X (cha C, H, O, N) c cng thc phn t trng vi cng thc n gin nht, va tc
dng vi axit va tc dng vi kim. Trong X, % khi lng ca nguyn t C, H, N ln lt l 40,449% ;
7,865% ; 15,73%. Khi cho 4,45g X phn ng hon ton vi NaOH (un nng) c 4,85g mui khan.
Nhn nh no v X sau y khng ng :
A. X va tc dng vi dung dch HCl, va tc dng vi dung dch NaOH
B. Phn t X cha 1 nhm este
C. X d tan trong nc hn Alanin
D. X l hp cht no, tp chc.
p n : C
Phng php : Xc nh cng thc phn t da trn t l phn trm nguyn t
%mC : %mH : %mO : %mN = 40,449 : 7,865 : 35,956 : 15,73
=> nC : nH : nO : nN = 3,37 : 7,865 : 2,25 : 1,12 = 3 : 7 : 2 : 1
V CTPT trng CTGN => X l C3H7O2N
V X phn ng NaOH to mui => c nhm COO
,nX = nmui = 0,05 mol => Mmui = 97g
=> X ch c th l : H2N-C2H4COOH

TNH AN GIANG Mn: KHOA HC T NHIN HA HC
THPT CHUYN THOI Thi gian lm bi: 50 pht, khng k thi gian pht
NGC HU
( thi c 40 cu / 4 trang) M : 132

Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: ung nng 100 gam dung dch Glucoz 18% vi lng d dung dch AgNO3 trong NH3 n khi
phn ng xy ra hon ton thu c m gam Ag. Gi tr ca m l:
A. 16,2 B. 21,6 C. 10,8 D. 32,4
Cu 2: Cho cc kim loi sau: Li, Na, Al, Ca, Sr. S kim loi kim trong dy l:
A. 1 B. 3 C. 2 D. 4
Cu 3: Dung dch X gm 0,1 mol K+; 0,2 mol Mg2+; 0,1 mol Na+; 0,2 mol Cl- v a mol Y-. Iom Y- v gi
tr ca a l:
A. OH v 0,4 B. NO3 v 0,4 C. OH v 0,2 D. NO3 v 0,2
Cu 4: Cho 0,3 mol hn hp X gm H2NC3H5(COOH)2 (axit glutamic) v
(H2N)2C5H9COOH (lysin) v 400ml dung dch HCl 0,1 M, thu c dung dch Y. Bit Y phn ng vi
va ht 800ml dung dch NaOH 1M. S mol lysin trong hn hp X l:
A. 0,2 B. 0,25 C. 0,1 D. 0,15
Cu 5: Kim loi c dng ph bin to trang sc, c tc dng bo v sc khe l:
A. ng B. Bc C. St D. St ty
Cu 6: Hp th hon ton 3,36 lt kh CO2 (ktc) vo dung dch cha 0,15 mol NaOH v 0,1 Ba(OH)2,
thu c m gam kt ta. Gi tr ca m l:
A. 19,700 B. 14,775 C. 29,550 D. 9,850
Cu 7: Trong iu kin thng, cht trng thi kh l:
A. etanol B. glyxin C. Metylamin D. anilin
Cu 8: Ha tan hon ton 6,5g Zn bng dung dch H2SO4 long thu c V lt H2 (ktc). Gi tr ca V l:
A. 4,48 lt B. 3,36 lt C. 2,24 lt D. 1,12 lt
Cu 9: Phn ng khng phi l phn ng oxi ha kh l:
A. 2 KMnO4 t0
K 2 MnO4 MnO2 O2 B. Cl2 Ca OH 2 CaOCl2 H 2O
C. Fe2O3 6HNO3 2Fe NO3 3 3H 2O D. 2NaOH Cl2 NaCl NaClO H 2O
Cu 10: Cng thc ha hc ca st (III) hidroxit l:
A. Fe2O3 B. Fe(OH)3 C. Fe3O4 D. Fe2(SO4)3
Cu 11: Khi lm th nghim vi H2SO4 c nng thng sinh ra kh SO2. hn ch kh SO2 thot ra
gy nhim mi trng, ngi ta thng nt ng nghim bng bng tm dung dch.
A. Mui n B. gim n C. kim D. ancol
Cu 12: Dung dch glucoz v saccarozo u c tnh cht ha hc chung l:
A. ha tan Cu(OH)2 trong iu kin thng B. c v ngt, d tan trong nc
C. phn ng vi nc brom D. phn ng thy ngn
Cu 13: kh mi tanh ca c (gy ra do mt s amin), ta c th ra c vi:
A. nc B. nc mui C. cn D. gim
Cu 14: Lin kt ha hc trong phn t no sau y l lin kt ion:
A. NaCl B. HCl C. H2O D. Cl2
Cu 15: Cht khng thy phn trong mi trng axit l:
A. Glucozo B. saccarozo C. xenlulozo D. tinh bt
Cu 16: C cc dung dch ring bit khng dn nhn: NH4Cl, AlCl3, FeCl3, (NH4)2SO4. Dung dch thuc
th cn thit nhn bit cc dung dch trn l:
A. NaOH B. Ba(OH)2 C. NaHSO4 D. BaCl2

Cu 17: Este X c cng thc phn t C2H4O2. un nng 9,0g X trong dung dch NaOH va n khi
phn ng xy ra hon ton thu c m gam mui. Gi tr ca m l:
A. 12,3 B. 8,2 C. 15,0 D. 10,2
Cu 18: Loi vt liu polime no sau y c cha nguyn t Nit:
A. Cao su buna B. Nha poli(vinyl clorua)
C. t visco D. t nilon-6,6
Cu 19: S ng phn amin bc 1 ca cng thc C4H11N l:
A. 8 B. 3 C. 4 D. 2
Cu 20: t chy hon ton 2 amin no n chc ng ng k tip cn 2,24 lt O2 thu c 1,12 lt CO2
(cc kh u o iu kin tiu chun). Cng thc ca 2 amin l:
A. C2H5NH2, C3H7NH2 B. C3H7NH2, C4H9NH2
C. C4H9NH2, C5H11NH2 D. CH3NH2, C2H5NH2
Cu 21: Mt mu kh thi ra c cho qua dung dch CuSO4, thy xut hin kt ta mu en. Hin tng
ny do kh thi c
A. SO2 B. H2S C. CO2 D. NO2
Cu 22: Protetin tham gia phn ng mu biure to sn phm c mu
A. trng B. C. tm D. vng
Cu 23: Pht biu no sau y khng ng:
A. Dng nc kh bo qun thc phm l phng php an ton nht
B. Dng nc x l cc ion kim loi nng gy nhim ngun nc
C. mt trnh b kh do thiu vitamin A nn n c rt, gc, c chua.
D. Cc amin u khng c, c s dng ch bin thc phm.
Cu 24: Kim loi Cu khng tan trong dung dch:
A. HNO3 long B. hon3 c nng C. H2SO4 c nng D. H2SO4 long
Cu 25: Cho hn hp X gm Fe, Cu vo dung dch HNO3 long, nng thu c kh NO, dung dch Y v
cn li cht rn cha tan Z. Cho Z tc dng vi dung dch H2SO4 long thy c kh thot ra. Thnh phn
cht tan trong dung dch Y l:
A. Fe(NO3)2 B. Fe(NO3)2 v Cu(NO3)2
C. Fe(NO3)3 v Fe(NO3)2 D. Fe(NO3)3 v Cu(NO3)2
Cu 26: Ha tan hon ton mt lng Ba vo dung dch cha a mol HCl thu c dung dch X v a mol
H2. Trong cc cht sau: Na2SO4, Na2CO3, Al, Al2O3, AlCl3, Mg, NaOH, NaHCO3. S cht tc dng vi
dung dch X l:
A. 7 B. 6 C. 5 D. 4
Cu 27: t chy hon ton m gam 1 cht bo triglixerit cn 1,61 mol O2, sinh ra 1,14 mol CO2 v 1,06
mol H2O. Cho 7,088g cht bo tc dng va vi dung dch NaOH th khi lng mui to thnh l:
A. 7,312g B. 7,512g C. 7,412g D. 7,612g
Cu 28: Cho dy cht sau: H2NCH(CH3)COOH, C6H5OH (phnol), CH3COOCH3, C2H5OH, CH3NH3Cl.
S cht trong dy tc dng c vi dung dch KOH un nng l:
A. 5 B. 3 C. 4 D. 2
Cu 29: C 5 dung dch NH3, HCl, NH4Cl, Na2CO3, CH3COOH cng nng c nh ngu nhin l
A, B, C, D, E. Gi tr pH v kh nng dn in ca dung dch theo bng sau:
Dung dch A B C D E
pH 5,25 11,53 3,01 1,25 11,00
Kh nng dn in Tt Tt Km Tt Km
Cc dung dch A, B, C, D, E ln lt l
A. NH4Cl, NH3, CH3COOH, HCl, Na2CO3 B. CH3COOH, NH3, NH4Cl, HCl, Na2CO3
C. NH4Cl, Na2CO3, CH3COOH, HCl, NH3 D. Na2CO3, HCl, NH3, NH4Cl, CH3COOH
Cu 30: Hn hp 2 este X v Y l hp cht thm c cng cng thc phn t l C8H8O2. Cho 4,08g hn
hp trn phn ng vi va dung dch cha 1,6g NaOH, thu c dung dch Z cha 3 cht hu c.
Khi lng mui c trong dung dch Z l:
A. 3,34g B. 5,50g C. 4,96g D. 5,32g
Cu 31: Ha tan ht 3,264 gam hn hp X gm FeS2, FeS, Fe, CuS v Cu trong 600ml dung dch HNO3
1M ung nng, sau khi kt thc cc phn ng thu c dung dch Y v 1,8816 lt (ktc) mt cht kh
thot ra. Cho Y tc dng vi lng d dung dch BaCl2 thu c 5,92 gam kt ta. Mt khc, dung dch

Y c th ha tan ti a m gam Fe. Bit trong qu trnh trn, sn phm kh duy nht ca N+5 l NO. Gi tr
ca m l
A. 9,760 B. 9,120 C. 11,712 D. 11,256
Cu 32: Hn hp X gm Mg, Fe, Fe3O4, CuO, trong oxi chim 20% khi lng. Cho m gam X tan
hon ton vo dung dch Y gm H2SO4 1,65M v NaNO3 1M, thu c dung dch z ch cha 3,66m gam
mui trung ha v 1,792 lt kh NO (dktc). Dung dch z phn ng ti a vi 1,22 mol KOH. Gi tr ca m
l :
A. 32 B. 24 C. 28 D. 36
Cu 33: Khi nh t t n d dung dch KOH vo dung dch hn hp gm X mol HC1 v y mol ZnCl2,
kt qu ca th nghim c biu din theo th sau :
Tng (x + y + z) l:
A. 2,0 B. 1,1 C. 0,8 D. 0,9
Cu 34: Nhm t li ch kinh t, mt s trang tri chn nui heo bt chp th on dng mt s ha
cht cm trn vo thc n vi liu lng cao trong c Salbutamol. Salbutamol gip heo ln nhanh ,
t l nc cao. Mu sc tht hn. Nu con ngi n phi tht heo c nui c s dng Salbutamol th s
gy ra nhc c, gim vn ng ca c, khp khin c th pht trin khng bnh thng. Salbutamol c
cng thc cu to thu gn nht nh sau :
Salbutamol c cng thc phn t l :

A. C3H22O3N B. C13H19O3N C. C13H20O3N D. C13H21O3N
Cu 35: Tin hnh cc th nghim sau :
(a) Cho dung dch AgNO3 vo dung dch HCl
(b) Cho Al2O3 vo dung dch HCl long d
(c) Cho Cu vo dung dch HCl c nng d
(d) Cho Ba(OH)2 vo dung dch KHCO3
Sau khi kt thc cc phn ng, s th nghim thu c cht rn l :
A. 2 B. 3 C. 1 D. 4
Cu 36: Ha tan hon ton a gam Na vo 100 ml dung dch Y gm H2SO4 0,5M v HCl 1M, thy thot
ra 6,72 lt kh (dktc). C cn dung dch sau phn ng thu c m gam cht rn. gi tr ca m gn nht vi
A. 28 B. 27 C. 29 D. 30
Cu 37: ung nng 0,4 mol hn hp E gm ipeptit X, tripeptit Y v tetrapeptit Z u mch h bng
lng va dung dch NaOH, thu c dung dch cha 0,5 mol mui ca glyxin, 0,4 mol mui ca
alanin, 0,2 mol mui ca valin. Mt khc t chy m gam E trong O2 va thu c hn hp CO2, H2O
v N2, trong tng khi lng CO2 v H2O l 78,28 gam. Gi tr ca m gn nht vi gi tr no sau y
?
A. 45 B. 40 C. 50 D. 35
Cu 38: X, Y, Z l 3 este u no mch h (khng cha nhm chc khc v (Mx < My < Mz). un nng
hn hp E cha X,Y,Z vi dung dch NaOH va thu c 1 ancol T v hn hp F cha 2 mui A, B
c t l mol tng ng l 5 : 3 (MA< MB). Dn ton b T qua bnh ng Na d thy khi lng bnh tng
12 gam v ng thi thu c 4,48 lt H2 (dktc). t chy ton b F thu c Na2CO3, CO2 v 6,3g
H2O.S nguyn t hidro c trong Y l
A. 6 B. 8 C. 12 D. 10

(1) Cho xenlulozo vo ng nghim cha nc Svayde, khuy u thy xenlulozo tan ra.
(2) T visco , t axetat l t tng hp
(3) t nitron (hay olon) c dng dt vi may qun o m hoc bn thnh si len an o rt
(4) Cc hp cht hu c thng c nhit nng chy, nhit si cao (kh bay hi)
(5) Trong phn ng trng gng, glucozo ng vai tr cht oxi ha
S pht biu ng l :
A. 2 B. 3 C. 5 D. 4
Cu 40: Cho m gam hn hp X gm Na,Ca tan ht vo dung dch Y cha 0,08 mol NaHCO3 v 0,04 mol
CaCl2, sau phn ng thu c 7 gam kt ta v thy thot ra 0,896 lt kh (dktc). Gi tr ca m l :
A. 1,2 B. 1,56 C. 1,72 D. 1,66
p n
1-B 6-A 11-C 16-B 21-B 26-B 31-D 36-C
2-C 7-C 12-A 17-D 22-C 27-A 32-A 37-D
3-B 8-C 13-D 18-D 23-D 28-C 33-B 38-B
4-A 9-C 14-A 19-C 24-D 29-C 34-D 39-A
5-B 10-B 15-A 20-D 25-A 30-A 35-B 40-A
HNG DN CHI TIT

Cu 1:
Tng qut: Glucozo -> 2Ag
=> nAg = 2nGlucozo = 0,2 mol
=> m = 21,6 g
n p B
Cu 2:
Ch c Li, Na
p n C
Cu 3:
Phng php: bo ton in tch
Trong X: nK 2nMg 2nNa nCl n.nY
a.n 0, 4
V trong dung dch c Mg 2 nn Y khng th l OH
=> Y ch c th l NO3 (0,4 mol)
p n B
Cu 4
X gm: a mol axit glutamic: HOOC-(CH2)2-CH(NH2)-COOH
V b mol lysin H2N-(CH2)4-CH(NH2)-COOH
a b 0,3 mol
1
Xt c qu trnh: nCOOH nHCl nNaOH

nCOOH 2a b 0,8 0, 4 0, 4mol
a 0,1; b 0, 2 mol
p n A
Cu 5: p n B
Cu 6:
Phng php: Vi dng bi CO2 + kim
Nu nCO2 nOH 2nCO2 nCO3 nOH nCO2 ; nHCO3 nCO2 nCO3
C: nOH 0,35mol ; nCO2 0,15mol
nCO3 0,15mol ; c nBaOH 0,1mol
2
nBaCO3 0,1mol
Vy m 19, 700 g
p n A
Cu 7: p n C
Cu 8:
Zn H 2 SO4 ZnSO4 H 2
nH 2 nZn 0,1mol
VH 2 2, 24 lit
p n C
Cu 9:
Phn ng oxi ha kh l phn ng c s trng gim s oxi ha.
p n C
Cu 10: p n B
Cu 11:
trnh SO2 thot ra khi cn tm bng vi kim OH c phn ng:
2OH SO2 SO32 H 2O
Phn ng to mui khng bay hi v khng c nh SO2.
p n C
Cu 12:
C glucozo v saccarozo u c nhiu nhm OH k nhau

p n A
Cu 13:
Dng gim l axit nh to mui vi amin, d ra tri.
ng thi axit yu nn khng nh hng ln n cht lng tht c.
p n D
Cu 14:
Lin kt ion thng c to bi kim loi mnh (kim, kim th) v phi kim mnh (halogen)
p n A.
Cu 15:
Glucozo l monosaccarit nn khng c phn ng thy phn
p n A
Cu 16:
Khi dng Ba(OH)2 th:
- NH4Cl: c si bt kh:
Ba OH 2 2 NH4Cl BaCl2 2NH3 2H2O
- AlCl3: C kt ta trng keo, sau kt ta tan dn:
3Ba OH 2 2 AlCl3 3BaCl2 2 Al OH 3
2 Al OH 3 Ba OH 2 Ba AlO2 2 4H 2O
- FeCl3 : c kt ta nu
2FeCl3 3Ba OH 2 2Fe OH 3 3BaCl2
- (NH4)2SO4: c kt ta trng v c si bt kh
Ba OH 2 NH 4 2 SO4 BaSO4 2NH3 2H 2O
p n B
Cu 17:
Este X: C2H4O2 ch c 1 cng thc cu to duy nht l: HCOOCH3
HCOOCH3 NaOH HCOONa CH3OH
nX nHCOONa 0,15 mol
m 10, 2 g
p n D
Cu 18: n n D
Cu 19:
Cc ng phn amin bc 1 ca C4H11N l
C C C C NH 2
C C C NH 2 C
C C CH3 C NH 2
CH3 3 C NH2
p n C
Cu 20:
Phng php: t cng thc trung bnh, Bo ton nguyn t.
Gi cng thc trung bnh ca 2 amin l: Cn H 2 n3 N
Phn ng chy:
Cn H 2n3 N 1,5n 0,75 O2 nCO2 n 1,5 H 2O 0,5N2
Bo ton O: 2nO2 2nCO2 nH 2O
nH 2O 0,1 mol
Da vo phng trnh ha hc:
nH 2O nCO2 1,5na min
na min 1/ 30 mol
=> S C trung bnh trong amin = 1,5

Vy 2 amin l: CH3NH2 v C2H5NH2
p n D
Cu 21:
Do c kt ta CuS => khi ban u l H2S
(CuS khng tan trong axit)
Cu 22:
p n C
Cu 23:
C rt nhiu amin c (VD: CH3NH2, C6H5NH2)
Cu 24: n n D
Cu 25:
X + HNO3 long nng -> Y + cht rn Z khng tan
=> Z c Cu v c th c Fe
V Z + H2SO4 long thy c kh thot => Z phi c Fe d
=> trong Y ch c Fe(NO3)2
p n A
Cu 26:
Ba 2HCl BaCl2 H 2
V nH 2 a mol nHCl c phn ng
Ba 2H 2O Ba OH 2 H 2
Vy X gm BaCl2, Ba(OH)2
Cc cht tc dng vi dung dch X l:
NaSO4; Na2CO3; Al; Al2O3; NaHCO3
Cu 27:
Phng php: Bo ton khi lng, bo ton nguyn t
Phn ng chy cht bo: Bo ton khi lng
m mO2 mCO2 mH 2O m 17, 72 g
Bo ton nguyn t : nC nCO2 1,14; nH 2nH 2O 2,12 mol
nO X 2nCO2 nH2O 2nO2 0,12 mol
X c cng thc chung l RCOO 3 C3 H 5 (RCOO- l cc gc axit c th khc nhau trong cng 1 phn t)
Phn ng: RCOO 3 C3 H 5 3NaOH 3RCOONa C3 H5 OH 3
nX nC3H5 OH 1/ 6.nO X 0, 02 mol nNaOH 3nX 0, 06 mol
3
Xt trong 7,088g X th nX 0,008 mol nNaOH 0,024 mol

Bo ton khi lng ta c: mmui = mX mNaOH mC3 H5 OH 7,312 g
3
p n A
Cu 28
Cc cht tha mn l: H2NCH(CH3)COOH; C6H5OH; CH3COOC2H5; CH3NH3Cl.
p n C
Cu 29:
Kh nng dn in ph thuc vo kh nng phn ly ra ion ca cc cht
Cc cht in ly tt th s dn in tt v ngc li.
Kh nng dn in tt: NH4Cl, Na2CO3, HCl
Kh nng dn in km: NH3, CH3COOH
V pH cc dung dch theo th t: Na2CO3, NH3 > NH4Cl, CH3COOH > HCl
p n C
Cu 30:
B1: Xc nh CTCT ca 2 este
(X, Y) + NaOH -> 3 cht hu c
=> gm: mui ca axit hu c
nhh = 0,03 mol; nNaOH = 0,04 mol

=> X v Y khng th cng phn ng vi NaOH theo t l mol 1: 2 c
=> C 1 trong 2 cht phn ng vi NaOH theo t l mol 1 : 2
Vy CTCT ca 2 cht l: HCOOC6H4CH3 (X); HCOOCH2C6H5 (Y)
B2: Tnh m
Cc phn ng:
HCOOC6 H 4CH 3 2 NaOH HCOONa CH 3C6 H 4ONa H 2O
HCOOCH 2C6 H 5 NaOH HCOONa C6 H 5CH 2OH
2nX nY nNaOH 0,04 mol; nX nY 0,03mol
nX 0,01; nY 0,02
=> mmui(Z) = mHCOONa mCH3C6 H 4ONa 3,34 g
p n A
Cu 31:
Phng php: Qui i: bo ton nguyn t, bo ton electron
B1: Xc nh thnh phn ion trong dung dch Y
nBaSO4 nS X 0,024 mol
Qui hn hp X v Fe; Cu; S mFe mCu 2, 496 g
nNO 0, 084 mol nNO3 sau nHNO3 bd nNO 0,516
Bo ton O: 3nHNO3 bd nNO 3nNO3 sau 4nSO4 nH 2O
nH 2O 0, 072 mol
Bo ton H: nHNO3 bd 2nH 2O nH du nH du 0, 456 mol ch to Fe3
B2: Xc nh s mol cc nguyn t trong X
Bo ton e: 3nFe 2nCu 6nS 3nNO 0, 252 mol
nFe 0, 024; nCu 0, 018 mol
Ha tan Fe ti a => ch c Fe Fe2
3Fe 8H 2 NO3 3Fe2 2 NO 4 H 2O
Fe Cu 2 Fe 2 Cu
Fe 2 Fe3 3Fe 2
mFe 0,375nH nCu 2 0,5nFe3 0, 201 mol
m 11, 256 g
p n D
Cu 32:
Phng php:
- Qui i, bo ton electron, bo ton nguyn t, bo ton in tch
- p dng cng thc tnh nhanh khi Hn hp cht + HNO3 to sn phm kh ca Nit
nH 2nO 2nNO2 4nNO 10nN2O 12nN2 10nNH
4
B1: lp phng trnh lin quan n s mol H phn ng

+
t a lm th tch dung dch Y v b l s mol NH 4

Trong X: mKL = 0,8m ; mO = 0,2 m
(qui hn hp v kim loi v oxi)
=> nH 4nNO 10nNH 2nNO
4
0, 08.4 10b 2.0, 2m /16 2.1, 65a 1

B2: Lp phng trnh lin quan n khi lng mui sau phn ng
Bo ton N:
nNO3 Z a 0,08 b
=> mmui 0,8m 18b 23a 62. a 0, 08 b 96.1, 65a 3, 66m
2

B3: Lp phng trnh lin quan n bo ton in tch cc ion trong dung dch sau phn ng vi KOH.
Khi KOH phn ng vi X th sn phm cha 1,22 mol K+; a mol Na+ ; 1,65a mol SO42 v a 0,08 b
mol NO3
Bo ton in tch: nK nNa 2nSO4 nNO3
1, 22 a 1, 65a.2 a 0, 08 b3
T 1 , 2 , 3 a 0, 4; b 0,02; m 32 g
p n A
Cu 33:
Phng php: Vi bi tp Zn 2 OH th
Nu c hin tng kt ta nOH 4nZn2 2nZnOH
2
Ti nKOH 0,6 mol th bt u c kt ta => Khi HCl va b trung ha ht

nHCl x 0, 6 mol
Ti nKOH 1,0 mol v 1,4 mol u to cng mt lng kt ta
1
=> ti nKOH 1,0 mol th Zn 2 d nZnOH . nKOH nHCl 0, 2 mol z
2
2
Ti nKOH 1, 4 ml th kt ta tan 1 phn n KOH nHCl 4nZnCl2 2nZnOH
2
nZnCl2 y 0,3 mol

x y z 0, 6 0,3 0,1 1,1 mol
p n B
Cu 34:
Salbutamol c CTPT l C13H21O3N
p n D
Cu 35:
(a) AgNO3 HCl AgCl HNO3
(c) Cu khng phn ng vi HCl
(d) Ba OH 2 2KHCO3 K2CO3 BaCO3 2H2O
p n B
Cu 36:
nH 2nH2SO4 nHCl 0, 2 mol nH2 axit 0,1mol nH2 0,3 mol
=> C cc phn ng:
1
Na HCl NaCl H2
2
2Na H 2 SO4 Na2 SO4 H 2
1
Na H 2O NaOH H 2
2

nNaOH 2 nH2 nH2 axit 0, 4 mol
Vy khi c cn dung dch th c: 0,1 mol NaCl; 0,05 mol Na2 SO4 ; 0,4 mol NaOH
m 28,95 g
p n C
Cu 37:

Phng php qui i hp v thnh 1 cht i din, bo ton khi lng.
t: CT amino axit: Cn H 2 n 1O2 N
2
x 1 H O
xCn H 2n1O2 N hh E NaOH
Cn H 2nO2 NNa ; m hh mui = 120,7 gam
120, 7 32 1,1
Ta c: 14n 69 n ;x 2, 75
0, 4 11 0, 4
1,75 H2O
2,75Cn H 2n1O2 N C2,75n H5,5n0,75O3,75 N2,75 E
O2
CO2 H 2O N2
t nE a mol
mCO2 mH2O 44.2,75an 9 5,5n 0,75 a 78, 28 a 0,16 mol
32
mhh E 0,16 38,5. 0, 75 16.3, 75 14.2, 75 33,56 gam
11
p n D
Cu 38:
B1: Tm CTCT ca ancol T:
1
Gi cng thc ancol T l R(OH)n hoc Cx H 2x 2On : R OH n nNa R ONa n .n H 2
2
nROH 2 / n.nH2 0, 4 / n mol
n
mbnh tng = mancol mH 2 mancol 12, 4 g

M ROH 31n 14 x 2 16n
n
15n 14x 2 ( n x v 2 x 2 chn)

Ta ch thy vi n 2; x 2 th R 28 C2 H 4 tha mn.
Vy T l C2H4(OH)2 vi s mol l 0,2 mol
B2: Xc nh 2 mui A v B
C 2nancol ngoc axit
V ancol 2 chc nn cc este mch h phi c cc gc axit n chc
=> nmui = 2.0,2 = 0,4 mol
t cng thc 2 mui l Ca H 2 a 1O2 Na v Cb H 2b1O2 Na vi s mol ln lt l 5t v 3t
t 0, 05 mol
Khi t chy Ca H 2a1O2 Na 1,5a 1 O2 0,5Na2CO3 a 0,5 CO2 a 0,5 H 2O
Cb H 2b1O2 Na 1,5b 1 O2 0,5Na2CO3 b 0,5 CO2 b 0,5 H 2O
nH2O .2 nH A, B
0,35.2 0, 25 2a 1 0,15 2b 1
11 5a 3b
a 1; b 2 tha mn 2 cui HCOONa v CH3COONa
B3: Tm CTCT ca Y
Li c M X M Y M Z Y phi l: HCOOCH2CH2COOCCH3
S H trong Y 8
p n B
Cu 39:
(2) Sai. V t visco v t axetat l t bn tng hp
(4) Sai: V cc hp cht hu c khng bn nhit, d bay hi, d chy.
(5) Sai. V Glucozo trong phn ng ny ng vai tr l cht kh.
p n A
Cu 40:
1
Na H 2O NaOH H 2
2

Ca 2H 2O Ca OH 2 H 2
OH HCO3 CO32 H 2O
Ca 2 CO332 CaCO3
V nCaCO3 0, 07 mol nHCO3 0, 08 mol
C nOH 2nH 2 0, 08 mol Chng t Ca 2 thiu, CO32 d
nCa2 0, 07mol nCaCO3 nCa 0, 07 0, 04 0, 03mol
C: n Na 2nCa 0,08 mol nNa 0,02 mol
m 1, 66 g
p n A

TNH BC NINH Mn: KHOA HC T NHIN HA HC
M : 132
Cu 1: Dung dch cht no sau y c phn ng mu biure?

A. Lng trng trng. B. Metyl fomat. C. Glucoz. D.
imetyl amin.
Cu 2: phn bit 3 dung dch ring bit: H2NCH2COOH, CH3COOH, C2H5NH2 ta dng thuc th
no sau y?
A. Dung dch HCl. B. Dung dch NaOH. C. Natri. D. Qu
tm.
Cu 3: Dung dch nc brom tc dng vi dung dch ca cht no sau y nhit thng, to thnh
kt ta trng?
A. H2NCH2COOH. B. CH3NH2. C. CH3COOC2H5.
D. C6H5NH2 (anilin).
Cu 4: Cht khng c phn ng thy phn trong mi trng axit l
A. tinh bt. B. etyl axetat. C. GlyAla.
D. glucoz.
Cu 5: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut ton b qu trnh l 75%. Hp th
ton b lng kh CO2 sinh ra trong qu trnh trn vo dung dch nc vi trong, thu c 30,0 gam kt
ta v dung dch X. Bit dung dch X c khi lng gim 12,4 gam so vi dung dch nc vi trong ban
u. Gi tr ca m l
A. 48,0. B. 24,3. C. 43,2.
D. 27,0.
Cu 6: Nhng thanh Fe vo dung dch CuSO4. Sau mt thi gian, quan st thy hin tng g?
A. Thanh Fe c mu trng v dung dch nht dn mu xanh.
B. Thanh Fe c mu v dung dch nht dn mu xanh.
C. Thanh Fe c trng xm v dung dch nht dn mu xanh.
D. Thanh Fe c mu v dung dch dn c mu xanh.
Cu 7: Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376 lt (ktc) hn hp kh
X gm N2, N2O v dung dch cha 8m gam mui. T khi ca X so vi H2 bng 18. Gi tr ca m l
A. 17,28. B. 21,60. C. 19,44.
D. 18,90.
Cu 8: t chy hon ton m gam mt triglixerit X cn va x mol O2, sau phn ng thu c CO2 v
y mol H2O. Bit m = 78x 103y. Nu cho a mol X tc dng vi dung dch nc Br2 d th lng Br2
phn ng ti a l 0,15 mol. Gi tr ca a l
A. 0,20. B. 0,10. C. 0,05.
D. 0,15.
Cu 9: Pht biu no sau y khng ng?
A. kh mi tanh ca c sau khi m nu, ngi ta thng dng gim n.
B. Trong mi trng axit, fructoz chuyn thnh glucoz.
C. Tripeptit AlaGlyAla tc dng vi Cu(OH)2 trong mi trng kim to dung dch mu tm.
D. Dung dch anilin khng lm qu tm chuyn mu xanh.
Cu 10: Dung dch amino axit no sau y lm xanh qu tm?
A. Lysin. B. Glyxin. C. Alanin.
D. Axit glutamic.
Cu 11: Ha tan hon ton 2,4 gam Mg bng dung dch H2SO4 long, thu c V lt H2 ( ktc). Gi tr
ca V l
A. 2,24. B. 3,36. C. 4,48.
D. 5,60.

Cu 12: Cho 8,3 gam hn hp gm 2 amin no, n chc, mch h tc dng va vi 200 ml dung dch
HCl x mol/lt, thu c dung dch cha 15,6 gam hn hp mui. Gi tr ca x l
A. 0,5. B. 1,5. C. 2,0.
D. 1,0.
Cu 13: Cht no sau y khng phi amin bc mt?
A. C2H5NHCH3. B. CH3NH2. C. C6H5NH2.
D. C2H5NH2.
Cu 14: Trong mt s trng hp, khi ngi bnh b suy kit th c bc s ch nh truyn dch m
c th sm hi phc. Cht m trong dch truyn l
A. saccaroz. B. amin. C. glucoz.
D. amino axit.
Cu 15: Cho dung dch cha m gam glucoz tc dng vi lng d dung dch AgNO3 trong NH3 un
nng thu c ti a 10,8 gam Ag. Gi tr ca m l
A. 16,2. B. 18,0. C. 8,1.
D. 9,0.
Cu 16: Hn hp X gm Valin v GlyAla. Cho a mol X vo 100 ml dung dch HCl 1,0M, thu c
dung dch Y. Cho Y phn ng va vi 275 ml dung dch gm NaOH 1,0M un nng, thu c dung
dch cha 26,675 gam mui. Gi tr ca a l
A. 0,175. B. 0,275. C. 0,125.
D. 0,225.
Cu 17: Cho 2,24 gam bt st vo 200 ml dung dch CuSO4 0,05M. Sau khi cc phn ng xy ra hon
ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l
A. 3,84. B. 2,32. C. 1,68.
D. 0,64.
Cu 18: thy phn hon ton m gam este n chc X cn dng va ht 200 ml dung dch NaOH
0,25M, sau phn ng thu c 2,3 gam ancol v 3,4 gam mui. Cng thc ca X l
A. CH3COOCH3. B. HCOOCH3. C. CH3COOC2H5.
D. HCOOC2H5.
Cu 19: Cho dy cc cht: etyl axetat, triolein, glucoz, anilin, glyxin. S cht c phn ng vi dung
dch NaOH nhit thng l
A. 5 B. 2 C. 4
D. 3
Cu 20: Loi t no sau y c iu ch bng phn ng trng ngng?
A. T visco. B. T nitron. C. T nilon6,6.
D. T xenluloz axetat.
Cu 21: Cht no sau y va c phn ng vi H2NCH(CH3)COOH va c phn ng vi C2H5NH2?
A. CH3OH. B. NaOH. C. HCl.
D. NaCl.
Cu 22: Trng hp 1,50 tn etilen thu c m tn polietilen (PE) vi hiu sut phn ng bng 80%. Gi
tr ca m l
A. 1,500. B. 0,960. C. 1,200.
D. 1,875.
Cu 23: Cho cc cht: CH3NH2, CH3NHCH3, C6H5NH2 (anilin), NH3. Cht c lc baz mnh nht trong
dy trn l
A. CH3NH2. B. NH3. C. CH3NHCH3.
D. C6H5NH2.
Cu 24: Este no, n chc, mch h c cng thc phn t chung l
A. CnH2n+2O2 (n 2). B. CnH2n-2O2 (n 3). C. CnH2nO (n 3). D. CnH2nO2 (n
2).
Cu 25: Este CH3COOCH3 c tn gi l
A. etyl axetat. B. metyl axetat. C. etyl fomat.
D. metyl metylat.
Cu 26: Cht bo l trieste ca axit bo vi cht no sau y?
A. Etanol. B. Etylen glicol. C. Glixerol.
D. Metanol.

Cu 27: Kim loi c cng ln nht l
A. st. B. vng. C. crom.
D. nhm.
Cu 28: Este no sau y c phn t khi l 88?
A. Etyl axetat. B. Metyl fomat. C. Vinyl fomat.
D. Metyl axetat.
Cu 29: Hn hp X gm H2NCH2COOH (7,5 gam) v CH3COOC2H5 (4,4 gam). Cho ton b X tc dng
vi dung dch cha 0,2 mol NaOH, sau phn ng hon ton thu c dung dch Y. C cn dung dch Y
c m gam cht rn khan. Gi tr ca m l
A. 13,8. B. 15,8. C. 19,9.
D. 18,1.
Cu 30: Kt qu th nghim ca cc dung dch X, Y, Z vi thuc th c ghi bng sau:
X Qu tm Qu tm chuyn mu xanh
Y Cu(OH)2 trong mi trng kim Dung dch mu tm
Z Dung dch AgNO3 trong NH3 un nng Kt ta Ag trng
X, Y, Z ln lt l
A. metyl amin, lng trng trng, glucoz.
B. metyl amin, glucoz, lng trng trng.
C. glucoz, metyl amin, lng trng trng.
D. glucoz, lng trng trng, metyl amin.
Cu 31: S este c cng cng thc phn t C3H6O2 l
A. 3 B. 2 C. 1
D. 4
Cu 32: Thy ngn d bay hi v rt c. Nu chng may nhit k thy ngn b v th dng cht no
trong cc cht sau kh c thy ngn?
A. Bt st. B. Bt lu hunh. C. Bt than.
D. Nc.
Cu 33: Cht no sau y thuc loi polisaccarit?
A. Tinh bt. B. Fructoz. C. Saccaroz.
D. Glucoz.
Cu 34: Kim loi no sau y tc dng c vi nc nhit thng?
A. Fe. B. Na. C. Cu.
D. Ag.
Cu 35: X l aamino axit trong phn t c c mt nhm NH2 v mt nhm COOH. Cho 26,7 gam X
phn ng vi lng d dung dch HCl, thu c dung dch cha 37,65 gam mui. Cng thc ca X l
A. H2NCH2COOH. B. H2N[CH2]3COOH.
C. H2N[CH2]2COOH. D. H2NCH(CH3)COOH.
Cu 36: X phng ha hon ton 2,96 gam HCOOC2H5 bng mt lng dung dch NaOH va . C
cn dung dch sau phn ng, thu c m gam mui khan. Gi tr ca m l
A. 2,52. B. 3,28. C. 2,72.
D. 3,36.
Cu 37: Cho y gam kim loi M vo dung dch Fe2(SO4)3, sau phn ng hon ton khi lng phn dung
dch tng thm y gam. Kim loi M l
A. Cu. B. Ba. C. Na.
D. Ag.
Cu 38: Khi nu canh cua th thy cc mng riu cua ni ln l do
A. s ng t ca protein do nhit . B. phn ng mu ca protein.
C. s ng t ca lipit. D. phn ng thy phn ca
protein.
Cu 39: Cc cht no sau y u c phn ng thu phn trong mi trng axit?
A. Tinh bt, saccaroz, fructoz B. Tinh bt, xenluloz, saccaroz.
C. Tinh bt, xenluloz, fructoz. D. Tinh bt, xenluloz,
glucoz.

Cu 40: Phn t khi ca peptit GlyAla l
A. 146. B. 164. C. 128.
D. 132.
P N
1.A 2.D 3.D 4.D 5.C 6.B 7.B 8.C 9.B 10.A
11.A 12.D 13.A 14.D 15.D 16.C 17.B 18.D 19.D 20.C
21.C 22.C 23.C 24.D 25.B 26.C 27.C 28.A 29.B 30.A
31.B 32.B 33.A 34.B 35.D 36.C 37.A 38.A 39.B 40.A
LI GII CHI TIT
Cu 1:
Lng trng trng cng l protein.
p n A
Cu 2:
Dng : Qu tm :
+) H2NCH2COOH : Tm
+) CH3COOH :
+) C2H5NH2 : xanh
p n D
Cu 3:
p n D
Cu 4:
p n D
Cu 5:
Phng php : Tnh lng cht theo hiu sut phn ng.
Ta c : mdd gim = mCaCO3 mCO2 => nCO2 = 0,4 mol
(C6H10O5)n -> nC6H12O6 -> 2nCO2
=> ntinh bt = 1/2n . 100/75 . 0,4 = 4/15 mol
=> m = 43,2g
p n C
Cu 6:
Nh phn ng : Fe + CuSO4(xanh) -> FeSO4 + Cu()
p n B
Cu 7:
Phng php :
-Bo ton e
-Kim loi phn ng vi HNO3 to sn phm kh th p dng :
Cng thc : ne = nNO2 + 3nNO + 8nN2O + 10nN2 + 8nNH4NO3
C : MX = 36g , nX = 0,24 mol => nN2 = nN2O = 0,12 mol

Al s chuyn ht thnh Al(NO3)3 => nAl(NO3)3 = nAl = m/27 (mol)
=> mAl(NO3)3 = 7,89m < 8m => c NH4NO3 => nNH4NO3 = m/720 (mol)
Bo ton e : 3nAl = 8nN2O + 10nN2 + 8nNH4NO3
=> 3.m/27 = 8.0,12 + 10.0,12 + 8.m/720
=> m = 21,6g
p n B
Cu 8:
Phng php : Bo ton khi lng , Bo ton nguyn t
Bo ton khi lng : mX + mO2 = mCO2 + mH2O
=> nCO2 = (110x 121y)/44 = 2,5x 2,75y (mol)
Bo ton Oxi : 6nX + 2nO2 = 2nCO2 + nH2O => nX = 0,5x 0,75y

(s pi - 1).nX = nCO2 nH2O = 2,5x 2,75y y = 2,5y 3,75y
=> (S pi 1) = (2,5 3,75y) : (0,5x 0,75y) = 5
=> S pi = 6. V c 3 pi trong 3 nhm COO
=> S pi trong gc hidrocacbon = 3
=> nBr2 = 3nX => a = 0,05 mol
p n C
Cu 9:
B Sai. V trong mi trng kim th fructozo mi chuyn thnh glucozo.
p n B
Cu 10:
Lysin c 2 nhm NH2 v 1 nhm COOH
p n A
Cu 11:
Mg + H2SO4 -> MgSO4 + H2
=> nH2 = nMg = 0,1 mol
=> VH2 = 2,24 lit
p n A
Cu 12:
Tng qut : R-N + HCl -> RNHCl
Bo ton khi lng : mamin + mHCl = mmui
=> nHCl = 0,2 mol
=> x = 1M
p n D
Cu 13:
Amin bc 1 l amin ch c 1 nhm hidrocacbon thay th cho 1 H trong phn t NH3
p n A
Cu 14:
p n D
Cu 15:
Glucozo -> 2Ag
=> nGlucozo = nAg = 0,05 mol
=> m = 9g
p n D
Cu 16:
Trong a mol X c : x mol Valin ; y mol Gly-Ala
Xt tng qut : nNaOH = nHCl + nVal + 2nGly-Ala => x + 2y = 0,175 mol (1)
Li c: hn hp mui gm : x mol Val-Na ; y mol Gly-Na ; y mol Ala-Na ; 0,1 mol NaCl
=> mmui = 139x + 208y + 0,1.58,5 = 26,675g(2)
T (1),(2) => x = 0,075 ; y = 0,05 mol
=> a = 0,125 mol
p n C
Cu 17:
Fe + CuSO4 -> FeSO4 + Cu
, nFe = 0,04 mol ; nCuSO4 = 0,01 mol
=> cht rn gm : 0,01 mol Cu v 0,03 mol Fe
=> m = 2,32g
p n B
Cu 18:
V phn ng va => nNaOH = nancol = nmui = 0,05 mol
=> Mancol = 46g => C2H5OH
V Mmui = 68g => HCOONa
Vy este l HCOOC2H5
p n D
Cu 19:
Cc cht : etyl axetat, triolein, glyxin

p n D
Cu 20:
p n C
Cu 21:
p n C
Cu 22:
Phn ng : nCH2=CH2 -> (-CH2-CH2-)n
Bo ton khi lng : metilen p =mPE
Do H% = 80% => mPE = 80%.mEtilen = 1,2 tn.
p n C
Cu 23:
Cc gc hidrocacbon no gn vo N lm tng lc bazo
Cc gc hidrocacbon thm (C6H5-) gn vo N s lm gim lc bazo
Cng nhiu nhm s cng tng hiu lc.
p n C
Cu 24:
p n D
Cu 25:
p n B
Cu 26:
p n C
Cu 27:
p n C
Cu 28:
p n A
Cu 29:
Trong X c : 0,1 mol H2NCH2COOH v 0,05 mol CH3COOC2H5 phn ng vi NaOH
To ra cht rn gm : 0,1 mol H2NCH2COONa ; 0,05 mol CH3COONa ; 0,05 mol NaOH
=> m = 15,8g
p n B
Cu 30:
p n A
Cu 31:
Cc CTCT : HCOOC2H5 ; CH3COOCH3.
p n B
Cu 32:
Nh phn ng : Hg + S -> HgS
p n B
Cu 33:
p n A
Cu 34:
p n B
Cu 35:
X c dng : H2N-R-COOH + HCl -> ClH3NRCOOH
Bo ton khi lng : mX + mHCl = mMui => nHCl = 0,3 mol = nX
=> MX = 89g => X l CH3-CH(NH2)-COOH
p n D
Cu 36:
HCOOC2H5 + NaOH -> HCOONa + C2H5OH
=> nHCOONa = nHCOOC2H5 = 0,04 mol
=> m = 2,72g
p n C
Cu 37:
Cho y gam M vo th dung dch tng y gam => khng c cht thot ra khi dung dch
=> Cu + Fe2(SO4)3 -> CuSO4 + 2FeSO4

p n A
Cu 38:
p n A
Cu 39:
p n B
Cu 40:
p n A

S GD T THI TH THPT QUC GIA LN 1 NM 2017
TNH QUNG TR Mn: KHOA HC T NHIN HA HC
THPT CHU VN AN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Cho kim loi Ba d vo dung dch Al 2(SO4)3, thu c sn phm c:

A. Mt cht kh v hai cht kt ta. B. Mt cht kh v khng cht kt ta.
C. Mt cht kh v mt cht kt ta. D. Hn hp hai cht kh.
Cu 2: phn bit cc dung dch: CaCl 2, HCl, Ca(OH)2 dng dung dch ?
A. NaNO3 B. NaOH C. NaHCO3 D. NaCl
Cu 3: un nng tristearin trong dung dch NaOH thu c glixerol v ?
A.C17H35COONa B. C17H33COONa C. C15H31COONa D. C17H31COONa
Cu 4: Hai hp cht hu c no sau y l ng phn ca nhau?
A. amiloz v amilopectin. B. anilin v alanin.
C. vinyl axetat v metyl acrylat. D. etyl aminoaxetat v -aminopropionic.
Cu 5: Thy phn hon ton tripeptit X, thu c glyxin v alanin. S ng phn cu to ca X l.
A. 3 B. 4 C. 5 D. 6
Cu 6: Nhn nh no sau y l sai?
A. Dng dung dch Na2CO3 lm mt tnh cng ca nc nc cng ton phn.
B. Na2CO3 l nguyn liu trong cng nghip sn xut thy tinh, x phng.
C. Dng dung dch Na2CO3 ty sch vt du m bm trn chi tit my.
D. Na2CO3 l nguyn liu chnh dng trong y hc, cng ngh thc phm, ch to nc gii kht.
Cu 7: Cho x mol bt Fe vo dung dch cha y mol FeCl 3 v z mol HCl, sau khi kt thc phn ng thu
c dung dch X v cn li t mol kim loi khng tan. Biu thc lin h x, y, z, t l.
A. 2x = y + z + t B. x = y + z t C. x = 3y + z 2t D. 2x = y + z + 2t
Cu 9: Ln men hon ton a gam glucoz, thu c C 2H5OH v CO2. Hp th ht CO2 sinh ra vo
A. 30,6 B. 27,0 C. 15,3 D. 13,5
Cu 10: Ha tan hon ton 21,5 gam hn hp X gm Al, Zn, FeO, Cu(NO 3)2 cn dng ht 430 ml
dung dch H2SO4 1M thu c hn hp kh Y (ktc) gm 0,06 mol NO v 0,13 mol H 2, ng thi thu
c dung dch Z ch cha cc mui sunfat trung ha. C cn dung dch Z thu c 56,9 gam mui
khan. Thnh phn phn trm ca Al trong hn hp X c gi tr gn nht l:
A. 25,5% B. 18,5% C. 20,5% D. 22,5%
A. 2 B. 1 C. 4 D. 3
A. 66,98 B. 39,4 C. 47,28 D. 59,1
A. Phn ng gia ancol vi axit cacboxylic c gi l phn ng x phng ha.
B. Phn ng x phng ha l phn ng thun nghch.
C. Trong cng thc ca este RCOOR, R c th l nguyn t H hoc gc hidrocacbon.
D. Phn ng este ha l phn ng mt chiu.
Cu 16: Cho dung dch mui X vo dung dch mui Y, thu c kt ta Z. Cho Z vo dung dch
H2SO4 (long, d), thy thot ra kh khng mu; ng thi thu c kt ta T. X v Y ln lt l.
A. NaHSO4 v Ba(HCO3)2. B. Ba(HCO3)2 v Ba(OH)2.
C. Na2CO3 v BaCl2. D. FeCl2 v AgNO3.
Cu 17: Cho m gam hn hp gm Na, Na 2O, Ba, BaO vo lng nc d, thu c dung dch X v a
mol kh H2. Sc kh CO2 n d vo dung dch X, phn ng c biu din theo th sau:
Khi lng kt ta
23,64
Gi tr m l. a 0,4 S mol CO2

(1) Hiro ha hon ton glucoz cng nh fructoz thu c axit gluconic.
(2) Glucoz, fructoz l nhm cacbohirat n gin nht khng thy phn c.
(3) Thy phn n cng xenluloz trong mi trng axit to ra nhiu phn t monosaccarit.
(4) Trong phn t saccaroz gc -glucoz v gc -glucoz lin kt vi nhau qua nguyn t oxi.
(5) Tinh bt l cht rn v nh hnh, mu trng, iu kin thng khng tan trong nc.
(6) Phn t amiloz v amilopectin c cu trc mch phn nhnh.
S pht biu ng l.
A. 5 B. 4 C. 6 D. 3
Cu 20: Cho 3,72 gam hn hp gm Mg v Al vo V ml dung dch cha AgNO 3 x (mol/l) v
Cu(NO3)2 y (mol/l). Sau khi kt thc phn ng, thu c dung dch X v 20,0 gam rn Y. Cho dung
dch NaOH d vo X, thy lng NaOH phn ng l 18,4 gam. Lc ly kt ta nung ngoi khng kh
n khi lng khng i thu c 7,6 gam hn hp gm hai oxit. T l x : y l
A. 4 : 5 B. 2 : 3 C. 1 : 1 D. 1 : 3
Cu 21: un nng triglyxerit X vi dung dch NaOH va , thu c dung dch Y cha 2 mui natri
ca axit stearic v oleic. Chia Y lm 2 phn bng nhau. Phn 1 lm mt mu va dung dch cha
0,12 mol Br2. Phn 2 em c cn thu c 54,84 gam mui. Khi lng phn t ca X l.
A. 886 B. 888 C. 884 D. 890
Cu 22: Ha tan ht 12,48 gam hn hp gm Fe, FeO, Fe 3O4, Fe2O3 trong dung dch cha 0,74 mol
HNO3 (dng d), thu c 0,08 mol kh X v dung dch Y. Dung dch Y ha tan ti a x gam bt Cu.

Bit kh NO l sn phm kh duy nht ca c qu trnh v cc phn ng xy ra hon ton. Gi tr ca x
l.
Cu 23: Este X c to bi t mt axit cacboxylic hai chc v hai ancol n chc. t chy hon
ton X lun thu c CO 2 c s mol bng vi s mol O 2 phn ng. Thc hin s phn ng sau
(ng vi t l mol cc cht).
0 0
(1) X + 2H2 Ni,t
Y (2) X + 2NaOH t
Z + X 1 + X2
Bit rng X1 v X2 thuc cng dy ng ng v khi un nng X 1 vi H2SO4 c 1700C khng thu
c anken. Nhn nh no sau y l sai?
A. X, Y u c mch khng phn nhnh. B. Z c cng thc phn t l C4H2O4Na2.
C. X2 l ancol etylic. D. X c cng thc phn t l C7H8O4.
Cu 24: Tin hnh in phn dung dch cha NaCl v 0,15 mol Cu(NO 3)2 bng in cc tr, mng
ngn xp vi cng dng in khng i I = 5A trong thi gian 6562 giy th dng in phn, thy
khi lng dung dch gim 15,11gam. Dung dch sau in phn ha tan ti a m gam bt Fe, phn ng
to ra kh NO (sn phm kh duy nht ca N +5). Gi tr m l.
Cu 25: t chy hon ton 2,04 gam este X n chc thu c 5,28 gam CO 2 v 1,08 gam H2O.
Cng thc phn t ca X l.
Cu 26: t chy hon ton 0,1 mol hn hp X cha trimetylamin v hexametyleniamin cn dng
0,715 mol O2, sn phm chy gm CO2, H2O v N2. Mt khc cho 24,54 gam X trn tc dng vi dung
dch HCl long d, thu c m gam mui. Gi tr ca m l.
Cu 27: Trong iu kin thch hp, xy ra cc phn ng sau:
(a) 2Fe + 6H2SO4 Fe2(SO4)3 + 3SO2 + 6H2O
(b) 2FeO + 4H2SO4 Fe2(SO4)3 + SO2 + 4H2O
(c) Fe(OH)2 + H2SO4 FeSO4 + 2H2O
(d) 2Fe3O4 + 10H2SO4 3Fe2(SO4)3 + SO2 + 10H2O
Trong cc phn ng trn, phn ng xy ra vi dung dch H 2SO4 long l.
A. (d) B. (c) C. (a) D. (b)
- Th nghim 1: Cho thanh Fe vo dung dch H 2SO4 long.
- Th nghim 2: Nhng thanh Fe vo dung dch H 2SO4 long c thm vi git dung dch CuSO 4.
- Th nghim 3: Nhng thanh Cu vo dung dch FeCl 3.
- Th nghim 4: Nhng thanh Fe vo dung dch FeCl 3.
S trng hp n mn in ha l:
A. 2. B. 1. C. 4. D. 3.
Cu 29: un si hn hp X gm 12 gam axit axetic v 11,5 gam ancol etylic vi xc tc H 2SO4 c.
Kt thc phn ng thu c 11,44 gam este. Hiu sut phn ng este ha l:
A. 50%. B. 66,67%. C. 65,00%. D. 52,00%.
Cu 30: Phn ng trng bc c s dng trong cng nghip sn sut gng, rut phch. Ha cht
c dng thc hin phn ng ny l:
A. Saccaroz. B. Andehit axetic. C. Glucoz. D. Andehit fomic.
Cu 32: Hn hp M gm LysGlyAla, LysAlaLysLysLysGly v AlaGly trong oxi chim
21,3018% v khi lng. Cho 0,16 mol M tc dng va vi dung dch HCl thu c m gam mui.
Gi tr ca m l:
A. 86,16 B. 90,48 C. .83,28 D. 93,26
Cu 33: Hn hp E gm X, Y v Z l 3 peptit u mch h (M X > MY > MZ). t chy 0,16 mol X
hoc Y hoc Z u thu c s mol CO 2 ln hn s mol H2O l 0,16 mol. Nu un nng 69,8 gam

hn hp cha X, Y v 0,16 mol Z vi dung dch NaOH va thu c dung dch cha 101,04 gam
hai mui ca alanin v valin. Bit n X < nY. Phn trm khi lng ca X trong E gn nht vi :
A. 12 B. 95 C. 54 D. 10
Cu 34: Cho 0,01 mol mt este tc dng va vi 100ml dung dch NaOH 0,2M, un nng. Sn phm
to thnh gm mt ancol v mt mui c s mol bng nhau v bng s mol este. Mt khc, x phng ha
hon ton 1,29 gam este bng mt lng va 60ml dung dch KOH 0,25M, c cn dung dch sau
phn ng thu c 1,665 gam mui khan. Cng thc ca este l:
A. C2H4(COO)2C4H8 B. C4H8(COO)2C2H4 C. CH2(COO)2C4H8 D. C4H8(COO)C3H6
Cu 35: Ngm thanh Cu (d) vo dung dch AgNO 3 thu c dung dch X. Sau ngm thanh Fe
(d) vo dung dch X thu c dung dch Y. Bit cc phn ng xy ra hon ton. Dung dch Y c
cha cht tan l:
A. Fe(NO3)3. B. Fe(NO3)2.
C. Fe(NO3)2, Cu(NO3)2. D. Fe(NO3)3, Fe(NO3)2.
Cu 36: kh mi tanh ca c (gy ra do mt s amin) nn ra c vi ?
A. nc mui. B. nc. C. gim n. D. cn.
Cu 37: Dung dch Fe2(SO4)3 khng phn ng vi cht no sau y ?
A. NaOH. B. Ag. C. BaCl2. D. Fe.
Cu 38: Cho 6,675 gam mt amino axit X (phn t c 1 nhm NH2 v 1 nhm COOH) tc dng
va ht vi dung dch NaOH thu c 8,633 gam mui. Phn t khi ca X bng ?
A. 117. B. 89. C. 97. D. 75.
----------HT----------

PHN TCH HNG DN GII
THI TH THPT CHU VN AN QUNG TR LN 1
Cu 1: Chn C.
- Th t phn ng xy ra nh sau:
Ba + 2H2O
Ba(OH)2 + H2 (1)
Ba(OH)2 + Al2(SO4)3
Al(OH)3 trng keo + BaSO4 trng (2)
2Al(OH)3 + Ba(OH)2
Ba(AlO2)2 + 4H2O (3)
3BaSO4 2BaAlO2 4H 2
- Hay c th vit gn li: 5Bad 4H 2O Al 2 (SO4 )3
Vy sn phm thu c c mt cht kh (H2) v mt cht kt ta (BaSO 4).
Cu 2: Chn C.
CaCl2 HCl Ca(OH)2
A. NaNO3 Khng phn ng Khng phn ng Khng phn ng
B. NaOH Khng phn ng Khng hin tng Khng phn ng
C. NaHCO3 Khng phn ng Thot kh khng mu Kt ta trng
D. NaCl Khng phn ng Khng phn ng Khng phn ng
Cu 3: Chn A.
0
Cu 4: Chn C
- ng phn l nhng cht c cng cng thc phn t nhng khc nhau v cng thc cu to.
A. Sai, Amiloz v amilopectin u l thnh phn ca tinh bt c cng thc l (C 6H10O5)n nhng phn
t khi ca amylopectin ln hn nhiu so vi amiloz.
B. Sai, Anilin (C6H5NH2) v alanin (CH3CH(NH2)COOH) c cng thc phn t khc nhau.
C. ng, Vinyl axetat (CH3COOCH=CH2) v metyl acrylat (CH2=CHCOOCH3) c cng cng thc
phn t.
D. Sai, Etyl aminoaxetat (CH3COOC2H5) v -aminopropionic (CH3CH(NH2)COOH) c cng thc
phn t khc nhau.
Cu 5: Chn D
- C 6 ng phn ca X l: GGA ; GAG ; AGG ; AGA ; AAG ; GAA.
Cu 6: Chn D
Nguyn tc lm mm nc cng l lm gim nng ca Ca2+ v Mg2+ trong nc cng. V vy
Na2CO3 c dng lm mm nc cng tm thi, vnh cu v ton phn:
Mg 2 CO32
MgCO3 v Ca 2 CO32 CaCO3
ng dng ca Na2CO3:
- Nguyn liu trong cng nghip sn xut thy tinh, x phng , giy dt v iu ch mui khc.
- Ty sch vt m bm trn chi tit my trc khi sn , trng kim loi.
- Cng nghip sn xut cht ty ra.
Cu 7: Chn D
- V sau phn ng cn kim loi d nn Fe ch b oxi ha ln Fe2+.
BT: e
2n Fe n FeCl3 n HCl 2.(x t) y z 2x y z 2t

Cu 8: Chn B.
Cu 9: Chn D.
nCO2 nCaCO3
2 2
Cu 10: Chn C.
- Khi cho 21,5 gam X tc dng vi 0,43 mol H 2SO4 th :

m X 98n H 2SO 4 30n NO 2n H 2 m Z
BTKL
n H 2O 0, 26 mol
18
2n 2n H 2O 2n H 2 n n NO

BT:H
n NH 4 H 2SO4 0, 02 mol n Cu(NO3 ) 2 NH 4 0, 04 mol
4 2
2n H 2SO4 10n NH 4 4n NO 2n H 2
- Ta c n O(trong X) n FeO 0, 08mol
2
3n Al 2n Zn 3n NO 2n H 2 8n NH 4 0, 6
n Al 0,16 mol
- Xt hn hp X ta c:
27n Al 65n Zn m X 72n FeO 188n Cu(NO3 ) 2 8, 22 n Zn 0, 06 mol

27.0,16
%m Al .100 20, 09
21,5
Cu 11: Chn B.
Cu 12: Chn A.
(a) Cu(d) + 2Fe(NO3)3
(b) CO2 (d) + NaOH
NaHCO3
Cu 13: Chn D.
n BT: C
2
HCO3 OH Ba2
BaCO3 H 2O
mBaCO3 0,3.197 59,1(g)

Cu 14: Chn A.
Cu 15: Chn D.
A. Sai, Phn ng gia ancol vi axit cacboxylic c gi l phn ng este ha.
B. Sai, Phn ng x phng ha l phn ng mt chiu.
C. ng.
D. Sai, Phn ng este ha l phn ng thun nghch.
Cu 16: Chn C
- Cc phn ng xy ra:
A. 2NaHSO4 (X) + Ba(HCO3)2 (Y) BaSO4 (Z) + Na2SO4 + 2CO2 + 2H2O
BaSO4 (Z) + H2SO4 : khng xy ra phn ng
B. Ba(HCO3)2 (X) + Ba(OH)2 (Y)
2BaCO3 (Z) + 2H2O
BaCO3 (Z) + H2SO4 BaSO4 + CO2 + H2O
Lu : Y l dung dch mui do p n B khng tha mn.
C. Na2CO3 (X) + BaCl2 (Y)
BaCO3 (Z) + 2NaCl
BaCO3 (Z) + H2SO4
BaSO4 + CO2 + H2O

D. FeCl2 (X) + AgNO3 (Y) Fe(NO3)3 + AgCl + Ag
AgCl v Ag khng tc dng vi H 2SO4
Cu 17: Chn A
- Ti v tr kt ta max ta c: n BaCO3 n Ba(OH) 2 a 0,12 mol
- Ti v tr kt ta min ta c n OH n CO 2 0, 4 mol n NaOH n OH 2n Ba(OH) 2 0, 4 2.0,12 0,16 mol
- p dng bo ton e ton qu trnh ta c: m X 153n BaO 62n Na 2O 16n H 2 21, 4 (g)
Cu 18: Chn D
(1) Sai, hir ha glucz thu c sorbitol cn fructz th thu c ng phn ca sorbitol.
(2) ng, cc cacbohidrat tham gia phn ng thy phn l mantoz, saccarz,tinh bt v
xenlulz.
(3) ng, khi thy phn n cng xenlulz thu c glucz.
(4) Sai, trong phn t saccaroz gc -glucoz v gc -fructoz lin kt vi nhau bng C 1 O
C2.
(5) ng, tinh bt l cht rn v nh hnh, mu trng, iu kin thng khng tan trong nc.
(6) Sai, cc polime c mch phn nhnh thng gp l amylopectin v gliczen.
Vy c 3 pht biu ng l (2), (3) v (5).
Cu 19: Chn B.
Cu 20: Chn A
20(g) rn
Ag,Cu
Mg,Al AgNO3,Cu(NO3) 2
t0
Mg2 ,Al 3 ,Cu2 (d ) ,NO3 Mg(OH) 2 ,Cu(OH) 2 MgO,CuO
NaOH
3,72(g) dung dch hn h p
dung dch X hn h p kt ta 7,6(g)oxit
- Gi c l s mol Cu , cn li trong dung dch X. Xt qu trnh phn ng ca dung dch X vi lng

2+
d dung dch NaOH ta c:

24nMg 27nAl m kim lo i 24a 27b 3,72 a 0,11

+ 2nMg2 4nAl 3 2nCu2 nNaOH 2a 4b 2c 0,46 b 0,04
40a 80c 7,6 c 0,04
40nMgO 80nCuO moxit
- Xt dung dch hn hp cha AgNO 3 v Cu(NO3)2 ta c:
nAgNO3 2nCu(NO3 )2 nNO3
x 2y 3nAl 3 2nMg2 2nCu2 0,42 x 0,12
x 4
+
108nAg 64nCu mrn
108x 64(y 0,04) 20
y 0,15 y 5
Cu 21: Chn A
nBr
- Gi s triglixerit X c c to thnh t 2 axit oleic v 1 axit stearic th: nE 2 0,06mol
2
- Xt hn hp mui c: 304nC17H33COONa 306nC17H35COONa mmui 304.0,06.2 306.0,06 54,84(g)
- Ta nhn thy biu thc trn hon ton chnh xc nn gi s ban u l ng.
- Vy X l (C17H33COO)2C3H5(OOCC17H35), suy ra M X 886
Cu 22: Chn C
- Quy i hn hp rn thnh Fe v O. Khi cho rn tc dng vi 0,74 mol HNO 3 th:
56nFe 16nO mhn h p
56nFe 16nO 12,48
nFe 0,18mol
BT:e BT:e

3nFe 2nO 3nNO 3nFe 2nO 0,24 nO 0,15mol
- p dng bo ton e ton qu trnh. Khi cho dung dch tc dng vi lng d Cu th :

nHNO3 2nO 3 nNO 2nO 2nFe
nNO 4
0,11mol nCu(bhon tan)
2
0,135mol mCu 8,64(g)
Cu 23: Chn B
- X l este thun chc c hai nhm cha vy X c dng CxHyO4
- Khi t este X th s mol CO2 bng s mol O2 phn ng th este X c dng Cx(H2O)m
- X l este hai chc v phn ng vi H 2 theo t l 1 : 2 nn X c k = 4.
- Xt hn hp ancol ta c:
+ X1 tch nc 1700C khng thu c anken nn X 1 l CH3OH.
+ X1 v X2 l ng ng ca nhau nn X1 v X2 ln lt l CH3OH v C2H5OH.
T tt cc d kin trn ta c este X l: CH3OOC C C C COOC2H5
- Phng trnh phn ng:
0
CH3OOC C C COOC2 H5 (X) 2NaOH
t
NaOOC C C COONa CH3OH(X1 ) C2 H5OH(X 2 )
0
CH3OOC C C COOC2 H5 (X) 2H 2 Ni, t
CH3OOC CH 2 CH 2 COOC2 H5 (Y)
Cu 24: Chn B
It
- Ta c ne (trao i) 0,34mol
96500
- Cc qu trnh in phn din ra nh sau :
Ti catot Ti anot
Cu2+ + 2e Cu 2Cl- Cl2 + 2e
0,15 mol 0,3 mol 0,15 mol 2x mol 2x mol 2x mol
2H2O + 2e 2OH - + H2 H2O 4H +
+ O2 + 4e
0,04 mol 0,04 mol 0,02 4y mol y mol 4y mol
mol
- Xt khi lng gim sau in phn ta c:

BT:e
2nCl 2 4nO2 ne trao i 2x 4y 0,34 x 0,1mol

71nCl 2 32nO2 mdd gim 64nCu 2nH2
71x 32y 5,47 y 0,06mol
- Dung dch sau in phn cha: Na +, H+ : 0,2 mol v NO3-: 0,3 mol.
- Khi cho dung dch sau in phn tc dng vi Fe d th:
3Fe 8H 2NO3
3Fe2 2NO 4H 2O
0,075mol 0,2mol
mFe bha tan 0,075.56 4,2(g)

Cu 25: Chn A
BTKL m m H 2O m X BT: O 2n n H 2O 2n O 2
n O 2 CO 2 0,135 mol n X CO 2 0, 015 mol
32 2
n
C X CO 2 8 : X l C8H8O 2
nX
Cu 26: Chn D
(CH3 )3 N (A) 5, 25O 2 n A n B 0,1 n A 0, 06
- t chy X
H 2 N(CH 2 ) 6 NH 2 (B) 10O 2 5, 25n A 10n B 0, 715 n B 0, 04
- Trong 0,1 mol X th c 8,18 gam trong 24,54 gam X th c 0,18 mol A v 0,12 mol B.
BTKL
n HCl 0,18 2.0,12 0, 42 mol m 24,54 0, 42.36,5 39,87 (g)
Cu 27: Chn B
Phng trnh phn ng ng l:
(a) Fe + H2SO4 FeSO4 + H2 (b) FeO + H2SO4 FeSO4 + H2O
(c) Fe(OH)2 + H2SO4 FeSO4 + 2H2O (d) Fe3O4 + 4H2SO4 Fe2(SO4)3 + FeSO4 + 4H2O
Cu 28: Chn B.
- iu kin xy ra n mn in ha l: (3 iu kin bt buc)
Cu 29: Chn C.
H SO
c

- Phng trnh phn ng: CH 3COOH C2H 5OH
2 4
CH 3COOC2H 5 H 2O

o
0,2mol 0,25mol t 0,13mol
n CH3COOC2H5
H .100% 65%
n CH3COOH
Cu 30: Chn C
- Trong cng nghip: glucoz dng trng gng, trng rut phch (thay cho anehit v anehit c).
Cu 31: Chn D.
98nH2SO4 .100
C%
BTKL
Cu 32: Chn B.
- Nhn thy rng hn hp M c dng GlyAla(Lys)x (CTPT ca M l C56x H1012x O3x N22x )
16(3 x)
- Theo ta c: %mO 0,213018 x 1,5
12(5 6x) 16(3 x) 10 12x 14(2 2x)
0
t
- Khi cho M tc dng HCl th: GlyAla(Lys)1,5 5HCl 2,5H 2O GlyHCl AlaHCl Lys(HCl)2
BTKL
mmui mM 36,5nHCl 18nH2O 90,48(g)
Cu 33: Chn A.
nCO2 nH 2O 0,16
- Khi t 0,16 mol X th : nX 0,16 k X 4
0,5k X 1 0,5k X 1
- Tng t khi t ln lt 0,16 mol Y v Z th ta c kY = kZ = 4.
- Gi x l s mol ca hn hp E. Khi un nng 69,8 gam E vi NaOH va th :
BTKL
mmui mE 18nH 2O 40nNaOH 101,04 69,8 40.4t 18t t 0,22mol
+ Xt hn hp mui ta c:
111nAlaNa 139nValNa mmui 111nAlaNa 139nValNa 101,04 nAlaNa 0,76

nAlaNa nValNa 4nE nAlaNa nValNa 0,88 nValNa 0,12
- Ta nhn thy rng nZ > nValNa, nn peptit Z trong E l (Ala)4 (0,16 mol)
- Theo ta c X l (Val)a(Ala)4 a v Y l (Val)b(Ala)4 b.

BT:Val
nX a nY b 0,12
nX a nY b 0,12
BT:Ala nX nY nX 0,02 v nY = 0,04
nX (4 a) nY (4 b) 0,12 4nX 4nY nX a nY b 0,12
a,b 4

n n 0,22 0,16 0,06 n n 0,06 a= 4 v b=1
X Y X Y
0,02.414
- Vy X v Y ln lt l (Val)4 (0,02 mol) v Val(Ala)3 (0,04 mol) %mX .100% 11,86%
69,8
Cu 34: Chn B.

nNaOH
- Khi cho 0,01 mol este tc dng vi 0,02 mol NaOH th: 2 . Mt khc s mol mui ancol thu
neste
c bng s mol este. Vy este c dng l R(COO)2 R'
t0
R(COO)2 R' 2KOH R(COOK) 2 R'(OH) 2
0,015mol 0,0075mol 0,0075mol
BTKL 0,465
mR'(OH)2 meste 56nKOH mmui khan 0,465(g) M R'(OH)2 62(C2H 4 (OH)2 )
0,0075
1,665
M mui 222 : C4H8(COOK)2 Este l: C4H8(COO)2 C2H 4
0,0075
Cu 35: Chn B.
- Cc phn ng xy ra:
Cu(d) + AgNO3 Cu(NO3)2 + Ag Cu(NO3)2 + Fe(d) Fe(NO3)2 + Cu
Vy dung dch Y cha Fe(NO3)2.
Cu 36: Chn C.
- Trong mi tanh ca c l hn hp cc amin (nhiu nht l trimetylamin) v mt s cht khc, chnh v
vy ngi ta dng gim n (thnh phn c cha CH3COOH) kh mi tanh ca c trc khi nu.
Cu 37: Chn B.
A. Fe2(SO4)3 + 6NaOH 2Fe(OH)3 nu + 3Na2SO4
B. Fe2(SO4)3 + Ag: khng xy ra (v khng tun theo quy tc ).
C. Fe2(SO4)3 + 3BaCl2
3BaSO4 trng + 2FeCl3
D. Fe2(SO4)3 + Fe 3FeSO4
Cu 38: Chn D.
TGKL 8,633 6,675 6, 675
n X 0,089 mol M X 75
40 18 0,089
Cu 39: Chn A.
Cu 40: Chn A.

TNH HI PHNG Mn: KHOA HC T NHIN HA HC
THPT TIN LNG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Ngm mt inh st trong dung dch HCl, phn ng xy ra chm. phn ng xy ra nhan hn,
ngi ta thm tip vo dung dch axit mt vi git dung dch no sau y
A. NaCl. B. FeCl3. C. H2SO4. D. Cu(NO3)2.
Cu 2: nhit cao, kh CO kh c cc oxit no sau y
A. Fe2O3 v CuO B. Al2O3 v CuO C. MgO v Fe2O3 D. CaO v MgO.
Cu 3: t chy 4,56 gam hn hp E cha metylamin, imetylamin, trimetylamin cn dng 0,36 mol O2.
Mt khc ly 4,56 gam E tc dng vi dung dch HCl long, d thu c lng mui l
Cu 4: Ha tan hon ton hn hp Mg, Al, Fe v Cu trong dung dch HNO3 (long d) thu c dung
dch X. Cho dung dch NaOH d vo dung dch X c kt ta Y. Nung kt ta Y n khi phn ng
nhit phn kt thc thu c ti a bao nhiu oxit
A. 3 B. 2 C. 1 D. 4
Cu 5: Ha tan hon ton 7,5 gam hn hp gm Mg v Al bng lng va V lt dung dch HNO3 1M.
Sau khi cc phn ng kt thc, thu c 0,672 lt N2 ( ktc) duy nht v dung dch cha 54,9 gam mui.
Gi tr ca V l
A. 0,72. B. 0,65. C. 0,70. D. 0,86.
Cu 6: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch
KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to
ca X l
A. CH3-CH2-COO-CH=CH2. B. CH2=CH-COO-CH2-CH3.
C. CH2=CH-CH2- COO -CH3. D. CH3-COO-CH=CH-CH3.
(a) Cc cht CH3NH2, C2H5OH, NaHCO3 u c kh nng phn ng vi HCOOH.
(b) Thnh phn chnh ca tinh bt l amilopectin.
(c) Cc peptit u tc dng vi Cu(OH)2 cho hp cht c mu tm c trng
(d) Anilin (C6H5NH2) tan t trong nc.
Trong cc pht biu trn, s pht biu ng l
A. 3. B. 2. C. 1. D. 4.
Cu 8: Dung dch X gm 0,01 mol Cu(NO3)2 v 0,1 mol NaHSO4. Khi lng Fe ti a phn ng c
vi dung dch X l (bit NO l sn phm kh duy nht ca NO3-)
Cu 9: un nng dung dch cha 0,2 mol hn hp gm glyxin v axit glutamic cn dng 320 ml dung
dch NaOH 1M, c cn dung dch sau phn ng, thu c lng mui khan l
Cu 10: Cho bit th t t tri sang phi ca cc cp oxi ha kh trong dy in ha (dy th in cc
chun) nh sau: Zn2+/Zn; Fe2+/Fe; Cu2+/ Cu; Fe3+/Fe2+; Ag+/Ag. Cc kim loi v ion u phn ng c
vi ion Fe2+trong dung dch l
A. Ag, Fe3+. B. Zn, Ag+. C. Ag, Cu2+. D. Zn, Cu2+.
Cu 11: X, Y, Z, T l mt trong cc dung dch sau: (NH4)2SO4, K2SO4, NH4NO3, KOH. Thc hin th
nghim nhn xt chng v c c kt qu nh sau:

Cht X Z T Y
dd Ba(OH)2, t0 C kt ta xut Khng hin Kt ta v kh thot ra C kh thot ra
hin tng
Cc dung dch X, Y, Z, T ln lt l
A. K2SO4, (NH4)2SO4, KOH, NH4NO3 B. (NH4)2SO4, KOH, NH4NO3, K2SO4
C. KOH, NH4NO3, K2SO4, (NH4)2SO4 D. K2SO4, NH4NO3, KOH, (NH4)2SO4
Cu 12: Trung ho 9,0 gam mt amin n chc Y cn 200 ml dung dch HCl 1M. CTPT ca Y l
A. C4H11N B. CH5N C. C3H9N D. C2H7N
Cu 13: Pht biu no sau y l sai
A. Metyl amin l cht kh, lm xanh qu tm m.
B. Cc ipeptit ha tan c Cu(OH)2 nhit thng.
C. Cc amino axit c nhit nng chy cao.
D. Cc cht bo c gc axit bo khng no thng l cht lng.
Cu 14: Kim loi c tnh kh mnh nht l
A. Fe B. Sn C. Ag D. Au
Cu 15: Trong cc kim loi Na, Fe, Cu, Ag, Al. C bao nhiu kim loi ch iu ch c bng phng
php in phn
A. 1. B. 2. C. 4. D. 3.
Cu 16: Khi cho HNO3 c vo ng nghim cha anbumin thy c kt ta mu
A. xanh thm B. tm C. en D. vng
Cu 17: Hai dung dch u phn ng c vi kim loi Fe l:
A. AgNO3 v H2SO4 long B. ZnCl2 v FeCl3
C. HCl v AlCl3 D. CuSO4 v HNO3 c ngui
Cu 18: Este X c cng thc phn t C2H4O2. un nng 9,0 gam X trong dung dch NaOH va n
khi phn ng xy ra hon ton thu c m gam mui. Gi tr ca m l
A. 8,2. B. 10,2 C. 12,3. D. 15,0
Cu 19: Cho hn hp Cu v Fe ha tan vo dung dch H2SO4 c nng ti khi phn ng hon ton, thu
c dung dch X v mt phn Cu khng tan. Cho dung dch NH3 d vo dung dch X thu c kt ta
Y. Thnh phn ca kt ta Y gm
A. Fe(OH)2. B. Fe(OH)2, Cu(OH)2. C. Fe(OH)3, Cu(OH)2. D. Fe(OH)3.
Cu 20: Este X c CTPT CH3COOC6H5. Pht biu no sau y v X l ng
A. Tn gi ca X l benzyl axetat.
B. X c phn ng trng gng.
C. Khi cho X tc dng vi NaOH (va ) th thu c 2 mui.
D. X c iu ch bng phn ng ca axit axetic vi phenol.
Cu 21: Cho 6,88 gam hn hp cha Mg v Cu vi t l mol tng ng l 1 : 5 vo dung dch cha 0,12
mol Fe(NO3)3. Sau khi cc phn ng hon ton thu c m gam kim loi. Gi tr ca m l:
A. 5,12 B. 3,84 C. 2,56 D. 6,96
Cu 22: Cho cc s chuyn ha sau:
H2 ,t KMnO4 T
H 2O
Z Y P Q o E
o
X 1500
Y T ;
0
C O2
HgSO4 , H2SO 4 Pd/PbCO3 H 2SO 4 , t
Bit phn t E ch cha mt loi nhm chc. Phn t khi ca E l

A. 132. B. 118. C. 104. D. 146.
Cu 23: in phn dung dch X gm FeCl2 v NaCl (t l mol tng ng l 1 : 2) vi in cc tr mng
ngn xp thu c dung dch Y cha hai cht tan, bit khi lng dung dch X ln hn khi lng dch
Y l 4,54 gam. Dung dch Y ha tan ti a 0,54 gam Al. Mt khc dung dch X tc dng vi lng d
dung dch AgNO3 thu c m gam kt ta. Gi tr m l
A. 14,35. B. 17,59. C. 17,22. D. 20,46.

Cu 24: Ha tan ht m gam hn hp X gm Mg, MgO, Mg(HCO3)2, MgSO3 bng mt lng va
dung dch H2SO4 30%, thu c 11,2 lt (ktc) hn hp kh Y v dung dch Z c nng 36%. T khi
ca Y so vi He bng 8. C cn Z c 72 gam mui khan. Gi tr ca m l
A. 20. B. 10. C. 15. D. 25.
Cu 25: Pht biu no sau y l sai
A. Theo chiu tng dn in tch ht nhn, cc kim loi kim c nhit nng chy gim dn.
B. cng mt chu k, bn knh kim loi kim ln hn bn kinh kim loi kim th.
C. KAl(SO4)2.12H2O, NaAl(SO4)2.12H2O v (NH4)Al(SO4)2.12H2O c gi l phn nhm.
D. Cc kim loi kim, kim th u tc dng vi nc ngay iu kin thng.
Cu 26: Khi b m, mt sc hoc sau cc ca phu thut, nhiu ngi bnh thng c truyn dch
m c th sm hi phc. Cht trong dch truyn c tc dng trn l
A. glucoz. B. saccaroz. C. amino axit. D. amin.
Cu 27: Pht biu no sau y l ng:
A. Tt c cc polime tng hp u c iu ch bng phn ng trng ngng.
B. Tt c cc polime u khng tc dng vi axit hay baz.
C. Protein l mt loi polime thin nhin.
D. Cao su buna-S c cha lu hunh trong phn t.
Cu 28: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX < MY < 70). C X v Y u c
kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KOH sinh ra mui. T khi
hi ca Y so vi X c gi tr l:
A. 1,403. B. 1,333. C. 1,304. D. 1,3.
Cu 29: Cp cht khng xy ra phn ng l
A. dung dch NaNO3 v dung dch MgCl2. B. dung dch NaOH v Al2O3.
C. K2O v H2O. D. Na v dung dch KCl.
Cu 30: Cc amino axit u c
A. kh nng lm i mu qu tm B. ng mt nhm amino
C. t nht 2 nhm COOH D. t nht hai nhm chc
Cu 31: Cho dy cc cht: triolein; saccaroz; nilon-6,6; t lapsan; xenluloz v glyxylglyxin. S cht
trong dy cho c phn ng thy phn trong mi trng kim l
A. 6 B. 4 C. 5 D. 3
Cu 32: Thc hin cc th nghim sau
(1) Cho bt Al vo dung dch NaOH (d).
(2) in phn dung dch NaCl bng in cc tr, khng mng ngn xp.
(3) Cho dung dch KI vo dung dch cha Na2Cr2O7 v H2SO4.
(4) Dn lung kh NH3 qua ng s cha CrO3.
(5) Cho bt Fe vo lng d dung dch FeCl3.
S th nghim thu c n cht l.
A. 2 B. 4 C. 5 D. 3
Cu 33: Hn hp X cha cc este u mch h gm hai este n chc v mt este a chc, khng no
cha mt lin kt i C=C. t chy hon ton 0,24 mol X cn dng 1,04 mol O2, thu c 0,93 mol
CO2 v 0,8 mol H2O. Nu thy phn X trong NaOH, thu c hn hp Y cha 2 ancol c cng s
nguyn t cacbon v hn hp Z cha 2 mui. Phn trm khi lng ca este n chc c khi lng
phn t ln trong X l
A. 22,7% B. 15,5% C. 25,7% D. 13,6%
Cu 34: Thc hin s phn ng (ng vi t l mol cc cht) sau:
0
t
(1) X NaOH X1 X 2 2H 2O (2) X1 H2SO4
Na 2SO4 X3
0 0
t t
(3) nX 2 nX 4 Nilon 6,6 2nH 2O (4) nX3 nX5 T lapsan + 2nH2O
Nhn nh no sau y l sai?
A. X c cng thc phn t l C14H22O4N2. B. X2 c tn thay th l hexan-1,6-iamin

C. X3 v X4 c cng s nguyn t cacbon. D. X2, X4 v X5 c mch cacbon khng phn
nhnh.
Cu 35: Ha tan ht m gam kim loi M cn dng 136 gam dung dch HNO 3 31,5%. Sau khi kt thc
phn ng thu c dung dch X v 0,12 mol kh NO duy nht. C cn dung dch X thu c
(2,5m + 8,49) gam mui khan. Kim loi M l:
A. Mg B. Cu C. Ca D. Zn
Cu 36: t chy hon ton mt este no 2 chc mch h X. Sc ton b sn phm chy vo dung dch
Ca(OH)2 d, sau phn ng thu c 5,0 gam kt ta v khi lng dung dch gim 2,08 gam. Bit khi
x phng ha X ch thu c mui ca axit cacboxylic v ancol. S ng phn ca X l:
A. 3 B. 4 C. 6 D. 5
Cu 37: Hn hp A gm mt peptit X v mt peptit Y (mi cht c cu to t 1 loi aminoaxit, tng
s nhm CO-NH- trong 2 loi phn t l 5) vi t l s mol n X : nY = 2 : 1. Khi thy phn hon ton m
gam hn hp A thu c 5,625 gam glyxin v 10,86 gam tyrosin. Ga tr ca m l:
Cu 38: Cho 1,752 gam amin n chc X tc dng vi dung dch HCl long d, thu c 2,628 gam
mui. S ng phn cu to ca X l
A. 4 B. 6 C. 8 D. 2
Cu 39: Cht no sau y khng phn ng vi dung dch HCl
A. H2N-CH2-COOH B. CH3COOH C. C2H5NH2 D. C6H5NH2
Cu 40: Ngi ta thng dng cc vt dng bng bc co gi cho ngi b trng gi (khi ngi b
mt mi, chng mtdo trong c th tch t cc kh c nh H2S). Khi vt bng bc b en do phn
ng:
4Ag + O2 + 2H2S 2Ag2S + 2H2O.
Cht kh trong phn ng trn l
A. O2. B. H2S. C. Ag. D. H2S v Ag.

PHN TCH HNG DN GII
THI TH THPT TIN LNG HI PHNG LN 1
Cu 1: Chn D.
- Khi ngm mt inh st vo dung dch HCl th: Fe + 2HCl FeCl2 + H2
+ Kh H2 sinh ra mt phn bm li trn inh st lm gim kh nng tip xc vi ion H+ nn phn ng xy
ra chm v kh H2 sinh ra s t.
- Khi nh thm dung dch Cu(NO3)2 vo th: Fe + Cu(NO3)2 Fe(NO3)2 + Cu
+ Trong dung dch lc ny hnh thnh mt pin in in cc Fe Cu c s chuyn dch cc electron v
ion H+ trong dung dch s nhn electron v vy lm cho phn ng xy ra nhanh v kh H 2 thot ra nhiu
hn.
Cu 2: Chn A.
Cc cht tha mn l: Fe 2O3v CuO .
Cu 3: Chn B.
- Quy i hn hp E: CH3NH2 ,(CH3 )2 NH,(CH3 )3 N thnh CnH2n+3N: a mol.
- t chy E: CnH2n+3N + (1,5n + 0,75)O2 nCO2 + (n + 1,5)H2O + 0,5N2
n O2 (1,5n 0,75)a 0,36 (1) v mE (14n 17)a 4,56 (2). T (1), (2) ta tnh c: a = 0,12 mol
BTKL
- Cho E tc dng vi HCl th n HCl n E 0,12 mol mmui = mE + 36,5nHCl = 8,94 (g)
Cu 4: Chn D.
Mg, Cu HNO3 Mg(NO3 ) 2 , Cu(NO3 ) 2 NaOH Mg(OH) 2 , Cu(OH) 2 t o MgO, CuO
H 2O
Fe, Al Fe(NO3 )3 , Al(NO3 )3 Fe(OH)3 Fe 2O3
- Lu :
+ Cho mt lng d NaOH vo Al3+, ban u c kt ta trng keo khng tan sau tan dn v to dung
dch trong sut.
+ H2O cng l mt oxit v theo nh ngha oxit l hp cht ca 2 nguyn t trong c 1 nguyn t l
oxi.
Vy c ti a l 4 oxit .
Cu 5: Chn D.
- Hng t duy 1: Bo ton nguyn t N
- Qu trnh: Mg,Al HNO3 Mg(NO3)2,Al(NO3)3,NH 4NO3 N 2 H 2O
7,5(g) V (l) 54,9 (g) hn h p mui 0,03 mol
24n Mg 27n Al 7,5 n Mg 0, 2

+ Ta c: 148n Mg(NO3 ) 2 213n Al(NO3 )3 80n NH 4 NO3 54,9 n Al 0,1
BT: e
2n Mg 3n Al 8n NH 4 NO3 10n N 2 n NH 4 NO3 0, 05
BT: N
VHNO3 2n Mg(NO3 )2 3n Al(NO3 )3 2n NH4 NO3 2n N2 0,86 (l)
- Hng t duy 2: Tnh theo s mol HNO3
m Al3 m Mg 2 18n NH 4 62n NO3 54,9

+Ta c: BT e BTDT n NH 4 0, 05 mol
n NO3 n NH 4 (8n NH 4 10n N 2 )
n HNO3 12n N 2 10n NH 4 0,86 mol

Cu 6: Chn A.
- T t khi ta suy ra MX 100 : C5H8 O2 v nX = 0,2 mol ; nKOH = 0,3 mol. t CTTQ ca X l:
RCOOR
- Hng t duy 1: Tm gc R
m rn 56nKOH d
+ Ta c: nKOH p = nRCOOK = nX = 0,2 mol nKOH d = 0,1 mol m M RCOOK 112
0,2
R l C2H5. Vy cng thc cu to ca X l C2H 5COOCH CH 2
m mKOH mrn
M R'OH X
BTKL
44 : CH 3CHO R l C2H3. Vy X l C2H 5COOCH CH 2
0,2
Cu 7: Chn A.
(a) ng, Phng trnh phn ng:
CH3NH2 + HCOOH
HCOONH3CH3
H SO

2
C2H5OH + HCOOH
4
HCOOC2H5 + H2O
o
t
NaHCO3 + HCOOH HCOONa + CO2 + H2O

(b) ng, Amilopectin chim t 70 80% khi lng tinh bt trong khi amiloz chim t 20 30% khi
lng tinh bt.
(c) Sai, Cc tripeptit tr ln (ipeptit khng c phn ng ny) u tc dng vi Cu(OH)2 cho hp cht c
mu tm c trng.
(d) ng, Anilin (C6H5NH2) l cht lng, si 184oC, khng mu, rt c, tan t trong nc nhng tan
nhiu trong benzen v etanol.
Vy c 3 pht biu ng l (a), (b), (d).
Cu 8: Chn C.
S oxi ha S kh
Fe Fe + 2e
2+
4H + NO3 + 3e
+ -
NO + 2H2O
(v lng Fe phn ng ti a nn Fe chuyn 0,08 0,02 0,06 0,01
ln Fe2+). Cu2+ + 2e Cu
0,01 0,02
2H+(d) + 2e H2
0,02 0,02 0,01
3n NO 2n Cu 2 2n H2

BT:e
n Fe 0,05 mol mFe 2,8 (g)
2
Cu 9: Chn B.
- Hng t duy 1: Xc nh cc cht c trong mui
0,32 mol
H 2 NCH 2COOH : x mol H 2 NCH 2COONa : x mol
NaOH
H 2O
HOOC(CH 2 ) 2 CH(NH 2 ) COOH : y mol NaOOC(CH 2 ) 2 CH(NH 2 ) COONa : y mol
x y 0, 2 x 0, 08
+ Ta c: mmui = 97x + 191y = 30, 68 (g)
x 2y 0,32 y 0,12
- Hng t duy 2: Bo ton khi lng
BTKL
+ Ta c: n H 2O n NaOH 0,32 mol mmui = m gly m glu 40n NaOH m H 2O 30, 68 (g)
Cu 10: Chn B.
- Da vo quy tc ta xc nh c cc cp cht c phn ng vi Fe2+ l Zn, Ag . Phn ng:
Zn + Fe2+ Zn2+ + Fe Fe2+ + Ag+

Fe3+ + Ag
Cu 11: Chn D.
Cht X: K2SO4 Z: KOH T: (NH4)2SO4 Y: NH4NO3

dd Ba(OH)2, t0 C kt ta xut Khng hin Kt ta v kh thot ra C kh thot ra
hin tng
- Phng trnh phn ng:
Ba(OH)2 + K2SO4 BaSO4 trng + 2KOH
Ba(OH)2 + NH4NO3: khng xy ra
Ba(OH)2 + (NH4)2SO4
BaSO4 trng + 2NH3 + 2H2O
Ba(OH)2 + 2NH4NO3 Ba(NO3)2 + 2NH3 + 2H2O
Cu 12: Chn D.
m 9
- Ta c: M Y Y 45 : Y l C2H 7 N
n Y 0, 2
Cu 13: Chn B.
Cu 14: Chn A.
Cu 15: Chn B.
- Na, Al c iu ch bng phng php in phn nng chy.
- Fe, Cu c iu ch bng c 3 phng php l in phn dung dch, nhit luyn v thy luyn.
- Ag c iu ch bng 2 phng php l in phn dung dch v thy luyn.
Vy ch c 2 kim loi Na v Al c bng mt phng php in phn.
Cu 16: Chn D.
- Nh vi git dung dch HNO 3 c vo ng nghim cha anbumin thy c kt ta mu vng.
Cu 17: Chn A.
Fe 2AgNO 3
Fe(NO 3 ) 2 2Ag
A. B. Fe + 2FeCl3
3FeCl2
Fe H 2SO 4 long
FeSO 4 H 2
C. Fe + 2HCl FeCl2 + H2 D. Fe + CuSO4

FeSO4 + Cu
Cu 18: Chn B.
- Phng trnh: HCOOCH3 NaOH
HCOONa CH3OH
mol: 0,15 0,15
m HCOONa 10, 2 (g)
Cu 19: Chn A.
H SO NH
- Qu trnh: Fe,Cu
2 4
Cu d v Fe 2 , Cu 2 ,SO 42
3
Fe(OH) 2
dd X
- Lu : Cc hiroxit hay mui ca cc kim loi Cu, Ag, Zn, Ni to phc tan trong dung dch NH3 d.
Cu 20: Chn C.
A. Sai, Tn gi ca X l phenyl axetat.
B. Sai, X khng c phn ng trng gng.
C. ng, Phng trnh: CH3COOC6H5 + NaOH CH3COONa + C6H5ONa + H2O
D. Sai, X c iu ch bng phn ng ca anhirit axetic vi phenol :
C6H5OH + (CH3CO)2O
CH3COOC6H5 + CH3COOH
Cu 21: Chn B.
- Hng t duy 1: Cn bng phng trnh
Mg + 2Fe3+
Mg2+ + 2Fe2+
mol: 0,02 0,04 0,04 n Fe3 cn li = 0,08 mol
Cu + 2Fe3+
Cu2+ + 2Fe2+
mol: 0,04 0,08 nCu d = 0,06 mol
Vy mrn = mCu d = 3,84 (g)

- Hng t duy 2: S dng bo ton e
- Ta c: n e cho 2(n Mg n Cu ) 0, 24 mol . Nhn thy: n Fe3 n e cho 3n Fe3 Fe3+ ch v Fe2+.
n e cho n Fe3
- Khi : nCu d = 0,06 mol m 3,84 (g)
2
Cu 22: Chn D.
- Phng trnh phn ng:
15000 C HgSO ,t o
2CH4 (X)
C2H 2 (Y) 3H 2 ; C2 H2 H2O
4
CH3CHO(Z)
Pd/PdCO
2CH3CHO(Z) O2 2CH3COOH(T); C2 H 2 (Y) H 2
0
3
C2 H 4 (P)
t
3C2H4 (P) 2KMnO4 4H2O 3C2H4 (OH)2 (Q) 2KOH 2MnO2
H SO
C2H4 (OH)2 (Q) 2CH3COOH(T)
2
o C2 H 4 (OOCCH3 ) 2 (E) 2H 2O
4
t
Vy M E 146
Cu 23: Chn D.
- Xt trng hp dung dch Y cha 2 cht tan l NaOH v NaCl. Qu trnh in phn din ra nh sau :
Ti catot: Ti Anot:
Fe2+ + 2e Fe 2Cl- Cl2 + 2e
x 2x x (2x + 2y) (x + y) (2x + 2y)
2H2O + 2e 2OH + H2 -
2y 2y y
3
- T phng trnh: Al 3H 2O NaOH Na[Al(OH)4 ] H 2 suy ra n OH n Al 0, 02 y 0, 01 mol
2
- Khi lng dung dch gim: 56x 71n Cl2 2n H2 4,54 x 0,03 mol
BT: e n Ag n FeCl 0, 03
FeCl2 :0, 03mol AgNO3
- Hn hp X: 2
m = 20, 46 gam
NaCl :0, 06 mol
BT: Cl
n 2n n 0,12
AgCl FeCl2 NaCl
Cu 24: Chn A.
Mg, MgO 0,5 mol khY (M Y 32)
- Qu trnh: X H 2SO 4 c c n
Mg(HCO3 ) 2 , MgSO3 dd30% dd Z (36%) MgSO4 : 0, 6 mol
58,8
- Ta c: n H 2SO4 n MgSO4 0, 6 mol m H 2SO 4 58,8 gam m dd H 2SO 4 196 gam
0,3
120n MgSO4
C% 36% m 200 m dd H 2SO4 m kh 20 gam
m m dd H 2SO 4 m kh
Cu 25: Chn D.
- Be khng tc dng vi nc ngay nhit thng trong khi Mg tan chm trong nc lnh khi un nng
th Mg tan nhanh trong nc.
Cu 26: Chn C.
- Trong cc chai dung dch m c nhiu cc axit amin m c th cn khi b m, mt sc hoc sau cc ca
phu thut c th sm hi phc. Ngoi ra c cc cht in gii v c th thm mt s cc vitamin,
sorbitol ty theo tn thng phm ca cc hng dc sn xut khc nhau.
Cu 27: Chn C.
A. Sai, Cc polime tng hp c th c iu ch bng phn ng trng ngng hoc trng hp. Ly v d:
trng hp vinyl clorua

B. Sai, Poli(vinyl axetat) (PVA) tc dng vi dung dch NaOH hay cao su thin nhin tc dng vi HCl:
C. ng, Protein l mt loi polime thin nhin c trong t tm, lng cu, len.
D. Sai, Trong cu trc ca cao su buna S khng c cha lu hunh.
xt,t o ,p
nCH 2 CH CH CH 2 nCH 2 CH C 6 H 5
[ CH 2 CH CH CH 2 CH 2 CH(C 6 H 5 ) ]
Buta 1,3ien Stiren Poli (butaien stiren) Cao su Buna S
Cu 28: Chn C.
- V X, Y u tham gia phn ng trng bc v tc dng vi KOH sinh ra mui nn X, Y c dng HCOOR
m MX < MY < 70 X l HCOOH ; Y l HCOOCH3. Vy d Y/X M Y : M X 1,304
Cu 29: Chn A.
A. NaNO3 + MgCl2 : khng xy ra B. 2NaOH + Al2O3
2NaAlO2 + H2O
C. K2O + H2O 2KOH D. 2Na + 2H2O 2NaOH + H2
Cu 30: Chn D.
- Trong phn t cc amino axit cha ng thi nhm amino NH2 v nhm cacboxyl COOH. Ty
thuc vo cc cht khc nhau m s nhm chc c trong cc cht c th ging nhau hoc khc nhau.
Cu 31: Chn B
- C 4 cht thy phn trong mi trng kim l: triolein; nilon-6,6; t lapsan; glyxylglyxin.
Triolein
N (CH2)6 N C (CH2)4 C
Poli(hexametylen -aipamit) hay nilon 6,6
H H O O
n
O CH2CH2 O C C
Poli(etylen - terephtalat) hay t lapsan
O O n
Glyxylglyxin H2NCH2CONHCH2COOH
Cu 32: Chn B.
C 4 th nghim thu c n cht l (1), (2), (3) v (4). PT phn ng :
(1) 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2
(2) 2NaCl + 2H2O 2NaOH + Cl2 + 2H2
dpdd
(3) KI + Na2Cr2O7 + H2SO4 K2SO4 + Cr2(SO4)3 + Na2SO4 + I2 + H2O

(4) 2NH3 + 2CrO3 N2 + Cr2O3 + 3H2O

Cu 33: Chn D
0,93
- Ta c: C X 3,875 . V khi thy phn X trong NaOH thu c 2 ancol c cng cacbon v 2
0, 24
mui
Trong X c 1 cht l HCOOC2H5 (A), este n chc cn li l RCOOC2H5 (B), este 2 chc (C) c
to t etylenglicol C2H4(OH)2 v hai axit cacboxylic HCOOH; RCOOH (trong gc R c 1 lin kt i
C=C)
quan h
+ Lc ny kA = 1 ; kB = 2 ; kC = 3. p dng
CO v H O
n B 2n C n CO2 n H 2O 0,13 (1)
2 2
BT: O
2n A 2n B 4n C 2n CO2 n H 2O 2n O2 0,58 (2) v nA + nB + nC = 0,24 (3)
+ T (1), (2), (3) ta tnh c: nA = 0,16 mol ; nB = 0,03 mol ; nC = 0,05 mol
BT: C
3.0,16 0,03.CB 0,05.CC 0,93 (4) (vi CB > 4, CC > 5)
+ Nu CB = 5 thay vo (4) ta c: CC = 6 Tha (nu CB cng tng th CC < 6 nn ta khng xt na).
7, 25
Vy (B) l CH2=CH-COOC2H5: 0,03 mol %m C 13, 61
22, 04
Cu 34: Chn C
t0
(1)C6H 4 (COONH3)2 (CH2 )6 2NaOH C6H 4(COONa)2(X 1) NH 2(CH 2 )6 NH2 (X 2 )
(2)C6H4(COONa)2(X1) H2SO4 C6H4(COOH)2(X 3) Na2SO4
0
(3) nHOOC(CH 2 ) 4 COOH(X 4 ) nNH 2 (CH 2 ) 6 NH 2 (X 2 )
t
( OC(CH 2 ) 6 CONH(CH 2 )6 NH) n 2n H 2 O
T nilon-6,6.
0
t
(4) nC6H 4 (COOH)2 (X 3) nC2H 4 (OH) 2 (X 5) ( OCC6H 4COOC2H 4O) n nH 2O .
T lapsan
X3 l C6H4 (COOH)2 c 8 nguyn t C v X4 l HOOC(CH2 )4 COOH c 6 nguyn t C.
Cu 35: Chn D.
- Khi cho m gam kim loi M tc dng vi 0,68 mol NaOH th :
nHNO3 4nNO nHNO3 4nNH 4
+ nNH 4 0,02mol nH 2O 0,3mol
10 2
BTKL
mM 63nHNO3 mX 30nNO 18nH2O m 16,9(g)
- Ta c ne trao i 3nNO 8nNH4 0,52mol
ne m 16,9a a 2
- M nM MM M M M 65(Zn) (vi a l s e trao i ca M)
a nM ne
Cu 36: Chn B.
- Khi t chy este X th :
nCO2 nCaCO3 nCO2 0,05 nCO2 0,05mol

100nCaCO3 (44nCO2 nH2O ) mdd gim 56nCO2 18nH2O 2,08 nH2O 0,04mol
- p dng bt bo ha, ta c : nX nCO2 nH2O 0,01mol . Vy este X c CTPT l C5H8O2
+ TH1 : X c to thnh t axit n chc v ancol hai chc :
HCOOCH2 CH2OOC2H5 v HOOC CH(CH)3 CH2 OOCH
C2H5OOC COOCH3 v CH3OOC CH2 COO CH3
Cu 37: Chn A.
- Khi gp X v Y vi t l mol tng ng l 1 : 3 c 2X Y
X2 Y 2H 2O (1)

nGly 0,075 5
+ T: X 2 Y l (Gly)5k (Tyr) 4k .
nTyr 0,06 4
(52).nX 5k 4k (52).nZ
nGly nTyr
+ Vi k = 1 n(Gly)5(Tyr)4 nX 2Y 0,015mol
5 4
BTKL
- Xt phn ng (1) ta c mX mY mX 2Y 18nH2O 14,865(g)
Cu 38: Chn C.
BTKL 2, 628 1, 752 1, 752
n HCl n X 0, 024 mol M X 73 : X l C4H11N
36,5 0, 024
- S ng phn ng vi cng thc ca X l 8
CH 3 CH 2 CH CH 3
CH 3 CH 2 CH 2 CH 2 NH 2
NH 2
CH 3
CH 3 CH CH 2 NH 2
CH 3 C NH2
CH 3
CH 3
CH 3 NH CH 2 CH 2 CH 3 CH 3 CH 2 NH CH 2 CH 3
CH 3 CH NH CH 3 CH 3 N CH 2 CH 3
CH 3 CH 3
Cu 39: Chn B.
Nhng cht tc dng c vi HCl thng gp trong ha hu c:
- Mui ca phenol : C6H5ONa + HCl
C6H5OH + NaCl
- Mui ca axit cacboxylic: RCOONa + HCl
RCOOH + NaCl
- Amin, anilin: R-NH2 + HCl
R-NH3Cl
- Aminoaxit: HOOC-R-NH2 + HCl
HOOC-R-NH3Cl
- Mui ca nhm cacboxyl ca aminoaxit: H2N-R-COONa + 2HCl
ClH3N-R-COONa + NaCl
- Mui amoni ca axit hu c: R-COO-NH3-R + HCl
R-COOH + R-NH3Cl
Vy CH 3COOH khng tc dng c vi HCl.
Cu 40: Chn C.
- Nhn thy: Ag Ag+ + 1e : Ag nhng electron nn Ag l cht kh.
----------HT----------

S GD T KIM TRA CHT LNG HC K I NM 2017
TNH LM NG Mn: KHOA HC T NHIN HA HC
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi b m mt sc ngi bnh c truyn dch ng thm nng lng. Cht trong dch
ng l:
A. Mantoz B. Saccaroz C. Glucoz D. Fructoz
Cu 2: Dy kim loi sp xp theo tnh kh tng dn l (tri sang phi):
A. Fe, Al, Mg B. Al, Mg, Fe C. Fe, Mg, Al D. Mg, Al, Fe
Cu 3: Bt ngt l mui ca:
A. axit oleic B. axit axetic C. axit aminoaxetic D. axit glutamic
A. Tt c cc amino axit u lng tnh.
B. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
C. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH) 2 cho hp cht mu tm.
D. Trong 1 phn t tetrapeptit c 4 lin kt peptit.
Cu 5: Dy gm cc kim loi u phn ng vi nc nhit thng thu c dung dch c mi
trng kim l:
A. Na, Ba, K B. Be, Na, Ca C. Na, Fe, K D. Na, Cr, K
Cu 6: Mt trong nhng cht liu lm nn v p k o ca tranh sn mi l nhng mnh vng lp lnh
cc mng. Ngi ta ng dng tch cht vt l g ca vng khi lm trang sn mi ?
A. C kh nng khc x nh sng B. Tnh do v c nh kim
C. Tnh do, tnh dn nhit D. Mm, c t khi ln
Cu 7: Polime no sau y trong thnh phn c cha nit ?
A. Polibutaien B. Polietilen C. Poli(vinyl clorua) D. Nilon-6,6
Cu 8 : Amino axit l hp cht hu c trong phn t c cha ?
A. nhm cacboxyl B. 1 nhm amino v 1 nhm cacboxyl
C. nhm amino D. nhm amino v nhm cacboxyl
T Qu tm Qu tm chuyn mu xanh
X, Y Cu(OH)2 Dung dch xanh lam
Z Nc brom Kt ta trng
X, Y, Z, T ln lt l:
A. Saccaroz, glucoz, anilin, etylamin. B. Saccaroz, anilin, glucoz, etylamin.
C. Anilin, etylamin, saccaroz, glucoz. D. Etylamin, glucoz, saccaroz, anilin.
Cu 10: Cho mt s tnh cht :
(1) C dng si (2) Tan trong nc
(3) Phn ng vi axit nitric c c xc tc (4) Tham gia phn ng trng bc
(5) B thy phn trong axit khi un nng
Cc tnh cht ca xenluloz l:
A. (1), (3), (5) B. (2), (3), (4) C. (3), (4), (5) D. (1), (2), (4)
Cu 11: Trong s cc cht sau: xeluloz, saccaroz, frutoz, glucoz. S cht khi thy phn n cng
ch thu c glucoz l:
A. tinh bt xenluloz B. Tinh bt, xenluloz, saccaroz

C. xenluloz, fructoz, saccaroz D. Tinh bt, saccaroz
A. Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng.
B. T nilon-6,6 c iu ch t hexametyleniamin v axit axetic.
C. T visco, t xenluloz axetat thuc loi t tng hp.
D. Si bng , t tm l polime thin nhin.
Cu 13: Sobitol l sn phm ca phn ng ?
A. Oxi ha glucoz bng AgNO3 trong ammoniac.
B. Kh glucoz bng H2 ,xt Ni un nng.
C. Ln men ancol etylic.
D. Glucoz tc dng vi Cu(OH) 2.
Cu 14: Tn gi ca ca C2H5NH2 l:
A. etylamin B. imetylamin C. metylamin D. propylamin
Cu 15: tch Ag ra khi hn hp Ag, Cu, Fe m khi lng Ag khng thay i th dng cht no
sau y ?
A. HCl B. HNO3 C. Fe2(SO4)3 D. AgNO3
Cu 16: chng minh glucoz c tnh cht ca andehit, ta cho dung dch glucoz phn ng vi ?
A. Cu(OH)2 nhit thng to dung dch mu xanh lam.
B. Dung dch AgNO3 trong ammoniac.
C. Kim loi Na.
D. Dung dch HCl.
Cu 17: C 3 cht hu c: H2NCH2COOH, C2H5COOH v CH3(CH2)3NH2. nhn bit cc cht trn
dng thuc th l:
A. qu tm B. NaOH C. HCl D. H2SO4
Cu 18: Bit ion Pb2+ trong dung dich oxi ha c Sn. Hai thanh kim loi Pb v Sn c ni vi nhau
bng dy dn in v nhng vo dung dch HCl th cht b n mn in ha l:
A. HCl B. Pb C. Sn D. Pb v Sn
Cu 19: Ming chui xanh tip xc vi dung dch iot cho mu xanh tm v trong ming chui xanh c:
A. glucoz B. mantoz C. tinh bt D. saccaroz
Cu 20: Cng thc ha hc ca cht no l este ?
A. CH3CHO B. HCOOCH3 C. CH3COCH3 D. CH3COOH
Cu 21: to b nhn to (cht bo rn) t du thc vt (cht bo lng) ta cho du thc vt thc hin
phn ng ?
A. ehirro ho B. X phng ho C. Hiro ho D. Oxi ho
Cu 22: Cho hn hp hai axit bo gm axit oleic v axit stearic tc dng vi glixerol. S triglixerit ti
a to thnh l:
A. 3 B. 5 C. 8 D. 6
Cu 23: Kim loi no sau y c cng ln nht trong tt c cc kim loi ?
A. Vonfam B. ng C. St D. Crom
Cu 24: Tnh cht ho hc c trng ca kim loi l:
A. tnh oxi ho B. tnh baz C. tnh kh D. tnh axit
Cu 25: Chn pht biu ng ?
A. Phn ng gia axit cacboxylic v ancol khi c mt ca axit sunfuric c l phn ng mt chiu.
B. Phn ng thu phn metyl axetat trong mi trng axit l phn ng thun nghch.
C. Khi thu phn cht bo lun thu c etilenglicol.
D. Tt c cc este phn ng vi dung dch kim lun thu c sn phm l mui v ancol.
Cu 26: Dy gm cc cht c sp xp theo th t tng dn lc baz t tri sang phi l:
A. phenylamin, etylamin, amoniac B. phenylamin, amoniac, etylamin
C. etylamin, amoniac, phenylamin D. etylamin, phenylamin, amoniac
Cu 27: Cht thuc loi isaccarit l:
A. fructoz B. glucoz C. xenluloz D. saccaroz
Cu 28: Hp cht no sau y thuc loi tripeptit ?

A. H2N-CH2-CO-NH-CH(CH3)-COOH B. H2N-CH2-CO-NH-CH2-CO-NH-CH2-COOH
C. H2N-CH2-CH2-CO-NH-CH2-COOH D. H2N-CH2-CH2-CO-NH-CH2-CH2-COOH
Cu 29: Tin hnh bn th nghim sau :
- Th nghim 1 : Nhng thanh Fe vo dung dch FeCl 3
- Th nghim 2 : Nhng thanh Fe vo dung dch CuSO 4
- Th nghim 3 : Nhng thanh Cu vo dung dch FeCl 3
- Th nghim 4 : Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl
S trng hp xut hin n mn in ho hc l:
A. 2 B. 1 C. 4 D. 3
Cu 30: Pht biu no di y khng ng ?
A. Bn cht ca n mn kim loi l qu trnh oxi ho-kh.
B. Nguyn tc chung iu ch kim loi l kh ion kim loi thnh nguyn t kim loi.
C. n mn ho hc pht sinh dng in.
D. Tnh cht ho hc c trng ca kim loi l tnh kh.
Cu 31: Etyl axetat c cng thc cu to thu gn l:
A. C2H5COOCH3. B. CH3COOCH3. C. CH3COOC2H5. D. CH3CH2COOC2H5.
Cu 32: Trong thnh phn ca du gi u thng c mt s este. Vai tr ca cc este ny l:
A. tng kh nng lm sch ca du gi. B. lm gim thnh phn ca du gi.
C. to mu sc hp dn. D. to hng thm mt, d chu.
Cu 33: Cho dung dch cha 14,6 gam Lysin (H2N-[CH2]4-CH(NH2)COOH) tc dng vi lng d dung
dch HCl, thu c dung dch cha m gam mui. Gi tr ca m l:
A. 21,90. B. 18,25. C. 16,43. D. 10,95.
Cu 34: t chy hon ton mt lng etyl axetat thu c 0,54 gam H2O v V lt (ktc) kh CO2. Gi
tr ca V l:
A. 0,538. B. 1,320. C. 0,672. D. 0,448.
Cu 35: Trng hp 224 lt etilen (ktc), thu c bao nhiu gam PE vi hiu sut 70% ?
A. 280 gam. B. 400 gam. C. 224 gam. D. 196 gam.
Cu 36: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c, xc tc axit sunfuric c, nng.
c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric, hiu sut phn ng t 90%.
Gi tr ca m l:
A. 6,3. B. 21,0. C. 18,9. D. 17,0.
Cu 37: Thy phn hon ton 42,96 gam hn hp gm hai tetrapeptit trong mi trng axit thu c
49,44 gam hn hp X gm cc aminoaxit no, mch h (ch cha 1 nhm cacboxyl COOH v 1 nhm
amino NH2). Cho ton b X tc dng vi dung dch HCl d, sau c cn dung dch thu c m gam
mui khan. Gi tr ca m l:
A. 66,96. B. 62,58. C. 60,48. D. 76,16.
Cu 38: t chy hon ton a gam triglixerit X cn va 4,83 mol O2, thu c 3,42 mol CO2 v 3,18
mol H2O. Mt khc, cho a gam X phn ng va vi dung dch NaOH, thu c b gam mui. Gi tr
ca b l:
A. 53,16. B. 57,12. C. 60,36. D. 54,84.
Cu 39: Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc
phn ng xy ra hon ton, thu c m gam rn. Bit th t trong dy in ha: Fe3+/Fe2+ ng trc
Ag+/Ag. Gi tr ca m l:
A. 64,8. B. 32,4. C. 54,0. D. 59,4.
Cu 40: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu
trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong thu c
330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l
132 gam. Gi tr ca m l:
A. 324,0. B. 405,0. C. 364,5. D. 328,1.
----------HT----------

KIM TRA CHT LNG HKI TNH LM NG LN 1
Cu 1: Chn C.
- Trong y hc: Glucoz c dng lm thuc tng lc cho ngi bnh v n d hp thu v cung cp nhiu
nng lng.
Cu 2: Chn A.
Tnh oxi ha ca ion kim loi tng dn
+ + 2+ 2+ + 2+ 3+ 2+ 2+ 3+ 2+ 2+ 2+ 2+ + 2+ 3+ 2+ + 2+ 3+
Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb 2H Cu Fe Hg Ag Pd Au
2+
Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb H2 Cu Fe Hg Ag Pd Au
Tnh kh ca kim loi gim dn
- Dy th in cc chun ca kim loi l dy sp xp cc kim loi theo th t tng dn th in cc

chun.
Theo chiu E0Mn+/M tng: Tnh oxi ha ca ion kim loi cng tng v tnh kh ca kim loi cng gim.
- Dy sp xp ng theo chiu tnh kh tng dn l: Fe Al Mg
Cu 3: Chn D.
- Mui mononatri ca axit glutamic l thnh phn chnh ca bt ngt hay m chnh.
Cu 4: Chn A.
A. ng, Tt c cc amino axit u l nhng lng tnh.
B. Sai, Cc hp cht peptit km bn trong c mi trng axit ln mi trng baz.
C. Sai, Cc ipeptit mch h tr ln mi c th tc dng c vi Cu(OH) 2 cho hp cht mu tm.
D. Sai, Trong 1 phn t tetrapeptit th ch c 3 lin kt peptit.
Cu 5: Chn A.
- Cc kim loi kim, kim th u tc dng vi H 2O nhit thng (tr Be khng phn ng vi
H2O bt k nhit no) v dung dch thu c l cc baz tng ng.
2M + 2H2O
2MOH + H2 (M l kim loi kim)
N + 2H2O
N(OH)2 + H2 (N l kim loi kim th, tr Be)
Cu 6: Chn B.
Cu 7: Chn D.
Polibutaien: ( CH 2 CH CH CH 2 ) n Polietilen: ( CH 2 CH 2 ) n
Poli(vinyl clorua) Nilon-6,6
CH2 CH N (CH2)6 N C (CH2)4 C
Cl n H H O O
n
Cu 8: Chn D.
- Amino axit l loi hp cht hu c tp chc m phn t cha ng thi nhm amino (NH2) v nhm
cacboxyl (COOH). Cng thc chung: (H2N)x R (COOH)y
Cu 9: Chn D.
T l Etylamin: C2H5NH2 Qu tm Qu tm chuyn mu xanh
Y l Glucoz: C6H12O6 Dung dch AgNO3 trong NH3 un nng Kt ta Ag trng sng
Z l Anilin: C6H5NH2 Nc brom Kt ta trng
X l Saccaroz: C12H22O11 Cu(OH)2 Dung dch xanh lam
Cu 10: Chn A.

- Cng thc phn t ca xenluloz: (C6H10O5)n c trng thi t nhin v tnh cht vt l sau:
- Xenluloz l cht rn hnh si, mu trng, khng mi, khng v, khng tan trong nc v trong dung
mi hu c thng thng nh benzen, ete.
- Xenluloz l thnh phn chnh to ra lp mng t bo thc vt, b khung ca cy ci.
- Xenluloz c nhiu trong trong cy bng (95 98 %), ay, gai, tre, na (50 80 %), g (40 50 %).
to
- Phn ng ca polisaccarit (thy phn): (C6H10O5)n + nH2O nC6H12O6
- Phn ng vi HNO3/H2SO4 c (phn ng este ha): da vo t l mol phn ng m sn phm to ra
H SO ,t o
l khc nhau. V d: [C6H7O2(OH)3]n + 3nHNO3 (c)
2 4
[C6H7O2(ONO2)3]n + 3nH2O
1: 3
- Phn ng vi anhirit axetic (c H2SO4 c):
[C6H7O2(OH)3]n + 3n(CH3CO)2O
[C6H7O2(OCOCH3)3]n + 3nCH3COOH
- Phn ng CS2 v NaOH: [C6H7O2(OH)3]n + nNaOH
[C6H7O2(OH)2ONa]n + nH2O
[C6H7O2(OH)2ONa]n + nCS2 [C6H7O2(OH)2OCSSNa]n
- Xenluloz khng phn ng vi Cu(OH)2, nhng tan c trong dd[Cu(NH3)4](OH)2 (nc
Svayde) to cht lng nht dng to t ng - amoniac.
Vy nhn nh ng l: (1), (3), (5).
Cu 11: Chn A.
Cc cacbohirat khi thy phn n cng ch thu c glucoz l: Tinh bt, xenluloz v mantoz.
H O
- Thy phn mantoz: C12H22O11
2C6H12O6 (glucoz)
2
H
H
- Thy phn tinh bt, xenluloz: (C6H10O5 ) n nH 2O nC6H12O6
Cu 12: Chn D.
A. Sai, Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng hp.
B. Sai, T nilon-6,6 c iu ch t hexametyleniamin v axit aipic.
C. Sai, T visco v t xenluloz axetat thuc loi t bn tng hp (hay t nhn to).
D. ng, Si bng v t tm l polime thin nhin.
Cu 13: Chn B.
Ni,t o
- Phn ng kh glucoz: CH2OH[CHOH]4CHO + H2 CH2OH[CHOH]4CH2OH (sobitol)
Cu 14: Chn A.
Tn gi Etylamin imetylamin Metylamin Propylamin
Cng thc cu to C2H5NH2 CH3NHCH3 CH3NH2 CH3CH2CH2NH2
Cu 15: Chn C.
- tch Ag ra khi hn hp gm Ag, Fe v Cu ta dng dung dch Fe2(SO4)3.
Fe2(SO4)3 + Fe 3FeSO4 Cu + Fe2(SO4)3 CuSO4 + 2FeSO4
- Ag khng tan trong dung dch Fe2(SO4)3 nn ta tch ly phn khng tan ra l Ag.
Cu 16: Chn B.
- Phn ng chng minh glucoz c tnh cht ca andehit l phn ng gia glucoz vi dung dch
AgNO3 trong NH3, un nng (thuc th Tollens) cho phn ng trng bc:
to
CH2OH[CHOH]4CHO + 2[Ag(NH3)2]OH CH2OH[CHOH]4COONH4 + 2Ag + 3NH3 + H2O
Cu 17: Chn A.
Cht
H2N-CH2-COOH C2H5COOH CH3(CH2)3NH2
Thuc th
Qu tm Khng i mu Ha . Ha xanh.
Cu 18: Chn C.
- Trong n mn in ha ca cp kim loi Sn-Pb, Sn l kim loi c tnh kh mnh hn ng vai tr l
anot (cc m) v b n mn cn Pb c tnh kh mnh hn ng vai tr l catot (cc dng) v c
bo v; khi Sn b n mn ht th lc Pb s b n mn.
Cu 19: Chn C.

- Trong ming chui xanh c cha tinh bt, khi cho tip xc vi dung dch iot th c mu xanh tm.
Ngc li, i vi ming chui chn th lc tinh bt b thy phn ht khi cho tip xc vi dung
dch iot th khng c hin tng xy ra.
Cu 20: Chn B.
Cng thc cu to CH3CHO HCOOCH3 CH3COCH3 CH3COOH
Thuc loi Anehit Este Xeton Axit cacboxylic
Cu 21: Chn C.
- Trong thnh phn cht bo rn c cha cc gc axit bo no do vy chuyn ha thnh cc cht bo
lng c cha cc gc axit bo khng no th ngi ta dng phn ng ehiro ha. Ngc li, chuyn
ha cht bo lng thnh cht bo rn ngi ta dng phn ng hiro ha.
Cu 22: Chn D.
- Gi A v B ln lt l cc gc ca axit bo: C 17H33COO- v C17H35COO- . C 6 triglixerit ti a
to thnh tng ng vi cc gc axit bo l : AAA ; ABA ; AAB ; BBB ; BAB ; BBA.
Cu 23: Chn D.
Cu 24: Chn C.
Cu 25: Chn B.
A. Sai, Phn ng gia axit cacboxylic v ancol khi c mt ca axit sunfuric c l phn ng thun
nghch.
B. ng, Phn ng thu phn metyl axetat trong mi trng axit l phn ng thun nghch.
C. Sai, Khi thu phn cht bo lun thu c glixerol.
D. Sai, Ly v d: HCOOC6H5 + 2NaOH HCOONa + C6H5ONa + H2O
Cu 26: Chn B.
- Dy sp xp tnh baz tng dn l: phenylamin (C 6H5NH2) < amoniac (NH3) < etylamin (C2H5NH2)
Cu 27: Chn D.
Cu 28: Chn B.
Cu 29: Chn A.
iu kin xy ra n mn in ha l: (3 iu kin bt buc)
Cu 30: Chn C.
A. ng, Bn cht ca n mn kim loi l qu trnh oxi ho-kh, chuyn kim loi thnh cation kim.
B. ng, Nguyn tc chung iu ch kim loi l kh ion kim loi thnh nguyn t kim loi.
C. Sai, n mn ho hc khng pht sinh dng in.
D. ng, Tnh cht ho hc c trng ca kim loi l tnh kh.
Cu 31: Chn C.
Cng thc cu to C2H5COOCH3 CH3COOCH3 CH3COOC2H5 CH3CH2COOC2H5
Tn gi Metyl propionat Metyl axetat Etyl axetat Etyl propionat
Cu 32: Chn D.
- Mt s este c mi thm ca hoa qu c dng trong cng nghip thc phm (bnh ko, nc gii
kht) v m phm (x phng, nc hoa).
Cu 33: Chn A.
BTKL
- Ta c: n HCl 2n lysin 0, 2 mol mmui = m lysin 36,5n HCl 21,9 (g)
Cu 34: Chn C.
- Khi t chy etyl axetat thu c: n CO 2 n H 2O 0, 03 mol VCO 2 0, 672 (l)

Cu 35: Chn D.
VC2H 4
- Ta c: m PE 28n PE 28. .H % 196 (g)
22, 4
Cu 36: Chn B.
H SO ,t o
- Phn ng: [C6H7O2(OH)3]n + 3nHNO3 (c)
2 4
29, 7 1
m HNO3 63n HNO3 63.3. . 21 (g)
297 90%
Cu 37: Chn A.
H
- Khi thy phn hn hp 2 peptit trong mi axit: (A) 4 3H 2O 4A
BTKL m X mpeptit 4
n H2O 0,36 mol n A n HCl 0, 48 mol
18 3
- Khi cho X tc dng vi dung dch HCl d th: A + HCl
AHCl
BTKL
n HCl n A 0, 48 mol mAHCl mA 36,5n HCl 66,96 (g)
Cu 38: Chn D.
- Khi t chy hon ton a gam triglixerit X th:
2n CO 2 n H 2O 2n O 2
BTKL
m X 44n CO 2 18n H 2O 32n O 2 53,16 (g)
BT:O
nX 0, 06 mol
6
- Khi cho X tc dng vi NaOH th : n NaOH 3n X 3n C3H5 (OH)3 0,18 mol
BTKL
m mui m X 40n NaOH 92n C3H5 (OH)3 54,84 (g)
Cu 39: Chn D.
- Ta c: n e cho max 3n Al 3n Fe 0,6 mol v n e cho min 3n Al 2n Fe 0,5 mol
- Nhn thy: n e cho max ne nhn = n Ag > n e cho min Al tan ht v Fe tan ht trong dung dch Ag+ thu
c hn hp sn phm gm cc cation Al3+, Fe2+, Fe3+ v rn ch c Ag vi m Ag 0,55.108 59, 4 (g)
Cu 40: Chn B.
- Khi hp th CO2 vo Ca(OH)2 d th: mdd gim = mCaCO3 44n CO2 132 n CO2 4,5 mol
n CO 2 1
mtinh bt = 162. . 405 (g)
2 H%

TNH HI DNG Mn: KHOA HC T NHIN HA HC
THPT ON THNG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Oxit no sau y l oxit axit

A. CrO B. Al2O3 C. CrO3 D. Fe2O3
Cu 2: Trong dung dch H 2N-CH2-COOH tn ti ch yu dng :
A. Anion B. Cation C. Phn t trung ha D. Ion lng cc
Cu 3: Trong t nhin cht hu c X c nhiu trong bng, ay, tre, ..., khi cho tc dng vi hn hp
HNO3/H2SO4 c un nng to cht hu c Y d chy, n mnh c dng lm thuc sng khng
khi. X l
A. Xenlulozo B. Tinh bt C. Glucozo D. Saccarozo
Cu 4: Trng hp no sau y to sn phm l ancol v mui natri ca axit cacboxylic
0 0
A. HCOOCH=CH-CH3 + NaOH
t
B. HCOOC(CH3)=CH2 + NaOH
t

0 0
C. CH2=C(CH3)COOH + NaOH t
D. HCOOCH2CH=CH2 + NaOH t

Cu 5: Th nghim no sau y c phn ng ha hc xy ra?
A. Cho dung dch Fe(NO3)3 vo dung dch AgNO3.
B. Cho Cr2O3 vo dung dch NaOH long.
C. Nh dung dch Br2 vo dung dch cha NaCrO2 v NaOH.
D. Cho bt Fe vo dung dch HNO3 c, ngui.
Cu 6: Cho V1 ml dung dch NaOH 0,4M vo V2 ml dung dch H2SO4 0,6M. Sau khi kt thc phn ng
thu c dung dch ch cha mt cht tan duy nht. T l V1 : V2 l
A. 1 : 3 B. 2 : 3 C. 3 : 2 D. 3 : 1
Cu 7: Polime X l cht rn trong sut, cho nh sng truyn qua tt nn c dng ch to thy tinh
hu c plexiglas. Monome to thnh X l :
A. H2N-[CH2]5-COOH B. CH2=C(CH3)COOCH3
C. CH2=CHCOOH D. CH2=CHCOOCH3
Cu 8: phn bit cc dung dch glucoz, saccaroz, v h tinh bt c th dng dy cht no sau
y lm thuc th ?
A. AgNO3/NH3 v NaOH. B. Cu(OH)2 v AgNO3/NH3.
C. HNO3 v AgNO3/NH3. D. Nc brom v NaOH.
Cu 9: Hn hp X gm FeCl2 v KCl c t l mol tng ng l 1 : 2. Ha tan hon ton 16,56 gam X
vo nc d thu c dung dch Y. Cho dung dch AgNO3 d vo Y, kt thc phn ng thu c m gam
kt ta. Gi tr m l
Cu 10: Nhn nh no sau y l sai
A. iu kin thng, cc amino axit l cht rn, d tan trong nc.
B. trng thi tinh th, cc amino axit tn ti dng ion lng cc (mui ni phn t).
C. Axit glutamic l thuc h tr thn kinh.
D. Trng ngng axit 6-aminohexanoic thu c nilon-6 c cha lin kt peptit.
Cu 11: Cho 15,94 gam hn hp gm alanin v axit glutamic tc dng va vi 200 ml dung dch
NaOH 1M, thu c dung dch X. Cho 450 ml dung dch HCl 0,8M vo dung dch X, c cn dung dch
sau phn ng thu c m gam rn khan. Gi tr m l

Cu 12: Cho cc polime : t visco, len, t tm , t axetat, bng, tinh bt. S polime thin nhin l :
A. 2 B. 3 C. 4 D. 5
Cu 13: Ln men hon ton m gam glucozo thnh ancol etylic. Ton b kh CO 2 sinh ra trong qu
trnh ny c hp th ht vo dung dch Ca(OH) 2 d to ra 40 gam kt ta. Gi tr m l :
A. 64,8 B. 72 C. 144 D. 36
Cu 14: Du m lu d b i thiu l do :
A. Cht bo b phn hy thnh cc mi kh chu B. Cht bo b oxi ha chm bi oxi
C. Cht bo b phn hy vi nc trong khng kh D. Cht bo b ra ra
Cu 15: Trong cng nghip, Al c iu ch bng cch no di y
A. in phn nng chy AlCl3. B. in phn dung dch AlCl3.
C. Cho kim loi Na vo dung dch AlCl3. D. in phn nng chy Al2O3.
Cu 16: ng dng no sau y khng phi l ca protein :
A. L thnh phn to nn cht do. B. L thnh phn cu to nn t bo.
D. L c s to nn s sng. C. L dinh dng trong thc n ca ngi v ng vt.
A. 2 B. 4 C. 5 D. 3
Cu 18: Trong cc dung dch sau: fructoz, glixerol, saccarozo, ancol etylic v tinh bt. S dung
dch c th ha tan c Cu(OH) 2 nhit thng l:
A. 4 B. 5 C. 3 D. 1
Cu 19: Cho dy cc cht sau: etyl axetat, triolein, t visco, saccaroz, xenlulz v fructz. S
cht trong dy thy phn trong dung dch axit l :
A. 4 B. 5 C. 3 D. 6
0
t
(1) X NaOH X1 X 2 2H 2O (2) X1 H2SO4
Na 2SO4 X3
0 0
t t
C. X3 v X4 c cng s nguyn t cacbon. D. X2, X4 v X5 c mch cacbon khng phn
nhnh.
A. Dung dch CuSO4 dng trong nng nghip d cha mc sng cho c chua.
B. Nh C2H5OH vo CrO3 thy hin tng bc chy.
C. Nh dung dch NH3 ti d vo dung dch CuSO 4 c kt ta xanh lam.
D. Cu l kim loi mu , thuc kim loi nng, mm v d dt mng.
Cu 22: Kim loi no di y c dng lm t bo quang in ?
A. Na B. Li C. Ba D. Cs
Cu 23: Cho 17,82 gam hn hp gm Na, Na 2 O, Ba, BaO (trong oxi chim 12,57% v khi lng)
vo nc d, thu c a mol kh H2 v dung dch X. Cho dung dch CuSO4 d vo X, thu c 35,54
gam kt ta. Gi tr ca a l.
A. 0,08 B. 0,12 C. 0,10 D. 0,06
(a) Gang l hp kim ca st c cha t 0,01 2% khi lng cacbon.
(b) Nc cng l nc cha nhiu ion Ca 2+ v Mg2+.
(c) Cho t t dung dch HCl vo dung dch K 2CrO4 thy dung dch t mu vng chuyn sang mu
da cam
(d) Hn hp gm Al v Fe3O4 dng hn ng ray.
(e) Nc kh c cng thc l CO 2 (rn), khng nng chy m thng hoa nn c dng to
mi trng lnh v kh rt tin cho vic bo qun thc phm.
S pht biu sai l
A. 2. B. 3. C. 4. D. 1.
Cu 25: un nng 0,2 mol hn hp X cha etyl fomat v etyl axetat vi dung dch AgNO3/NH3 (dng
d) thu c 17,28 gam Ag. Nu thy phn hon ton 28,84 gam X vi dung dch KOH va , thu c
m gam mui. Gi tr ca m l
Cu 26: Oxit no di y khng tan trong dung dch NaOH long ?
A. P2O5 B. Al2O3. C. Cr2O3 D. K2O
Cu 27: Hn hp X cha ba este mch h, trong phn t ch cha mt loi nhm chc v c to
bi t cc axit cacboxylic c mch khng phn nhnh. t chy ht 0,2 mol X cn dng 0,52 mol O2,
thu c 0,48 mol H2O. un nng 24,96 gam X cn dng 560 ml dung dch NaOH 0,75M thu c
hn hp Y cha cc ancol c tng khi lng l 13,38 gam v hn hp Z gm hai mui, trong c
a gam mui A v b gam mui B (MA < MB). T l gn nht a : b l
A. 0,6 B. 1,2 C. 0,8 D. 1,4
Cu 28: Ha tan ht m gam hn hp X gm Cu v Fe trong dung dch HCl long d, thu c 0,09 mol
kh H2 . Nu cho m gam X trn vo dung dch HNO3 long d, thu c 0,15 mol kh NO (sn phm kh
duy nht ca N+5). Gi tr ca m l
Cu 29: C by ng nghim ng ring bit trong nm ng nghim : (NH4)2SO4, FeCl2, Cr(NO3)3,
K2CO3, Al(NO3)3, K2Cr2O7 v (COONa)2. Cho Ba(OH)2 n d vo by ng nghim trn. Sau khi
cc phn ng kt thc s ng nghim thu c kt ta l :
A. 4 B. 5 C. 6 D. 7
Cu 30: iu khng nh no sau y l sai
A. Al(OH)3 phn ng c vi dung dch HCl v dung dch KOH.
B. Trong cc phn ng ha hc, kim loi Al ch ng vai tr l cht kh?
C. Kim loi Al tan c trong dung dch H2SO4 long, ngui.
D. Kim loi Al c tnh dn in tt hn kim loi Cu.
Cu 31: Cho t t dung dch HCl vo dung dch cha a mol Ba(AlO2)2 v b mol Ba(OH)2. Kt qu
th nghim c biu din trn th sau:
T l a : b l
A. 7 : 4. B. 4 : 7. C. 2 : 7. D. 7 : 2.
Cu 32: Dung dch saccarz khng c phn ng trng gng, nhng sau khi un nng vi dung
dch H2SO4 long to dung dch c phn ng trng gng. l do :
A. Mt phn t saccarz b thy phn thnh mt phn t glucz v mt phn t fructz
B. Mt phn t saccarz b thy phn thnh 2 phn t fructz
C. c s to thnh anhit axetic sau phn ng
D. Mt phn t saccarz b thy phn thnh 2 phn t glucz
Cu 33: Cho 2a mol bt Fe vo dung dch cha 5a mol AgNO3, sau khi phn ng xy ra hon ton, thu
c dung dch gm cc cht.
A. Fe(NO3)3. B. Fe(NO3)2 v Fe(NO3)3.
C. Fe(NO3)2, AgNO3. D. Fe(NO3)3 v AgNO3.
Cu 34: T no sau y thuc t nhn to
A. t olon B. t tm C. t visco D. t nilon-6,6
Cu 35: Cht A c cng thc phn t l C 4H9O2N, bit :
0 0
A + NaOH t
B + CH3OH (1) B + HCl d t
C + NaCl (2)
Bit B l mui ca -amino axit, cng thc cu to ca A, C ln lt l :
A. H2NCH2CH2COOCH3 v ClH3NCH2CH2COOH
B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH
C. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH
D. CH3CH2CH2(NH2)COOH v CH3CH2CH(NH3Cl)COOH
Cu 36: t chy hon ton m gam mt cht bo X cn 1,106 mol O2, sinh ra 0,798 mol CO 2 v 0,7
mol H2O. Cho 24,64 gam cht bo X tc dng va vi dung dch cha a mol Br 2. Gi tr ca a l:
A. 0,10. B. 0,12. C. 0,14. D. 0,16.
(a) Cho Mg vo dung dch Fe 2(SO4)3 d (b) Sc kh Cl2 vo dung dch FeCl 2
(c) Dn kh H2 d qua bt CuO nung nng (d) Cho Na vo dung dch CuSO 4 d
(e) Nhit phn AgNO 3 (f) in phn nng chy Al 2O3
Sau khi kt thc cc phn ng, s th nghin thu c kim loi l:
A. 4 B. 2 C. 3 D. 5
Cu 38: Ha tan 13,68 gam mui MSO 4 vo nc c dung dch X. in phn X (vi in cc tr,
cng dng in khng i) trong thi gian t giy, c m gam kim loi M duy nht catot v
0,784 lt kh anot. Cn nu thi gian in phn l 2t giy th tng th tch kh thu c c hai
in cc l 2,7888 lt. Bit th tch cc kh iu kin tiu chun. Gi tr ca m l:
A. 4,788. B. 4,480. C. 1,680. D. 3,920.
Cu 39: Nhn nh no sau y l ng
A. Nc cng l nc cha nhiu ion HCO3- v SO42-
B. lm mm tnh cng ca nc cng vnh cu bng cch un nng.
C. Nc t nhin thng c c tnh cng tm thi v tnh cng vnh cu.
D. Nc cng l tc nhn gy nhim ngun nc hin nay.
Cu 40: X phng ha hon ton triglyxerit X trong dung dch NaOH d, thu c glyxerol, natri oleat,
natri stearat v natri panmitat. Phn t khi ca X l
A. 860 B. 862 C. 884 D. 886
----------HT----------

PHN TCH HNG DN GII
THI TH ON THNG HI DNG LN 1
Cu 1: Chn C.
CrO, Fe2O3 l oxit baz, Al2O3 l oxit lng tnh.
Cu 2: Chn D.
Cu 3: Chn A.
Cu 4: Chn D.
- Cc phn ng xy ra:
0
t
HCOONa + CH3CH2CHO
0
t
HCOONa + CH3COCH3
0
C. CH2=C(CH3)COOH + NaOH
t
CH2=C(CH3)COONa + H2O
0
HCOONa + CH2=CH-CH2-OH
Cu 5: Chn C
A . Fe(NO3)2 + AgNO3 khng phn ng.
B. Cr2O3 ch phn ng vi NaOH c nng.
C. 3Br2 + 2NaCrO2 + 8NaOH 2Na2CrO4 + 6NaBr + 4H2O
D. Cr, Fe v Al b th ng ha vi HNO3 v H2SO4 c ngui.
Cu 6: Chn D
0,4V1 V 3
2NaOH H 2SO4
Na2SO4 H 2O. 0,6V2 1
0,4V1 0,6V2 2 V2 1
Cu 7 : Chn B.
COOCH3

CH2 C
n
CH3 CH3
Cu 8: Chn B.
Glucz Saccarz H tnh bt
Cu(OH)2 Phc xanh lam Phc xanh lam Khng hin tng
AgNO3/NH3 Kt ta bc Khng hin tng
Cu 9: Chn A
0,06 mol 0,12 mol
H O AgNO
- Qu trnh: FeCl 2 , KCl
2
dd Y
3
AgCl, Ag
16,56 (g ) X m (g)
BT: Cl
n AgCl 2n FeCl 2 n KCl 0, 24 mol
- Kt ta gm: m 40,92 (g)
BT: e

n Ag n FeCl 2 0, 06 mol
Cu 10: Chn B.
Cu 11: Chn D
A. ng, iu kin thng, cc amino axit l cht rn, d tan trong nc.
B. ng, Trong phn t amino axit, nhm NH2 v nhm COOH tng tc vi nhau to ion lng cc.
V vy amino axit kt tinh tn ti dng ion lng cc. Trong dung dch, dng ion lng cc chuyn mt
phn nh thnh dng phn t:

C. ng Axit glutamic l thuc h tr thn kinh.
D. Sai, Trng ngng axit 6-aminohexanoic thu c nilon-6 c cha lin kt peptit.
to
H 2 N [CH 2 ]5 COOH n ( HN [CH 2 ]5 CO ) n nH 2O
Lin kt CO-NH trong trng hp ny khng phi l lin kt peptit v khng dc to ra t cc - amino
axit.
Cu 12: Chn B.
C 3 polime thin nhin l l t tm, bng v tinh bt.
Cu 13: Chn D.
n n
nglucz CO2 CaCO3 0,2mol mglucz 36(g)
2 2
Cu 14 : Chn B.
Du m lu d b i thiu l do ni i C = C ca gc axit bo khng no b oxi ha chm bi oxi
trong khng kh to thnh peoxit, cht ny b thy phn thnh cc sn phm c mi kh chu.
Cu 15: Chn D
Cu 16: Chn A.
Protein l thnh phn khng th thiu ca tt c cc c th sin vt, n l c s ca s sng. Khng
nhng th, protein cn l mt loi thc n chnh ca con ngi v nhiu ng vt di dng tht c
trng.
Cu 17: Chn B.
C 4 th nghim thu c n cht l (1), (2), (3) v (4). PT phn ng :
(1) 2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2
(2) 2NaCl + 2H2O 2NaOH + Cl2 + 2H2
dpdd
(3) KI + Na2Cr2O7 + H2SO4 K2SO4 + Cr2(SO4)3 + Na2SO4 + I2 + H2O

(4) 2NH3 + 2CrO3 N2 + Cr2O3 + 3H2O
Cu 18: Chn C.
C 3 dung dch c th ha tan c Cu(OH)2 nhit thng l fructozo, glixerol v saccarozo.
Cu 19 : Chn B
C 5 cht b thy phn trong dung dch axit l : etyl axetat, triolein, saccaroz, xenlulz v fructz
Cu 20: Chn C
t0
(1)C6H 4 (COONH3)2 (CH2 )6 2NaOH C6H 4(COONa)2(X 1) NH 2(CH 2 )6 NH2 (X 2 )
(2)C6H4(COONa)2(X1) H2SO4 C6H4(COOH)2(X 3) Na2SO4
0
t
( OC(CH 2 ) 6 CONH(CH 2 )6 NH) n 2n H 2 O
T nilon-6,6.
t0
(4) nC6H 4 (COOH)2 (X 3) nC2H 4 (OH) 2 (X 5) ( OCC6H 4COOC2H 4O) n nH 2O .
T lapsan
X3 l C6H4 (COOH)2 c 8 nguyn t C v X4 l HOOC(CH2 )4 COOH c 6 nguyn t C.
Cu 21: Chn D
Cu 22: Chn D.
Cu 23: Chn A.
Quy i hn hp thnh Na, Ba v O. Ta c :
23nNa 137nBa 15,58
23nNa 137nBa 17,82 16nO nNa 0,32mol
nNa 2nBa2
98nCu(OH)2 233nBaSO4 35,54 98 233nBa2 35,54 nBa 0,06mol
2
n 2nBa 2nO

BT:e
nH 2 Na 0,08mol Cu 24: Chn A
2
(a) Sai, Gang l hp kim ca Fe vi C trong c cha t 2 5% khi lng Cacbon ngoi ra cn 1
lng nh cc nguyn t Si, Mn, S
(b) ng, Nc cng l nc cha nhiu ion Ca2+ v Mg2+.
(c) Sai, Cho t t dung dch HCl vo dung dch K 2CrO4 dung dch t mu vng chuyn sang mu lc
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O
(d) Sai, Bt nhm trn vi bt st(III) oxit (bt tecmit) c dng hn ng ray bng phn ng
0
nhit nhm: 2Al + Fe2O3 t
Al2O3 + 2Fe
(e) ng. Nc kh c nhng u im c bit i cho cng dng lm lnh v bo qun nh:
- Nc kh lnh hn (-78,5 C) nn bo qun c lu hn.
- Nc kh rt sch khi s dng v CO 2 ch thng hoa thnh dng kh ch khng b tan thnh
nc.
- Nc kh khi thng hoa (thnh dng kh) th to thnh mt lp kh CO 2 bao bc thc phm lm
c ch nhiu loi vi sinh vt gip thc phm ti lu v c mi v t nhin.
Ngoi ra nc kh cn c ng dng nhiu trong cc ngnh cng nghip khc nh lm sch, lm
nhin liu h thng tr trong mt s loi my bay. Hoc cng c th to ra cc sn phm iu khc
ngh thut.
Vy c 3 pht biu sai l (a), (c) v (d).
Cu 25: Chn D
HCOOC 2 H 5 AgNO3 /NH 3 n Ag
- 0,2 mol X n HCOOC2H5 0, 08 mol n CH3COOC2H5 0,12 mol
CH 3COOC 2 H 5 2
HCOOC2 H5 : 0,14 mol KOH HCOOK : 0,14 mol
- Cho 28,84 gam X mmui = 32,34 (g)
CH 3COOC 2 H5 : 0, 21 mol CH3COOK : 0, 21 mol
Cu 26: Chn C.
Cr2O3 tan c trong dung dch kim c v nng.
A. P2O5 + 6NaOH(d) 2Na3PO4 + 3H2O
B. Al2O3 + 2NaOH 2NaAlO2 + H2O
D. K2O + H2O 2KOH
Cu 27: Chn D.
- Quy i hn hp X thnh gc hidrocacbon C xHy v nhm COO (CO2). V vy khi t X th s mol
O2 tham gia phn ng chnh bng s mol O 2 t gc C xHy.
- Khi t 0,2 mol X (gi nh t nhm C xHy) th :
BT:O
nCO2 (khi t CxH y ) nO2 0,5nH2O 0,28 mCxH y 12nCO2 2nH2O 4,32(g)
- Cho 24,96 gam X tc dng vi NaOH th
6,48
nX(trong 24,96g) 0,2. 0,3mol
4,32
nCOO nNaOH 0,42 mCx H y 24,96 44nCOO 6,48
nCOO(trong 0,2 mol X) 0,42 0,28mol

1,5
+ Ta nhn thy rng nC(trong gc Cx H y ) nC(trong nhm COO) 0,28, v th s nguyn t C trong gc
CxHy bng s nhm COO trong cc phn t este.
n 0,42
+ Mc khc : nCOO NaOH 1,4 . T 2 d kin trn ta suy ra c cc este trong X l
nX 0,3
HCOOCH3,(COOCH3)2 v HCOOCH2CH2OOCH . Khi :
BTKL
68nHCOONa 134n(COONa)2 mX 40nNaOH mancol 28,38 nHCOONa 0,24mol

BT:Na
nHCOONa 2n(COONa)2 nNaOH 0,42
n(COONa)2 0,09mol
mHCOONa 0,24.68
1,353
m(COONa)2 0,09.134

Cu 28: Chn B
- Khi cho m gam X tc dng vi HCl long d th :
BT:e
nFe nH2 0,09mol
3nNO 3nFe
- Khi cho m gam X tc dng vi HNO3 long d th :
BT:e
nCu 0,09mol
2
mX 56nFe 64nCu 10,8(g)
Cu 29: Chn B.
(1) Ba(OH)2 + (NH4)2SO4 BaSO4 + 2NH3 + 2H2O
(2) Ba(OH)2 + FeCl2 Fe(OH)2 + BaCl2
(3) 7Ba(OH)2(d) + 2Cr(NO3)3 Ba(CrO2)2 + 6Ba(NO3)2 + 7H2O
(4) Ba(OH)2 + K2CO3 BaCO3 + KOH
(5) 7Ba(OH)2(d) + 2Al(NO3)3 Ba(AlO2)2 + 6Ba(NO3)2 + 7H2O
(6) 2Ba(OH)2 + K2Cr2O7 2BaCrO4 + 2KOH + 2H2O
(7) Ba(OH)2 + (COONa)2 Ba(COO)2 + 2NaOH
Vy c 5 ng nghim thu c k ta l (1), (2), (4), (6) v (7).
Cu 30: Chn D
Al(OH)3 3HCl AlCl3 3H 2O
A. ng, Cc phn ng ca Al(OH)3:
Al(OH)3 NaOH
Na[Al(OH) 4 ]
B. ng, Al l mt kim loi c tnh kh mnh, d b nhng e v chuyn thnh Al3+.
C. ng, Phng trnh: 2Al + 3H2SO4 Al2(SO4)3 + 3H2
D. Sai, Chiu gim dn dn in ca kim loi: Ag > Cu > Au > Al > Fe.
Cu 31: Chn A.
* Phn ng ca dung dch axit (cha ion H +) vi dung dch cha cc ion OH v AlO 2 (
[Al(OH) 4 ] )
u tin H+ trung ha OH nn lc u cha xut hin kt ta
H OH H 2O (1)
mol : b b
Sau mt thi gian, kt ta bt u xut hin v tng dn n cc i
H AlO2 H 2O Al(OH)3 (2)
mol : a a a
Cui cng th kt ta b ha tan dn cho n ht
3H Al(OH)3 Al3 3H 2O (3)
mol : 3a a
- S bin thin lng kt ta Al(OH) 3 theo lng H+ c biu din bng th sau:
- p dng vo bi ton trn nh sau:
nAl (OH)
3
nH
Bin son: NXT-diendanthpt.com
0 b b a b 4a 245
+ Ti v tr n H 0,8 mol c: n H n OH 0,8 mol b n Ba(OH) 2 0, 4 mol
+ Ti v tr n H 2,8 mol c:
4n AlO2 3n Al(OH)3 2,8 0,8 n AlO2 1, 4 mol a n Ba(AlO2 )2 0,7 mol
Vy a : b = 7 : 4
Cu 32: Chn A.

C12H 22O11 H 2O
H
HOCH 2[CHOH] 4 CHO HOCH 2[CHOH]3 COCH 2OH
saccarozo glucozo fructozo
0
HOCH 2[CHOH] 4 CHO 2AgNO3 3NH 3
t
HOCH 2[CHOH] 4 COONH 4 2Ag 2NH 4NO3
glucozo amoni gluconat
Cu 33: Chn B
V 2nFe nAgNO3 3nFe nn trong dung dch sau phn ng ch cha Fe(NO3)2 v Fe(NO3)3.
Cu 34: Chn C
T nhn to (t bn tng hp) l t c ngun gc t thin nhin c pha ch thm bng phng php
ha hc nh t visco, t xenlulz axetat
Cu 35: Chn B
0
- CH3CH(NH2)COOCH3 + NaOH
t
CH3CH(NH2)COONa + CH3OH (1)
0
- CH3CH(NH2)COONa + HCl d t
CH3CH(NH3Cl)COOH + NaCl (2)
Cu 36: Chn C.
- Khi t chy m gam X ta c h phng trnh sau :

BTKL
m X 44n CO2 18n H 2O 32n O2 12,32 (g)
n n H 2O
BT:O 2n CO2 n H 2O 2n O2 k X CO2 1 8 3CO 5CC
n O(trong X) 0, 014 mol nX
6
- Khi cho 24,64 gam X (tc l 0,028 mol X) tc dng vi dung dch Br 2 th : n Br2 5n X 0,14 mol
Cu 37: Chn C.
- Phng trnh xy ra:
(a) Mg + Fe2(SO4)3 MgSO4 + 2FeSO4 (1) Mg + FeSO4 MgSO4 + Fe (2)
+ Nu cho Mg tc dng vi Fe d th ch dng li phn ng (1) khi sn phm s khng c kim
3+
loi.
+ Nu cho Mg d tc dng vi Fe 3+ th xy ra c 2 phn ng (1) v (2) khi sn phm thu c c
cha kim loi.
o
(b) Cl2 + 2FeCl2
2FeCl3 t
(c) H2 + CuO Cu + H2O
2NaOH + H2 ; 2NaOH + CuSO 4
(d) 2Na + 2H2O Cu(OH)2 + Na2SO4
to pnc
(e) 2AgNO3 2Ag + 2NO2 + O2 (f) 2Al 2O3
4Al 3O2
Vy c 3 th nghim thu c kim loi l (c), (e), (f).
Cu 38: Chn B
Thi im Ti catot Ti anot
t (s) M 2
2e M 2H 2O
4e 4H O2
ne trao i = 0,14 mol 0,14mol 0,035mol
2t (s) M 2 2e M 2H 2O
4e 4H O2
ne trao i = 0,28 mol amol 2amol 0,28mol 0,07mol
2H 2O 2e 2OH H 2
2bmol bmol

- Ti thi im 2s (s), xt hn hp kh ta c :

BT:e
2nM 2 2nH 2 4nO2 2a 2b 0,28 a 0,0855
+
n
H2 0,1245 nO2 b 0,0545 b 0,0545
13,68
M MSO4 160 , suy ra M l Cu.
0,0855
- Ti thi im t (s) th nCu 2nO2 0,07mol mCu 4,48(g)
Cu 39: Chn C
A. Sai, Nc cng l nc cha nhiu ion Ca2+ v Mg2+
B. Sai, Phng php un nng ch c th lm mm c nc cng tm thi v trong nc cng tm
thi c cha cc ion Mg2+, Ca2+ v HCO3 khi un nng:
2HCO3 CO32 CO 2 H 2O khi Mg 2 ,Ca 2 CO32
o
t
MgCO3 ,CaCO3 (kt ta)
Lc b kt ta ta s thu c nc mm.
C. ng, Trong nc t nhin cha nhiu cc ion Ca2+, Mg2+ v HCO3 , Cl , SO 24 nn c c tnh
cng tm thi v tnh cng vnh cu.
D. Sai, Nc cng gy nhiu tr ngi vi i sng hng ngy v cho cc ngnh sn xut nh: lm
qun o mc nt, lm gim mi v thc n, ng cn lm tc ng dn nc, lm hng nhiu dung dch
pha ch nhng khng phi l tc nhn gy nhim ngun nc.
Cu 40: Chn A
NaOH
- Cho: (RCOO)3 C3H 5
C17 H 33COONa C17 H 35COONa C15H 31COONa C3H 5 (OH)3
triglyxerit X natri oleat natri stearat natri panmitat glyxerol
Vy cu to ca X l:
----------HT----------

TNH QUNG TR Mn: KHOA HC T NHIN HA HC
THPT LAO BO Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Kim loi no c tnh dn in tt nht trong cc kim loi sau?

A. Nhm. B. Bc. C. ng. D. Vng.
Cu 2: S electron lp ngoi cng ca cc nguyn t kim loi thuc nhm IIA l.
A. 4. B. 1. C. 2. D. 3.
Cu 3: Thuc th no sau y dng phn bit dung dch phenylamoni clorua v axit glutamic?
A. qu tm B. dung dch Br2 C. dung dch HCl D. dung dch NaOH
Cu 4: Dy cc cht u cho c phn ng thy phn l.
A. saccaroz, triolein, amiloz, xenluloz. B. amilopectin, xenluloz, glucoz, protein.
C. triolein, amiloz, fructoz, protein. D. amiloz, saccaroz, protein, fructoz.
Cu 5: Dy cc oxit no no sau y u b kh bi kh CO nhit cao?
A. Fe2O3, CuO, CaO. B. CuO, ZnO, MgO.
C. CuO, Al2O3, Cr2O3. D. CuO, PbO, Fe2O3.
Cu 6: Phn ng iu ch kim loi no sau y thuc phn ng thy luyn?
A. CuO + CO Cu + CO2 B. 2Al + 3CuO Al2O3 + 3Cu
1
C. Fe + CuSO4 FeSO4 + Cu D. CuSO4 + H2O Cu + O2 + H2SO4
2
Cu 7: Hai hp cht hu c no sau y l ng phn ca nhau?
A. amiloz v amilopectin. B. anilin v alanin.
C. vinyl axetat v metyl acrylat. D. etyl aminoaxetat v -aminopropionic.
Cu 8: Thy phn hon ton tripeptit X, thu c glyxin v alanin. S ng phn cu to ca X l.
A. 3 B. 4 C. 5 D. 6
Cu 9: Cho 200 ml dung dch FeCl 2 0,3M vo 250 ml dung dch AgNO 3 0,8M. Sau khi kt thc phn
ng thu c m gam kt ta. Gi tr m l.
Cu 10: Cho 4,725 gam bt Al vo dung dch HNO 3 long d, thu c dung dch X cha 37,275 gam
mui v V lt kh NO duy nht (ktc). Gi tr ca V l.
A. 7,168 lt B. 11,760 lt C. 3,584 lt D. 3,920 lt
Cu 11: Cho dy cc cht sau: anilin, saccaroz, amiloz, glucoz, triolein, tripanmitin, fructoz,
metyl fomat. S cht trong dy tc dng c vi nc Br 2 l.
A. 4 B. 5 C. 6 D. 3
Cu 12: Nhn nh no sau y l ng?
A. Metyl acrylat c tn ti ng phn hnh hc.
B. iu kin thng, anilin l cht lng, t tan trong nc nhng tan tt trong ancol etylic.
C. Tt c cc polime l nhng cht rn, u nng chy to thnh cht lng nht.
D. Monome l mt mc xch trong phn t polime.
Cu 13: t chy kim loi X trong oxi thu c oxit Y. Ha tan Y trong dung dch HCl long d, thu
c dung dch Z cha hai mui. Kim loi X l.
A. Mg B. Cr C. Fe D. Al
Cu 14: Nhn nh no sau y l sai?
A. Dng dung dch Na2CO3 lm mt tnh cng ca nc nc cng ton phn.
B. Na2CO3 l nguyn liu trong cng nghip sn xut thy tinh, x phng.
C. Dng dung dch Na2CO3 ty sch vt du m bm trn chi tit my.
D. Na2CO3 l nguyn liu chnh dng trong y hc, cng ngh thc phm, ch to nc gii kht.
Cu 15: t chy hon ton 2,04 gam este X n chc thu c 5,28 gam CO 2 v 1,08 gam H2O.
Cng thc phn t ca X l.
Cu 16: t chy hon ton 0,1 mol hn hp X cha trimetylamin v hexametyleniamin cn dng
0,715 mol O2, sn phm chy gm CO2, H2O v N2. Mt khc cho 24,54 gam X trn tc dng vi dung
dch HCl long d, thu c m gam mui. Gi tr ca m l.
Cu 17: Pht biu no sau y l sai?
A. CrO3 l oxit axit, tc dng vi nc to dung dch cha H 2CrO4 v H2Cr2O7.
B. Trong cc hp cht, crom c s oxi ha c trng l +2, +3 v +6.
C. Cr2O3 l oxit lng lnh, tc dng c vi dung dch NaOH long v dung dch HCl long.
D. t chy crom trong lng oxi d, thu c oxit crom (III).
Cu 18: Cho x mol bt Fe vo dung dch cha y mol FeCl 3 v z mol HCl, sau khi kt thc phn ng
thu c dung dch X v cn li t mol kim loi khng tan. Biu thc lin h x, y, z, t l.
A. 2x = y + z + t B. x = y + z t C. x = 3y + z 2t D. 2x = y + z + 2t
Cu 19: iu no sau y l sai khi ni v saccaroz v Gly-Val-Val?
A. u cho c phn ng thy phn. B. u ha tan c Cu(OH)2 iu kin
thng.
C. Trong phn t u cha lin kt glicozit. D. Trong phn t u cha 12 nguyn t cacbon.
Cu 20: un nng 8,55 gam este X vi dung dch KOH va , thu c ancol Y v 9,30 gam mui.
S ng phn ca X tha mn l.
A. 4 B. 2 C. 5 D. 3
A. Propan-2-amin l amin bc 1.
B. HOOC-[CH2]2-CH(NH2)-COOH c tn bn h thng l axit -aminoglutamic.
C. (CH3)2CH-NH-CH3 c tn thay th l N-meyl-propan-2-amin.
D. Triolein c cng thc phn t l C57H106O6.
Cu 22: Ln men m gam tinh bt thnh ancol etylic vi hiu sut ca c qu trnh l 75%. Lng CO 2
sinh ra c hp th hon ton vo dung dch Ca(OH) 2, thu c 60,0 gam kt ta v dung dch X.
tc dng ti a vi dung dch X cn dng dung dch cha 0,2 mol NaOH. Gi tr ca m l.
Cu 24: Cho CrO3 vo dung dch NaOH (dng d) thu c dung dch X. Cho dung dch H2SO4 d
vo X, thu c dung dch Y. Nhn nh no sau y l sai?
A. dung dch X c mu da cam.
B. dung dch Y c mu da cam.
C. dung dch X c mu vng.
D. dung dch Y oxi ha c Fe2+ trong dung dch thnh Fe3+.
Cu 25: Cho 23,44 gam hn hp gm phenyl axetat v etyl benzoat tc dng va vi 200 ml dung
dch NaOH 1M, c cn dung dch sau phn ng thu c m gam rn khan. Gi tr m l.
Cu 26: Nung nng 19,52 gam hn hp gm Al v Cr 2O3 trong iu kin khng c khng kh, sau mt
thi gian, thu c hn hp rn X. Ha tan ht X cn dng 600 ml dung dch HCl 1,6M thu c 0,18
mol kh H2 v dung dch Y. Cho dung dch NaOH d vo Y, thu c x gam kt ta. Gi tr ca x l.
Cu 27: Pht biu no sau y l khng ng khi ni v xenluloz?

A. Mi mc xch C6H10O5 c ba nhm OH t do, nn xenluloz c cng thc cu to l
[C6H7O2(OH)3]n.
B. Xenluloz tc dng c vi HNO 3 c trong H2SO4 c thu c xenluloz trinitrat c dng
lm thuc sng.
C. Xenluloz c cu to bi cc gc -glucoz lin kt vi nhau bng lin kt -1,4-glicozit.
D. Phn t xenluloz khng phn nhnh m xon li thnh hnh l xo.
A. 5,92 B. 4,68 C. 2,26 D. 3,46
Cu 32: Cho hn hp X gm 0,56 gam Fe v 0,12 gam Mg tc dng vi 250 ml dung dch CuSO 4.
Sau khi cc phn ng xy ra hon ton, thu c 0,92 gam kim loi. Nng mol/l ca dung dch
CuSO4 l:
A. 0,02M B. 0,04M C. 0,05M D. 0,10M
axit, tng s nhm CO-NH- trong 2 phn t l 5 ) vi t l mol X : Y = 1 : 3. Khi thy phn hon
ton m gam M thu c 81 gam glyxin v 42,72 gam alanin. Gi tr ca m l:
A. 116,28 B. 109,5 C. 104,28 D. 110,28
(a) Nguyn tc sn xut gang l oxi ha cc oxit st bng kh CO nhit cao.
(b) Cu v Fe2O3 t l mol 1 : 1 tan hon ton trong dung dch HCl d.
(c) Trong cc kim loi, Crom l kim loi cng nht, cn xesi mm nht.
(d) Al(OH)3, Cr(OH)3, Cr2O3 u tan trong dung dch NaOH long.
(e) Thch cao sng c s dng b bt trong y hc.
(f) Sr, Na, Ba v Be u tc dng mnh vi H 2O nhit thng.
S pht biu ng l
A. 3. B. 4. C. 5. D. 6.
Cu 37: Ha tan hon ton 30 gam hn hp X gm Mg, MgO, Mg(NO3)2 trong dung dch H2SO4. Sau
phn ng thu c dung dch Y ch cha mt mui sunfat v 4,48 lt NO (ktc, sn phm kh duy nht).
S mol H2SO4 phn ng l
Cu 38: Ha tan hon ton 1,28 gam Cu vo dung dch cha 7,56 gam HNO 3 thu c dung dch X v
V lt hn hp kh gm NO v NO 2 (ktc). Cho X tc dng hon ton vi 105 ml dung dch KOH 1M,
sau lc b kt ta c dung dch Y. C cn Y c cht rn Z. Nung Z n khi lng khng i,
thu c 8,78 gam cht rn. Gi tr V l

A. 0,336. B. 0,448. C. 0,560. D. 0,672.
Cu 39: Cho dy cc cht: m-CH3COOC6H4CH3, p-HOOCC6H4OH; m-CH3COOC6H4OH,
ClH3NCH2COONH4, p-C6H4(OH)2, ClH3NCH2COOH, p-HOC6H4CH2OH, ClH3NCH2COOCH3,
CH3NH3NO3. S cht trong dy m 1 mol cht phn ng ti a c vi 2 mol NaOH l
A. 3. B. 6. C. 5. D. 4.
Cu 40: Cho 14,58 gam hn hp X gm cht bo Y v axit Z (trong Y c to t glixerol v axit
Z) tc dng va vi 0,05 mol NaOH, thu c 0,92 gam glixerol. Khi lng phn t ca axit Z l
A. 284 vC. B. 282 vC. C. 280 vC. D. 256 vC.
----------HT----------

PHN TCH HNG DN GII
THI TH THPT LAO BO QUNG TR LN 1
Cu 1: Chn B
- Th t kh nng dn in gim dn: Ag > Cu > Au > Al.
Cu 2: Chn C
- Nhm IIA gm cc kim loi kim th c cu hnh lp ngoi cng l ns 2 (c ti a 2e).
Cu 3: Chn D
Thuc th qu tm dung dch Br2 dung dch HCl dung dch NaOH
Tch lp (do to
C6H5NH3Cl
Khng hin Tan to dung thnh anilin t tan)
Ha
tng dch ng nht To dung dch ng
HOOC-(CH2)2CH(NH2)-COOH
nht
Cu 4: Chn A
- Cc cht tham gia phn ng thy phn l: saccaroz, triolein, amiloz, xenluloz, amylopectin,
protein.
Cu 5: Chn D
- Dng CO nhit cao c th kh c cc oxit kim loi ng sau Al trong dy in ha.
Vy cc oxit tha mn l: Fe 2O3, CuO, CuO, ZnO, Cr2O3, PbO.
Cu 6: Chn C
- Phng php thy luyn cn gi l phng php t, c dng iu ch nhng kim loi c
hot ng ha hc thp nh Au, Ag, Hg, Cu. C s ca phng php ny l dng nhng dung dch thch
hp nh dung dch H2SO4, NaOH, NaCN ha tan kim loi hoc hp cht ca kim loi v tch ra
khi phn khng tan c trong qungSau cc ion kim loi trung dung dch c kh bng kim loi
c tnh kh mnh hn nh Fe, Zn
- Phng trnh phn ng: Fe + CuSO4
Cu + FeSO4
Cu 7: Chn C
- ng phn l nhng cht c cng cng thc phn t nhng khc nhau v cng thc cu to.
A. Sai, Amiloz v amilopectin u l thnh phn ca tinh bt c cng thc l (C 6H10O5)n nhng phn
t khi ca amylopectin ln hn nhiu so vi amiloz.
B. Sai, Anilin (C6H5NH2) v alanin (CH3CH(NH2)COOH) c cng thc phn t khc nhau.
C. ng, Vinyl axetat (CH3COOCH=CH2) v metyl acrylat (CH2=CHCOOCH3) c cng cng thc
phn t.
D. Sai, Etyl aminoaxetat (CH3COOC2H5) v -aminopropionic (CH3CH(NH2)COOH) c cng thc
phn t khc nhau.
Cu 8: Chn D
- C 6 ng phn ca X l: GGA ; GAG ; AGG ; AGA ; AAG ; GAA.
Cu 9: Chn B
- Phng trnh: FeCl2 + 3AgNO3 Fe(NO3)3 + 2AgCl + Ag
mol: 0,06 0,2 0,12 0,06
m 108n Ag 143,5n AgCl 23, 7 (g)

Cu 10: Chn D
BT: e
3n NO 8n NH4 3n Al 0,525 m mAl 18n NH4 62.(3n NO 8n NH4 ) 37, 275 n NH4 0
Vy trong dung dch X khng cha NH 4 VNO 22, 4.n Al 3,92 (l)
Cu 11: Chn A
Nhng cht tc dng vi dung dch brom gm:
- Hidrocacbon: Xiclopropan (C3H6), Anken, Ankin, Ankadien, Stiren.
- Cc hp cht hu c c gc hidrocacbon khng no.
- Andehit (-CHO)
- Cc hp cht c nhm chc andehit: Axit fomic, Este ca axit fomic, Glucoz, Mantoz
- Phenol (C6H5-OH) v anilin (C 6H5-NH2) phn ng th vng thm.
Vy c 4 cht tha mn l: metyl fomat, anilin, glucoz, triolein.
Cu 12: Chn B
A. Sai, Cu to ca metyl acrylat: CH 2=CH-COO-CH3 khng c tn ti ng phn hnh hc.
B. ng, iu kin thng, anilin l cht lng, t tan trong nc nhng tan tt trong ancol etylic.
C. Sai, Hu ht polime l cht rn, khng bay hi, khng c nhit nng chy xc nh.
D. Sai, Cc phn t to nn tng mt xch ca polime c gi l monome.
Cu 13: Chn C
O HCl
A. Qu trnh phn ng: Mg
2
MgO MgCl2
O HCl
B. Qu trnh phn ng: Cr
2
Cr2O3 CrCl3
O HCl
C. Qu trnh phn ng: Fe
2
Fe3O4 FeCl2 , FeCl3
O HCl
D. Qu trnh phn ng: Al
2
Al 2O3 AlCl3
Cu 14: Chn D
Nguyn tc lm mm nc cng l lm gim nng ca Ca2+ v Mg2+ trong nc cng. V vy
Na2CO3 c dng lm mm nc cng tm thi, vnh cu v ton phn:
Mg 2 CO32
ng dng ca Na2CO3:
- Nguyn liu trong cng nghip sn xut thy tinh, x phng , giy dt v iu ch mui khc.
- Ty sch vt m bm trn chi tit my trc khi sn , trng kim loi.
- Cng nghip sn xut cht ty ra.
Cu 15: Chn A
BTKL m m H 2O m X BT: O 2n n H 2O 2n O 2
n O 2 CO 2 0,135 mol n X CO 2 0, 015 mol
32 2
n
C X CO 2 8 : X l C8H8O 2
nX
Cu 16: Chn D
(CH3 )3 N (A) 5, 25O 2 n A n B 0,1 n A 0, 06
- t chy X
H 2 N(CH 2 ) 6 NH 2 (B) 10O 2 5, 25n A 10n B 0, 715 n B 0, 04
- Trong 0,1 mol X th c 8,18 gam trong 24,54 gam X th c 0,18 mol A v 0,12 mol B.

BTKL
n HCl 0,18 2.0,12 0, 42 mol m 24,54 0, 42.36,5 39,87 (g)
Cu 17: Chn C
A. ng, CrO3 l oxit axit khi tc dng vi nc to dung dch cha 2 axit H 2CrO4 v H2Cr2O7.
B. ng, Trong cc hp cht, crom c s oxi ha c trng l +2, +3 v +6.
C. Sai, Cr2O3 l oxit lng lnh, tc dng c vi dung dch HCl long nhng khng tan trong NaOH
long, ch tc dng vi NaOH c nng hoc nng chy.
D. ng, t chy crom trong lng oxi d, thu c Cr2O3.
Cu 18: Chn D
- V sau phn ng cn kim loi d nn Fe ch b oxi ha ln Fe 2+.
BT: e
2n Fe n FeCl3 n HCl 2.(x t) y z 2x y z 2t
Cu 19: Chn C
H 2O
C12 H 22O11 C6H12O 6 C6 H12O6
A. ng, Thy phn:
2H 2O
Gly Val Val Gly 2Val

B. ng, Saccaroz ha tan Cu(OH) 2 iu kin thng to dung dch mu xanh lam trong khi
tripeptit Gly-Val-Val ha tan Cu(OH)2 iu kin thng to dung dch mu tm.
C. Sai, Trong phn t saccaroz cha cc lin kt glicozit trong khi tripeptit Gly-Val-Val cha cc lin
kt peptit.
D. ng, Trong phn t ca saccaroz (C12H22O11) v Gly-Val-Val (C12H23O4N3) u cha 12 nguyn
t cacbon.
Cu 20: Chn A
- t cng thc tng qut ca este X l: RCOOR
- Ta c: neste = nmui m meste < mmui R + 44 + R < R+ 44 + 39 R < 39.
BTKL
+ Vi R = 29 Y l C2H5OH 56n KOH 8,55 46n Y 9,3 n Y n KOH 0,075 mol
8,55
MX 114 : X l C3H5COOC2H5 c 4 ng phn.
0, 075
BTKL
+ Vi R = 15 Y l CH3OH 56n KOH 8,55 32n Y 9,3 n Y n KOH 0,03125 mol
8,55
MX 273, 6 : loi.
0, 03125
Cu 21: Chn A
A. ng, Cu to ca propan-2-amin: CH3-CH(NH2)-CH3 y l amin bc 1.
B. Sai, HOOC-[CH2]2-CH(NH2)-COOH c tn bn h thng l axit -aminoglutaric.
C. Sai, (CH3)2CH-NH-CH3 c tn thay th l N-metylpropan-2-amin.
Lu : Khi gi tn mt hp cht hu c gia ch v ch s khng c du - ; gia s v ch s c
du - ; gia s v s s c du , .
D. Sai, Triolein c cng thc phn t l C 57H104O6.
Cu 22: Chn B
- Cho CO2 vo dung dch Ca(OH)2
CaCO3: 0,6 mol v Ca(HCO3)2.
- Cho NaOH tc dng ti a th: Ca(HCO3)2 + 2NaOH
CaCO3 + Na2CO3 + 2H2O
0,1 0,2

n CO 2 8
BT: C
n CO2 n CaCO3 2n Ca(HCO3 ) 2 0,8 mol ntinh bt = mol mtinh bt = 86, 4 (g)
2H% 15
Cu 23: Chn C
- Cc phn ng xy ra:
2BaCO3 (Z) + 2H2O
BaCO3 (Z) + 2NaCl
BaCO3 (Z) + H2SO4
BaSO4 + CO2 + H2O
Cu 24: Chn A
- Ta c cn bng sau: ,
Cr2O72- + H2O
2CrO42- + 2H+

mu vng mu da cam
CrO3 + 2NaOHd
Na2CrO4 + H2O (dung dch X c mu vng)
2Na2CrO4 + H2SO4 d
Na2Cr2O7 + Na2SO4 + H2O (dung dch Y c mu da cam)
Cu 25: Chn A
CH 3COOC6 H 5 : x mol 2x y n NaOH 0, 2 x 0, 04
- t:
C 6 H 5 COOC 2 H 5 : y mol 136x 150y 23, 44 y 0,12
CH 3COONa : 0, 04 mol C6H 5ONa : 0, 04 mol
- Hn hp rn khan gm: mrn = 25, 2 (g)
C6 H 5COONa : 0,12 mol
Cu 26: Chn B
H 2 :0,18mol
t0 HCl
Al,Cr2O3 Al,Al 2O3,Cr,Cr2O3
Al 3 ,Cr 3 ,Cr 2 ,Cl
NaOH
NaAlO2,NaCrO2 Cr(OH) 2
19,52(g) 19,52 (g) rn X dung dch Y dung dch sau p x (g)
- Khi cho hn hp rn X tc dng vi dung dch cha 0,96 mol HCl th :
BT:H nHCl 2nH2 nH O
nH2O 0,3mol nCr2O3 2 0,1mol
2 3
mrn 152nCr2O3
+ Xt hn hp rn ban u ta c: nAl 0,16mol
27
BT:e 3nAl 2nH2
- Xt qu trnh nhit nhm ta c: nCr2O3(p ) 0,06mol
2
- Khi cho dung dch Y tc dng vi NaOH d th: m 86nCr(OH)2 2.86.nCr2O3 (p ) 10,32(g)
Cu 27: Chn D
A. ng, mi mc xch C6H10O5 c ba nhm OH t do, nn xenluloz c cng thc cu to l
[C6H7O2(OH)3]n.
B. ng, C6H7O2(OH)3 + 3HNO3
H 2SO4
C6H7O2(ONO2)3 (xenluloz trinitrat) + 3H 2O

Lu : Xenluloz trinitrat cn c gi l thuc n khng khi.
C. ng, Xenluloz c cu to bi cc gc -glucoz lin kt vi nhau bng lin kt -1,4-
glicozit.
D. Sai, phn t xenluloz c mch khng phn nhnh v khng xon. Xenluloz l cht rn mu
trng hnh si, khng mu khng mi khng v, khng tan trong nc ngay c khi un nng, khng tan
trong cc dung mi hu c k c cc dung mi thng thng nh ete, benzen.
Cu 28: Chn D.
xt,p,t o
Cu 29: Chn B.
Cu 30: Chn B.
Cu 31: Chn D.
t0
amol amol amol amol
0
t
bmol 2bmol bmol
a 2b 0,05 a 0,01mol
a 0,01 b 0,02mol
Cu 32: Chn B.
TGKL
BT:e

Cu 33: Chn A.
m mamin
nHCl mui
BTKL
36,5
Cu 35: Chn C.
XY3 3H 2O
nGly 1,08 9
nAla 0,48 4
(52).nX 9k 4k (52).nZ

mM 57nC2H 3ON 14nCH 2 18nH 2O 104,28(g)
Cu 36: Chn A.
C 3 pht biu ng l (b), (c) v (e).

(a) Sai, nguyn tc sn xut gang l kh cc oxit st bng kh CO nhit cao. Nguyn tc sn
xut thp l oxi ha cc tp cht trong gang nh cacbon v lu hunh thnh nhng oxit.
2FeCl 3 v 2FeCl 3 Cu
(b) ng, ban u Fe2O3 HCl 2FeCl 2 CuCl 2 .
amol 2amol 2amol amol
(c) ng, trong cc kim loi, crom l kim loi cng nht, cn xesi mm nht.
(d) Sai, Cr2O3 tan trong dung dch kim c, nng.
(e) ng, Thch cao nung CaSO4.H2O c dng b bt, c tng, c cc mu chi tit trong
thit k ni tht.
(f) Sai, Be khng tc dng vi nc mi iu kin nhit .
Cu 37: Chn D.
- Khi cho 30 gam X tc dng vi H2SO4 ta c h sau :
24nMg 40nMgO 148nMg(NO3 )2 mX 24nMg 40nMgO 148nMg(NO3 )2 30 nMg 0,3mol
BT:e
2nMg 3nNO 2nMg 0,6 nMgO 0,2mol
BT:N 2n n
2nMg(NO3 )2 nNO Mg(NO3 )2 0,2 Mg(NO3 )2 0,1mol
nH 2SO4 nMgSO4 nMg nMgO nMg(NO3 )2 0,6mol
Cu 38: Chn B.
- Cht rn Z gm KNO3 v KOH(d). Khi nung Z ta thu c KNO2 v KOH(d). Theo ta c :
85nKNO2 56nKOH mrn
85nKNO2 56nKOH 8,78
nKNO2 0,1mol
BT:K BT:K

nKNO2 nKOH nKOH(ban u)
nKNO2 nKOH 0,105 nKOH(d ) 0,005mol
BT:N
nNO2 nNO nHNO3 nKNO2 0,02mol VNO,NO2 0,448(l)
Cu 39: Chn B.
- C 6 cht trong dy m 1 mol cht phn ng ti a c vi 2 mol NaOH l :
m-CH3COOC6H4CH3, p-HOOCC6H4OH, ClH3NCH2COONH4, p-C6H4(OH)2, ClH3NCH2COOH v
ClH3NCH2COOCH3.
Cu 40: Chn A.
- Khi cho 14,85 gam X tc dng vi 0,05 mol NaOH ta c :
nY nC3H5(OH)3 0,01mol nZ nNaOH 3nC3H5(OH)3 0,02mol nH2O nZ 0,02mol
BTKL
mRCOONa(Z) mX 40nNaOH 92nC3H5(OH)3 18nH2O 15,3(g)
15,3
M RCOONa 306 M RCOOH 284
0,05

TNH THI BNH Mn: KHOA HC T NHIN HA HC
THPT PH DC Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Phn ng no sau y l sai

A. Cr(OH)3 + NaOH
NaCrO2 + 2H2O
B. 3Zn + 2CrCl3
3ZnCl2 + 2Cr
C. 2Cr + 3Cl2
2CrCl3
D. 2Na2CrO4 + H2SO4 Na2Cr2O7 + Na2SO4 + H2O
Cu 2: Dung dch anilin (C6H5NH2) khng phn ng c vi cht no sau y
A. NaOH B. Br2 C. HCl D. HCOOH
0 0
t
t

0 0

Cu 6: Mt phn t xenluloz c phn t khi l 15.106, bit rng chiu di mi mc xch C6H10O5
khong 5.10-7 (mm). Chiu di ca mch xenluloz ny gn ng l
A. 3,0.10-2 (mm) B. 4,5.10-2 (mm) C. 4,5.10-1 (mm) D. 3,0.10-1 (mm)
Cu 7: t chy 0,01 mol este X n chc bng lng oxi va , thu c 448 ml kh CO2 (ktc). Mt
khc un nng 6,0 gam X vi dung dch KOH va , thu c lng mui l :
Cu 10: Ha tan ht 3,24 gam bt Al trong dung dch HNO3 d, thu c 0,02 mol kh X duy nht v
dung dch Y cha 27,56 gam mui. Kh X l
A. NO2 B. N2O C. N2 D. NO

A. 860 B. 862 C. 884 D. 886
Cu 12: phn bit cc dung dch ring bit: anilin, glucoz v alanin, ta dng dung dch no sau y
A. NaOH B. AgNO3/NH3 C. HCl D. Br2
kt ta. Gi tr m l
Cu 14: Hn hp E cha ba peptit u mch h gm peptit X (C4H8O3N2), peptit Y (C7HxOyNz) v
peptit Z (C11HnOmNt). un nng 28,42 gam E vi dung dch NaOH va , thu c hn hp T gm 3
mui ca glyxin, alanin v valin. t chy ton b T cn dng 1,155 mol O2, thu c CO2, H2O, N2 v
23,32 gam Na2CO3. Phn trm khi lng ca X trong hn hp E l
A. 4,64% B. 6,97% C. 9,29% D. 13,93%
Cu 15: t chy hon ton 14,24 gam hn hp X cha 2 este u no, n chc, mch h thu c CO2
v H2O c tng khi lng l 34,72 gam. Mt khc un nng 14,24 gam X vi dung dch NaOH va ,
thu c hn hp Y cha 2 ancol k tip v hn hp Z cha 2 mui ca 2 axit cacboxylic k tip, trong
c a gam mui A v b gam mui B (MA < MB). T l gn nht ca a : b l
A. 0,6 B. 1,25 C. 1,20 D. 1,50
[C6H7O2(OH)3]n.
lm thuc sng.
to ra kh NO (sn phm kh duy nht ca N +5). Gi tr m l.
Cu 21: Hp th ht 0,1 mol CO2 vo dung dch c cha 0,08 mol NaOH v 0,1 mol Na 2CO3, thu
c dung dch X. Nh t t dung dch HCl vo dung dch X n khi thot ra 0,08 mol kh CO 2 th
thy ht x mol HCl. Gi tr x l
A. 0,16. B. 0,15. C. 0,18. D. 0,17.
Cu 22: Nung hn hp gm m gam Al v 0,04 mol Cr2O3 mt thi gian, thu c hn hp rn X. Ha
tan hon ton X trong dung dch HCl c, nng, va (khng c khng kh) thu c 0,1 mol kh H 2
v dung dch Y. Y phn ng ti a vi 0,56 mol NaOH (bit cc phn ng xy ra trong iu kin khng
c khng kh). Gi tr m l

A. 1,62. B. 2,16. C. 2,43. D. 3,24.
Cu 23: un nng 26,5 gam hn hp X cha mt axit khng no (c 1 lin kt i C=C trong phn t)
n chc, mch h v mt ancol no n chc, mch h vi H 2SO4 c lm xc tc thu c m gam
hn hp Y gm este, axit v ancol. t chy hon ton m gam Y cn dng 1,65 mol O 2, thu c 55
gam CO2. Cho m gam Y tc dng vi 0,2 mol NaOH ri c cn dung dch c bao nhiu gam cht rn
khan?
A. 16,1. B. 18,2. C. 20,3. D. 18,5.
Cu 24: S ipeptit ti a c th to ra t hn hp gm alanin v glyxin l
A. 2. B. 1. C. 3. D. 4.
Cu 25: Ha tan hon ton 5,4 gam Al bng dung dch H 2SO4 long d, thu c V lt kh H 2 ( iu
kin tiu chun). Gi tr ca V l
A. 3,36. B. 2,24. C. 6,72. D. 4,48.
Cu 26: Cho cc dung dch : glucoz, glixerol, fomandehit, etanol. Thuc th duy nht c th dng
phn bit c dng c 4 dung dch l
A. Dung dch AgNO3/NH3. B. Nc Br2.
C. Cu(OH)2 D. Na kim loi.
Cu 27: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l
A. protit lun cha chc hiroxyl. B. protit lun l cht hu c no.
C. protit lun cha nit. D. protit c khi lng phn t ln hn.
Cu 28: Cho cc cu hnh electron nguyn t sau :
(a) 1s22s22p63s1 (b) 1s22s22p3
(c) 1s22s22p63s23p6 (d) 1s22s22p63s23p63d64s2
C bao nhiu cu hnh electron l ca nguyn t kim loi ?
A. 1 B. 4 C. 3 D. 2
Cu 29: Kim loi c nhng tnh cht vt l chung no sau y :
A. Tnh do, tnh dn in, tnh cng.
B. Tnh dn in, tnh dn nhit, tnh do, c nh kim.
C. Tnh do, tnh dn in, c nhit nng chy cao.
D. C nh kim, tnh dn in, c khi lng ring nh.
Cu 30: Este no n chc c to thnh t axit n n chc mch h v ancol no n chc mch
h c cng thc phn t l :
A. CnH2nO2 (n 2) B. CnH2nO2 (n 3)
C. CnH2n+2O2 (n 2) D. CnH2n+2O2 (n 4)
Cu 31: Hn hp X gm metyl fomat, anehit acrylic v metyl acrylat. t chy hon ton m gam X
ri hp th ht sn phm chy vo dung dch Ca(OH) 2 d, thu c 9 gam kt ta v khi lng
dung dch gim 3,78 gam. Gi tr ca m l :
A. 1,95 B. 1,54 C. 1,22 D. 2,02
Cu 32: Poli(vinyl clorua) c iu ch t kh thin nhin (cha 95% metan v th tch) theo s
chuyn ho v hiu sut (H) nh sau :
H 15% H 95% H 90%
Metan Axetilen Vinyl clorua Poli(vinyl clorua).
Th tch kh thin nhin (ktc) cn iu ch c 1 tn PVC l :
A. 5589,08 m3 B. 1470,81 m3 C. 5883,25 m3 D. 3883,24 m3
A. 66,98 B. 39,4 C. 47,28 D. 59,1
A. 3 B. 2 C. 4 D. 5
A. 16,6 B. 18,85 C. 17,25 D. 16,9
Cu 36: Chia 2m gam hn hp X gm 2 kim loi c ha tr khng i thnh 2 phn bng nhau. Cho
phn mt tan ht trong dung dch HCl d thu c 2,688 lt H 2 (kc). Nung nng phn 2 trong oxi d
thu c 4,26 gam hn hp oxit. Gi tr ca m l :
A. 4,68 gam B. 1.17 gam C. 3,51 gam D. 2,34 gam .
Cu 37 : Cu hnh electron ca nguyn t Cu (Z=29) dng c bn l :
A.1s22s22p63s23p64s13d10. B. 1s22s22p63s23p63d104s1.
C. 1s22s22p63s23p63d94s2. D. 1s22s22p63s23p64s23d9.
Cu 38 : Dy gm cc oxit u b Al kh nhit cao l :
A. PbO, K2O, SnO. B. FeO, MgO, CuO. C. Fe3O4, SnO, CaO. D. FeO, CuO, Cr2O3
Cu 39 : Cht X c cng thc phn t C 4H9O2N. Bit :
X + NaOH Y + CH4O Y + HCl d Z + NaCl
Cng thc cu to thu gn ca X v Z c th ln lt l :
A. CH3CH(NH3)COOCH3 v CH3CH(NH3Cl)COOH.
B. CH3CH2(NH2)COOCH3 v CH3CH(NH3Cl)COOH.
C. H2NCH2CH2COOC2H3 v CH3CH(NH3Cl)COOH.
D. H2NCH2CH2COOC2H5 v ClH3NCH2COOH.
Cu 40: Vt liu polime no sau y c cha nguyn t nit ?
A. Nha poli (vinyl clorua) B. T visco. C. T nilon-6,6. D. Cao su buna.
----------HT----------

PHN TCH HNG DN GII
THI TH THPT PH DC THI BNH LN 1
Cu 1: Chn B.
PT phn ng : Zn + 2CrCl3 2ZnCl2 + CrCl2.
Cu 2: Chn A.
B. + 3Br2 + 3HBr C. C6H5NH2 + HCl C6H5NH3Cl

D. C6H5NH2 + HCOOH C6H5NH3OOCH
Cu 3: Chn D
- Cc phn ng xy ra:
0
t
HCOONa + CH3CH2CHO
0
t
HCOONa + CH3COCH3
0
t
0
Cu 4: Chn D
Cu 5: Chn C
B. Sai, Phng php un nng ch c th lm mm c nc cng tm thi v trong nc cng tm
thi c cha cc ion Mg2+, Ca2+ v HCO3 khi un nng:
o
t
D. Sai, Nc cng gy nhiu tr ngi vi i sng hng ngy v cho cc ngnh sn xut nh: lm
qun o mc nt, lm gim mi v thc n, ng cn lm tc ng dn nc, lm hng nhiu dung dch
pha ch nhng khng phi l tc nhn gy nhim ngun nc.
Cu 6: Chn C
M mch xenlulz
nmc xch 92592 l mch xenlulz nmc xchdmc xch 0,046(mm) 4,5.102 (mm)
162
Cu 7: Chn D
n CO2
- Ta c: C X 2 : X l C2H4O2 c cng thc cu to: HCOOCH3
nX
- Khi cho 0,1 mol X tc dng vi KOH thu c mui l HCOOK: 0,1 mol mmui = 8, 4 (g)
Cu 8: Chn B
V 2nFe nAgNO3 3nFe nn trong dung dch sau phn ng ch cha Fe(NO3)2 v Fe(NO3)3.
Cu 9: Chn D
Al(OH)3 NaOH
Na[Al(OH) 4 ]
C. ng, Phng trnh: 2Al + 3H2SO4
Al2(SO4)3 + 3H2

Cu 10: Chn B
m Y 213n Al(NO3 )3
BT:Al
n Al(NO3 )3 n Al 0,12 n NH4 NO3 0, 025mol
80
Go a l s e nhn ca X BT:e
0,02a 3nAl 8nNH4NO3 0,16 a 8.Vy X l N2O.
Cu 11: Chn A
NaOH
- Cho: (RCOO)3 C3H 5 C17 H 33COONa C17 H 35COONa C15H 31COONa C3H 5 (OH)3
Vy cu to ca X l:
Cu 12: Chn D
Anilin GlucOz Alanin
Br2 Mt mu dung dch Mt mu dung dch Khng hin tng
brom v c kt ta trng brom
Cu 13: Chn A
0,06 mol 0,12 mol
H O AgNO
2
dd Y
3
AgCl, Ag
16,56 (g ) X m (g)
BT: Cl
- Kt ta gm: m 40,92 (g)
BT: e

Cu 14: Chn A
4
- Ta c BT:Na
n AlaNa, GlyNa, ValNa 2n Na 2CO 3 0, 44 m n Ala, Gly,Val (1,5n CO 2 n O 2 ) n CO 2 0,99
3
- Quy i hn hp E thnh C2H3ON, CH2 v H2O th :
57nC2H3ON 14nCH 2 18nH 2O 28,42 nC2H 3ON 0,44
BT:C nGly,Ala,Val
2nC2H3ON nCH 2 nCO2 0,99 nCH 2 3nVal nAla 0,11 nmc xch 4,4
2,25n n X n Y n Z
C2H 3ON 1,5nCH 2 nO2 1,155 nH 2O nX nY nZ 0,1
Trong E c cha peptit c s mc xch ln 4,4 (5, 6 hoc 7). Vy Z l pentapeptit (Gly)4Ala, X l
ipeptit (Gly)2 v Y l ipeptit AlaVal (khng th l tripeptit (Gly)2Ala v khi thy phn hn hp E s
khng thu c mui ca Val).

BT:C
4n X 7n Y 11n Z n CO2 0,99 n X 0, 01
0, 01.132
Ta c : 2n X 2n Y 5n Z 2n NaOH 0, 44 n Y 0, 01 %m X .100 4, 64
132n 174n 317n 28, 42 28, 42
X Y Z n Z 0, 08
Cu 15: Chn B
- Khi t X cha 2 este no, n chc, mch h th ta lun c: n CO2 n H 2O 0,56 mol
BTKL m CO 2 H 2O m X BT: O 2n n H 2O 2n O 2
n O 2 0, 64 mol n X CO 2 0, 2 mol
32 2

0,56
- Ta c: C X 2,8 . V khi cho X tc dng vi NaOH thu c 2 ancol k tip v 2 mui ca 2 axit
0, 2
HCOOCH3 : x mol x y 0, 2 x 0,12
cacboxylic k tip nn 2 este trong X ln lt l
CH 3COOC 2 H5 : y mol 2x 4y 0,56 y 0, 08
- Hn hp mui Z gm HCOONa (A): 0,12 mol v CH3COONa (B): 0,08 mol a : b 1, 243
Cu 16: Chn A
- Ta c cn bng sau: ,
Cr2O72- + H2O
2CrO42- + 2H+

mu vng mu da cam
CrO3 + 2NaOHd
2Na2CrO4 + H2SO4 d Na2Cr2O7 + Na2SO4 + H2O (dung dch Y c mu da cam)
Cu 17: Chn A
- t:
C6 H 5COOC 2 H 5 : y mol 136x 150y 23, 44 y 0,12
CH 3COONa : 0, 04 mol C6H 5ONa : 0, 04 mol
Cu 18: Chn B
H 2 :0,18mol
t0 HCl
NaOH
BT:H nHCl 2nH2 nH O
2 3
mrn 152nCr2O3
27
BT:e 3nAl 2nH2
2
Cu 19: Chn D
[C6H7O2(OH)3]n.
B. ng, C6H7O2(OH)3 + 3HNO3 H 2SO4
glicozit.
Cu 20: Chn B
It
96500
Ti catot Ti anot
Cu 2+
+ 2e Cu 2Cl -
Cl2 + 2e

2H2O + 2e 2OH - + H2 H2O 4H+ + O2 + 4e
mol

BT:e

71x 32y 5,47 y 0,06mol
3Fe 8H 2NO3
3Fe2 2NO 4H 2O
0,075mol 0,2mol
mFe bha tan 0,075.56 4,2(g)

Cu 21: Chn A.
- Dung X thu c cha cc ion sau : HCO 3-, CO32- v Na+. Xt dung dch X ta c :
nHCO3 2nCO32 nNa nHCO3 2nCO32 0,28 nHCO3 0,12mol
BTDT
BT:C
n n 2 nCO2 nNa2CO3
nHCO3 nCO32 0,2 nCO32 0,08mol

HCO3 CO3
(Vi nNa nNaOH 2nNa2CO3 0,28mol )

- Cho HCl tc dng vi dung dch Y th : nH nCO32 nCO2 0,08 0,08 0,16mol VHCl 0,16(l)
Cu 22: Chn D.
- Khi cho hn hp rn X tc dng vi HCl th : nHCl 2nH2 2nO(trong X) 2.0,1 2.0,04.3 0,44mol
- Khi cho dung dch Y tc dng vi 0,56 mol NaOH th dung dch thu c gm NaCl v NaAlO 2. Khi
ta c : nNaCl nHCl 0,44mol nNaAlO2 nNaOH nNaCl 0,12mol mAl 0,12.27 3,24(g)
Cu 23: Chn C.
- Nhn thy rng lng oxi dng t hn hp Y bng vi lng oxi dng t X.
- Gi s t 26,5 gam hn hp X th s mol O 2 phn ng l 1,65 mol v lng CO2 to thnh l 1,25
mol. Khi ta c :
1,5nCO2 nO2 m 32nO2 44nCO2
naxit 0,15mol v
BTKL
nH2O X 1,35mol
1,5 18
- p dng bt bo ha ta c : nCO2 nH2O naxit nancol nancol naxit (nCO2 nH2O ) 0,25mol
- p dng bt bo ha ta c :
BT:C
0,15.n 0,25m nCO2 1,25 n 5 v m=2
(Vi n v m ln lt l s nguyn t C trong axit v ancol)
Vy trong X cha C4H7COOH (0,15 mol) v C 2H5OH (0,25 mol).
- Gi s cho hn hp X tc dng vi 0,2 mol NaOH, khi ta c :
nC4H 7COONa 0,15mol v nNaOH 0,05mol m mui 122nC4H 7COONa 40n NaOH 20,3(g)
Cu 24: Chn D.
C 4 i peptit ti a c to ra t hn hp gm glyxin v alanin l : Gly Gly, Ala Ala, Ala Gly
v Gly Ala.
Cu 25: Chn C.
3n
BT:e
nH 2 Al 0,3mol VH 2 6,72(lit)
2
Cu 26: Chn C.
glucoz glixerol fomandehit etanol
Cu(OH)2 To phc mu xanh To phc mu un nng thy xut Khng hin
lam, un nng thy xanh lam hin kt ta gch tng

xut hin kt ta (Cu2O)
gch (Cu2O)
Cu 27: Chn C.
Cu 28: Chn D.
C 2 cu hnh electron l ca nguyn t kim loi l (a) Al v (d) Fe
Cu 29: Chn B.
Tnh cht vt l chung ca kim loi l tnh dn in, tnh dn nhit, tnh do, c nh kim, cc tnh
cht vt l trn ch yu u do cc electron t do trong kim loi gy ra.
Cu 30: Chn A.
Cu 31: Chn D.
- V dng 1 lng d Ca(OH) 2 nn n CO2 n CaCO3 0,09 mol
vi mdd gim mCaCO3 (44nCO2 18nH2O ) 3,78 nH2O 0,07mol
- Xt hn hp cc cht trong X: HCOOCH3 (k=1); CH2=CH-CHO (k=2) v CH2=CH-COOCH3 (k=2)
quan h
CO v H O
nC3H4O nC4H6O2 nCO2 nH2O 0,02 mol
2 2
n CO 2 4n C4H 6O 2
- m X(min) th n C2H 4O2 min khi v ch khi: n C3H 4O 0 n C2H 4O 2 0, 005 mol
2
m X(min) 60n C2H 4O 2 86n C4H 6O 2 2, 02 (g) (tha mn vi p n ca ).
0, 02
- Lu : Nu ta cho n C3H 4O n C 4H 6O 2 0, 01 mol th lc ny ta s gii ra c chnh xc p
2
n ca bi cho.
Cu 32: Chn C.
H .H .H 2nC2H3Cl
- Ta c : H 1 2 3 0,12825 nCH 4 0,25.103 mol
100 H
nCH 4
VCH 4 (trong t nhin) .22,4 5883,25(m3 )
0,95
Cu 32: Chn C.

102nA
C. ng, %mA .100% 50,5 %mB 49,5
102nA 60nB
D. Sai, Este A c 7 ng phn tng ng l: CH 3COO-C3H7 (2 ng phn) ; HCOO-C4H9 (4 ng
phn) ; C2H5COOC2H5 (1 ng phn) v axit B ch c 1 ng phn l CH 3COOH.
Cu 33: Chn D.
n BT: C
2

HCO3 OH Ba2
BaCO3 H 2O
mBaCO3 0,3.197 59,1(g)

Cu 34: Chn A.
0
HOCH2[CHOH]4CH2OH
thy phn xenluloz.
Cu 35: Chn A.
t0
mrn 138nK 2CO3 56nKOH(d ) 16,6(g)

Cu 36 : Chn D.
- Ta c : nO(trong oxit) nH 2 0,12mol mkim lo i moxit 16nO 2,34(g)
Cu 37 : Chn B.
Cu 38 : Chn D
Cc oxit b nhm kh nhit cao l cc oxit ca kim loi ng sau nhm trn dy in ha.
Cu 39 : Chn A.
CH3CH(NH3)COOCH3 (X) + NaOH CH3CH(NH2)COONa (Y) + CH3OH
CH3CH(NH2)COONa (Y) + HCl CH 3CH(NH3Cl)COOH (Z) + NaCl
Cu 40: Chn C.

TNH BC GIANG Mn: KHOA HC T NHIN HA HC
THPT PHNG SN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi un nng 25,8 gam hn hp gm ancol etylic v axit axetic c H2SO4 c lm xc tc thu
c 14.08 gam este. Nu t chy hon ton hn hp ban u thu c 23,4 ml nc. Hiu sut ca
phn ng este ha l
A. 70% B. 80% C.75% D. 85%
Cu 2: Sn phm ca phn ng thy phn saccaroz l
A. Glucoz v fructoz B. ancoletylic C. glucoz D. fructoz
Cu 3: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi
A. nc Br2. B. dung dch NaOH. C. dung dch HCl. D. dung dch NaCl.
Cu 4: Kt qu th nghim ca cc hp cht hu c A, B, C, D, E nh sau:
A Dung dch AgNO3 trong mi trng NH3 un nng Kt ta Ag trng sng
B Cu(OH)2 trong mi trng kim, un nng Kt ta Cu2O gch
C Cu(OH)2 nhit thng Dung dch xanh lam
D Nc Br2 Mt mu dung dch Br2
E Qy tm Ha xanh
Cc cht A, B, C, D, E ln lt l:
A. Etanal, axit etanoic, metyl axetat, phenol, etyl amin.
B. Metyl fomat, etanal, axit metanoic, glucoz, metyl amin.
C. Metanal, glucoz, axit metanoic, fructoz, metyl amin.
D. Metanal, metyl fomat, axit metanoic, metyl amin, glucoz.
Cu 5: Cht no sau y khng tham gia phn ng trng hp
A. CH3 CH3 B. CH2=CHCl
C. CH2=CH2 D. CH2=CHCH2 =CH
Cu 6: Thnh phn chnh ca qung xierit l
A. FeCO3 B. Fe3O4 C. FeS2 D. Al2O3. 2H2O
Cu 7: Cp cht no sau y khng xy ra phn ng ha hc
A. Fe + dung dch HCl B. Cu + dung dch FeCl3
C. Cu + dung dch FeCl2 D. Fe + dung dch FeCl3
Cu 8: Cho m gam hn hp X gm Cu v Fe vo dung dch H2SO4 long (d), kt thc phn ng thu
c 2,24 lt kh H2 (ktc). Khi lng ca Fe trong 2m gam X l
A. 4.48 B. 11,2 C. 16,8 D. 1,12
Cu 9: Pht biu no sau y l ng
A. Thch cao khan (CaSO4.H2O) c dng lm phn vit bng, b bt khi gy xng.
B. Trong t nhin, cc kim loi kim tn ti di dng hp cht.
C. St l kim loi nng, c tnh dn in, dn nhit tt nht trong cc kim loi.
D. Phn chua c cng thc l NaAl(SO4)2.12H2O c dng lm trong nc c.
Cu 10: Hiro ha ht 132,6 gam triolein (vi xc tc Ni, t) sinh ra m gam cht bo rn. Gi tr ca m l
A. 132,9 B. 133,2 C. 133,5 D. 133,8

Cu 11: T lt tr em sau khi git thng vn cn st li mt lng nh ammoniac, d lm cho tr b
vim da, thm ch mn nga, ty . kh sch amoniac nn dng cht g sau y cho vo nc x
cui cng git ?
A. Phn chua B. Gim n C. Mui n D. Gng ti
Cu 12: Cr(OH)3 khng phn ng vi
A. Dung dch NH3 B. Dung dch H2SO4 long
C. Dung dch brom trong NaOH D. Dung dch KOH d.
Cu 13: S ng phn este mch h, c cng thc phn t C3H4O2 l
A. 2 B. 4 C. 1 D. 3
Cu 14: Glyxin khng phn ng c vi cht no di y?
A. Cu B. HCl C. KOH D. Na2CO3
Cu 15: Kim loi no sau y c nhit si nng chy cao nht trong cc kim loi
A. St B. Vonfram C. Km D. ng
Cu 16: Cho dung dch NaOH n d vo dung dch cha hn hp FeCl2 v AlCl3, thu c kt ta X.
Nung X trong khng kh n khi lng khng i thu c cht rn Y. Vy Y l.
A. Fe2O3. B. Fe2O3 v Al2O3. C. Al2O3. D. FeO.
(a) Cho Mg vo dung dch Fe2(SO4)3 d (b) Sc kh Cl2 vo dung dch FeCl2
(c) Dn kh H2 d qua bt CuO nung nng (d) Cho Na vo dung dch CuSO4 d
(e) Nhit phn AgNO3 (f) in phn nng chy Al2O3
A. 4 B. 2 C. 3 D. 5
Cu 18: Cho 50 ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 trong dung
dch NH3 thu c 2,16 gam Ag kt ta. Nng mol/l ca dung dch glucoz dng l:
A. 0,20M. B. 0,01M. C. 0,10M. D. 0,02M.
Cu 19: X phng ha hon ton 14,25 gam este n chc, mch h vi 67,2 gam dung dch KOH 25%,
chng ct dung dch sau phn ng, thu c phn rn X v 57,9 gam cht lng Y. Dn ton b Y qua
bnh ng Na d, thy thot ra 32,76 lt kh H2 (ktc). Phn trm khi lng ca mui trong rn X l.
A. 48,8% B. 49,9% C. 54,2% D. 58,4%
Cu 20: Nhit phn hon ton hn hp X gm a mol KNO3 v b mol Fe(NO3)2 trong bnh chn khng
thu c cht rn Y v hn hp kh Z. Cho ton b Z vo nc th thu c dung dch HNO3 v khng
c kh thot ra. Biu thc lin h gia a v b l:
A. a = 2b B. a = 3b C. b = 2a D. b = 4a
Cu 21: Ha tan ht 8,1 gam kim loi X vo dung dch HCl ly d thy thu c 10,08 lt kh H2 (ktc).
Nhn xt v kim loi X l ng
A. X c dn in ln hn so vi Cu. B. X l kim loi nh hn so vi nc.
C. X tan c trong dung dch HCl v NH3. D. X l kim loi c tnh kh mnh.
Cu 22: Cho 3 th nghim sau:
(1) Cho t t dung dch AgNO3 n d vo dung dch Fe(NO3)2.
(2) Cho bt st t t n d vo dung dch FeCl3.
(3) Cho t t dung dch AgNO3 n d vo dung dch FeCl3.
Trong mi th nghim, s mol ion Fe3+ bin i tng ng vi th no sau y
Fe3+ Fe3+ Fe3+
t t t
(a) (b) (c)
A. 1-a, 2-c, 3-b. B. 1-a, 2-b, 3-c. C. 1-b, 2-a, 3-c. D. 1-c, 2-b, 3-a.

Cu 23: t chy hon ton 1 mol cht bo thu c lng CO2 vo H2O hn km nhau 8 mol. Mt khc
a mol cht bo trn tc dng ti a vi 600ml dung dch Br2 1M. Gi tr a l
A.0,10 B. 0,15 C. 0,20 D. 0,30
Cu 24: Cho cc dy cht sau: stiren, metyl fomat, anilin, fructoz, anehit axetic, axit fomic, phenol. S
cht trong dy c kh nng lm mt mu nc Br2
A. 6 B. 5 C. 4 D. 3
Cu 25: Cho lung kh CO (d ) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn
ng hon ton, thu c 8,3 gam hn hp cht rn. Khi lng CuO c trong hn hp ban u l :
A. 4,0 B. 0,8 C. 2,0 D. 8,3
Cu 26: Cht A l mt -aminoaxit mch cacbon khng phn nhnh. Cho 0,1 mol A vo dung dch cha
0,25 mol HCl d, thu c dung dch B. phn ng ht vi dung dch B cn va 300ml dung dch
NaOH 1,5M un nng, sau phn ng thu c dung dch D. Nu c cn dung dch D, th thu c 33,725
gam cht rn khan. Tn ca A l
A. Glyxin B. Alanin C. Axit glutamic D. Axit -
aminobutiric
Cu 27: X, Y l hai axit cacboxylic u n chc, mch h (trong phn t X, Y cha khng qu 2 lin
kt v 50 < MX < MY); Z l este c to bi X, Y v etylen glicol. t chy 13,12 gam hn hp E
cha X, Y, Z cn dng 0,50 mol O2. Mt khc 0,36 mol E lm mt mu va dung dch cha 0,1 mol
Br2. Nu un nng 13,12 gam E vi 200 ml dung dch KOH 1M (va ), c cn dung dch sau phn ng
thu c hn hp F gm a gam mui A b b gam mui B (MA < MB). T l ca a : b gn nht vi gi tr
no sau y
A. 2,9 B. 2,7 C. 2,6 D. 2,8
Cu 28: Cho m gam Na vo 200 ml dung dch hn hp NaOH 1M v Ba(OH)2 0,5M, n phn ng hon
ton thu c dung dch X. Cho dung dch X vo 200 ml dung dch hn hp Al2(SO4)3 0,5M v HCl 1M,
n phn ng hon ton thu c 31,1 gam kt ta. Gi tr ln nht ca m l:
A. 4,6. B. 23. C. 2,3. D. 11,5.
(1) S kt ta ca protein bng nhit c gi l s ng t.
(2) Si bng v t tm c th phn bit bng cch t chng.
(3) Dng dung dch HCl c th tch ring benzen ra khi hn hp gm benzen v anilin.
(4) Glucoz c v ngt hn fructoz.
(5) nhn bit glucoz v fructoz c th dng dung dch AgNO3 trong NH3 un nng.
(6) Go np do hn go t do trong go np cha nhiu amilopectin hn.
S nhn xt ng l:
A. 4. B. 3. C. 5. D. 6.
(a) Trong bng tun hon cc nguyn t ha hc, crom thuc nhm VIIIB
(b) Crom khng tc dng vi dung dch axit HNO3 v H2SO4 c ngui
(c) Khi thm dung dch kim vo mui cromat s to thnh icromat
(d) Trong mi trng axit, mui crom (VI) b kh thnh mui crom (III)
(e) CrO l oxit baz, Cr2O3 l oxit lng tnh, CrO3 l oxit axit
(g) Lu hunh, photpho, ancol etylic u bc chy khi tip xc vi CrO3
S pht biu ng
A. 4 B. 5 C. 6 D. 2
Cu 31: in phn dung dch no sau y, th c kh thot ra c 2 in cc (ngay t lc mi u bt
u in phn)
A. Cu(NO3)2 B. FeCl2 C. K2SO4 D. FeSO4
Cu 32: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO 3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi
cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V
l

A. 8,96 B. 4,48 C. 10,08 D. 6,72
Cu 33 : X gm hai aminoaxxit no, h (cha mt nhm -NH2, mt nhm COOH) l Y v Z
(Bit MZ = 1,56MY). Cho a gam X tc dng 40,15 gam dung dch HCl 20% thu c dung dch A.
tc dng ht cc cht trong dung dch A cn 140 ml dung dch KOH 3M. Mt khc, t chy hon ton
a gam X thu c sn phm chy gm CO 2, H2O, N2 c dn qua bnh ng dung dch Ca(OH) 2 d
thy khi lng bnh tng 32,8 gam. Phn t khi ca Z l :
A. 117 B. 139 C. 147 D. 123
Cu 34: t chy hon ton 0,35 mol hn hp X gm metyl propionat, metyl axetat v 2 hirocacbon
mch h cn va 28,448 lt O2 (ktc), to ra 14,4 gam H2O. Nu cho 0,35 mol X vo dung dich Br2
d th s mol Br2 phn ng ti a l
A. 0,42. B. 0,26. C. 0,33. D. 0,40.
Cu 35: Cho m gam hn hp X gm glyxin v axit glutamic tc dng vi 0,4 mol HCl thu c dung
dch Y, Y phn ng ti a vi 0,8 mol NaOH thu c 61,9 gam hn hp mui. % Khi lng glyxin c
trong X l
A. 50,51%. B. 25,25%. C. 43,26%. D. 37,42%.
Cu 36: t chy 2,15 gam hn hp gm Zn, Al v Mg trong kh oxi d, thu c 3,43 gam hn hp
X. Ton b X phn ng va vi V ml dung dch H 2SO4 0,5M. Bit cc phn ng xy ra hon ton.
Gi tr ca V l
A. 160. B. 480. C. 240. D. 360.
Cu 37 : Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO 2 sinh ra
thu c hp th hon ton vo dung dch Ca(OH) 2, thu c 550 gam kt ta v dung dch X. un k
dung dch X thu thm c 100 gam kt ta. Gi tr ca m l
Cu 38: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c
dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH
phn ng l :
Cu 39: Cho m gam hn hp Na, Ba vo nc thu c dung dch A v 6,72 lt kh (kc). Th tch
dung dch hn hp H2SO4 0,5M v HCl 1M cn dng trung ha dung dch A l
A. 0,3 lt B. 0,2 lt C. 0,4 lt D. 0,5 lt
Cu 40: Este X (C8H8O2) tc dng vi lng d dung dch KOH, un nng thu c hai mui hu c
v nc. X c tn gi l
A. phenyl fomat. B. benzyl fomat. C. metyl benzoat. D. phenyl axetat.
----------HT----------

PHN TCH HNG DN GII
THI TH THPT PHNG SN BC GIANG LN 1
Cu 1: Chn B.

H 2SO 4
CH 3COOC 2 H 5 H 2O

CH 3COOH 0,16 mol
Tm tt qu trnh: 25,8 (g)
C 2 H 5OH O2 m H 2O D H 2O .V 23, 4.1
H 2 O : n H 2O 1,3 mol
18 18 18
C 2 H 5OH : x 46x 60y 25,8 x 0,3 0,16
- Gi H .100% 80%
CH 3COOH : y 3x 2y 1,3 y 0, 2 0, 2
Cu 2: Chn A.
H 2O
- Thy phn saccaroz trong mi trng axit: C12H 22O11 C6 H12O6 C6 H12O6
Saccarozo H Glucozo Fructozo
Cu 3: Chn A.
- Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi dung dch Br2 to kt ta trng
Cu 4: Chn B.
A: HCOOCH3 Dung dch AgNO3 trong mi trng NH3 un nng Kt ta Ag trng sng
B: CH3CHO Cu(OH)2 trong mi trng kim, un nng Kt ta Cu2O gch
C: HCOOH Cu(OH)2 nhit thng Dung dch xanh lam
D: C6H12O6 (glucoz) Nc Br2 Mt mu dung dch Br2
E: CH3NH2 Qy tm Ha xanh
Cu 5: Chn A.
- iu kin cc cht tham gia phn ng trng hp l trong phn t cht phi c lin kt bi hoc
vng km bn.
xt,t o ,p
Trng hp etilen to polietilen (PE): nCH 2 CH 2
( CH 2 CH 2 ) n
Trng hp vinyl clorua to poli(viny lclorua) (PVC):
xt,t o ,p
nCH 2 CH 2
( CH 2 C H 2 ) n
|
Cl
Trng hp buta-1,3-ien to polibutaien hay cao su buna:
xt,t o ,p
nCH 2 CH CH CH 2
( CH 2 CH CH CH 2 ) n
Trong phn t etan: CH3 CH3 khng c lin kt bi nn khng tham gia phn ng trng hp.
Cu 6: Chn A.
- Qung boxit cha thnh phn chnh l Al2O3. 2H2O.
- Mt s loi qung st quan trng:
+ Qung hematit cha Fe2O3 khan.
+ Qung hematit nu cha Fe2O3.nH2O.
+ Qung manhetit cha Fe3O4 l qung giu st nht, nhng him c trong t nhin.
+ Ngoi ra cn c qung xierit cha FeCO3 , qung pirit st cha FeS2.
Cu 7: Chn C.
- xc nh chiu ca phn ng oxi ha kh ta da vo quy tc :
Cht oxi ha yu Cht oxi ha mnh
Cht kh mnh Cht kh yu
- Chiu phn ng: Cht oxi ha mnh + Cht kh mnh Cht oxi ha yu + Cht kh yu
- Cc phng trnh xy ra:
Fe + 2HCl
FeCl2 + H2 Cu + 2FeCl3
2FeCl2 + CuCl2
Cu + FeCl2 : khng xy ra Fe + 2FeCl3
3FeCl2
Cu 8: Chn B.
BT:e
n Fe (trong m gam X) n H 2 0,1mol . Vy mFe(trong 2m gam X) 2.0,1.56 11,2(g)

- Lu : Cu khng tc dng vi H2SO4 long.
Cu 9: Chn B.
A. Sai, Thch cao nung c cng thc l CaSO4.H2O dng lm phn vit bng, b bt khi gy xng.
B. ng, Trong t nhin, cc kim loi kim ch tn ti di dng hp cht.
C. Sai, Kim loi dn in tt nht l Ag ch khng phi l Fe.
D. Sai, Cng thc phn chua l K2SO4.Al2(SO4)3.24H2O hay KAl(SO4)2.12H2O.
Cu 10: Chn C.
Ni,t o
- Phng trnh: (C17H33COO)3C3H5 + 3H2 (C17H35COO)3C3H5
mol: 0,15 0,15
m (C17 H35COO)3 C3H 5 0,15.890 133,5 (g)
Cu 11: Chn B.
- T lt tr em sau khi git thng lu li lng amoniac v bt git m mt thng khng nhn thy
c. Vi s lng cht ho hc cn xt li ny rt c th lm cho da b vim, thm ch b sng ty au
nga. Bi vy, khi git t lt, nu nh vo nc git mt vi git gim n, cc loi cht trn s c kh
sch.
Cu 12: Chn A.
- Cc phn ng ca Cr(OH)3:
Cr(OH)3 NH3 : khng phn ng 2Cr(OH)3 3H2SO4
Cr2 (SO4 )3 6H2O
2Cr(OH)3 3Br2 10NaOH
2Na 2CrO4 6NaBr 8H 2O
Cr(OH)3 KOH K[Cr(OH) 4 ]
Cu 13: Chn C.
3.2 2 4
Ta c: = = 2 = 1COO 1CC C3H4O2 l este n chc, mch h trong phn t c 1
2
lin kt C=C. Vy ch c 1 ng phn tng ng l: HCOOCH CH 2 .
Cu 14: Chn A.
- Glyxin (H2N-CH2-COOH) trong phn t cha ng thi nhm amino (NH2) v nhm cacboxyl
(COOH) nn n va th hin tnh axit v va th hin tnh baz c th tc dng c vi HCl, KOH,
Na2CO3 nhng khng tc dng vi li kim loi Cu .
Cu 15: Chn B.
- Nhng kim loi khc nhau c nhit nng chy khc nhau. Kim loi c nhit nng chy thp l
thy ngn (Hg) nng chy -390C v kim loi nng chy nhit cao nht l vonfram (W) nng chy
34100C.

Cu 16: Chn A.
NaOH(d ) O2 H 2O t o
- Qu trnh: FeCl 2 ,AlCl 3 Fe(OH)2 (X) Fe(OH)3 Fe2O3 (Y)
FeCl2 + 2NaOH
Fe(OH)2 + 2NaCl
AlCl3 + NaOH Al(OH)3 + NaCl ; v NaOH d nn: Al(OH)3 + NaOH Na[Al(OH)4]
1 to
Trong khng kh: 2Fe(OH)2 + O2 + H2O 2Fe(OH)3 v nung: 2Fe(OH)3 Fe2O3 +
2
3H2O
Cu 17: Chn C.
- Phng trnh xy ra:
3+
loi.
+ Nu cho Mg d tc dng vi Fe3+ th xy ra c 2 phn ng (1) v (2) khi sn phm thu c c cha
kim loi.
to
(b) Cl2 + 2FeCl2
2FeCl3 (c) H2 + CuO Cu + H2O
2NaOH + H2 ; 2NaOH + CuSO4
to pnc
(e) 2AgNO3 2Ag + 2NO2 + O2 (f) 2Al 2O3
4Al 3O2
Cu 18: Chn A.
n Ag 0, 01
- Ta c: n C6H12O 6 0, 01 mol C M 0, 2 M
2 0, 05
Cu 19: Chn D.
m dd .C% m m KOH
- Ta c: n KOH 0,3 mol n H 2O dd 2,8 mol
56 18
- Hng t duy 1: Tm cng thc cu to ca este
ROH Na
- Cht lng Y gm: 57,9 (g) 2n H 2 n ROH n H 2O 2,925 n ROH 0,125 mol
H 2O : 2,8 mol
m Y m H 2O
M ROH 60 : ROH l C3H 7 OH m n este n ROH 0,125 mol
n ROH
14, 25
M este 114 : C 2H 3COOC3H 7 mui trong rn X l C2H3COOK: 0,125 mol
0,125
BTKL
m X meste mdd KOH m Y 23,55 (g) . Vy %mC2H3COOK 58, 4%
- Hng t duy 2: Tm lng KOH d
+ Ta c: n este n ROH nKOH p = 0,125 mol nKOH d = 0,175 mol
BTKL
+ Rn X gm RCOOK v KOH d mR 'COOK mX mKOH d = 13,75 (g) %mmui
58, 4%
Cu 20: Chn C.
- Hng t duy 1: Cn bng phng trnh phn ng
to to
2KNO3 2KNO2 + O2 4Fe(NO3)2 2Fe2O3 + 8NO2 + O2
mol: a 0,5a b 2b 0,25b
- Cho hn hp kh Z vo H2O: 4NO2 + O2 + 2H2O
4HNO3
mol: 2b 0,5b
m nO 2
0,5a 0, 25b 2a b
- Hng t duy 2: Bo ton e
5 5 3
3 3
K N O3 :amol t 0 K N O2 , Fe2 O3 qu trnh K N O3 2e K N O2
X
oxi ha kh 2 3
2 5 H 2O
5 Fe(NO ) Fe O 1e
Fe(N O3 )2 :bmol NO2 O2 H N O3 3 2 2 3
BT:e
n Fe(NO3 )2 2n KNO3 b 2a
Cu 21: Chn D.
m x 3
X .n 2n H 2 0,9 (vi n l ha tr ca X) M X 9x
BT: e
M X 27 X l Al.
MX
A. Sai, Theo th t dn in gim dn l: Ag Cu Au Al Fe .
B. Sai, Nhm l kim loi nh ( D 2, 7g / cm3 ) nng hn so vi nc ( D 1g / cm3 ).
C. Sai, Al ch tan trong dung dch HCl cn dung dch NH3 th khng tan, v NH3 c tnh baz yu khng
ha tan c Al(OH)3.
D. ng, Al l kim loi c tnh kh mnh: Al Al3 3e .
Cu 22: Chn B.
- th (a) cho thy lng Fe3+ t 0 tng dn sau khng i nn ng vi th nghim (1).
+ Phng trnh phn ng : Ag Fe2
Ag Fe3
- th (b) cho thy lng Fe3+ gim dn v 0 nn ng vi phn ng (2).
+ Phng trnh phn ng : Fe 2Fe3 3Fe2
- th (c) cho thy lng Fe3+ khng i nn ng vi phn ng (3).
+ Phng trnh phn ng : Ag Cl AgCl
Cu 23: Chn A.
- Khi t cht bo E ta c: (k E 1) n E nCO2 n H2O (k E 1) n E 8n E k E 9 3COO 6CC
n Br2
- Khi cho a mol E tc dng ti a vi 0,6 mol Br2 a n E 0,1mol
6
Cu 24: Chn A.
Nhng cht tc dng vi dung dch brom gm:
- Hidrocacbon: Xiclopropan (C3H6), Anken, Ankin, Ankadien, Stiren.
- Cc hp cht hu c c gc hidrocacbon khng no.
- Andehit (-CHO)
- Cc hp cht c nhm chc andehit: Axit fomic, Este ca axit fomic, Glucoz, Mantoz
- Phenol (C6H5-OH) v anilin (C 6H5-NH2) phn ng th vng thm.
Vy c 6 cht tha mn l: stiren, metyl fomat, anilin, anehit axetic, axit fomic, phenol.
Cu 25: Chn A.
m Al2O3 ,CuO m Al2O3 ,Cu 9,1 8,3
- Ta c : n O n CuO 0,05 mol mCuO 4 gam
16 16
Cu 26: Chn C.
0,1 mol B 0,25 mol
- Gp qu trnh: (NH 2 ) x R(COOH) y HCl NaOH
(NH 2 ) x R(COONa) y , NaCl H 2O
0,25mol 0,45mol
0,1mol A 33,725 (g) D
- Ta c: n H2O n NaOH 0, 45 mol m A m D m H 2O m NaOH m HCl 14, 7 gam

BTKL
MA = 147: H2 NC3H5 (COOH)2 . Vy A l Axit glutamic .

Cu 27: Chn C.

O 2 : 0,5 mol CO 2 H 2O
- Qu trnh 1: 13,12 (g) E . Gi a, b, c ln lt l mol ca X, Y,

KOH : 0, 2 mol
a (g) A b (g) B
Z.
a b 2c n KOH 0, 2 mol
BT: O n CO 2 0, 49 mol
+ Ta c: 2n CO 2 n H 2O 2.(a b 2c) 2n O 2 1, 4
BTKL n H 2O 0, 42 mol
44n CO 2 18n H 2O m E m O 2 29,12
- Qu trnh 2: Khi cho E tc dng vi dung dch Br2, nhn thy n Br2 0,1 n E 0,36 Trong X, Y
ch c 1 cht tham gia phn ng cng Br2, khi Z c to bi X, Y cng c phn ng cng Br2.
+ Gi X l cht c 2 lin kt Y c cha 1 lin kt v Z c cha 3 lin kt .
n X n Y n Z n KOH a b 2c 0, 2 a 0, 03 mol

+ Ta c h sau: n CO2 n H 2O n X 2n Z a 2c 0, 07 b 0,13 mol
* 0,36.(a c) 0,1.(a b c) c 0, 02 mol
n E .(n X n Z ) n Br2 .n E
n.0, 03 m.0,13 0, 02.(n m 2) 0, 49 (vi n,m l s C ca X, Y vi n 3 v m 2).
BT: C
B : CH 2 CH COONa : 0, 05mol a
+ Xt n = 3 suy ra n = 2. T Z gm 2, 617
A : CH 3 COONa : 0,15 mol b
+ Nu n > 3 th m < 2 : khng tha iu kin.
Cu 28: Chn D.
- Khi thm m gam Na vo dung dch hn hp NaOH v Ba(OH)2 th:
(x 0,2) mol 0,1mol
NaOH , Ba(OH) 2 Al2 (SO 4 )3 HCl BaSO 4 , Al(OH)3 (vi x l s mol Na thm vo)
0,2mol
X 0,1mol 31,1 gam
31,1 233n BaSO4

- Nhn thy: n Ba 2 n SO 2 n BaSO4 n Ba 2 0,1mol n Al(OH)3 0,1 mol
4 78
- Hng t duy 1:
+ x t gi tr ln nht th kt ta Al(OH)3 t cc i ri tan li mt phn
nOH 4n Al3 n H n Al(OH)3 0,9mol m n NaOH x 0, 2 nOH 2n Ba(OH)2 x 0,5mol
- Hng t duy 2 :
0,2 mol 0,2 mol 0,1mol
+ p dng BTNT Cl, S v Al dung dch sau phn ng gm: NaCl ; Na 2SO 4 ; NaAlO 2
BT:Na
n NaOH n NaCl 2n Na 2SO4 n NaAlO2 0,7 x 0,7 0, 2 0,5 m Na 11,5gam

Cu 29: Chn A.
(1) ng, S ng t l s ng li ca protein v tch ra khi dung dch khi un nng hoc thm axit,
baz, mui. S kt ta ca protein bng nhit cng c gi l s ng t.
(2) ng, Si bng cha thnh phn chnh l xenluloz khi t chy khng c mi kht v mi ging
nh mi t giy. T tm khi t chy c mi kht nh mi tc chy do trong thnh phn ca t tm
c kt tinh t protein.
(3) ng, Cho dung dch HCl d vo benzen v anilin th anilin tan trong HCl cn phn khng tan l
benzen sau ta chit lc phn khng tan thu c benzen. em dung dch cn li gm c HCl d v
C6H5NH3Cl sau khi chit tc dng vi NaOH ta thu c anilin khng tan.
(4) Sai, Glucoz hay cn gi l ng nho , fructoz c nhiu trong mt ong v ngt ca n gp 2,5
ln glucoz.

(5) Sai, Khng dng AgNO3/NH3 v c 2 cht u c kh nng tham gia phn ng. nhn bit glucoz
v fructoz th ta dng dung dch Br2 v glucoz lm mt mu dung dch Br2 trong khi fructoz th
khng.
(6) ng, Trong tinh bt, amilopectin chim khong 70-80% . Trong go np cha thnh phn
amilopectin cao hn go t v vy go np s do hn go t.
Vy c 4 nhn xt ng l (1), (2), (3), (6).
Cu 30: Chn A.
(a) Sai, Cu hnh Cr(Z=24): 1s22s22p63s23p63d54s1 : Cr nm chu k 4, nhm VIB.
(b) ng, Cr b th ng ha khi tc dng vi dung dch axit HNO3 v H2SO4 c ngui.

Cr2O72 H 2O .
(c) Sai, Tng qut: 2CrO 24 2H

mu vng mu da cam
- Trong mi trng kim, mui icromat chuyn ha thnh cromat v ngc li trong mi trng axit,
mui cromat chuyn ha thnh icromat.
(d) ng, Trong mi trng axit, mui crom (VI) c tnh oxi ha mnh v b kh thnh mui crom (III).
V d: K2Cr2O7 + 14HCl 2KCl + 3CrCl3 +3Cl2 + 7H2O
(e) ng.
(g) ng, Phn ng 3S 4CrO3
2Cr2O3 3SO2 v C2H5OH 4CrO3
2Cr2O3 2CO2 3H2O
Vy c 4 pht biu ng.
Cu 31: Chn C.
Ti catot Ti anot
H2 O + 2e 2OH- + H2 H2O 4H+ + O2 + 4e
Bn cht ca in phn dung dch K 2SO4 l c cn dung dch.

Cu 32: Chn A.
- Ta c : ne(max) 2nCu nFe(NO3 )2 1,2 v
NO3 3e 4H
NO H 2O
- Qu trnh kh NO3 xy ra nh sau :
- 1,2mol
VNO 8,96(l)
Cu 33 : Chn A.
- Khi cho X tc dng vi 0,22 mol HCl ri em dung dch thu c tc dng vi 0,42 mol thi :
nA nKOH nHCl 0,42 0,22 0,2mol .
- t CTTQ ca X l CnH2n1O2N , t X th : CnH 2n1O2N
O2
nCO2 (n 0,5)H 2O
0,2mol 0,2n 0,2(n0,5)
- Theo ta c : 44nCO2 18nH2O mdd tng 44.0,2n 18(n 0,5) 32,8 n 2,5
Vy trong X c cha NH2CH2COOH(Y) mZ 1,56mY 117 (NH 2CH(CH 3 )COOH)
Cu 34: Chn A.
- Ta thc hin php quy i sau : C2H5COOCH3 C3H8.CO2 v CH3COOCH3 C2H6 .CO2
Hn hp X sau quy i gm: C3H8, C2H6, CxHy v CO2
- Khi t hn hp X sau khi quy i (gm cc hidrocacbon v CO2) th lng O2 dng t ton b X
cng chnh l lng O2 cn dng t hon ton hn hp hidrocacbon trong X .
+ Ta c: n HC n C2H5COOCH3 n CH3COOCH3 n C x H y n X 0,35
BT: O 2nO2 nH2O quan hCO2 v H 2O
nCO2 (sp khi t HC) 0,87 khi t H.C
nHC (k HC 1) nCO2 nH2O
2
nBr2 nHC .k HC nCO2 nH 2O nHC 0,87 0,8 0,35 0,42 mol
Cu 35: Chn A.

- Xt ton qu trnh phn ng ta c h sau :
nGly 2nGlu nNaOH nHCl
a 2b 0,4 a 0,2

97nGlyNa 191nGluNa2 mmui 58,5nNaCl
97a 191b 38,5 b 0,1
75nGly
%mGly .100 50,51
75nGly 147nGlu
Cu 36: Chn A.
moxit mkim loi
nO(trong oxit) 0,08mol nH2SO4 nO(trong oxit) 0,08mol VH2SO4 0,16(l)
16
Cu 37 : Chn D.
- Cho CO2 tc dng vi dung dch Ca(OH) 2 :
BT:C
nCO2 nCaCO3(1) 2nCaCO3(sau khi un nng) 0,75mol
H2SO4 ln men nCO2
C6H10O5 C6H12O6 CO2 C2H 5OH . mtinh bt 162. 750(g)
3,75mol 7,5mol 2H
Cu 38: Chn C.
- Ta c : nNaOH 2nNH2C3H5(COOH)2 nHCl 0,65mol
Cu 39: Chn A.
- Dung dch A cha : nOH 2nH 2 0,6mol
- Trung ha dung dch A th : nOH nH 2nH 2SO4 nHCl 2.0,5V V 0,6 V 0,3(l)
Cu 40: Chn D.
0
CH 3COOC6H 5 2NaOH
t
CH 3COONa C6H 5ONa H 2O
phenylaxetat
----------HT----------

TNH NGH AN Mn: KHOA HC T NHIN HA HC
THPT THANH CHNG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Pht biu khng ng l :

A. Cc kim loi Na, K, Ba c cu trc mng tinh th lp phng tm khi.
B. Phng php c bn iu ch kim loi kim th l in phn nng chy mui clorua ca chng.
C. Nhit nng chy ca cc kim loi kim gim dn t Li & Cs.
D. Tt c cc nguyn t kim loi kim th u tc dng vi nc gii phng kh H2.
Cu 2: Phi kim X tc dng vi kim loi M thu c cht rn Y. Ha tan Y vo nc c dung dch
Z. Thm AgNO3 d vo dung dch Z c cht rn G. Cho G vo dung dch HNO3 c nng d thu
c kh mu nu v cht rn F. Kim loi M v cht rn F ln lt l:
A. Al v AgCl B. Fe v AgCl C. Cu v AgBr D. Fe v AgF
(1) Cu + H2SO4 c, ngui (5) Cu + HNO3 c, ngui
(2) Cu(OH)2 + glucoz (6) axit axetic + NaOH
(3) Gly-Gly-Gly + Cu(OH)2/NaOH (7) AgNO3 + FeCl3
(4) Cu(NO3)2 + FeCl2 + HCl (8) Al + Cr2(SO4)3
S phn ng xy ra iu kin thng ?
A. 5. B. 7. C. 8. D. 6.
Cu 4: Cht no sau y khng c phn ng thy phn?
A. Glucoz B. Cht bo C. Saccaroz D. Xenluloz
Cu 5: Tnh cht vt l ca kim loi khng do cc electron t do quyt nh l
A. Tnh dn in. B. nh kim. C. Khi lng ring. D. Tnh dn nhit.
Cu 6: Cho m gam hn hp X gm K, Ca tan ht vo dung dch Y cha 0,12 mol NaHCO3 v 0,04 mol
CaCl2, sau phn ng thu c 7 gam kt ta v thy thot ra 0,896 lt kh (ktc). Gi tr ca m l
A. 1,72. B. 1,56. C. 1,98. D. 1,66.
Cu 7: lu anilin trong khng kh, n dn dn ng sang mu nu en, do anilin
A. tc dng vi oxi khng kh.
B. tc dng vi kh cacbonic.
C. tc dng vi nit khng kh v hi nc.
D. tc dng vi H2S trong khng kh, sinh ra mui sunfua c mu en.
Cu 8: Sc 0,02 mol Cl2 vo dung dch cha 0,06 mol FeBr 2 thu c dung dch A. Cho AgNO3 d
vo A thu c m gam kt ta. Bit cc phn ng xy ra hon ton. Gi tr ca m l :
A. 30,46 B. 12,22 C. 28,86 D. 24,02
A. Saccaroz lm mt mu nc brom.
B. Xenluloz c cu trc mch phn nhnh, xon vo nhau to thnh si xenluloz.
D. Glucoz b kh bi dung dch AgNO 3 trong NH3.
Cu 10: in phn dung dch X cha 0,03 mol Fe 2(SO4)3 v 0,02 mol CuSO4 trong 4632 giy vi dng
in mt chiu c cng I = 2,5A. Bit hiu sut in phn l 100%. Khi lng dung dch gim
sau in phn l:
Cu 11: Thy phn hon ton 1 mol tetrapeptit X mch h thu c 3 mol glyxin v 1 mol alanin. S

cu to ca X tha mn l
A. 3. B. 5. C. 6. D. 4.
Cu 12: Cho vo ng nghim 1 ml dung dch lng trng trng 10%, thm tip 1 ml dung dch NaOH
30% v 1 git dung dch CuSO4 2%. Lc nh ng nghim, hin tng quan st c l
A. C kt ta xanh lam, sau tan ra to dung dch xanh lam.
B. C kt ta xanh lam, sau kt ta chuyn sang mu gch.
C. C kt ta xanh lam, sau tan ra to dung dch mu tm.
D. C kt ta xanh lam, kt ta khng b tan ra.
(1) Nhng thanh Fe nguyn cht vo dung dch CuCl 2.
(2) Nhng thanh Fe nguyn cht vo dung dch FeCl 3.
(3) Nhng thanh Fe nguyn cht vo dung dch HCl long, c nh vi git CuCl2.
(4) Cho dung dch FeCl 3 vo dung dch AgNO3.
(5) thanh thp lu ngy ngoi khng kh m.
S trng hp xy ra n mn in ha l.
A. 4. B. 2. C. 3. D. 1.
Cu 14: Hin tng no di y khng ng thc t ?
A. Nh vi git axit nitric c vo dung dch lng trng trng thy xut hin mu vng.
B. Trn ln lng trng trng, dung dch NaOH v c mt t CuSO 4 thy xut hin mu xanh c
trng.
C. un nng dung dch lng trng trng thy xut hin hin tng ng t.
D. t chy da hay tc thy c mi kht.
Cu 15: Ho tan hon ton mt lng Ba vo dung dch cha a mol HCl thu c dung dch X v a
mol H2. Trong cc cht sau: Na2SO4, Na2CO3, Al, Al2O3, AlCl3, Mg, NaOH v NaHCO3. S cht tc
dng c vi dung dch X l
A. 7. B. 6. C. 5. D. 4.
Cu 16: Cho s sau (cc phn ng u c iu kin v xc tc thch hp):
X2 + O2 X3
Cu ,t 0
(X) C5H8O4 + 2NaOH 2X1 + X2
2X2 + Cu(OH)2 Phc cht c mu xanh + 2H2O.
Pht biu no sau y sai:
A. X l este a chc, c kh nng lm mt mu nc brom.
B. X1 c phn t khi l 68.
C. X2 l ancol 2 chc, c mch C khng phn nhnh.
D. X3 l hp cht hu c a chc.
Cu 17: Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na 2CO3 thu
c V lt kh CO2. Ngc li cho t t tng git ca dung dch cha a mol Na 2CO3 vo dung dch
cha b mol HCl thu c 2V lt kh CO 2 (cc th tch kh o cng iu kin). Mi quan h gia a v
b l :
A. a = 0,75b. B. a = 0,8b. C. a = 0,35b. D. a = 0,5b.
Cu 18: Dung dch CuSO4 long c dng lm thuc dit nm cho hoa. iu ch 800 gam dung
dch CuSO4 5%, ngi ta ha tan CuSO4.5H2O vo nc. Khi lng CuSO 4.5H2O cn dng l ?
Cu 19: Thy phn 14,6 gam Gly-Ala trong dung dch NaOH d thu c m gam mui. Gi tr ca m
l :
A. 20,8 B. 18,6 C. 22,6 D. 20,6
Cu 20: Ngi ht thuc l nhiu thng mc cc bnh nguy him v ng h hp. Cht gy hi ch
yu c trong thuc l l :
A. Mophin. B. Heroin. C. Cafein. D. Nicotin.
Cu 21: Cho 16,55 gam hn hp X gm Fe3O4, Fe(NO3)2 v Al tan hon ton trong dung dch cha
0,775 mol KHSO4 long. Sau khi cc phn ng xy ra hon ton thu c dung dch Y ch cha 116,65

gam mui sunfat trung ha v 2,52 lt (ktc) kh Z gm 2 kh trong c mt kh ha nu ngoi khng
23
kh, t khi ca Z so vi H2 l . Mt khc, cho ton b lng hn hp X trn vo nc, sau khi
9
cc phn ng kt thc, thu c m gam rn Y. Gi tr ca m gn nht vi gi tr no sau y ?
A. 13,7. B. 14,8. C. 12,5. D. 15,6.
Cu 22: Cho 15,6 gam mt kim loi kim X tc dng vi nc (d). Sau phn ng thu c 4,48 lt
kh hiro ( ktc). Kim loi X l
A. Li. B. K. C. Na. D. Rb.
Cu 23: Este c CTPT C2H4O2 c tn gi no sau y?
A. metyl propionat. B. metyl fomat. C. metyl axetat. D. etyl fomat.
Cu 24: Cho hn hp M gm hai cht hu c X, Y. Trong X l mt axt hu c hai chc, mch h,
khng phn nhnh (trong phn t c mt lin kt i C=C) v Y l ancol no, n chc, mch h. t
chy hon ton 22,32 gam M thu c 14,40 gam H2O. Nu cho 22,32 gam M tc dng vi K d thu
c 4,256 lt H2 (ktc). Phn trm khi lng ca Y trong M gn nht vi gi tr no sau y?
A. 27,25%. B. 62,40%. C. 72,70%. D. 37,50%.
Cu 25: Nhn nh no sau y l ng?
A. Saccaroz, amiloz v xenluloz u cho c phn ng thy phn.
B. Tinh bt v xenluloz u c cng thc l (C6H10O5)n nn chng l ng phn ca nhau.
C. Xenluloz c to bi cc gc -glucoz lin kt vi nhau bi lin kt - 1,4-glicozit.
D. Thy phn n cng amilopectin, thu c hai loi monosaccarit.
Cu 26: Thuc th dng phn bit hai dung dch Na 2CO3 v Ca(HCO3)2 l?
A. dung dch NaHCO3. B. dung dch Ca(OH)2.
C. dung dch NaOH. D. dung dch NaCl.
mui. S ng phn cu to ca X l.
A. 2 B. 1 C. 6 D. 8
Cu 28: Cho 0,01 mol - amino axit X tc dng va vi 200 ml dung dch KOH 0,1M hay 100 ml
dung dch HCl 0,1M. Nu cho 0,03 mol X tc dng vi 40 gam dung dch NaOH 7,05% c cn dung
dch sau phn ng, thu c 6,15 gam cht rn. Cng thc ca X l.
A. (H2N)2C3H5COOH. B. H2NC4H7(COOH)2.
C. H2NC2H3(COOH)2. D. H2NC3H5(COOH)2.
Cu 29: Hn hp X gm tripeptit A v tetrapeptit B u c cu to bi glyxin v alanin. Thnh
phn phn trm khi lng nit trong A v B theo th t l 19,36% v 19,44%. Thu phn 0,1 mol
hn hp X bng lng dung dch NaOH va , thu c dung dch Y. C cn dung dch Y thu c
36,34 gam hn hp mui. T l mol A v B trong hn hp X l :
A. 3 : 2 B. 3 : 7 C. 7 : 3 D. 2 : 3
Cu 30: Cho hn hp H gm Fe2O3 v Cu tc dng ht vi dung dch HCl d, thu c dung dch X
cha 40,36g cht tan v mt cht rn khng tan. Cho mt lng d dung dch AgNO3 vo dung dch X
n khi phn ng kt thc th thu c 0,01 mol kh NO v m gam kt ta Z. Bit NO l sn phm kh
duy nht ca N+5. Gi tr ca m l :
A. 113,44g B. 91,84g C. 107,70g D. 110,20g
Cu 31: t chy ht 25,56g hn hp H gm hai este n chc thuc cng dy ng ng lin tip v
mt amino axit Z thuc dy ng ng ca glyxin (MZ > 75) cn ng 1,09 mol O2, thu c CO2 v
H2O vi t l mol tng ng 48 : 49 v 0,02 mol kh N2. Cng lng H trn cho tc dng ht vi dung
dch KOH, c cn dung dch sau phn ng c m gam rn khan v mt ancol duy nht. Bit KOH dng
d 20% so vi lng phn ng. Gi tr ca m l
A. 38,792 B. 34,760 C. 31,880 D. 34,312
Cu 32: Nung bt Fe2O3 vi a gam bt Al trong kh tr, thu c 11,78 gam hn hp rn X. Cho ton b
X vo lng d dung dch NaOH, thu c 1,344 lt H2 (ktc). Bit cc phn ng u xy ra hon ton.
Gi tr ca a l
A. 1,95. B. 3,78. C. 2,43. D. 2,56.
Cu 33: Cho cc pht biu sau y:
(a) Glucozo c gi l ng nho do c nhiu trong qu nho chn.
(b) Cht bo l ieste ca glixerol vi axit bo.
(c) Phn t amilopectin c cu trc mch phn nhnh..
(d) Trong mt ong cha nhiu fructozo.
(e) Tinh bt l mt trong nhng lng thc c bn ca con ngi.
S pht biu ng l
A. 5 B. 6 C. 3 D. 4
Cu 34: X l dung dch HCl nng x mol/l. Y l dung dch gm Na2CO3 v NaHCO3 c cng nng
y mol/l. Nh t t n ht 100 ml X vo 100 ml Y, thu c V lt kh CO2 (ktc). Nh t t n ht 100
ml Y vo 100 ml X, thu c 2V lt kh CO2 (ktc). T l x : y bng
A. 8 : 5. B. 6 : 5. C. 4 : 3. D. 3 : 2.
Cu 35: Cho dy cc cht : Al, Al(OH)3, Zn(OH)2, NaHCO3 v Na2SO4. S cht trong dy va phn
ng vi dung dch HCl va phn ng vi dung dch NaOH l :
A. 2 B. 5 C. 3 D. 4
Cu 36: Protein l c s to nn s sng v hai thnh phn chnh ca t bo l nhn v nguyn sinh
cht u hnh thnh t protein. Protein cng l hp cht chnh trong thc n con ngi. Trong phn t
protein, cc gc aminoaxit c gn vi nhau bng lin kt
A. Glicozit B. Hidro C. Amit D. Peptit
Cu 37: Gia tinh bt, saccarozo, glucozo c c im chung no sau y:
A. Chng u thuc loi cacbohidrat
B. Chng u tc dng vi Cu(OH) 2 cho dung dch mu xanh lam
C. u b thy phn trong mi trng xit
D. u khng tham gia phn ng trng bc
Cu 38: Cho cc cp cht :
(1) dung dch FeCl3 v Ag (2) dung dch Fe(NO3)2 v dung dch AgNO3
(3) S v H2SO4 (c nng) (4) CaO v H 2O
(5) dung dch NH3 + CrO3 (6) S v dung dch H2SO4 long
S cp cht c xy ra phn ng l:
A. 5 B. 4 C. 2 D. 3
Cu 39: rut non ca c th ngi nh tc dng xc tc ca cc enzim nh lipaza v dch mt, cht
bo b thy phn thnh :
A. axit bo v glixerol B. axit cacboxylic v glixerol
C. CO2 v H2O D. NH3, CO2 v H2O
Cu 40: Pht biu no sau y khng ng ?
A. Cc peptit m phn t ch cha t 11 n 50 gc -aminoaxit c gi l polipeptit.
B. Cc protein u l cht rn, nhit nng chy cao v d tan trong nc.
C. Peptit mch h phn t cha hai gc -aminoaxit c gi l ipeptit.
D. Peptit mch h phn t cha hai lin kt peptit CO-NH c gi l ipeptit.
PHN TCH HNG DN GII
THI TH THPT THANH CHNG NGH AN LN 1
Cu 1: Chn D.
A. ng, Cc kim loi kim v kim th (Ba, Ra) c cu trc mng tinh th lp phng tm khi.
B. ng, Phng php c bn iu ch kim loi kim, kim th l in phn nng chy mui clorua
ca chng: 2MCln 2M + nCl2.
C. ng, Nhit nng chy ca cc kim loi kim gim dn t Li n Cs.
D. Sai, Tt c cc nguyn t kim loi kim th (tr Be) u tc dng vi nc gii phng kh H 2.
Cu 2: Chn B.

- Khi cho kim loi M (Fe) tc dng vi phi kim X (Cl2) :
to
Fe + Cl2 FeCl3 Fe + FeCl3
FeCl2
- Ha tan Y vo nc c dung dch Z gm FeCl2, FeCl3.
- Thm AgNO3 d vo dung dch Z :
FeCl3 + 3AgNO3 Fe(NO3)3 + 3AgCl FeCl2 + 3AgNO3
Fe(NO3)3 + 2AgCl + Ag
- em cht rn G gm AgCl, Ag vo dung dch HNO 3 c nng d :
Ag + 2HNO3 AgNO3 + NO2 + H2O AgCl + HNO3: khng phn ng
Cht rn F l AgCl.
Cu 3: Chn C.
- Cc phn ng xy ra:
(1) Cu + 2H2SO4 c, ngui
CuSO4 + SO2 + 2H2O
(5) Cu + 4HNO3 c, ngui
Cu(NO3)2 + 2NO2 + 2H2O
(2) Cu(OH)2 + 2C6H12O6
(C6H11O6)2Cu + 2H2O
(6) CH3COOH + NaOH CH3COONa + H2O
(3) Gly-Gly-Gly + Cu(OH)2/NaOH : to phc mu tm
(7) 3AgNO3 + FeCl3
3AgCl + Fe(NO3)3
(4) 3Fe2+ + 4H+ + NO3
3Fe3+ + NO + 2H2O
(8) 2Al + Cr2(SO4)3 Al2(SO4)3 + 2Cr
Vy c 8 phn ng u xy ra iu kin thng.
Cu 4: Chn A.
Nhng cht tham gia phn ng thy phn:
- Este, cht bo b thy phn trong mi trng axit v mi trng kim.
- isaccarit, polisaccarit (saccaroz, mantoz, tinh bt, xenluloz) b thy phn trong mi trng
axit
- Peptit v protein thy phn trong mi trng axit, ln mi trng kim. Nu thy phn khng hon
ton peptit trong mi trng axit th thu c cc peptit nh hn v hn hp cc amino axit.
Cu 5: Chn C.
Kim loi c nhng tnh cht vt l chung l : tnh dn in, dn nhit, nh kim v tnh do. Cc tnh
cht trn u do cc electron t do trong kim loi gy ra.
Cu 6: Chn C.
- Cho m gam X vo dung dch Y ta c : nOH 2nH 2 0,08mol
Ca2 OH HCO3
CaCO3 H 2O
0,07mol 0,08mol 0,12mol 0,07mol

BT:e
nK 2nCa 2nH2 nK 2nCa 0,08 nK 0,02mol
BT:C mX 39nK 40nCa 1,98(g)
n n n n 0,03 n 0,03mol
Ca Ca2 CaCl 2 Ca Ca
Cu 7: Chn A.
- lu anilin ngoi khng kh th anilin chuyn sang mu nu en v b oxi ha bi oxi khng kh.
Cu 8: Chn C.
TH1 : Cl2 phn ng vi Br- trc.
Khi dung dch sau phn ng gm Fe 2+ (0,06 mol), Cl- (0,04 mol) v Br- (0,08 mol)
- Cho A tc dng vi AgNO3 th : nAg nFe2 0,06mol,nAgCl 0,04mol v nAgBr 0,08mol .
Vy m 188nAgBr 143,5nAgCl 108nAg 27,26(g)
TH2 : Cl2 phn ng vi Fe2+ trc.
Khi dung dch sau phn ng gm Fe2+ (0,02 mol), Fe3+ (0,04 mol) Cl- (0,04 mol) v Br- (0,12 mol)

Vy m 188nAgBr 143,5nAgCl 108nAg 30,46(g)
Suy ra 27,26 m 30,26
Cu 9: Chn D.
A. Saccaroz khng lm mt mu nc brom.
B. Xenluloz l mt polime to thnh t cc mt xch glucoz bi cc lin kt 1,4glicozit.
c cu trc mch khng phn nhnh, khng xon.
C. Tinh bt l hn hp gm amiloz v amilopectin. Amiloz chim t 20 30% khi lng tinh bt.
Trong phn t amilozo cc gc glucoz ni vi nhau bi lin kt 1,4glicozit to thnh mt chui
mch di khng phn nhnh. Amilopectin chim khong 70 80% khi lng tinh bt. Amilopectin c
cu to phn nhnh v c ni vi nhau bi lin kt 1,4glicozit v 1,6glicozit.
D. Glucoz b oxi ha bi dung dch AgNO3 trong NH3.
Cu 10: Chn C.
It
- Ta c ne 0,12mol . Qu trnh in phn xy ra nh sau :
96500
Ti catot Ti anot
Fe 3+
+ e Fe 2+
H2O 4H + O2
+
+ 4e
0,06 0,06 0,06 0,03 0,12
Cu 2+
+ 2e Cu
0,02 0,04 0,02
Fe 2+
+ 2e Fe
0,02 0,01
Vy mdung dch gim = 64nCu 56nFe 32nO2 2,8(g)
Cu 11: Chn A.
C 3 cu to ca X tha mn l : GlyGlyGlyAla, AlaGlyGlyGly v GlyAlaGlyGly.
Cu 12: Chn C.
Cu 13: Chn C.
- iu kin xy ra n mn in ha l:
+ C cc cp in cc khc nhau v bn cht, c th l kim loi kim loi, kim loi phi kim. Kim
+ Cc cp in cc phi tip xc trc tip hoc gin tip vi nhau thng qua dy dn.
+ Cc in cc phi cng tip xc vi mt dung dch cht in li.
(1) Xy ra qu trnh n mn in ha: Fe + CuCl2 FeCl2 + Cu
- Khi Cu gii phng ra bm vo thanh Fe th hnh thnh v s cp pin in ha Fe Cu.
+ cc m (anot) xy ra s oxi ha Fe: Fe Fe2 2e
+ cc dng (catot) xy ra s kh Cu2+ : Cu 2 2e Cu
(2) Xy ra qu trnh n mn ha hc: Fe + 2FeCl3 3FeCl2
(3) Va xy ra qu trnh n mn in ha v qu trnh n mn ha hc:
+ Qu trnh n mn ha hc : Fe + HCl FeCl2 + H2.
+ Qu trnh n mn in ha tng t nh (2).
(4) Khng xy ra qu trnh n mn, pt phn ng : FeCl 3 + AgNO3 Fe(NO3)3 + AgCl
(5) Cho thp (hp kim ca Fe v C) vo dung dch HCl xut hin s n mn in ha:
- Anot l Fe ti anot xy ra s oxi ha Fe : Fe Fe 2+ + 2e
2OH H2
- Catot l C ti anot xy ra s kh H + : 2H2O 2e
Vy, c 3 th nghim m Fe khng xy ra qu trnh n mn in ha l (1), (3) v (5).
Cu 14: Chn B.
A. ng, khi cho dung dch axit nitric c vo dung dch lng trng trng thy c kt ta mu vng
xut hin.
B. Sai, trn ln lng trng trng, dung dch NaOH v c mt t CuSO 4 thy xut hin mu tm xanh
c trng.
C. ng, un nng lng trng trng thy xut hin kt ta l do hin tng ng t ng t
protein.
D. ng, v thnh phn ca tc v da l protein nn khi t c mi kht.
Cu 15: Chn B
- Dung dch X gm BaCl2 (0,5a mol) v Ba(OH)2 (0,5a mol)
- C 6 cht tc dng c vi dung dch X l Na2SO4, Na2CO3, Al, Al2O3, AlCl3 v NaHCO3.
Ba2+ + SO42- BaSO4 Ba2+ + CO32- BaCO3
Ba(OH)2 + Al + H2O Ba(AlO2)2 + H2 Ba(OH)2 + Al2O3 Ba(AlO2)2 + H2O
3Ba(OH)2 + 2AlCl3 3BaCl2 + 2Al(OH)3 Ba(OH)2 + NaHCO3 BaCO3 + H2O
Cu 16: Chn D.
HCOOCH-CH(CH3)-OOCH (X) + 2NaOH 2HCOONa (X 1) + HOCH2-CH(OH)-CH3 (X2)
0
HOCH2-CH(OH)-CH3(X2) + O2 Cu,t
OHC-CO-CH3 (X3) + 2H2O.
A. ng, X l este a chc, c kh nng lm mt mu nc brom.
B. ng, X1 l HCOONa v M X1 68 .
C. ng, HOCH2-CH(OH)-CH3 (X2) l ancol hai chc c mch C khng phn nhnh.
D. Sai, OHC-CO-CH3 (X3) l hp cht hu c tp chc.
Cu 17: Chn A.
- Cho t t a mol HCl vo b mol Na 2CO3 th : nCO2 (1) nHCl nNa2CO3 nCO2 b a
nHCl
- Cho t t b mol Na2CO3 vo a mol HCl th : nCO2 (2) 0,5b
2
nCO2 (1) V 1 ba 1
- Theo bi ta c : a 0,75b
nCO2 (2) 2V 2 0,5b 2
Cu 18: Chn C.
800.0,05
- Ta c: nCuSO4 0,25mol mCuSO4 .5H 2O 62,5(g)
160
Cu 19: Chn A.
0
- Phn ng : Gly Ala 2NaOH
t
GlyNa AlaNa H 2O
mmui 97nGlyNa 111nAlaNa 20,8(g)
Cu 20: Chn D.
- Nicotin (C10H14N2)c nhiu trong cy thuc l. Cu to ca n:
- Nicotin l cht lng snh nh du, khng mu, c mi thuc l, tan c trong nc. Khi ht thuc l,
nicotin thm vo mu v theo dng mu i vo phi. Nicotin l mt trong nhng cht c cc mnh (t 1
n 2 git nicotin c th git cht mt con ch), tnh c ca n c th snh vi axit xianhiric HCN.
- Nicotin ch l mt trong s cc cht ha hc c hi c trong khi thuc l (trong khi thuc l c cha
ti 1400 hp cht ha hc khc nhau). Dung dch nicotin trong nc c dng lm thuc tr su cho
cy trng. Nhng ngi nghin thuc l thng mc bnh ung th phi v nhng bnh ung th khc.
Cu 21: Chn B.
- Khi cho 16,55 gam X tc dng vi dung dch cha 0,775 mol KHSO 4 th hn hp kh Z thu c gm
NO (0,0125 mol) v H2 (0,1 mol). Xt qu trnh phn ng ta c :

mX 136nKHSO4 mmui mZ n 2nH2O 2nH2
BTKL
nH2O 0,2625mol nNH4 KHSO4 0,0125
18 4
- Xt hn hp rn X ta c :
nNH 4 nNO nO(trong oxit) nKHSO4 4nNO 2nH 2 10nNH 4
BT:N
nFe(NO3 )2 0,0125 mol vnFe3O4 0,05mol
2 4 8
m 232nFe3O4 nFe(NO3 )2
nAl X 0,1mol
27
- Khi ha tan hn hp rn X vo nc th : 2Al 3Fe(NO3 )2
2Al(NO3 )3 3Fe
0,1mol 0,0125mol 1
mol
120
- Vy hn hp rn sau phn ng hn hp rn sau phn ng gm Fe 3O4(khng tan), Al(d) v Fe
BTKL
mrn mX 213nAl(NO3 )3 14,875(g)
Cu 22: Chn B.
15,6
BT:e
nX 2nH2 0,4 M X 39 . Vy X l K
0,4
Cu 23: Chn B.
Este c CTPT C2H4O2 ch c mt ng phn l HCOOCH 3 (metyl fomat)
Cu 24: Chn D
mM 2nH2O 16nO(trongM) 22,32 2.0,8 16(4nX nY )
- Khi t 22,32 gam M th : nCO2
12 12
22,32 2.0,8 16(4nX nY )
nCO2 nH 2O 2nX nY 0,8 2nX nY 88nX 4nY 11,12(1)
12
- Khi cho lng M trn tc dng vi K d th : 2nX nY 2nH2 0,38(2)
- T ta gii h (1) v (2) c : nX 0,12mol v nY 0,14mol , suy ra nCO2 0,9mol .
- Xt hn hp M ta c :
BT:C
anX bnY nCO2 0,12a 0,14b 0,9 a 4 v b=3
- Vy X v Y ln lt l : HOOC CH CH COOH (0,12mol) v C3H7OH(0,14mol)
0,14.60
%mC3H7OH(Y ) .100 37,63
22,32
Cu 25: Chn A.
B. Sai, Tinh bt v xenluloz u c cng thc phn t ca mi mc xch l C6H10O5, nhng gi tr n
(s mc xch) ca tinh bt v xenlulz khc nhau nn tinh bt v xenlulz khng l ng phn ca
nhau.
C. Sai, Xenluloz c to bi cc gc -glucoz lin kt vi nhau bi lin kt - 1,4-glicozit.
D. Sai, Thy phn n cng amylopectin ch thu c glucz
Cu 26: Chn C.
Dung dch Na2CO3 Dung dch Ca(HCO3)2
A. dung dch NaHCO3. Khng hin tng Khng hin tng
B. dung dch Ca(OH)2. Kt ta trng Kt ta trng
C. dung dch NaOH. Khng hin tng Kt ta trng
D. dung dch NaCl. Khng hin tng Khng hin tng
Cu 27: Chn A.
m mX 5,4
- Ta c nX mui 0,12mol M X 45 . Vy CTPT ca X l C2H7N
36,5 0,12
- X c hai ng phn l C2H5NH2 v (CH3)2 NH
Cu 28: Chn A.
- Gi CTCT ca X l (NH2 )a R(COOH)b .
nHCl n
- Cho 0,01 mol X ln lt tc dng vi HCl v NaOH ta c : a 1 v b= NaOH 2
nX nX
- Khi cho 0,03 mol X tc dng vi 0,0675 mol NaOH ta c : nH2O 2nX 0,06mol
4,41
BTKL
mX mrn khan 18nH2O 40nNaOH 4,41(g) M X 147 R l C3H 5.
0,03
- Vy CTCT ca X l NH2C3H5(COOH)2
Cu 29: Chn A
3M N 3.14
- MA 217 , vy peptit A l Gly(Ala)2
%N 0,1936
4M N 4.14
- MB 288 , vy peptit B l Gly(Ala)3
%N 0,1944
- Khi cho 0,1 mol X tc dng vi NaOH th :
n A nB n X nA nB 0,1
n 0,06 3
A
97nGlyNa 111nAlaNa mmui 97(nA nB ) 111(2nAla 3nAla ) 36,34
nB 0,04 2
Cu 30: Chn D.
Cu(d )
Fe2O3,Cu
Fe2 ,Cu2 ,H (d ) ,Cl
HCl

AgNO3
Fe3 ,Cu2 ,NO3 NO Ag,AgCl
hn h p H 40,36(g)cht tan dung dch sau phn ng 0,01mol m(g) Z
Ta c :
mcht tan 36,5nHCl(d ) 40,36 0,04.36,5
nHCl(d ) 4nNO 0,04mol nFe2O3 nCu(p ) 0,1mol
2M FeCl 2 M CuCl 2 389

BT:e
nAg nFeCl 2 3nNO 0,2 0,01.3 0,17mol
BT:Cl m 108nAg 143,5nAgCl 110,2(g)
n AgCl nHCl 6nFe O

2 3
nHCl(d ) 0,64mol
Cu 31: Chn A
- Khi t hn hp H th :

BTKL
44nCO2 18nH 2O mH 32nO2 28nN 2
44nCO2 18nH 2O 59,88 nCO2 0,96mol
+ nCO2 48
n 49nCO2 48nH 2O 0 nH 2O 0,98 mol
H 2O 49

BT:N
namino axit 2nN 2
namino axit 0,04mol
+ mH 12nCO2 2nH2O 28nN2 n 0,32 mol
namino axit neste nCOO este
32
n
- Ta c CH CO2 2,666 m Camino axit 2 nn trong H c cha HCOOCH3 v CH3COOCH3.
nH
- Khi cho H tc dng vi lng d dung dch KOH th :
+ nCH3OH neste 0,36
BTKL
mrn mH 1,2.56.nKOH 32nCH3OH 18nH2O 38,972(g)
Cu 32: Chn B.
BT:e 102nAl 2O3 56nFe mX 27nAl(d ) 10,7 nAl 3O3 0,05
nAl(d ) 1,5nH2 0,04
nAl 2O3 2nFe nFe 0,1

BT;Al
nAl(ban u) 2nAl 2O3 nAl(d ) 0,14 mAl(ban u) 3,78(g)
Cu 33: Chn D.
C 4 pht biu ng l (a), (c), (d) v (e).
(b) Sai, Cht bo l trieste ca glixerol vi axit bo.
Cu 34: Chn D.
0,1y mol 0,1mol
V
- Nh t t X vo Y: HCl Na2CO3 ,NaHCO3 nCO2 nH nCO32 0,1x 0,1y (1)
0,1x mol 22,4
dung dch Y
- Nh t t Y vo X. Gi a s mol ca Na2CO3 v NaHCO3 phn ng:
amol amol 3a 0,1x
2nCO32 nHCO3 nH

Na2CO3 ,NaHCO3 HCl 2V (2)
n 2 n nCO
2a
dung dch Y 0,1x mol CO3 HCO3 2
22,4
- Thay (2) vo (1) suy ra x : y 3 : 2
Cu 35: Chn D.
* Cc hp cht lng tnh thng gp :
- Cc hidroxit lng tnh: Al(OH)3. Zn(OH)2. Cr(OH)3, Sn(OH)2, Pb(OH)2, Be(OH)2
- Cc oxit lng tnh : Al2O3, ZnO, Cr2O3, BeO, PbO, SnO
- Cc mui c nhng gc axit sau : HCO3-, HPO42-, H2PO4-, HS-, HSO3-.
- Mui lng tnh (c to thnh t axit yu v baz yu) : HCOONH4, CH3COONH3CH3, (NH4)2-
CO3
Lu : + Cc kim loi Al, Zn, Sn, Pb, Be khng phi l cht lng tnh.
+ HPO2- c tnh baz, HSO4- c tnh axit, kim loi v este khng phi l cht lng tnh.
Vy Zn(OH) 2 cht lng tnh.
Vy c 4 cht va phn ng vi dung dch HCl va phn ng vi dung dch NaOH l :
Al, Al(OH)3, Zn(OH)2 v NaHCO3
Cu 36: Chn D.
Lin kt ca nhm CO vi nhm NH gia hai n v - amino axit c gi l lin kt peptit, cn cc
lin kt amit c to thnh t cc aminoaxit khng phi dng hoc t cc hp cht iaxit v iamin.
Cu 37: Chn A.
Cu 38 : Chn B.
C 4 cp cht xy ra phn ng l (2), (3), (4) v (5).
(1) FeCl3 + Ag khng phn ng (2) Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag.
(3) S + H2SO4(c, nng) SO2 + H2O (4) CaO + H2O Ca(OH)2
(5) NH3 + CrO3 Cr2O3 + N2 + H2O (6) S + H2SO4(long) khng phn ng.
Cu 39: Chn A.
Qu trnh thy phn cht bo trong c th ngi xy ra nh sau :
0
(RCOO)3C3H5 + NaOH t
3RCOONa C3H 5 (OH)3
Cu 40: Chn C.
A. Sai, peptit c chia thnh hai loi :
* Oligopeptit gm cc peptit gm cc peptit c t 2 10 gc aminoaxit.
* Polipeptit gm cc peptit c t 11 n 50 gc aminoaxit. Polipeptit ca protein.
B. Sai, Protein c chia lm 2 loi : dng protein hnh si v protein hnh cu
Protein hnh cu gm : abumin (long trng trng g), hemoglobin (mu)
Protein hnh si gm : keratin (tc, mng, sng), fibroin (t tm, mng nhn)
- Tnh tan : Protein hnh si hon ton khng tan trong nc, ngc li cc protein hnh cu tan trong
nc to thnh dung dch keo.
C. ng, nu peptit c n mc xch th s c (n 1) lin kt peptit nn ipeptit s c 1 lin kt peptit.

D. Sai, peptit mch h phn t cha hai lin kt peptit CO-NH c gi l tripeptit.
----------HT----------

S GD T TP. H NI THI TH LN 1 QUC GIA NM 2017
TRNG THPT CHUYN Mn: KHOA HC T NHIN HA HC
KHOA HC T NHIN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 357
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: t chy hon ton este no, n chc, mch h (X) thy th tch O2 cn t gp 1,25 th tch
CO2 to ra. S lng cng thc cu to ca X l:
A. 4 B. 3. C. 5. D. 6.
Cu 2: Ly 7,8 gam kali tc dng hon ton vi nc thu c V lt kh (ktc). Gi tr ca V l:
A. 2,24 lt. B. 1,12 lt. C. 0,56 lt. D. 4,48 lt.
Cu 3: Cht no sau y khng c phn ng thy phn ?
A. Gly-Ala. B. Saccaroz. C. Tristearin. D. Fructoz.
Cu 4: Cho m gam fructoz tc dng vi H 2 (xc tc Ni, t0, hiu sut 80%) thu c 36,4 gam sobitol.
Gi tr ca m l:
A. 45,0. B. 36,0. C. 45,5. D. 40,5.
Cu 5: Ha tan ht a mol Al vo dung dch X vo dung dch cha 2a mol NaOH thu c dung dch X.
Kt lun no sau y l ng ?
A. Sc CO2 d vo dung dch X thu c a mol kt ta.
B. Dung dch X khng phn ng vi dung dch CuSO 4.
C. Thm 2a mol HCl vo dung dch X thu c 2a/3 mol kt ta.
D. Dung dch X lm qu tm chuyn sang mu .
Cu 6: Nc thi cng nghip thng cha cc ion kim loi nng nh Hg 2+, Pb2+, Fe3+... x l s b
nc thi trn, lm gim nng cc ion kim loi nng vi chi ph thp, ngi ta s dng cht no sau
y ?
A. Ca(OH)2. B. NaCl. C. HCl. D. KOH.
Cu 7: Mt chn s c khi lng m 1 gam. Cho vo chn mt hp cht X, cn li thy c khi lng
m2 gam. Nung chn trong khng kh n khi lng khng i, ri ngui chn, cn li thy nng
m3 gam, bit m1 < m3 < m2. C bao nhiu cht trong cc cht cho sau y tha mn th nghim trn:
NaHCO3, NaNO3, NH4Cl, I2, K2CO3, Fe, Fe(OH)2 v FeS2 ?
A. 5. B. 6. C. 4. D. 3.
Cu 8: Thnh phn chnh ca qung Mandehit l:
A. FeCO3. B. Fe2O3. C. FeS2. D. Fe3O4.
Cu 9: Cht no sau y phn ng vi Cu(OH) 2 / NaOH to dung dch mu tm ?
A. Anbumin. B. Glucoz. C. Glyxyl alanin. D. Axit axetic.
Cu 10: Cho dung dch mui X n d vo dung dch mui Y, thu c kt ta Z. Cho Z vo dung
dch HNO3 (long, d), thu c cht rn T v kh khng mu ha nu trong khng kh. X v Y ln
lt l :
A. AgNO3 v Fe(NO3)2. B. AgNO3 v FeCl2. C. AgNO3 v FeCl3. D. Na2CO3 v BaCl2.
A. CH2=C(CH3)COOCH3. B. CH2=CH-CN.
C. CH2=CH-Cl. D. H2N-(CH2)6-COOH.
Cu 12: Amin no sau y tn ti trng thi kh iu kin thng ?
A. anilin. B. iso propyl amin. C. butyl amin. D. trimetyl amin.
Cu 13: Pht biu khng ng l :
A. Cc kim loi Na, K, Ba c cu trc mng tinh th lp phng tm khi.

B. Phng php c bn iu ch kim loi kim th l in phn nng chy mui clorua ca chng.
C. Nhit nng chy ca cc kim loi kim gim dn t Li & Cs.
D. Tt c cc nguyn t kim loi kim th u tc dng vi nc gii phng kh H 2.
A. 5. B. 7. C. 8. D. 6.
Cu 16: Cho a mol st tc dng vi a mol kh clo, thu c hn hp rn X. Cho X vo nc, thu c
dung dch Y. Bit cc phn ng xy ra hon ton. Dung dch Y khng tc dng vi cht no sau y ?
A. AgNO3. B. Cu. C. NaOH. D. Cl2.
Cu 17: Cho hn hp M gm Fe2O3, ZnO v Fe tc dng vi dung dch HX (long) thu c dung
dch Y, phn kim loi khng tan Z v kh T. Cho Y tc dng vi lng d dung dch AgNO 3 c cht
rn Q. Cho Q vo dung dch HNO3 d thy thot kh NO v cht rn G mu trng. Axit HX v cht rn
trong Q l :
A. HCl v Ag. B. HCl v AgCl, Ag. C. HCl v AgCl. D. HBr v AgBr, Ag.
Cu 18: Phn ng no sau y l sai ?
A. Cu + 4HNO3 c ngui Cu(NO3)2 + 2NO2 + 2H2O.
B. 4Fe(OH)2 + O2 + 2H2O 4Fe(OH)3.
C. 3Zn + 2CrCl3 2Cr + 3ZnCl2.
D. CuO + 2HCl CuCl2 + H2O.
Cu 19: Cho cc kim loi : Al, Cu, Au, Ag. Kim loi dn in tt nht trong cc kim loi ny l :
A. Ag. B. Cu. C. Al. D. Au.
Cu 20: Cht no sau y trng thi rn iu kin thng ?
A. Glyxin. B. Triolein. C. Etyl aminoaxetat. D. Anilin.
Cu 21: Ha tan hon ton hn hp X (gm x mol Fe, y mol Cu, z mol Fe 2O3, v t mol Fe3O4) trong
dung dch HCl khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui. Mi
quan h gia s mol cc cht c trong hn hp X l :
A. x + y = 2z + 2t B. x + y = z + t C. x + y = 2z + 2t D. x + y = 2z + 3t
b l :
A. a = 0,75b. B. a = 0,8b. C. a = 0,35b. D. a = 0,5b.
l :
A. 20,8 B. 18,6 C. 22,6 D. 20,6
Cu 25: Ngi ht thuc l nhiu thng mc cc bnh nguy him v ng h hp. Cht gy hi ch
yu c trong thuc l l :
A. Mophin. B. Heroin. C. Cafein. D. Nicotin.
A. Trong phn ng este ha t ancol v axit, phn t nc c ngun gc t nhm OH ca axit
cacboxylic.

B. Khng th iu ch c phenyl axetat t phenol v axit axetic.
C. Phn ng este ha gia axit cacboxylic v ancol l phn ng thun nghch.
D. Thy phn este n chc trong mi trng baz lun cho sn phm l mui v ancol.
Cu 27: Cho 17,6 gam hn hp X gm Fe v Cu phn ng vi dung dch HCl long (d), n khi phn
ng xy ra hon ton thu c 4,48 lt kh H 2(ktc) v dung dch cha m gam mui. Gi tr m l :
Cu 28: Cht X (c M = 60 v cha C, H, O). Cht X phn ng c vi Na, NaOH, v NaHCO 3. Tn
gi ca X l :
A. axit axetic B. axit fomic C. metyl fomat D. metyl axatat
Cu 29: t chy hon ton m gam hn hp A gm xenluloz, tinh bt, glucoz v saccaroz cn 2,52
lt O2 (ktc) thu c 1,8 gam H 2O. Gi tr m l
A. 6,20 B. 5,25 C. 3,60 D. 3,15
Cu 30: Benzyl axetat l mt este c mi thm ca ha nhi. Cng thc cu to ca benzyl axetat l
A. CH3COOC6H5 B. CH3COOCH2C6H5 C. C6H5CH2COOCH3 D. C6H5COOCH3
Cu 31: in phn mt lng d dung dch MgCl 2 (in cc tr, c mng ngn xp bao in cc) vi
cng dng in 2,68A trong 2 gi. Sau khi dng in phn khi lng dung dch gim m gam, gi
thit nc khng bay hi, cc cht tch ra u khan. Gi tr ca m l :
A. 8,7 B. 18,9 C. 7,3 D. 13,1
Cu 32: Ha tan m gam hn hp gm Na v Ba vo nc thu c dung dch X. Sc kh CO2 vo dung
dch X. Kt qu th nghim c biu din theo th sau:
n BaCO3
0,5
n CO2
0 0,4a a 2a x
Gi tr ca m v x ln lt l :
A. 228,75 v 3,0 B. 228,75 v 3,25 C. 200 v 2,75 D. 200,0 v 3,25
Cu 33: Hn hp X gm Al, Ca, Al4C3 v CaC2. Cho 15,15 gam X vo nc d, ch thu c dung
dch Y v hn hp kh Z (C2H2, CH4, H2). t chy ht Z, thu c 4,48 lt CO2(ktc) v 9,45 gam
H2O. Nh t t 200ml dung dch HCl 2M vo Y, thu c m gam kt ta. Gi tr m l :
A. 15,6 B. 19,5 C. 27,3 D. 16,9
Cu 34: Cho m gam hn hp M (c tng s mol 0,03 mol) gm ipeptit X, tripeptit Y, tetrapeptit Z v
pentapeptit T (u mch h) tc dng vi dung dch NaOH va , thu c hn hp Q gm mui ca
Gly, Ala v Val. t chy hon ton Q bng mt lng oxi va , thu ly ton b kh v hi em hp
th vo bnh ng nc vi trong d, thy khi lng tng 13,23 gam v c 0,84 lt kh(ktc) thot ra.
Gi tr ca m gn nht vi gi tr no sau y ?
A. 6,0 B. 6,9 C. 7,0 D. 6,08
Cu 35: Hp cht hu c X mch h c cng thc phn t C4H6O4. Bit rng khi un X vi dung dch
bazo to ra hai mui v mt ancol no n chc mch h. Cho 17,7 gam X tc dng vi 400 ml dung
dch NaOH 1M, c cn dung dch sau phn ng thu c khi lng cht rn khan l :
Cu 36: Cho ln men 45 gam glucoz iu ch ancol etylic, hiu sut phn ng 80%, thu c V lt
CO2 (ktc). Gi tr ca V l :
A. 11,20 B. 5,60 C. 8,96 D. 4,48
Cu 37: X gm hai aminoaxxit no, h (cha mt nhm -NH2, mt nhm COOH) l Y v Z (Bit
MZ = 1,56MY). Cho a gam X tc dng 40,15 gam dung dch HCl 20% thu c dung dch A. tc
dng ht cc cht trong dung dch A cn 140 ml dung dch KOH 3M. Mt khc, t chy hon ton a

gam X thu c sn phm chy gm CO 2, H2O, N2 c dn qua bnh ng dung dch Ca(OH) 2 d
thy khi lng bnh tng 32,8 gam. Phn t khi ca Z l :
A. 117 B. 139 C. 147 D. 123
Cu 38: Cho 8,28 gam cht hu c A cha C, H, O (c CTPT trng CTG) tc dng vi dung dch
NaOH va , sau chng kh, phn hi thu c ch c nc, phn cht rn khan khi lng 13,32
gam. Nung lng cht rn ny trong oxi d, sau phn ng hon ton thu c 9,54 gam Na 2CO3; 14,52
gam CO2 v 2,7 gam nc. Cho phn cht rn trn vo dung dch H 2SO4 long d thu c hai cht
hu c X, Y (bit MX < MY).S nguyn t hiro c trong Y l :
A. 6 B. 8 C. 10 D. 2
Cu 39: ha tan ht 38,36 gam hn hp R gm Mg, Fe3O4, Fe(NO3)2 cn 0,87 mol dung dch
H2SO4 long, sau khi cc phn ng xy ra hon ton thu c 111,46 gam sunfat trung ha v 5,6 lt
(ktc) hn hp kh X gm hai kh khng mu, t khi hi ca X so vi H2 l 3,8 (bit c mt kh khng
mu ha nu ngoi khng kh).Phn trm khi lng Mg trong R gn vi gi tr no sau y ?
A. 31,28 B. 10,8 C. 28,15 D. 25,51
Cu 40: Cho 26 gam hn hp cht rn A gm Ca, MgO, Na2O tc dng ht vi dung dch HCl 1M
(va ) thu c dung dch A trong c 23,4 gam NaCl. Gi tr ca V l:
A.0,09 B. 1,20 C. 0,72 D. 1,08
----------HT----------
PHN TCH HNG DN GII
THI TH CHUYN KHOA HC T NHIN - H NI LN 1
Cu 1: Chn A.
3n 2
- Phn ng : C n H 2n O 2 O 2 nCO 2 nH 2O
2
mol : 1 (1,5n 1) n
vi n O2 1, 25n CO2 1,5n 1 1, 25n n 4 . Vy X l C4H8O2 c 4 ng phn cu to l:
HCOOCH2CH2CH3 ; HCOOCH(CH3 )CH3 ; CH3COOCH2CH3 ; CH3CH2COOCH3
Cu 2: Chn A.
nK
- Ta c : n H 2 0,1 mol VH 2 2, 24 (l)
2
Cu 3: Chn D.
H
A. H2NCH2CONHCH(CH3)COOH + H2O H2NCH2COOH + H2NCH(CH3)COOH
H
B. Saccaroz: C12H22O11 H2O C6H12O6 (glucoz) + C6H12O6 (fructoz)
H
C17 H35COOH C3H5 (OH)3
C. Tristerin: (C17 H35COO)3 C3H5 H 2O
o
t
D. Fructoz khng tham gia phn ng thy phn.
Cu 4: Chn A.
m sobitol 1
- Ta c : m C6H12O 6 180. . 45 (g)
182 h%
Cu 5: Chn A.
- Phn ng : 2Al + 2NaOH + 2H 2O 2NaAlO2 + 3H2
mol : a 2a a (NaOH d)
- Dung dch X thu c gm: NaAlO2 (a mol) v NaOH d (a mol).

CO 2 NaAlO 2 2H 2O
Al(OH)3 NaHCO3

A. ng, Sc CO2 d vo dung dch X th: a mol a mol
CO 2 NaOH NaHCO3
B. Sai, Trong dung dch X c NaOH d phn ng vi dung dch CuSO 4 :
CuSO4 + NaOH Cu(OH)2 + Na2SO4
C. Sai, Khi thm 2a mol HCl vo dung dch X th :
HCl + NaOH NaCl + H2O HCl + NaAlO2 + H2O Al(OH)3 + NaCl
mol: a a a a a
- Phn ng xy ra va do vy ch c a mol kt ta ca Al(OH) 3.
D. Sai, Dung dch X c NaOH d nn lm qu tm chuyn sang mu xanh.
Cu 6: Chn A.
- x l nc thi c cha cc ion kim loi nng nh Hg2+, Pb2+, Fe3+,... ngi ta s dng dung dch
kim, khi phn ng s xy ra v hnh thnh cc kt ta hiroxit ca kim loi nng, t ta lc b kt
ta i.
- L do s dng Ca(OH)2 m khng s dng KOH hoc NaOH v Ca(OH)2 gi thnh r (mua CaO ngoi
th trng sau cho tc dng vi H2O thu c Ca(OH)2), d s dng v ph bin hn so vi KOH
(NaOH)
Cu 7: Chn C.
- Cc cht I2, K2CO3 khi nung trong khng kh c khi lng khng thay i so vi ban u do vy
khng tha mn iu kin m1 < m3 < m2.
to
- Nu X l NaHCO3 (gi s m2 = 84 gam), nung X: 2NaHCO3 Na2CO3 + CO2 + H2O thu c
s mol ca Na2CO3 : 0,5 mol m3 = 53 gam. Tha iu kin : m1 < m3 < m2.
to
- Nu X l NaNO3 (gi s m2 = 85 gam), nung X: 2NaNO3 2NaNO2 + O2 thu c s mol ca
NaNO2 : 1 mol m3 = 69 gam. Tha iu kin : m1 < m3 < m2.
to
- Nu X l NH4Cl (gi s m2 = 84 gam), nung X: NH4Cl NH3 (kh) + HCl (kh) ngui cn li
th thy khi lng bng ca chn s do vy khng tha iu kin m 1 < m3 < m2.
to
- Nu X l Fe (gi s m2 = 56 gam), nung X: 2xFe + yO2 2FexOy thu c s mol ca FexOy :
1 x 1,2,3 16y
mol vi m3 = 56 > m2 gam. Khng tha iu kin : m1 < m3 < m2.
x y 1,3,4 x
to
- Nu X l Fe(OH)2 (gi s m2 = 90 gam), nung X: 4Fe(OH)2 + O2 2Fe2O3 + 4H2O thu c s
mol ca Fe2O3 : 0,5 mol m3 = 60 gam. Tha iu kin : m1 < m3 < m2.
to
- Nu X l FeS2 (gi s m2 = 120 gam), nung X: 4FeS2 + 11O2 2Fe2O3 + 8SO2 thu c s mol
ca Fe2O3 : 0,5 mol m3 = 60 gam. Tha iu kin : m1 < m3 < m2.
Vy c 4 cht tha mn th nghim trn l: NaHCO 3 ; NaNO3 ; Fe(OH)2 ; FeS2.
Cu 8: Chn D.
- Qung st quan trng l : qung hematit (Fe2O3 khan), qung hematit nu (Fe2O3.nH2O), qung
manhetit (Fe3O4), qung xierit (FeCO3), qung pirit st (FeS2).
Cu 9: Chn A.
- Khi cho anbumin (protein c trong lng trng trng) phn ng vi Cu(OH) 2 to dung dch mu tm.
Cu 10: Chn A.
A. AgNO3 + Fe(NO3)2
Fe(NO3)3 + Ag
3Ag + 4HNO3
3AgNO3 + NO + 2H2O
B. 3AgNO3 + FeCl2
3Ag + 4HNO3
3AgNO3 + NO + 2H2O v AgCl + HNO3 : khng phn ng
C. 3AgNO3 v FeCl3
Fe(NO3)3 + 3AgCl

AgCl + HNO3 : khng phn ng
D. Na2CO3 + BaCl2
BaCO3 + 2NaCl
BaCO3 + 2HCl BaCl2 + CO2 + H2O
Cu 11: Chn A.
Cu 12: Chn D.
- Metyl-, imetyl-, trimetyl- v etylamin l nhng cht kh iu kin thng.
Cu 13: Chn D.
A. ng, Cc kim loi kim v kim th (Ba, Ra) c cu trc mng tinh th lp phng tm khi.
B. ng, Phng php c bn iu ch kim loi kim, kim th l in phn nng chy mui clorua
ca chng: 2MCln 2M + nCl2.
C. ng, Nhit nng chy ca cc kim loi kim gim dn t Li n Cs.
D. Sai, Tt c cc nguyn t kim loi kim th (tr Be) u tc dng vi nc gii phng kh H 2.
Cu 14: Chn B.
to
FeCl2
Cht rn F l AgCl.
Cu 15: Chn C.
- Cc phn ng xy ra:
CuSO4 + SO2 + 2H2O
Cu(NO3)2 + 2NO2 + 2H2O
(2) Cu(OH)2 + 2C6H12O6
(C6H11O6)2Cu + 2H2O
(7) 3AgNO3 + FeCl3
3AgCl + Fe(NO3)3
(4) 3Fe2+ + 4H+ + NO3
3Fe3+ + NO + 2H2O
(8) 2Al + Cr2(SO4)3
Al2(SO4)3 + 2Cr
2a a
2FeCl 3 Hn hp rn X gm: FeCl3:
+ Ban u: 2Fe 3Cl 2 mol v Fe d: mol.
a a 2a 3 3
3
3FeCl 2 Phn ng va nn dd Y cha FeCl2.

+ Sau khi cho nc vo rn X: Fe 2FeCl3
a 2a a
3 3
- em dung dch Y tc dng vi cc cht sau:
FeCl2 + 3AgNO3
Fe(NO3)3 + 2AgCl trng + Ag .
FeCl2 + 2NaOH
Fe(OH)2 trng xanh + 2NaCl
2FeCl2 + Cl2 2FeCl3
Cu + FeCl2: khng phn ng
Cu 17: Chn A.
HCl AgNO3 HNO3
- Qu trnh: Fe2O3, ZnO,Fe FeCl 3,FeCl 2 ,ZnCl 2 Ag,AgCl AgCl
Hn h p M dung dch Y r n Q rn G
Cu 18: Chn C.
Cu 19: Chn A.
- Dy sp xp tnh dn in gim dn : Ag > Cu > Au > Al.
Cu 20: Chn A.
- Triolein, Etyl aminoaxetat, Anilin trng thi lng trong khi Glyxin trng thi rn.
Cu 21: Chn B.
BT:e
2nFe 2nCu 2nFe3O4 2nFe2O3 x y z t

Cu 22: Chn A.
nHCl
2
nCO2 (1) V 1 ba 1
nCO2 (2) 2V 2 0,5b 2
Cu 23: Chn C.
800.0,05
160
Cu 24: Chn A.
0
t
GlyNa AlaNa H 2O
Cu 25: Chn D.
- Nicotin (C10H14N2)c nhiu trong cy thuc l. Cu to ca n:
- Nicotin l cht lng snh nh du, khng mu, c mi thuc l, tan c trong nc. Khi ht thuc l,
nicotin thm vo mu v theo dng mu i vo phi. Nicotin l mt trong nhng cht c cc mnh (t 1
n 2 git nicotin c th git cht mt con ch), tnh c ca n c th snh vi axit xianhiric HCN.
- Nicotin ch l mt trong s cc cht ha hc c hi c trong khi thuc l (trong khi thuc l c cha
ti 1400 hp cht ha hc khc nhau). Dung dch nicotin trong nc c dng lm thuc tr su cho
cy trng. Nhng ngi nghin thuc l thng mc bnh ung th phi v nhng bnh ung th khc.
Cu 26: Chn D.
A. ng, Phn ng:
B. ng, iu ch este t phn ng cho anhiric axetic tc dng vi phenol :

H
(CH3CO)2 O C6H5OH CH3COOC2H5 CH3COOH
C. ng, Phn ng este ha gia axit cacboxylic v ancol l phn ng thun nghch.

D. Sai, Ly v d : HCOOC6H5 + 2NaOH
HCOONa + C6H5ONa + H2O
Cu 27: Chn A.
BT:e
nFe nH2 0,2mol mFeCl 2 127nFe 25,4(g)
Cu 28: Chn A.
2CH 3COOH 2Na
2CH 3COONa H 2 CH 3COOH NaOH
CH 3COONa H 2O
CH 3COOH NaHCO3
CH 3COONa CO 2 H 2O
Cu 29: Chn D.
- Khi t chy hn hp cc cacbohidrat ta lun c : nO2 nCO2 0,1125 mol
BTKL
mA 44nCO2 mH2O 32n O2 3,15(g)
Cu 30: Chn B.
- Cc este thng c mi thm d chu ca tri cy , hoa qu chng hn :
Cu 31: Chn D.
pdd
- Phn ng : MgCl2 + 2H2O Mg(OH)2 + H2 + Cl2
It n
- Ta c : ne trao i 0,2mol nMgCl 2 nCl 2 nH 2 e trao i 0,2mol
96500 2
mdung dch gim 58nMg(OH)2 2nH 2 71nCl 2 13,1(g)
Cu 32: Chn D.
Th t xy ra phn ng:
Ba(OH)2 + CO2
BaCO3 + H2O (1)
mol : a a a
2NaOH + CO2
Na2CO3 + H2O (2)
mol : b 0,5b 0,5b
Na2CO3 + CO2 + H2O
2NaHCO3 (3)
mol : 0,5b 0,5b
BaCO3 + CO2 + H2O Ba(HCO3 )2 (4)
mol : a a
- Lng kt ta tng dn n cc i a mol ng vi phn ng (1), phn ng ny cn a mol CO 2. Lng
kt ta khng thay i mt thi gian ng vi phn ng (2) v (3), phn ng ny cn b mol CO2. Sau
lng kt ta tan dn n ht ng vi phn ng (4), lng CO2 cn dng trong phn ng ny l a mol.
Phn tch th trn nh sau:

- Ti v tr kt ta cc i: n Ba(OH)2 n BaCO3 n CO2 0, 4a 0,5 mol a 1, 25 mol
- Xt on s mol CO2 t a n 2a ta c: n CO2 n NaOH a 1, 25 mol
m 23n Na 137n Ba 200 (g)
- Ti v tr s mol CO2 l x mol th: n BaCO3 n OH n CO 2
n CO 2 x (2n Ba(OH) 2 n NaOH ) n BaCO3 3, 25 mol
Cu 33: Chn D.
- Quy i 15,15 gam hn hp X thnh Ca, Al v C. Xt qu trnh t hn hp kh Z, ta c h sau:
40nCa 27nAl 12nC mX 40nCa 27nAl 12nC 15,15 nCa 0,15mol

nC nCO2 nC 0,2 nAl 3 0,25mol
2n 3n 2n 2n 3n 1,05 n 0,2mol
Ca Al H 2O Ca Al C
- Dung dch Y gm Ca2+ (0,15 mol), AlO2- (0,25 mol) v OH-. Xt dung dch Y c:
BTDT
nOH 2nCa2 nAlO2 0,05mol
- Khi cho 0,4 mol HCl tc dng vi dung dch Y ta nhn thy : nAlO2 nH nOH 4nAlO2
4nAlO2 (nH nOH ) 13
nAl(OH)3 mol mAl(OH)3 16,9(g)
3 60
Cu 34: Chn D.
- Quy i hn hp M thnh C2H3ON (a mol), - CH2 (b mol) v H2O (c mol)
- Hn hp Q thu c ( quy i) gm C 2H4ONa (a mol) v CH2 (b mol). Khi t Q ta c :
nC2H 3ON 2nN 2 a 0,075 a 0,075

nH 2O nM c 0,03 c 0,03
44n 44(1,5a b) 18(2a b) 13,23 b 0,09
CO2 18nH 2O mdd t ng
Vy mM 57nC2H3ON 14n CH 2 18nH 2O 6,075(g)
Cu 35: Chn A.
t0
- Phn ng : HCOO CH 2 COOCH 3 NaOH HCOONa HO CH 2 COONa CH 3OH
BTKL
mrn khan mX 40nNaOH 32nCH3OH 28,9(g)
Cu 36: Chn C.
ln men
- Phn ng : C6H12O6
2C2H 5OH 2CO2
H 80%
0,25mol 0,25.2.0,8mol
VCO2 8,96(l)
Cu 37: Chn A.
- Khi cho X tc dng vi 0,22 mol HCl ri em dung dch thu c tc dng vi 0,42 mol thi :
nA nKOH nHCl 0,42 0,22 0,2mol .
- t CTTQ ca X l CnH2n1O2N , t X th : CnH 2n1O2N
O2
nCO2 (n 0,5)H 2O
0,2mol 0,2n 0,2(n0,5)
- Theo ta c : 44nCO2 18nH2O mdd tng 44.0,2n 18(n 0,5) 32,8 n 2,5
Vy trong X c cha NH2CH2COOH (Y) M Z 1,56M Y 117
Cu 38: Chn A.
- Khi cho 8,28 gam A tc dng vi NaOH th :
m 40nNaOH mrn khan

BTKL
nH 2O(sp khi t c dng v i NaOH) X 0,12mol (v i nNaOH 2nNa2CO3 0,18mol)
18
- Khi t hn hp rn khan th :
BT:H
nH(trong X) nH2O(sp ch y) nH2O(sp phn ng v i NaOH) nNaOH 0,36mol

mX 12nC nH
BT:C
nC(trongX ) nCO2 nNa2CO3 0,42mol nO(trongX ) 0,18mol
16
nC : nH : nO 7: 6: 3 , theo A c CTPT trng vi CTG nht ca A nn CTPT ca A l
C7H6O3
nX 0,06 1 nX 1
- Nhn thy rng v
nNaOH 0,18 3 nH2O(sn phm phn ng v i NaOH) 2
- T cc d kin trn ta suy ra c CTCT ca A l : HCOOC6H4 OH
0
- Phng trnh phn ng: HCOOC6H 4OH(A) 3NaOH t
HCOONa C6H 4 (ONa)2 2H 2O
- Cho hn hp rn qua H2SO4 d thu c HCOOH (X) v C6H4(OH)2 (Y). Vy s nguyn t H trong
Y l 6.
Cu 39: Chn C.
- Hn hp kh X gm 0,2 mol H2 v 0,05 mol NO.
m 98nH2SO4 mmui mX

BTKL
nH2O R 0,57mol
18
- Xt hn dung dch mui v hn hp R c :
2n 2nH 2 2nH 2O n nNO

BT:H
nNH 4 H 2SO4 0,05mol nFe(NO3 )2 NH 4 0,05mol
4 2
nO(trong oxit) 2nH 2SO4 2nH 2 4nNO 10nNH 4
nFe3O4 0,08mol
4 4.2
m 232nFe3O4 180nFe(NO3 )2
%mMg R .100 28,15
mR
Cu 40: Chn D.
n m 62nNa2O

BT:Na
nNa2O NaCl 0,2mol nCa nMgO A 0,34mol
2 40
1,08
- Cho A tc dng vi HCl th : nHCl 2(nNa2O nCa nMgO ) 1,08mol VHCl 1,08(l)
1

TNH QUNG NINH Mn: KHOA HC T NHIN HA HC
THPT CHUYN H LONG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 101
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1 : 1) bng HNO3, thu c V lt X gm

NO, NO2 (o ktc) v dung dch Y (ch cha hai mui v axit d). T khi ca X so vi H2 bng 19.
Gi tr ca V l:
A. 2,24 lt B. 3,36 lt C. 4,48 lt D. 5,6 lt
Cu 2: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1
mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe
v tripeptit Gly-Ala-Val. Peptit x c th l:
A. Gly-Phe-Gly-Ala-Val B. Gly-Ala-Val-Val-Phe
C. Gly-Ala-Val-Phe-Gly D. Val-Phe-Gly-Ala-Gly
A. Cht bo nh hn nc v khng tan trong nc.
B. Cht bo l este ca glixerol v cc axit bo.
C. Hidro hoa hon ton triolein hoc trilinolein u thu c tristearin.
D. Du m ng thc vt b i thiu do ni i C=C gc axit khng no ca cht bo b oxi ha
chm bi oxi khng kh to thnh peoxit cht ny b thy phn thnh cc sn phm c mi kh chu.
Cu 4: Ha tan hon ton 11,2 gam CaO v H 2O d thu c dung dch X. Sc t t kh CO2 vo dung
dch X, qua qu trnh kho st ngi ta lp c th nh sau:
Khi lng kt ta
x 15x S mol CO2

Gi tr ca X l:
A. 0,050 B. 0,040 C. 0,025 D. 0,020
Cu 5: Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO 2 sinh ra
thu c hp th hon ton vo dung dch Ca(OH) 2, thu c 550 gam kt ta v dung dch X. un k
dung dch X thu thm c 100 gam kt ta. Gi tr ca m l:
Cu 6: Tng hp 120 kg polimetylmetacrylat t axit v ancol thch hp, hiu sut ca phn ng este
ha l 30% v phn ng trng hp l 80%. Khi lng ca axit cn dng l:
A. 103,2 kg B. 430 kg C. 113,52 kg D. 160kg
Cu 7: St ty l st trng thit. nu lp thic b xc su ti lp st th kim loi b n mn trc l:
A. C hai u b n mn nh nhau B. Khng kim loi no b n mn
C. Thic D. St
Cu 8: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67
gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc
ca X c th l :
A. (H2N)2C3H5COOH B. H2NC3H5(COOH)2 C. H2NC3H6COOH D. H2NC2H3(COOH)2

Cu 9: Cht X lng tnh, c cng thc phn t C 3H9O2N. Cho 18,2 gam X tc dng va vi dung
dch NaOH, sau phn ng c cn dung dch thu c 16,4 gam mui khan. Tn gi ca X l :
A. Amoni propionat B. Alanin
C. Metylamoni propionat D. Metylamoni axetat
Cu 10: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c
dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH
phn ng l :
Cu 11: Cho Al tc dng vi ln lt cc dung dch axit sau: HCl; HNO 3 long; H2SO4 c, nng;
HNO3 c, ngui; H2SO4 long. S dung dch c th ha tan c Al l:
A. 3 B. 2 C. 5 D. 4
Cu 12: Cho Mg n d vo dung dch cha ng thi Cu , Fe v Ag . S phn ng xy ra l:
2+ 3+ +
A. 4 B. 3 C. 2 D. 5
Cu 13: Dung dch FeSO4 b ln CuSO4. Phng php n gin loi tp cht l :
A. Cho mt l nhm vo dung dch
B. Cho l st vo dung dch
C. Cho l ng vo dung dch
D. Cho dung dch NH3 cho n d vo dung dch, lc ly kt ta Fe(OH) 2 ri ho tan vo dung dch
H2SO4 long.
Cu 14: Cho cc dung dch C6H5NH2, CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung
dch trn, s dung dch c th lm i mu phenolphtalein l:
A. 4 B. 3 C. 5 D. 2
Cu 15: Nc c cha cc ion : Ca , Mg , HCO3 , SO4 v Cl gi l :
2+ 2+ - 2- -
A. Nc c tnh cng vnh cu B. Nc c tnh cng ton phn

C. Nc mm D. Nc c tnh cng tm thi
Cu 16: Cho cc cht CH3COOH (1), HCOO-CH2CH3 (2), CH3CH2COOH (3), CH3COO-CH2CH3 (4),
CH3CH2CH2OH (5). Dy cc cht sp xp theo th t nhit si gim dn l :
A. (3) > (1) > (4) > (5) > (2) B. (3) > (5) > (1) > (4) > (2)
C. (1) > (3) > (4) > (5) > (2) D. (3) > (1) > (5) > (4) > (2)
Cu 17: thu c kim loi Pb t PbO theo phng php nhit luyn, c th dng cht no sau y ?
A. Cu B. CO2 C. S D. H2
Cu 18: Cho dy cc kim loi sau: Al, Cu, Fe, Au. S kim loi trong dy phn ng c vi dung dch
H2SO4 c, nng l
A. 3 B. 4 C. 2 D. 1
Cu 19: Cu hnh electron ca nguyn t Cu (Z = 29) trng thi c bn l
A. 1s22s22p63s23p63d104s1 B. 1s22s22p63s23p63d94s2
2 2 6 2 6 1 10
C. 1s 2s 2p 3s 3p 4s 3d D. 1s22s22p63s23p64s23d9
Cu 20: xc nh glucoz trong nc tiu ca ngi b bnh i tho ng ngi ta dng:
A. natri hidroxit B. ng (II) hidroxit C. Axit axetic D. ng (II) oxit
Cu 21: Chia m gam Al thnh 2 phn bng nhau:
- Phn 1: Cho tc dng vi l ng d dung dch NaOH, sinh ra x mol kh H2
- Phn 2: Cho tc dng vi lng d HNO3 long, sinh ra y mol kh N2O (sn phm kh duy nht). Quan
h gia x v y l:
A. x = 2y B. y = 2x C. x = 4y D. x = y
Cu 22: Ha tan hon ton m gam hn hp X gm Al, Fe vo dung dch H2SO4 long, d thu dc
10,08 lt kh (kc). Bit Fe chim 60,87% v khi lng. Gi tr m l
Cu 23: Trong cc kim loi sau: Liti, Natri, Kali, Rubidi. Kim loi nh nht l
A. Liti B. Natri C. Kali D. Rubidi.
Cu 24: Nhm chc no sau y c cht bo ?
A. axit B. ancol C. este D. andehit

Cu 25: Clo ha PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo
phn ng vi k mt xch trong mch PVC. Gi tr cu k l?
A. 4 B. 6 C. 3 D. 5
Cu 26: Cht X c cng thc phn t C4H9O2N. Bit :
X + NaOH Y + H2 O Y + HCl d Z + H2 O
Cng thc ca cu to thu gn ca X v Z c th ln lt l :
A. H2NCH2CH2COOC2H5 v ClH3NCH2COOH.
B. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH.
C. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH.
D. H2NCH2CH2COOC2H5 v CH3CH(NH3Cl)COOH.
Cu 27: S chuyn ha tinh bt trong c th c biu din trong s
A. Tinh bt glucoz extrin mantoz CO2 + H2O
B. Tinh bt extrin mantoz glucoz CO2 + H2O
C. Tinh bt extrin glucoz mantoz CO2 + H2O
D. Tinh bt mantoz extrin mantoz CO2 + H2O
Cu 28: Ch dng thm thc th no sau y c th nhn bit c 3 l mt nhn cha cc dung dch
H2SO4, BaCl2, Na2SO4?
A. Qu tm C. Bt ng B. Dung dch AgNO3 D. Dung dch Ba(NO3)2
Cu 29: Cao su no sau y l sn phm ca phn ng ng trung ngng ?
A. Cao su isopren B. Cao su Clopren C. Cao su Buna-N D. Cao su Buna
Cu 30: Cho m gam hn hp Na, Ba vo nc thu c dung dch A v 6,72 lt kh (kc). Th tch
dung dch hn hp H2SO4 0,5M v HCl 1M cn dng trung ha dung dch A l :
A. 0,3 lt B. 0,2 lt C. 0,4 lt D. 0,5 lt
Cu 31: Cho dy cc dung dch: axit axetic, phenyamoni clorua, natri axetat, metylamin, glyxin,
phenol. S cht trong dy tc dng c vi NaOH :
A. 4 B. 3 C. 5 D. 6
Cu 32 : Cho cc th nghim sau:
(a) Cho dung dch Al(NO3)3 tc dng vi dung dch NH3 d
(b) Cho dung dch KOH d vo dung dch AlCl 3
(c) Cho dung dch HCl d vo dung dch NaAlO 2
(d) Dn kh CO2 d vo dung dch KAlO2
S th nghim thu c kt ta khi phn ng kt thc l :
A. 1 B. 2 C. 3 D. 4
Cu 33: Cho 30 gam hn hp X gm Mg, Al, ZnO v Fe(NO3)2 tan hon ton trong dung dch cha
0,725 mol H2SO4 long. Sau khi cc phn ng xy ra hon ton, thu c dung dch Y ch cha 90,400
gam mui sunfat trung ha v 3,920 lt kh Z (ktc) gm hai kh N2 v H2. Bit t khi ca Z so vi H2
l 33. Phn trm khi lng ca nhm trong hn hp X gn vi gi tr no sau y ?
A. 14,15% B. 13,0% C. 13,4% D. 14,1%
Cu 34: Hn hp A gm mt peptit X v mt peptit Y (mi cht c cu to t 1 loi aminoaxit, tng
s nhm -CO-NH- trong 2 loi phn t l 5) vi t l s mol n X : nY = 2 : 1. Khi thy phn hon ton m
gam hn hp A thu c 5,625 gam glyxin v 10,86 gam tyrosin. Ga tr ca m l:
Cu 35: Hn hp X gm mt axit cacboxylic Y v mt este Z (Y, Z u mch h khng phn nhnh).
un nng 0,275 mol X cn dng 200 ml dung dch NaOH 2M thu c hn hp 2 mui v hn hp 2
ancol. un nng ton b 2 ancol ny vi H 2SO4 c 140oC thu c 7,5 gam hn hp 3 ete. Ly hn
hp 2 mui trn nung vi vi ti xt ch thu c mt kh duy nht, kh ny lm mt mu va dung
dch 44 gam Br2 thu c sn phm cha 85,106% brom v khi lng. Khi lng ca Z trong X l:
Cu 36: X, Y, Z l 3 este u n chc, mch h (trong Y v Z khng no c mt lin kt C=C v
c tn ti ng phn hnh hc). t chy 21,62 gam hn hp E cha X, Y, Z vi oxi va , sn phm
chy dn qua dung dch Ca(OH) 2 d thy khi lng dung dch gim 34,5 gam so vi trc phn ng.
Mt khc, un nng 21,62 gam E vi 300 ml dung dch NaOH 1M (va ), thu c hn hp F ch

cha 2 mui v hn hp gm 2 ancol k tip thuc cng dy ng ng. Khi lng ca mui c khi
lng phn t ln hn trong hn hp F l:
Cu 37: Thy phn m gam hn hp X gm mt s este n chc, mch h bng dung dch NaOH va
thu c a gam hn hp mui v b gam hn hp ancol. t chy hon ton a gam hn hp mui
trong O2 va thu c hn hp kh Y v 11,13 gam Na2CO3. Dn ton b Y qua nh ng dung dch
Ca(OH)2 d, thu c 34,5 gam kt ta, ng thi thy khi lng bnh tng 19,77 gam so vi ban u.
un b gam hn hp ancol vi H2SO4 c 140oC thu c 6,51 gam hn hp cc ete. Cc phn ng
xy ra hon ton. Ga tr m l:
Ca(OH)2 d, sau phn ng thu c 5,0 gam kt ta v khi lng dung dch gim 2,08 gam. Bit khi
x phng ha X ch thu c mui ca axit cacboxylic v ancol. S ng phn ca X l:
A. 3 B. 4 C. 6 D. 5
Cu 39: t chy hon ton 10,58 gam hn hp X cha ba este u n chc, mch h bng lng oxi
va , thu c 8,96 lt kh CO 2 (ktc). Mt khc, hidro ha hon ton 10,58 gam X cn dng 0,07
mol H2 (xc tc, to) thu c hn hp Y. un nng ton b Y vi 250 ml dung dch NaOH 1M, c cn
dung dch sau phn ng, thu c mt ancol Z duy nht v m gam rn khan. Ga tr ca m l :
Cu 40: Ha tan ht m gam kim loi M cn dng 136 gam dung dch HNO 3 31,5%. Sau khi kt thc
phn ng thu c dung dch X v 0,12 mol kh NO duy nht. C cn dung dch X thu c
(2,5m + 8,49) gam mui khan. Kim loi M l:
A. Mg B. Cu C. Ca D. Zn
----------HT----------

THI TH THPT CHUYN H LONG LN 1 M 101
Cu 1: Chn D.
- Ta c : nFe nCu 0,1mol . Xt hn hp kh X c:

BT: e
3n NO n NO 2 3n Fe 2n Cu
n NO n NO 2 0,125 mol V 5, 6 (l)
n NO n NO 2
Cu 2: Chn C.
- Ghp cc on mch vi nhau ta thu c X l: Gly-Gly-Ala-Val-Phe hoc Gly-Ala-Val-Phe-Gly
Cu 3: Chn B.
A. ng, Cht bo nh hn nc v khng tan trong nc.
B. Sai, Cht bo l trieste ca glixerol v cc axit bo.
(C17 H 33COO)3 C3H 5 3H 2 Ni,t o
C. ng, Phn ng: (C17 H 35COO)3 C3H 5
(C17 H 31COO)3 C3H 5 6H 2
D. ng, Du m ng thc vt b i thiu do ni i C=C gc axit khng no ca cht bo b oxi ha
Cu 4: Chn C.
- Bn cht phn ng :
CO2 + Ca(OH)2
CaCO3 + H2O (1)
CaCO3 + CO2 + H2O Ca(HCO3 )2 (2)
- Phn tch th: lng kt ta tng dn n cc i ng vi phn ng (1), sau lng kt ta tan dn
n ht ng vi phn ng (2).
- Ti thi im:
n CO 2 (1) x mol m CaCO3 (1) 100x
n CO 2 (2) 15x mol m CaCO3 (2) 100n CaCO 3 100.(2 n Ca(OH) 2 n CO 2 (2) ) 100.(0, 4 15x)
m m CaCO3 (1) m CaCO3 (2) 100x 100.(0, 4 15x) x 0, 025 mol
Cu 5: Chn D.
BT:C
nCO2 nCaCO3(1) 2nCaCO3(sau khi un nng) 0,75mol
H SO ln men
- Qu trnh: C6H10O5
2 4
C6H12O6
CO2 C2H 5OH .
3,75mol 7,5mol
nCO2
mtinh bt 162. 750(g)
2H%
Cu 6: Chn B.
- Qu trnh iu ch:
H ,t o xt,t o
CH 2 C(CH3 )COOH CH3OH CH 2 C(CH3 )COOCH3 [ CH 2 C(CH3 ) COOCH3 ]
m 1 1
- Ta c: m C4H 6O 2 86. PMM . . 430 kg
100 h1 % h 2 %
Cu 7: Chn D.
- St ty l st trng thic. Trong phng php bo v b mt: thic l kim loi kh b oxi ha nhit
thng, mng oxit thic mng v mn cng c tc dng bo v thic v thic oxit khng c li c mu
trng bc kh p. Thic l kim loi mm, d b sy st. Nu vt sy st su ti lp st bn trong th s
xy ra n mn in ha hc, kt qu l st b n mn nhanh.
Cu 8: Chn B.
- t cng thc ca X l : (H2N)x-R-(COOH)y.

n NaOH
- Khi cho X tc dng vi NaOH th: y 2
nX
n BTKL m m HCl
- Khi cho X tc dng vi NaOH th: x HCl 1 M X 147
nX 0, 02
Vy X l H 2 NC3H 5 (COOH) 2
Cu 9: Chn D.
- X l cht lng tnh, cng thc c dng : RCOONH3R.
- Khi cho X tc dng vi NaOH nhn thy : mmui > mX R + 17 < 23 R < 6.
Vy cng thc cu to ca X l: CH3COONH3CH3 (Metylamoni axetat).
Cu 10: Chn C.
- Thc hin gp qu trnh, rt ra nhn xt: n NaOH 2n NH 2C3H5 (COOH) 2 n HCl 0, 65mol
Cu 11: Chn D.
- C 4 dung dch c th ha tan c Al l:
2Al 6HCl (l)
2AlCl3 3H 2

2Al 3H 2SO 4(l)
Al 2 (SO 4 ) 3 3H 2
Al + 4HNO3 long
Al(NO3)3 + NO + 2H2O
2Al + 6H2SO4 c, nng
Al2(SO4)3 + 3SO2 + 3H2O
- Lu : Al b th ng ha bi HNO3 c, ngui.
Cu 12: Chn A.
- p dng quy tc th Mg u phn ng vi c 3 dung dch trn. S phn ng xy ra l:
Mg + 2Ag+
Mg2+ + 2Ag Mg + Cu2+
Mg2+ + Cu
Mg + 2Fe3+ Mg2+ + 2Fe2+ Mg + Fe2 + Mg2+ + Fe
Cu 13: Chn B.
A. Sai, Cho mt l nhm vo dung dch th khng loi b c CuSO 4.
B. ng, loi b CuSO4 ra khi dung dch ta cho l Fe vo dung dch vi mc ch loi b Cu2+ ra
khi dung dch.
C. Sai, Cho l ng vo dung dch th khng loi b c.
D. Sai, Cho dung dch NH3 cho n d vo dung dch, lc ly kt ta Fe(OH) 2 ri ho tan vo dung
dch H2SO4 long. y l mt qu trnh kh phc tp.
Cu 14: Chn D.
Dung dch C6H5NH2 CH3NH2 NaOH C2H5OH H2NCH2COOH
Mu
Khng i mu Hng Hng Khng i mu Khng i mu
phenolphtalein
Cu 15: Chn B.
- Nc cng l nc c cha nhiu cation Ca2+, Mg2+. Nc cha t hoc khng cha cc ion trn c
gi l nc mm.
- Nc cng tm thi: Tnh cng tm thi ca nc cng l do cc mui Ca(HCO3)2, Mg(HCO3)2 gy
ra:
- Nc cng vnh cu: Tnh cng vnh cu ca nc l do cc mui CaCl2, MgCl2, CaSO4, MgSO4 gy
ra,gi l vnh cu v khi un nng mui s khng phn hy
- Nc c tnh cng ton phn: L nc c c tnh cng tm thi v vnh cu.
Vy Nc c cha cc ion : Ca2+, Mg2+, HCO3-, SO42- v Cl- gi l nc cng ton phn.
Cu 16: Chn D.
cng cao.
si cao hn.
nhau:
Vy dy sp xp theo nhit si gim dn l: (3) > (1) > (5) > (4) > (2).
Cu 17: Chn D.
- Phng php nhit luyn c ng dng rng ri trong cng nghip iu ch nhng kim loi c
hot ng ha hc trung bnh nh Zn, Cr, Fe, Sn, PbC s ca phng php ny l kh nhng ion kim
loi trong cc hp cht nhit cao bng cc kim loi mnh nh C, CO, H2 hoc Al, kim loi kim,
to
kim th. Phn ng: H2 + PbO Pb + H2O
Cu 18: Chn A.
- Hu ht cc kim loi u cho phn ng vi H 2SO4 c, nng tr Au, Pt. Vy c 3 kim loi tha.
Cu 19: Chn A.
- Cu hnh electron ca nguyn t Cu (Z = 29) : 1s22s22p63s23p63d104s1
Cu 20: Chn B.
- xc nh glucoz trong nc tiu ca ngi b bnh i tho ng ngi ta dng Cu(OH) 2. Hin
tng: to phc mu xanh lam.
Cu 21: Chn C.
BT: e
3n Al 2n H2 8n N2O x 4y
Cu 22: Chn A.

BT:e
3nAl 2nFe 2nH2 3nAl 2nFe 0,9
nAl 0,2
56nFe 56nFe m 27nAl 56nFe 13,8(g)
%Fe 56n 27n 0,6087 nFe 0,15
56nFe 27nAl Fe Al
Cu 23: Chn A.
Cu 24: Chn C.
Cu 25: Chn C.
- Phn ng: (C2H3Cl)k + Cl2 C2kH3k-1Clk+1 + HCl
35,5(k 1)
- Ta c: %Cl 0,6396 k 3
12.2k 3k 1 35,5(k 1)
Cu 26 Chn C.
- Cc phn ng xy ra :
CH3CH2(NH3)COOCH3 (X) + NaOH
CH3CH2(NH3)COONa (Y) + H2O
CH3CH2(NH3)COONa (Y) + HCl CH3CH(NH3Cl)COOH (Z) + H2O
Cu 27: Chn B.
- S chuyn ha tinh bt trong c th c biu din trong s :
- Qu trnh lm bnh m l qu trnh extrin ha bng men v bng nhit. Cm chy l hin tng extrin
ha bng nhit.
- n bnh m, cm chy d tiu v c v hi ngt v phn t tinh bt c phn ct nh thnh cc
isaccarit v monosaccarit
Cu 28: Chn A.
Thuc th H2SO4 BaCl2 Na2SO4
Qy tm Mu Khng hin tng Khng hin tng
H2SO4 Kt ta trng Khng hin tng
Cu 29: Chn C.
- Cao su buna N: ng trng hp buta-1,3-ien v acrilonitrin:

=
Buta -1,3- ien acrilonitrin Cao su buna N

Cu 30: Chn A.
- Dung dch A cha : nOH 2nH 2 0,6mol
- Trung ha dung dch A th : nOH nH 2nH 2SO4 nHCl 2.0,5V V 0,6 V 0,3(l)
Cu 31: Chn A.
- Cc cht hu c tc dng vi NaOH thng gp l :
to
C6H5ONa + H2O
-COONa + H2O
to
RNH2 + NaCl + H2O
H2NRCOONa + H2O
Vy c 4 cht tha mn l: axit axetic, phenyamoni clorua, glyxin, phenol.
Cu 32: Chn B.
- Cc phn ng xy ra:
(a) Al(NO3)3 + 3NH3 + 3H2O
Al(OH)3 + 3NH4NO3
(b) AlCl3 + 3NaOHd
Al(OH)3 + 3NaCl ; Al(OH)3 + NaOH
Na[Al(OH)4]
(c) NaAlO2 + HCl + H2O
Al(OH)3 + NaCl ; Al(OH)3 + 3HCl
AlCl3 + 3H2O
(d) CO2 d + KAlO2 + 2H2O Al(OH)3 + KHCO3
Vy c 2 phn ng to kt ta l (a), (d).
Cu 33: Chn C.
- Hn hp Z gm N2 (0,05 mol) v H2 (0,125 mol)
- Khi cho X tc dng vi dung dch H2SO4 long, ta c :
m 98nH2SO4 mZ mY 2n 2nH2 2nH2O

BTKL
nH2O X 0,5mol nNH4 H2SO4 0,05mol
18 4
- Xt hn hp rn X ta c :
2nN 2 nNH 4 2nH 2SO4 12nN 2 2nH 2 10nNH 4

BT:N
nFe(NO3 )2 0,075 mol v nZnO 0,05mol
2 2
24nMg 27nAl mX 180nFe(NO3 )2 81nZnO 12,45
nMg 0,35 0,15.27
+ BT:e %mAl .100 13,5

2n Mg 3n Al 10n N 2
2n H 2
8n NH 4 11,15 n Al 0,15 30
Cu 34: Chn A.
- Khi gp X v Y vi t l mol tng ng l 1 : 3 c 2X Y
X2 Y 2H 2O (1)
nGly 0,075 5
+ T: X 2 Y l (Gly)5k (Tyr) 4k
nTyr 0,06 4

(52).nX 5k 4k (52).nZ
nGly nTyr
+ Vi k = 1 n(Gly)5(Tyr)4 nX 2Y 0,015mol
5 4
BTKL
(1) mX mY mX 2Y 18nH2O 14,865(g)
Cu 35: Chn B.
- Nhn thy rng, khi cho hn hp X gm axit Y v este Z thu c hai ancol v hai mui nn Z l este
hai chc c to t axit hai chc v hai ancol, ta c h sau :
nY nZ nX nY nZ 0,275 nY 0,15mol
+
nY 2nZ nNaOH nY 2nZ 0,4 nZ 0,125mol
- Khi un nng ton b lng ancol thu c vi H 2SO4 c 140oC th :
n 2n BTKL
+ nH 2O ancol Z 0,125mol mancol mete 18nH 2O 9,75(g)
2 2
m
M ancol ancol 39 , vy hn hp ancol gm CH3OH v C2H5OH.
nancol
- Xt qu trnh hn hp mui tc dng vi NaOH/ CaO (t 0), ri cho hn kh tc dng vi Br 2 ta c :
mBr2
mkh 51,7 mkh mdn xut halogen mBr2 7,7(g)
%mBr2
m
- Gi s kh thu c l anken th : M hidrocacbon kh 28(C2 H 4 ) .
nBr2
C2H3COONa v NaOOC CH CH COONa .
Vy este Z l CH3OOC CH CH COOC2H5 vi mZ 19,75(g)
Cu 36: Chn D.
- Khi t chy hn hp E ri hp th sn phm chy vo dung dch Ca(OH) 2 d, ta c h sau:
12nC nH 16nO mE 12nCO2 2nH 2O 32nE 21,62 nCO2 0,87mol

100nCaCO3 (44nCO2 18nH 2O ) mdung dch gim 56nCO2 18n H 2O 34,5 n H 2O 0,79mol
n n n 0,3 n 0,3mol
E NaOH E E
+ p dng bt bo ha ta c : nY nZ nCO2 nH2O 0,08mol nX nE nY nZ 0,22mol
nCO2
+ C CE 2,9 nn trong E c cha HCOOCH3.
nE
- Theo d kin bi thi hn hp ancol thu c ng ng k tip nn hn hp ancol gm CH 3OH v
C2H5OH, mc khc trong Y v Z c mt lin C = C ng thi c ng phn hnh hc. T tt c cc
nCO2 2nX
d kin trn ta suy ra: CY,Z 5 . Mc khc, ta c : C Y,Z 5,375 .
nY nZ
Vy este Y v Z ln lt l CH3 CH CH COOCH3 v CH3 CH CH COOC2H5
mCH3 CH CH COONa 0,08.108 8,64(g)
Cu 37: Chn C.
44nCO2 18nH 2O mbnh t ng nCO2 0,345mol

- Xt qu trnh t a gam hn hp mui ta c: nCO2 nCaCO3 nH 2O 0,255mol
n 2n n 0,21mol
X Na2CO3 X
+ nO2 (p ) nCO2 0,5(nH2O nNa2CO3 ) 0,42mol mmui mbnh tng mNa2CO3 32nO2 17,46(g)
- Xt qu trnh un b gam hn hp ancol vi H2SO4 c 140oC ta c :
n n
nH 2O ancol X 0,105mol mancol mete 18nH 2O 8,4(g)
2 2
- Xt qu trnh thy m gam hn hp X bng dung dch NaOH va , p dng :
BTKL
mX mmui mancol 40nNaOH 17,46(g) (vi nNaOH 2nNa2CO3 0,21mol )
Cu 38: Chn D.
nCO2 nCaCO3
nCO2 0,05mol
- Khi t chy este X th:
100nCaCO3 (44nCO2 nH 2O ) mdd gim
nH 2O 0,04mol
- p dng bt bo ha, ta c : nX nCO2 nH2O 0,01mol . Vy este X c CTPT l: C5H8O4
HCOOCH2 CH2OOC2H5 ; HOOC CH(CH)3 CH2 OOCH v HCOO-(CH2)3-OOCH
+ TH2 : X c to thnh t axit a chc v ancol n chc :
C2H5OOC COOCH3 v CH3OOC CH2 COO CH3
Vy c 5 ng phn ca X tha mn.
Cu 39: Chn B.
- Hidro ha hon ton hn hp X th : mY mX 2nH2 10,72(g)
- Gi s t chy hon ton hn hp Y (CTTQ ca Y l CnH2nO2) th :
m 12nCO2 2nH2O
+ nCO2 nH2O 0,4 mol nY nCOO Y 0,16mol
32
nCO2
- Ta c : CY 2,5 . Vy trong Y c cha este HCOOCH3
nY
- Khi cho lng Y trn tc dng vi 0,25 mol NaOH th ancol Z thu c l CH3OH
vi nCH3OH nY 0,16mol BTKL
mrn khan mY 40nNaOH 32nCH3OH 15,6(g)
Cu 40: Chn D.
- Khi cho m gam kim loi M tc dng vi 0,68 mol NaOH th :
nHNO3 4nNO nHNO3 4nNH 4
+ nNH 4 0,02mol nH 2O 0,3mol
10 2
BTKL
mM 63nHNO3 mX 30nNO 18nH2O m 16,9(g)
- Ta c ne trao i 3nNO 8nNH4 0,52mol
ne m 16,9a a 2
m nM MM M M M 65(Zn) (vi a l s e trao i ca M)
a nM ne

THPT H TRUNG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Dung dch mui X tc dng vi dung dch NaOH, thu c kt ta mu xanh. Mui X l:
A. MgSO4 B. FeSO4 C. CuSO4 D. Fe2(SO4)3.
Cu 2: Kim loi no sau y c khi lng ring nh nht ?
A. Li B. Cs C. Na D. K
Cu 3: Hp cht no sau y cng hp c vi nc Br 2 ?
A. Anilin. B. metyl fomat C. glucoz D. triolein
Cu 4: X l mt l -amino axit c cng thc phn t C 3H7O2N. Cng thc cu to ca X l:
A. H2NCH(CH3)COOH B. H2NCH2CH2COOH C. H2NCH2COOCH3 D. CH2=CHCOONH4
Cu 5: Kim loi no sau y khng tc dng c vi dung dch FeCl 3 ?
A. Ag B. Fe C. Cu D. Ca
Cu 6: Nhng thanh Ni ln lt vo cc dung dch: FeCl 3, CuCl2, AgNO3, HCl v FeCl2. S trng
hp xy ra n mn in ha l:
A. 3 B. 4 C. 2 D. 1
Cu 7: un nng m1 gam este X (C4H8O2) vi dung dch NaOH va , thu c m 2 gam mui. Bit
rng m1 < m2, tn gi ca X l:
A. isopropyl fomat B. metyl propionat C. etyl axetat D. propyl fomat
Cu 8: iu khng nh no sau y l sai ?
A. Trong mt ong cha nhiu fructoz v glucoz.
B. Saccaroz cho c phn ng thy phn trong mi trng axit.
C. Dng dung dch AgNO3/NH3, un nng nhn bit glucoz v saccaroz.
D. Saccaroz c to bi mt gc -glucoz v -fructoz.
Cu 9: Cho hn hp gm 18,56 gam Fe 3O4 v 7,68 gam Cu vo 600 ml dung dch HCl 1M, kt thc
phn ng thu c dung dch X v cn li x gam rn khng tan. Gi tr ca x l:
Cu 10: Cho hn hp gm Ba (2a mol) v Al 2O3 (3a mol) vo nc d, thu c 0,08 mol kh H 2 v
cn li m gam rn khng tan. Gi tr ca m l:
Cu 11: T nilon-6,6 c tnh dai bn, mm mi ng mt, t thm nc, git mau kh nhng km
bn vi nhit, vi axit v kim. T nilon-6,6 c iu ch t phn ng trng ngng gia ?
A. axit terephatlic v etylen glicol. B. axit -aminocaproic v axit aipic.
C. hexametyleniamin v axit aipic. D. axit -aminoenantoic v etylen glycol
A. Este no, n chc, mch h c cng thc tng qut l CnH2nO2 (n 2).
B. Thng thng cc este th lng, nh hn nc v rt t tan trong nc.
C. Thy phn este trong mi trng axit lun thu c axit cacboxylic v ancol.
D. t chy mt este no, n chc, mch h thu c CO2 v H2O c t l mol 1 : 1.
Cu 13: Mt lng ln nc thi cng nghip cha qua x l trc tip ra sng sui l nguyn
nhn chnh gy nhim ngun nc ti nhiu khu vc hin nay. x l s b mu nc thi cha
cc ion Pb2+, Fe3+, Cu2+ , Hg2+ ngi ta c th dng ?
A. H2SO4 B. NaCl C. Ca(OH)2 D. HCl
Cu 14: Pht biu no sau y l sai ?
A. Lin kt CONH gia hai n v -amino axit gi l lin kt peptit.
B. Cc peptit u cho phn ng mu biure.
C. Cc peptit u b thy phn trong mi trng axit hoc mi trng kim.
D. Cc peptit thng th rn, c nhit nng chy cao v d tan trong nc.
Cu 15: un nng 4,05 gam este X (C10H10O2) cn dng 35 gam dung dch KOH 8%, c cn dung
dch sau phn ng, thu c m gam mui. Gi tr m l:
Cu 16: un nng 121,5 gam xenluloz vi dung dch HNO 3 c trong H2SO4 c (dng d), thu
c x gam xenluloz trinitrat. Gi tr ca x l:
A. 222,75 gam B. 186,75 gam C. 176,25 D. 129,75
Cu 17: Th nghim no sau y khng to ra n cht ?
A. Cho bt nhm vo dung dch NaOH. B. Cho bt Cu vo dung dch AgNO 3.
C. Cho Na vo dung dch FeCl 2. D. Cho dung dch FeCl3 vo dung dch AgNO 3.
Cu 18: Cp cht no sau y u thuc loi polime tng hp ?
A. poli(metylmetacrylat) v amiloz. B. t visco v t olon.
C. t xenluloz axetat v t lapsan. D. poli(vinylclorua) v t nilon-6,6.
Cu 19: Phn ng no sau y l ng ?
0
A. H2N-CH2-COONa + HCl (d)
t
H2N-CH2-COOH + NaCl
0
B. CH3COOCH2C6H5 + 2NaOH
t
CH3COONa + C6H5CH2ONa + H2O
0
C. CH2OH[CHOH]4CHO + Br2 + H2O
t
CH2OH[CHOH]4COOH + HBr.
0
D. ClH3N-CH2-COOH + NaOH (d) t
ClH3N-CH2-COONa + H2O
Cu 20: Cho cc dung dch sau: HCl, Na2CO3, AgNO3, Na2SO4, NaOH v KHSO4. S dung dch tc
dng c vi dung dch Fe(NO3)2 l:
A. 4 B. 3 C. 6 D. 5
A. Propan-2-amin l amin bc 1.
B. HOOC-[CH2]2-CH(NH2)-COOH c tn bn h thng l axit -aminoglutamic.
C. (CH3)2CH-NH-CH3 c tn thay th l N-meyl-propan-2-amin.
D. Triolein c cng thc phn t l C 57H106O6.
Cu 22: Ln men m gam tinh bt thnh ancol etylic vi hiu sut ca c qu trnh l 75%. Lng CO 2
sinh ra c hp th hon ton vo dung dch Ca(OH) 2, thu c 60,0 gam kt ta v dung dch X.
tc dng ti a vi dung dch X cn dng dung dch cha 0,2 mol NaOH. Gi tr ca m l.
[C6H7O2(OH)3]n.
lm thuc sng.
to ra kh NO (sn phm kh duy nht ca N+5). Gi tr m l.
Cu 29: un nng triglyxerit X vi dung dch NaOH va , thu c dung dch Y cha 2 mui natri
ca axit stearic v oleic. Chia Y lm 2 phn bng nhau. Phn 1 lm mt mu va dung dch cha
0,12 mol Br2. Phn 2 em c cn thu c 54,84 gam mui. Khi lng phn t ca X l.
A. 886 B. 888 C. 884 D. 890
Cu 30: Ha tan ht 12,48 gam hn hp gm Fe, FeO, Fe 3O4, Fe2O3 trong dung dch cha 0,74 mol
HNO3 (dng d), thu c 0,08 mol kh X v dung dch Y. Dung dch Y ha tan ti a x gam bt Cu.
Bit kh NO l sn phm kh duy nht ca c qu trnh v cc phn ng xy ra hon ton. Gi tr ca x
l.
Cu 31: Pht biu no sau y l ng:
A. Tt c cc polime tng hp u c iu ch bng phn ng trng ngng.
B. Tt c cc polime u khng tc dng vi axit hay baz.
C. Protein l mt loi polime thin nhin.
D. Cao su buna-S c cha lu hunh trong phn t.
(a) Gang l hp kim ca st c cha t 0,01 2% khi lng cacbon.
(b) Nc cng l nc cha nhiu ion Ca2+ v Mg2+.
(c) Cho t t dung dch HCl vo dung dch K2CrO4 thy dung dch t mu vng chuyn sang mu da
cam
(d) Hn hp gm Al v Fe3O4 dng hn ng ray.
(e) Nc kh c cng thc l CO2 (rn), khng nng chy m thng hoa nn c dng to mi
trng lnh v kh rt tin cho vic bo qun thc phm.
S pht biu sai l
A. 2. B. 3. C. 4. D. 1.
Cu 33: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l:
A. CH3CHO, C2H5OH, C2H6, CH3COOH. B. C2H6, C2H5OH, CH3CHO, CH3COOH.
C. C2H6, CH3CHO, C2H5OH, CH3COOH. D. CH3COOH, C2H6, CH3CHO, C2H5OH.
Cu 34: Cc cht trong dy no sau y khi tc dng vi dung dch AgNO3/NH3 d u to ra sn phm
l kt ta:
A. fructoz, anehit axetic, amilopectin, xenluloz. B. ivinyl, glucoz, metyl fomat, amiloz.
C. glucoz, metyl fomat, saccaroz, anehit axetic. D. vinylaxetilen, glucoz, metyl fomiat,
axetanehit.
un Y vi H2SO4 c 170oC khng to ra anken. Nhn xt no sau y ng
A. Cht X c mch cacbon phn nhnh.
B. Cht Z khng tham gia phn ng trng bc.
C. Cht Y c nhit si cao hn ancol etylic.
D. Phn t cht Z c s nguyn t hiro bng s nguyn t oxi.
Cu 36: Hp cht hu c X c cng thc phn t C 3H4O4 tc dng vi dung dch NaOH un nng

0
theo s phn ng sau : X + 2NaOH t
Y + Z + H2O. Bit Z l mt ancol khng c kh nng
tc dng vi Cu(OH)2 iu kin thng. iu khng nh no sau y l ng ?
A. X c cng thc cu to l HCOO-CH2-COOH.
B. X cha hai nhm OH.
C. Y c cng thc phn t l C2O4Na2.
D. un nng Z vi H2SO4 c 1700C thu c anken.
Cu 37: Cho 8,96 gam bt Fe vo bnh cha 200 ml dung dch NaNO 3 0,4M v H2SO4 0,9M. Sau khi
kt thc cc phn ng, thm tip lng d dung dch Ba(OH) 2 vo bnh (khng c mt oxi), thu c
m gam rn khng tan. Bit kh NO l sn phm kh duy nht ca NO 3-. Gi tr ca m l:
Cu 38: in phn dung dch X gm FeCl2 v NaCl (t l mol tng ng l 1 : 2) vi in cc tr mng

ngn xp thu c dung dch Y cha hai cht tan, bit khi lng dung dch X ln hn khi lng dch
Y l 4,54 gam. Dung dch Y ha tan ti a 0,54 gam Al. Mt khc dung dch X tc dng vi lng d
dung dch AgNO3 thu c m gam kt ta. Gi tr m l
A. 14,35. B. 17,59. C. 17,22. D. 20,46.
Cu 39: Ha tan ht m gam hn hp X gm Mg, MgO, Mg(HCO3)2, MgSO3 bng mt lng va
dung dch H2SO4 30%, thu c 11,2 lt (ktc) hn hp kh Y v dung dch Z c nng 36%. T khi
ca Y so vi He bng 8. C cn Z c 72 gam mui khan. Gi tr ca m l
A. 20. B. 10. C. 15. D. 25.
Cu 40: Thc hin phn ng nhit nhm hn hp X cha mt oxit st, 0,02 mol Cr2O3 v 0,04 mol Al
sau mt thi gian thu c hn hp cht rn Y. Chia Y thnh hai phn bng nhau. Phn 1 tc dng vi
H2SO4 c nng d thu c 0,896 lt SO2 (ktc, sn phm kh duy nht). Phn 2 tc dng va 250
ml dung dch HCl 1M thu c dung dch Z v 0,336 lt H2 (ktc), dung dch Z tc dng ti a x mol
NaOH thu c 6,6 gam hn hp kt ta. Bit cc phn ng xy ra hon ton. Gi tr ca x l:
A. 0,27. B. 0,3. C. 0,28. D. 0,25.
----------HT----------

PHN TCH HNG DN GII
THI TH THPT H TRUNG THANH HA LN 1
Cu 1: Chn C.
A. MgSO4 + 2NaOH
Mg(OH)2 trng + Na2SO4
B. FeSO4 + 2NaOH
Fe(OH)2 trng xanh + Na2SO4
C. CuSO4 + 2NaOH
Cu(OH)2 xanh lam + Na2SO4
D. Fe2(SO4)3 + 3NaOH Fe(OH)3 nu + Na2SO4
Cu 2: Chn A.
- Trong dy cc kim loi kim th khi lng ring tng dn theo th t: Li < Na < K < Rb < Cs.
Cu 3: Chn D.
- Phn ng cng l mt phn ng ca cht hu c, trong hai (hay nhiu hn) phn t kt hp vi nhau
to thnh mt phn t ln hn.
+ Anilin tham gia phn ng th Br 2 trn vng thm
+ Metyl fomat, glucoz b oxi ha bi dung dch Br 2.
+ Triolein tham gia phn ng cng Br2 vo ni i C=C ca gc axit oleic.
Cu 4: Chn A.
Cu 5: Chn A.
- Cc kim loi phn ng vi Fe 3+ tun theo quy tc l:
Fe + FeCl3 FeCl2 Cu + 2FeCl3 2FeCl2 + CuCl2
- Cc kim loi c tnh kh mnh nh Ca th khng tun theo quy tc m phn ng nh sau:
2Fe(OH)3 + 3CaCl2 + H2
3Ca + 4H2O + 2FeCl3
Cu 6: Chn C.
- Cho Ni vo dung dch FeCl 3: Khng tha mn iu kin (1).
CuCl2, AgNO3, HCl v FeCl2
- Cho Ni vo dung dch CuCl 2: Tha mn.
- Cho Ni vo dung dch AgNO 3: Tha mn.
- Cho Ni vo dung dch HCl v FeCl 2: Khng tha mn iu kin (1).
Cu 7: Chn B.
0
- Phn ng: RCOOR(m1) + NaOH t
RCOONa (m2) + ROH
- Nhn thy rng m1 < m2 tc l M Na > MR nn gc R < 23 l gc CH3 tha mn yu bi .
Vy X l C2H 5COOCH3 (metyl propionat).
Cu 8: Chn D.
A. ng, Trong mt ong cha nhiu fructoz v glucoz nhng hm lng fructoz chim nhiu hn s
vi glucoz.
B. ng, Thy phn saccaroz trong mi trng axit thu c glucoz v fructoz.
C. ng, Gucoz cho phn ng trng bc cn saccaroz th khng tham gia phn ng.
D. Sai, Trong phn t saccaoz gc glucoz v gc fructoz lin kt vi nhau qua nguyn t oxi
gia C1 ca glucoz v C2 ca fructoz (C1 O C2).
Cu 9: Chn C.
- Phn ng: Fe3O4 8HCl Cu 3FeCl 2 CuCl 2 4H2O
mol: 0,08 0,6 0,12
d: 0,005 0 0,045
mrn khng tan 232nFe3O4 (d ) 64nCu(d ) 4,04(g)

Cu 10: Chn B.
-Phn ng: Ba Al 2O3 H 2O
Ba(AlO2 )2 H 2
mol: 2a 3a 0,08 (Al 2O3 d : a mol)
BT:e
nBa nH2 a 0,04 mol m 0,04.M Al 2O3(d ) 102a 4,08(g)
Cu 11: Chn C.
o
t
axit aipic hexametyleniamin poli(hexametylen-aipamit) hay t nilon
6,6
Cu 12: Chn C.
- Thy phn cc este c dng sau y khng thu c ancol l:
H SO

2
RCOOCH=CH-R + H2O
4
RCOOH + R-CH2-CHO
o
t
H SO

2
RCOOC(CH3)=CH-R + H2O
4
RCOOH + R-CH2-CO-CH3
o
t
H SO

2
RCOOC6H5-R + H2O
4
RCOOH + R-C6H5OH (-C6H5: phenyl)
o
t
Cu 13: Chn C.
- x l nc thi c cha cc ion kim loi nng nh Hg2+, Pb2+, Fe3+,... ngi ta s dng dung dch
kim, khi phn ng s xy ra v hnh thnh cc kt ta hiroxit ca kim loi nng, t ta lc b kt
ta i.
- L do s dng Ca(OH)2 m khng s dng KOH hoc NaOH v Ca(OH)2 gi thnh r (mua CaO ngoi
th trng sau cho tc dng vi H2O thu c Ca(OH)2), d s dng v ph bin hn so vi KOH
(NaOH)
Cu 14: Chn B.
- Cc peptit c t hai lin kt peptit tr ln (tc l tripeptit) mi tham gia phn ng mu biure.
Cu 15: Chn B.
- X tc dng vi KOH th: RCOOC6H 4R' 2KOH
RCOOK KOC6H 4R' H 2O
0,025mol 0,05mol 0,025mol
BTKL
mmui mX 56nKOH 18nH2O 6,4(g)
Cu 16: Chn A.
H SO
- Phn ng: C6H 7O2 (OH)3 3HONO2
2 4
C6H 7O2 (ONO2 )3 3H 2O
0,75mol 0,75mol
mC6H 7O2 (ONO2 )3 0,75.297 222,75(g)

Cu 17: Chn D.
A. 2Al + 2NaOH + 2H2O
2NaAlO2 + 3H2
B. Cu + 2AgNO3
Cu(NO3)2 + 2Ag
C. 2Na + FeCl2 + 2H2O
2NaCl + Fe(OH)2 + H2
D. FeCl3 + 3AgNO3
Fe(NO3)3 + 3AgCl
Cu 18: Chn D.
Cu 19: Chn C.
0
A. H2N-CH2-COONa + HCl (d)
t
ClH3N-CH2-COOH + NaCl
0
B. CH3COOCH2C6H5 + NaOH
t
CH3COONa + C6H5CH2OH
0
D. ClH3N-CH2-COOH + 2NaOH (d)
t
H2N-CH2-COONa + NaCl + 2H2O
Cu 20: Chn D.

(1) 3Fe 2 4H NO3
3Fe3 NO 2H 2O
(2) Fe(NO3 ) 2 Na 2CO3
FeCO3 2NaNO3
(3) Fe(NO3 ) 2 AgNO3
Fe(NO3 )3 Ag
(4) Fe(NO3 ) 2 2NaOH
Fe(OH) 2 2NaNO3
(5) 3Fe 2 4H NO3
3Fe3 NO H 2O
Vy c 5 dung dch tc dng c vi Fe(NO 3)2 l HCl, Na2CO3, AgNO3, NaOH v KHSO4.
Cu 21: Chn A
A. ng, Cu to ca propan-2-amin: CH3-CH(NH2)-CH3 y l amin bc 1.
B. Sai, HOOC-[CH2]2-CH(NH2)-COOH c tn bn h thng l axit -aminoglutaric.
C. Sai, (CH3)2CH-NH-CH3 c tn thay th l N-metylpropan-2-amin.
Lu : Khi gi tn mt hp cht hu c gia ch v ch s khng c du - ; gia s v ch s c
du - ; gia s v s s c du , .
D. Sai, Triolein c cng thc phn t l C 57H104O6.
Cu 22: Chn B
- Cho CO2 vo dung dch Ca(OH)2
CaCO3: 0,6 mol v Ca(HCO3)2.
- Cho NaOH tc dng ti a th: Ca(HCO3)2 + 2NaOH CaCO3 + Na2CO3 + 2H2O
0,1 0,2
n 8

BT: C
n CO2 n CaCO3 2n Ca(HCO3 )2 0,8 mol ntinh bt = CO 2 mol mtinh bt = 86, 4 (g)
2H% 15
Cu 23: Chn C
- Cc phn ng xy ra:
2BaCO3 (Z) + 2H2O
BaCO3 (Z) + 2NaCl
BaCO3 (Z) + H2SO4
BaSO4 + CO2 + H2O
Cu 24: Chn A
- Ta c cn bng sau: , 2CrO42- + 2H+

Cr2O72- + H2O

mu vng mu da cam
CrO3 + 2NaOHd
2Na2CrO4 + H2SO4 d
Na2Cr2O7 + Na2SO4 + H2O (dung dch Y c mu da cam)
Cu 25: Chn A
- t:
C6 H 5COOC 2 H 5 : y mol 136x 150y 23, 44 y 0,12
CH 3COONa : 0, 04 mol C6 H 5ONa : 0, 04 mol
Cu 26: Chn B
H 2 :0,18mol
0
t HCl
NaOH
BT:H nHCl 2nH2 nH O
2 3
mrn 152nCr2O3
27
BT:e 3nAl 2nH2
2
Cu 27: Chn D
[C6H7O2(OH)3]n.
B. ng, C6H7O2(OH)3 + 3HNO3 H 2SO4
glicozit.
Cu 28: Chn B
It
96500
Ti catot Ti anot
Cu2+ + 2e Cu 2Cl- Cl2 + 2e
2H2O + 2e 2OH - + H2 H2O 4H+ + O2 + 4e
mol

BT:e

71x 32y 5,47 y 0,06mol
3Fe 8H 2NO3
3Fe2 2NO 4H 2O
0,075mol 0,2mol
mFe bha tan 0,075.56 4,2(g)

Cu 29: Chn A
nBr2
- Gi s triglixerit X c c to thnh t 2 axit oleic v 1 axit stearic th: nE
0,06mol
2
- Xt hn hp mui c: 304nC17H33COONa 306nC17H35COONa mmui 304.0,06.2 306.0,06 54,84(g)
- Ta nhn thy biu thc trn hon ton chnh xc nn gi s ban u l ng.
- Vy X l (C17H33COO)2C3H5(OOCC17H35), suy ra M X 886
Cu 30: Chn C
- Quy i hn hp rn thnh Fe v O. Khi cho rn tc dng vi 0,74 mol HNO 3 th:
56nFe 16nO mhn h p
56nFe 16nO 12,48
nFe 0,18mol
BT:e BT:e

3nFe 2nO 3nNO 3nFe 2nO 0,24 nO 0,15mol
- p dng bo ton e ton qu trnh. Khi cho dung dch tc dng vi lng d Cu th :
nNO HNO34 O 0,11mol nCu(bhon tan)

n 2n 3 nNO 2nO 2nFe
0,135mol mCu 8,64(g)
2
Cu 31: Chn C.
A. Sai, Cc polime tng hp c th c iu ch bng phn ng trng ngng hoc trng hp. Ly v d:
trng hp vinyl clorua
B. Sai, Poli(vinyl axetat) (PVA) tc dng vi dung dch NaOH hay cao su thin nhin tc dng vi HCl:
C. ng, Protein l mt loi polime thin nhin c trong t tm, lng cu, len.
D. Sai, Trong cu trc ca cao su buna S khng c cha lu hunh.
xt,t o ,p
nCH 2 CH CH CH 2 nCH 2 CH C 6 H 5
[ CH 2 CH CH CH 2 CH 2 CH(C 6 H 5 ) ]
Buta 1,3ien Stiren Poli (butaien stiren) Cao su Buna S
Cu 32: Chn A.
(a) Sai, Gang l hp kim ca Fe vi C trong c cha t 2 5% khi lng Cacbon ngoi ra cn 1
lng nh cc nguyn t Si, Mn, S
(b) ng, Nc cng l nc cha nhiu ion Ca2+ v Mg2+.
(c) Sai, Cho t t dung dch HCl vo dung dch K2CrO4 dung dch t mu vng chuyn sang mu lc
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O
(d) Sai, Bt nhm trn vi bt st(III) oxit (bt tecmit) c dng hn ng ray bng phn ng nhit
0
nhm: 2Al + Fe2O3 t
Al2O3 + 2Fe
(e) ng. Nc kh c nhng u im c bit i cho cng dng lm lnh v bo qun nh:

- Nc kh lnh hn (-78,5 C) nn bo qun c lu hn.
- Nc kh rt sch khi s dng v CO2 ch thng hoa thnh dng kh ch khng b tan thnh nc.
- Nc kh khi thng hoa (thnh dng kh) th to thnh mt lp kh CO2 bao bc thc phm lm c
ch nhiu loi vi sinh vt gip thc phm ti lu v c mi v t nhin.
Ngoi ra nc kh cn c ng dng nhiu trong cc ngnh cng nghip khc nh lm sch, lm
nhin liu h thng tr trong mt s loi my bay. Hoc cng c th to ra cc sn phm iu khc ngh
thut.
Vy c 3 pht biu sai l (a), (c) v (d).
Cu 33: Chn C.
nh ngha: Nhit si ca cc hp cht hu c l nhit m ti p sut hi bo ha trn b mt
cht lng bng p sut kh quyn.
cng cao.
si cao hn.
nhau:
Vy dy sp xp ng l: C2H 6 CH3CHO C2 H5OH CH3COOH
Cu 34: Chn D.
Nhng cht tc dng c vi dung dch AgNO 3/NH3:
Ank-1-in (ankin c lin kt ba u mch): Phn ng th H bng ion kim loi Ag:
- Phng trnh: RCCH + AgNO 3 + NH3
RCCAg + NH4NO3
- c bit: CHCH (axetilen) + 2AgNO 3 + 2NH3 AgCCAg + 2NH4NO3
Andehit (phn ng trng gng): Trong phn ng ny andehit ng vai tr l cht kh:
- Phng trnh: R-(CHO)x + 2xAgNO3 + 3xNH3 + xH2O
R(COONH4)x + 2xAg + 2xNH4NO3
- c bit: HCHO (anehit fomic) + 4AgNO 3 + 6NH3 + 2H2O (NH4)2CO3 + 4Ag + 4NH4NO3
Cc hp cht khc:
- Axit fomic: HCOOH; Este ca axit fomic: HCOOR; Glucoz,Fructoz: C 6H12O6; Mantoz:
C12H22O11
Vy nhng cht to kt ta vi AgNO3/NH3 l:
Vinyl axetilen Glucoz, Fructoz Metyl fomat Axetanehit, Anehit axetic ivinyl
CHCCH=CH2 C6H12O6 HCOOCH3 CH3CHO CHCCCH
Cu 35: Chn B.
- Este X, mch h, 2 chc c cng thc phn t l C6H6O4 ng vi 4 2COO 2CC
- Ancol Y khng phn ng vi Cu(OH)2 iu kin thng v khi un vi H2SO4 c 170oC khng to
ra anken Y l CH3OH.
Vy este X c to ra t axit khng no, mch h 2 chc, c l lin kt CC v CH3OH.
H SO

HOOCC CCOOH (Z) 2CH 3OH (Y)
2 4
H 3COOCC CCOOCH 3 (X) 2H 2O
o
t
A. Sai, Trong X c mch cacbon khng phn nhnh.
B. ng.
C. Sai, Cht Y c nhit si thp hn C2H5OH.
D. Sai, Phn t cht Z c 2 nguyn t hiro v 4 nguyn t oxi.

Cu 36: Chn C.
o
t
- Phn ng: HOOC-COOCH3 (X) + 2NaOH NaOOC-COONa (Y) + CH3OH (Z) + H2O
A. Sai, X c cng thc cu to l HOOC-COOCH3.
B. Sai, X cha nhm COO v COOH.
C. ng, Y c cng thc phn t l C2O4Na2.
D. Sai, un nng CH3OH vi H2SO4 c 1700C thu c 1 ete l CH3OCH3.
Cu 37: Chn B.
- Khi cho 0,16 mol Fe tc dng vi dung dch hn hp gm 0,08 mol NaNO 3 v 0,18 mol H2SO4 ta
c cc qu trnh phn ng xy ra nh sau:
S oxi ha S kh
Fe2 2e
Fe NO3 4H 3e
NO 2H 2O
0,08mol 0,36mol 0,24mol 0,08mol
2H 2e
H2
0,04mol 0,04mol 0,02mol
3nNO 2nH2
BT:e
nFe2 0,14mol
2
- Khi cho dung dch thu c tc dng vi lng d dung dch Ba(OH) 2 th:
nFe(OH)2 nFe2 0,14mol v nBaSO4 0,18mol m 90nFe(OH)2 233nBaSO4 54,54(g)
Cu 38: Chn D.
- Xt trng hp dung dch Y cha 2 cht tan l NaOH v NaCl. Qu trnh in phn din ra nh sau :
Ti catot: Ti Anot:
Fe + 2e Fe
2+
2Cl- Cl2 + 2e
x 2x x (2x + 2y) (x + y) (2x + 2y)
2H2O + 2e 2OH- + H2
2y 2y y
3
- T phng trnh: Al 3H 2O NaOH Na[Al(OH)4 ] H 2 suy ra
2
n OH n Al 0, 02 y 0, 01 mol
- Khi lng dung dch gim: 56x 71n Cl2 2n H2 4,54 x 0,03 mol
BT: e
FeCl2 :0, 03mol AgNO3 n Ag n FeCl2 0, 03
- Hn hp X: m =
NaCl :0, 06 mol
BT: Cl
n AgCl 2n FeCl2 n NaCl 0,12
20, 46 gam
Cu 39: Chn A.
Mg, MgO 0,5 mol khY (M Y 32)
- Qu trnh: X H 2SO 4 c c n
Mg(HCO3 ) 2 , MgSO3 dd30% dd Z (36%) MgSO4 : 0, 6 mol
58,8
- Ta c: n H 2SO4 n MgSO4 0, 6 mol m H 2SO 4 58,8 gam m dd H 2SO 4 196 gam
0,3
120n MgSO4
C% 36% m 200 m dd H 2SO4 m kh 20 gam
m m dd H 2SO 4 m kh
Cu 40: Chn C.
t0
P1 H 2SO4 SO2 : 0,04 mol
0,02mol 0,04mol
t0 H 2 : 0,015 mol
- Qu trnh: Fe x O y , Cr2O3 , Al Y
P2 HCl
dung dch Z NaOH kt ta
X
0,25mol x mol 6,6 gam

BT:H n HCl 2n H 2 BT:O
- Xt P2 ta c: n H 2O 0,11 mol n O(Y) n O(X) n H 2O 0,11 mol
2
- Xt P1 : quy i hn hp Y thnh : Al : 0,02 mol; Cr : 0,02 mol ; O : 0,11 mol v Fe.
BT:e 2n O 2n SO2 3n Cr 3n Al
n Fe 0, 06 mol
3
2
Fe :x mol 2
Cr :y mol Al3 : 0, 02 mol
+ Dung dch Z: ; v
BT: Fe 3 BT:Cr 3

Fe :(0,06 x) mol
Cr :(0, 02 y) mol Cl : 0, 25 mol
90n Fe(OH)2 107n Fe(OH)3 86n Cr(OH)2 6, 6 -17x 86 y 0,18 x 0, 04
BTDT (Z)
2n Fe2 3n Fe3 2n Cr 2 3n Cr 3 3n Al3 n Cl x y 0, 05 y 0, 01
(V dung dch Z phn ng ti a vi NaOH nn kt ta Cr(OH)3 tan ht).
- Hng t duy 1:
+ Ta c: nNaOH ti a = x = 2n Fe 2 3n Fe3 2n Cr 2 4n Cr 3 4n Al3 0, 28 mol
- Hng t duy 2:
+ Dung dch sau cng cha: n NaCrO2 0,01mol; n NaAlO2 0,02mol v n NaCl 0, 25mol
BT:Na
n NaOH n NaCrO2 n NaAlO2 n NaCl 0, 28mol

THPT HM LONG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Kh no sau y l tc nhn ch yu gy ma axit ?

A. N2. B. NH3. C. CH4. D. SO2.
(1) CuO + H2 Cu + H2O (2) 2CuSO4 + 2H2O 2Cu + O2 + 2H2SO4
(3) Fe + CuSO4 FeSO4 + Cu (4) 2Al + Cr2O3 Al2O3 + 2Cr
S phn ng dng iu ch kim loi bng phng php nhit luyn l.
A. 4 B. 3 C. 2 D. 1
Cu 3: Cp cht no sau y khng phn ng c vi nhau?
A. Anilin + nc Br2 B. Glucoz + dung dch AgNO3/NH3, un nng.
C. Metyl acrylat + H2 (xt Ni, t0) D. Amiloz + Cu(OH)2.
Cu 4: Tn ca hp cht CH3-CH2-NH-CH3 l ?
A. Etylmetylamin. B. Metyletanamin C. N-metyletylamin D. Metyletylamin
Cu 5: bo v v tu bin, ngi ta thng dng phng php no sau y ?
A. Dng cht c ch s n mn. B. Dng phng php in ha.
C. Dng hp kim chng g. D. Cch li kim loi vi mi trng bn ngoi.
Cu 6: Dy cc ion xp theo chiu gim dn tnh oxi ha l.
A. Ag+, Cu2+, Fe3+, Fe2+ . B. Ag+ , Fe3+, Cu2+, Fe2+.
3+ + 2+ 2+
C. Fe , Ag , Cu , Fe . D. Fe3+, Cu2+, Ag+, Fe2+.
Cu 7: Hp cht no sau y thuc loi ipeptit ?
A. H2N-CH2-CO-NH-CH2-CO-NH-CH2-COOH. B. H2N-CH2-CH2-CO-NH-CH2-COOH
C. H[HN-CH2-CH2-CO]2OH. D. H2N-CH2-CO-NH-CH(CH3)-COOH.
Cu 8: Trong s cc loi t sau: t nitron; t visco; t nilon-6,6; t lapsan. C bao nhiu loi t thuc
t nhn to (t bn tng hp) ?
A. 3. B. 2. C. 1. D. 4
Cu 9: Ha tan ht m gam bt nhm trong dung dch HCl d, thu c 0,16 mol kh H 2. Gi tr m l.
Cu 10: Ha tan ht 15,755 gam kim loi M trong 200 ml dung dch HCl 1M, c cn dung dch sau
phn ng thu c 23,365 gam rn khan. Kim loi M l.
A. Ba B. Al C. Na D. Zn
Cu 11: Cho cc cht: etyl axetat, anilin, metyl aminoaxetat, glyxin, tripanmitin. S cht tc dng
c vi dung dch NaOH l.
A. 2. B. 4. C. 3. D. 5.
Cu 12: Saccaroz v glucoz u c:
A. phn ng vi Cu(OH)2 nhit thng to thnh dung dch xanh lam.
B. phn ng vi nc brom.
C. phn ng thu phn trong mi trng axit.
D. phn ng vi AgNO3 trong dung dch NH3, un nng.
Cu 13: Cho 18,92 gam este X n chc, mch h tc dng vi dung dch NaOH va , thu c
6,88 gam ancol metylic v mui ca axit cacboxylic Y. Cng thc phn t ca Y l.
Cu 14: Cho 22,02 gam mui HOOC-[CH2]2-CH(NH3Cl)COOH tc dng vi 200 ml dung dch gm

NaOH 1M v KOH 1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l.
Cu 15: Cho phn ng: NaCrO2 + Br2 + NaOH Na2CrO4 + NaBr + H2O. Sau khi phn ng cn
bng, tng h s ti gin ca phn ng l.
A. 25. B. 24. C. 26. D. 28.
Cu 16: Kim loi c nhng tnh cht vt l chung no sau y?
A. Tnh do, tnh dn nhit, nhit nng chy cao.
B. Tnh do, tnh dn in, tnh dn nhit v c nh kim.
C. Tnh dn in, tnh dn nhit, c khi lng ring ln, c nh kim.
D. Tnh do, c nh kim, tnh cng.
Cu 17: Pht biu no sau y sai ?
A. Sn phm ca phn ng x phng ho cht bo l glixerol v x phng.
B. S nguyn t hiro trong phn t este n v a chc lun l mt s chn.
C. Nhit si ca tristearin thp hn hn so vi triolein.
D. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn.
Cu 18: Cho cc cht sau: HOOC-[CH2]2-CH(NH2)COOH (1), H2N-CH2-COOCH3 (2), ClH3N-CH2-
COOH (3), H2N-[CH2]4-CH(NH2)COOH (4), HCOONH4 (5). S cht va tc dng vi dung dch HCl;
va tc dng vi dung dch NaOH l.
A. 2 B. 5 C. 4 D. 3
Cu 19: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na 2CO3
0,2M v NaHCO3 0,2M. Sau khi phn ng kt thc, th tch kh CO 2 thu c ktc l.
A. 448 ml. B. 672 ml. C. 336 ml. D. 224 ml.
Cu 20: Cho 50,0 gam hn hp X gm Fe3O4, Cu v Mg vo dung dch HCl long d, sau phn ng
c 2,24 lt H2 (ktc) v cn li 18,0 gam cht rn khng tan. Phn trm khi lng Fe 3O4 trong X l.
A. 46,4%. B. 59,2%. C. 52,9%. D. 25,92%
Cu 21: Cho m gam hn hp M (c tng s mol 0,03 mol) gm ipeptit X, tripeptit Y, tetrapeptit Z v
pentapeptit T (u mch h) tc dng vi dung dch NaOH va , thu c hn hp Q gm mui ca
Gly, Ala v Val. t chy hon ton Q bng mt lng oxi va , thu ly ton b kh v hi em hp
th vo bnh ng nc vi trong d, thy khi lng tng 13,23 gam v c 0,84 lt kh(ktc) thot ra.
Gi tr ca m gn nht vi gi tr no sau y ?
A. 6,0 B. 6,9 C. 7,0 D. 6,08
Cu 22: Hp cht hu c X mch h c cng thc phn t C4H6O4. Bit rng khi un X vi dung dch
bazo to ra hai mui v mt ancol no n chc mch h. Cho 17,7 gam X tc dng vi 400 ml dung
dch NaOH 1M, c cn dung dch sau phn ng thu c khi lng cht rn khan l :
A. 11,20 B. 5,60 C. 8,96 D. 4,48
Cu 24: ha tan ht 38,36 gam hn hp R gm Mg, Fe3O4, Fe(NO3)2 cn 0,87 mol dung dch
H2SO4 long, sau khi cc phn ng xy ra hon ton thu c 111,46 gam sunfat trung ha v 5,6 lt
(ktc) hn hp kh X gm hai kh khng mu, t khi hi ca X so vi H2 l 3,8 (bit c mt kh khng
mu ha nu ngoi khng kh).Phn trm khi lng Mg trong R gn vi gi tr no sau y ?
A. 31,28 B. 10,8 C. 28,15 D. 25,51

A. 5. B. 7. C. 8. D. 6.
Cu 27: Thnh phn chnh ca qung Mandehit l:
A. FeCO3. B. Fe2O3. C. FeS2. D. Fe3O4.
Cu 28: Cht no sau y phn ng vi Cu(OH) 2 / NaOH to dung dch mu tm ?
A. Anbumin. B. Glucoz. C. Glyxyl alanin. D. Axit axetic.
Cu 29: Cho dung dch mui X n d vo dung dch mui Y, thu c kt ta Z. Cho Z vo dung
dch HNO3 (long, d), thu c cht rn T v kh khng mu ha nu trong khng kh. X v Y ln
lt l :
A. AgNO3 v Fe(NO3)2. B. AgNO3 v FeCl2. C. AgNO3 v FeCl3. D. Na2CO3 v BaCl2.
A. CH2=C(CH3)COOCH3. B. CH2=CH-CN.
C. CH2=CH-Cl. D. H2N-(CH2)6-COOH.
A. 11,20 B. 5,60 C. 8,96 D. 4,48
Cu 32: Cht X (c M = 60 v cha C, H, O). Cht X phn ng c vi Na, NaOH, v NaHCO 3. Tn
gi ca X l :
A. axit axetic B. axit fomic C. metyl fomat D. metyl axatat
Cu 33: t chy hon ton m gam hn hp A gm xenluloz, tinh bt, glucoz v saccaroz cn 2,52
lt O2 (ktc) thu c 1,8 gam H 2O. Gi tr m l
A. 6,20 B. 5,25 C. 3,60 D. 3,15
Cu 34: Phn ng no sau y l sai ?
A. Cu + 4HNO3 c ngui Cu(NO3)2 + 2NO2 + 2H2O.
B. 4Fe(OH)2 + O2 + 2H2O 4Fe(OH)3.
C. 3Zn + 2CrCl3 2Cr + 3ZnCl2.
D. CuO + 2HCl CuCl2 + H2O.
Cu 35: Cho cc kim loi : Al, Cu, Au, Ag. Kim loi dn in tt nht trong cc kim loi ny l :
A. Ag. B. Cu. C. Al. D. Au.
Cu 36: Cho hn hp rn X gm cc cht c cng s mol gm BaO, NaHSO 4, FeCO3 vo lng nc
d, lc ly kt ta nung ngoi khng kh n khi lng khng i, thu c rn Y cha ?
A. BaSO4 B. BaO v BaSO4
C. BaSO4 v Fe2O3 D. BaSO4, BaO v Fe2O3.
Cu 37: Cho m gam dung dch mui X vo m gam dung dch mui Y, thu c 2m gam dung dch Z
cha hai cht tan. Cho dung dch BaCl 2 d hoc dung dch Ba(OH) 2 d vo Z, u thu c a gam kt
ta. Mui X, Y ln lt l.
A. NaHCO3 v NaHSO4 B. NaOH v KHCO3
C. Na2SO4 v NaHSO4. D. Na2CO3 v NaHCO3
Cu 38: Nhng thanh Fe nng m gam vo 300 ml dung dch CuSO4 1M, sau mt thi gian, thu c
dung dch X c cha CuSO4 0,5M, ng thi khi lng thanh Fe tng 4% so vi khi lng ban u.
Gi s th tch dung dch khng thay i v lng Cu sinh ra bm hon ton vo thanh st. Gi tr m l.
mui. S ng phn cu to ca X l.
A. 2 B. 1 C. 6 D. 8
Cu 40: t chy 34,32 gam cht bo X bng lng oxi va , thu c 96,8 gam CO 2 v 36,72 gam
nc. Mt khc 0,12 mol X lm mt mu ti a V ml dung dch Br 2 1M. Gi tr ca V l.
A. 120 ml B. 360 ml C. 240 ml D. 480 ml
----------HT----------

PHN TCH HNG DN GII
THI TH THPT HM LONG BC NINH LN 1
Cu 1: Chn D.
- Ma axt l hin tng ma m trong nc ma c pH di 5,6 ; c to ra bi lng kh thi
SO2 v NOx t cc qu trnh pht trin sn xut con ngi tiu th nhiu than , du m v cc nhin
liu t nhin khc.
Cu 2: Chn C.
- Phng php nhit luyn c ng dng rng ri trong cng nghip iu ch nhng kim loi c
hot ng ha hc trung bnh nh Zn, Cr, Fe, Sn, PbC s ca phng php ny l kh nhng ion kim
loi trong cc hp cht nhit cao bng cc kim loi mnh nh C, CO, H2 hoc Al, kim loi kim,
kim th.
Vy c 2 phn ng tha mn l (1), (4).
Cu 3: Chn D.
A.
to
B. C6H12O6 + 2[Ag(NH3)2]OH CH2OH[CHOH]4COONH4 + 2Ag + 3NH3 + H2O
Ni, t o
C. CH2=CH-COOCH3 + H2 CH3-CH2-COOCH3
D. Amiloz + Cu(OH)2 : khng phn ng
Cu 4: Chn A.
Hp cht Tn gc chc Tn thay th
CH3-CH2-NH-CH3 Etylmetylamin N-metyletanamin
Cu 5: Chn B.
Phng php in ha:
- bo v v tu bin bng thp, ngi ta gn cht nhng tm km vo phn v tu ngm trong nc
bin. V khi gn ming Zn ln v tu bng thp s hnh thnh mt pin in, phn v tu bng thp l cc
dng, cc l Zn l cc m v b n mn theo c ch:
anot (cc m): Zn Zn2+ + 2e catot (cc dng): 2H2O + O2 + 4e 4OH-
Kt qu l v tu c bo v, Zn l vt hi sinh, n b n mn.
Cu 6: Chn B.
Tnh oxi ha ca ion kim loi tng dn
+ + 2+ 2+ + 2+ 3+ 2+ 2+ 3+ 2+ 2+ 2+ 2+ + 2+ 3+ 2+ + 2+ 3+
Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb 2H Cu Fe Hg Ag Pd Au
2+
Li K Ba Ca Na Mg Al Mn Zn Cr Fe Ni Sn Pb H2 Cu Fe Hg Ag Pd Au
Tnh kh ca kim loi gim dn
- Dy th in cc chun ca kim loi l dy sp xp cc kim loi theo th t tng dn th in cc

chun.
Theo chiu E0Mn+/M tng: Tnh oxi ha ca ion kim loi cng tng v tnh kh ca kim loi cng gim.
- Dy sp xp ng theo chiu tnh oxi ha gim dn l: Ag+ < Fe3+ < Cu2+ < Fe2+.
Cu 7: Chn D.
- H2N-CH2CO-NH-CH(CH3)-COOH l ipeptit v c to t cc amino axit l NH2CH2COOH
(glyxin), NH2CH(CH3)COOH (alanin).
Cu 8: Chn C.

- Cc loi t nhn to (hay t bn tng hp) xut pht t cc polime thin nhin (thng thng polime
thin nhin l xenloluz) nhng c ch bin thm bng phng php ha hc nh: t visco, t
xenluloz axetat.
Cu 9: Chn C.
BT: e 2n 8
n Al H 2 mol m Al 2,88 (g)
3 75
Cu 10: Chn A.
- Xt trng hp 1: M khng tc dng vi H2O.
BTKL m 36,5n HCl m M
n H 2 r 0,155 mol . Nhn thy 2n H2 n HCl : v l.
2
- Xt trng hp 2: M tc dng vi H2O.
+ Phn ng: 2M + 2nHCl
2MCln + nH2 2M + 2nH2O
2M(OH)n + H2
mol: 0,2/n 0,2 0,2/n a na a
0, 03
+ Ta c: mrn = m M 35,5n Cl 17n OH 15, 755 35,5.0, 2 17.an 23, 365 an 0, 03 a
n
15, 755 15, 755n n2
M M 137 : Ba
0, 03 0, 2 0, 03 0, 2

n n
Cu 11: Chn B.
Cc cht hu c tc dng vi NaOH thng gp l :
to
C6H5ONa + H2O
-COONa + H2O
to
RNH2 + NaCl + H2O
H2NRCOONa + H2O
Vy c 4 cht tha mn l: etyl axetat, metyl aminoaxetat, glyxin, tripanmitin.
Cu 12: Chn A.
Tnh cht ha hc Saccaroz Glucoz
Cu(OH)2 , t thng
o
To thnh dung dch xanh lam To thnh dung dch xanh lam
Nc br2 Khng lm mt mu nc Br2 Lm mt mu nc Br2
Thy phn To glucoz v fructoz Khng c phn ng
AgNO3 / NH3, un nng Khng c phn ng To kt ta trng Ag
Cu 13: Chn C.
18,92
- Ta c: n X n CH3OH 0, 215 mol M X 88 : X l C2H5COOCH3 Y l C3H 6O 2
0, 215
Cu 14: Chn C.
BTKL
- Ta c: n H 2O n OH n NaOH n KOH 0, 4 mol mrn = mmui + mkim m H 2O = 34, 02 (g)
Cu 15: Chn A.
2x Cr 3 Cr 6 3e
- Qu trnh oxi ha kh:
3x Br2 2e 2Br

- Cn bng phn ng: 2NaCrO 2 + 3Br2 + 8NaOH 2Na2CrO4 + 6NaBr + 4H2O
Cu 16: Chn B.
- Tnh cht vt l chung ca kim loi l: tnh do, tnh dn in, tnh dn nhit v nh kim.
Cu 17: Chn C.
A. ng, Khi thy phn cht bo (RCOO)3C3H5 trong mi trng kim th sn phm thu c l x
phng RCOONa v glixerol C3H5(OH)3.
B. ng, Cng thc tng qut ca este l: CnH2n + 2 - 2k - 2aO2a vi cc gi tr ca a v k th s nguyn t
H trong phn t este lun l s chn.
C. Sai, V phn t khi ca tristearin > triolein nn nhit si ca tristearin cao hn so vi triolein.
D. ng, Trong cng nghip, chuyn ha cht bo lng thnh cht bo rn ngi ta dng phn ng
hiro ha.
Cu 18: Chn C.
* Nhng cht va tc dng vi HCl v va tc dng vi NaOH thng gp trong hu c:
H 2 NRCOOH NaOH H 2 NRCOONa H 2O
- Aminoaxit:
H 2 NRCOOH HCl ClH3 NRCOOH
H 2 NRCOOR NaOH H 2 NRCOONa ROH
- Este ca aminoaxit:
H 2 NRCOOR HCl ClH3 NRCOOR
RCOONH3R ' NaOH RCOONa R ' NH 2 H 2O
- Mui ca amoni ca axit hu c:
RCOONH3R ' HCl RCOOH NH 4Cl
RNH3HCO3 ,(RNH3 ) 2 CO3 NaOH RNH 2 Na 2CO3 H 2O
- Mui amoni ca axit v c:
RNH3HCO3 ,(RNH3 ) 2 CO3 HCl RNH3Cl CO2 H 2O
Vy c 4 cht tha mn l: (1), (2), (4) v (5).
Cu 19: Chn D.
- Ta c: nCO2 nHCl nNa2CO3 0,01mol VCO2 0,224(l)
Cu 20: Chn A.
- Khi cho 50 gam X tc dng vi HCl d, ta c h sau :
64nCu 232nFe3O4 24nMg mX m rn khng tan 32 nCu 0,1mol
BT:e
2nCu 2nFe3O4 2nMg 2nH 2 0,2 nFe3O4 0,1mol %mFe3O4 46,4
n n 0,1mol
Fe3O4 nCu Mg
Cu 21: Chn D.
- Quy i hn hp M thnh C2H3ON (a mol), - CH2 (b mol) v H2O (c mol)
- Hn hp Q thu c ( quy i) gm C 2H4ONa (a mol) v CH2 (b mol). Khi t Q ta c :
nC2H 3ON 2nN 2 a 0,075 a 0,075

nH 2O nM c 0,03 c 0,03
44n 44(1,5a b) 18(2a b) 13,23 b 0,09
CO2 18nH 2O mdd t ng
Vy mM 57nC2H3ON 14n CH 2 18nH 2O 6,075(g)
Cu 22: Chn A.
t0
- Phn ng : HCOO CH 2 COOCH 3 NaOH HCOONa HO CH 2 COONa CH 3OH
BTKL
mrn khan mX 40nNaOH 32nCH3OH 28,9(g)
Cu 23: Chn C.

ln men
- Phn ng : C6H12O6
2C2H 5OH 2CO2
H 80%
0,25mol 0,25.2.0,8mol
VCO2 8,96(l)
Cu 24: Chn C.
- Hn hp kh X gm 0,2 mol H2 v 0,05 mol NO.
m 98nH2SO4 mmui mX

BTKL
nH2O R 0,57mol
18
- Xt hn dung dch mui v hn hp R c :
2n 2nH 2 2nH 2O n nNO

BT:H
nNH 4 H 2SO4 0,05mol nFe(NO3 )2 NH 4 0,05mol
4 2
nO(trong oxit) 2nH 2SO4 2nH 2 4nNO 10nNH 4
nFe3O4 0,08mol
4 4.2
m 232nFe3O4 180nFe(NO3 )2
%mMg R .100 28,15
mR
Cu 25: Chn B.
to
FeCl2
Cht rn F l AgCl.
Cu 26: Chn C.
- Cc phn ng xy ra:
CuSO4 + SO2 + 2H2O
Cu(NO3)2 + 2NO2 + 2H2O
(2) Cu(OH)2 + 2C6H12O6
(C6H11O6)2Cu + 2H2O
(7) 3AgNO3 + FeCl3
3AgCl + Fe(NO3)3
(4) 3Fe2+ + 4H+ + NO3
3Fe3+ + NO + 2H2O
(8) 2Al + Cr2(SO4)3
Al2(SO4)3 + 2Cr
2a a
2FeCl 3 Hn hp rn X gm: FeCl3:
+ Ban u: 2Fe 3Cl 2 mol v Fe d: mol.
a a 2a 3 3
3
3FeCl 2 Phn ng va nn dd Y cha FeCl2.

+ Sau khi cho nc vo rn X: Fe 2FeCl3
a 2a a
3 3
- em dung dch Y tc dng vi cc cht sau:
FeCl2 + 3AgNO3
Fe(NO3)3 + 2AgCl trng + Ag .
FeCl2 + 2NaOH
Fe(OH)2 trng xanh + 2NaCl
2FeCl2 + Cl2 2FeCl3
Cu + FeCl2: khng phn ng

Cu 27: Chn D.
- Qung st quan trng l : qung hematit (Fe2O3 khan), qung hematit nu (Fe2O3.nH2O), qung
manhetit (Fe3O4), qung xierit (FeCO3), qung pirit st (FeS2).
Cu 28: Chn A.
- Khi cho anbumin (protein c trong lng trng trng) phn ng vi Cu(OH) 2 to dung dch mu tm.
Cu 29: Chn A.
A. AgNO3 + Fe(NO3)2
Fe(NO3)3 + Ag
3Ag + 4HNO3
3AgNO3 + NO + 2H2O
B. 3AgNO3 + FeCl2
3Ag + 4HNO3
3AgNO3 + NO + 2H2O v AgCl + HNO3 : khng phn ng
C. 3AgNO3 v FeCl3 Fe(NO3)3 + 3AgCl
AgCl + HNO3 : khng phn ng
D. Na2CO3 + BaCl2
BaCO3 + 2NaCl
BaCO3 + 2HCl BaCl2 + CO2 + H2O
Cu 30: Chn A.
Cu 31: Chn C.
ln men
- Phn ng : C6H12O6
2C2H 5OH 2CO2
H 80%
0,25mol 0,25.2.0,8mol
VCO2 8,96(l)
Cu 32: Chn A.
2CH 3COOH 2Na
2CH 3COONa H 2 CH 3COOH NaOH
CH 3COONa H 2O
CH 3COOH NaHCO3
CH 3COONa CO 2 H 2O
Cu 33: Chn D.
- Khi t chy hn hp cc cacbohidrat ta lun c : nO2 nCO2 0,1125 mol
BTKL
mA 44nCO2 mH2O 32n O2 3,15(g)
Cu 34: Chn C.
Cu 35: Chn A.
- Dy sp xp tnh dn in gim dn : Ag > Cu > Au > Al.
Cu 36: Chn C.
- Cho hn hp X vo nc ta c: BaO + NaHSO 4 BaSO4 + NaOH + H2
- Hn hp rn gm BaSO4, FeCO3. Khi nung hn hp rn trong khng kh n khi lng khng i:
o
4FeCO3 + O2
t
2Fe2O3 + 4CO2
Vy rn Y thu c l BaSO 4 v Fe 2O3
Cu 37: Chn C.
- Cc phn ng xy ra:
Na2SO4 + BaCl2
BaSO4 + 2NaCl ; 2NaHSO4 + BaCl2
BaSO4 + Na2SO4 + 2HCl
Na2SO4 + Ba(OH)2 BaSO4 + 2NaOH ; NaHSO4 + Ba(OH)2
NaOH + BaSO4 + H2O
Khi lng kt ta thu c l nh nau.

Cu 38: Chn B.
- Cho Fe tc dng vi 0,3 mol CuSO 4 (lng CuSO4 ch phn ng 0,15 mol) th :
mtng
mtng M CuFe.nCu2 (p ) 1,2(g) mFe 30(g)
%Fetng
Cu 39: Chn A.
m mX 5,4
- Ta c nX mui 0,12mol M X 45 . Vy CTPT ca X l C2H7N
36,5 0,12
Vy X c 2 ng phn l: C2H5NH2 v (CH3)2 NH
Cu 40: Chn C.
nO(trongX) mX 12nCO2 2nH2O
- Khi t 34,32 gam cht bo X th: nX 0,04mol
6 16.6
n nH 2O
- p dng bt bo ha c: nCO2 nH 2O nX (k X 1) k X CO2 1 5 3CO 2CC
nX
- Cho 0,12 mol X tc dng vi dung dch Br 2 th: nBr2 2nX 0,12.2 0,24mol VBr2 0,24(l)

TNH QUNG BNH Mn: KHOA HC T NHIN HA HC
THPT HNG VNG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Cht no sau y khng tham gia phn ng trng hp ?

A. CH3 CH3 B. CH2=CHCl C. CH2=CH2 D. CH2=CHCH2
=CH
Cu 2: Thnh phn chnh ca qung xierit l
A. FeCO3 B. Fe3O4 C. FeS2 D. Al2O3. 2H2O
Cu 3: Cp cht no sau y khng xy ra phn ng ha hc ?
A. Fe + dung dch HCl B. Cu + dung dch FeCl3
C. Cu + dung dch FeCl2 D. Fe + dung dch FeCl3
Cu 4: Cho m gam hn hp X gm Cu v Fe vo dung dch H2SO4 long (d), kt thc phn ng thu
c 2,24 lt kh H2 (ktc). Khi lng ca Fe trong 2m gam X l
A. 4.48 B. 11,2 C. 16,8 D. 1,12
Cu 5: Khi un nng 25,8 gam hn hp gm ancol etylic v axit axetic c H2SO4 c lm xc tc thu
c 14.08 gam este. Nu t chy hon ton hn hp ban u thu c 23,4 ml nc. Hiu sut ca
phn ng este ha l
A. 70% B. 80% C.75% D. 85%
Cu 6: Sn phm ca phn ng thy phn saccaroz l
A. Glucoz v fructoz B. ancoletylic C. glucoz D. fructoz
Cu 7: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi
A. nc Br2. B. dung dch NaOH. C. dung dch HCl. D. dung dch NaCl.
E Qy tm Ha xanh
A. Thch cao khan (CaSO4.H2O) c dng lm phn vit bng, b bt khi gy xng.
B. Trong t nhin, cc kim loi kim tn ti di dng hp cht.
C. St l kim loi nng, c tnh dn in, dn nhit tt nht trong cc kim loi.
D. Phn chua c cng thc l NaAl(SO4)2.12H2O c dng lm trong nc c.
Cu 10: Hiro ha ht 132,6 gam triolein (vi xc tc Ni, t) sinh ra m gam cht bo rn. Gi tr ca m l
A. 132,9 B. 133,2 C. 133,5 D. 133,8

Cu 11: T lt tr em sau khi git thng vn cn st li mt lng nh ammoniac, d lm cho tr b
vim da, thm ch mn nga, ty . kh sch amoniac nn dng cht g sau y cho vo nc x
cui cng git ?
A. Phn chua B. Gim n C. Mui n D. Gng ti
Cu 12: Cr(OH)3 khng phn ng vi ?
A. Dung dch NH3 B. Dung dch H2SO4 long
C. Dung dch brom trong NaOH D. Dung dch KOH d.
Cu 13: S ng phn este mch h, c cng thc phn t C3H4O2 l
A. 2 B. 4 C. 1 D. 3
Cu 14: Glyxin khng phn ng c vi cht no di y ?
A. Cu B. HCl C. KOH D. Na2CO3
Cu 15: Kim loi no sau y c nhit si nng chy cao nht trong cc kim loi ?
A. St B. Vonfram C. Km D. ng
Cu 16: Cho dung dch NaOH n d vo dung dch cha hn hp FeCl2 v AlCl3, thu c kt ta X.
Nung X trong khng kh n khi lng khng i thu c cht rn Y. Vy Y l
A. Fe2O3. B. Fe2O3 v Al2O3. C. Al2O3. D. FeO.
(a) Cho Mg vo dung dch Fe2(SO4)3 d (b) Sc kh Cl2 vo dung dch FeCl2
(c) Dn kh H2 d qua bt CuO nung nng (d) Cho Na vo dung dch CuSO4 d
(e) Nhit phn AgNO3 (f) in phn nng chy Al2O3
Sau khi kt thc cc phn ng, s th nghin thu c kim loi l
A. 4 B. 2 C. 3 D. 5
Cu 18: Cho 50 ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 trong dung
dch NH3 thu c 2,16 gam Ag kt ta. Nng mol/l ca dung dch glucoz dng l
A. 0,20M. B. 0,01M. C. 0,10M. D. 0,02M.
Cu 19: X phng ha hon ton 14,25 gam este n chc, mch h vi 67,2 gam dung dch KOH 25%,
chng ct dung dch sau phn ng, thu c phn rn X v 57,9 gam cht lng Y. Dn ton b Y qua
bnh ng Na d, thy thot ra 32,76 lt kh H2 (ktc). Phn trm khi lng ca mui trong rn X l
A. 48,8% B. 49,9% C. 54,2% D. 58,4%
Cu 20: Nhit phn hon ton hn hp X gm a mol KNO3 v b mol Fe(NO3)2 trong bnh chn khng
thu c cht rn Y v hn hp kh Z. Cho ton b Z vo nc th thu c dung dch HNO3 v khng
c kh thot ra. Biu thc lin h gia a v b l:
A. a = 2b B. a = 3b C. b = 2a D. b = 4a
Cu 21: Ngm mt inh st trong dung dch HCl, phn ng xy ra chm. phn ng xy ra nhan hn,
ngi ta thm tip vo dung dch axit mt vi git dung dch no sau y
A. NaCl. B. FeCl3. C. H2SO4. D. Cu(NO3)2.
Cu 22: nhit cao, kh CO kh c cc oxit no sau y
A. Fe2O3 v CuO B. Al2O3 v CuO C. MgO v Fe2O3 D. CaO v MgO.
Cu 23: t chy 4,56 gam hn hp E cha metylamin, imetylamin, trimetylamin cn dng 0,36 mol
O2. Mt khc ly 4,56 gam E tc dng vi dung dch HCl long, d thu c lng mui l
Cu 24: Ha tan hon ton hn hp Mg, Al, Fe v Cu trong dung dch HNO3 (long d) thu c dung
dch X. Cho dung dch NaOH d vo dung dch X c kt ta Y. Nung kt ta Y n khi phn ng
nhit phn kt thc thu c ti a bao nhiu oxit kim loi
A. 3 B. 2 C. 1 D. 4
Cu 25: Ha tan hon ton 7,5 gam hn hp gm Mg v Al bng lng va V lt dung dch HNO3
1M. Sau khi cc phn ng kt thc, thu c 0,672 lt N2 ( ktc) duy nht v dung dch cha 54,9 gam
mui. Gi tr ca V l
A. 0,72. B. 0,65. C. 0,70. D. 0,86.

Cu 26: Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch
KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to
ca X l
A. CH3-CH2-COO-CH=CH2. B. CH2=CH-COO-CH2-CH3.
C. CH2=CH-CH2- COO -CH3. D. CH3-COO-CH=CH-CH3.
(a) Cc cht CH3NH2, C2H5OH, NaHCO3 u c kh nng phn ng vi HCOOH.
(b) Thnh phn chnh ca tinh bt l amilopectin.
(c) Cc peptit u tc dng vi Cu(OH)2 cho hp cht c mu tm c trng
(d) Anilin (C6H5NH2) tan t trong nc.
Trong cc pht biu trn, s pht biu ng l
A. 3. B. 2. C. 1. D. 4.
Cu 28: Dung dch X gm 0,01 mol Cu(NO3)2 v 0,1 mol HCl. Khi lng Fe ti a phn ng c vi
dung dch X l (bit NO l sn phm kh duy nht ca NO3-)
Cu 29: un nng dung dch cha 0,2 mol hn hp gm glyxin v axit glutamic cn dng 320 ml dung
dch NaOH 1M, c cn dung dch sau phn ng, thu c lng mui khan l
Cu 30: Cho bit th t t tri sang phi ca cc cp oxi ha kh trong dy in ha (dy th in cc
chun) nh sau: Zn2+/Zn; Fe2+/Fe; Cu2+/ Cu; Fe3+/Fe2+; Ag+/Ag. Cc kim loi v ion u phn ng c
vi ion Fe2+trong dung dch l
A. Ag, Fe3+. B. Zn, Ag+. C. Ag, Cu2+. D. Zn, Cu2+.
Cu 31: Cht khng c phn ng thy phn l
A. glucoz. B. etyl axetat. C. Gly-Ala. D. saccaroz.
Cu 32: thu c kim loi Cu t dung dch CuSO4 theo phng php thu luyn, c th dng kim
loi no sau y?
A. Ca. B. Na. C. Ag. D. Fe.
Cu 33: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l
A. CH3CHO, C2H5OH, C2H6, CH3COOH. B. C2H6, C2H5OH, CH3CHO, CH3COOH.
C. C2H6, CH3CHO, C2H5OH, CH3COOH. D. CH3COOH, C2H6, CH3CHO, C2H5OH.
Cu 34: Cc cht trong dy no sau y khi tc dng vi dung dch AgNO3/NH3 d u to ra sn phm
l kt ta
A. fructoz, anehit axetic, amilopectin, xenluloz. B. ivinyl, glucoz, metyl fomat, amiloz.
C. glucoz, metyl fomat, saccaroz, anehit axetic. D. vinylaxetilen, glucoz, metyl fomiat,
axetanehit.
un Y vi H2SO4 c 170oC khng to ra anken. Nhn xt no sau y ng
A. Cht X c mch cacbon phn nhnh.
B. Cht Z khng tham gia phn ng trng bc.
C. Cht Y c nhit si cao hn ancol etylic.
D. Phn t cht Z c s nguyn t hiro bng s nguyn t oxi.
Cu 36: Cho cc s phn ng sau (theo ng t l mol):
C7H18O2N2 (X) + NaOH X1 + X2 + H2O X1 + 2HCl X3 + NaCl
X4 + HCl X3 X4 t nilon-6 + H2O
Pht biu no sau y ng
A. X2 lm qu tm ha hng. B. Cc cht X, X4 u c tnh lng tnh.
C. Phn t khi ca X ln hn so vi X3. D. Nhit nng chy ca X1 nh hn X4.

Cu 37: Trn 2,43 gam Al vi 9,28 gam Fe3O4 ri nung nng cho phn ng xy ra mt thi gian, lm
lnh c hn hp X gm Al, Fe, Al2O3, FeO v Fe3O4. Cho ton b X phn ng vi dung dch HCl d
thu c 2,352 lt H2 (ktc) v dung dch Y. C cn Y c a gam mui khan. Xc nh gi tr ca a l
A. 27,965 B. 16,605 C. 18,325 D. 28,326
Cu 38: Cho 0,3 mol hn hp X gm 2 este n chc tc dng va vi 200 ml dung dch NaOH 2M
un nng, thu c hp cht hu c no mch h Y c phn ng trng bc v 37,6 gam hn hp mui hu
c. t chy hon ton Y ri cho sn phm hp th ht vo bnh cha dung dch nc vi trong d, thy
khi lng bnh tng 24,8 gam. Khi lng ca X l
A. 30,8 gam. B. 33.6 gam. C. 32,2 gam. D. 35,0 gam.
Cu 39: Cho m gam hn hp M gm ipeptit X, tripeptit Y, tetrapeptit Z v pentapeptit T (u mch h)
tc dng vi dung dch NaOH va , thu c hn hp Q gm mui ca Gly, Ala v Val. t chy
hon ton Q bng mt lng oxi va , thu ly ton b kh v hi em hp th vo bnh ng nc vi
trong d, thy khi lng bnh tng 13,23 gam v c 0,84 lt kh (ktc) thot ra. Mt khc, t chy hon
ton m gam M, thu c 4,095 gam H2O. Gi tr ca m gn nht vi gi tr no sau y
A. 6,0. B. 6,5. C. 7,0. D. 7,5.
Cu 40: Dung dch X gm 0,02 mol Cu(NO3)2 v 0,1 mol H2SO4. Khi lng Fe ti a phn ng c
vi dung dch X l (bit NO l sn phm kh duy nht ca NO3-).
A. 4,48 gam. B. 5,60 gam. C. 3,36 gam. D. 2,24 gam. `
-----------HT-----------

PHN TCH HNG DN GII
THI TH THPT HNG VNG QUNG BNH LN 1
Cu 1: Chn A.
Cu 2: Chn A.
Cu 3: Chn C.
Fe + 2HCl
FeCl2 + H2 Cu + 2FeCl3
2FeCl2 + CuCl2
Cu + FeCl2 : khng xy ra Fe + 2FeCl3
3FeCl2
Cu 4: Chn B.
BT:e
n Fe (trong m gam X) n H 2 0,1mol . Vy mFe(trong 2m gam X) 2.0,1.56 11,2(g)

- Lu : Cu khng tc dng vi H2SO4 long.
Cu 5: Chn B.

H 2SO 4
CH 3COOC 2 H 5 H 2O

CH 3COOH 0,16 mol
Tm tt qu trnh: 25,8 (g)
C 2 H 5OH O2 m H 2O D H 2O .V 23, 4.1
H 2 O : n H 2O 1,3 mol
18 18 18
C 2 H 5OH : x 46x 60y 25,8 x 0,3 0,16
- Gi H .100% 80%
CH 3COOH : y 3x 2y 1,3 y 0, 2 0, 2
Cu 6: Chn A.
H 2O
- Thy phn saccaroz trong mi trng axit: C12H 22O11 C6 H12O6 C6 H12O6
Saccarozo H Glucozo Fructozo
Cu 7: Chn A.
- Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi dung dch Br2 to kt ta trng
Cu 8: Chn B.
Cu 9: Chn B.
A. Sai, Thch cao nung c cng thc l CaSO4.H2O dng lm phn vit bng, b bt khi gy xng.
B. ng, Trong t nhin, cc kim loi kim ch tn ti di dng hp cht.
C. Sai, Kim loi dn in tt nht l Ag ch khng phi l Fe.
D. Sai, Cng thc phn chua l K2SO4.Al2(SO4)3.24H2O hay KAl(SO4)2.12H2O.
Cu 10: Chn C.
Ni,t o
- Phng trnh: (C17H33COO)3C3H5 + 3H2 (C17H35COO)3C3H5
mol: 0,15 0,15
m (C17 H35COO)3 C3H 5 0,15.890 133,5 (g)
Cu 11: Chn B.

- T lt tr em sau khi git thng lu li lng amoniac v bt git m mt thng khng nhn thy
c. Vi s lng cht ho hc cn xt li ny rt c th lm cho da b vim, thm ch b sng ty au
nga. Bi vy, khi git t lt, nu nh vo nc git mt vi git gim n, cc loi cht trn s c kh
sch.
Cu 12: Chn A.
- Cc phn ng ca Cr(OH)3:
Cr(OH)3 NH3 : khng phn ng
2Cr(OH)3 3H2SO4
Cr2 (SO4 )3 6H2O
2Cr(OH)3 3Br2 10NaOH
2Na 2CrO4 6NaBr 8H 2O
Cr(OH)3 KOH K[Cr(OH) 4 ]
Cu 13: Chn C.
3.2 2 4
Ta c: = = 2 = 1COO 1CC C3H4O2 l este n chc, mch h trong phn t c 1
2
lin kt C=C. Vy ch c 1 ng phn tng ng l: HCOOCH CH 2 .
Cu 14: Chn A.
Cu 15: Chn B.
Cu 16: Chn A.
NaOH(d ) O2 , t
o
- Qu trnh: FeCl 2 ,AlCl 3 Fe(OH)2 (X) Fe2O3 (Y)
FeCl2 + 2NaOH
Fe(OH)2 + 2NaCl
AlCl3 + 3NaOH
Al(OH)3 + NaCl ; v NaOH d nn: Al(OH)3 + NaOH
Na[Al(OH)4]
to
Nung trong khng kh: 4Fe(OH)2 + O2 2Fe2O3 + 4H2O
Cu 17: Chn C.
- Phng trnh xy ra:
3+
loi.
+ Nu cho Mg d tc dng vi Fe3+ th xy ra c 2 phn ng (1) v (2) khi sn phm thu c c cha
kim loi.
to
(b) Cl2 + 2FeCl2
2NaOH + H2 ; 2NaOH + CuSO4
to pnc
(e) 2AgNO3 2Ag + 2NO2 + O2 (f) 2Al 2O3
4Al 3O2
Cu 18: Chn A.
n Ag 0, 01
- Ta c: n C6H12O 6 0, 01 mol C M 0, 2 M
2 0, 05
Cu 19: Chn D.
m dd .C% m m KOH
- Ta c: n KOH 0,3 mol n H 2O dd 2,8 mol
56 18
ROH Na
- Cht lng Y gm: 57,9 (g) 2n H 2 n ROH n H 2O 2,925 n ROH 0,125 mol
2H O : 2,8 mol
m Y m H 2O
M ROH 60 : ROH l C3H 7 OH m n este n ROH 0,125 mol
n ROH

14, 25
M este 114 : C 2H 3C OOC3H 7 mui trong rn X l C2H3COOK: 0,125 mol
0,125
BTKL
m X meste mdd KOH m Y 23,55 (g) . Vy %mC2H3COOK 58, 4%
Cu 20: Chn C.
- Hng t duy 1: Cn bng phng trnh phn ng
to to
2KNO3 2KNO2 + O2 4Fe(NO3)2 2Fe2O3 + 8NO2 + O2
mol: a 0,5a b 2b 0,25b
- Cho hn hp kh Z vo H2O: 4NO2 + O2 + 2H2O
4HNO3
mol: 2b 0,5b
m nO 2
0,5a 0, 25b 2a b
Cu 21: Chn D.
Cu 22: Chn A.
Cu 23: Chn B.
- Quy i hn hp E: CH3NH2 ,(CH3 )2 NH,(CH3 )3 N thnh CnH2n+3N: a mol.
- t chy E: CnH2n+3N + (1,5n + 0,75)O2 nCO2 + (n + 1,5)H2O + 0,5N2
n O2 (1,5n 0, 75)a 0,36 (1) v mE (14n 17)a 4,56 (2). T (1), (2) ta tnh c: a = 0,12 mol
BTKL
- Cho E tc dng vi HCl th: n HCl n E 0,12 mol mmui = mE + 36,5nHCl = 8,94 (g)
Cu 24: Chn A.
Mg, Cu HNO3 d Mg(NO3 ) 2 , Cu(NO3 ) 2 NaOH d

Fe, Al Fe(NO3 )3 , Al(NO3 )3
Mg(OH) 2 ,Cu(OH) 2 t o MgO,CuO
H 2O
Fe(OH)3 Fe 2O3
- Lu : Cho mt lng d NaOH vo Al3+, ban u c kt ta trng keo khng tan sau tan dn v to
dung dch trong sut.
Cu 25: Chn D.
- Hng t duy 1: Bo ton nguyn t N
7,5 (g) V (l) 54,9 (g) hn h p mui 0,03 mol
24n Mg 27n Al 7,5 n Mg 0, 2

BT: e
BT: N
- Hng t duy 2: Tnh theo s mol HNO3
m Al3 m Mg 2 18n NH 4 62n NO3 54,9

+Ta c: BT e BTDT n NH 4 0, 05 mol
n NO3 n NH 4 (8n NH 4 10n N 2 )
n HNO3 12n N 2 10n NH 4 0,86 mol

Cu 26: Chn A.
- T t khi ta suy ra MX 100 : C5H8 O2 v nX = 0,2 mol ; nKOH = 0,3 mol. t CTTQ ca X l:
RCOOR

m rn 56nKOH d
+ Ta c: nKOH p = nRCOOK = nX = 0,2 mol nKOH d = 0,1 mol m M RCOOK 112
0,2
R l C2H5. Vy cng thc cu to ca X l C2H 5COOCH CH 2
Cu 27: Chn A.
(a) ng, Phng trnh phn ng:
CH3NH2 + HCOOH
HCOONH3CH3
H SO

2
C2H5OH + HCOOH
4
HCOOC2H5 + H2O
o
t
NaHCO3 + HCOOH HCOONa + CO2 + H2O

(b) ng, Amilopectin chim t 70 80% khi lng tinh bt trong khi amiloz chim t 20 30% khi
lng tinh bt.
(c) Sai, Cc tripeptit tr ln (ipeptit khng c phn ng ny) u tc dng vi Cu(OH)2 cho hp cht c
mu tm c trng.
(d) ng, Anilin (C6H5NH2) l cht lng, si 184oC, khng mu, rt c, tan t trong nc nhng tan
nhiu trong benzen v etanol.
Vy c 3 pht biu ng l (a), (b), (d).
Cu 28: Chn C.
S oxi ha S kh
Fe Fe + 2e
2+
4H + NO3 + 3e
+ -
NO + 2H2O
0,01 0,02
2H+(d) + 2e H2
0,02 0,02 0,01
3n NO 2n Cu 2 2n H2

BT:e
n Fe 0,05 mol mFe 2,8 (g)
2
Cu 29: Chn B.
0,32 mol
H 2 NCH 2COOH : x mol H 2 NCH 2COONa : x mol
NaOH
H 2O
HOOC(CH 2 ) 2 CH(NH 2 ) COOH : y mol NaOOC(CH 2 ) 2 CH(NH 2 ) COONa : y mol
x y 0, 2 x 0, 08
+ Ta c: mmui = 97x + 191y = 30, 68 (g)
x 2y 0,32 y 0,12
Cu 30: Chn B.
- Da vo quy tc ta xc nh c cc cp cht c phn ng vi Fe2+ l Zn, Ag . Phn ng:
Zn + Fe2+ Zn2+ + Fe Fe2+ + Ag+ Fe3+ + Ag
Cu 31: Chn A.
Cu 32: Chn D.
Cu 33: Chn C.
Cu 34: Chn D.
Nhng cht to kt ta vi AgNO3/NH3 l:
Vinyl axetilen Glucoz, Fructoz Metyl fomat Axetanehit, Anehit axetic ivinyl
CHCCH=CH2 C6H12O6 HCOOCH3 CH3CHO CHCCCH
Cu 35: Chn B.
- Este X, mch h, 2 chc c cng thc phn t l C6H6O4 ng vi 4 2COO 2CC

- Ancol Y khng phn ng vi Cu(OH)2 iu kin thng v khi un vi H2SO4 c 170oC khng to
ra anken Y l CH3OH.
Vy este X c to ra t axit khng no, mch h 2 chc, c l lin kt CC v CH3OH.
H SO

HOOCC CCOOH (Z) 2CH 3OH (Y)
2 4
H 3COOCC CCOOCH 3 (X) 2H 2O
o
t
A. Sai, Trong X c mch cacbon khng phn nhnh.
B. ng.
C. Sai, Cht Y c nhit si thp hn C2H5OH.
D. Sai, Phn t cht Z c 2 nguyn t hiro v 4 nguyn t oxi.
Cu 36: Chn B.
- Cc phn ng xy ra:
to
nH 2 N[CH 2 ]5 COOH (X 4 ) ( HN [CH 2 ]5 CO ) n nH 2O
nilon 6
H2 N[CH2 ]5 COOH (X4 ) HCl

ClH3N[CH2 ]5 COOH (X3 )
H2 N[CH2 ]5 COONa (X1) 2HCl
ClH3N[CH 2 ]5 COOH (X3 ) NaCl
H2 N [CH2 ]5 COO NH3CH3 (X) NaOH

H 2 N[CH2 ]5 COONa (X1) CH3NH2 (X2 ) H2O
A. Sai, X2 lm qu tm ha xanh.
B. ng. X v X4 u c tnh lng tnh.
C. Sai, Phn t khi ca X l 162 trong khi phn t khi ca X3 l 167,5.
D. Sai, Nhit nng chy ca X1 ln hn X4.
Cu 37: Chn A.
0,09 mol 0,04 mol 0,105 mol
to
- Qu trnh: Al ,Fe3O4 hn h p X HCl d
AlCl 3,FeCl 2 ,FeCl 3 H 2O H 2
dung dch sau p
BT: H
+ Ta c: n O (Fe3O4 ) n H 2O 0,16 mol n HCl 2(n H2 n H 2O ) 0,53 mol
- Hng t duy 1:
BTKL
a mY 36,5HCl 2n H2 18n H2O mX 36,5HCl 2n H2 18n H2O 27,965 (g)
- Hng t duy 2:
+ Ta c: a m KL 35,5n Cl 27n Al 56n Fe 35,5n HCl 27,965 (g)
Cu 38: Chn C.
- Nhn thy: nX = 0,3 < nNaOH = 0,4 trong X c cha 1 este ca phenol (A) v este cn li l (B)
(A) : RCOOC6H 4R ' n A n B 0,3 n A 0,1 n H 2O n A 0,1
Vi
(B) : R1COOCH CHR 2 2n A n B 0, 4 n B 0, 2 n Y n B 0, 2
- Khi t chy cht Y no, n chc, mch h (R2CH2CHO: 0,2 mol) lun thu c n CO2 n H 2O
n CO 2
44n CO2 18n H 2O 24,8 n CO2 0, 4 mol m C Y 2 : Y l CH 3CHO
0, 2
BTKL
m X mmui + mY + m H 2O mNaOH = 32, 2 (g)
Cu 39: Chn A.
- Hng t duy 1: Quy i hn hp M thnh CnH2n-1ON v H2O.
NaOH
- Khi : CnH2n-1ON
CnH2nO2NNa (mui trong hn hp Q).

- Khi t:
Na2CO3
CnH 2nO2NNa O2
Ca(OH) d
Q
CO2 ,H 2O,N 2
2
mb.t ng 13,23(g) v N 2 : 0,0375 mol
BT: N n NaOH n Q
n Q 2n N 2 0,075 mol v
BT: Na
n Na 2CO3 0,0375 mol
2 2

BT: H
n H 2O 0, 075n
BT: C m 44n CO2 18n H 2O 13, 23 n 3, 2
n CO 2 0, 075n 0, 0375
- Khi t:
0,075 mol a mol
O
C n H 2n 1ON , H 2O
2
n H 2O (n 0,5).0, 075 a 0, 2275 a 0, 025 mol m M 5,985 (g)
m (g) M
- Hng t duy 2: Quy i hn hp M thnh C2H3ON, CH2, H2O.
x mol Na2CO3
- Khi t: C2H 4O2NNa,CH 2 O2 0,0375 mol
Ca(OH)2 d
Q CO2 ,H 2O,N 2 mb.t ng 13,23(g) v N 2
BT: N n NaOH n C 2H 4O 2 NNa
n C2H 4O2 NNa 2n N2 0,075 mol v
BT: Na
n Na 2CO3 0, 0375 mol
2 2
m

BT: H
n H 2O 2n C2H 4O 2 NNa n CH 2 0,15 x
BT: C 44n CO 2 18n H 2O 13, 23 x 0, 09 mol
n CO 2 2n C 2H 4O 2 NNa n CH 2 n Na 2CO3 0,1125 x
- Khi t:
0,075 mol 0,09 mol a mol
O
C 2 H 4O 2 NNa , CH 2 , H 2 O
2
n H 2O 0, 2025 a 0, 2275 a 0, 025 mol m M 5,985 (g)
m (g) M
Hng t duy 2.1 : Chn khong gi tr
- Gi s hn hp M ch cha ipeptit :
- Khi
nH2O(M) nM nN2 0,0375
BT:H
nCH2 nH2O(sn phm khi t M) 1,5nC2H3ON nH2O(M) 0,0775
mM(max) 57nC2H3ON 14nCH2 18nH2O 6,035(g) . Vy mM < 6,035.
Hng t duy 3: p dng CT
nH2O nCO2 0,5nQ nH O 0,24
- t Q th 2 .
18nH2O 44nCO2 13,23 nCO2 0,2025
- t M th :
3nQ
BT:C
nCO2 (t M) nCO2 (t Q) nNa2CO3 0,24 nO2 (t Q) 1,5 nC nQ 0,30375
4
m nO2 (t Q) nCO2 (t M)
BTKL
mM 44nCO2 18nH2O 28nN2 32nO2 5,985(g)
Cu 40: Chn B.
S oxi ha S kh
Fe Fe + 2e
2+
4H + NO3 + 3e
+ -
NO + 2H2O
0,02 0,04
2H+(d) + 2e H2

0,04 0,04 0,02
3n NO 2n Cu 2 2n H2
BT:e
n Fe 0,1 mol m Fe 5,6 (g)
2

THPT L THI T Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Dy kim loi sp xp theo tnh kh tng dn l (tri sang phi):

A. Fe, Al, Mg B. Al, Mg, Fe C. Fe, Mg, Al D. Mg, Al, Fe
Cu 2: Bt ngt l mui ca:
A. axit oleic B. axit axetic C. axit aminoaxetic D. axit glutamic
A. Tt c cc amino axit u lng tnh.
B. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
C. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH) 2 cho hp cht mu tm.
D. Trong 1 phn t tetrapeptit c 4 lin kt peptit.
Cu 4: Dy gm cc kim loi u phn ng vi nc nhit thng thu c dung dch c mi
trng kim l:
A. Na, Ba, K B. Be, Na, Ca C. Na, Fe, K D. Na, Cr, K
Cu 5: Mt trong nhng cht liu lm nn v p k o ca tranh sn mi l nhng mnh vng lp lnh
cc mng. Ngi ta ng dng tch cht vt l g ca vng khi lm trang sn mi ?
A. C kh nng khc x nh sng B. Tnh do v c nh kim
C. Tnh do, tnh dn nhit D. Mm, c t khi ln
Cu 6: Polime no sau y trong thnh phn c cha nit ?
A. Polibutaien B. Polietilen C. Poli(vinyl clorua) D. Nilon-6,6
Cu 7 : Amino axit l hp cht hu c trong phn t c cha ?
A. nhm cacboxyl B. 1 nhm amino v 1 nhm cacboxyl
C. nhm amino D. nhm amino v nhm cacboxyl
Cu 9: Cht no di y l etyl axetat ?
A. CH3COOCH2CH3 B. CH3COOH
C. CH3COOCH3 D. CH3CH2COOCH3
Cu 10: un nng 5,18 gam metyl axetat vi 100ml dung dich NaOH 1M n phn ng hon ton.
C cn dung dch sau phn ng, thu c m gam cht rn khan. Gi tr ca m l:
A. 8,20 B. 6,94 C. 5,74 D. 6,28
Cu 11: Cht no sau y cn c gi l ng mt ong ?
A. Saccaroz B. Fructoz C. Glucoz D. Amilopectin
Cu 12: Ln men hon ton a gam glucoz, thu c C 2H5OH v CO2. Hp th ht CO2 sinh ra vo
A. 30,6 B. 27,0 C. 15,3 D. 13,5
Cu 13: Mt phn t polieilen c khi lng phn t bng 56000u. H s polime ha ca phn t
polietylen ny l:
A. 20000 B. 2000 C. 1500 D. 15000
Cu 14: Polime c cu trc mng li khng gian l:
A. Polietilen B. Poli(vinyl clorua) C. Amilopectin D. Nha bakelit
Cu 15: Cho dy cc dung dch sau: C 6H5NH2, NH2CH2COOH, HOOC[CH2]2CH(NH2)COOH
C2H5NH2, NH2[CH2]2CH(NH2)COOH. S dung dch trong dy lm i mu qu tm ?

A. 4 B. 5 C. 2 D. 3
Cu 16: Cho cc cht sau: CH3COOCH3, HCOOCH3, HCOOC6H5, CH3COOC2H5. Cht c nhit
si thp nht l:
A. HCOOC6H5 B. CH3COOC2H5 C. HCOOCH3 D. CH3COOCH3
Cu 17: Khng nh no sau y ng ?
A. un nng tinh bt vi dung dch axit th xy ra phn ng khu mch polime.
B. Trng hp axit -amino caproic thu c nilon-6.
C. Polietilen l polime trng ngng.
D. Cao su buna c phn ng cng.
Cu 20: Cht A c cng thc phn t l C 4H9O2N, bit:
t0 t0
A + NaOH B + CH3OH (1) B + HCl d C + NaCl (2)
Bit B l mui ca -amino axit, cng thc cu to ca A, C ln lt l:
A. H2NCH2CH2COOCH3 v ClH3NCH2CH2COOH
B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH
C. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH
D. CH3CH2CH2(NH2)COOH v CH3CH2CH(NH3Cl)COOH
A. 0,10. B. 0,12. C. 0,14. D. 0,16.
A. 4 B. 2 C. 3 D. 5

A. 2 B. 1 C. 4 D. 3
Cu 24: t chy hon ton 1 lng hn hp 2 este. Dn sn phm chy ln lt qua bnh (1) ng
P2O5 d v bnh (2) ng dung dch Ca(OH) 2 d, thy khi lng bnh (1) tng 6,21 gam, cn bnh
(2) thi c 34,5 gam kt ta. Cc este trn thuc loi este no sau y ?
A. Este no, n chc, mch h B. Este khng no
C. Este thm D. Este a chc
Cu 25: t chy hon ton m gam hn hp X gm 2 este ng phn cn dng 4,704 lt kh O 2 , thu
c 4,032 lt CO2 v 3,24 gam H2O. Nu cho m gam X tc dng ht vi 110 ml dung dch KOH
1M. C cn dung dch sau ph ng th thu c 7,98 gam cht rn khan, trong c a mol mun Y
v b mol mui Z (M Y > MZ ). Cc th tch kh u o iu kin chun. T l a : b l:
A. 2 : 3 B. 3 : 2 C. 2 : 1 D. 1 : 5
Cu 26: Trong thnh phn ca du gi u thng c mt s este. Vai tr ca cc este ny l:
A. tng kh nng lm sch ca du gi. B. lm gim thnh phn ca du gi.
C. to mu sc hp dn. D. to hng thm mt, d chu.

Cu 27: Cho dung dch cha 14,6 gam Lysin (H2N-[CH2]4-CH(NH2)COOH) tc dng vi lng d dung
dch HCl, thu c dung dch cha m gam mui. Gi tr ca m l:
A. 21,90. B. 18,25. C. 16,43. D. 10,95.
Cu 28: t chy hon ton mt lng etyl axetat thu c 0,54 gam H2O v V lt (ktc) kh CO2. Gi
tr ca V l:
A. 0,538. B. 1,320. C. 0,672. D. 0,448.
Cu 29: Trng hp 224 lt etilen (ktc), thu c bao nhiu gam PE vi hiu sut 70% ?
Cu 30: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c, xc tc axit sunfuric c, nng.
c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric, hiu sut phn ng t 90%.
Gi tr ca m l:
A. 6,3. B. 21,0. C. 18,9. D. 17,0.
A. 3 B. 2 C. 4 D. 5
A. 16,6 B. 18,85 C. 17,25 D. 16,9
Cu 33: Ha tan ht hn hp gm Mg, Al v Al(NO 3)3 trong dung dch cha NaHSO 4 v 0,06 mol
NaNO3 kt thc phn ng thu c dung dch X cha cc mui trung ha c khi lng 115,28 gam
v V lt (kc) hn hp kh T gm N2O v H2 (t l 1 : 1). Cho dung dch NaOH d vo X thy lng
NaOH phn ng l 36,8 gam, ng thi thu c 13,92 gam kt ta. Gi tr ca V l:
A. 1,344 B. 1,792 C. 2,24 D. 2,016
Cu 34: Cho cc cht sau y: H 2, AgNO3/NH3 d, Cu(OH)2, NaOH v O2. Vi iu kin thch hp,
s cht phn ng vi glucoz:
A. 2 B. 4 C. 3 D. 5
Cu 35: Ha tan 13,68 gam mui MSO 4 vo nc c dung dch X. in phn X (vi in cc tr,
cng dng in khng i) trong thi gian t giy, c m gam kim loi M duy nht catot v
0,784 lt kh anot. Cn nu thi gian in phn l 2t giy th tng th tch kh thu c c hai
in cc l 2,7888 lt. Bit th tch cc kh iu kin tiu chun. Gi tr ca m l:
A. 4,788. B. 4,480. C. 1,680. D. 3,920.
A. Khi b m mang thai cn b sung cc thc n giu st.
B. Saccarin (C7H5NO3S) l mt loi ng ha hc c gi tr dinh dng cao v ngt gp 500
ln saccaroz nn c th dng cho ngi mc bnh tiu ng.
C. Du m qua s dng nhit cao (rn, quay) nu ti s dng c nguy c gy ung th.
D. Melamine (cng thc C 3H6N6) khng c gi tr dinh dng trong sa, ngc li c th gy ung
th, si thn.
Cu 37: Trn 2,43 gam Al vi 9,28 gam Fe 3O4 ri nung nng sau mt thi gian thu c hn hp X
gm Al, Fe, Al2O3, FeO v Fe3O4. Cho ton b X phn ng vi dung dch HCl d thu c 2,352 lt
H2 (ktc) v dung dch Y. C cn Y c a gam mui khan. Xc nh gi tr ca a l:
A. 27,965 B. 16,605 C. 18,325 D. 28,326
A. Dung dch CuSO4 dng trong nng nghip d cha mc sng cho c chua.
B. Nh C2H5OH vo CrO3 thy hin tng bc chy.

C. Nh dung dch NH3 ti d vo dung dch CuSO 4 c kt ta xanh lam.
D. Cu l kim loi mu , thuc kim loi nng, mm v d dt mng.
Cu 39: Kim loi no di y c dng lm t bo quang in ?
A. Na B. Li C. Ba D. Cs
Cu 40: Cho 8,64 gam Al vo dung dch X (c to thnh bng cch ha tan 74,7 gam hn hp Y
gm CuCl2 v FeCl3 vo nc). Kt thc phn ng thu c 17,76 gam cht rn gm hai kim loi. T
l s mol FeCl3 : CuCl2 trong hn hp Y l:
A. 2 : 1 B. 3 : 2 C. 3 : 1 D. 5 : 3
----------HT----------

PHN TCH HNG DN GII
THI TH THPT L THI T HI PHNG LN 1
Cu 1: Chn A
Cu 2: Chn D.
- Mui mononatri ca axit glutamic l thnh phn chnh ca bt ngt hay m chnh.
Cu 3: Chn A.
A. ng, Tt c cc amino axit u l nhng lng tnh.
B. Sai, Cc hp cht peptit km bn trong c mi trng axit ln mi trng baz.
C. Sai, Cc ipeptit mch h tr ln mi c th tc dng c vi Cu(OH) 2 cho hp cht mu tm.
D. Sai, Trong 1 phn t tetrapeptit th ch c 3 lin kt peptit.
Cu 4: Chn A.
- Cc kim loi kim, kim th u tc dng vi H2O nhit thng (tr Be khng phn ng vi
H2O bt k nhit no) v dung dch thu c l cc baz tng ng.
2M + 2H2O
2MOH + H2 (M l kim loi kim)
N + 2H2O N(OH)2 + H2 (N l kim loi kim th, tr Be)
Cu 5: Chn B.
Cu 6: Chn D.
Polibutaien: ( CH 2 CH CH CH 2 ) n Polietilen: ( CH 2 CH 2 ) n
Poli(vinyl clorua) Nilon-6,6
CH2 CH N (CH2)6 N C (CH2)4 C
Cl n H H O O
n
Cu 7: Chn D.
- Amino axit l loi hp cht hu c tp chc m phn t cha ng thi nhm amino (NH2) v nhm
cacboxyl (COOH). Cng thc chung: (H2N)x R (COOH)y
Cu 8: Chn B.
Cu 9: Chn A.
Cu 10: Chn B.
t0
- Phn ng: CH 3COOCH 3 NaOH CH 3COONa CH 3OH
mrn khan 40nNaOH(d ) 82nCH 3COONa 6,94(g)

Cu 11: Chn B.
- Saccaroz hay cn gi l ng ma, ng tht nt.
- Fructoz l thnh phn chnh ca mt ong (fructoz c ngt ln nht trong cc loi cacbohidrat).
- Glucoz hay cn gi l ng nho, ng tri cy.
- Amilopectin l mt on mch ca tinh bt.
Cu 12: Chn D.
nCO2 nCaCO3
2 2
Cu 13: Chn B.
56000
- Ta c: M ( CH 2 CH 2 )n 56000 n 2000
28
Cu 14: Chn D.
- Cc polime mch phn nhnh thng gp l amilopectin v glicozen.
- Cc polime mch khng gian thng gp l cao su lu ha v nha rezit (nha bakelit).
- Cc polime mch khng phn nhnh thng gp l cn li.
Cu 15: Chn D.

- Cc amin c tnh baz nn c kh nng lm i mu qu tm chuyn thnh mu xanh tr anilin (v
ng ng ca n) khng lm i mu qu tm do c tnh baz yu.
- i vi cc amino axit c dng (H 2N)x-R-(COOH)y th :
+ Nu x > y : qu tm chuyn sang mu xanh
+ Nu x = y : qu tm khng i mu.
+ Nu x < y : qu tm chuyn sang mu .
Vy c 3 dung dch lm i mu qu tm l:
Dung dch HOOC[CH2]2CH(NH2)COOH C2H5NH2 NH2[CH2]2CH(NH2)COOH
Mu qu tm Xanh Xanh
Cu 16: Chn C.
cng cao.
si cao hn.
nhau:
Vy cht c nhit si thp nht l HCOOCH3.
Cu 17: Chn D.
A. Sai, un nng tinh bt vi dung dch axit th xy ra phn ng ct mch polime .
B. Sai, Trng hp axit -aminocaproic thu c nilon-6.
C. Sai, Polietilen l polime c iu ch t phn ng trng hp.
D. ng, Trong phn t cao su buna: ( CH2 CH CH CH2 ) cn lin kt i C = C, nn c th
tham gia phn ng cng.
Cu 18: Chn A.
Cu 20: Chn B.
t0
CH3CH(NH2)COOCH3 + NaOH CH3CH(NH2)COONa + CH3OH (1)
0
CH3CH(NH2)COONa + HCl d t
CH3CH(NH3Cl)COOH + NaCl (2)
Cu 21: Chn C.

BTKL
m X 44n CO2 18n H 2O 32n O2 12,32 (g)
n n H 2O
n O(trong X) 0, 014 mol n X
6
Cu 22: Chn C.
- Phng trnh xy ra:
+ Nu cho Mg tc dng vi Fe 3+ d th ch dng li phn ng (1) khi sn phm s khng c kim
loi.
cha kim loi.

to
(b) Cl2 + 2FeCl2
to pnc
(e) 2AgNO3 2Ag + 2NO2 + O2 (f) 2Al 2O3
4Al 3O2
Cu 23: Chn A.
(a) Cu(d) + 2Fe(NO3)3
(b) CO2 (d) + NaOH
NaHCO3
Cu 24: Chn A.
mbnh 1 tng mbnh 2 tng
- t chy hn hp este th: nH2O 0,345mol v nCO2 nCaCO3 0,345mol
18 100
- Nhn thy rng nH2O nCO2 , nn trong X ch cha cc este no, n chc, mch h.
Cu 25: Chn D.
- Khi t chy m gam X ta nhn thy nCO2 nH 2O X cha 2 este no, n chc mch h.
BT:O 2nCO2 nH 2O 2nO2 n
nCOO nX 0,06mol CX CO2 3(C3H 6O2 )
2 nX
- Khi cho m gam X trn tc dng vi 0,11 mol KOH th :
68nHCOOK 82nCH3COOK mrn khan 56nKOH 5,18 nHCOOK 0,05mol n 0,01 1
CH3COOK
nHCOOK nCH3COOK nX 0,06 nCH3COOK 0,01mol nHCOOK 0,05 5
Cu 26: Chn D.
- Mt s este c mi thm ca hoa qu c dng trong cng nghip thc phm (bnh ko, nc gii
kht) v m phm (x phng, nc hoa).
Cu 27: Chn A.
BTKL
- Ta c: n HCl 2n lysin 0, 2 mol mmui = m lysin 36,5n HCl 21,9 (g)
Cu 28: Chn C.
- Khi t chy etyl axetat thu c: n CO 2 n H 2O 0, 03 mol VCO 2 0, 672 (l)
Cu 29: Chn D.
VC2H 4
- Ta c: m PE 28n PE 28. .H % 196 (g)
22, 4
Cu 30: Chn B.
H SO ,t o
- Phn ng: [C6H7O2(OH)3]n + 3nHNO3 (c) 2 4
29, 7 1
m HNO3 63n HNO3 63.3. . 21 (g)
297 90%
Cu 31: Chn A.
0
HOCH2[CHOH]4CH2OH
thy phn xenluloz.

Cu 32: Chn A.
t0
mrn 138nK 2CO3 56nKOH(d ) 16,6(g)

Cu 33: Chn B.
- Hn hp Mg, Al v Al(NO) 3 tc dng vi dung dch cha NaHSO 4 (x mol) v 0,06 mol NaNO 3.
- Dung dch X gm Mg2 (0,24mol) , Al 3 (y mol) , Na (x 0,06mol),NH 4 (y mol) v SO42- (x mol).
(Lu : s mol ca Mg2+ c tnh nhanh qu trnh cho dung dch X tc dng vi 0,92 mol NaOH
13,92
c 13,92 gam vi mc ch thun tin gii bi tp, c nMg2 nMg(OH)2 0,24mol )
58
+ Xt dung dch X:

BTDT
n Na 2n Mg 2 3n Al3 n NH 4 2n SO 4 2 x 0, 06 0, 24.2 3y z 2x (1)
23n Na 24n Mg2 27n Al3 18n NH4 96nSO42 mX 23(x 0,06) 0, 24.24 27y 18t 96x 115, 28(2)
- Xt hn hp kh T ta c : nH2 nN2O t mol
- M n NaHSO4 10n NH4 10n N2O 2n H2 x 10z 12t (3)
- Xt dung dch thu c sau khi cho X tc dng vi dung dch cha 0,92 mol NaOH, ta c:

BTDT
n Na 2n SO 4 2 n AlO 2 x 0, 06 0,92 2x y (4)
- Gii h (1), (2), (3) v (4) ta c t 0, 04 mol . Khi nH 2 nN 2O 0,04mol VT 1,792(l)
Cu 34: Chn B.
- C 4 cht tc dng vi glucoz l: H 2, AgNO3/NH3 d, Cu(OH)2 v O2
0
HOCH 2[CHOH] 4 CHO H 2
Ni,t
HOCH 2[CHOH] 4 CH 2OH
0
HOCH 2[CHOH] 4 CHO 2AgNO3 3NH 3
t
HOCH 2[CHOH] 4 COONH 4 2Ag 2NH 4NO3
2C6H12O6 Cu(OH)2
(C6H11O6 )2 Cu 2H2O
0
C6H12O6 6O2
t
6CO2 6H 2O
Cu 35: Chn B.
Thi im Ti catot Ti anot
2
t (s) M 2e
M 2H 2O
4e 4H O2
ne trao i = 0,14 mol 0,14mol 0,035mol
2t (s) M 2 2e
M 2H 2O
4e 4H O2
ne trao i = 0,28 mol amol 2amol 0,28mol 0,07mol
2OH H 2
2H 2O 2e
2bmol bmol
- Ti thi im 2s (s), xt hn hp kh ta c :

BT:e
2nM 2 2nH 2 4nO2 2a 2b 0,28 a 0,0855
+
n
H2 0,1245 nO2 b 0,0545 b 0,0545
13,68
M MSO4 160 , suy ra M l Cu.
0,0855
- Ti thi im t (s) th nCu 2nO2 0,07mol mCu 4,48(g)
Cu 36: Chn B.
Cu 37: Chn A.
- Khi cho hn hp X tc dng vi dung dch HCl d, ta c: n O (Fe3O4 ) n H 2O 0,16 mol
BT: H
n HCl 2(n H2 n H 2O ) 0,53 mol

Cu 38: Chn C.
A. ng, Dung dch CuSO4 dng trong nng nghip d cha mc sng cho c chua.
B. ng, Nh C2H5OH vo CrO3 thy hin tng bc chy:
C2H5OH + 2CrO3 Cr2O3 + 2CO2 + 3H2O
C. Sai, Nh dung dch NH 3 ti d vo dung dch CuSO 4 xy ra cc phn ng sau :
CuSO4 + 2NH3 + 2H2O
Cu(OH)2xanh lam + (NH4)2SO4
Cu(OH)2 + 4NH3 [Cu(NH3)2](OH)2 : phc mu xanh lam
D. ng, Cu l kim loi mu , thuc kim loi nng, mm v d dt mng.
Cu 39: Chn D.
Cu 40: Chn C.
- Xt qu trnh phn ng ca Al vi dung dch X ta c:
133,5n AlCl3 127n FeCl2 m Al m Y m r 65,58(g) n AlCl3 0,32 mol

BTKL
BT:Al
n AlCl3 n Al 0,32 n FeCl2 0,18mol

135n CuCl2 162,5n FeCl3 m Y 74, 7
n CuCl2 0,12 n 3
- Trong Y c: BT:Cl FeCl3
2n CuCl2 3n FeCl3 3n AlCl3 2n FeCl2 1,32 n FeCl3 0,36
n CuCl 2 1

TNH PH YN Mn: KHOA HC T NHIN HA HC
THPT PHM VN NG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Trong s cc cht sau: xeluloz, saccaroz, frutoz, glucoz. S cht khi thy phn n cng
ch thu c glucoz l:
A. tinh bt xenluloz B. Tinh bt, xenluloz, saccaroz
C. xenluloz, fructoz, saccaroz D. Tinh bt, saccaroz
A. Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng.
B. T nilon-6,6 c iu ch t hexametyleniamin v axit axetic.
C. T visco, t xenluloz axetat thuc loi t tng hp.
D. Si bng , t tm l polime thin nhin.
Cu 3: Sobitol l sn phm ca phn ng ?
A. Oxi ha glucoz bng AgNO3 trong ammoniac.
B. Kh glucoz bng H2 ,xt Ni un nng.
C. Ln men ancol etylic.
D. Glucoz tc dng vi Cu(OH) 2.
Cu 4: Tn gi ca ca C2H5NH2 l:
A. etylamin B. imetylamin C. metylamin D. propylamin
Cu 5: tch Ag ra khi hn hp Ag, Cu, Fe m khi lng Ag khng thay i th dng cht no sau
y ?
A. HCl B. HNO3 C. Fe2(SO4)3 D. AgNO3
Cu 6: chng minh glucoz c tnh cht ca andehit, ta cho dung dch glucoz phn ng vi ?
A. Cu(OH)2 nhit thng to dung dch mu xanh lam.
B. Dung dch AgNO3 trong ammoniac.
C. Kim loi Na.
D. Dung dch HCl.
Cu 7: C 3 cht hu c: H2NCH2COOH, C2H5COOH v CH3(CH2)3NH2. nhn bit cc cht trn
dng thuc th l:
A. qu tm B. NaOH C. HCl D. H2SO4
Cu 8: Bit ion Pb trong dung dich oxi ha c Sn. Hai thanh kim loi Pb v Sn c ni vi nhau
2+
bng dy dn in v nhng vo dung dch HCl th cht b n mn in ha l:

A. HCl B. Pb C. Sn D. Pb v Sn
Cu 9: Ming chui xanh tip xc vi dung dch iot cho mu xanh tm v trong ming chui xanh c:
A. glucoz B. mantoz C. tinh bt D. saccaroz
Cu 10: Cng thc ha hc ca cht no l este ?
A. CH3CHO B. HCOOCH3 C. CH3COCH3 D. CH3COOH
Cu 11: to b nhn to (cht bo rn) t du thc vt (cht bo lng) ta cho du thc vt thc hin
phn ng ?
A. ehirro ho B. X phng ho C. Hiro ho D. Oxi ho
Cu 12: Cho hn hp hai axit bo gm axit oleic v axit stearic tc dng vi glixerol. S triglixerit ti
a to thnh l:
A. 3 B. 5 C. 8 D. 6
Cu 13: Kim loi no sau y c cng ln nht trong tt c cc kim loi ?

A. Vonfam B. ng C. St D. Crom
Cu 14: Tnh cht ho hc c trng ca kim loi l:
A. tnh oxi ho B. tnh baz C. tnh kh D. tnh axit
Cu 15: Chn pht biu ng ?
A. Phn ng gia axit cacboxylic v ancol khi c mt ca axit sunfuric c l phn ng mt chiu.
B. Phn ng thu phn metyl axetat trong mi trng axit l phn ng thun nghch.
C. Khi thu phn cht bo lun thu c etilenglicol.
D. Tt c cc este phn ng vi dung dch kim lun thu c sn phm l mui v ancol.
Cu 16: Dy gm cc cht c sp xp theo th t tng dn lc baz t tri sang phi l:
A. phenylamin, etylamin, amoniac B. phenylamin, amoniac, etylamin
C. etylamin, amoniac, phenylamin D. etylamin, phenylamin, amoniac
Cu 17: Cht thuc loi isaccarit l:
A. fructoz B. glucoz C. xenluloz D. saccaroz
Cu 18: Hp cht no sau y thuc loi tripeptit ?
A. H2N-CH2-CO-NH-CH(CH3)-COOH B. H2N-CH2-CO-NH-CH2-CO-NH-CH2-COOH
C. H2N-CH2-CH2-CO-NH-CH2-COOH D. H2N-CH2-CH2-CO-NH-CH2-CH2-COOH
Cu 19: Hn hp X cha ba este mch h, trong phn t ch cha mt loi nhm chc v c to
bi t cc axit cacboxylic c mch khng phn nhnh. t chy ht 0,2 mol X cn dng 0,52 mol O2,
thu c 0,48 mol H2O. un nng 24,96 gam X cn dng 560 ml dung dch NaOH 0,75M thu c
hn hp Y cha cc ancol c tng khi lng l 13,38 gam v hn hp Z gm hai mui, trong c
a gam mui A v b gam mui B (MA < MB). T l gn nht a : b l:
A. 0,6 B. 1,2 C. 0,8 D. 1,4
Cu 20: un nng 0,1 mol hn hp E cha X, Y bng dung dch NaOH (va ). C cn dung dch
sau phn ng thu c m gam mui ca glyxin, alanin v valin. t chy hon ton lng mui ny
thu c 0,2 mol Na2CO3 v hn hp gm CO2, H2O, N2 trong tng khi lng ca CO2 v H2O
l 65,6 gam. Mt khc t chy 1,51m gam hn hp E cn dng a mol O 2 thu c CO2, H2O v N2.
Gi tr ca a gn nht vi ?
A. 3,0 B. 2,5 C. 3,5 D. 1,5
Cu 21: C by ng nghim ng ring bit trong nm ng nghim (NH4)2SO4, FeCl2, Cr(NO3)3,
K2CO3, Al(NO3)3, K2Cr2O7 v (COONa)2. Cho Ba(OH)2 n d vo by ng nghim trn. Sau khi
cc phn ng kt thc s ng nghim thu c kt ta l:
A. 4 B. 5 C. 6 D. 7
Cu 22: Hp cht hu c n chc X phn t ch cha cc nguyn t C, H, O v khng c kh nng
trng bc. X tc dng va vi 96 gam dung dch KOH 11,66%. Sau phn ng c cn dung dch
thu c 23 gam cht rn Y v 86,6 gam nc. t chy hon ton Y thu c sn phm gm 15,68
lt CO2 (ktc); 7,2 gam nc v mt lng K 2CO3. Cng thc cu to ca X l:
A. CH3COOC6H5. B. HCOOC6H4CH3. C. HCOOC6H5. D. H3C6H4COOH.
A. 0,10. B. 0,12. C. 0,14. D. 0,16.
A. 4 B. 2 C. 3 D. 5

A. 66,98 B. 39,4 C. 47,28 D. 59,1
Cu 27: Nhn xt no sau y ng ?
A. a s cc polime d ha tan trong cc dung mi thng thng.
B. a s cc polime khng c nhit nng chy xc nh.
C. Cc polime u bn vng di tc ng ca axit, baz.
D. Cc polime d bay hi.
Cu 29: Mt tripeptit X mch h c cu to t 3 amino axit l glyxin, alanin, valin. S cng thc
cu to ca X l:
A. 6 B. 3 C. 4 D. 8
Cu 30: Cacbohidrat no sau y c dng lm nguyn liu sn xut t visco ?
A. Saccaroz B. Tinh bt C. Glucoz D. Xenluloz
Cu 31: Cho 11 gam hn hp X gm hai este n chc, mch h tc dng ht vi 200 gam dung dch
KOH 5,6% un nng, chng ct dung dch sau phn ng thu c Y gm hai ancol ng ng k tip
c cn phn dung dch cn li c m gam cht rn khan. Cho Y vo bnh na d th khi lng bnh
tng 5,35 gam v c 1,68 lt kh thot ra (kc). Bit 16,5 gam X lm mt mu ti a dung dch cha a
gam Br2. Gi tr gn ng ca (m + a) l :
A. 40,7 B. 60,7 C. 56,7 D. 52,7
Cu 32: Cho cc pht biu sau v cacbohidrat :
(c) Trong dung dch glucoz v saccarozo u ha tan Cu(OH) 2 to phc mu xanh lam.
(d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit ch thu
(e) Khi un nng glucoz vi dung dch AgNO 3/NH3 thu c Ag.
(g) Glucoz v saccaroz u tc dng vi H 2 (xc tc Ni, un nng) to sorbitol.
S pht biu ng l:
A. 3 B. 4 C. 5 D. 6
Cu 33: Tin hnh in phn vi in cc tr v mng ngn xp mt dung dch cha m gam hn hp
CuSO4 v NaCl cho n khi nc bt u b in phn c hai in cc th dng li. anot thu
c 0,896 lt kh (kc). Dung dch sau khi in phn c th ha tan ti a 3, 2 gam CuO. Gi tr ca
m l:
A. 11,94 B. 9,60 C. 5,97 . D. 6,40
Cu 34: Ha tan hon ton 25,3 gam hn hp X gm Mg, Al v Zn bng dung dch HNO 3. Sau khi
phn ng kt thc thu c dung dch Y v 4,48 lt (kc) kh Z (gm hai hp cht kh khng mu) c
khi lng 7,4 gam. C cn dung dch Y thu c 122,3 gam hn hp mui. S mol HNO 3 tham
gia phn ng gn nht vi gi tr no sau y ?
A. 1,81 mol B. 1,95 mol C. 1,8 mol. D. 1,91 mol
Cu 36: Hn hp X cha cht A (C5H16O3N2) v cht B (C4H12O4N2) tc dng vi dung dch NaOH va
, un nng cho n khi phn ng xy ra hon ton ri c cn thu c m gam hn hp Y gm 2 mui

D v E (MD < ME) v 4,48 lt (ktc) hn hp Z gm 2 amin no, n chc, ng ng k tip c t khi so
vi H2 bng 18,3. Khi lng ca mui E trong hn hp Y l:
A. 4,24 B. 3,18 C. 5,36 D. 8,04
Cu 37: Hn hp gm 1,3 mol Mg v x mol Zn vo dung dch cha 2 mol Cu v 2 mol Ag+ sau phn
2+
ng hon ton, lc b phn dung dch thu c cht rn gm 2 kim loi. Gi tr ca x c th l:

A. 1,8 B. 2 C. 2,2 D. 1,5
Cu 38: in phn 200 ml dung dch CuSO4 0,75M bng in cc tr vi cng dng in khng i
I = 5A, n khi khi lng dung dch gim 13,35 gam th dng in phn. Thi gian in phn l ?
Cu 39: Nh t t n d dung dch Ba(OH) 2 ln lt vo cc dung dch sau: NaHCO 3, AlCl3,
NaHSO4, (NH4)2CO3, FeCl3, Na2SO4 v KNO3. S trng hp thu c kt ta l:
A. 4 B. 6 C. 7 D. 5
Cu 40: X l -amino axit trong phn t cha 1 nhm NH2 v 1 nhm -COOH. Ly 0,01 mol X tc
dng va vi dung dch HCl 0,1M thu c dung dch Y. Cho 400 ml dung dch KOH 0,1M vo
Y, c cn dung dch sau phn ng, thu c 2,995 gam rn khan. Cng thc cu to ca X l.
A. H2N-CH2-CH2-COOH B. (CH3)2-CH-CH(NH2)-COOH
C. H2N-CH2-COOH D. CH3-CH(NH2)2-COOH
----------HT----------

PHN TCH HNG DN GII
THI TH THPT PHM VN NG PH YN LN 1
Cu 1: Chn A.
Cc cacbohirat khi thy phn n cng ch thu c glucoz l: Tinh bt, xenluloz v mantoz.
H O
- Thy phn mantoz: C12H22O11
2C6H12O6 (glucoz)
2
H
H
- Thy phn tinh bt, xenluloz: (C6H10O5 ) n nH 2O nC6H12O6
Cu 2: Chn D.
A. Sai, Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng hp.
B. Sai, T nilon-6,6 c iu ch t hexametyleniamin v axit aipic.
C. Sai, T visco v t xenluloz axetat thuc loi t bn tng hp (hay t nhn to).
D. ng, Si bng v t tm l polime thin nhin.
Cu 3: Chn B.
Ni,t o
- Phn ng kh glucoz: CH2OH[CHOH]4CHO + H2 CH2OH[CHOH]4CH2OH (sobitol)
Cu 4: Chn A.
Tn gi Etylamin imetylamin Metylamin Propylamin
Cng thc cu to C2H5NH2 CH3NHCH3 CH3NH2 CH3CH2CH2NH2
Cu 5: Chn C.
- tch Ag ra khi hn hp gm Ag, Fe v Cu ta dng dung dch Fe2(SO4)3.
Fe2(SO4)3 + Fe 3FeSO4 Cu + Fe2(SO4)3 CuSO4 + 2FeSO4
- Ag khng tan trong dung dch Fe2(SO4)3 nn ta tch ly phn khng tan ra l Ag.
Cu 6: Chn B.
- Phn ng chng minh glucoz c tnh cht ca andehit l phn ng gia glucoz vi dung dch
AgNO3 trong NH3, un nng (thuc th Tollens) cho phn ng trng bc:
to
Cu 7: Chn A.
Cht
H2N-CH2-COOH C2H5COOH CH3(CH2)3NH2
Thuc th
Qu tm Khng i mu Ha . Ha xanh.
Cu 8: Chn C.
- Trong n mn in ha ca cp kim loi Sn-Pb, Sn l kim loi c tnh kh mnh hn ng vai tr l
anot (cc m) v b n mn cn Pb c tnh kh mnh hn ng vai tr l catot (cc dng) v c
bo v; khi Sn b n mn ht th lc Pb s b n mn.
Cu 9: Chn C.
- Trong ming chui xanh c cha tinh bt, khi cho tip xc vi dung dch iot th c mu xanh tm.
Ngc li, i vi ming chui chn th lc tinh bt b thy phn ht khi cho tip xc vi dung
dch iot th khng c hin tng xy ra.
Cu 10: Chn B.
Cng thc cu to CH3CHO HCOOCH3 CH3COCH3 CH3COOH
Thuc loi Anehit Este Xeton Axit cacboxylic
Cu 11: Chn C.
- Trong thnh phn cht bo rn c cha cc gc axit bo no do vy chuyn ha thnh cc cht bo
lng c cha cc gc axit bo khng no th ngi ta dng phn ng ehiro ha. Ngc li, chuyn
ha cht bo lng thnh cht bo rn ngi ta dng phn ng hiro ha.
Cu 12: Chn D.
- Gi A v B ln lt l cc gc ca axit bo: C 17H33COO- v C17H35COO- . C 6 triglixerit ti a
to thnh tng ng vi cc gc axit bo l : AAA ; ABA ; AAB ; BBB ; BAB ; BBA.
Cu 13: Chn D.
Cu 14: Chn C.
Cu 15: Chn B.

A. Sai, Phn ng gia axit cacboxylic v ancol khi c mt ca axit sunfuric c l phn ng thun
nghch.
B. ng, Phn ng thu phn metyl axetat trong mi trng axit l phn ng thun nghch.
C. Sai, Khi thu phn cht bo lun thu c glixerol.
D. Sai, Ly v d: HCOOC6H5 + 2NaOH HCOONa + C6H5ONa + H2O
Cu 16: Chn B.
- Dy sp xp tnh baz tng dn l: phenylamin (C 6H5NH2) < amoniac (NH3) < etylamin (C2H5NH2)
Cu 17: Chn D.
Cu 18: Chn B.
Cu 19: Chn D.
- Quy i hn hp X thnh gc hidrocacbon C xHy v nhm COO (CO2). V vy khi t X th s mol
O2 tham gia phn ng chnh bng s mol O 2 t gc C xHy.
- Khi t 0,2 mol X (gi nh t nhm C xHy) th :
BT:O
nCO2 (khi t CxH y ) nO2 0,5nH2O 0,28 mCxH y 12nCO2 2nH2O 4,32(g)
- Cho 24,96 gam X tc dng vi NaOH th
6,48
nX(trong 24,96g) 0,2. 0,3mol
4,32
nCOO nNaOH 0,42 mCx H y 24,96 44nCOO 6,48
nCOO(trong 0,2 mol X) 0,42 0,28mol

1,5
+ Ta nhn thy rng nC(trong gc Cx H y ) nC(trong nhm COO) 0,28 , v th s nguyn t C trong gc
CxHy bng s nhm COO trong cc phn t este.
n 0,42
+ Mc khc : nCOO NaOH 1,4 . T 2 d kin trn ta suy ra c cc este trong X l
nX 0,3
HCOOCH3,(COOCH3)2 v HCOOCH2CH2OOCH . Khi :

BTKL
68nHCOONa 134n(COONa)2 mX 40nNaOH mancol 28,38 nHCOONa 0,24mol

BT:Na
nHCOONa 2n(COONa)2 nNaOH 0,42 n(COONa)2 0,09mol
m 0,24.68
HCOONa 1,353
m(COONa)2 0,09.134
Cu 20: Chn B.
- Qui i 0,1 mol E thnh C2H3ON, -CH2 v H2O.
+ Vi nC2H3ON 2nNa2CO3 0,4mol v nH2O nE 0,1mol
- Cho 0,1 mol E tc dng vi dung dch NaOH thu c hn hp mui ( quy i) gm C 2H4O2NNa
(0,4 mol) v CH2. Khi t hon ton lng mui trn th theo d kin bi, ta c :
44nCO2 18nH 2O mbnh tng 44(1,5nC2H 3ON nCH 2 ) 18(2nC2H 4O2Na nCH 2 ) 65,6(g) n CH 2 0,4mol
Suy ra nO2 (tham gia phn ng ch y) 2,25nC2H 3ON 1,5nCH 2 1,5mol
Vy nO2 (khi t 1,51mgamE) =1,51.1,5 = 2,265mol
Cu 21: Chn B.
(1) Ba(OH)2 + (NH4)2SO4
BaSO4 + 2NH3 + 2H2O
(2) Ba(OH)2 + FeCl2
Fe(OH)2 + BaCl2
(3) 4Ba(OH)2(d) + 2Cr(NO3)3
Ba(CrO2)2 + 3Ba(NO3)2 + 4H2O
(4) Ba(OH)2 + K2CO3
BaCO3 + 2KOH
(5) 4Ba(OH)2(d) + 2Al(NO3)3
Ba(AlO2)2 + 3Ba(NO3)2 + 4H2O
(6) 2Ba(OH)2 + K2Cr2O7
2BaCrO4 + 2KOH + H2O
(7) Ba(OH)2 + (COONa)2
Ba(COO)2 + 2NaOH

Vy c 5 ng nghim thu c kt ta l (1), (2), (4), (6) v (7).
Cu 22: Chn A.
86,8 84,8
- Ta c nKOH 0,2mol v nH 2O(trong dd KOH) 84,8(g) nH 2O(sp p v i KOH) 0,1mol
18
BTKL
- mX mmui 18nH2O(sp p v i KOH) 56nKOH 13,6(g)
nC(trong X) nCO2 nK 2CO3 0,8mol

- Khi t chy hn hp Y th :
nH(trong X) 2nH 2O(t Y) 2nH 2O(sp p v i KOH) nKOH 0,8mol

m 12nC nH
nO(trong X) X 0,2mol
16
n
Ta c C:H :O nC :nH :nO 8: 8: 2(C8H8O2 ) mc khc OH 2 X l este c to thnh t
nX
phenol hoc ng ng.
- Theo d kin bi th X khng tham gia phn ng trng bc, vy X l CH3COOC6H 5
Cu 23: Chn C.

BTKL
m X 44n CO2 18n H 2O 32n O2 12,32 (g)
n n H 2O
n O(trong X) 0, 014 mol n X
6
Cu 24: Chn C.
- Phng trnh xy ra:
+ Nu cho Mg tc dng vi Fe 3+ d th ch dng li phn ng (1) khi sn phm s khng c kim
loi.
cha kim loi.
to
(b) Cl2 + 2FeCl2
to pnc
(e) 2AgNO3 2Ag + 2NO2 + O2 (f) 2Al 2O3
4Al 3O2
Cu 25: Chn C.

102nA
C. ng, %mA .100% 50,5 %mB 49,5
102nA 60nB

D. Sai, Este A c 7 ng phn tng ng l: CH 3COO-C3H7 (2 ng phn) ; HCOO-C4H9 (4 ng
phn) ; C2H5COOC2H5 (1 ng phn) v axit B ch c 1 ng phn l CH 3COOH.
Cu 26: Chn D.
n BT: C
2
HCO3 OH Ba2
BaCO3 H 2O
mBaCO3 0,3.197 59,1(g)

Cu 27: Chn B.
A. Sai, a s cc polime khng tan trong cc dung mi thng thng.
B. ng, Hu ht cc polime khng c nhit nng chy xc nh, nng chy nhit kh rng.
C. Sai, Ly v d nh:
D. Sai, Cc polime khng bay hi.

Cu 28: Chn B.
Cu 29: Chn A.
- C 6 cng thc cu to l:
GlyAlaVal, GlyValAla, AlaGlyVal, AlaValGly, ValGlyAla, ValAlaGly.
Cu 30: Chn D.
- T visco c to thnh t phn ng gia xenluloz vi CS 2 v NaOH to thnh mt dung dch
nht gi l visco. Bm dung dch ny qua nhng l rt nh ri ngm trong dung dch H2SO4 to
thnh t visco.
Cu 31: Chn D.
- Xt hn hp ancol Y :
+ Cho Y tc dng vi Na th : nY nX 2nH2 0,15mol
mY
BTKL
mY mbnh tng 2nH2 5,5(g) M Y 36,66 . Vy trong Y gm CH3OH v C2H5OH
nY
nCH3OH nC2H5OH 2nH2 nCH OH 0,1mol
Vi 3
32nCH3OH 46nC2H5OH 5,5 nC2H5OH 0,05mol
- Khi cho 11 gam X tc dng vi 0,2 mol KOH th :

BTKL
mrn khan mX 56nKOH mY 16,7(g)
m
- Xt hn hp X ta c : M X X 73,33 . Vy trong X c cha HCOOCH3,
nX
m 60nHCOOCH3 11 60.0,1
+ Gi B l este cn li c: M B X 100(C2H 3COOC2H 5 ) .
nB 0,05

Vy hn hp X gm HCOOCH3 (0,1 mol) v C2H3COOC2H5 (0,05 mol)
- Khi cho 16,5 gam X (tc 0,15 mol HCOOCH3 v 0,075 mol C2H3COOC2H5) tc dng vi Br2 th :
nBr2 nHCOOCH3 nC2H3COOC2H5 0,225mol mBr2 36(g)
Vy mrn khan mBr2 52,7(g)
Cu 32: Chn B.
- C 4 nhn nh ng l (a), (b), (c) (e).
(d) Sai, Khi thy phn tinh bt ch thu c glucoz cn khi thy phn saccaroz th thu c c
glucoz v fructoz.
(g) Sai, Ch c glucoz phn ng vi H 2 (Ni. t0) thu c sorbitol, saccaroz th khng tham gia
phn ng hiro ha.
Cu 33: Chn A.
- V dung dch ha tan c CuO nn dung dch sau in phn c cha H + (tc l ti anot nc
in phn). Ta c : nH 2nCuO 0,08mol
Ti catot Ti anot
Cu2+ + 2e Cu 2Cl- Cl2 + 2e
x mol 2x mol x mol 2y mol y mol 2y mol
H2O 4H +
+ O2 + 4e
0,08 mol 0,02 mol 0,08 mol

BT:e
2n 2nCl 2 4nO2 2x 2y 0,08 x 0,06mol
Xt hn hp kh ta c: Cu2
nCl 2 nkh nO2
y 0,02 y 0,02mol
m 160nCuSO4 58,5nNaCl 11,94(g)
Cu 34: Chn D.
nNO nN2O 0,2 nNO 0,1mol
30nNO 44nN2O 7,4 nN2O 0,1mol
nNO3 (trong mui) 3nNO 8nN2O 9nNH4 1,1 9x
- Ta c: mmui mkim loi 18nNH4 62nNO3 122,3 25,3 18x 62(1,1 9x) x 0,05mol
nHNO3 10nNH 4 4nNO 10nN 2O 1,9mol
Cu 35: Chn D.
98nH2SO4 .100
C%
BTKL
Cu 36: Chn D.
- Khi cho hn hp X tc dng vi NaOH va th :
t0
(C2H5 NH3 ) 2 CO3 (A) 2NaOH Na 2CO3 (D) 2C2H5 NH 2 2H 2O
t0
(COONH3CH3 ) 2 (B) 2NaOH (COONa) 2 (E) CH3NH 2 2H 2O
n C2H5 NH 2 n CH3NH 2 0, 2 n C2H5NH 2 0, 08mol n E 0,5n CH3NH 2 0, 06 mol

45n C2H5 NH 2 31n CH3NH 2 0, 2.18,3.2 n CH3NH 2 0,12 mol m E 0, 06.134 8, 04(g)

Cu 37: Chn D.
- Hn hp kim loi gm Ag v Cu, gi s hn hp gm Mg v Zn tc dng va vi dung dch cha 2
2nCu2 nAg 2nMg
mol Cu2+ v 2 mol Ag+ th : nZn 1,7mol (Khng c p n).
2
- Chng t dung dch sau phn ng cha Mg2+, Zn2+ v Cu2+. V vy nZn 1,7mol

Cu 38: Chn D.
- Qu trnh in phn xy ra nh sau :
Ti catot Ti anot
2
Cu 2e
Cu 4H 4e O2
2H2O
H2O 2e H2 2OH
- Theo bi ta c h sau :

BT:e
2nH 2 2nCu2 4nO2 4nO2 2nH2 0,3 nO 0,1125mol
2
64nCu2 2nH 2 32nO2 mdd gim 32nO2 2nH 2 3,75 nH 2 0,075mol
96500ne
- Vy ne 4nO2 0,45mol t 8685(s)
I
Hng t duy 2 :
m 80nCuO 13,35 80.0,15
- Ta c nH2O dd gim 0,075mol
18 18
96500ne
- Vy ne 2nCuO 2nH 2O 0,45mol t 8685(s)
I
Cu 39: Chn D.
Ba(OH)2 + 2NaHCO3 BaCO3 + Na2CO3 + H2O
4Ba(OH)2 + 2AlCl3
Ba(AlO2)2 + 3BaCl2 + 4H2O
Ba(OH)2 + 2NaHSO4 BaSO4 + Na2SO4 + H2O
Ba(OH)2 + (NH4)2CO3 BaCO3 + 2NH3 + H2O
3Ba(OH)2 + 2FeCl3 3BaCl2 + 2Fe(OH)3
Ba(OH)2 + Na2SO4 BaSO4 + 2NaOH
Ba(OH)2 + KNO3 : khng phn ng
Vy c 5 trng hp thu c kt ta l: NaHCO 3, NaHSO4, (NH4)2CO3, FeCl3 v Na2SO4.
Cu 40: Chn C.
- Rn khan gm KOH (d), KCl, NH2RCOOK, vi nKCl nX 0,01mol v nNH2RCOOK nX 0,01mol
BT:K
nKOH(d ) nKOH nKCl nNH2RCOOK 0,02mol
mmui 74,5nKCl 56nKOH(d )
mNH2RCOOK 113 R l CH 2 X l NH 2CH 2COOH (glyxin)
nNH2RCOOK

THPT TRIU SN 1 THI TH THPT QUC GIA LN 1 NM 2017
Mn: KHOA HC T NHIN HA HC
( thi c 40 cu / 4 trang) Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi un nng cht X c cng thc phn t C5H10O2 vi dung dch NaOH thu c
C2H5COONa v ancol Y. Y c tn l
A. Ancol Etylic B. Ancol Propyolic C. Ancol isopropyolic D. Ancol Metylic
Cu 2: Cho dung dch lng trng trng tc dng vi dung dch axit nitric c,c hin tng
A. Kt ta mu tm B. Dung dch mu xanh
C. Kt ta mu vng D. Kt ta mu trng
Cu 3: Cho dy cc cation kim loi :Ca , Cu , Na , Zn2+ .Cation kim loi no c tnh oxi ha mnh
2+ 2+ +
nht trong dy
A. Ca2+ B. Cu2+ C. Na+ D. Zn2+
A. Theo chiu tng dn ca in tch ht nhn,nhit nng chy ca kim loi kim gim dn
B. nhit thng, tt c cc kim loi kim th u tc dng c vi nc
C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh
D. Nhm bn trong mi trng khng kh v nc l do mng oxi Al 2O3 bn vng bo v
Cu 5: Cho s sau :
0
HCl (d )
X (C4H9O2N) X1 X2 X3 H2N-CH2COOK
NaOH,t CH3OH,HCl (khan) KOH
Vy X2 l :
A. ClH3N-CH2COOH B. H2N-CH2-COOH
C. H2N-CH2-COONa D. H2N-CH2COOC2H5
Cu 6: Cho hn X gm Zn, Fe vo dung dch cha AgNO 3 v Cu(NO3)2, sau phn ng thu c hn
hp Y gm 2 kim loi v dung dch Z. Cho NaOH d vo dung dch Z thu c 2 kt ta gm 2
hidroxit kim loi.Dung dch Z cha
A. Zn(NO3)2, AgNO3,Fe(NO3)3 B. Zn(NO3)2 ,Fe(NO3)2
C. Zn(NO3)2, Fe(NO3)2, Cu(NO3)2 D. Zn(NO3)2,Cu(NO3)2, Fe(NO3)3
Cu 7: Oxit no sau y l lng tnh ?

A. Fe2O3 B. CrO C. Cr2O3 D. CrO3
u in phn)
Cu 9: Hp cht H2N-CH2-COOH phn ng c vi : (1) NaOH, (2) HCl, (3) C2H5OH, (4) HNO2
A. (1), (2), (3), (4) B. (2), (3), (4) C. (1), (2), (4) D. (1), (2), (3)
Cu 10: Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v khi lng.Cho
X tc dng vi dung dch hn hp gm KNO 2 v HCl thu c ancol Y. Oxi ha khng hon ton Y
thu c xeton Z. Pht biu no sau y ng ?
A. Tch nc Y ch thu c 1 anken duy nht B.Tn thay th ca Y l propan-2-ol
C.Phn t X c mch cacbon khng phn nhnh D.Trong phn t X c 1 lin kt bi
Cu 11: Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l
A. Na, Cu B. Ca, Zn C. Fe, Ag D. K, Al
A. Enzin l nhng cht hu cht c bn cht protein
B. Cho glyxin tc dng vi HNO2 c kh bay ra
C. Phc ng saccarozo c cng thc l (C 12H21O11)2Cu
D. Tetrapeptit thuc loi polipeptit
b l :
A. a = 0,75b. B. a = 0,8b. C. a = 0,35b. D. a = 0,5b.
l :
A. 20,8 B. 18,6 C. 22,6 D. 20,6
Cu 18: Thy phn 44 gam hn hp T gm 2 este cng cng thc phn t C 4H8O2 bng dung dch
KOH d. Chng ct dung dch sau phn ng thu c hn hp ancol Y v cht rn khan Z. un nng
Y vi H2SO4 c 1400C, thu c 14,3 gam hn hp cc ete. Bit cc phn ng xy ra hon ton.
Khi lng mui trong Z l
A. 27,25%. B. 62,40%. C. 72,70%. D. 37,50%.
Cu 20: Cht X c cng thc phn t C 3H4O2, tc dng vi dung dch NaOH thu c CHO 2Na. Cng
thc cu to ca X l
A. HCOO-C2H5. B. CH3-COOH. C. CH3-COO-CH3. D. HCOO-C2H3.
Cu 21: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l
A. HCOOCH3, C2H5OH, HCOOH, CH3COOH. B.CH3COOH, HCOOH, C2H5OH, HCOOCH3.
C. CH3COOH, C2H5OH, HCOOH, HCOOCH3. D.HCOOH, CH3COOH, C2H5OH, HCOOCH3.
Cu 23: Cho cc cht sau: HCl, AgNO3, Cl2, KMnO4/H2SO4 long, Cu. S cht tc dng c vi dung
dch Fe(NO3)2 l
A. 3. B. 2. C. 5. D. 4.
trong X l

A. 50,51%. B. 25,25%. C. 43,26%. D. 37,42%.
Cu 25: X, Y l hai hp cht hu c n chc phn t ch cha C, H, O. Khi t chy X, Y vi s mol
bng nhau hoc khi lng bng nhau u thu c vi t l mol tng ng 2 : 3 v vi t l mol tng
ng 1 : 2. S cp cht X, Y tha mn l
A. 4. B. 6. C. 5. D. 3.
Cu 26: Polime X dai, bn vi nhit v gi nhit tt nn dt vi, may qun o m , X l
A. Poliacrilonitrin B. Poli (vinylclorua) C. Polibutaien D. Polietilen
Cu 27: C 5 hn hp, mi hn hp gm 2 cht rn c s mol bng nhau: Na2O v Al2O3; Cu v
Fe2(SO4)3; KHSO4 v KHCO3; BaCl2 v CuSO4; Fe(NO3)2 v AgNO3. S hn hp c th tan hon ton
trong nc (d) ch to ra cc cht tan tt trong nc l
A. 5. B. 3. C. 4. D. 2
Cu 28: Cho m gam bt st vo dung dch X cha AgNO3 v Cu(NO3)2 n khi cc phn ng kt thc
thu c cht rn Y v dung dch Z. Cho dung dch Z tc dng ht vi dung dch NaOH d, thu c a
gam kt ta T gm hai hidroxit kim loi. Nung T n khi lng khng i thu c b gam cht rn.
Biu thc lin h gia m, a, b c th l
A. m = 8,225b 7a. B. m = 8,575b 7a. C. m = 8,4 3a. D. m = 9b 6,5a.
(1) Nung hn hp Fe v KNO3 trong kh tr. (2) Cho lung kh H2 i qua bt CuO nung nng.
(3) t dy Mg trong bnh kn cha y SO2. (4) Nhng dy Ag vo dung dch HNO3
S th nghim xy ra phn ng oxi ha kim loi:
A. 1. B. 4. C. 2. D. 3.
Cu 30: Hn hp X gm a mol Al v b mol Na. Hn hp Y gm b mol Al v a mol Na. Thc hin 2 th
nghim sau. Th nghim 1: Ha tan hn hp X vo nc d thu c 5,376 lt kh H2, dung dch X1 v m
gam cht rn khng tan. Th nghim 2: Ha tan hn hp Y vo nc d thu c dung dch Y1 trong
khi lng NaOH l 1,2 gam. Bit th tch kh o ktc. Tng khi lng Al trong hn hp X v Y l
Cu 31: Chia dung dch hn hp X gm Al2(SO4)3 v Fe2(SO4)3 thnh hai phn bng nhau. Phn mt ha
tan va ng 2,56 gam bt Cu. Phn hai tc dng vi 200 ml dung dch Ba(OH)2 1M, thu c 50,5 gam
kt ta. Cc phn ng xy ra hon ton. T l mol gia Al2(SO4)3 v Fe2(SO4)3 trong dung dch hn hp
X l
A. 1 : 1. B. 1 : 2. C. 1 : 3. D. 1 : 4.
Cu 32: Nhit phn mui amoni icromat: (NH4)2Cr2O7 thu c sn phm l
A. Cr2O3, N2, H2O B. Cr2O3, NH3, H2O C. CrO3, N2, H2O D. CrO3, NH3, H2O
Cu 33: un nng triglyxerit X vi dung dch NaOH va thu c dung dch Y cha 2 mui natri ca
axit stearic v oleic. em c cn dung dch Y thu c 54,84 gam mui. Bit X lm mt mu va
dung dch cha 0,12 mol Br2. Phn 2. Khi lng phn t ca X l
A. 886 B. 888 C. 884 D. 890
Cu 34: Aminoaxit X (CnH2n+1O2N), trong phn trm khi lng cacbon chim 51,28%. Gi tr ca n
l
A. 2 B. 3 C. 5 D. 4
Cu 35: Cht no sau y tc dng vi tripanmitin
A. H2. B. Dung dch NaOH. C. Dung dch Br2. D. Cu(OH)2.
Cu 36: Cho 5,6 gam Fe vo 200 ml dung dch Cu(NO3)2 0,5M v HCl 1,2 M thu c kh NO v m
gam kt ta. Xc nh m. Bit rng NO l sn phm kh duy nht ca NO3- v khng c kh H2 bay ra
A. 0,64 B. 2,4 C. 0,32 D. 1,6
Cu 37: phn bit cc dung dch glucoz, saccaroz v h tinh bt c th dng dy cht no sau
y lm thuc th ?

Cu 38: Cho 35 gam hn hp cc amin gm anilin, metylamin, imetylamin, imetylmetylamin tc
dng va vi 300ml dung dch HCl 1M. Khi lng mui khan thu c sau phn ng l:
Cu 39: Nhng phn ng ha hc ln lt chng minh rng phn t glucoz c nhm chc CHO
v c nhiu nhm OH lin k nhau l:
A. Phn ng trng gng v phn ng ln men ru.
B. Phn ng trng gng v phn ng vi Cu(OH) 2 nhit phng cho dung dch mu xanh
lam.
C. Phn ng to phc vi Cu(OH) 2 v phn ng ln men ru.
D. Phn ng ln men ru v phn ng thy phn.
Cu 40: Ly 0,3 mol hn hp X gm H2NC3H5(COOH)2 v H2NCH2COOH cho vo 400 ml dung
dch HCl 1M th thu c dung dch Y. Y tc dng va vi 800 ml dung dch NaOH 1M thu c
dung dch Z. Lm bay hi Z thu c m gam cht rn khan. Gi tr ca m l:
A. 61,9 B. 28,8 C. 52,2 D. 55,2
----------HT----------

PHN TCH HNG DN GII
THI TH THPT TRIU SN 1 - LN 1
Cu 1: Chn A.
0
C2H 5COOC2H 5 NaOH
t
C2H 5COONa C2H 5OH
etylpropylat Natripropylat etanol
Cu 2: Chn C.
Khi cho dung dch axit nitric c vo dung dch lng trng trng thy c kt ta mu vng xut hin.
Nhm R-C6H4-OH ca mt s amino axit trong protien phn ng vi HNO3 cho hp cht mi mang
nhm NO2 c mu vng, ng thi protein b ng t bi HNO3 to thnh kt ta.
Cu 3: Chn B.
Tnh oxi ha gim dn theo dy : Cu2+ > Zn2+ > Ca2+ > Na+
Cu 4: Chn B.
A. ng, Theo chiu tng dn in tch ht nhn,nhit nng chy ca kim loi kim gim dn
B. Sai, Mg tc dng vi nc nhit cao, Be khng tc dng vi nc mi iu kin nhit .
C. ng, Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh
D. ng, Thc t, cc son ni lm bng nhm c 1 lp oxit Al 2O3 bn ngn cn khng cho Al tip
xc vi H2O. iu ny cng xy ra tng t vi Cr v Zn.
Cu 5: Chn A.
NH2CH2COOC2H5 (X) + NaOH H2N-CH2-COONa (X1) + C2H5OH
H2N-CH2-COONa (X1) + HCl ClH3N-CH2-COOH (X2) + NaCl
ClH3N-CH2-COOH (X2) + CH3OH ClH3N-CH2-COOCH3 (X3) + H2O
ClH3N-CH2-COOCH3 (X3) + 2KOH H2N-CH2-COOK + KCl + CH3OH + H2O
Cu 6: Chn C.
Ag,Cu :hn h p rn Y
Zn,Fe AgNO3,Cu(NO3 )2 Zn2 ,Fe2 ,Cu2 ,NO3 NaOH
Fe(OH) 2 ,Cu(OH) 2 Na2ZnO2 ,NaNO3
hn h p X dung dch hn h p dung dch Z hn h p kt ta dung dch sn phm
- Vy dung dch Z chc Zn(NO3)2, Fe(NO3)2 v Cu(NO3)2
Cu 7: Chn C.
Oxit baz Oxit baz Oxit lng tnh Oxit axit
Cu 8: Chn C.
Ti catot Ti anot
H2 O + 2e 2OH- + H2 H2O 4H+ + O2 + 4e

Cu 9: Chn A.
H2N-CH2-COOH + NaOH H2N-CH2-COONa + H2O
H2N-CH2-COOH + HCl ClH3N-CH2-COOH

H2N-CH2-COOH + C2H5OH H2N-CH2-COOC2H5 + H2O
H
05 C 0
H2N-CH2-COOH + HONO HO -CH2-COOH + N2 + H2O
Cu 11: Chn D.
Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l nhng kim
loi hot ng mnh nh kim loi kim, kim th v nhm.
Cu 12: Chn D.
A. ng, bn cht ca enzim l nhng cht hu cht c bn cht protein
B. ng, Cho glyxin tc dng vi HNO2 c kh bay ra
05 C 0
C. ng, Phc ng saccarozo c cng thc l (C12H21O11)2Cu
2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + 2H2O
D. Sai, peptit c chia thnh hai loi :
* Polipeptit gm cc peptit c t 11 n 50 gc aminoaxit.
Cu 13: Chn A.
Cu 14: Chn B.
BT:e

Cu 15: Chn A.
nHCl
2
nCO2 (1) V 1 ba 1
nCO2 (2) 2V 2 0,5b 2
Cu 16: Chn C.
800.0,05
160
Cu 17: Chn A.
0
t
GlyNa AlaNa H 2O
Cu 18: Chn A.
- un nng hn hp Y vi H2SO4 th : nH2O 0,5nT 0,25mol
BTKL
mY mete 18nH2O 18,8(g)
- T tc dng vi NaOH th
BTKL
mZ mT 40nNaOH mY 53,2(g) (v i nNaOH nT 0,5mol)
Cu 19: Chn D
12 12
22,32 2.0,8 16(4nX nY )
12
- Xt hn hp M ta c :
BT:C
anX bnY nCO2 0,12a 0,14b 0,9 a 4 v b=3
0,14.60
%mC3H7OH(Y ) .100 37,63
22,32
Cu 20: Chn D.
0
HCOOCH CH 2 (C3H 4O2 ) NaOH
t
HCOONa CH 3CHO
Cu 21: Chn A.
Cu 22: Chn C.
Cu 23: Chn D.
C 4 cht tc dng c vi Fe(NO3)2 l HCl, AgNO3, Cl2 v KMnO4/H2SO4 long. PT phn ng :
3Fe2 4H NO3
3Fe3 NO 2H2O

Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag.
6Fe(NO3)2 + 3Cl2 4Fe(NO3)3 + 2FeCl3
10Fe(NO3)2 + 2KMnO4 + H2SO4 Fe(NO3)3 + Fe2(SO4)3 + K2SO4 + 2MnSO4 + H2O
Cu 24: Chn A.
a 2b 0,4 a 0,2

97a 191b 38,5 b 0,1
75nGly
%mGly .100 50,51
75nGly 147nGlu
Cu 25: Chn B.
- Khi t chy X, Y c cng s mol, khi lng MX = MY.
n CO2 (X) : n CO2 (Y) 2 : 3 n C(X) 2 n (X) 2 X : C 2 H 4O 2
- Ta c: v
n H 2 O(X) : n H 2 O(Y) 1: 2 n C(Y) 3 n H(Y) 4 Y : C 3H 8O
+ C 2 ng phn ca X C2H4O2 l: CH3COOH v HCOOCH3
+ C 3 S ng phn ca Y C3H8O l: CH3CH2CH2OH; CH3CH(OH)CH3 v CH3OC2H5
Vy s cp (X, Y) tha l: 3.2 = 6
Cu 26: Chn A.
Cu 27: Chn D.
Hn hp Na2O v Al2O3:
Na2O + H2O 2NaOH 2NaOH + Al2O3 2NaAlO2 + H2O
1 mol 2 mol 2 mol 1 mol
- Dung dch sau phn ng cha NaAlO2 l cht tan tt trong nc.
Hn hp Cu v Fe2(SO4)3: 2Cu + Fe2(SO4)3 2CuSO4 + FeSO4
1 mol 0,5 mol
- Dung dch sau phn ng cha CuSO4; FeSO4 v Fe2(SO4)3 d l cc cht tan tt trong nc.
Hn hp KHSO4 v KHCO3: KHSO4 + KHCO3 K2SO4 + CO2 + H2O
1 mol 1 mol
- Sau phn ng thu c K2SO4 tan tt trong nc nhng kh CO2 t tan trong H2O, do vy hn hp trn
khng hon ton tan trong nc.
Hn hp BaCl2 v CuSO4: BaCl2 + CuSO4 BaSO4 + CuCl2
1 mol 1 mol
- Sau phn ng thu c BaSO4 kt ta khng tan trong nc.
Hn hp Fe(NO3)2 v AgNO3: Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag
1 mol 1 mol
- Sau phn ng thu c Ag kt ta khng tan trong nc.
Vy c 2 hn hp c th tan tt trong nc d.
Cu 28: Chn B.
- Hng t duy 1:
Fe + 2AgNO3
Fe(NO3)2 + 2Ag ; Fe + Cu(NO3)2
Fe(NO3)2 + Cu
mol: x 2x y y

(Y) Ag : 2x mol, Cu : y mol
(x y) mol 2x mol t mol
x y mol t y mol x mol y mol 0,5x mol y mol
Fe AgNO3 ,Cu(NO3)2 2 2 t0
,NO3
NaOH
Fe , Cu Fe(OH)3 ,Cu(OH) 2 Fe2O3 ,CuO
m (g)X dung dch X
dung dch Z a(g) b(g)

Theo m gam
56(x y) m (1) m
xy
Theo a gam 56
+ Ta c h sau: 90(x + y) 98(t y) a (2)
(1), (3)

Theo b gam t y b m
80(x + y) 80(t y) b (3)

80 56
+ Thay (x + y) v (t y) vo (2) ta c biu thc: m 8,575b 7a
- Hng t duy 2:
m m 45
BT: Fe
n Fe n Fe(OH) 2 mol n Fe 2O3 mol m Fe(OH) 2 m gam
56 112 28
10 49b 70m
M m Fe2O3 m CuO b m CuO b m gam BT: Cu
m Cu(OH) 2 gam
7 40
45m 49b 70m
- Ta c: m Fe(OH) 2 m Cu(OH) 2 a a m 8,575b 7a
28 40
Cu 29: Chn D.
- Cc phn ng xy ra:
to
(1) Nng nng KNO3: 2KNO3 2KNO2 O2 sau Fe tc dng vi O 2:
to
3Fe 2O2 Fe3O4
o
t
(2) H 2 CuO Cu H 2O : phn ng kh oxit kim loi.
(3) 2Mg SO2
2MgO S
(4) 3Ag 4HNO3
3AgNO3 NO 2H 2O
Vy c 3 phn ng oxi ha kim loi l (1), (3) v (4).
Cu 30: Chn C.
amol bmol
H 2O n H2
- Th nghim 1: Al , Na X 1 H 2 Al d . Ta c: n Na b 0,12 mol
2
hn h p X 0,24 mol m gam
0,12mol amol 0,03mol 0,12mol
H 2O BT: Na
- Th nghim 2: Al , Na NaOH ,NaAlO2 . Khi :
a 0,15 mol
dung dch Y dung dchY2
m Al 27.(a b) 7, 29 gam
Cu 31: Chn B.
- Gi x l s mol ca Al2(SO4)3 n Al3 2x mol
- Phn 1: ha tan va ng vi 0,04 mol Cu n Cu n Fe2 (SO4 )3 0,04 mol
- Phn 2: tc dng vi 0,2 mol dung dch Ba(OH)2 thu c kt ta gm:
Fe(OH)3: Nhn thy 3n Fe3 n OH n Fe(OH)3 0, 08 mol m Fe(OH)3 8,56 (g)
BaSO4: Nu n BaSO 4 n Ba 2 0, 2 mol m BaSO 4 m Fe(OH)3 50,5 gam
nSO24 3(n Al2 (SO4 )3 n Fe2 (SO4 )3 ) 3x 0,12 mBaSO4 699x 27,96 (g)
Al(OH)3: Xt trng hp to kt ta ca Al(OH)3 (vi n OH cn li = 0,16 mol)

- Trng hp 1: Al(OH)3 khng b ha tan.
+ Khi 3n Al3 6x n OH 0,16 x 0, 0267 m nSO24 3x 0,12 0, 2 x 0,0267 (v l)
- Trng hp 2: Al(OH)3 b ha tan mt phn
+ Khi : n Al(OH)3 4n Al3 n OH 8x 0,16 m Al(OH)3 624x 12, 48 (g)
n Al2 (SO4 )3 1
m m Fe(OH)3 m BaSO4 m Al(OH)3 50,85 x 0,02 mol . Vy
n Fe 2 (SO4 )3 2
Cu 32: Chn A.
to
- Nhit phn mui amoni icromat: (NH4)2Cr2O7 Cr2O3 + N2 + 4H2O
Cu 33: Chn A.
- Gi s triglyxerit X c to ra t 1 gc axit stearic v 2 gc axit oleic. Trong phn t ca X lc ny
cha 2 lin kt C=C.
n Br2
- Khi cho X tc dng vi dung dch Br2 th: n X 0, 06 mol
2
NaOH n C17H33COONa 2n X 0,12 mol
- Khi cho X mmui = 54,84 gam (tha yu cu bi ton)
n C17H35COONa n X 0, 06 mol
- Nu nh trng hp trn khng tha thi ta suy ra trng hp cn li l X c to ra t 2 gc axit
stearic v 1 gc axit oleic. Khi MX = 888
Vy M X 886 .
Cu 34: Chn C.
12n
- Ta c: %C 0,5128 n 5
14n 47
Cu 35: Chn B.
- Tripanmitin c cng thc (C15H31COO)3C3H5 tham gia phn ng thy phn trong mi trng axit v
kim.
(C15H31COO)3C3H5 + 3NaOH
3C15H31COONa + C3H5(OH)3
Cu 36: Chn A.
S oxi ha S kh
Fe Fe + 2e
2+
3e + 4H + NO3 NO + 2H2O ;
+ -
Cu2+ + 2e Cu
0,1 0,2 0,18 0,24 0,01 0,1 0,2
(v sau phn ng c cht rn nn Fe
chuyn ln Fe2+).
2n Fe 3n NO
- Nhn thy: ne nhn > ne cho nCu p = = 0,01 mol mrn = mCu p = 0, 64 (g)
2
Cu 37: Chn B.
Thuc th Glucoz Saccaroz H tnh bt
AgNO3/NH3 Kt ta trng bc Khng hin tng Khng hin tng
Cu 38: Chn B.
BTKL
mmui khan mamin 36,5nHCl 45,95(g)
Cu 39: Chn B.
Tnh cht ca ancol a chc (poliancol hay poliol):
- Dung dch glucoz ha tan Cu(OH)2 cho dung dch phc ng glucoz c mu xanh lam
2C6H12O6 + Cu(OH)2
(C6H11O6)2Cu + 2H2O
Tnh cht ca anehit:
- Vi dung dch AgNO3 trong NH3, un nng (thuc th Tollens) cho phn ng trng bc.

to
Cu 40: Chn A.
- Xt ton b qu trnh phn ng ta c
2nA nB nNaOH nHCl 2nA nB 0,4 nB 0,2mol
- Khi cho dung dch Y tc dng vi NaOH th nH2O nNaOH 0,8mol
BTKL
mrn khan 147nA 75nB 36,5nHCl 40nNaOH 18nH2O 61,9(g)

THPT YN PHONG 2 Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Polime ca loi vt liu nao sau y c cha nguyn t nit ?

A. Cao su buna. B. T nilon-6,6.
C. T visco. D. Nha poli (vinyl clorua).
HCl NaOH
Cu 2: Cho chui phn ng sau: X Y X . Cht no sau y ph hp:
A. H2N-CH2-COOH. B. C6H5NH2. C. Ala-Gly. D. HCOONH4.
Cu 3: S ng phn este mch h ng vi cng thc phn t C3H6O2 l:
A. 3. B. 4. C. 1. D. 2.
Cu 4: Cht c phn ng vi dung dch Br2 l:
A. Phenyl clorua. B. Alanin. C. Metyl amin. D. Triolein.
Cu 5: Trng hp no sau y to hp cht Fe(II) ?
A. Nhng thanh st vo dung dch H2SO4 long. B. t dy st trong bnh ng kh Cl2.
C. Nhng thanh st vo dung dch AgNO3 d. D. Cho bt Fe vo dung dch HNO3 d.
Cu 6: Nhng mt l st (d) vo dung dch cha mt trong cc cht sau: FeCl3, AlCl3, CuSO4,
Pb(NO3)2, H2SO4 c nng. Sau phn ng ly l st ra, c bao nhiu trng hp to mui st (II) ?
A. 2. B. 3. C. 4. D. 5.
Cu 7: Dy kim loi tan hon ton trong H2O iu kin thng l:
A. Fe, Na, K. B. Ca, Ba, K. C. Ca, Mg, Na. D. Al, Ba, K.
Cu 8: Glyxin l tn gi ca cht no sau y?
A. C6H5NH2. B. CH3NH2.
C. H2N-CH2-COOH. D. CH3-CH(NH2)-COOH.
Cu 9: Cho 2,655 gam amin no, n chc, mch h X tc dng vi lng d dung dich HCl. Sau khi
phn ng xy ra hon ton, thu c 4,8085 gam mui. Cng thc phn t ca X l:
A. C3H9N. B. C3H7N. C. CH5N. D. C2H7N.
Cu 10: Phn ng no sau y l phn ng nhit nhm ?
to
A. 3Al + 3CuSO4
Al2(SO4)3 + 3Cu. B. 8Al + 3Fe3O4 4Al2O3 + 9Fe.
pnc
C. 2Al2O3 4Al + 3O2. D. 2Al + 3H2SO4
Al2(SO4)3 + 3H2.
Cu 11: Gluxit nao sau y c goi la ng ma?
A. Saccaroz. B. Tinh bt . C. Glucoz. D. Fructoz.
Cu 12: Cc kim loa Fe, Cr, Cu cng tan trong dung dich no sau y?

A. Dung dich HCl. B. Dung dich HNO3 c, ngu .
C. Dung dich HNO3 long. D. Dung dich H2SO4 c, ngu .
Cu 13: Kim loai X tc dung vi H2SO4 long cho kh H2. Mt khc oxit ca X bi kh H2 kh thnh kim
loai nhit cao. X la kim loai nao ?
A. Fe. B. Al. C. Mg. D. Cu.
Cu 14: Cho 10 gam hn hp gm Fe v Cu tc dng vi dung dch H2SO4 long d. Sau phn ng thu
c 2,24 lt H2 lt kh hidro ( kc) dung dic h X v m gam kim loa khng tan. Gi tri c a m l
0
Cu 15: Cho s sau: X Cu(OH)2 /OH
dung dch mu xanh lam t
kt ta g ch . X la dung
dich no sau y:
A. Protein. B. Triolein. C. Glucoz. D. Vinyl fomat.
Cu 16: Cho 33,9 gam hn hp bt Zn v Mg (t l 1 : 2) tan ht trong dung dch hn hp gm NaNO3
v NaHSO4 thu c dung dch A ch cha m gam hn hp cc mui trung ha v 4,48 lt (kc) hn hp
kh B gm N2O v H2. Hn hp kh B c t khi so vi He bng 8,375. Gi tr gn nht ca m l :
A. 240. B. 300. C. 312. D. 308.
Cu 17: Hn hp X g m valin (c cng thc C4H8NH2COOH)) v ipeptit Glyxylalanin. Cho m gam X
vo 100ml dung dich H2SO4 0,5M (long), thu c dung dich Y. Cho ton b Y phn ng va vi
100ml dung dch NaOH 1M v KOH 1,75M un nng thu c dung dch cha 30,725 gam mui.
Phn trm khi lng ca Valin trong X l :
A. 65,179%. B. 54,588%. C. 45,412%. D. 34,821%.
(1) Tt c cc ion kim loi ch b kh.
(2) Hp cht cacbohirat v hp cht amino axit u cha thnh phn nguyn t ging nhau.
(3) Dung dch mui mononatri ca axit glutamic lm qu tm chuyn sang mu xanh.
(4) Cho kim loi Ag vo dung dch FeCl2 th thu c kt ta AgCl.
(5) Tnh cht vt l chung ca kim loi do cc electron t do gy ra.
(6) Phn ng thy phn este v protein trong mi trng kim u l phn ng mt chiu.
S nhn nh ng l
A. 3 B. 2 C. 4 D. 5
Cu 19: Chn cp cht khng xy ra phn ng?
A. dung dch AgNO3 v dung dch Fe(NO3)2.
B. dung dch Fe(NO3)2 v dung dch KHSO4.
C. dung dch H2NCH2COONa v dung dch KOH.
D. dung dch C6H5NH3Cl v dung dch NaOH.
Cu 20: Cho cc dung dch FeCl3, HCl, HNO3 long, AgNO3, ZnCl2 v dung dch cha (KNO3, H2SO4
long). S dung dch tc dng c vi kim loi Cu nhit thng l
A. 2 B. 5 C. 3 D. 4
Cu 21: Dy cc polime khi t chy hon ton u thu c kh N2
A. t olon, t tm, t capron, cao su buna-N.
B. t lapsan, t enng, t nilon-6, xenluloz.
C. protein, nilon-6,6, poli(metyl metacrylat), PVC.
D. amilopectin, cao su buna-S, t olon, t visco.
Cu 22: Ha tan hon ton hn hp H gm Mg (5a mol) v Fe3O4 (a mol) trong dung dch cha
KNO3 v 0,725 mol HCl, c cn dung dch sau phn ng th thu c lng mui khan nng hn khi
lng hn hp H l 26,23g. Bit kt thc phn ng thu c 0,08 mol hn kh Z cha H2 v NO, t khi
ca Z so vi H2 bng 11,5. % khi lng st c trong mui khan c gi tr gn nht vi
A. 17% B. 18% C. 26% D. 6%
Cu 23: Cho cc s phn ng sau (theo ng t l mol):
C7H18O2N2 (X) + NaOH X1 + X2 + H2O X1 + 2HCl X3 + NaCl
X4 + HCl X3 X4 t nilon-6 + H2O
Pht biu no sau y ng
A. X2 lm qu tm ha hng. B. Cc cht X, X4 u c tnh lng tnh.
C. Phn t khi ca X ln hn so vi X3. D. Nhit nng chy ca X1 nh hn X4.
Cu 24: Trn 2,43 gam Al vi 9,28 gam Fe3O4 ri nung nng cho phn ng xy ra mt thi gian, lm
lnh c hn hp X gm Al, Fe, Al2O3, FeO v Fe3O4. Cho ton b X phn ng vi dung dch HCl d
thu c 2,352 lt H2 (ktc) v dung dch Y. C cn Y c a gam mui khan. Xc nh gi tr ca a l
A. 27,965 B. 16,605 C. 18,325 D. 28,326
Cu 26: Hn hp E gm 3 chui peptit X, Y, Z u mch h (c to nn t Gly v Lys). Chia hn hp
lm hai phn khng bng nhau. Phn 1: c khi lng 14,88 gam c em thy phn hon ton trong
dung dch NaOH 1 M th dng ht 180 ml, sau khi phn ng thu c hn hp F cha a gam mui Gly
v b gam mui Lys. Mt khc, t chy hon ton phn cn li th thu c t l th tch gia CO 2 v hi
nc thu c l 1 : 1. T l a : b gn nht vi gi tr :
A. 1,57 B. 1,67 C. 1,40 D. 2,71
Cu 27: Cho hn hp X gm FexOy, Fe, MgO, Mg. Cho m gam hn hp X trn tc dng vi dung dch
HNO3 d thu c 6,72 lt hn hp kh N2O v NO (dktc) c t khi so vi H2 l 15,933 v dung dch Y.
C cn dung dch Y thu c 129,4 gam mui khan. Cho m gam hn hp X tc dng vi dung dch
H2SO4 c nng d thu c 15,68 lt kh SO2 (ktc, sn phm kh duy nht) v dung dch Z. C cn
dung dch Z thu c 104 gam mui khan. Gi tr gn nht ca m l
A. 22,0 B. 28,5 C. 27,5 D. 29,0
Cu 28: Phn bit cc cht CaCl2, HCl, Ca(OH)2 c th dng dung dch
A. NaOH. B. NaHCO3. C. Na2CO3. D. NaNO3.
Cu 29: Nhn xt no di y l ng
A. Tripeptit ha tan Cu(OH)2 (phn ng mu biure) to dung dch xanh lam.
B. Trong phn t protein lun c nguyn t nit.
C. Tinh bt v xenluloz l ng phn ca nhau.
D. Este l nhng cht hu c d tan trong nc.
Cu 30: Trong 4 kim loi sau: Fe, Na, Al, Cr. Kim loi n khi tip xc vi axit v kim loi kh mm, d
ko si, d dt mng trong 4 kim loi theo th t l
A. Na v Fe. B. Cr v Al. C. Na v Al. D. Cr v Fe.
Cu 31: X phng ha hn hp gm CH3COOCH3 v CH3COOC2H5 thu c sn phm gm
A. 2 mui v 2 ancol B. 2 mui v 1 ancol C. 1 mui v 1 ancol D. 1 mui v 2 ancol
Cu 33: Nguyn t ha hc no sau y thuc nhm kim loi kim th
A. Natri. B. Bari. C. Nhm. D. Kali.
Cu 34: Nhn xt no sau y sai
A. Glucoz c dng lm thuc tng lc cho ngi gi, tr em, ngi m.
B. G c dng ch bin thnh giy.
C. Xenluloz c phn ng mu vi iot.
D. Tinh bt l mt trong s ngun cung cp nng lng cho c th.
Cu 35: X, Y, Z, T l mt trong cc cht sau: glucoz, anilin (C6H5NH2), fructoz v phenol (C6H5OH).
Tin hnh cc th nghim nhn bit chng v ta c kt qu nh sau:
Thuc th X T Z Y
(+): phn ng
Nc Br2 Kt ta Nht mu Kt ta (-)
(-): khng phn ng
dd AgNO3/NH3, to (-) Kt ta (-) Kt ta

dd NaOH (-) (-) (+) (-)
Cc cht X, Y, Z, T ln lt l
A. glucoz, anilin, phenol, fructoz B. anilin, fructoz, phenol, glucoz.
C. phenol, fructoz, anilin, glucoz D. fructoz, phenol, glucoz, anilin
Cu 36: Cho 13,5 gam hn hp gm 3 amin no, n chc, mch h tc dng va vi 300 ml dung
dch HCl x M, thu c dung dch cha 24,45 gam hn hp mui. Gi tr ca x l
A. 0,5. B. 1,4. C. 2,0. D. 1,0.
A. 4. B. 6. C. 5. D. 3.
A. 5. B. 3. C. 4. D. 2
Cu 36: Chn D.
- Phng trnh: RNH2 HCl RNH3Cl
m m RNH 2

BTKL
n HCl RNH3Cl 0,3mol C M(HCl) 1 M
36,5
Cu 37: Chn B.
- Ta c: v
Vy s cp (X, Y) tha l: 3.2 = 6
Cu 38: Chn A.
Cu 39: Chn D.
Hn hp Na2O v Al2O3:
1 mol 0,5 mol
Hn hp KHSO4 v KHCO3: KHSO4 + KHCO3
K2SO4 + CO2 + H2O

1 mol 1 mol
1 mol 1 mol
1 mol 1 mol
Cu 40: Chn B.
- Hng t duy 1:
Fe + 2AgNO3
Fe(NO3)2 + Cu
mol: x 2x y y
Fe AgNO3 ,Cu(NO3)2 t0
Fe2 , Cu2 ,NO3 Fe(OH)3 ,Cu(OH) 2 Fe2O3 ,CuO
NaOH
m (g)X dung dch X

Theo m gam
56(x y) m (1) m
xy
Theo a gam 56
+ Ta c h sau: 90(x + y) 98(t y) a (2)
(1), (3)

Theo b gam t y b m
80(x + y) 80(t y) b (3)

80 56
- Hng t duy 2:
m m 45
BT: Fe
56 112 28
10 49b 70m
m Cu(OH) 2 gam
7 40
45m 49b 70m
28 40
----------HT----------

PHN TCH HNG DN GII
THI TH THPT YN PHONG 2 BC NINH LN 1
Cu 1: Chn B.
Cu 2: Chn B.
HCl NaOH
C6H5NH2 (X) C6H5NH3Cl(Y) C6H5NH2 (X)
Cu 3: Chn D.
C 2 ng phn este mch h ng vi CTPT l C3H6O2 l HCOOC2H5, CH3COOCH3.
Cu 4: Chn D.
Cu 5: Chn A.
B. Fe + 3AgNO3(d) Fe(NO3)3 + 3Ag
C. Fe + Cl2 FeCl3
D. Fe + 4HNO3(d) Fe(NO3)3 + NO + 2H2O
Cu 6: Chn C.
C 4 trng hp to mui st (II) l : FeCl3, CuSO4, Pb(NO3)2 v H2SO4(c, nng)
Cu 7: Chn B.
Cu 8: Chn C.
Cu 9: Chn D.
m mamin
BTKL
nHCl namin mui 0,059mol M amin 45(C2H 7N)
36,5
Cu 10: Chn B.
Cu 11: Chn A.
A. Saccaroz. B. Tinh bt . C. Glucoz. D. Fructoz.
ng ma ng nho ng mt ong
Cu 12: Chn C.
Lu : Cr, Fe v Al b th ng ha bi HNO3, H2SO4 c ngui.
Cu 13: Chn A.
Cu 14: Chn C.
BT:e
nFe nH2 0,1 mCu 10 56nFe 4,4(g)
Cu 15: Chn C.
Cu 16: Chn D
0,3mol 0,6mol 0,3mol 0,6mol 0,15mol 0,05mol
2 2 2
Zn , Mg NaNO3,NaHSO4
Zn , Mg ,Na ,NH 4 ,SO4 N 2O , H 2 H 2O
hn h p kim lo i dung dch hn h p dung dch A hn h p B
2nZn2 2nMg2 8nN 2O 2nH 2
BT:e
nNH 4 0,0625mol
BT:N
nNaNO3 2nN 2O nNH 4 0,3625mol
8
nNaHSO4 4nNH 4 2nH 2
nNaHSO4 10nNH 4 10nN 2O 2nH 2 2,225mol
BT:H
nH 2O 0,9375mol
2
BTKL
mA mkim loi 85nNaNO3 120nNaHSO4 mB 18nH2O 308,1375(g)
Cu 17: Chn B.
amol bmol amol bmol bmol 0,1mol 0,175mol 0,05mol
Val ,Gly ,Ala , Na , K ,SO42

Val ,GlyAla H 2SO4 dung dch Y NaOH,KOH
hn h p X 0,05mol 30,725(g) mui

116nVal 74nGly 88nAla mmui 39nK 23nNa 96nSO42 116a 74b 88b 16,8 a 0,075
BTDT
n n n n n 2n a b b 0,175 b 0,05
Val Gly Ala K Na SO4 2
%mVal 54,58
Cu 18: Chn A.
(1) Sai, Fe2+, Cr2+ b oxi ha bi cc cht oxi ha mnh nh KMnO4, O2.
(2) Sai, hp cht amino axit cha C, H, O v N cn hp cht cacbohidrat khng cha N.
(3) ng, HOOC-CH2-CH2-CH(NH2)-COONa (mono natri glutamate) lm qu tm ha xanh.
(4) Sai, khi cho Ag tc dng vi dung dch FeCl2 khng c phn ng xy ra.
(5) ng, cc tnh cht nh tnh dn in, dn nhit, do, nh kim u do electron t do gy ra.
(6) ng, phn ng thy phn este v protein trong mi trng kim u l phn ng mt chiu.
Vy c 3 nhn nh ng l (3), (5), (6).
Cu 19: Chn C.
A. AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag.
B. 3Fe2+ + NO3- + 4H+ 3Fe3+ + NO + 2H2O
D. C6H5NH3Cl + NaOH C6H5NH2 + NaCl + H2O
Cu 20: Chn D.
C 4 cht tc dng c vi kim loi Cu iu kin thng l FeCl3, HNO3 long, AgNO3 v dung dch
cha (KNO3, H2SO4 long).
Cu + 2FeCl3 CuCl2 + 2FeCl2 Cu + HNO3(long) Cu(NO3)2 + NO + H2O
Cu + 2AgNO3 Cu(NO3)2 + 2Ag 3Cu + 2NO3 + 8H+ 3Cu2+ + 2NO + 4H2O
Cu 21: Chn A.
Cc polime khi t chy hon ton u thu c kh N2 chng t trong phn t polime c cha N.
Vy cc polime c thnh phn cha N l : t olon, t tm, t capron, cao su buna-N.
Cu 22: Chn A.
BT:N
nNH4 nKNO3 nNO (x 0,06)mol
mmui mH 39nK 18nNH4 35,5nCl 16nO(trong H) 39x 18(x 0,06) 35,5.0,725 64a
mmui mH 26,23
57x 64a 1,5725 x 0,0725mol

10nNH 4 2nO(trong H) 4nNO 2nH 2 nHCl
10(x 0,06) 8a 0,28 0,725 a 0,04mol
0,04.3.56
mH 24.5a 232a 14,08(g) mmui khan 40,31(g) %mFe .100 16,67
40,31
Cu 23: Chn B.
- Cc phn ng xy ra:
to
nH 2 N[CH 2 ]5 COOH (X 4 ) ( HN [CH 2 ]5 CO ) n nH 2O
nilon 6
H2 N[CH2 ]5 COOH (X4 ) HCl

ClH3N[CH2 ]5 COOH (X3 )
H2 N[CH2 ]5 COONa (X1) 2HCl
ClH3N[CH 2 ]5 COOH (X3 ) NaCl
H2 N [CH2 ]5 COO NH3CH3 (X) NaOH
H 2 N[CH2 ]5 COONa (X1) CH3NH2 (X2 ) H2O
A. Sai, X2 lm qu tm ha xanh.
B. ng. X v X4 u c tnh lng tnh.
C. Sai, Phn t khi ca X l 162 trong khi phn t khi ca X3 l 167,5.
D. Sai, Nhit nng chy ca X1 ln hn X4.
Cu 24: Chn A.

0,09 mol 0,04 mol 0,105 mol
to
- Qu trnh: Al ,Fe3O4 hn h p X HCl d
AlCl 3,FeCl 2 ,FeCl 3 H 2O H 2
dung dch sau p
BT: H
+ Ta c: n O (Fe3O4 ) n H 2O 0,16 mol n HCl 2(n H2 n H 2O ) 0,53 mol
- Hng t duy 1:
BTKL
a mY 36,5HCl 2n H2 18n H2O mX 36,5HCl 2n H2 18n H2O 27,965 (g)
- Hng t duy 2:
Cu 25: Chn C.
Vi
n CO 2
0, 2
BTKL
Cu 26: Chn A.
+ Cc mt xch to ra tng ng vi cc - amino axit:
- Hng t duy 1: S dng CTTQ ca peptit

+ Gi s mc xch ca Gly l x v Lys l y ta c CTTQ ca E l:
0
C2x 6y H3x 12y 2O x y1N x 2y
O2 ,t
(2x 6y)CO 2 (1,5x 6y 1)H 2O
3x 12y 2
n CO2 n H2O 2x 6y
2 x 2
+ Ta c: n E 0, 0658 mol
n NaOH n E .(x y) 14,88 y 0, 7353
(x y) 0,18

57x 128y 3
BT: Gly Lys n GlyNa xn E 0,1316 mol a

1,57
n LysNa yn E 0, 0484 mol b
- Hng t duy 2: Quy i v hn hp cc - amino axit v H2O.

+ Ta c : GlymLysn (E) H2O
H
mGly nLys
Gly(C2 H5O2 N):x mol
O2 ,t 0
BT: C
n CO2 2x 6y
E Lys (C6 H14O2 N2 ):y mol n CO2 n H2O 0,5x y z (1)
H O : z mol

BT: H
n 2,5x 7y z
2
H 2O

BTKL
75n Gly 146n Lys m E 18n H2O 75x 146y 14,88 18z

v (2)

BT: Na
n n n x y 0,18
GlyNa LysNa NaOH
a
1,57
+ T (1), (2) ta tnh c: x 0,1316 mol ; y 0, 0484 mol; z 0,1141 mol . Vy
b
- Hng t duy 2.1: Ta c th quy i hn hp E v cc axyl v H2O nh sau: C2 H3ON, C6 H12ON 2 v
H2O sau gii tng t nh trn ta cng c th tm c kt qu.
- Hng t duy 3: Tch cht
tch
+ Ta c: C2H5O2N(Gly) C2H3ON H2O v
tch
C6H12O2N2 (Lys) C2H3ON (CH2 )4 NH H2O
C2H3ON :x mol
O2 ,t 0
BT:C
nCO2 2x 4z
E H2O:y mol mnH2O nCO2 0,5x 0,5z y (1)

BT:H2
(CH ) NH :zmol
nH2O 1,5x 4,5z y
2 4
+ Ta c :
x n NaOH 0,18 mol
BTKL
71n (CH2 )4 NH 18n H2O mE 57n C2H3ON 71x 18y 4,62(2)
y 0, 0658 mol n GlyNa x z 0,1316 mol a

+ T (1), (2) ta tnh c: 1,57
z 0, 0484 mol n LysNa z 0, 0484 mol b
Cu 27: Chn D.
- Hng t duy 1:
Fe3 , Mg 2 , NH 4 , NO3 NO , N 2O (1)
HNO
3
129,4(g) dd Y 0,26 mol 0,04 mol

- Tm tt qu trnh: Fe, Mg, O
m gam X
H 2SO4
Fe3 , Mg 2 ,SO24 SO2 (2)
104(g) dd Z 0,7 mol
2nSO2 3n NO 8n N2O
BT: e cho (1) v (2)

n NH4 NO3 0, 0375mol
8
m KL m NH 4 m NO3 129, 4 (1)

BTDT cho (1) v (2)

2n SO24 n NO3 n NH4
BTKL

m KL mSO24 104
(2)
(1) (2)
62(2n SO24 n NH4 ) 96n SO24 24,725 n SO42 0,8 mol
+ Xt qu trnh (2):
BT: e BTDT
2n SO24 2n SO2 2n O n O 0,1 mol
m m KL mO 28,8 gam
m
KL m Y m 2
SO4 104 0,8.96 27, 2 gam
- Hng t duy 2:
2nSO2 3n NO 8n N2O

BT: e cho (1) v (2)
n NH4 NO3 0, 0375mol
8
+ Gi T l hn hp mui cha Fe(NO3)2 v Mg(NO3)2 suy ra: mT mY mNH4NO3 126, 4gam
+ p dng phng php tng gim khi lng + bo ton in tch cho hn hp T v Z ta c:
mT m Z 126, 4 104
2n NO nSO 2 0,8mol
3 4 2.M NO MSO 2 2.62 96
3 4
BT: S BT: H
+ Xt qu trnh (2): n H2O n H2SO4 nSO2 n SO 2 1,5 mol
4
mX mH2SO4 mZ mSO2 mH2O m 28,8gam

BTKL

Cu 28: Chn B.
Thuc th CaCl2 HCl Ca(OH)2
A. NaOH Khng hin tng
B. NaHCO3 Khng hin tng C kh CO2 thot ra C kt ta trng
C. Na2CO3 C kt ta trng C kh CO2 thot ra C kt ta trng
D. NaNO3 Khng hin tng
Cu 29: Chn B.
A. Sai, Tripeptit ha tan Cu(OH)2 (phn ng mu biure) to dung dch mu tm.
B. ng, Trong phn t protein lun c nguyn t nit.
C. Sai, Tinh bt v xenluloz khng phi l ng phn ca nhau.
D. Sai, Este l nhng cht hu c t tan trong nc v trong phn t khng c lin kt hiro.
Cu 30: Chn C.
Cu 31: Chn D.
CH3COOCH3 NaOH
CH3COONa CH3OH
- Phng trnh phn ng: 1 mui v 2 ancol
CH3COOC 2 H 5 NaOH
CH 3COONa C 2 H 5OH
Cu 32: Chn B.
- Cc kim loi kim th thuc nhm IIA gm cc nguyn t: Be, Mg, Ca, Sr, Ba, Ra.
Cu 34: Chn C.
- Xenluloz khng c phn ng vi I2 ch tinh bt mi c phn ng ny to dung dch c mu xanh tm.
Cu 35: Chn B.
T: C6H12O6 Y: C6H12O6
Thuc th X: C6H5NH2 Z: C6H5OH
(glucoz) (fructoz)
Nc Br2 Kt ta trng Nht mu Kt ta trng Khng phn ng
dd AgNO3/NH3, t o
Khng phn ng Kt ta Ag Khng phn ng Kt ta Ag
dd NaOH Khng phn ng Khng phn ng C phn ng Khng phn ng
Cu 36: Chn D.
- Phng trnh: RNH2 HCl RNH3Cl
m m RNH 2

BTKL
n HCl RNH3Cl 0,3mol C M(HCl) 1 M
36,5
Cu 37: Chn B.
- Ta c: v
Vy s cp (X, Y) tha l: 3.2 = 6
Cu 38: Chn A.
Cu 39: Chn D.
Hn hp Na2O v Al2O3:

1 mol 0,5 mol
1 mol 1 mol
1 mol 1 mol
1 mol 1 mol
Cu 40: Chn B.
- Hng t duy 1:
Fe + 2AgNO3
Fe(NO3)2 + Cu
mol: x 2x y y
,NO3
NaOH
m (g)X dung dch X

Theo m gam
56(x y) m (1) m
xy
Theo a gam 56
+ Ta c h sau: 90(x + y) 98(t y) a (2)
(1), (3)

Theo b gam t y b m
80(x + y) 80(t y) b (3)

80 56
- Hng t duy 2:
m m 45
BT: Fe
56 112 28
10 49b 70m
m Cu(OH) 2 gam
7 40
45m 49b 70m
28 40

TNH PH TH Mn: KHOA HC T NHIN HA HC
THPT VNH CHN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Este c CTPT C2H4O2 c tn gi no sau y?

A. metyl propionat. B. metyl fomat. C. metyl axetat. D. etyl fomat.
Cu 2: Kh hon ton m gam Fe2O3 cn va 3,36 lt kh CO ( ktc). Khi lng st thu c sau
phn ng l
A. 8,4. B. 5,6. C. 2,8. D. 16,8.
Cu 3: Cht no sau y khng dng lm mm nc cng tm thi?
A. Na2CO3 B. Na3PO4 C. Ca(OH)2 D. HCl
Cu 4: S amin bc ba c cng thc phn t C 5H13N l.
A. 3 B. 2 C. 5 D. 4
Cu 5: Dung dch X cha 0,06 mol H2SO4 v 0,04 mol Al2(SO4)3. Nh rt t t dung dch Ba(OH) 2
vo X th lng kt ta cc i c th thu c l bao nhiu gam?
A. 48,18 B. 32,62 C. 46,12 D. 42,92
Cu 6: X l mt l -amino axit c cng thc phn t C 3H7O2N. Cng thc cu to ca X l:
A. H2NCH(CH3)COOH B. H2NCH2CH2COOH C. H2NCH2COOCH3 D. CH2=CHCOONH4
Cu 7: Kim loi no sau y khng tc dng c vi dung dch FeCl3 ?
A. Ag B. Fe C. Cu D. Ca
Cu 8: Nhng thanh Ni ln lt vo cc dung dch: FeCl 3, CuCl2, AgNO3, HCl v FeCl2. S trng
hp xy ra n mn in ha l:
A. 3 B. 4 C. 2 D. 1
Cu 9: Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l :
Cu 11: Cho Etylamin phn ng vi CH3I (t l mol 1 :1) thu c cht ?
A. imetylamin B. N-Metyletanamin C. N-Metyletylamin D. ietylamin
Cu 12: Dy gm cc cht c xp theo chiu tnh baz tng dn t tri qua phi l
A. C6H5NH2, NH3, CH3NH2. B. CH3NH2, NH3, C6H5NH2
C. NH3, CH3NH2, C6H5NH2. D. CH3NH2, C6H5NH2, NH3.
Cu 13: Cho kh CO d i qua hn hp X gm FeO, CuO v MgO nung nng, sau khi cc phn ng
xy ra hon ton thu c cht rn Y. Thnh phn cht rn Y gm ?
A. FeO, Cu, Mg. B. Fe, Cu, MgO. C. Fe, CuO, Mg. D. FeO, CuO, Mg.
Cu 14: Cch no sau y khng iu ch c NaOH ?
A. in phn dung dch NaCl c mng ngn xp, in cc tr.
B. Cho dung dch Ca(OH)2 tc dng vi dung dch Na2CO3.
C. Cho Na2O tc dng vi nc.
D. Sc kh NH3 vo dung dch Na2CO3.
Cu 15: Qung boxit c dng sn xut kim loi no sau y ?
A. Mg. B. Na. C. Cu. D. Al.

Cu 16: Nung m gam hn hp X gm bt Al v Fe3O4 sau mt thi gian thu c cht rn Y. ho
tan ht Y cn V lt dung dch H2SO4 0,7M (long). Sau phn ng thu c dung dch Z v 0,6 mol kh.
Cho dung dch NaOH vo dung dch Z n d, thu c kt ta M. Nung M trong chn khng n
khi lng khng i thu c 44 gam cht rn T. Cho 50 gam hn hp A gm CO v CO2 qua ng s
c cht rn T nung nng. Sau khi T phn ng ht thu c hn hp kh B c khi lng gp 1,208
ln khi lng ca A. Gi tr ca (m - V) gn vi gi tr no sau y nht ?
A. 58,4 B. 61,5 C. 63,2 D. 65,7
Cu 17: Ha tan hon ton m gam hn hp X gm Mg, Fe, FeCO3 v Cu(NO3)2 bng dung dch cha
H2SO4 long v 0,045 mol NaNO3 thu c dung dch Y ch cha 62,605 gam mui trung ha (khng
c ion Fe3+) v 3,808 lt (ktc) hn hp kh Z (trong c 0,02 mol H2) c t khi so vi O2 bng 19/17.
Cho dung dch NaOH 1M vo Y n khi lng kt ta t cc i l 31,72 gam th va ht 865 ml. Gi
tr m l
A. 32,8. B. 27,2. C. 34,6. D. 28,4.
Cu 18: Hp cht no sau y cho c phn ng trng gng
A. CH3COOCH3 B. H2N-CH2-COOH C. HCOOC2H5 D. CH3COONH4
Cu 19: Hn hp X cha cc cht hu c u mch h, thun chc gm 2 ancol n chc, k tip trong
dy ng ng v 1 este hai chc. t chy hon ton 0,2 mol X cn dng 10,304 lt kh O2 (ktc), thu
c 14,96 gam CO2 v 9 gam nc. Mt khc un nng 18,48 gam X vi dung dch NaOH d, thu c
5,36 gam mt mui duy nht v hn hp Y cha 2 ancol. un nng ton b Y vi H2SO4 c 1400C
thu c m gam hn hp ete. Bit hiu sut ete ha ca 2 ancol trong Y u bng 80%. Gi tr gn nht
ca m l
A. 10 B. 4,0 C. 11 D. 9,0
(1) Sc kh H2S qua dung dch K2Cr2O7 trong mi trng axit, un nng.
(2) Cho dung dch Na3PO4 vo dung dch AgNO3.
(3) Cho phn chua vo dung dch sa
(4) Cho vi sng vo dung dch Cu(NO3)2
(5) Cho AgNO3 d vo dung dch hn hp Fe(NO3)3 v HCl
Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l
A. 5. B. 2. C. 4. D. 3.
Cu 21: Nh t t n d dung dch Ba(OH) 2 ln lt vo cc dung dch sau: NaHCO 3, AlCl3,
NaHSO4, (NH4)2CO3, FeCl3, Na2SO4 v KNO3. S trng hp thu c kt ta l:
A. 4 B. 6 C. 7 D. 5
Cu 22: X l -amino axit trong phn t cha 1 nhm NH2 v 1 nhm -COOH. Ly 0,01 mol X tc
dng va vi dung dch HCl 0,1M thu c dung dch Y. Cho 400 ml dung dch KOH 0,1M vo
Y, c cn dung dch sau phn ng, thu c 2,995 gam rn khan. Cng thc cu to ca X l.
A. H2N-CH2-CH2-COOH B. (CH3)2-CH-CH(NH2)-COOH
C. H2N-CH2-COOH D. CH3-CH(NH2)2-COOH
Cu 23: Cho dy cc cht: metyl acrylat, tristearin, metyl fomat, vinyl axetat, triolein, glucoz,
fructoz. S cht trong dy tc dng c vi nc Br 2 l.
A. 5 B. 7 C. 6 D. 4
Cu 24: Nhng thanh Fe vo 200 ml dung dch FeCl 3 x (mol/l) v CuCl2 y (mol/l). Sau khi kt thc
phn ng, ly thanh Fe ra lau kh cn thn, cn li thy khi lng khng i so vi trc phn ng.
Bit lng Cu sinh ra bm hon ton vo thanh Fe. T l x : y l:
A. 3 : 4 B. 1 : 7 C. 2 : 7 D. 4 : 5
Cu 25: T nilon-6,6 c tnh dai bn, mm mi ng mt, t thm nc, git mau kh nhng km
bn vi nhit, vi axit v kim. T nilon-6,6 c iu ch t phn ng trng ngng gia ?
A. axit terephatlic v etylen glicol. B. axit -aminocaproic v axit aipic.
C. hexametyleniamin v axit aipic. D. axit -aminoenantoic v etylen glycol
A. Este no, n chc, mch h c cng thc tng qut l CnH2nO2 (n 2).

B. Thng thng cc este th lng, nh hn nc v rt t tan trong nc.
C. Thy phn este trong mi trng axit lun thu c axit cacboxylic v ancol.
D. t chy mt este no, n chc, mch h thu c CO2 v H2O c t l mol 1 : 1.
Cu 27: Si dy ng c dng lm dy phi qun o, ngoi khng kh m lu ngy b t.
ni li mi t , ta nn dng kim loi no dy c bn nht ?
A. Al. B. Cu. C. Fe. D. Mg.
Cu 28: Kim loi kim no di y c s dng lm t bo quang in ?
A. Li. B. Na. C. K. D. Cs.
Cu 29: Cht c s dng b bt trong y hc v c tng l:
A. Thch cao nung. B. Thch cao sng. C. Thch cao khan. D. vi.
Cu 30: Hematit l loi qung st c trong t nhin vi thnh phn chnh l:
A. FeCO3. B. Fe3O4. C. Fe2O3. D. FeS2.
A. ng sunfat khan c s dng pht hin du vt ca nc c trong cht lng.
B. P, C, S t bc chy khi tip xc vi CrO3.
C. Trong v tri t, st chim hng lng cao nht trong s cc kim loi.
D. Cho bt CrO3 vo dung dch Ba(OH)2 d thu c kt ta mu vng.
Cu 34: in phn 10 ml dung dch AgNO 3 0,4M (in cc tr) trong thi gian 10 pht 30 giy vi
dng in c cng I = 2A, thu c m gam Ag. Gi s hiu sut phn ng in phn t 100%.
Gi tr ca m l:
A. Axit glutamic. B. Axit stearic. C. Axit axetic. D. Axit aipic.
Cu 36: Cho lung kh H 2 d qua hn hp cc oxit CuO, Fe 2O3, Al2O3, MgO nung nng nhit
cao. Sau phn ng, hn hp cht rn thu c gm ?
A. Cu, Fe, Al, Mg. B. Cu, FeO, Al2O3, MgO.
C. Cu, Fe, Al2O3, MgO. D. Cu, Fe, Al, MgO.
Cu 37: Hn hp E cha ba este mch h (khng cha chc khc). t chy hon ton m gam E cn
dng va 1,165 mol O2. Mt khc, thy phn hon ton lng E trn bng NaOH thu c hn hp
cc mui v ancol. t chy hon ton lng mui thu c 11,66 gam Na 2CO3 thu c 0,31 mol
CO2, cn nu t chy hon ton lng ancol thu c th cn va 0,785 mol O 2 thu c 0,71 mol
H2O. Gi tr m l :
A. 18,16 B. 20,26 C. 24,32 D. 22,84
Cu 38: Cho m gam hn hp X gm K, Ca tan ht vo dung dch Y cha 0,12 mol NaHCO3 v 0,04
mol CaCl2, sau phn ng thu c 7 gam kt ta v thy thot ra 0,896 lt kh (ktc). Gi tr ca m l:
A. 1,72. B. 1,56. C. 1,98. D. 1,66.
Cu 39: lu anilin trong khng kh, n dn dn ng sang mu nu en, do anilin
A. tc dng vi oxi khng kh.
B. tc dng vi kh cacbonic.
C. tc dng vi nit khng kh v hi nc.
D. tc dng vi H2S trong khng kh, sinh ra mui sunfua c mu en.
Cu 40: Sc 0,02 mol Cl2 vo dung dch cha 0,06 mol FeBr 2 thu c dung dch A. Cho AgNO3 d
vo A thu c m gam kt ta. Bit cc phn ng xy ra hon ton. Gi tr ca m l:
A. 30,46 B. 12,22 C. 28,86 D. 24,02

----------HT----------

PHN TCH - HNG DN GII
THI TH THPT VNH CHN LN 1
Cu 1: Chn B.
- Este c CTPT C2H4O2 ch c mt ng phn l HCOOCH 3 (metyl fomat).
Cu 2: Chn B.
n O n CO
- Ta c : n Fe 2O3 0, 05 mol m Fe 0, 05.2.56 5, 6 (g)
3 3
Cu 3: Chn D.
- Nc cng tm thi cha cc ion Ca2+, Mg2+, HCO3, khi cho HCl vo nc cng tm thi s khng
loi b c ion Ca2+, Mg2+ do vy khng c s dng lm mm nc cng.
Cu 4: Chn A.
CTPT: C5H13N Bc 1 Bc 2 Bc 3
S ng phn 8 6 3
Cu 5: Chn A.
- Kt ta thu c gm BaSO 4 v Al(OH)3. lng kt ta t cc i th:
+ n BaSO4 nSO24 n Ba 2 3n Al2 (SO4 )3 n H2SO4 0,18 mol
+ V: 3n Al3 n OH n H 0, 24 n Al(OH)3 n Al3 0, 08 mol
Vy m 78m Al(OH)3 233n BaSO 4 48,18 (g)
Cu 6: Chn A.
Cu 7: Chn A.
- Cc kim loi phn ng vi Fe 3+ tun theo quy tc l:
Fe + FeCl3 FeCl2 Cu + 2FeCl3 2FeCl2 + CuCl2
- Cc kim loi c tnh kh mnh nh Ca th khng tun theo quy tc m phn ng nh sau:
2Fe(OH)3 + 3CaCl2 + H2
3Ca + 4H2O + 2FeCl3
Cu 8: Chn C.
- Cho Ni vo dung dch FeCl 3: Khng tha mn iu kin (1).
CuCl2, AgNO3, HCl v FeCl2
- Cho Ni vo dung dch CuCl 2: Tha mn.
- Cho Ni vo dung dch AgNO 3: Tha mn.
- Cho Ni vo dung dch HCl v FeCl 2: Khng tha mn iu kin (1).
Cu 9: Chn D.
- Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l nhng
kim loi hot ng mnh nh kim loi kim, kim th v nhm.
Cu 10: Chn D.
A. ng, Bn cht ca enzim l nhng cht hu cht c bn cht protein.
05 C 0
C. ng, Phc ng saccarozo c cng thc l (C 12H21O11)2Cu.
2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + 2H2O
D. Sai, Peptit c chia thnh hai loi :

Cu 11: Chn B.
- Phn ng : C2H 5NH 2 CH3I
1:1
C2H 5NHCH3
etylamin N metylet anamin
Cu 12: Chn A.
Cu 13: Chn B.
- Tc nhn kh CO c th kh c cc oxit kim loi ng sau Al trong dy in ha do vy hn hp
rn Y thu c l: Fe, Cu v MgO.
Cu 14: Chn D.
pdd
A. 2NaCl + 2H2O
2NaOH + Cl2 + H2
coma
ng nga
n
B. Ca(OH)2 + Na2CO3
CaCO3 + 2NaOH
C. Na2O + H2O 2NaOH
D. NH3 + Na2CO3 : khng phn ng
Cu 15: Chn D.
- Qung boxit cha thnh phn chnh l Al2O3. 2H2O. iu ch Al trong cng nghip:
+ cc m xy ra s kh ion Al3+ thnh kim loi Al: Al3+ +3e
Al
+ cc dng xy ra s oxi ha O2- thnh kh O2: 2O2
O2 + 4e
pnc
- Phng trnh in phn Al2O3 nng chy: 2Al2O3 4Al + 3O2
Cu 16: Chn A.
mB mA 1,208mA mA
- Khi cho nung T vi hn hp kh A th nO(trongT) 0,65
16 16
- Xt hn hp rn T ta c :
160nFe2O3 72nFeO mT 44 nFe O 0,05 2n nFeO
2 3 nFe3O4 (X) Fe2O3 0,2mol
3nFe2O3 nFeO nO(trongT) 0,65 nFeO 0,5 3
1,4
- Khi cho m gam X tc dng vi H2SO4 th : nH2SO4 4nFe3O4 nH2 1,4mol VH2SO4 2(l)
0,7
- Dung dch Z gm Al3+, SO42- (1,4 mol), Fe2+ v Fe3+ (vi nFe3 2nFe2O3 v nFe2 nFeO )
nSO42 2nFe2 3nFe3 mX 27nAl 232nFe3O4 59,9(g)

BTDT(Z)
nAl 3 0,5mol Cu 17:
3 mX V 57,9(g)

Chn B.
0,045mol 0,045mol 0,02mol
2 a 2 2
Mg,Fe,FeCO3,Cu(NO3)2 H 2SO4, NaNO3 Mg ,Fe ,Cu , Na ,NH 4 ,SO4 H 2 ,CO2 ,N x Oy
m(g)X dung dch hn h p 62,605(g)Y 0,17mol hn h p Z
0,045mol
-- Cho Mg2 ,Fea ,Cu2 , Na ,NH 4 ,SO42 Fe(OH)a,Cu(OH) 2,Mg(OH) 2 Na2SO4

NaOH
62,605(g)Y 31,72(g)
(1)
n Fea n Mg 2 n Cu 2 n NH 4 n NaOH 0,865 mol
BTDT n Na n Fe n n Mg 2 n Cu 2 n NH 4
n H 2SO 4 n SO 4 2 0, 455 mol
2
mmax 56n Fea 24n Mg 2 64n Cu 2 17(n OH n NH ) 56n Fea 24n Mg 2 64n Cu 2 17,015 17n NH
4 4
- Ta c: m Y 56n Fea 24n Mg 2 64n Cu 2 23n Na 18n NH 96n SO42

4
62,605 17,075 17 n NH4 23.0,045 18n NH4 96.0, 455 n NH 0,025 mol
4
2n H 2SO4 4n NH 4 2n H 2
BT: H
n H 2O 0,385 mol
2

BTKL
m X m Y m Z 18n H 2O 85n NaNO3 98n H 2SO 4 27, 2 (g)
Cu 18: Chn C.
Cu 19: Chn A.
BTKL
mX 44nCO2 18nH 2O 32nO2 9,42(g) v
0,34 0,5 0,46
BT:O
n O(X) 2nCO2 n H2O 2nO2 0, 26 mol
- V n H2O n CO2 nn trong X cha hai ancol no, n chc mch h.
n CO2 0,34
m CX 1, 7 vy hai ancol trong X l CH3OH v C2H5OH.
nX 0, 2
- Cho 18,48 gam X tc dng vi NaOH, ta c:
mX(1) 9, 42 1
. Trong 18,48g X cha
mX(2) 18,84 2
n ROH n R '(COOR)2 0, 4
n ROH 0,36
BT:O
n ROH 4n R '(COOR)2 0,52 n R '(COOR)2 0, 04
BTKL
n NaOH 2n R '(COOR) 0,08 mol mX(2) 40nNaOH mmui mROH mROH 16,32(g)
2
18,48 0,08 5,36
n C2H5OH n CH3OH n ROH 2n R '(COOR)2 0, 44

n C2H5OH 0,16 mol

- Ta c:
46n C2H5OH 32n CH3OH 16,32
n CH3OH 0, 28mol

- Xt qu trnh phn ng ete ha vi H = 100% ta c :
n CH3OH n C2H5OH BTKL
n H 2O 0, 22 mol mete 32nCH3OH 46nC2H5OH 18n H2O 12,36(g)
2
V hiu sut to ete bng 80% mete 12,36.0,8 9,888(g)
Cu 20: Chn C.
(1) H2S + K2Cr2O7 + H2SO4
K2SO4 + Cr2(SO4)3 + H2O
(2) Na3PO4 + 3AgNO3
Ag3PO4 + 3NaNO3
(3) Al2(SO4)3 + 3Na2CO3 (dung dch sa) + 3H2O
2Al(OH)3 + 3CO2 + 3Na2SO4
(4) CaO (vi sng) + Cu(NO3)2 + H2O
Ca(NO3)2 + Cu(OH)2
(5) AgNO3 + HCl AgCl + HNO3
Vy c 4 phn ng to kt ta l (2), (3), (4) v (5).
Cu 21: Chn D.
Ba(OH)2 + 2NaHCO3 BaCO3 + Na2CO3 + H2O
4Ba(OH)2 + 2AlCl3
Ba(AlO2)2 + 3BaCl2 + 4H2O
Ba(OH)2 + 2NaHSO4 BaSO4 + Na2SO4 + H2O
Ba(OH)2 + (NH4)2CO3 BaCO3 + 2NH3 + H2O
3Ba(OH)2 + 2FeCl3 3BaCl2 + 2Fe(OH)3
Ba(OH)2 + Na2SO4 BaSO4 + 2NaOH
Ba(OH)2 + KNO3 : khng phn ng
Vy c 5 trng hp thu c kt ta l: NaHCO 3, NaHSO4, (NH4)2CO3, FeCl3 v Na2SO4.
Cu 22: Chn C.

- Rn khan gm KOH (d), KCl, NH2RCOOK, vi nKCl nX 0,01mol v nNH2RCOOK nX 0,01mol
BT:K
nKOH(d ) nKOH nKCl nNH2RCOOK 0,02mol
mmui 74,5nKCl 56nKOH(d )
mNH2RCOOK 113 R l CH 2 X l NH 2CH 2COOH (glyxin)
nNH2RCOOK
Cu 23: Chn A.
Vy c 5 cht trong dy tc dng c vi nc Br 2 metyl acrylat, metyl fomat, vinyl axetat,
triolein v glucoz.
Cu 24: Chn C.
n
- Khi Fe tc dng vi x mol FeCl 3 th : mgim FeCl 3 .56 28x
2
- Khi Fe tc dng vi y mol CuCl 2 th : mt ng M CuFenCu2 8y
- Theo yu cu ca bi khi lng thanh st sau phn ng khng i th ta c phng trnh sau :
x 2
+ mgim mtng 28x 8y
y 7
Cu 25: Chn C.
o
t
axit aipic hexametyleniamin poli(hexametylen-aipamit) hay t nilon
6,6
Cu 26: Chn C.
- Thy phn cc este c dng sau y khng thu c ancol l:
H SO

2
RCOOCH=CH-R + H2O
4
RCOOH + R-CH2-CHO
o
t
H SO

2
RCOOC(CH3)=CH-R + H2O
4
RCOOH + R-CH2-CO-CH3
o
t
H 2SO4

RCOOC6H5-R + H2O RCOOH + R-C6H5OH (-C6H5: phenyl)
o
t
Cu 27: Chn B.
- Khi dng Cu ni li th lc ny trn dy ng b n mn ha hc (qu trnh n mn chm).
- Khi dng Zn, Mg, Fe th lc ny trn dy ng hnh thnh cp in cc kim loi kim loi v b n
mn in ha hc (qu trnh n mn xy ra nhanh hn).
Cu 28: Chn D.
Cu 29: Chn A.
Cu 30: Chn C.
Cu 31: Chn C.
A. ng, ng sunfat hp th nc to thnh CuSO4.5H2O mu xanh nn CuSO4 khan c s dng
pht hin du vt ca nc c trong cht lng.
B. ng, Cc cht nh C2H5OH, P, C, S t bc chy khi tip xc vi CrO3.
C. Sai, Trong v tri t, Nhm chim hng lng cao nht trong s cc kim loi.
D. ng, Cho bt CrO3 vo dung dch Ba(OH)2 d thu c kt ta mu vng.
CrO3 + Ba(OH)2
BaCrO4 vng + H2O
Cu 32: Chn A.
Cu 33: Chn A.
Cu 34: Chn C.
Ti catot Ti anot

Ag+ + e Ag H2O 4H+ + O2 + 4e
0,004 0,004 0,004
H2O + 2e H2 + 2OH-
It
- Ta c ne trao i 0,013mol > ne Ag nhng = 0,004 mol mAg 0,004.108 0,432(g)
96500
Cu 35: Chn B.
A. Axit glutamic B. Axit stearic C. Axit axetic D. Axit aipic
HOOC(CH2)2CH(NH2)-COOH (C17H35COO)3C3H5 CH3COOH HOOC(CH2)4COOH
Cu 36: Chn C.
in ha. Vy cht rn thu c gm Cu, Fe, Al 2O3, MgO.
Cu 37: Chn B.
- Khi t hn hp mui ta c : nCOO nNaOH 2nNa2CO3 0,22mol
- Xt qu trnh t hon ton lng ancol c :
nOH(trong ancol) 2nO2 nH2O

BT:O
nCO2 0,54mol (vi nOH nCOO = 0,22 mol)
2

BTKL
mancol 44nCO2 18nH2O 32nO2 11,42(g)
- Xt qu trnh t chy hn hp mui c :
+ Nhn thy rng : nO2 (t mui) nO2 (t E) nO2 (t ancol) 0,38mol v nCOONa nCOO 0,22mol
BT:O
nH2O 2nCOONa 2nO2 3nNa2CO3 2nCO2 0,25mol
BTKL
mmui 44nCO2 18nH2O 106nNa2CO3 32nO2 17,64(g)
- Khi cho hn hp E tc dng vi NaOH th:
BTKL
mE mmui mancol 40nNaOH 20,26(g)
Cu 38: Chn C.
- Cho m gam X vo dung dch Y th: nOH 2nH 2 0,08mol ; n HCO3 0,12 mol v
n CaCO3 0,07 mol
- T phn ng: Ca2 OH HCO3
CaCO3 H2O ta suy ra n Ca 2 n CaCO3 0, 07 mol

BT:e
nK 2nCa 2nH2
BT:C nK 0,02mol mX 39nK 40nCa 1,98(g)
n Ca nCa2 nCaCl 2 0,03 mol
Cu 39: Chn A.
- lu anilin ngoi khng kh th anilin chuyn sang mu nu en v b oxi ha bi oxi khng kh.
Cu 40: Chn C.
TH1 : Cl2 phn ng vi Br- trc.
Khi dung dch sau phn ng gm Fe 2+ (0,06 mol), Cl- (0,04 mol) v Br- (0,08 mol)
m 188nAgBr 143,5nAgCl 108nAg 27,26(g)
TH2 : Cl2 phn ng vi Fe2+ trc.
Khi dung dch sau phn ng gm Fe 2+ (0,02 mol), Fe3+ (0,04 mol) Cl- (0,04 mol) v Br- (0,12 mol)
m 188nAgBr 143,5nAgCl 108nAg 30,46(g) Vy 27,26 m 30,26

THPT VNH BO Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Este X mch h c cng thc phn t C5H8O2, c to bi mt axit Y v mt ancol Z. Vy Y

khng th l
A. CH3COOH. B. C2H5COOH. C. C3H5COOH. D. HCOOH.
Cu 2: Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c
3,36 gam cht rn. Gi tr ca m l
A. 2,88. B. 2,16. C. 4,32. D. 5,04.
Cu 3: iu ch kim loi kim ngi ta dng phng php
A. thu luyn B. nhit luyn C. in phn dung dch D. in phn nng chy
Cu 4: Dy no di y gm cc cht c kh nng ha tan Cu(OH)2 to hp cht mu tan trong trong
nc
A. etilen glycol, axit axetic v GlyAlaGly B. ancol etylic, fructoz v GlyAlaLysVal
C. glixerol, glucoz v GlyAla D. ancol etylic, axit fomic v LysVal
Cu 5: Mui mononatri ca amino axit no sau y c dng lm bt ngt (m chnh)?
A. Lysin. B. Alanin. C. Axit glutamic. D. Axit amino axetic.
Cu 6: Oxit no sau y l oxit lng tnh :
A. Cr2O3. B. CrO. C. Fe2O3. D. MgO.
Cu 7: Cho x mol Fe tc dng vi dung dch cha y mol AgNO3. dung dch sau phn ng tn ti cc
ion Fe3+, Fe2+ th gi tr ca a = y : x l
A. 3 < a < 3,5. B. 1 < a < 2. C. 0,5 < a < 1. D. 2 < a < 3.
Cu 8: t chy hon ton 1 mol cht bo X, thu c lng CO2 v H2O hn km nhau 8 mol. Mt
khc a mol cht bo X trn tc dng ti a vi 600 ml dung dch Br2 1M. Gi tr ca a l
A. 0,15 B. 0,10 C. 0,30 D. 0,20
Cu 9: Trong cc hin tng thc hnh di y, hin tng no miu t khng chnh xc.
A. Cho mu Na vo dung dch ng FeCl3 thy c kh thot ra ng thi c kt ta mu nu .
B. Thm dung dch NH3 d vo dung dch AlCl3 thy c kt ta, sc kh CO2 d vo ng nghim cha
kt ta trn thy kt ta tan.
C. Nhng l st nh sch g vo dung dch CuSO4, l st chuyn sang mu .
D. Th mu km vo hai ng nghim u cha dung dch H2SO4. Thm vo ng nghim th nht vi
git CuSO4 thy kh thot ra ng nghim ny nhanh hn.
AlCl3 + NH3 + H2O
Cu 10: Mt loi nc cng c cha cc ion: Ca2+, Mg2+, Cl- v SO42-. Ha cht no trong s cc cht
sau y c thm lm mm loi nc cng trn
A. K2CO3. B. NaOH C. NaCl D. KNO3
Cu 11: Kim loi Al khng phn ng vi cht no sau y trong dung dch :
A. Fe2(SO4)3 B. CuSO4 C. HCl D. MgCl2
Cu 12: Hp cht hu c X c cng thc C3H12N2O3. Khi cho 12,4 gam X tc dng vi 200 ml dung
dch NaOH 1,5M thu c 4,48 lt ( ktc) kh Y lm xanh giy qu tm m. C cn dung dch sau phn
ng thu c cht rn c khi lng l
A. 16,2 gam. B. 17,4 gam. C. 17,2 gam. D. 13,4 gam

Cu 13: Cht no sau y trng hp to poli(metyl metacrylic) :
A. CH2=C(CH3)COOCH3 B. CH2=CHCOOCH3
C. CH3COOCH=CH2 D. CH2=C(CH3)COOC2H5
Cu 14: Cho s phn ng sau:
Cl 2 + dung dch KOH d
(NH4)2Cr2O7 t0 dung dch HCl,t 0
X Y Z
+ dung dch H2SO4 long
T
Trong X, Y, Z v T u l cc hp cht khc nhau ca crom. Cht T l
A. K2Cr2O7. B. K2CrO4. C. Cr2(SO4)3. D. CrSO4.
Cu 15: Trong phng th nghim, cht rn tinh khit no sau y khng c tc dng ht m :
A. NaCl B. NaOH C. CaO D. CaCl2
Cu 16: Cho hn hp gm 0,1 mol Zn v 0,2 mol Mg vo 400ml dung dch cha ng thi Cu(NO 3)2
1M v AgNO3 1M. Sau khi phn ng xy ra hon ton, thu c cht rn X. Ha tan hon ton X trong
lng d dung dch HNO3, thu c V lt kh NO (sn phm kh duy nht N +5, ktc). Gi tr ca V l:
A. 5,60 B. 6,72 C. 4,48 D. 2,24
Cu 17: Bng di y ghi li hin tng khi lm th nghim vi cc cht X, Y ,Z, T dng dung dch
vi dung mi nc:
Thuc th
X Y Z T
Cht
Dung dch
Khng c kt ta Ag Khng c kt ta Ag
AgNO3/NH3 un nh
Cu(OH)2 khng
Cu(OH)2, lc nh Dung dch xanh lam Dung dch xanh lam Dung dch xanh lam
tan
Mt mu nc
Mt mu nc Khng mt mu Khng mt mu
Nc brom brom v c kt
brom nc brom nc brom
ta trng
Cc cht X, Y, Z, T ln lt l
A. Phenol, Axit fomic, saccaroz, glucoz B. Anilin, glucoz, glixerol, fructoz
C. Anilin, mantoz, etanol, axit acrylic D. Phenol, glucoz, glixerol, mantoz
Cu 18: Hn hp X gm C2H5OH, HCHO, CH3COOH, HCOOCH3, CH3COOC2H3,
CH3CH(OH)COOH v CH2OHCH(OH)CHO. t chy hon ton 13,8 gam X cn dng va 12,04
lt O2 (ktc), thu c CO2 v 9 gam H2O. Thnh phn phn trm theo khi lng ca CH 3COOC2H3
trong X l:
A. 15,58% B. 12,46% C. 31,16% D. 24,92%
(a) Cho Mg vo dung dch Fe 2(SO4)3 d.
(b) Sc kh H2S vo dung dch FeCl 3
(c) Cho dung dch KHSO4 vo dung dch Ba(HCO3)2
(d) Cho K d vo dung dch Ca(H2PO4)2
(e) Cho dung dch (NH4)2CO3 vo dung dch Ba(OH)2
S th nghim thu c kt ta l :
A. 3 B. 2 C. 5 D. 4
Cu 20: C 3,94g hn hp X gm bt Al v Fe3O4( trong Al chim 41,12% v khi lng) thc
hin phn ng nhit nhm hon ton hn hp X trong chn khng thu c hn hp Y. Ha tan hon
ton Y trong dung dch cha 0,314 mol HNO 3 thu c dung dch Z ch c cc mui v 0,021mol mt
kh duy nht l NO. C cn dung dch Z, ri thu ly cht rn khan nung trong chn khng n khi
lng khng i thu c hn hp kh v hi T. Khi lng ca T gn gi tr no nht sau y?
A. 14,15g B. 15,35g C. 15,78g D. 14,58g
Cu 21: Hn hp X gm Mg, Al, Al2O3 v MgCO3 (trong oxi chim 25,157% v khi lng).
Ha tan ht 19,08 gam X trong dung dch cha 1,32 mol NaHSO 4 v x mol HNO3, kt thc phn ng
thu c dung dch Y ch cha cc mui trung ha c khi lng 171,36 gam v hn hp kh Z gm
CO2, N2O, H2. T khi ca Z so vi He bng 7,5. Cho dung dch NaOH d vo Y, thu c 19,72
gam kt ta. Gi tr ca x l :
A. 0,10 B. 0,18 C. 0,16 D. 0,12
Cu 22: t chy 16,8 gam bt Fe trong V lt (ktc) hn hp kh gm Cl2 v O2, thu c hn hp
rn X gm cc oxit v mui (khng thy kh thot ra). Ha tan X trong 480 ml dung dch HCl 1M,
thu c dung dch Y. Cho dung dch AgNO3 d vo Y, thy thot ra 0,03 mol kh NO (sn phm
kh duy nht ca N +5), ng thi thu c 132,39 gam kt ta. Gi tr ca V l.
A. 6,272 lt B. 7,168 lt C. 6,720 lt D. 5,600 lt
Cu 23: Phn ng ha hc no sau y l sai ?
0
A. Ba(HCO3) t
BaO + 2CO2 + H2O B. 2FeCl2 + Cl2 2FeCl3
C. Cr + NaOH + H2O NaCrO2 + H2 D. Al(OH)3 + NaOH NaAlO2 + 2H2O
Cu 24: Tin hnh in phn dung dch NaCl bng in cc tr, thu c mt kh X duy nht. iu
khng nh no sau y l ng ?
A. X l kh oxi B. X l kh clo
C. X l kh hiro D. C dng mng ngn xp
Cu 25: rut non ca c th ngi nh tc dng xc tc ca cc enzim nh lipaza v dch mt, cht
bo b thy phn thnh :
A. axit bo v glixerol B. axit cacboxylic v glixerol
C. CO2 v H2O D. NH3, CO2 v H2O
Cu 25: Chn A.
Qu trnh thy phn cht bo trong c th ngi xy ra nh sau :
0
(RCOO)3C3H5 + NaOH t
3RCOONa C3H 5 (OH)3
Cu 26: t chy hon ton 1,53 gam este X thu c 3,3 gam CO2 v 1,35 gam H2O. Cng thc
phn t ca X l.
Cu 27: Th nghim no sau y thu c mui st (II).
A. t chy bt st trong kh clo.
B. Cho bt st vo lng d dung dch bc nitrat.
C. Cho natri kim loi vo lng d dung dch Fe (III) clorua.
D. t chy hn hp bt gm st v lu hunh trong iu kin khng c khng kh.
Cu 28: Cho cc este sau thy phn trong mi trng kim : C6H5COOCH3, HCOOCH=CH-CH3,
CH3COOCH=CH2, C6H5OOCCH=CH2, HCOOCH=CH2,C6H5OOCCH3, HCOOC2H5, C2H5OOCCH3.
C bao nhiu este khi thy phn thu c ancol
A. 3 B. 4 C. 5 D. 6
Cu 29: Nhng mt thanh magie vo dung dch c cha 0,8 mol Fe(NO 3)3 v 0,05 mol Cu(NO3)2 . Sau
mt thi gian, ly thanh kim loi ra, ra sch, cn li thy khi lng tng 11,6 gam so vi thanh kim
loi ban u. Khi lng magie phn ng l
A. 6,96 gam B. 20,88 gam C. 25,2 gam D. 24 gam
A. Cc peptit m phn t ch cha t 11 n 50 gc -aminoaxit c gi l polipeptit.
B. Cc protein u l cht rn, nhit nng chy cao v d tan trong nc.
C. Peptit mch h phn t cha hai gc -aminoaxit c gi l ipeptit.
D. Peptit mch h phn t cha hai lin kt peptit CO-NH c gi l ipeptit.
Cu 31: Cho 4,48 gam hn hp etyl axetat v phenyl axetat (c t l mol 1 : 1) tc dng ht vi 800 ml
dung dch NaOH 0,1M thu c dung dch X. C cn dung dch X, thu c m gam cht rn khan. Gi
tr m l :
A. 5,6 B. 4,88 C. 3,28 D. 6,4
Cu 32: ipeptit X c cng thc : NH2CH2CONHCH(CH3)COOH. Tn gi ca X l :
A. Alanylglixyl B. Alanylglixin C. glyxylalanin D. Glyxylalanyl
Cu 33: Hn hp X nng m gam gm mantozo v tinh bt. Chia X thnh hai phn bng nhau

-Phn 1 : Ha tan trong nc d, lc ly kt ta ri cho dung dch phn ng ht vi dung dch
AgNO3/NH3 d thu c 0,03 mol Ag
-Phn 2 : un nng vi dung dch H2SO4 long thc hin phn ng thy phn. Hn hp sau phn
ng c trung ha bi dung dch NaOH sau cho ton b sn phm thu c tc dng ht vi
AgNO3/NH3 d thu c 0,192 mol Ag. Bit hiu sut phn ng thy phn t 60%. Gi tr ca m l :
A. 45,9 g B. 35,553 g C. 49,14 g D. 52,38 g
Cu 34: Vt liu polime no sau y c cha nguyn t nit?
A. Nha poli(vinyl clorua). B. T visco.
C. T nilon-6,6. D. Cao su buna.
Cu 35: Kim loi Cu khng tan trong dung dch
A. H2SO4 c nng. B. HNO3 c nng. C. HNO3 long. D. H2SO4 long.
Cu 36: Cho glucoz ln men thnh ancol etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp
th ht vo dung dch Ca(OH)2 d to ra 50 gam kt ta, bit hiu sut qu trnh ln men t 80%. Khi
lng glucoz cn dng l
Cu 37: Kim loi c con ngi dng ph bin ch to trang sc, c tc dng bo v sc kho l
A. st. B. st ty. C. bc. D. ng.
Cu 38: Mt mu kh thi c sc vo dung dch CuSO4, thy xut hin kt ta mu en. Hin tng
ny do trong kh thi c ?
A. NO2. B. H2S. C. CO2. D. SO2.
Cu 39: un nng 100 gam dung dch glucoz 18% vi lng d dung dch AgNO3 trong NH3, n
khi phn ng xy ra hon ton thu c m gam Ag. Gi tr ca m l:
Cu 40: un nng este CH3OOCCH=CH2 vi mt lng va dung dch NaOH, sn phm thu c
l:
A. CH2=CHCOONa v CH3OH. B. CH3COONa v CH2=CHOH.
C. CH3COONa v CH3CHO. D. C2H5COONa v CH3OH.
----------HT----------

THI TH THPT VNH BO LN 1
Cu 1: Chn B.
Vy X khng th l C2H5COOCH=CH2 v :
t0
C2H5COOCH=CH2 + NaOH C2H5COONa + CH3CHO
Cu 2: Chn A.
3,36 2n n
- Rn ch cha Fe, c nFe 0,06
BT:e
nMg Fe FeCl 3 0,12 mMg 2,88(g)
56 2
Cu 3: Chn D.
Cu 4: Chn A.
2C2H4(OH)2 + Cu(OH)2 [C2H4(OH)O]2Cu(xanh lam) + H2O
2CH3COOH + Cu(OH)2 (CH3COO)2Cu(xanh lam) + 2H2O
GlyAlaGly to phc mu tm xanh vi Cu(OH)2.
Cu 5: Chn C.
Bt ngt (m chnh) l mui mononatri ca axit glutamic (hay mononatri glutamat)
HOOC CH 2 CH 2CH(NH 2 )COOH HOOC CH 2 CH 2CH(NH 2 )COONa
axit glutamic mononatri glutamat
Cu 6: Chn A.
Cu 7: Chn D.
- dung dch thu c tn ti cc ion Fe2+ v Fe3+ th
y
2nFe nAgNO3 3nFe 2x y 3x 2 3 2 a 3
x
Cu 8: Chn B.
quan h
- t X th
CO v H O
nX (k X 1) nCO2 nH2O k X 1 8 k X 9 3 CO 6 CC
2 2
nBr2
- Cho a mol X tc dng vi Br2 th : a 0,1mol
6
Cu 9: Chn B.
Cu 10: Chn A.
Ca2 CO32
CaCO3 Mg2 CO32
MgCO3
Cu 11: Chn D.
A. 2Al 3Fe2 (SO4 )3 Al2 (SO4 )3 6FeSO4 . Nu Al d th 2Al 3FeSO4 Al 2 (SO4 )3 3Fe
B. 2Al 3CuSO4
Al 2 (SO4 )3 3Cu
C. 2Al 6HCl 2AlCl3 3H 2
D. Al + MgCl2 khng xy ra phn ng
Cu 12: Chn B.
(CH3NH3 )2 CO3 2NaOH
Na2CO3 2CH3NH 2 H 2O
C nNaOH(d ) 0,1 mrn 40nNaOH(d ) 106nNa2CO3 14,6(g)

Cu 13: Chn A.
COOCH3

CH2 C
n
CH3 CH3
Cu 14: Chn A.

0
(NH 4 )2 Cr2O7
t
Cr2O3(X) N 2 H 2O
0
Cr2O3 (X) HCl t
CrCl 3(Y) H 2O
CrCl 3(Y) Cl 2 KOH K 2CrO4 (Z) KCl H2O
K 2CrO4 (Z) H 2SO4 K 2SO4 K 2Cr2O7 (T) H 2O
Cu 15: Chn A.
- Trong phng th nghim ta hay gp c ha cht c tc dng ht m nh: H2SO4 c, dung dch kim v
cc cht khan CuSO4, CaCl2, CaO, P2O5. Vy NaCl khng khng c tc dng ht m.
Cu 16: Chn C.
- Hng t duy 1 :
0,1mol 0,2mol 0,4mol 0,4mol 0,1mol 0,2mol 1,2mol 0,4mol
2 2 2
- Qu trnh: Zn , Mg Cu(NO3 )2 ,AgNO3 Zn ,Mg ,Cu ,NO3 Ag ,Cu
hn h p kl dd ddsau phn ng(T) rnX
BTDT
nNO 2nMg2 2nZn2 BT:Cu
nCu2 (T) 3
0,3 mol
nCu(X) nCu(NO3 )2 nCu2 (T) 0,1mol
(T) 2
BT:e
- Khi cho X tc dng vi HNO3 th
2nCu n Ag 3n NO n NO 0, 2 mol VNO 4, 48(l)
- Hng t duy 2: p dung bo ton e cho ton qu trnh phn ng
2n Mg 2n Zn
0, 2 VNO 4, 48(l)
BT:e
n NO
3
Cu 17: Chn B.
Thuc th
Anilin Glucoz Glixerol Fructoz
Cht
Dung dch
Khng c kt ta Ag Khng c kt ta Ag
AgNO3/NH3 un nh
Cu(OH)2 khng
Cu(OH)2, lc nh Dung dch xanh lam Dung dch xanh lam Dung dch xanh lam
tan
Mt mu nc
Mt mu nc Khng mt mu Khng mt mu
Nc brom brom v c kt
brom nc brom nc brom
ta trng
Cu 18: Chn A.
- Quy i:
HCHO,CH3COOH, HCOOCH3 , HOCH 2CH OH CHO,CH3CH OH COOH Cn H 2n On
CH 2O C 2 H 4O 2 C3H6O3
(Lu : ta cng c th quy i C n H 2n O n thnh CH2O, v bn cht bi ton khng thay i).
x mol y mol z mol
- Qu trnh: (C 2 H 5OH)C 2 H 6O , (CH 3COOC 2 H 3 )C 4 H 6O 2 , C n H 2n O n O2 CO 2 H 2O

13,8(g) X 0,5375 mol 0,5 mol
BTKL m X 32n O 2 18n H 2O quan h

n CO 2 0,5 mol y x nCO2 nH2O y x .
44 CO2 v H 2O

BT: C
2n C2H6O 4n C4H 6O 2 nn Cn H 2nO n n CO 2 2x 4x nz 0,5
y 0,025 %m C4H 6O2 15,58
m X 46n C2H 6O 86n C4H 6O 2 30n.n Cn H 2nO n m X 46x 86x 30nz 13,8
Cu 19: Chn A.
(a) Mg Fe2 (SO4 )3
MgSO4 2FeSO4

(b) H2S + FeCl3 FeCl2 + S + HCl
(c) KHSO4 + Ba(HCO3)2 K2SO4 + BaSO4 + CO2 + H2O
(d) K + H2O + Ca(H2PO4)2 Ca3(PO4)2 + K3PO4 + H2
(e) (NH4)2CO3 + Ba(OH)2 BaCO3 + NH3 + H2O
Vy c c 4 phn ng to kt ta l (b), (c), (d) v (e) khng sinh ra n cht.
Cu 20: Chn B.
0,01mol 0,06mol 3 2 3 0,015mol 0,03mol
Al, Al2O3 HNO
- Qu trnh: Fe3O4 , Al t0 Al , Fe , Fe t0 N O, NO2

3
Z Fe2O3 , Al2O3 T 2

X
Fe, Fe x O y NH4 , NO3 5,46(g)
O2 , H 2O
BT:O n H 2n O(X) 4n NO
nO(X) 4n Fe3O4 0,04 . Xt dung dch Z c n NH 0, 015
4 10
BT:Fe
n NO n HNO3 n NH n NO 0, 278 v nFe2 nFe3 3nFe3O4 2nFe2O3 0,03
BT:N
3 4
BT:Al
n Al n Al3 2n A l2 O3 0, 06 m Z 56(n Fe 2 n Fe3 ) 24n Al3 18n NH 4 62n NO3 20,806 (g)
BTKL
- Khi nung Z th mT mZ 160n Fe2O3 102n Al2O3 15,346(g)
Cu 21: Chn C.
0,25157.19,08
- Theo bi ta c : nO(trong X) 0,3mol
16
- Khi cho dung dch tc dng vi NaOH d ta c : nMg2 nMg(OH)2 0,34mol

3nAl 3 nNH 4 2nSO42 nNa 2nMg2 0,64
BTDT
nAl 0,2mol

- Xt dung dch Y c
nNH 4 0,04mol
27nAl 18nNH 4 mY 96nSO42 23nNa 24nMg2 6,12

- Quy i hn hp rn X thnh Mg, Al, O v C. Xt hn hp rn X ta c
mX 24nMg 27nAl 16nO

BT:C
nMgCO3 nC 0,06mol
12
- Quay li hn hp rn X vi Al, Al2O3, Mg v MgCO3 c : nMg nMg2 nMgCO3 0,28mol
nO(trongX) 3nMgCO3
BT:O
nAl 2O3 0,04mol nAl nAl 3 2nAl 2O3 0,12mol
3
n nN2O 2y
- Xt hn hp kh Z ta c : CO2 nN2O 2y nCO2 2y 0,06 nH2 y mol
nH 2 y
- Xt ton b qu trnh phn ng ca X vi dung dch cha 1,32 mol NaHSO 4 v x mol HNO3 c:
nNaHSO4 nHNO3 4nNH 4 2nH 2

BT:H
nH 2O 0,5x y 0,58
2
BTKL
m 63nHNO3 120nNaHSO4 mY mZ 18nH2O
19,08 63x 120.1,32 171,36 90y 18(0,5x y 0,58) 54x 72y 4,32(1)
BT:N
2nN2O nNH4 nHNO3 2(2y 0,06) 0,04 x x 4y 0,08(2)
- Gii h (1) v (2) ta c : x 0,16 v y = 0,06
Cu 22: Chn C.
- Gi x l s mol Cl 2. Khi cho hn hp X tc dng vi HCl th :
n nHCl nH (d )
nO2 H 0,09mol (vi nH (d ) 4nNO 0,24mol )
4 4
- Khi cho dung dch X tc dng vi AgNO 3 c: nAgCl nCl 2nCl 2 nHCl 2x 0,48

143,5nAgCl 108nAg m
143,5(2x 0,48) 108y 132,39 x 0,03
BT:e
n Ag 3n NO 2nCl 2 4nO2 3n Fe 2x y 0,45 y 0,21

Vy VCl 2 ,O2 (0,21 0,09).22,4 6,72(l)
Cu 23: Chn C.
- Cr khng tc dng c vi dung dch NaOH long.
Cu 24: Chn C.
- Khi in phn dung dch NaCl khng c mn ngn th:
pdd
2NaCl + 2H2O 2NaOH + H2 + Cl2 Cl2 + 2NaOH
NaCl + NaClO + H2O
Vy kh thu c duy nht l H 2.
Cu 26: Chn B.
1,53 n 5
- Khi t chy X nhn thy: n CO2 n H 2O 0, 075 mol M X n X l C5H10O2
0, 075
Cu 27: Chn B.
to
A. 2Fe 3Cl2 2FeCl3
B. Fe + 3AgNO3 (d)
Fe(NO3)3 + 3Ag
C. 6Na + 3H2O + 2FeCl3
2Fe(OH)3 + 6NaCl + 3H 2
to
D. Fe S FeS
Cu 28: Chn A.
C este khi thy phn thu c ancol l C 6H5COOCH3, HCOOC2H5 v C2H5OOCCH3.
Cc este cn li khi thy phn thu c :
0
HCOOCH=CH-CH3 + NaOH
t
HCOONa + CH3CH2CHO
0
CH3COOCH=CH2 + NaOH
t
CH3COONa + CH3CHO
0
C6H5OOCCH=CH2 + 2NaOH
t
CH2=CH-COONa + C6H5ONa + H2O
0
HCOOCH=CH2 + NaOH
t
HCOONa + CH3CHO
0
C6H5OOCCH3 + 2NaOH t
CH3COONa + C6H5ONa + H2O
Cu 29: Chn C.
- Dung dch thu c sau phn ng gm Mg 2+, Fe2+, Cu2+ v NO3-.
- p dng phng php tng gim khi lng v bo ton e ta c :
n
mthanh KL tng nFe(NO3 )2 (p ) .M FeMg nCu(NO3)2 .M CuMg Fe(NO3 )3 .24
2
11,6 32nFe(NO3 )2 (p ) 40.0,05 0,4.24 nFe(NO3 )2 (p ) 0,6mol
nFe(NO3 )3 2nCu(NO3 )2 2nFe(NO3 )3(p ) 0,8 2.0,05 2.0,6
BT:e
nMg(p ) 1,05mol
2 2
- Vy mMg(p ) 1,05.24 25,2(g)
Cu 30: Chn C.
A. Sai, peptit c chia thnh hai loi :
B. Sai, Protein c chia lm 2 loi : dng protein hnh si v protein hnh cu
Protein hnh cu gm : abumin (long trng trng g), hemoglobin (mu)
Protein hnh si gm : keratin (tc, mng, sng), fibroin (t tm, mng nhn)
- Tnh tan : Protein hnh si hon ton khng tan trong nc, ngc li cc protein hnh cu tan trong
nc to thnh dung dch keo.
C. ng, nu peptit c n mc xch th s c (n 1) lin kt peptit nn ipeptit s c 1 lin kt peptit.
D. Sai, peptit mch h phn t cha hai lin kt peptit CO-NH c gi l tripeptit.
Cu 31: Chn D.
- Theo bi ta c : nCH3COOC2H5 nCH3COOC6H5 0,02mol
- Khi cho 4,48 gam hn hp trn tc dng vi 0,08 mol NaOH th : nH2O nCH3COOC6H5 0,02mol
BTKL
mrn mhn h p 40nNaOH 18nH2O 6,4(g)
Cu 32: Chn D.
Cu 33: Chn C.
nAg
- Xt phn 1 ta c : nmantz 0,015mol
2
- Xt phn 2 ta c :
nAg (4nmantz 2ntinh bt ).H 2nmantz(d ) (4.0,015 2x).0,6 0,015.0,4.2 0,192 x 0,12
Vy m 2(342nmantz 162ntinh bt ) 49,14(g)
Cu 34: Chn C.
Cu 35: Chn D.
Cu 36: Chn B.
- Sc CO2 vo dung dch Ca(OH)2 d th : nCO2 nCaCO3 0,5mol
nCO2
nC6H12O6 0,3125mol mC6H12O6 56,25(g)
2H%
Cu 37: Chn C.
- Trong cc loi hng trang sc th bc c bit n ph bin nht vi hai chc nng chnh l: lm p
v trnh gi.
- i vi tr nh th bc c xem nh l ba h mnh. Chnh v vy, hu nh b no cng c eo cho
mt chic lc bc nh xinh trnh gi v theo di sc kho cho b.
- Trang sc bc d kiu no v u cng u c li cho sc kho.
- Ngoi kh nng trnh gi v co gi, bc cn c tc dng lu thng khp v ng tim mch.
Cu 38: Chn B.
- Phn ng: CuSO4 + H2S CuS den + H2SO4
Cu 39: Chn C.
mdd C6H12O6 .C%
- Ta c: mAg 108.nAg 108.2. .h% 21,6 (g)
180
Cu 40: Chn A.
- Phn ng: CH3OOCCH=CH2 + NaOH
CH2=CHCOONa + CH3OH

TNH QUNG NAM Mn: KHOA HC T NHIN HA HC
THPT TIU LA Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Dung dch mui khng phn ng vi Fe l :

A. AgNO3. B. CuSO4. C. MgCl2. D. FeCl3.
Cu 2: Amin X c cng thc phn t C5H13N. S amin bc III ca X l :
A. 3 B. 4 C. 2 D. 5
Cu 3: Este CH2=C(CH3)-COO-CH2-CH3 c tn gi l
A.vinyl propionat B. metyl acrylat C. etyl fomat D. etyl metacylat
Cu 4: Cht no c nhit nng chy cao nht trong cc cht sau :
A. CH2(NH2)COOH. B. CH3CH2OH. C. CH3CH2NH2. D. CH3COOCH3.
Cu 5: Cho cc nhn nh sau :
(a) Vinyl axetat khng lm mt mu dung dch brom.
(b) Anilin v phenol u lm mt mu nc brom nhit thng.
(c) Trng ngng caprolactam thu c t capron.
(d) Cao su lu ho, amilopectin ca tinh bt l nhng polime c cu trc mng khng gian.
(e) Peptit, tinh bt, xenluloz v t lapsan u b thy phn trong dung dch NaOH long, un nng.
S nhn nh ng l
A. 1 B. 2 C. 3 D. 4
Cu 6: Etyl axetat khng tc dng vi
A. H2O (xc tc H2SO4 long, un nng). B. H2 (xc tc Ni, nung nng).
C. dung dch Ba(OH)2 (un nng). D. O2, t0.
(1) Kh SO2 gy ra hin tng hiu ng nh knh.
(2) Kh CO2 gy ra hin tng ma axit.
(3) Cc dng nhin liu nh than, du m v kh t nhin c gi l nhin liu ha thch.
(4) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon.
(5) Cc ngun nng lng: thy in, gi, mt tri u l nhng ngun nng lng sch.
Nhng pht biu ng l
A. (3), (4), (5). B. (1), (2), (4). C. (1), (2), (4), (5). D. (2), (3), (4), (5).
Cu 8: Gi s 1 tn ma cy p ra c 900 kg nc ma c nng saccaroz l 14%. Hiu sut ca
qu trnh sn xut saccaroz t ma t c 90%. Vy lng ng ct trng thu c t 1 tn ma cy
l:
A. 113,4 kg B. 140,0 kg C. 126,0 kg D. 213,4 kg
Cu 9: Cho hn hp gm a (mol) Mg v b (mol) Fe vo dung dch cha c (mol) AgNO3, khi cc phn
ng xy ra hon ton thu c dung dch X gm 2 mui v cht rn Y (gm 2 kim loi).
A. 2a c 2(a + b). B. 2a < c < 2(a + b). C. c 2(a + b). D. 2(a b) < c < 2(a +
b).
Cu 10: t chy hon ton m gam hn hp X gm C2H4O2, C3H4O2, CH2O v C3H6O3 cn dng V lt
kh oxi (ktc) thu c 3,36 lt kh CO2 (ktc) v 2,7 gam nc. Gi tr ca m v V ln lt l
A. 4,5g v 3,36 lt B. 2,1g v 3,36 lt C. 2,1g v 4,48 lt D. 4,5g v 4,48 lt
Cu 11: Nhit phn Fe(NO3)2 trong mi trng kh tr. Sau khi cc phn ng xy ra hon ton, thu c
sn phm gm:

A. FeO, NO2, O2. B. Fe2O3, NO2, O2. C. Fe3O4, NO2, O2. D. Fe, NO2, O2.
Cu 12: Hp th ht 4,48 lt CO2 (ktc) vo dung dch cha x mol KOH v y mol K2CO3 thu c
200ml dung dch X. Ly 100ml X cho t t vo 300 ml dung dch HCl 0,5M thu c 2,688 lt kh (kc).
Mt khc, 100 ml X tc dng vi Ba(OH)2 d thu c 39,4 gam kt ta. Gi tr ca x l
A. 0,15 B. 0,2 C. 0,06 D. 0,1
Cu 13: Ln lt cho mt mu Ba v cc dung dch K2SO4, NaHCO3, HNO3 v NH4Cl. S trng hp
xut hin kt ta l
A. 3 B. 4 C. 2 D. 1
Cu 14: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip
nhau (MX < MY). t chy hon ton mt lng M cn dng va 0,225 mol O2, thu c H2O, N2 v
0,12 mol CO2. Cng thc phn t ca Y l
A. C3H9N. B. C2H7N. C. C4H11N. D. CH5N.
Ca(OH)2 d, sau phn ng thu c 5,0 gam kt ta v khi lng dung dch gim 2,08 gam. Bit khi x
phng ho X ch thu c mui ca axit cacboxylic v ancol. S ng phn ca X l:
A. 4 B. 5. C. 3. D. 6.
Cu 16: Hn hp X gm CH3COOC2H5, C2H5COOCH3 v C2H5OH. t chy hon ton m gam hn
hp X thu c 0,6 mol CO2 v 0,7 mol H2O. Thnh phn phn trm v khi lng ca C2H5OH bng
A. 34,33% B. 51,11% C. 50,00% D. 20,72%
Cu 17: Cho 6,9 gam Na vo dung dch HCl thu c dung dch X c cha 14,59 gam cht tan. Cho
dung dch X vo dung dch AgNO3 d n phn ng hon ton thu c a gam kt ta. Gi tr ca a l:
Cu 18: X phng ha hon ton 4,4 gam CH3COOC2H5 bng mt lng dung dch NaOH va . C
cn dung dch sau phn ng, thu c m gam mui khan. Gi tr ca m l
A. 4,1. B. 3,7. C. 4,2. D. 6,4.
Cu 19: St ty l hp kim ca st v kim loi M. M l:
A. Zn. B. Pb. C. Cr. D. Sn.
Cu 20: Cho m gam glucoz ln men thnh ancol etylic. Kh sinh ra cho vo nuc vi trong d thu c
120 gam kt ta, bit hiu sut qu trnh ln men t 60%. Gi tr m l
A. 225 gam. B. 180 gam. C. 112,5 gam. D. 120 gam.
Cu 21: Ha tan 9,61 gam hn hp X gm 3 kim loi Ba, Al v Fe vo nc (ly d) thu c 2,688 lt
H2 (kc) v cht rn Y. Cho Y tc dng ht vi CuSO4 thu c 7,04 gam Cu. Phn trm khi lng ca
Al trong X l :
A. 22,47 % B. 33,71 % C. 28,09 % D. 16,85 %
Cu 22: Cho cc pht biu sau :
(1) Khi un nng NH2-CH2-CH2-COOH c xc tc thch hp th thu c hn hp cc peptit
(2) Metylamin, amoniac v anilin u u lm giy qu tm m chuyn sang mu xanh
(3) Sobitol l hp cht hu c tp chc.
(4) T ha hc gm t nhn to v t tng hp.
(5) Nh dung dch I2 vo dung dch h tinh bt, ri un nng dung dch thu c xut hin mu xanh
tm
S pht biu ng l :
A. 1 B. 2 C. 3 D. 4
Cu 23: Cho 17,6 gam hn hp X gm Fe v Cu phn ng vi dung dch HCl long (d), n khi phn
ng xy ra hon ton thu c 4,48 lt kh H2 (ktc) v dung dch cha m gam mui. Gi tr ca m l ?
A. 25,4 gam. B. 31,8 gam. C. 24,7 gam D. 18,3 gam
Cu 24: Cho t t n d dung dch NaOH vo dung dch X cha hn hp Al(NO3)3, HCl v HNO3. Kt
qu th nghim c biu din trn th sau, gi tr ca a l

A. 1,5 B. 1,2 C. 0,8 D. 1,25
Cu 25: Ba cht hu c n chc, mch h X, Y, Z c cng cng thc phn t C3H6O2 v c cc tnh
cht: X, Y, Z u phn ng c vi dung dch NaOH; X, Z u khng c kh nng tc dng vi kim
loi Na; khi un nng cht X vi dung dch H2SO4 long th trong s cc sn phm thu c, c mt cht
c kh nng tham gia phn ng trng bc. Cc cht X, Y, Z ln lt l
A. CH3COOCH3, C2H5COOH, HCOOC2H5. B. HCOOC2H5, CH3COOCH3, C2H5COOH.
C. HCOOC2H5, C2H5COOH, CH3COOCH3. D. C2H5COOH, HCOOC2H5, CH3COOCH3.
Cu 26: Trng hp hirocacbon no sau y to ra polime dng sn xut cao su buna
A. Penta-1,3-ien. B. Buta-1,3-ien. C. But-2-en. D.2-metylbuta-1,3-
ien.
Cu 27: Cho hn hp Fe, Mg vo dung dch AgNO3 v Cu(NO3)2 th thu c dung dch A v 1 kim
loi. Kim loi thu c sau phn ng l :
A. Cu B. Ag C. Fe D. Mg
Cu 28: Cho cc cht: HCOO-CH3, CH3-COOH, CH3-COOCH=CH2, CH3-CH2-CHO v (COOCH3)2.
S cht trong dy thuc loi este l
A. 4 B. 2. C. 3. D. 1.
Cu 29: t chy hon ton 9,65 gam hn hp X gm cc amin no h thu c 17,6 gam CO2 v 12,15
gam H2O. Nu cho 19,3 gam X tc dng vi HCl d c m gam mui. Xc nh m?
(a) Ag vo HNO3 long. (b) Cr vo HCl long, nng.
(c) Fe vo H2SO4 long ngui (d) Sc kh H2S vo dung dch FeCl2
(e) Cho Na2O vo dung dch K2SO4 (f) Cho Al2O3 vo dung dch KHSO4
Trong cc th nghim trn, s trng hp xy ra phn ng l
A. 2. B. 4. C. 3. D. 5.
Cu 31: Pht biu khng ng l
A. CO2 l th phm chnh ca hin tng bin i kh hu
B. CF2Cl2 l th phm chnh gy thng tng ozon.
C. SO2 l th phm chnh ca hin tng ma axit.
D. Nhin liu ha thch cc nc ang s dng nh than , du m, kh t nhin l nhin liu sch.
Cu 32: Cho cc chuyn ha sau:
xt , t 0
X + H2O Y;
Y + Br2 + H2O Axit gluconic + HBr
Axit gluconic + NaHCO3 Z + Natri gluconat + H2O;
as,clorophin
Z + H2O X + E
Cc cht X v Y ln lt l
A. saccaroz v glucoz. B. tinh bt v glucoz. C. xenluloz v glucoz. D. tinh bt v
fructoz.
Cu 33: Hn hp A gm Fe(NO3)3, Al, Cu v MgCO3. Ha tan 28,4 gam A bng dung dch H2SO4 thu
c dung dch B ch cha 65,48 gam mui v V lt hn hp Z (kc) gm NO, N2O, N2, H2 v CO2
(trong c 0,02 mol H2) c t khi so vi H2 l 16. Cho B tc dng vi lng d BaCl2 thu c 123,49

gam kt ta. Mt khc, nu cho t t NaOH vo B th lng kt ta cc i thu c l 31,92 gam. Gi
tr ca V l :
A. 3,36 lt B. 4,48 lt C. 5,6 lt D. 5,6 lt
Cu 34: Hn hp A gm 3 este mch h, khng phn nhnh c to bi axit propionic, axit oxalic v
hai ancol n chc. t chy hon ton 25,4 gam A cn dng 33,6 lt O2 (kc), thu c 16,2 gam H2O.
Nu cho 25,4 gam A vo dung dch Br2 d th s mol Br2 tham gia phn ng l :
Cu 35: Amino axit X c cng thc H2N- CxHy -(COOH)2. Cho 0,1 mol X vo 0,2 lt dung dch H2SO4
0,5M thu c dung dch Y. Cho Y phn ng va vi dung dch gm NaOH 1M v KOH 3M thu
c dung dch cha 36,7 gam mui. Phn trm khi lng ca nit trong X l :
A. 11,966%. B. 10,687%. C. 10,526% D. 9,524%.
Cu 36: Hn hp X nng m gam gm mantozo v tinh bt. Chia X thnh hai phn bng nhau
-Phn 1 : Ha tan trong nc d, lc ly kt ta ri cho dung dch phn ng ht vi dung dch
AgNO3/NH3 d thu c 0,03 mol Ag
-Phn 2 : un nng vi dung dch H2SO4 long thc hin phn ng thy phn. Hn hp sau phn
ng c trung ha bi dung dch NaOH sau cho ton b sn phm thu c tc dng ht vi
AgNO3/NH3 d thu c 0,192 mol Ag. Bit hiu sut phn ng thy phn t 60%. Gi tr ca m l :
A. 45,9 g B. 35,553 g C. 49,14 g D. 52,38 g
Cu 37: Hn hp X gm 2 aminoaxit no (ch c nhm chc COOH v NH2 trong phn t) trong t
l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt
khc t chy hon ton 3,83 gam hn hp X cn 3,192 lt oxi ktc. Dn ton b sn phm chy gm
CO2, H2O v N2 vo dung dch nc vi trong d th khi lng kt ta thu c l :
Cu 38: un nng a gam mt hp cht hu c X (cha C,H,O) mch khng phn nhnh vi dung dch
cha 11,2 gam KOH n khi phn ng xy ra hon ton, thu c dung dch A, trung ha KOH d
trong dung dch A cn dng 80 ml dung dch HCl 0.5M. Lm bay hi hn hp sau khi trung ha mt
cch cn thn, ngi ta thu c 7,36 gam hn hp hai ancol n chc Y v 18,34 gam hn hp hai
mui Z. Gi tr ca a l
Cu 39: un nng 0,4 mol hn hp E gm ipeptit X, tripeptit Z u mch h bng lng va
dung dch NaOH thu c dung dch cha 0,5 mol mui ca glyxin ;0,4 mol mui ca alanin v 0,2
mol mui ca valin. Mt khc t chy m gam E trong oxi va thu c hn hp CO 2, H2O v N2.
Trong tng khi lng ca CO 2 v H2O l 78,28 gam. Gi tr gn nht ca m l :
A. 55,6 B. 45,1 C. 43,2 D. 33,5
Cu 40: Cho 7,65 gam hn hp X gm Al v Al2O3 (trong Al chim 60% khi lng) tan hon ton
trong dung dch Y gm H2SO4 v NaNO3, thu c dung dch Z ch cha 3 mui trung ha v m gam
hn hp kh T (trong T c 0,015 mol H2). Cho dung dch BaCl 2 d vo Z n khi cc phn ng xy ra
hon ton, thu c 93,2 gam kt ta. Cn nu cho Z phn ng vi NaOH th lng NaOH phn ng
ti a l 0,935 mol. Gi tr ca m gn nht gi tr no sau y :
A. 2,5 B. 3,0 C. 1,0 D. 1,5
----------HT----------

THI TH THPT TIU LA LN 1
Cu 1: Chn C.
A. Fe + AgNO3 Fe(NO3)2 + Ag B. Fe + CuSO4 FeSO4 + Cu
D. Fe + 2FeCl3 3FeCl2
Cu 2: Chn A.
X c 3 ng phn amin bc III l : (CH3)2N-nC3H7, (CH3)2NCH(CH3)2 v CH3NH(C2H5)2.
Cu 3: Chn D.
Cu 4: Chn A.
Nc cng tm thi l nc cha nhiu ion Ca2+, Mg2+ v HCO3-.
Cu 5: Chn B.
C 2 nhn nh ng l (b) v (d).
(a) Sai, Vinyl axetat lm mt mu dung dch brom : CH3COOCH=CH2 + Br2 CH3COOCH(Br)-
CH2(Br)
(c) Sai, Trng hp caprolactam thu c t capron.
(d) Sai, ch c peptit v t lapsan b thy phn trong dung dch NaOH long, un nng.
Cu 6: Chn B.
CH 3COOH C 2 H 5OH
A. CH 3COOC 2 H 5 H 2O
H 2SO 4
C. 2CH 3COOC 2 H 5 Ba(OH) 2

(CH 3COO) 2 Ba 2C 2 H 5OH
D. CH 3COOC 2 H 5 O 2 4CO 2 4H 2O
Cu 7: Chn A.
(1) Sai, cc kh gy ra hiu hng nh knh ch yu l : hi nc, CO2, CH4, N2O, O3 cc kh CFC, CF6
(2) Sai, SO2 v cc kh NxOy l nguyn nhn gy ra hin tng ma axit

Cu 8: Chn A.
900.14
- Khi lng saccaroz l: msaccaroz 126 kg
100
- Khi lng ng ct trng thu c t 1 tn ma cy l: msaccaroz.H% 126.0,9 113, 4 kg
Cu 9: Chn B.
Mg,Fe AgNO3 Mg(NO3)2,Fe(NO3)2 Ag,Fe(d ) 2nMg nAg 2nMg 2nFe 2a c 2a 2b
hn h p cmol dung dch X rn Y
Cu 10: Chn A.
- Ta thc hin php gp sau : C3H4O2 H2O C3H6O3 suy ra hn hp X gm C2H4O2, CH2O v
C3H6O3
- Hn hp X c CTTQ l CnH2nOn v Cn H2n On nO2 nCO2 nH2O
n CO2 n H 2O n O2 0,15 mol VO 3,36 (l)
- T phn ng trn ta c : BTKL 2
m X 44n CO2 18n H 2O 32n O2 m X 4,5(g)
Cu 11: Chn B
t0 1
2Fe(NO3 )2 Fe2O3 4NO2 O2
2
Cu 12: Chn C.
Dung dch X gm KHCO3 v K2CO3 :
Khi cho 100 ml dung dch X tc dng vi 0,15 mol HCl th : nCO32 nHCl nCO2 0,03 (1)

Khi cho 100 ml dung dch X tc dng vi Ba(OH)2 d th :
BT:C
nCO32 nHCO3 nBaCO3 0,2 (2)
T (1) v (2) ta suy ra trong 100 ml dung dch X cha 0,03 mol CO32 v 0,17 mol HCO3 .Vy trong
200 ml dung dch X cha 0,06 mol CO32 v 0,34 mol HCO3 .
BTDT(X)
nK 2nCO32 nHCO3 0,74
BT:C
nK 2CO3 nCO32 (X) nHCO3 (X) nCO2 (sc vo) 0,2
BT:K
nKOH nK 2nK 2CO3 0,34
Cu 13: Chn C.
Khi cho Ba tc dng ln lt vi cc dung dch th c 2 trng hp xut hin kt ta l : K2SO4 v
NaHCO3
Ba H 2O K 2SO 4 BaSO 4 KOH H 2 v Ba 2H 2O 2NaHCO3 Na 2CO3 BaCO3 H 2
Cu 14: Chn B.
4 n
nX,Y (nO2 1,5nCO2 ) 0,06 CM CO2 2 . V s nguyn t C ca anken 2 nn X v Y ln lt
3 nX,Y
l
CH3NH2 v C2H5NH2 (C2H7N).
Cu 15: Chn B.
nCO2 nBaCO3 0,05 m mddgim 100nCaCO3 (44nCO2 18nH 2O ) nH 2O 0,04
BT:C
quan h nCO2 nH2O nCO2 2nH2O

nX 0,01 C : H : 5: 8 X l C5H8O4
CO v H O
2 2 kX 1 nX nX
Cc ng phn m este X c to t ancol 2 chc v axit n chc l
HCOOCH2CH2CH2OOCH , HCOOCH 2CH(OOCH)CH3 v HCOOCH2CH2OOCCH3 ,
Cc ng phn m este X c to t ancol n chc v axit hai chc l
CH3OOC COOC2 H5 v CH3OOCCH2COOCH3 .Vy X c tt c 5 ng phn
Cu 16: Chn A
- Cc este trong X c CTPT l C4H8O2 . Khi t X th :

BT:C
4nC4H8O2 2nC2H5OH nCO2 0,6 nC4H8O2 0,1 0,1.46.100
BT:H %mC2H5OH 34,33
4n 3n n 0,7 n 0,1 0,1(46 88)
C4H8O2 C2H 5OH H 2O C 2 H 5OH
Cu 17: Chn A.

BT:Na
nNaCl nNaOH nNa 0,3 nNaCl 0,14
BT:Cl
nAgCl nNaCl 0,14

58,5nNaCl 40nNaOH 14,59 nNaOH 0,16 nAg2O 0,5nNaOH 0,08
m 143,5nAgCl 232nAg2O 38,65(g)
Cu 18: Chn A.
0
CH 3COOC2H 5 NaOH
t
CH 3COONa C2H 5OH
0,05mol 0,05mol
mCH3COONa 0,05.82 4,1(g)

Cu 19: Chn D.
Cu 20: Chn B.
nCO2
BT:C
nCO2 nCaCO3 1,2 ngluczo 1 mgluczo 180(g)
2H
Cu 21: Chn C.

Ba(AlO2 )2 H 2 (0,12mol)
H 2O
Ba,Al,Fe
Fe,Al
CuSO4
Fe2 ,Al 3 ,SO42 Cu
9,61(g) X rn Y dd sau p 0,11mol
4nBa nH 2 4nBa 0,12 nBa 0,03

BT:e

ton qu trnh
2nBa 3nAl 2nFe 2nH 2 2nCu 2nBa 3nAl 2nFe 0,46 nAl 0,1
137n 27n 56n 9,61 n 0,05
137nBa 27nAl 64nCu mX Ba Al Fe Cu
%mAl 28,09
Cu 22: Chn A.
- C 1 nhn nh ng l (4)
(1) Sai, V NH2-CH2-CH2-COOH l amino axit nn khng th thu c hn hp peptit.
(2) Sai, Anilin khng lm i mu qu tm v cht ch th phenolphtalein.
(3) Sai, Sobitol cha 6 nhm chc OH.
(5) Sai, Khi un nng th iot b gii phng ra khi phn t tinh bt nn lm mt mu xanh tm.
Cu 23: Chn A.
Fe HCl FeCl 2 H 2 . mFeCl 2 0,2.127 25,4(g)
0,2mol 0,2mol
Cu 24: Chn D
- Ti v tr n OH 0,06 th n HCl n HNO3 n OH 0,06
- Ti v tr n Al(OH)3 (max) 0,15 n AlCl3 n Al(OH)3 (max) 0,15
BT:Al
n OH (n HCl n HNO3 ) 0, 288a 0,06

- Ti v tr n OH = 0,288a th n Al(OH)3 (1)
3 3
- Ti v tr n OH 0, 448a th n Al(OH)3 (2) 4n Al3 (n OH n HCl n HNO3 ) 0,6 (0, 488a 0,06)
0, 288a 0, 06
M n Al(OH)3 (1) n Al(OH)3 (2) 0, 6 (0, 488a 0, 06) a 1, 25
3
Cu 25: Chn C.
- Cc ng phn n chc c CTPT C3H6O2 l CH3COOH, HCOOC2H5 v CH3COOCH3.
- X, Z khng tc dng c Na trong phn t X v Z khng c H linh ng (tc l khng c nhm
COOH hoc OH). Mt khc khi thy phn X thu c hp cht hu c c kh nng tham gia phn
ng trng bc. Vy X, Y v Z ln lt l HCOOC 2H5, CH3COOH v CH3COOCH3.
Cu 26: Chn B.
to , p, xt
nCH2 CH CH CH2 CH2 CH CH CH2
n
Buta-1,3-ien Cao su buna
Cu 27: Chn B.
- Kim loi thu c sau phn ng l Ag. Phng trnh phn ng :
Mg + 2AgNO3 Mg(NO3)2 + 2Ag Fe + 2AgNO3 Fe(NO3)2 + 2Ag
- Nu AgNO3 d th Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag
Cu 28: Chn C.
- Este l nhng hp cht hu c m trong phn t c cha nhm chc COO (cacboxylat). Da vo c
im cu to, c 3 cht thuc loi este l : HCOO-CH3, CH3-COOCH=CH2, (COOCH3)2.
Cu 29: Chn A.
BT:C BT:H
- t 9,65 (g) X th nC nCO2 0,4 mol v nH 2nH 2O 1,35 mol

mX 12nC nH
nN 0,25 mol . Trong 19,3 gam X cha 0,5 mol N, khi cho X tc dng vi HCld
14
BTKL
th nHCl(p ) nN 0,5 mol mmui mX 36,5nHCl 37,55(g)
Cu 30: Chn B.
C 5 th nghim xy ra phn ng iu kin thng l (a), (b), (c), (e) v (f).
(a) 3Ag + 4HNO3 (long) 3AgNO3 + NO + 2H2O (b) Cr + 2HCl(long) CrCl2 + H2
(c) Fe + H2SO4(long, ngui) FeSO4 + H2 (d) H2S + FeCl2 : khng xy ra phn ng
(e) Na2O + H2O 2NaOH (f) Al2O3 + KHSO4 Al2(SO4)3 + K2SO4 + H2O
Cu 31: Chn D.
Nhin liu ha thch l cc loi nhin liu c to thnh bi qu trnh phn hy k kh ca cc sinh vt
cht b chn vi cch y hn 300 triu nm.
- Cc nhin liu ha thch l ti nguyn khng ti to bi phi mt hang triu nm to ra chng.
- Vic t nhin liu ha thch to ra khong 21,3 t tn CO2 mi nm, m CO2 l mt trong nhng kh
gy hiu ng nh knh, lm cho nhit trung bnh ca b mt ca tri t tng.
Cu 32: Chn B.
H
C6H10O5 n (X) nH2O nC6H12O6 (Y)
CH2OH[CHOH]4 CHO(Y) Br2 H2O CH2OH[CHOH]4 COOH(axit gluconic) 2HBr
CH2OH[CHOH]4 COOH NaHCO3 CH2OH[CHOH]4 COONa (natri gluconat) CO2 (Z) H2O
6nCO2 (Z) 5nH2O C6H10O5 n (X) .
clorophin,as
Vy X, Y ln lt l tinh bt v glucoz.
Cu 33: Chn B.
0,02mol
Fe(NO3 )3,Al,Cu,MgCO3 NO,N 2O,N 2 , H 2 Fen ,Al 3 ,Mg2 ,Cu2 ,NH 4 ,SO42 H 2O
H 2SO4
28,4(g) A hn h p khZ 65,48(g) B

2
- Khi cho B tc dng vi BaCl2 th
BT:SO4
nH2SO4 nBaSO4 0,53
- Khi cho B tc dng vi NaOH th
BT:Na
nNaOH 2nNa2SO4 1,06 v nNH3 nH2O
BTKL
18nH2O 17nNH3 mB 40nNaOH m 142nNa2SO4 nNH4 nNH3 nH2O 0,02
- Khi cho A tc dng vi H2SO4 th :
2nH 2SO4 4nNH 4 2nH 2

BT:H
nH 2O 0,47
BTKL
mZ mA 98nH 2SO4 mB 18nH 2O 6,4
2
m 6,4
nZ Z 0,2 VZ 4,48(l)
M Z 16.2
Cu 34: Chn C.
m 32nO2 18nH2O m 12nCO2 2nH2O

BTKL
nCO2 A 1,3 nO(A) A 0,5
44 32
nO(A)
- Gi s hn hp ch cha este n chc (ch c to bi axit propionic) nA max 0,25
2
quan h
CO v H O
nA (k A 1) nCO2 nH2O k A 1,6 nBr2 (p max) nA (k A 1) 0,4
2 2
nO(A )
- Gi s hn hp ch cha este hai chc (ch c to bi axit oxalic) nA min 0,125
4
quan h
CO v H O
nA (k A 1) nCO2 nH2O k A 3,2 nBr2 (p min) nA (k A 1) 0,275
2 2
Cu 35: Chn C.

0,1mol 0,1mol x mol 3x mol
2 2
H 2NCx H y (COOH)2 (X) H 2SO4 XH ,H ,SO4
X
NaOH,KOH 2
,SO4 ,Na , K
0,1mol 0,1mol dung dch X 36,7(g) Y
BTDT
(Y )
nNa nK 2nSO42 2nX 2 4x 0,4 x 0,1
13,1
mX 2 mY 96nSO42 39nK 23nNa 13,1 M X 2 131 M X 133 %N 10,52
0,1
Cu 36: Chn C.
nAg
- Xt phn 1 ta c : nmantz 0,015mol
2
- Xt phn 2 ta c :
nAg (4nmantz 2ntinh bt ).H 2nmantz(d ) (4.0,015 2x).0,6 0,015.0,4.2 0,192 x 0,12
Vy m 2(342nmantz 162ntinh bt ) 49,14(g)
Cu 37: Chn B.
- Khi cho 3,83 gam X tc dng vi HCl th : n NH2 nHCl 0,03 mol
mO 80 80mN 80.0,03.14
- Theo bi ta c : nO 0,1mol
mN 21 21.16 21.16
- Khi t chy hon ton 3,83 gam hn hp X th :

BT:O
2nCO2 nH2O nO 2nO2 2nCO2 nH2O 0,385 nCO2 0,13mol

12nCO2 2nH 2O mX 16nO mN
12nCO2 2nH 2O 1,81 nH 2O 0,125mol
- Dn sn phm chy vo nc vi trong d th : nCaCO3 nCO2 0,13mol mCaCO3 13(g)
Cu 38: Chn D.
- Xt ton b qu trnh phn ng ta c : nH2O nHCl 0,04mol
BTKL
mX mmui mancol 18nH2O 36,5nHCl mKOH 13,76(g)
Cu 39: Chn D.
- Quy i 0,4 mol hn hp E thnh C2H3ON, -CH2 v H2O, khi :
nC2H3ON nGly nAla nVal 1,1 mol , nCH2 nAla 3nVal 1 mol v nH2O nE 0,4mol
Vy khi lng ca 0,4 mol E l : mE 57nC2H3ON 14nCH2 18nH2O 83,9(g)
- Khi t chy 0,4 mol E th :
44nCO2 18nH2O 195,7(g)
nCO2 2nC2H3ON nCH2 3,2
mCO2 ,H2O(khi t m gam E) 78,28 2 m
nH2O 1,5nC2H3ON nCH2 nH2O 3,05 m m E 33,56(g)
CO2 ,H2O (khi t 0,4 mol E) 195,7 5 2,5
Cu 40: Chn D.
Al 3 ,Na ,NH 4 ,SO42 N x Oy ,H 2 H 2O
Al,Al 2O3 NaNO3,H 2SO4
7,65(g) hn h p X dung dch Y dung dch Z m (g) khT
- Khi cho dung dch Z tc dng vi BaCl2 d th : n H2SO4 n BaSO4 0, 4 mol

- Xt qu trnh hn hp X tc dng vi dung dch Y ta c :
m 27n Al
+ n Al (trong X) 0,17 mol n Al2O3 X 0, 03mol BT:Al
n Al3 (trong Z) n Al 2n Al2O3 0, 23mol
102
+ Khi dung dch Z tc dng vi 0,935 mol NaOH th :
2n H 2SO4 2n H 2 4n NH 4
n NH 4 n NaOH 4n Al3 0, 015mol
BT:H
n H 2O 0,355mol
2

BTDT
(Z)
n Na 2n SO42 n NH4 3n Al3 0,095mol m Z 23n Na 27n Al3 18n NH4 96n SO42 47,065(g)
BTKL
m T m X 98n H 2SO 4 85n NaNO3 18n H 2O m Z 1, 47 (g) .

TNH BNH PHC Mn: KHOA HC T NHIN HA HC
THPT PHC LONG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi un nng cht X c cng thc phn t C5H10O2 vi dung dch NaOH thu c
C2H5COONa v ancol Y. Y c tn l
A. Kt ta mu tm B. Dung dch mu xanh
C. Kt ta mu vng D. Kt ta mu trng
Cu 3: Cho dy cc cation kim loi :Ca , Cu , Na , Zn2+ .Cation kim loi no c tnh oxi ha mnh
2+ 2+ +
nht trong dy
A. Theo chiu tng dn ca in tch ht nhn,nhit nng chy ca kim loi kim gim dn
Cu 5: Cho s sau :
0
HCl (d )
Vy X2 l :
A. ClH3N-CH2COOH B. H2N-CH2-COOH
C. H2N-CH2-COONa D. H2N-CH2COOC2H5
u in phn)
Cu 9: Hp cht H2N-CH2-COOH phn ng c vi : (1) NaOH, (2) HCl, (3) C2H5OH, (4) HNO2
A. (1), (2), (3), (4) B. (2), (3), (4) C. (1), (2), (4) D. (1), (2), (3)
Cu 10: Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v khi lng.Cho
A. Tch nc Y ch thu c 1 anken duy nht B.Tn thay th ca Y l propan-2-ol
C.Phn t X c mch cacbon khng phn nhnh D.Trong phn t X c 1 lin kt bi
Cu 11: Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l

b l :
A. a = 0,75b. B. a = 0,8b. C. a = 0,35b. D. a = 0,5b.
l :
A. 20,8 B. 18,6 C. 22,6 D. 20,6
Cu 18: Thy phn 44 gam hn hp T gm 2 este cng cng thc phn t C 4H8O2 bng dung dch
KOH d. Chng ct dung dch sau phn ng thu c hn hp ancol Y v cht rn khan Z. un nng
Y vi H2SO4 c 1400C, thu c 14,3 gam hn hp cc ete. Bit cc phn ng xy ra hon ton.
Khi lng mui trong Z l
A. 27,25%. B. 62,40%. C. 72,70%. D. 37,50%.
Cu 20: Cht X c cng thc phn t C 3H4O2, tc dng vi dung dch NaOH thu c CHO 2Na. Cng
thc cu to ca X l
A. HCOO-C2H5. B. CH3-COOH. C. CH3-COO-CH3. D. HCOO-C2H3.
Cu 21: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l
A. HCOOCH3, C2H5OH, HCOOH, CH3COOH. B.CH3COOH, HCOOH, C2H5OH, HCOOCH3.
C. CH3COOH, C2H5OH, HCOOH, HCOOCH3. D.HCOOH, CH3COOH, C2H5OH, HCOOCH3.
Cu 23: Cho cc cht sau: HCl, AgNO3, Cl2, KMnO4/H2SO4 long, Cu. S cht tc dng c vi dung
dch Fe(NO3)2 l
A. 3. B. 2. C. 5. D. 4.
trong X l
A. 50,51%. B. 25,25%. C. 43,26%. D. 37,42%.

A. 4. B. 6. C. 5. D. 3.
A. 5. B. 3. C. 4. D. 2
(1) Nung hn hp Fe v KNO3 trong kh tr. (2) Cho lung kh H2 i qua bt CuO nung nng.
(3) t dy Mg trong bnh kn cha y SO2. (4) Nhng dy Ag vo dung dch HNO3
S th nghim xy ra phn ng oxi ha kim loi:
A. 1. B. 4. C. 2. D. 3.
Cu 30: Hn hp X gm a mol Al v b mol Na. Hn hp Y gm b mol Al v a mol Na. Thc hin 2 th
nghim sau. Th nghim 1: Ha tan hn hp X vo nc d thu c 5,376 lt kh H2, dung dch X1 v m
gam cht rn khng tan. Th nghim 2: Ha tan hn hp Y vo nc d thu c dung dch Y1 trong
khi lng NaOH l 1,2 gam. Bit th tch kh o ktc. Tng khi lng Al trong hn hp X v Y l
Cu 31: Chia dung dch hn hp X gm Al2(SO4)3 v Fe2(SO4)3 thnh hai phn bng nhau. Phn mt ha
tan va ng 2,56 gam bt Cu. Phn hai tc dng vi 200 ml dung dch Ba(OH)2 1M, thu c 50,5 gam
kt ta. Cc phn ng xy ra hon ton. T l mol gia Al2(SO4)3 v Fe2(SO4)3 trong dung dch hn hp
X l
A. 1 : 1. B. 1 : 2. C. 1 : 3. D. 1 : 4.
Cu 32: Nhit phn mui amoni icromat: (NH4)2Cr2O7 thu c sn phm l
A. Cr2O3, N2, H2O B. Cr2O3, NH3, H2O C. CrO3, N2, H2O D. CrO3, NH3, H2O
Cu 33: un nng triglyxerit X vi dung dch NaOH va thu c dung dch Y cha 2 mui natri ca
axit stearic v oleic. em c cn dung dch Y thu c 54,84 gam mui. Bit X lm mt mu va
dung dch cha 0,12 mol Br2. Phn 2. Khi lng phn t ca X l
A. 886 B. 888 C. 884 D. 890
Cu 34: Aminoaxit X (CnH2n+1O2N), trong phn trm khi lng cacbon chim 51,28%. Gi tr ca n
l
A. 2 B. 3 C. 5 D. 4
Cu 35: Cht no sau y tc dng vi tripanmitin
A. H2. B. Dung dch NaOH. C. Dung dch Br2. D. Cu(OH)2.
Cu 36: Cho 5,6 gam Fe vo 200 ml dung dch Cu(NO3)2 0,5M v HCl 1,2 M thu c kh NO v m
gam kt ta. Xc nh m. Bit rng NO l sn phm kh duy nht ca NO3- v khng c kh H2 bay ra
A. 0,64 B. 2,4 C. 0,32 D. 1,6
Cu 37: phn bit cc dung dch glucoz, saccaroz v h tinh bt c th dng dy cht no sau
y lm thuc th ?
Cu 38: Cho 35 gam hn hp cc amin gm anilin, metylamin, imetylamin, imetylmetylamin tc
dng va vi 300ml dung dch HCl 1M. Khi lng mui khan thu c sau phn ng l:

Cu 39: Nhng phn ng ha hc ln lt chng minh rng phn t glucoz c nhm chc CHO
v c nhiu nhm OH lin k nhau l:
A. Phn ng trng gng v phn ng ln men ru.
B. Phn ng trng gng v phn ng vi Cu(OH) 2 nhit phng cho dung dch mu xanh
lam.
C. Phn ng to phc vi Cu(OH) 2 v phn ng ln men ru.
D. Phn ng ln men ru v phn ng thy phn.
Cu 40: Ly 0,3 mol hn hp X gm H2NC3H5(COOH)2 v H2NCH2COOH cho vo 400 ml dung
dch HCl 1M th thu c dung dch Y. Y tc dng va vi 800 ml dung dch NaOH 1M thu c
dung dch Z. Lm bay hi Z thu c m gam cht rn khan. Gi tr ca m l:
A. 61,9 B. 28,8 C. 52,2 D. 55,2
----------HT----------

THI TH THPT PHC LONG LN 1
Cu 1: Chn A.
0
C2H 5COOC2H 5 NaOH
t
C2H 5COONa C2H 5OH
Cu 2: Chn C.
Cu 3: Chn B.
Tnh oxi ha gim dn theo dy : Cu2+ > Zn2+ > Ca2+ > Na+
Cu 4: Chn B.
A. ng, Theo chiu tng dn in tch ht nhn,nhit nng chy ca kim loi kim gim dn
B. Sai, Mg tc dng vi nc nhit cao, Be khng tc dng vi nc mi iu kin nhit .
C. ng, Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh
D. ng, Thc t, cc son ni lm bng nhm c 1 lp oxit Al 2O3 bn ngn cn khng cho Al tip
xc vi H2O. iu ny cng xy ra tng t vi Cr v Zn.
Cu 5: Chn A.
NH2CH2COOC2H5 (X) + NaOH H2N-CH2-COONa (X1) + C2H5OH
H2N-CH2-COONa (X1) + HCl ClH3N-CH2-COOH (X2) + NaCl
ClH3N-CH2-COOH (X2) + CH3OH ClH3N-CH2-COOCH3 (X3) + H2O
Cu 6: Chn C.
Ag,Cu :hn h p rn Y
Zn,Fe AgNO3,Cu(NO3 )2 Zn2 ,Fe2 ,Cu2 ,NO3 NaOH
- Vy dung dch Z chc Zn(NO3)2, Fe(NO3)2 v Cu(NO3)2
Cu 7: Chn C.
Cu 8: Chn C.
Ti catot Ti anot
H2 O + 2e 2OH- + H2 H2O 4H+ + O2 + 4e

Cu 9: Chn A.
H2N-CH2-COOH + NaOH H2N-CH2-COONa + H2O
H2N-CH2-COOH + HCl ClH3N-CH2-COOH

H
050 C
Cu 11: Chn D.
Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l nhng kim
loi hot ng mnh nh kim loi kim, kim th v nhm.
Cu 12: Chn D.
A. ng, bn cht ca enzim l nhng cht hu cht c bn cht protein
050 C
C. ng, Phc ng saccarozo c cng thc l (C 12H21O11)2Cu
2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + 2H2O
D. Sai, peptit c chia thnh hai loi :
Cu 13: Chn A.
Cu 14: Chn B.
BT:e

Cu 15: Chn A.
nHCl
2
nCO2 (1) V 1 ba 1
nCO2 (2) 2V 2 0,5b 2
Cu 16: Chn C.
800.0,05
160
Cu 17: Chn A.
0
t
GlyNa AlaNa H 2O
Cu 18: Chn A.
- un nng hn hp Y vi H2SO4 th : nH2O 0,5nT 0,25mol
BTKL
mY mete 18nH2O 18,8(g)
- T tc dng vi NaOH th
BTKL
mZ mT 40nNaOH mY 53,2(g) (v i nNaOH nT 0,5mol)
Cu 19: Chn D
12 12
22,32 2.0,8 16(4nX nY )
12
- Xt hn hp M ta c :
BT:C
anX bnY nCO2 0,12a 0,14b 0,9 a 4 v b=3
0,14.60
%mC3H7OH(Y ) .100 37,63
22,32
Cu 20: Chn D.
0
HCOOCH CH 2 (C3H 4O2 ) NaOH
t
HCOONa CH 3CHO
Cu 21: Chn A.
Cu 22: Chn C.
Cu 23: Chn D.
C 4 cht tc dng c vi Fe(NO3)2 l HCl, AgNO3, Cl2 v KMnO4/H2SO4 long. PT phn ng :
3Fe2 4H NO3 3Fe3 NO 2H2O
Fe(NO3)2 + AgNO3 Fe(NO3)3 + Ag.
6Fe(NO3)2 + 3Cl2 4Fe(NO3)3 + 2FeCl3

10Fe(NO3)2 + 2KMnO4 + H2SO4 Fe(NO3)3 + Fe2(SO4)3 + K2SO4 + 2MnSO4 + H2O
Cu 24: Chn A.
a 2b 0,4 a 0,2

97a 191b 38,5 b 0,1
75nGly
%mGly .100 50,51
75nGly 147nGlu
Cu 25: Chn B.
- Ta c: v
Vy s cp (X, Y) tha l: 3.2 = 6
Cu 26: Chn A.
Cu 27: Chn D.
Hn hp Na2O v Al2O3:
1 mol 0,5 mol
1 mol 1 mol
1 mol 1 mol
1 mol 1 mol
Cu 28: Chn B.
- Hng t duy 1:
Fe + 2AgNO3
Fe(NO3)2 + Cu
mol: x 2x y y

,NO3
NaOH
m (g)X dung dch X

Theo m gam
56(x y) m (1) m
xy
Theo a gam 56
+ Ta c h sau: 90(x + y) 98(t y) a (2)
(1), (3)

Theo b gam t y b m
80(x + y) 80(t y) b (3)

80 56
- Hng t duy 2:
m m 45
BT: Fe
56 112 28
10 49b 70m
m Cu(OH) 2 gam
7 40
45m 49b 70m
28 40
Cu 29: Chn D.
- Cc phn ng xy ra:
to
(1) Nng nng KNO3: 2KNO3 2KNO2 O2 sau Fe tc dng vi O 2:
to
3Fe 2O2 Fe3O4
o
t
(2) H 2 CuO Cu H 2O : phn ng kh oxit kim loi.
(3) 2Mg SO2
2MgO S
(4) 3Ag 4HNO3
3AgNO3 NO 2H 2O
Vy c 3 phn ng oxi ha kim loi l (1), (3) v (4).
Cu 30: Chn C.
amol bmol
H 2O n H2
- Th nghim 1: Al , Na X 1 H 2 Al d . Ta c: n Na b 0,12 mol
2
hn h p X 0,24 mol m gam
0,12mol amol 0,03mol 0,12mol
H 2O BT: Na
- Th nghim 2: Al , Na NaOH ,NaAlO2 . Khi :
a 0,15 mol
dung dch Y dung dchY2
m Al 27.(a b) 7, 29 gam
Cu 31: Chn B.
- Gi x l s mol ca Al2(SO4)3 n Al3 2x mol
- Phn 1: ha tan va ng vi 0,04 mol Cu n Cu n Fe2 (SO4 )3 0,04 mol
- Phn 2: tc dng vi 0,2 mol dung dch Ba(OH)2 thu c kt ta gm:
Fe(OH)3: Nhn thy 3n Fe3 n OH n Fe(OH)3 0, 08 mol m Fe(OH)3 8,56 (g)
BaSO4: Nu n BaSO 4 n Ba 2 0, 2 mol m BaSO 4 m Fe(OH)3 50,5 gam
nSO24 3(n Al2 (SO4 )3 n Fe2 (SO4 )3 ) 3x 0,12 mBaSO4 699x 27,96 (g)
Al(OH)3: Xt trng hp to kt ta ca Al(OH)3 (vi n OH cn li = 0,16 mol)

- Trng hp 1: Al(OH)3 khng b ha tan.
+ Khi 3n Al3 6x n OH 0,16 x 0, 0267 m nSO24 3x 0,12 0, 2 x 0,0267 (v l)
+ Khi : n Al(OH)3 4n Al3 n OH 8x 0,16 m Al(OH)3 624x 12, 48 (g)
n Al2 (SO4 )3 1
m m Fe(OH)3 m BaSO4 m Al(OH)3 50,85 x 0,02 mol . Vy
n Fe 2 (SO4 )3 2
Cu 32: Chn A.
to
- Nhit phn mui amoni icromat: (NH4)2Cr2O7 Cr2O3 + N2 + 4H2O
Cu 33: Chn A.
- Gi s triglyxerit X c to ra t 1 gc axit stearic v 2 gc axit oleic. Trong phn t ca X lc ny
cha 2 lin kt C=C.
n Br2
- Khi cho X tc dng vi dung dch Br2 th: n X 0, 06 mol
2
NaOH n C17H33COONa 2n X 0,12 mol
- Khi cho X mmui = 54,84 gam (tha yu cu bi ton)
n C17H35COONa n X 0, 06 mol
- Nu nh trng hp trn khng tha thi ta suy ra trng hp cn li l X c to ra t 2 gc axit
stearic v 1 gc axit oleic. Khi MX = 888
Vy M X 886 .
Cu 34: Chn C.
12n
- Ta c: %C 0,5128 n 5
14n 47
Cu 35: Chn B.
- Tripanmitin c cng thc (C15H31COO)3C3H5 tham gia phn ng thy phn trong mi trng axit v
kim.
(C15H31COO)3C3H5 + 3NaOH
3C15H31COONa + C3H5(OH)3
Cu 36: Chn A.
S oxi ha S kh
Fe Fe + 2e
2+
3e + 4H + NO3 NO + 2H2O ;
+ -
Cu2+ + 2e Cu
0,1 0,2 0,18 0,24 0,01 0,1 0,2
(v sau phn ng c cht rn nn Fe
chuyn ln Fe2+).
2n Fe 3n NO
- Nhn thy: ne nhn > ne cho nCu p = = 0,01 mol mrn = mCu p = 0, 64 (g)
2
Cu 37: Chn B.
Thuc th Glucoz Saccaroz H tnh bt
AgNO3/NH3 Kt ta trng bc Khng hin tng Khng hin tng
Cu 38: Chn B.
BTKL
mmui khan mamin 36,5nHCl 45,95(g)
Cu 39: Chn B.
Tnh cht ca ancol a chc (poliancol hay poliol):
- Dung dch glucoz ha tan Cu(OH)2 cho dung dch phc ng glucoz c mu xanh lam
2C6H12O6 + Cu(OH)2
(C6H11O6)2Cu + 2H2O
Tnh cht ca anehit:
- Vi dung dch AgNO3 trong NH3, un nng (thuc th Tollens) cho phn ng trng bc.

to
Cu 40: Chn A.
- Xt ton b qu trnh phn ng ta c
2nA nB nNaOH nHCl 2nA nB 0,4 nB 0,2mol
- Khi cho dung dch Y tc dng vi NaOH th nH2O nNaOH 0,8mol
BTKL
mrn khan 147nA 75nB 36,5nHCl 40nNaOH 18nH2O 61,9(g)

TNH BC GIANG Mn: KHOA HC T NHIN HA HC
THPT NH NAM Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Dung dch no sau y lm mm tnh cng ca nc cng vnh cu ?

A. NaHCO3 B. Ca(OH)2 C. HCl D. Na2CO3
Cu 2: Dung dch no sau y lm qu tm ha xanh?
A. anilin B. alanin C. metylamin D. axit glutamic
Cu 3: Cht no sau y khng tc dng vi dung dch Br2?
A. alanin B. triolein C. anilin D. glucoz
Cu 4: un nng xenluloz trong dung dch H 2SO4 long, sn phm thu c l?
A. saccaroz B. amiloz C. glucoz D. fructoz
Cu 5: Sc 0,15 mol kh CO2 vo 200 ml dung dch Ba(OH) 2 1M, sau khi kt thc phn ng, thu
c m gam kt ta. Gi tr m l.
Cu 6: Cho dy cc cht: tristearin, phenylamoni clorua, imetylamin, metyl axetat, alanin, amoni
fomat. S cht trong dy tc dng vi dung dch NaOH un nng l.
A. 4 B. 2 C. 5 D. 3
Cu 7: Cho cc dung dch long: (1) AgNO 3, (2) FeCl2, (3) HNO3, (4) FeCl3, (5) hn hp gm
NaNO3 v HCl. S dung dch phn ng c vi Cu l.
A. 2 B. 5 C. 3 D. 4
A. Cc hp kim nh, bn, chu c nhit cao v p sut ln c dng ch to tn la.
B. Dung dch natri cacbonat dng ty sch vt du m bm trn chi tit my.
C. Dung dch natri cacbonat c dng lm mm tnh cng ca nc cng tm thi.
D. Trong t nhin, cc kim loi kim tn ti di dng n cht.
Cu 9: trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung
dch HCl 1M. Cng thc phn t ca X l
A. C3H5N. B. C2H7N. C. C3H7N. D. CH5N.
Cu 10: Cho 5,6 gam Fe vo 200 ml dung dch cha HNO3 4M v H2SO4 2M thu c dung dch X v
kh NO. X c th ho tan ti a m gam Cu. Bit NO l sn phm kh duy nht ca NO3-. Gi tr ca m l
Cu 11: Hp cht no sau y thuc loi ipeptit
A. H2N-CH2CO-NH-CH(CH3)-COOH. B. H2N-CH2-NH-CH2COOH.
C. H2N-CH2-CH2-CO-NH-CH2-CH2-COOH. D. H2N-CH2-CH2-CO-NH-CH2-COOH.
Cu 12: Cho cc pht biu sau :
(a) T nilon-6,6 c iu ch t hexametyleniamin v axit axetic.
(d) Cc este ch c iu ch t axit cacboxylic v ancol.
(c) Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
(d) Anilin phn ng vi axit HCl to ra mui phenylamoni clorua.
(e) Trong phn t amilopectin cc mc xch glucz ch c ni vi nhau bi lin kt 1,6
gliczit
S nhn nh khng ng l :
A. 3 B. 2 C. 5 D. 1

Cu 13: Cho a mol Ba vo dung dch cha 2a mol Na2CO3, thu c dung dch X v kt ta Y. Nhit
phn hon ton kt ta Y, ly kh sinh ra sc vo dung dch X, thu c dung dch Z. Cht tan c trong Z
l.
A. Ba(HCO3)2 v NaHCO3 B. Na2CO3
C. NaHCO3 D. NaHCO3 v Na2CO3
Cu 14: Khi cho Na d vo dung dch Fe2(SO4)3, FeCl2 v AlCl3 th c hin tng xy ra c 3 cc l :
A. c kt ta B. c kh thot ra C. c kt ta ri tan D. khng hin
tng
Cu 15: Ha tan hon ton 6,48 g Mg bng dung dch X cha NaNO3 v HCl va n khi phn ng
xy ra hon ton thu c dung dch Y cha m gam mui clorua v 3,584 l hn hp Z gm 2 kh (c mt
kh ha nu trong khng kh) c t khi so vi H2 l 13,25. Gi tr ca m l :
Cu 16: Th nghim ha hc khng sinh ra cht kh l:
A. Cho kim loi Ba vo dung dch CuSO 4. B. Nhit phn hon ton KMnO 4
C. Sc kh H2S vo dung dch CuSO4. D. Cho Na2CO3 vo lng d dung dch H2SO4
Cu 17: Cho Mg vo dung dch cha FeSO4 v CuSO4. Sau phn ng thu c cht rn X ch c 1 kim
loi v dung dch Y cha 2 mui. Phn ng kt thc khi :
A. CuSO4 v FeSO4 ht v Mg d B. FeSO4 d, CuSO4cha phn ng, Mg ht.
C. CuSO4 ht, FeSO4 cha tham gia phn ng, Mg ht. D. CuSO4 d, FeSO4 cha phn ng, Mg
ht.
Cu 18: iu khng nh no sau y l sai :
A. un nng nc cng tm thi thy kh khng mu thot ra.
B. Cho CrO3 vo lng d dung dch NaOH thu c dung dch c cha hai mui.
C. Tnh cht vt l chung ca kim loi l tnh do, tnh dn in, dn nhit v tnh nh kim.
D. Cu c th tan trong dung dch hn hp NaNO3 v HCl
Cu 19: Hn hp X cha hai este u n chc (trong phn t ch cha mt loi nhm chc). un
nng 0,15 mol X cn dng 180 ml dung dch NaOH 1M, chng ct dung dch sau phn ng thu c
ancol etylic v 14,1 gam hn hp Y gm ba mui. Phn trm khi lng ca este c khi lng phn
t ln trong hn hp X l.
A. 84,72% B. 23,63% C. 31,48% D. 32,85%
Cu 20: Tin hnh in phn dung dch cha NaCl 0,4M v Cu(NO 3)2 0,5M bng in cc tr, mng
ngn xp vi cng dng in khng i I = 5A trong thi gian 8492 giy th dng in phn,
anot thot ra 3,36 lt kh (ktc). Cho m gam bt Fe vo dung dch sau in phn, kt thc phn ng,
thy kh NO thot ra (sn phm kh duy nht ca N +5) v 0,8m gam rn khng tan. Gi tr ca m l.
(1) iu kin thng, trimetylamin l cht kh, tan tt trong nc.
(2) trng thi tinh th, cc amino axit tn ti di dng ion lng cc.
(3) Lc baz ca cc amin u mnh hn amoniac.
(4) Oligopeptit gm cc peptit c t 2 n 10 gc - amino axit v l c s to nn protein.
(5) Anilin lu ngy trong khng kh c th b oxi ha v chuyn sang mu nu en.
(6) Cc amino axit c nhit nng chy cao, ng thi b phn hy.
S nhn nh ng l.
A. 5 B. 4 C. 6 D. 3
Cu 22: Hn hp X gm mt axit cacboxylic hai chc, no, mch h, hai ancol no n chc k tip nhau
trong dy ng ng v mt ieste to bi axit v 2 ancol . t chy hon ton 4,84 gam X thu c
7,26 gam CO2 v 2,70 gam H2O. Mt khc, un nng 4,84 gam X trn vi 80 ml dung dch NaOH 1M,
sau khi phn ng xy ra hon ton thm va 10 ml dung dch HCl 1M trung ha lng NaOH d
thu c dung dch Y. C cn dung dch Y thu c m gam mui khan, ng thi thu c 896 ml hn
hp ancol (o ktc) c t khi hi so vi H2 l 19,5. Gi tr ca m l:

Cu 23: Dung dch FeSO4 b ln CuSO4. Phng php n gin loi tp cht l:
A. Cho dung dch NH3 cho n d vo dung dch, lc ly kt ta Fe(OH)2 ri ha tan vo dung dch
H2SO4 long.
B. Cho mt l nhm vo dung dch.
C. Cho l ng vo dung dch.
D. Cho l st vo dung dch.
X to vi dung dch iot hp cht c mu xanh tm. Polime X l
A. tinh bt. B. xenluloz. C. saccaroz. D. glicogen.
lng glucoz cn dng l
A. Cho dung dch Ca(OH)2 tc dng vi dung dch Na2CO3.
B. in phn dung dch NaCl c mng ngn xp, in cc tr.
C. Sc kh NH3 vo dung dch Na2CO3.
D. Cho Na2O tc dng vi nc.
Cu 30: in phn 200 ml dung dch CuSO4 0,75M bng in cc tr vi cng dng in khng i
I = 5A, n khi khi lng dung dch gim 13,35 gam th dng in phn. Thi gian in phn l ?
Cu 31: Cho 17,64 gam axit glutamic vo 200 ml dung dch NaOH 1M, c cn dung dch sau phn
ng thu c m gam rn khan. Gi tr m l.
Cu 32: X l tripeptit, Y l tetrapeptit v Z l hp cht c CTPT l C 4H9NO4 (u mch h). Cho 0,2
mol hn hp E cha X, Y, Z tc dng hon ton vi dung dch cha 0,59 mol NaOH (va ). Sau
phn ng thu c 0,09 mol ancol n chc; dung dch T cha 3 mui (trong c mui ca Ala v
mui ca mt axit hu c no, n chc, mch h) vi tng khi lng l 59,24 gam. Phn trm khi
lng ca X trong E l:
A. 16,45% B. 17,08% C. 32,16% D. 25,32%
Cu 33: Ha tan ht 15,0 gam hn hp X gm Fe, Fe3O4, FeCO3 v Fe(NO3)2 trong dung dch cha
NaHSO4 v 0,16 mol HNO 3, thu c dung dch Y v hn hp kh Z gm CO2 v NO (t l mol
tng ng 1 : 4). Dung dch Y ha tan ti a 8,64 gam bt Cu, thy thot ra 0,03 mol kh NO. Nu
cho dung dch Ba(OH)2 d vo Y, thu c 154,4 gam kt ta. Bit cc phn ng xy ra hon ton v
kh NO l sn phm kh duy nht ca c qu trnh. Phn trm khi lng ca Fe n cht trong hn
hp X l:
A. 48,80% B. 33,60% C. 37,33% D. 29,87%
Cu 34: Ba dung dch A, B, C tha mn:
- A tc dng vi B thu c kt ta X, cho X vo dung dch HNO3 long d, thy thot ra kh khng
mu ha nu ngoi khng kh; ng thi thu c kt ta Y.
- B tc dng vi C thy kh thot ra, ng thi thu c kt ta.
- A tc dng C thu c kt ta Z, cho Z vo dung dch HCl d, thy kh khng mu thot ra.
A, B v C ln lt l.
A. CuSO4, Ba(OH)2, Na2CO3. B. FeCl2, AgNO3, Ba(OH)2
C. NaHSO4, Ba(HCO3)2, Fe(NO3)3. D. FeSO4, Ba(OH)2, (NH4)2CO3.

Cu 35: Nung hn hp gm m gam Al v 0,04 mol Cr2O3 mt thi gian, thu c hn hp rn X. Ha
tan hon ton X trong dung dch HCl c, nng, va (khng c khng kh) thu c 0,1 mol kh H 2
v dung dch Y. Y phn ng ti a vi 0,56 mol NaOH (bit cc phn ng xy ra trong iu kin khng
c khng kh). Gi tr m l:
A. 1,62. B. 2,16. C. 2,43. D. 3,24.
Cu 36: Dung dch no di y lm xanh qu m ?
A. Glyxin (H2NCH2COOH). B. Anilin (C6H5NH2).
C. Lysin ( (H2N)2C5H9COOH). D. Axit glutamic (H2NC3H5(COOH)2).
Cu 37: Cho m gam hn hp X gm metylamin v etylamin tc dng va vi 0,2 mol HCl , sau
phn ng thu c 14,9 gam mui. Gi tr m l:
A. 8,2. B. 10,7. C. 12,1. D. 7,6.
Cu 38: Loi t khng phi t tng hp l
A. t capron. B. t clorin. C. t polieste. D. t axetat.
Cu 39: un nng 18 gam glucoz vi dung dch AgNO 3/NH3 d th thu c m gam Ag. Gi tr ca
m l :
A. 7,20. B. 2,16. C. 10,8. D. 21,6.
Cu 40: Cho dung dch cha a mol Ba(HCO 3)2 tc dng vi dung dch c cha a mol cht tan X.
thu c khi lng kt ta ln nht th X l:
A. Ba(OH)2. B. H2SO4. C. Ca(OH)2 . D. NaOH.
----------HT----------

THI TH THPT NH NAM LN 1
Cu 1: Chn D.
- Nguyn tc lm mm nc cng l lm gim nng ion Ca2+, Mg2+. C 2 phng php chnh lm
mm nc cng l:
Cu 2: Chn C.
Cu 3: Chn A.
Cu 4: Chn C.
H 2O
- Phn ng: (C6H10O5)n C6H12O6 (glucoz)
H
Cu 5: Chn A.
n
- Nhn thy: OH 2 n BaCO3 n CO2 0,15 mol m BaCO3 29,55 (g)
n CO2
Cu 6: Chn C.
- C 5 cht tha mn l: tristearin, phenylamoni clorua, metyl axetat, alanin, amoni fomat.
Cu 7: Chn D.
- C 4 cht tha mn l: (1) AgNO 3, (3) HNO3, (4) FeCl3, (5) hn hp gm NaNO 3 v HCl
- Phng trnh:
Cu + 2AgNO3
Cu(NO3)2 + 2Ag
3Cu + 8HNO3
3Cu(NO3)2 + 2NO + 4H2O
Cu + 2FeCl3
CuCl2 + 2FeCl2
3Cu + 8H+ + 2 NO3 3Cu2+ + 2NO + 4H2O
Cu 8: Chn D.
D. Sai, Kim loi kim c tnh kh mnh d b oxi ha bi cc cht oxi ha c sn trong thin nhin v
vy trong t nhin kim loi kim tn ti di dng hp cht.
Cu 9: Chn D.
C mX 25.0,124 3,1 v nHCl nX 0,1 M X 31(CH3NH2 )
Cu 10: Chn C.
S oxi ha S kh
Fe Fe2 2e 4H NO3 3e NO 2H 2O
0,1mol 0,2mol 1,6mol 0,8mol 1,2mol 0,4mol
2
Cu Cu 2e
amol 2a
2nFe 2a 3nNO a 0,5 mCu 32(g)

BT:e
Cu 11: Chn A.
Peptit c to thnh t cc amino axit, vy H2N-CH2CO-NH-CH(CH3)-COOH l ipeptit v c
to t cc amino axit l NH2CH2COOH (glyxin), NH2CH(CH3)COOH (alanin).
Cu 12: Chn D.
(a) Sai, T nilon-6,6 c iu ch t hexametyleniamin v axit aipic
(b) Sai, Cc este c th c iu ch t anhiric axit v ancol (hoc phenol v ng ng)
(c) Sai, Cc hp cht peptit u km bn trong mi trng axit v baz
(d) ng, C6H5NH2 + HCl C6H5NH3Cl (phenylamoni clorua)
(e) Sai, Trong phn t amilopectin cc mc xch glucz c ni vi nhau bi lin kt 1,6
gliczit v 1,4 gliczit.
Cu 13: Chn B

t0
BaCO3(Y) BaO CO2
amol amol
Ba H 2O Na2CO3 dung dch X dung dch Z
amol 2amol CO2
Na2CO3 NaOH
Na2CO3
amol 2amol 2amol
Cu 14: Chn B.
Fe 2 (SO 4 )3 6Na 6H 2O
2Fe(OH) 3 3Na 2SO 4 3H 2
FeCl 2 2Na 2H 2O
Fe(OH) 2 Na 2SO 4 H 2
AlCl3 4Na 2H 2O NaAlO 2 3NaCl 2H 2
T PT phn ng ta nhn thy c 3 PT trn u c kh H2 thot ra
Cu 15: Chn B.
0,14mol 0,02mol
2
Mg NaNO3,HCl Na ,Mg ,NH 4 ,Cl NO , H 2 H 2O
dung dch hn h p dung dch Y hn h p khZ
2nMg 3nNO 2nH 2 nHCl 4nNO 2nH 2 10nNH 4 0,7

BT:e
nNH 4 0,01 BT:N
8 nNaNO3 nNO nNH 4 0,15
mY 23nNa 24nMg2 18nNH 4 35,5nCl 34,96(g)
Cu 16: Chn C.
A. Ba 2H 2O CuSO 4 Cu(OH) 2 BaSO 4 H 2
o
t
B. 2KMnO 4 K 2 MnO 4 MnO 2 O 2
C. H 2S CuSO 4
CuS H 2SO 4
D. Na 2CO3 H2SO4 Na 2SO4 CO2 H2O
Cu 17: Chn C.
Ch xy ra mt phn ng sau : Mg + CuSO4 MgSO4 + Cu.
Cu 18: Chn B.
Cu A. ng, nc cng tm thi c cha Mg(HCO3)2 v Ca(HCO3)2. Khi un nng nc cng tm thi
0 0
th : Mg(HCO3 ) 2 t
MgCO3 CO 2 2H 2O Ca(HCO3 ) 2 t
CaCO3 CO2 2H 2O
Cu B. Sai, khi cho CrO3 vo NaOH d th dung dch thu c ch cha mui Na2CrO4
CrO3 + 2NaOH Na2CrO4 + H2O
Cu C. ng, Tnh cht vt l chung ca kim loi l tnh do, tnh dn in, dn nhit v tnh nh kim.
Cu D. ng, Cu 4H NO3 Cu2 NO 2H 2O
Cu 19: Chn C
n
- Cho X tc dng vi NaOH, nhn thy rng 1 NaOH 2 nn trong hn hp c cha mt este ca
nX
phenol (hoc ng ng). Gi A v B ln lt l 2 este (B l este ca phenol), c:
nA nB nX 0,15 nA 0,12mol

nA 2nB 2nNaOH 0,18 nB 0,03mol
BTKL
mX mY 18nH2O 46nC2H5OH 40nNaOH 12,96(g) (vi nH2O nB 0,03mol )
mX
- Ta c M X 86,4 v theo bi th dung dch sau phn ng cha ancol etylic.
nX
T cc d kin suy ra este c CTCT l HCOOC 2H5.
74nHCOOC2H 5
- Xt hn hp X ta c : %mA .100 68,52 %mB 31,48
mX

Cu 20: Chn B.
It
- Ta c ne trao i = 0,44mol . Qu trnh in phn xy ra nh sau :
96500
Ti anot Ti catot
Cu 2+
+ 2e Cu 2Cl
-
Cl2 + 2e
0,15 0,3 0,15 x 2x
2H2O + 2e 2OH- + H2 H2O 4H+ + 4e + O2
0,08 0,04 4y y
nCl 2 nO2 0,15 nCl 0,08mol nNaCl 0,16mol
2
2nCl 2 4nO2 0,44 nO2 0,07mol nCu(NO3 )2 0,2mol
- Dung dch sau in phn cha Na + (0,16 mol), NO3- (0,4 mol) v H+
+ Xt dung dch sau in phn c :
BTDT
nH nNO3 nNa 0,24mol
- Cho m gam Fe tc dng vi dung dch trn th : 3Fe 8H 2NO3
3Fe2 2NO 4H 2O
+ Theo ta c : mFe mrn khng tan mFe (bha tan) m 0,8m 0,09.56 m 25,2(g)
Cu 21: Chn B.
- C 4 nhn nh ng l: (1), (2), (4) v (5).
(1) ng, iu kin thng metyl, trimetyl, imetyl v etyl amin l nhng cht kh c mi khai kh
chiu, c v tan tt trong nc.
(2) ng, Cc amino axit l nhng cht rn dng tinh th tn ti di dng ion lng cc, c v ngt,
d tan trong nc v nhit nng chy cao.
(3) Sai, Anilin c lc baz yu hn ammoniac.
(4) ng, Peptit c chia thnh hai loi :
(5) ng, lu anilin ngoi khng kh th anilin chuyn sang mu nu en v b oxi ha bi oxi khng
kh.
(6) Sai, Cc amino axit c nhit nng chy cao khng b phn hy.
Cu 22: Chn B.
- Gi A, B v C ln lt l este, ancol v axit.
BT:O mX 12nCO2 2nH2O
- Khi t 4,84 gam X : nO(trong X) 0,16mol
16
- Khi cho 4,84 gam X tc dng vi 0,08 mol NaOH v dung dch thu c tc dng va vi 0,01
2nA nB 2nC nO(trong X) 4nA nB 4nC 0,16 nA 0,01mol

mol HCl th : 2nA 2nC nNaOH nHCl 2nA 2nC 0,07 nB 0,02mol
2n n n 2n n 0,04 n 0,025mol
A B ancol A B C
- Khi ta c nH O(sp) 2nC nHCl 0,06mol
2
mmui mX 40nNaOH 36,5nHCl mancol 18 nH 2O(sp) 5,765(g) Cu 23: Chn D.

BTKL
A. Sai, Cho dung dch NH3 cho n d vo dung dch, lc ly kt ta Fe(OH) 2 ri ho tan vo dung
B. Sai, Cho mt l nhm vo dung dch th khng loi b c CuSO 4.
D. ng, loi b CuSO4 ra khi dung dch ta cho l Fe vo dung dch vi mc ch loi b Cu2+ ra
khi dung dch.
Cu 24: Chn A.
- Phng trnh ha hc n gin biu din qu trnh quang hp ca cy xanh:

nh s ng
6nCO2 + 5nH2O (C6H10O5)n (X) + 6nO2
clorophin
- Khi cho tinh bt to vi dung dch iot to hp cht c mu xanh tm.
Cu 25: Chn C.
Cu 26: Chn D.
Cu 27: Chn B.
nCO2
nC6H12O6 0,3125mol mC6H12O6 56,25(g)
2H%
Cu 28: Chn C.
v trnh gi.
Cu 29: Chn C.
A. Ca(OH)2 + Na2CO3 CaCO3 + 2NaOH
pdd
B. 2NaCl + 2H2O
2NaOH + Cl2 + H2
coma
ng nga
n
C. NH3 + Na2CO3 : khng c phn ng
D. Na2O + H2O 2NaOH
Cu 30: Chn D.
Ti catot Ti anot
Cu2 2e
Cu 4H 4e O2
2H2O
H2O 2e H2 2OH

BT:e
2
96500ne
- Vy ne 4nO2 0,45mol t 8685(s)
I
Cu 31: Chn B.
n NaOH
- V 2n axit glutamic n NaOH mrn = m C5H 7O 4 NNa 2 191. = 19,1 (g)
2
Cu 32: Chn A.
- t X (a mol) ; Y (b mol) ; Z: HCOONH3CH2COOCH3 (c mol).
- Khi cho X, Y, Z tc dng vi NaOH thu c ancol l CH 3OH: 0,09 mol c = 0,09 mol
v 3 mui ln lt l AlaNa; GlyNa; HCOONa: 0,09 mol. Ta c h sau:
n GlyNa n AlaNa n NaOH n HCOONa 0,5 n GlyNa 0,17 mol

BT: Na

97 GlyNa 111n AlaNa 59, 24 68n HCOONa 53,12
n AlaNa 0,33 mol
n Gly (trong X,Y) 0,17 n Z 0,08 mol v a + b = 0,2 c = 0,11 mol
0, 08 0,33
- Ta c s mt xch Gly 0, 73 v Ala 3 trong X hoc Y khng c mt xch Gly v
0,11 0,11
c 2 mt xch u cha 3Ala nn Y l Gly(Ala)3: 0,08 mol v X l (Ala)3 : 0,03 mol.
m
Vy %m X X .100% 16, 45
mE

Cu 33: Chn C.
- Dung dch Y gm Fe3+, H+, Na+, NO3- v SO42- (dung dch Y khng cha Fe2+, v khng tn ti
dung dch cng cha Fe2+, H+ v NO3-).
BT:e
nFe3 2nCu 3nNO 0,18mol
- Khi cho dung dch Y tc dng vi 0,135 mol Cu th:
nH (d ) 4nNO 0,12mol

m 107n Fe3
- Khi cho dung dch Y tc dng vi Ba(OH) 2 ta c: n BaSO4 n NaHSO4 0,58mol
233
- Xt dung dch Y, c: n NO3 2n SO 4 2 (3n Fe3 n H n Na ) 0, 08 mol
BTDT
mY 23n Na 56n Fe3 n H 62n NO3 96nSO42 84,18(g)
BT:H nNaHSO4 nHNO3 nH (d )

nH 2O 0,31mol
2
- Xt hn hp kh Z, c nCO2 x mol v nNO 4x mol . Mt khc :
BTKL
44n CO2 30n NO mX 120n NaHSO4 n HNO3 mT 18n H2O 44x 4x.30 4,92(g) x 0,03mol
- Quay tr li hn hp rn X, ta c:
BT:N n nNO nHNO3 0,08 0,12 0,16
nFe(NO3 )2 NO3 0,02mol v nFeCO3 nCO2 0,03mol
2 2
nO(trong oxit) nNaHSO4 nHNO3 2nCO2 4nNO nH (d )
m nFe3O4 nFe3O4 0,01mol
4 8
m X 232n Fe3O 4 116n FeCO3 180n Fe(NO3 ) 2
%m Fe .100 37,33
mX
Cu 34: Chn D.
- A tc dng vi dung dch B : FeSO4 (A) + Ba(OH)2 (B) Fe(OH)2 + BaSO4 (Y).
Vy kt ta X gm Fe(OH)2 v BaSO4
- X tc dng vi HNO3 long d : 3Fe(OH)2 + 10HNO3 3Fe(NO3)3 + NO + 8H2O.
Vy kt ta Y l BaSO4
- B tc dng vi dung dch C : Ba(OH)2 (B) + (NH4)2CO3 (C) BaCO3 + 2NH3 + 2H2O
- A tc dng vi dung dch C : FeSO4 (A) + (NH4)2CO3 (C) FeCO3 (Z) + (NH4)2SO4
- Z tc dng vi dung dch HCl th : FeCO 3 (Z) + 2HCl FeCl2 + CO2 + H2O
Cu 35: Chn D.
- Khi cho hn hp rn X tc dng vi HCl th : nHCl 2nH2 2nO(trong X) 2.0,1 2.0,04.3 0,44mol
- Dung dch Y gm AlCl3 (x mol). CrCl3 (y mol), CrCl2 (z mol) khi cho tc dng ti a vi 0,56 mol
NaOH th: 4n Al3 4n Cr3 2n Cr 2 n OH 4x 4y 2z 0,56 (1)

y z 0, 08
BT: Cr
v (2) . T (1), (2) suy ra x = 0,08 mol m Al 0, 08.27 2,16 (g)

BT: Cl
3x 3y 2z 0, 44
Cu 36: Chn C.
Hp cht Glyxin Anilin Lysin Axit glutamic
Mu qu m Khng i mu Khng mu Xanh
Cu 37: Chn D.
BTKL
m X mmui + 36,5nHCl = 7,6
Cu 38: Chn D.
- T axetat thuc loi t bn tng hp (t nhn to) cn t capron, t polieste, t clorin thuc loi t
tng hp.
Cu 39: Chn D.
- Ta c : m Ag 108.2.n C6H12O6 21, 6 (g)
Cu 40: Chn A.
Ba(HCO3)2 + Ba(OH)2 2BaCO3 + 2H2O
mol: a a 2a m BaCO3 394a (g)
Ba(HCO3)2 + H2SO4
BaSO4 + 2CO2 + 2H2O
mol: a a a m BaSO4 233a (g)
Ba(HCO3)2 + Ca(OH)2 CaCO3 + BaCO3 + 2H2O
mol: a a a a mCaCO3 mCaCO3 297a (g)
Ba(HCO3)2 + 2NaOH Na2CO3 + BaCO3 + 2H2O
mol: a a 0,5a 0,5a mBaCO3 98,5a (g)

THPT NGUYN XUN NGUYN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: iu kin thng, th nghim no sau y khng xy ra phn ng ?

A. Cho dung dch BaCl2 vo dung dch NaHCO3.
B. Cho dung dch Na2CO3 vo nc cng vnh cu.
C. Cho CaO vo nc d.
D. Cho dung dch NaHSO4 vo dung dch Ba(HCO3)2.
Cu 1: Cho 7,2 gam imetylamin vo dung dch HNO 3 long d, sau khi kt thc phn ng thu c
m gam mui. Gi tr ca m l:
Cu 3: in phn 200 ml dung dch CuSO4 0,75M bng in cc tr vi cng dng in khng i I
= 5A, n khi khi lng dung dch gim 13,35 gam th dng in phn. Thi gian in phn l ?
Cu 4: T nilon-6,6 c iu ch t ?
A. Caprolaptam. B. Axit terephtalic v etylen glicol.
C. Axit aipic v hexametylen iamin. D. Vinyl xianua.
A. Metylamin lm dung dch phenolphthalein chuyn sang mu xanh.
B. Anilin to kt ta trng vi nc brom.
C. Riu cua ni ln khi un nng l hin tng ng t protein.
D. Nh natri hiroxit vo dung dch phenylamoni clorua thy hin tng phn lp cht lng.
Cu 6: Trong s cc kim loi sau y: Ag, Cu, Au, Al. Kim loi c tnh dn in tt nht l
A. Ag. B. Cu. C. Au. D. Al.
Cu 7: H2 kh c oxit no di y ?
A. Al2O3. B. CaO. C. MgO. D. CuO.
A. Nhm v crom u phn ng vi dung dch HCl theo cng t l s mol
B. Hn hp gm Ba(NO3)2 v NaHCO3 c th tan hon ton trong nc d
C. Ch dng dung dch NaOH phn bit c hn hp gm Mg, Al2O3 v MgO
D. Cr(III) oxit tan c trong dung dch NaOH long nhit thng.
Cu 9: t chy hon ton 29,2 gam hn hp X gm andehit acrylic, metyl axetat, andehit axetic v
etylen glicol thu c 1,15 mol CO2 v 23,4 gam H2O. Mt khc, khi cho 36,5 gam hn hp X trn tc
dng ht vi dung dch AgNO3 trong NH3 th thu c ti a m gam Ag. Gi tr gn nht ca m l
A. 43,5 B. 64,8 C. 53,9 D. 81,9
Cu 10: Khi lm th nghim vi cc cht sau X, Y, Z, T dng dung dch nc ca chng thy c cc
hin tng sau:
- Cht X tan tt trong dung dch HCl v to kt ta trng vi dung dch brom.
- Cht Y v Z u ha tan c Cu(OH)2 to dung dch xanh lam.
- Cht T v Y u to kt ta khi un nng vi dung dch AgNO3/NH3.
Cc cht X, Y, Z, T u khng lm i my qu tm.
A. anilin, fructoz, glixerol, metanal B. phenol, fructoz, etylen glicol, metanal.
C. anilin, glucoz, etylen glicol, metanol. D. phenol, glucoz, glixerol, etanal.

Cu 11: t chy hon ton 8,7 gam hn hp A gm etylen iamin v anehit oxalic hp th ton b sn
phm chy qua bnh ng 200 ml dung dch Ba(OH)2 1M th thu c m gam kt ta. Gi tr ca m l
A. 23,64 gam B. 29,55 gam. C. 19,7 gam. D. 39,4 gam.
Cu 12: in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp)
n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi
khng ng k). Tng khi lng cc mui c trong dung dch sau in phn l
A. 28,9 gam B. 18,8 gam. C. 19,5 gam. D. 10,1 gam.
Cu 13: Pht biu no sau y sai
A. Na2CO3 dng ty sch vt du m bm trn chi tit my trc khi sn
B. C th dng thng lm bng st chuyn ch H2SO4 v HNO3 c ngui.
C. Be c dng lm cht ph gia ch to hp kim c tnh n hi, bn, cht khng b n mn
D. Thi kh NH3 qua CrO3 un nng thy cht rn chuyn t mu sang mu en
(a) Cho Al vo dung dch FeCl3 d. (b) Cho dung dch AgNO3 d vo dung dch FeCl2.
(c) Nhit phn Cu(NO3)2. (d) t nng FeCO3 trong khng kh.
(e) in phn dung dch AgNO3 vi in cc tr.
Sau khi kt thc cc phn ng, s th nghim thu c kim loi l
A. 2 B. 3 C. 4 D. 5
Cu 16: Cho hn hp X gm Fe2O3 v ZnO, Cu tc dng vi dung dch HCl (d) thu c dung dch Y
v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta gm :
A. Fe(OH)2 v Cu(OH)2. B. Fe(OH)2, Cu(OH)2 v Zn(OH)2.
C. Fe(OH)3. D. Fe(OH)3 v Zn(OH)2.
Cu 17: Hn hp E cha 3 amin no, n chc, mch h. t chy hon ton m gam E cn 0,255
mol O2. Sn phm chy thu c c cha 0,03 mol N 2. Nu cho lng E trn tc dng ht vi HNO 3
d th khi lng mui thu c l:
A. 5,17 B. 6,76 C. 5,71 D. 6,67
Cu 18: Hn hp E cha Gly v mt hp cht hu c c cng thc phn t C4H12O4N2 t l mol
tng ng l 2:1. Cho 3,02 gam E tc dng (va ) vi dung dch cha NaOH. C cn dung dch
sau phn ng thu c m gam rn khan gm hn hp 2 mui v mt cht kh l cht hu c c kh
nng lm xanh giy qu m. Gi tr ca m c th l:
A. 3,59 hoc 3,73 B. 3,28 C. 3,42 hoc 3,59 D. 3,42
Cu 19: Cht rn kt tinh, nhit nng chy cao, d tan, l tnh cht ca cht no sau y?
A. C6H5NH2 B. C2H5OH
C. CH3COOH D. H2NCH2CH2COOH
Cu 20: Cht no sau y c kh nng lm qu tm xanh?
A. Alanin B. Anilin C. Etylamin D. Glyxin
Cu 21: Cht no sau y c cng thc phn t l C3H4O2?
A. Vinylfomat B. Etylfomat C. Metylaxetat D. Phenylaxetat
Cu 22: Axit oleic c cng thc l:
A. C15H31COOH B. C17H35COOH C. C17H33COOH D. C17H31COOH
Cu 23: Cho cc cht sau: Glucoz, saccaroz, isopren, axit metacrylic, vinyl axetat, phenyl amin,
metyl fomat, phenol, fructoz. S cht phn ng c vi dung dch nc brom nhit thng l:
A. 6 B. 7 C. 8 D. 5

Cu 24: Thy phn 51,3 gam saccaroz trong 100 ml dung dch HCl 1M vi hiu sut 60%. Trung
ha lng axit bng NaOH va ri cho AgNO 3/NH3 (va ) vo, sau khi cc phn ng hon ton
thy xut hin m gam kt ta. Gi tr ca m l:
A. 38,88 B. 53,23 C. 32,40 D. 25,92
Cu 25: Chia 2m gam hn hp X gm 2 kim loi c ho tr khng i thnh 2 phn bng nhau. Cho phn
mt tan ht trong dung dch HCl (d) thu c 2,688 lt H2 (o ktc). Nung nng phn hai trong oxi
(d) thu c 4,26 gam hn hp oxit. Gi tr ca m l:
Cu 26: Cu hnh electron ca nguyn t Cu (Z=29) trng thi c bn l
A. 1s22s22p63s23p64s13d10. B. 1s22s22p63s23p63d104s1.
C. 1s22s22p63s23p63d94s2. D. 1s22s22p63s23p64s23d9.
Cu 27: Dy gm cc oxit u b Al kh nhit cao l:
A. PbO, K2O, SnO. B. FeO, MgO, CuO. C. Fe3O4, SnO, BaO. D. FeO, CuO, Cr2O3.
Cu 28: Cht X c Cng thc phn t C4H9O2N. Bit:
X + NaOH Y + CH4O Y + HCl d Z + NaCl
Cng thc cu to thu gn ca X v Z c th ln lt l
A. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH.
B. CH3CH2(NH2)COOCH3 v CH3CH(NH3Cl)COOH.
C. H2NCH2CH2COOC2H3 v CH3CH(NH3Cl)COOH.
D. H2NCH2CH2COOC2H5 v ClH3NCH2COOH.
Cu 29: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung
dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn
ng l
Cu 30: X, Y, Z l ba este u no v mch h (khng cha nhm chc khc v MX < MY < MZ ). un
nng hn hp E cha X, Y, Z vi dung dch NaOH va thu c mt ancol T v hn hp F cha hai
mui A v B c t l mol tng ng l 5 : 3 (MA < MB). Dn ton b T qua bnh ng Na d thy khi
lng bnh tng 12 gam ng thi thu c 4,48 lt kh H2 (o ktc). t chy ton b F thu c
Na2CO3, CO2 v 6,3 gam H2O. S nguyn t hiro c trong Y l:
A. 10. B. 6. C. 8. D. 12.
Cu 31: Cht hu c mch h X c cng thc phn t trng vi cng thc n gin nht. t chy hon
ton m gam X cn va 6,72 lt O2 (o ktc), thu c 0,55 mol hn hp gm CO2 v H2O. Hp th
ht sn phm chy vo 200 ml dung dch Ba(OH)2 1M, sau phn ng khi lng phn dung dch gim
bt 2 gam. Cho m gam X tc dng va vi 0,1 mol NaOH, thu c 0,9 gam H2O v mt cht hu c
Y. Pht biu no sau y sai?
A. t chy hon ton Y thu c CO2 v H2O theo t l mol 1 : 1.
B. X phn ng c vi NH3.
C. C 4 cng thc cu to ph hp vi X.
D. Tch nc Y thu c cht hu c khng c ng phn hnh hc.
Cu 32: Cho m gam hn hp M gm ipeptit X, tripeptit Y, tetrapeptit Z v pentapeptit T (u mch h)
tc dng vi dung dch NaOH va , thu c hn hp Q gm mui ca Gly, Ala v Val. t chy
hon ton Q bng mt lng oxi va , thu ly ton b kh v hi em hp th vo bnh ng nc vi
trong d, thy khi lng bnh tng 13,23 gam v c 0,84 lt kh (ktc) thot ra. Mt khc, t chy hon
ton m gam M, thu c 4,095 gam H2O. Gi tr ca m gn nht vi gi tr no sau y
A. 6,0. B. 6,5. C. 7,0. D. 7,5.
Cu 33: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam
mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X c
th l:
A. (H2N)2C3H5COOH. B. H2NC2H3(COOH)2. C. H2NC3H6COOH. D. H2NC3H5(COOH)2.

(a) Sc kh Cl2 vo dung dch NaOH nhit thng.
(b) Sc kh Cl2 d vo dung dch FeSO4.
(c) Cho hn hp NaHSO4 v NaHCO3 (t l mol 1 : 1) vo nc.
(d) Cho hn hp Cu v Fe2O3 (t l mol 1 : 1) vo dung dch HCl d.
(e) Sc kh NO2 vo dung dch KOH.
Sau khi cc phn ng kt thc, s th nghim m dung dch thu c c hai mui l:
A. 2. B. 5. C. 3. D. 4.
Cu 35: Cho dy cc kim loi: Cu, Ni, Zn, Mg, Ba, Fe. S kim loi trong dy phn ng vi dung dch
FeCl3 d to kt ta l:
A. 5. B. 4. C. 1. D. 3.
Cu 36: Tng hp 120 kg polimetylmetacrylat t axit v ancol thch hp, hiu sut ca phn ng este
ha l 30% v phn ng trng hp l 80%. Khi lng ca axit cn dng l:
A. 160 kg. B. 430 kg. C. 103,2 kg. D. 113,52 kg.
Cu 37: Cho cc ng dng sau y ?
(a) dng trong ngnh cng nghip thuc da. (b) dng cng nghip giy.
(c) cht lm trong nc. (d) cht cm mu trong ngnh nhum vi.
(e) kh chua t trng, st trng chung tri, ao nui.
S ng dng ca phn chua (K 2SO4.Al2(SO4)3.24H2O) l:
A. 2. B. 5. C. 4. D. 3.
Cu 38: Hy cho bit dng qu tm c th phn bit c dy cc dung dch no sau y ?
A. glyxin, alanin, lysin. B. glyxin, valin, axit glutamic.
C. alanin, axit glutamic, valin. D. glyxin, lysin, axit glutamic.
Cu 39: Cho 24,5 gam tripeptit X c cng thc Gly-Ala-Val tc dng vi 600 ml dung dch NaOH
1M, sau khi phn ng xy ra hon ton thu c dung dch Y. em Y tc dng vi dung dch HCl d
ri c cn cn thn (trong qu trnh c cn khng xy ra phn ng ha hc) th thu c cht rn khan
c khi lng l m gam. Gi tr ca m l
A. 70,55. B. 59,60. C. 48,65. D. 74,15.
Cu 40: Cho 18,5 gam cht hu c X (c cng thc phn t C3H11N3O6) tc dng vi 400 ml dung
dch NaOH 1M to thnh nc, mt cht hu c a chc bc mt v m gam hn hp cc mui v c.
Gi tr ca m l:
A. 23,10. B. 24,45. C. 21,15. D. 19,10.
----------HT----------

THI TH THPT NGUYN XUN NGUYN LN 1
Cu 1: Chn A.
A. BaCl2 + NaHCO3: khng phn ng nhit thng.
B. Ca2 CO32
CaCO3 v Mg2 CO32 MgCO3
C. CaO + H2O Ca(OH)2
D. BaCl2 + NaHSO4 BaSO4 + NaCl + HCl
Cu 2: Chn A.
- Ta c: nHNO3 nCH3NHCH3 0,16mol mmui mCH3NHCH3 63nHNO3 17,28(g)
Cu 3: Chn D.
Ti catot Ti anot
2
Cu 2e
Cu 4H 4e O2
2H2O
H2O 2e H2 2OH

BT:e
2
96500ne
- Vy ne 4nO2 0,45mol t 8685(s)
I
Cu 4: Chn C.
o
t
axit aipic hexametyleniamin poli(hexametylen-aipamit) hay t nilon 6,6
Cu 5: Chn A.
A. Sai, Metylamin lm dung dch phenolphthalein chuyn sang mu hng.
B. ng, Anilin to kt ta trng vi nc brom.
C. ng, Riu cua ni ln khi un nng l hin tng ng t protein.

D. ng, Nh natri hiroxit vo dung dch phenylamoni clorua thy hin tng phn lp cht lng.
C6H5NH3Cl + NaOH C6H5NH2 (cht lng t tan) + NaCl + H2O
Cu 6: Chn A.
- Th t gim dn dn in l: Ag > Cu > Au > Al > Fe.
Cu 7: Chn D.
in ha. Vy oxit l CuO.
Cu 8: Chn B.
A. Sai, Al + HCl AlCl3 + H2 v Cr + HCl CrCl2.
B. ng, hn hp gm Ba(NO3)2 v NaHCO3 c th tan hon ton trong nc d. Khi dng NaOH ch
phn bit c Al2O3 trong hn hp gm Mg, Al2O3 v MgO.
Hin tng : Al2O3 tan c trong dung dch NaOH cn Mg v MgO khng tan.
D. Sai, Cr(III) oxit tan c trong dung dch kim c, nng.

Cu 9: Chn C.
Cx H 4O Cy H 6O2
- Qu trnh : C2H 3CHO,CH 3CHO,CH 3COOCH 3,C2H 4 (OH) 2

O2
CO2 H 2O
29,2(g) X 1,15mol 1,3mol
44nCO2 18nH2O
BTKL
nO2 1,4 mol
32

BT:O
nCx H 4O 2nCy H6O2 2nCO2 nH 2O 2nO2 0,8
nCH3CHO nC2H3CHO nCx H 4O 0,2
BT:H

4nCx H 4O 6nCy H6O2 2nH 2O 2,6 nCH3COOCH3 nC2H 4 (OH)2 nCy H6O2 0,3

- Trong 29,2 (g) X cha 0,2 mol CH3CHO v C2H3CHO vy trong 36,5 (g) X cha 0,25 mol CH3CHO
v C2H3CHO.
- Cho 36,5 (g) X tc dng vi AgNO3 th : nAg 2(nC2H3CHO nCH3CHO ) 2nCx H 4O 0,5 mAg 54(g)
Cu 10: Chn A.
Anilin (X) Metanal (T) Glixerol (Z) Fructoz (Y)
Nc Br2 C6H2NH2(Br)3 Mt mu nc brom
Dd AgNO3/NH3 Ag Ag
Cu(OH)2 To phc tan mu To phc tan mu
xanh lam xanh lam
Cu 11: Chn C.
Nhn thy, NH2CH=CHNH2 (etylen iamin) v OHC-CHO (anhit oxalic) u c phn t khi l 58.
8,7
nA 0,15
BT:C
nCO2 2(nNH 2CH CHNH 2 nOHCCHO ) 0,3
58
n
Ta c OH nCO2 nOH nBaCO3 nOH nCO2 0,1 mBaCO3 19,7(g)
2
Cu 12: Chn C.
- Qu trnh phn ng xy ra nh sau :
Ti anot Ti catot
Cu 2+
+ 2e Cu 2Cl Cl2
-
+ 2e
a 2a a 0,1 0,05 0,1
H2O 4H+ + 4e + O2
2a -0,1 2a -0,1 0,5a 0,025
mdd gim 64nCu 71nCl 2 32nO2 10,75 a 0,1mol

BT:Cu
n Cu(NO3 ) 2 0, 05 mol
Dung dch sau phn ng cha : v 0,1 mol HNO3
BT:K
n KNO3 n K 0,1mol
mmui 101nKNO3 188nCu(NO3 )2 19,5(g)
Cu 13: Chn D.
- Thi kh NH3 qua CrO3 un nng thy cht rn chuyn t mu sang mu lc thm :
NH3 + 2CrO3( thm)
Cr2O3(lc thm) + N2 + H2O
Cu 14: Chn B.
(a) Al FeCl3
AlCl 2 FeCl2 (b)
AgNO3 FeCl 2
Fe(NO3 )3 FeCl3 Ag
o o
t t
(c) Cu(NO3 ) 2 CuO NO2 O2 (f) FeCO3 O2 Fe2O3 CO2
dpdd
(g) AgNO3 H 2O Ag HNO3 O2

Vy c 2 th nghim thu c kim loi l (b) v (g).
Cu 15: Chn D.
- Hn hp X phn ng va vi NaOH m n NaOH n este trong X c cha 1 este ca phenol.
- Gi A l este n chc, B l este ca phenol. n B n NaOH n X 0,1 n A 0,3 n B 0, 2 mol
0,2mol 0,1mol
este n chc,este c to t phenol (ng ng) NaOH hn h p mui cht hu cY H 2O

0,3mol hn h p X 0,4mol 37,6(g)
V Y no, n chc, c phn ng trng gng nn Y l anehit vi n Y n A 0, 2 mol

0,4
Khi t Y th nCO2 nH2O m 44nCO2 18nH2O 24,8 nCO2 0,4 CY 2.Vy Y lCH 3CHO
0,2
BTKL
nH2O nB 0,1mol mX mmui 44nCH3CHO 18nH2O 40nNaOH 32,2(g)
Cu 16: Chn A.
Cu (rn Z khng tan )
HCl(d )
Fe2O3,Zn,Cu
Fe2 ,Zn2 ,Cu2 ,H (d ) ,Cl
NaOH(d )
Fe(OH) 2,Cu(OH) 2 NaCl, Na2ZnO2
hn h p X dung dch Y hn h p kt ta dung dch sau p
Cu 17: Chn B.
- t CTTQ ca hn hp E l C nH2n + 3N. Khi t E th:
3n 1,5 1
CnH2n + 3N + O2 nCO2 + (n + 1,5)H2O + N2
2 2
mol: 0,255 0,03
3n 1,5 7
n E 2n N 2 0, 06 mol v n O 2 n E n m E 2,98 (g)
2 3
- Cho lng E trn tc dng ht vi HNO 3 d th: mmui = m E 63.n HNO3 6, 76 (g)
Cu 18: Chn B.
- Trong hn hp 3,02 gam E cha C2H5O2N: 0,02 mol v (COONH3CH3)2: 0,01 mol.
n H2 NCH2COONa 0, 02 mol
- Khi cho hn hp E tc dng vi NaOH th: mrn = 3, 28 (g)
n (COONa)2 0, 01 mol
Cu 19: Chn D.
Cu 20: Chn C.
Cu 21: Chn B.
Cu 22: Chn C.
Cu 23: Chn B.
- C 7 cht lm mt mu dung dich Br 2 l: Glucoz, isopren, axit metacrylic, vinyl axetat, phenyl
amin, metyl fomat, phenol.
Cu 24: Chn B.
- Khi thy phn saccaroz vi H = 60% th: n C6H12O6 2n C12H 22O11 .h % 0,18 mol
- Khi tc dng vi AgNO 3 th: m 108n Ag 143,5n AgCl 108.2.n C6H12O 6 143,5.n HCl 53, 23 (g)
Cu 25: Chn D.
- Ta c: nO(trong oxit) nH 2 0,12mol mkim lo i moxit 16nO 2,34(g)
Cu 26: Chn B.
Cu 27: Chn D.
- Phn ng nhit nhm l phn ng ha hc ta nhit trong nhm l cht kh nhit cao. Phng
php ny dng kh cc oxit kim loi ng sau Al trong dy in ha.
Vy cc oxit tha mn iu kin trn l: PbO, SnO, FeO, CuO, Fe3O4, Cr2O3.

Cu 28: Chn A.
- Cc phn ng xy ra:
CH3CH(NH2)COOCH3 (X) + NaOH
CH3CH(NH2)COONa (Y) + CH4O
CH3CH(NH2)COONa (Y) + HCl d CH3CH(NH3Cl)COOH (Z) + NaCl
Cu 29: Chn A.
- Thc hin gp qu trnh, rt ra nhn xt: n NaOH 2n NH 2C3H5 (COOH) 2 n HCl 0, 65mol
Cu 30: Chn C.
- Dn ton b ancol T qua bnh ng Na d th :
BTKL
mT mbnh tng 2nH2 12,4(g)
2nH 2 0,4 m 12,4a a 2
- Ta c nT MT T M T 62(C2H 4 (OH)2 )
a a nT 0,4
- Khi t hn hp E th ta thu c : nCO2 nH2O 0,35mol
m nNaOH nCOO 2nT 0,4mol nNa2CO3 0,2mol
- Xt hn hp E ta c:
BT:C
nC(trong mui) nCO2 nNa2CO3 0,55mol
nA nB 2nT nA 0,25mol BT:C CA 1
nA CA nBCB 0,55 0,25CA 0,15CB 0,55
nA : nB 5: 3 nB 0,15mol CB 2
Vy hai mui A v B ln lt l HCOONa v CH 3COONa
X, Y v Z ln lt l C2H4 (OOCH)2 HCOOCH2 CH2OOCCH3 v C2H4 (OOCCH3)2 .
Vy s nguyn t H trong Y l 8
Cu 31: Chn C.
nCO nH2O 0,55 nCO2 0,3mol
- Xt hn hp CO2 v H2O ta c: 2
197nCaCO3 (44nCO2 18nH2O ) mdd gim 2 nH2O 0,25mol
BT:O
nO(trong X) 2nCO2 nH2O 2nO2 (p ) 0,25mol
- C nC : nH : nO 6:10: 5 v CTCT trng vi CT n gin nht nn CTPT ca X l C6H10O5
nA 1
- Mt khc ta nhn thy rng
nNaOH 2
- T cc 2 d kin trn ta c CTCT ca X l HOCH2CH2COOCH2CH2COOH
v X cn 2 ng phn cn li: HOCH2CH2COOCH(CH3)COOH ;
HOCH(CH3)COOCH(CH3)COOH
0
- PT phn ng: HOCH 2CH 2COOCH 2CH 2COOH(X) 2NaOH
t
2HOCH 2CH 2COONa(Y) H 2O
0
A. ng, 2HOCH 2CH 2COONa(Y) 6O2
t
5CO2 5H 2O Na2CO3
B. ng, HOCH2CH2COOCH2CH2COOH(X) NH3 HOCH 2CH 2COOCH 2CH 2COONH 4
C. Sai, X c tt c 3 cng thc cu to (vit trn).
H O
D. ng, HOCH2CH2COOH(Y) 2
CH 2 CH COOH
Cu 32: Chn A.
Quy i hn hp M thnh C2H3ON, CH2 (x mol), H2O.
+ Khi t mui Q gm C2H4O2NNa v CH2 (x mol) th:
BT: N n NaOH n C 2H 4O 2 NNa
n C2H 4O2 NNa 2n N2 0,075 mol
BT: Na
n Na 2CO3 0, 0375 mol
2 2

BT: H
n H 2O 2n C2H 4O 2 NNa n CH 2 0,15 x
+ 44n CO 2 18n H 2O 13, 23 x 0, 09 mol
BT: C
n CO 2 2n C2H 4O 2 NNa n CH 2 n Na 2CO3 0,1125 x

- Khi t:
0,075 mol 0,09 mol a mol
O
C 2 H 4O 2 NNa , CH 2 , H 2 O
2
n H 2O 0, 2025 a 0, 2275 a 0, 025 mol m M 5,985 (g)
m (g) M
Cu 33: Chn D.
- t cng thc ca X l : (H2N)x-R-(COOH)y.
n
- Khi cho X tc dng vi NaOH th: y NaOH 2
nX
n BTKL m m HCl
- Khi cho X tc dng vi NaOH th: x HCl 1 MX 147
nX 0, 02
Vy X l H 2 NC3H 5 (COOH) 2
Cu 34: Chn D.
(a) ng, Cl2 + 2NaOH
NaCl + NaClO + H2O
(b) ng, 3Cl2 + 6FeSO4
2Fe2(SO4)3 + 2FeCl3
(c) Sai, NaHSO4 + NaHCO3
Na2SO4 + CO2 + H2O
Fe2O3 HCl
2FeCl3 H 2O

1 mol 2 mol
(d) ng, Dung dch thu c gm 2 mui FeCl2 , CuCl2 .
2FeCl3 Cu
FeCl2 CuCl2

2 mol 1 mol
(e) ng, 2NO2 + 2KOH KNO2 + KNO3 + H2O
Cu 35: Chn C.
- Khi dng mt lng d FeCl3 th cc kim loi Cu, Ni, Zn, Mg, Fe xy ra phn ng:
M + 2FeCl3
MCl2 + 2FeCl2
- Khi cho Ba vo dung dch FeCl3 th: 3Ba + 6H2O + 2FeCl3
3BaCl2 + 2Fe(OH)3 nu + 2H2
Cu 36: Chn B.
- Qu trnh iu ch:
H ,t o xt,t o
CH 2 C(CH3 )COOH CH3OH CH 2 C(CH3 )COOCH3 [ CH 2 C(CH3 ) COOCH3 ]
m 1 1
- Ta c: m C4H 6O 2 86. PMM . . 430 kg
100 h1 % h 2 %
Cu 37: Chn C.
- C 4 ng dng ca phn chua (K 2SO4.Al2(SO4)3.24H2O) l (a), (b), (c) v (d).
Cu 38: Chn D.
Thuc th Glyxin Lysin Axit glutamic
Qu tm Khng mu Xanh
Cu 39: Chn D.
- Gp qu trnh: cho tripeptit X v NaOH phn ng cng lc vi HCl th :
NaOH HCl
NaCl H2O
mol: 0,6 0,6 0,6 0,6
0
Gly Ala Val 2H 2O 3HCl
t
GlyHCl AlaHCl ValHCl
mol: 0,1 0,2 0,3 0,1 0,1 0,1
mmui mGlyHCl mAlaHCl mValHCl 58,5nNaCl 74,15(g)
Cu 40: Chn D.
- Phn ng: HCO3H3N(CH2)2NH3NO3 + 3NaOH Na2CO3 + NaNO3 + H2N(CH2)2NH2 + 3H2O
mol: 0,1 0,4 0,1 0,1

m 85nNaNO3 106nNa2CO3 19,1(g)

TNH BN TRE Mn: KHOA HC T NHIN HA HC
THPT NGUYN NH CHIU Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Oxit no sau y l oxit axit

A. CrO B. Al2O3 C. CrO3 D. Fe2O3
Cu 2: Kim loi no sau y l kim loi kim th
A. Ca B. Na C. Al D. Fe
Cu 3: Phn trm khi lng ca nguyn t oxi trong glucoz l
A. 44,44% B. 53,33% C. 51,46% D. 49,38%
Cu 5: Nhit phn hiroxit Fe (II) trong khng kh n khi khi lng khng i thu c
A. Fe3O4 B. FeO C. Fe2O3 D. Fe
Cu 6: Phn ng no sau y l sai
A. Cr(OH)3 + NaOH
NaCrO2 + 2H2O
B. 3Zn + 2CrCl3
3ZnCl2 + 2Cr
C. 2Cr + 3Cl2
2CrCl3
D. 2Na2CrO4 + H2SO4 Na2Cr2O7 + Na2SO4 + H2O
Cu 7: Dung dch anilin (C6H5NH2) khng phn ng c vi cht no sau y
A. NaOH B. Br2 C. HCl D. HCOOH
0 0
t
t

0 0

Cu 11: Mt phn t xenluloz c phn t khi l 15.106, bit rng chiu di mi mc xch C6H10O5
khong 5.10-7 (mm). Chiu di ca mch xenluloz ny gn ng l
A. 3,0.10-2 (mm) B. 4,5.10-2 (mm) C. 4,5.10-1 (mm) D. 3,0.10-1 (mm)
Cu 12: t chy 0,01 mol este X n chc bng lng oxi va , thu c 448 ml kh CO2 (ktc).
Mt khc un nng 6,0 gam X vi dung dch KOH va , thu c lng mui l :
Cu 15: Ha tan ht 3,24 gam bt Al trong dung dch HNO3 d, thu c 0,02 mol kh X duy nht v
dung dch Y cha 27,56 gam mui. Kh X l
A. NO2 B. N2O C. N2 D. NO
A. 860 B. 862 C. 884 D. 886
Cu 17: phn bit cc dung dch ring bit: anilin, glucoz v alanin, ta dng dung dch no sau y
A. NaOH B. AgNO3/NH3 C. HCl D. Br2
kt ta. Gi tr m l
Cu 19: S ng phn cu to ng vi amin c cng thc phn t C4H11N l.
A. 7 B. 6 C. 8 D. 5
A. Xenluloz tan tt trong imetyl ete.
B. Saccaroz c kh nng tham gia phn ng trng gng.
C. Glucoz th hin tnh oxi ha khi tc dng vi H2 (xc tc Ni, to).
D. Amiloz v amilopectin l ng phn ca nhau.
Cu 21: Cho V1 ml dung dch NaOH 0,4M vo V2 ml dung dch H2SO4 0,6M. Sau khi kt thc phn ng
thu c dung dch ch cha mt cht tan duy nht. T l V1 : V2 l
A. 1 : 3 B. 2 : 3 C. 3 : 2 D. 3 : 1
Cu 22: Ha tan ht m gam hn hp X gm Cu v Fe trong dung dch HCl long d, thu c 0,09 mol
kh H2. Nu cho m gam X trn vo dung dch HNO3 long d, thu c 0,15 mol kh NO (sn phm kh
duy nht ca N+5). Gi tr ca m l
Cu 23: Th nghim no sau y c phn ng ha hc xy ra
A. Cho dung dch Fe(NO3)3 vo dung dch AgNO3.
B. Cho Cr2O3 vo dung dch NaOH long.
C. Nh dung dch Br2 vo dung dch cha NaCrO2 v NaOH.
D. Cho bt Fe vo dung dch HNO3 c, ngui.
Cu 24: Nhn nh no sau y l sai
A. iu kin thng, cc amino axit l cht rn, d tan trong nc.
B. trng thi tinh th, cc amino axit tn ti dng ion lng cc (mui ni phn t).
C. Axit glutamic l thuc h tr thn kinh.
D. Trng ngng axit 6-aminohexanoic thu c nilon-6 c cha lin kt peptit.
Cu 25: Hiro ha hon ton a mol cht hu c X mch h cn dng a mol H2 (xc tc Ni, t0) thu c
este Y c cng thc phn t C4H8O2. S ng phn tha mn ca X l
A. 5 B. 3 C. 4 D. 6
Cu 26: Cho hn hp gm Na, Ba v Al vo lng nc d, thy thot ra V lt kh H2 (ktc); ng thi
thu c dung dch X v cn li 1,08 gam rn khng tan. Sc kh CO2 d vo X, thu c 12,48 gam kt
ta. Gi tr ca V l
A. 1,792 lt B. 3,584 lt C. 7,168 lt D. 8,960 lt

sau phn ng thu c m gam rn khan. Gi tr m l
Cu 28: un nng 0,2 mol hn hp X cha etyl fomat v etyl axetat vi dung dch AgNO3/NH3 (dng
d) thu c 17,28 gam Ag. Nu thy phn hon ton 28,84 gam X vi dung dch KOH va , thu c
m gam mui. Gi tr ca m l
Cu 29: Thc hin cc phn ng sau:
(1) Cho Na vo dung dch CuSO4.
(2) in phn dung dch CuSO4 bng in cc tr.
(3) Thi lung kh H2 n d qua ng nghim cha CuO.
(4) Nung nng hn hp gm Al v CuO trong kh tr.
(5) Cho bt Fe vo dung dch CuCl2.
Sau khi kt thc th nghim, s trng hp thu c Cu n cht l
A. 5 B. 2 C. 4 D. 3
A. 0,6 B. 1,25 C. 1,20 D. 1,50
Cu 31: Cho hn hp gm Fe2O3 v Cu vo lng d dung dch H2SO4 long thu c dung dch X v
cn li mt phn rn khng tan. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Fe,
NaNO3, Cl2 v KMnO4
A. 3 B. 2 C. 1 D. 4
Cu 32: Hn hp X cha hai hp cht hu c gm cht Y (C2H7O2N) v cht Z (C4H12O2N2). un nng
9,42 gam X vi dung dch NaOH d, thu c hn hp T gm hai amin k tip c t khi so vi He bng
9,15. Nu cho 9,42 gam X tc dng vi dung dch HCl long d, thu c dung dch c cha m gam
mui ca cc hp cht hu c. Gi tr ca m l
Cu 33: Cho 17,82 gam hn hp gm Na, Na2O, Ba, BaO (trong oxi chim 12,57% v khi lng)
vo nc d, thu c a mol kh H2 v dung dch X. Cho dung dch CuSO4 d vo X, thu c 35,54
gam kt ta. Gi tr ca a l.
A. 0,08 B. 0,12 C. 0,10 D. 0,06
Cu 34: Cho dy cc cht: triolein; saccaroz; nilon-6,6; t lapsan; xenluloz v glyxylglyxin. S cht
trong dy cho c phn ng thy phn trong mi trng kim l
A. 6 B. 4 C. 5 D. 3
A. 2 B. 4 C. 5 D. 3
Cu 36: Hn hp X cha cc este u mch h gm hai este n chc v mt este a chc, khng no
cha mt lin kt i C=C. t chy hon ton 0,24 mol X cn dng 1,04 mol O2, thu c 0,93 mol
CO2 v 0,8 mol H2O. Nu thy phn X trong NaOH, thu c hn hp Y cha 2 ancol c cng s
nguyn t cacbon v hn hp Z cha 2 mui. Phn trm khi lng ca este n chc c khi lng
phn t ln trong X l

A. 22,7% B. 15,5% C. 25,7% D. 13,6%
0
t
(1) X NaOH X1 X 2 2H 2O (2) X1 H2SO4
Na 2SO4 X3
0 0
t t
C. X3 v X4 c cng s nguyn t cacbon. D. X2, X4 v X5 c mch cacbon khng phn nhnh.
Cu 38: Tin hnh in phn dung dch CuSO4 v NaCl bng in cc tr, mng ngn xp vi cng
dng in khng i, ta c kt qu ghi theo bng sau:
Thi gian (s) Khi lng catot tng Anot Khi lng dung dch gim
3088 m (gam) Thu c kh Cl2 duy nht 10,80 (gam)
6176 2m (gam) Kh thot ra 18,30 (gam)
T 2,5m (gam) Kh thot ra 22,04 (gam)
Gi tr ca t l :
Cu 39: Hn hp E cha ba peptit u mch h gm peptit X (C4H8O3N2), peptit Y (C7HxOyNz) v
peptit Z (C11HnOmNt). un nng 28,42 gam E vi dung dch NaOH va , thu c hn hp T gm 3
mui ca glyxin, alanin v valin. t chy ton b T cn dng 1,155 mol O2, thu c CO2, H2O, N2 v
23,32 gam Na2CO3. Phn trm khi lng ca X trong hn hp E l
A. 4,64% B. 6,97% C. 9,29% D. 13,93%
Cu 40: Ha tan ht 12,06 gam hn hp gm Mg v Al2O3 trong dung dch cha HCl 0,5M v H2SO4
0,1M. Sau khi kt thc phn ng thu c dung dch X. Cho t t dung dch NaOH 1M vo dung dch X,
phn ng c biu din theo th sau:
Nu cho t t V ml dung dch NaOH 0,3M v Ba(OH)2 0,1M vo dung dch X, thu c kt ta ln nht,
ly kt ta nung ngoi khng kh n khi lng khng i thu c m gam rn khan. Gi tr ca m l
-----------HT-----------

THI TH THPT NGUYN NH CHIU LN 1
Cu 1: Chn C.
- CrO, Fe2O3 l oxit baz, CrO3 l oxit axit, Al2O3 l oxit lng tnh.
Cu 2: Chn A.
Cu 3: Chn B.
- CTPT ca glucoz l C6H12O6 c %O = 53,33
Cu 4: Chn C.
- T nhn to (t bn tng hp) l t c ngun gc t thin nhin c pha ch thm bng phng php
ha hc nh t visco, t xenluloz axetat
Cu 5: Chn C.
- Phng trnh: 4Fe(OH)2 + O2(khng kh) 2Fe2O3 + H2O
Cu 6: Chn B.
- Triong mi trng axit, mui Cr(III) th hin tnh oxi ha v d b nhng cht kh nh Zn kh thnh
mui Cr(II): Zn + 2CrCl3
ZnCl2 + 2CrCl2
Cu 7: Chn A.
Cu 8: Chn D.
0
t
HCOONa + CH3CH2CHO
0
t
HCOONa + CH3COCH3
0
t
0
Cu 9: Chn D.
Cu 10: Chn C.
B. Sai, Phng php un nng ch c th lm mm c nc cng tm thi v trong nc cng tm thi
c cha cc ion Mg2+, Ca2+ v HCO3 khi un nng:
to
D. Sai, Nc cng gy nhiu tr ngi vi i sng hng ngy v cho cc ngnh sn xut nh: lm qun
o mc nt, lm gim mi v thc n, ng cn lm tc ng dn nc, lm hng nhiu dung dch pha
ch nhng khng phi l tc nhn gy nhim ngun nc.
Cu 11: Chn B.
- Ta c:
M mch xenlulz
nmc xch 92592 l mch xenlulz nmc xchdmc xch 0,046(mm) 4,5.102 (mm)
162
Cu 12: Chn D.
n
- Ta c: C X CO2 2 : X l C2H4O2 c cng thc cu to: HCOOCH3
nX
Cu 13: Chn B.
- V 2nFe nAgNO3 3nFe nn trong dung dch sau phn ng ch cha Fe(NO3)2 v Fe(NO3)3.
Cu 14: Chn D.
Al(OH)3 NaOH
Na[Al(OH) 4 ]
C. ng, Phng trnh: 2Al + 3H2SO4 Al2(SO4)3 + 3H2
Cu 15: Chn B.
BT:Al m Y 213n Al(NO3 )3
n Al(NO3 )3 n Al 0,12 mol n NH 4 NO3 0,025mol
80
BT:e
- Go a l s e nhn ca X p dng: 0, 02a 3n Al 8n NH 4 NO3 0,16 a 8 . Vy X l
N 2O .
Cu 16: Chn A.
NaOH
- Cho: (RCOO)3 C3H 5
C17 H 33COONa C17 H 35COONa C15H 31COONa C3H 5 (OH)3
Vy cu to ca X l:
Cu 17: Chn D.
Thuc th Anilin: C6H5NH2 Glucoz: C6H12O6 Alanin: C3H7O2N
Mt mu dung dch Mt mu dung dch
Br2 Khng hin tng
brom v c kt ta trng brom
Cu 18: Chn A.
0,06 mol 0,12 mol
H O AgNO
2
dd Y
3
AgCl, Ag
16,56 (g ) X m (g)
BT: Cl
- Kt ta gm: m 40,92 (g)
BT: e

Cu 19: Chn C.
ng phn amin bc n- C4H9NH2, CH3CH(CH3)CH2NH2, CH3CH2CH(CH3)NH2 v (CH3)3CNH2.
1
ng phn amin bc C2H5NHC2H5, n-C3H7NHCH3 v (CH3)2CHNHCH3.
2
ng phn amin bc C2H5NH(CH3)2.
3
Vy amin c CTPT l C4H11N c 8 ng phn cu to.
Cu 20: Chn C.
A. Sai, Xenluloz khng tan trong nc ngay c khi un nng v khng tan trong dung mi hu c nh
benzene, ete (trong c imetyl ete).
B. Sai, Saccaroz khng c kh nng tham gia phn ng trng gng.
C. ng, Glucoz (C6H12O6) th hin tnh oxi ha khi tc dng vi H2 (xt Ni, t0) to sorbitol (C6H14O6)
D. Sai, Amiloz v amilopectin l thnh chnh ca tinh bt c cng thc l (C6H10O5)n trong phn t
khi ca amilopectin ln hn so vi amiloz, v vy 2 cht trn khng phi ng phn ca nhau.
Cu 21: Chn D.
- Phng trnh: 2NaOH H 2SO 4
Na 2SO 4 H 2O

mol: 0,4V1 0,6V2
0, 4V1 V 3
- V sau phn ng ch thu c 1 cht tan nn phn ng trn va 0, 6V2 1
2 V2 1
Cu 22: Chn B.
- Khi cho X tc dng vi HCl long ta c: n H 2 n Fe 0, 09 mol
BT: e 3n Fe 3n NO
- Khi cho X tc dng vi HNO3 long ta c:
n Cu 0, 09 mol m X 10,8 (g)
2
Cu 23: Chn C.
A . Fe(NO3)2 + AgNO3 : khng phn ng.
B. Cr2O3 ch phn ng vi NaOH c nng.
C. 3Br2 + 2NaCrO2 + 8NaOH 2Na2CrO4 + 6NaBr + 4H2O
D. Cr, Fe v Al b th ng ha vi HNO3 v H2SO4 c ngui.
Cu 24: Chn D.
A. ng, iu kin thng, cc amino axit l cht rn, d tan trong nc.
B. ng, Trong phn t amino axit, nhm NH2 v nhm COOH tng tc vi nhau to ion lng cc. V
vy amino axit kt tinh tn ti dng ion lng cc. Trong dung dch, dng ion lng cc chuyn mt
phn nh thnh dng phn t:
C. ng Axit glutamic l thuc h tr thn kinh.

D. Sai, Trng ngng axit 6-aminohexanoic thu c nilon-6 c cha lin kt peptit.
to
nH 2 N [CH 2 ]5 COOH n ( HN [CH 2 ]5 CO ) n nH 2O
Lin kt CO-NH trong trng hp ny khng phi l lin kt peptit v khng dc to ra t cc - amino
axit.
Cu 25: Chn D.
Ni,t 0
- Phng trnh: C4H6O2 (X) H 2 C4H8O2 (Y)
mol: a a a
Vy X l este mch h, khng no (c mt lin kt C = C) v n chc. X c 6 ng phn l:
HCOOCH=CHCH3 (cis trans), HCOOC(CH3)=CH2, HCOOCH2CH=CH2
CH3COOCH=CH2 v CH2=CHCOOCH3
Cu 26: Chn C.
H O CO
- Qu trnh: Na,Ba,Al
2
Al d v Na ,Ba2 ,AlO2
2
Al(OH) 3
1,08 (g) dung dch X 0,16 mol
BTDT (X)
- Ta c: n AlO2 n Al(OH)3 0,16 mol
n Na 2n Ba 2 0,16
m 2n Na 4n Ba n H 2 n H 2 2(n Na 2n Ba 2 ) 0,32 mol VH 2 7,168 (l)
Cu 27: Chn A.
89n Ala 147n Glu 15,94 n Ala 0, 08 mol
- Ta c:
n Ala 2n Glu n NaOH 0, 2 n Glu 0, 06 mol
BT:Na
n NaCl n NaOH 0, 2 mol mX 125,5n AlaHCl 183,5n GluHCl 58,5n NaCl 32,75(g)
Cu 28: Chn D.

HCOOC 2 H 5 AgNO3 /NH 3
- Cho 0,2 mol X
CH 3COOC 2 H 5
n Ag
n HCOOC2H5 0,08 mol n CH3COOC2H5 0,12 mol
2
HCOOC2 H5 : 0,14 mol KOH HCOOK : 0,14 mol
- Cho 28,84 gam X mmui = 32,34 (g)
CH 3COOC 2 H 5 : 0, 21 mol CH 3 COOK : 0, 21 mol
Cu 29: Chn C.
- C 4 trng hp thu c Cu n cht l (2), (3), (4), (5). Cc phn ng xy ra:
(1) 2Na + CuSO4 + 2H2O
Cu(OH)2 + Na2SO4 + H2
to
(2) 2CuSO4 + 2H2O
dpdd
2Cu + 2H2SO4 + O2 (3) H2 + CuO Cu + H2O
to
(4) 2Al + 3CuO Al2O3 + 3Cu (5) Fe + CuCl2 FeCl2 + Cu
Cu 30: Chn B.
n O 2 0, 64 mol n X CO 2 0, 2 mol
32 2
0,56
0, 2
cacboxylic k tip nn 2 este trong X ln lt l:

CH 3COOC 2 H5 : y mol 2x 4y 0,56 y 0, 08
Cu 31: Chn D.
H 2SO4 (d )
- Phn ng: Fe2O3,Cu Fe2 ,Cu2 ,H (d ) ,SO42 Cu (rn khng tan) .
hn h p dung dch X
- Dung dch X tc dng c vi 4 cht sau:

Fe CuSO4
Cu FeSO4 v Fe + H 2SO4
FeSO4 H 2
3Fe2 NO3 4H
3Fe3 NO 2H 2O
6FeSO4 3Cl2
2Fe2 (SO4 )3 2FeCl3
10FeSO4 2KMnO4 8H2SO4
5Fe2 (SO4 )3 K 2SO4 2MnSO4 8H2O
Cu 32: Chn B.
- Cho
x mol y mol
Y : HCOONH 3CH 3 NaOH

T (M T 36, 6) : CH 3 NH 2 v C 2H 5 NH 2
x mol
9, 42 (g)X x mol y mol y mol
Z : H 2 NCH 2COONH 3C 2H 5 HCl
CH 3 NH 3 Cl, Cl H 3 NCH 2COOH , C 2H 5 NH 3Cl
y mol
m (g )
- Hng t duy 1: Tnh theo khi lng ca tng mui
77x 120y 9, 42 x 0, 06
+ Ta c: mmui = 11, 77 (g)
31x 45y 36, 6.(x y) y 0, 04
- Hng t duy 2: Bo ton khi lng
BTKL
+ Ta c: nHCl = x + 2y = 0,14 mol mmui = mX + mHCl - mHCOOH = 11, 77 (g)

Cu 33: Chn A.
- Quy i hn hp thnh Na, Ba v O. Ta c :
23n Na 137n Ba 15,58
23n Na 137n Ba 17,82 16n O n Na 0,32 mol
n Na 2n Ba 2
98n Cu(OH) 2 233n BaSO 4 35,54 98 233n Ba 2 35,54 n Ba 0, 06 mol
2
BT:e n 2n Ba 2n O
n H 2 Na 0, 08 mol
2
Cu 34: Chn B.
- C 4 cht thy phn trong mi trng kim l: triolein; nilon-6,6; t lapsan; glyxylglyxin.
Cu 35: Chn B.
- C 4 th nghim thu c n cht l (1), (2), (3) v (4). Phng trnh phn ng:
(1) 2Al + 2NaOH + 2H2O
2NaAlO2 + 3H2
(2) 2NaCl + 2H2O
dpdd
2NaOH + Cl2 + H2
(3) 6KI + Na2Cr2O7 + 7H2SO4
4K2SO4 + Cr2(SO4)3 + Na2SO4 + 3I2 + 7H2O
(4) 2NH3 + 2CrO3 N2 + Cr2O3 + 3H2O
Cu 36: Chn D.
0,93
- Ta c: C X 3,875 . V khi thy phn X trong NaOH thu c 2 ancol c cng cacbon v 2
0, 24
mui
Trong X c 1 cht l HCOOC2H5 (A), este n chc cn li l RCOOC2H5 (B), este 2 chc (C) c
to t etylenglicol C2H4(OH)2 v hai axit cacboxylic HCOOH; RCOOH (trong gc R c 1 lin kt i
C=C)
quan h
+ Lc ny kA = 1 ; kB = 2 ; kC = 3. p dng
CO v H O
n B 2n C n CO2 n H 2O 0,13 (1)
2 2
BT: O
2n A 2n B 4n C 2n CO2 n H 2O 2n O2 0,58 (2) v nA + nB + nC = 0,24 (3)
+ T (1), (2), (3) ta tnh c: nA = 0,16 mol ; nB = 0,03 mol ; nC = 0,05 mol
BT: C
3.0,16 0,03.CB 0,05.CC 0,93 (4) (vi CB > 4, CC > 5)
+ Nu CB = 5 thay vo (4) ta c: CC = 6 Tha (nu CB cng tng th CC < 6 nn ta khng cn xt na).
7, 25
Vy (B) l CH2=CH-COOC2H5: 0,03 mol %m C 13, 61
22, 04
Cu 37: Chn C.
t0
(1)C6H 4 (COONH3 ) 2 (CH2 )6 2NaOH C6H4 (COONa)2 (X1 ) NH2 (CH2 )6 NH2 (X2 )
(2)C6H4 (COONa) 2 (X1) H 2SO4
C6H 4 (COOH) 2 (X3 ) Na 2SO4
0
t
( OC(CH 2 ) 6 CONH(CH 2 ) 6 NH ) n 2nH 2O
nilon-6,6
0
t
(4) nC6H 4 (COOH)2 (X 3) nC2H 4 (OH)2 (X 5) ( OCC6H 4COOC2H 4O) n nH 2O
T lapsan
- Cht X3 l C6H4 (COOH)2 c 8 nguyn t C v X4 l HOOC(CH2 ) 4 COOH c 6 nguyn t C.

Cu 38: Chn A.
- Gi a l s mol ca NaCl. Qu trnh in phn xy ra nh sau:
Thi gian (s) Ti catot Ti anot
t = 3088 Cu 2+
+ 2e Cu 2Cl -
2e + Cl2
ne = 2x x 2x x 2x 2x x
t = 6176 Cu 2+
+ 2e Cu 2Cl -
2e + Cl2

ne = 4x = 0,32 0,16 0,32 0,16 a 0,5a
2H2O
4e + 4H + O2 +
0,32 - a 0,08 - 0,25a

Cu 2+
+ 2e Cu 2Cl -
2e + Cl2
0,2 0,4 0,2 0,2 0,2 0,1
t=?
2H2O + 2e 2OH- + H2 2H2O 4e + 4H+ + O2
2y y 2a (0,4 + 2y) - 0,2 0,5y + 0,05
- Ti thi im t = 3088 c: mdd gim 64nCu 71nCl 2 135x 10,8 x 0,06 mol
- Ti thi im t = 6176 (s) c: mdd gim 64nCu 71nCl 2 32nO2 18,3 a 0,2 mol
- Ti thi im t (s) c: mdd gim 64nCu 71nCl 2 32nO2 2nH 2 22,04 y 0,03 mol
0,46
ne(trao i) 2nCu 2nH 2 2.0,2 2.0,03 0,46 mol t .3088 8878(s)
0,16
Cu 39: Chn A.
4

BT:Na
n AlaNa,GlyNa, ValNa 2n Na 2CO3 0, 44 mol m n Ala, Gly,Val (1,5n CO 2 n O 2 ) n CO 2 0,99 mol
3
- Quy i hn hp E thnh C2H3ON, CH2 v H2O. Lp h sau:
57n C 2H 3ON 14n CH 2 18n H 2O 28, 42 n C 2H 3ON 0, 44
BT:C
2n C 2H 3ON n CH 2 n CO 2 0,99 n CH 2 3n Val n Ala 0,11
2, 25n n
C 2 H 3ON 1,5n CH 2 n O 2 1,155 H 2O n X n Y n Z 0,1
nGly,Ala,Val
nmc xch 4,4
nX nY nZ
Trong E c cha peptit c s mc xch ln 4,4 (5, 6 hoc 7). Vy Z l pentapeptit (Gly)4Ala, X l
ipeptit (Gly)2 v Y l ipeptit AlaVal (khng th l tripeptit (Gly)2Ala v khi thy phn hn hp E s
khng thu c mui ca Val).
BT:C
4n X 7n Y 11n Z n CO2 0,99 n X 0, 01
0, 01.132
- Ta c: 2n X 2n Y 5n Z 2n NaOH 0, 44 n Y 0, 01 %m X .100% 4, 64
132n 174n 317n 28, 42 28, 42
X Y Z n Z 0, 08
Cu 40: Chn B.
- Ti v tr kt ta khng i th: n Mg(OH) 2 2a
BT:Al n Al(OH)3
- Ti v tr kt ta t cc i th: n Al(OH)3 5a n Mg(OH) 2 3a n Al 2O3 1,5a
2
m 102n Al2O3 24n Mg 12,06 102a 3a.24 12,06 a 0,06 mol
nH (d ) nNaOH 4nAl(OH)3 2nMg(OH)2 17a 4.3a 2.2a 0,06 mol
+ Khi : nHCl 2nH2SO4 2nMg 6nAl 2O3 nH (d ) x 1, 2 n H 2SO4 0,12 mol; n HCl 0,6 mol
- Xt TH1 : Al(OH)3 t cc i. Gi V lt dung dch KOH, Ba(OH)2.
0,12mol 0,18mol 0,06mol 0,12mol 0,6mol 0,3V mol 0,1V mol 0,12mol 0,18mol 0,1V mol 0,12mol 0,09mol
t0
Mg2 , Al 3 , H ,SO42 , Cl NaOH ,Ba(OH) 2 Mg(OH) 2 ,Al(OH) 3 ,BaSO4 MgO ,Al 2 O3 ,BaSO
dung dch X dung dch hn h p hn h p kt ta hn h p rn
+ Ta c: nOH 2n Ba(OH)2 n KOH 3n Al(OH)3 2n Mg(OH)2 n H V 1,68 lt
+ Nhn thy: n Ba 2 nSO42 n BaSO4 (max) nSO42 0,12 mol
mrn 102n Al2O3 40n MgO 233n BaSO 4 41,94 gam
- V trng hp th lng Al(OH)3 v BaSO4 kt ta cc i nn ta khng xt trng hp tip theo.

TNH PH YN Mn: KHOA HC T NHIN HA HC
THPT NG GIA T Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Trong iu kin thch hp glucoz ln men to thnh kh CO2 v

A. CH3CHO. B. HCOOH. C. CH3COOH. D. C2H5OH.
Cu 2: Cht X c cng thc phn t C4H6O2. Khi X tc dng vi dung dch NaOH sinh ra cht Y c
cng thc phn t C3H3O2Na. Cht X c tn gi l
A. metyl acrylat. B. metyl metacrylat. C. metyl axetat. D. etyl acrylat.
Cu 3: Hn hp X gm C2H5NH2 v NH2C2H4NH2 . Cho 7,5 gam X tc dng va vi dung dch
H2SO4 thu c 17,3 gam mui. Phn trm khi lng ca C2H5NH2 trong X l :
A. 60. B. 90 C. 48 D. 72
Cu 4: iu kin thng, kim loi no sau y khng phn ng vi nc :
A. Rb. B. Na. C. Fe. D. Ca.
Cu 5: Cho 0,6 gam mt kim loi ho tr II phn ng ht vi dung dch H2SO4 long, d, thu c 0,56 lt H2
(ktc). Kim loi l
A. Ca. B. Zn. C. Mg. D. Sr.
(1) Amino axit l cc cht rn mu trng, kt tinh, tng i d tan trong nc.
(2) Cc amin c s cacbon nh hn hoc bng 3, n chc, mch h l cht kh mi khai ging NH3.
(3) Si bng, t tm v t olon thuc loi polime thin nhin.
(5) Saccaroz v mantoz ch c cu to mch vng
(8) Trng ngng axit aminoenantoic thu c nilon 6
S pht biu sai l
A. 4 B. 3 C. 5 D. 2
Cu 7: Trong bn polime cho di y, polime no cng loi polime vi t lapsan
A. T tm B. T nilon-6,6 C. Xenluloz trinitrat D. Cao su thin
nhin
Cu 8: Ho tan 5,4 gam bt Al vo 150 ml dung dch X cha Fe(NO3)3 1M v Cu(NO3)2 1M. Kt thc
phn ng thu c m gam rn. Gi tr ca m l
A. 10,95. B. 13,20. C. 13,80. D. 15,20.
Cu 9: Este X c cng thc phn t l C4H6O2 khi thy phn trong mi trng axit thu c ancol
c kh nng lm mt mu nc brom. Cng thc cu to thu gn ca X l:
A. CH3COO-CH=CH2 B. HCOO-CH=CH-CH3
C. HCOO-CH2CH=CH2 D. CH2=CH-COOCH3
Cu 10: Polime no sau y l polime nhn to ?
A. Xenluloz trinitrat B. PVC C. PE D. Cao su lu ha
Cu 11: Polime no sau y c cu trc mng khng gian ?
A. Cao su buna B. Aminoz C. Glicogen D. Cao su lu ha
Cu 12: N metyletanamin c cng thc l:
A. C2H5NHCH3 B. CH3NHCH3 C. CH3NH2 D. CH3NH2C2H5

Cu 13: Ha tan 6 gam glyxin vo 200 ml dung dch hn hp cha HCl 0,1M v H 2SO4 0,15M thu
c dung dch X. Cho 6,8 gam NaOH tan ht trong dung dch X c dung dch Y. Sau khi cc
phn ng hon ton, c cn Y thu c m gam cht rn khan. Gi tr ca m l:
A. 13,59 B. 14,08 C. 12,84 D. 15,04
Cu 14: Hp cht X khng no mch h c cng thc phn t C5H8O2, khi tham gia phn ng x
phng ho thu c mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph
hp vi X (khng k ng phn hnh hc)
A. 4 B. 5 C. 2 D. 3
Cu 15: Dy gm cc cht c xp theo chiu lc baz tng dn t tri qua phi l
A. C6H5NH2, NH3, CH3NH2. B. CH3NH2, C6H5NH2, NH3.
C. NH3, CH3NH2, C6H5NH2. D. CH3NH2, NH3, C6H5NH2.
Cu 16: phn bit cc dung dch ring bit: NaCl, MgCl2, AlCl3, FeCl3, c th dng dung dch
A. HCl. B. Na2SO4. C. NaOH. D. HNO3.
Cu 17: Peptit no sau y khng c phn ng mu biure?
A. Gly-Ala-Gly. B. Ala-Gly. C. Ala-Ala-Gly-Gly. D. Ala-Gly-Gly.
Cu 18: Cho cc cht CH3COOH (1), HCOO-CH2CH3 (2), CH3CH2COOH (3), CH3COO-CH2CH3 (4),
CH3CH2CH2OH (5). Dy cc cht sp xp theo th t nhit si gim dn l
A. (3) > (1) > (5) > (4) > (2). B. (3) > (5) > (1) > (4) > (2).
C. (1) > (3) > (4) > (5) > (2). D. (3) > (1) > (4) > (5) > (2).
Cu 19: Dung dch FeSO4 b ln CuSO4. Phng php n gin loi tp cht l:
A. Cho dung dch NH3 cho n d vo dung dch, lc ly kt ta Fe(OH)2 ri ha tan vo dung dch
H2SO4 long.
B. Cho mt l nhm vo dung dch.
C. Cho l ng vo dung dch.
D. Cho l st vo dung dch.
X to vi dung dch iot hp cht c mu xanh tm. Polime X l
A. tinh bt. B. xenluloz. C. saccaroz. D. glicogen.
Cu 21: Ha tan ht 17,76 gam hn hp X gm FeCl2, Mg, Fe(NO3)2 v Al vo dung dch cha 0,408
mol HCl thu c dung dch Y v 1,6128 lt kh NO (o ktc). Cho t t AgNO3 vo Y n phn ng
hon ton th thy lng AgNO3 phn ng l 0,588 mol, kt thc phn ng thu c 82,248 gam kt ta;
0,448 lt kh NO2 sn phm kh duy nht (o ktc) v dung dch Z ch cha m gam mui. Gi tr m gn
nht vi ?
Cu 22: Hp cht hu c X c cng thc phn t C 2H8O3N2. Cho X phn ng vi lng d dung dch
NaOH v un nng, thu c dung dch Y v 1 amin bc 2. Cng thc cu to ca X l:
A. CH3CH2NH3NO3. B. (CH3)2NH2NO3. C. H2NCH2NH3HCO3. D. HCOONH3CH3.
Cu 23: Cho dy cc kim loi: Cu, Ni, Zn, Mg, Ba v Ag. S kim loi trong dy phn ng vi dung
dch FeCl3 d to kt ta l
A. 5. B. 3. C. 1. D. 4.
Cu 24: Cho cc c im sau v phn ng este ho: (1) hon ton, (2) thun nghch, (3) to nhit
mnh, (4) nhanh, (5) chm. Phn ng este ho nghim ng cc c im ?
A. (1), (4). B. (2), (5). C. (1), (3), (4). D. (1), (3).
Cu 25: Khi t chy hon ton mt hp cht hu c X, thu c hn hp kh CO2 v hi nc c t l
mol l 1:1. Cht X c th ln men ru. Cht X l cht no trong cc cht sau?
A. etyl axetat. B. tinh bt. C. glucoz. D. sacacroz.
(a) Nhng thanh Fe vo dung dch CuSO4.
(b) Dn kh CO qua Fe2O3 nung nng.
(c) in phn dung dch NaCl bo ha, c mng ngn.
(d) t bt Fe trong kh oxi.

(e) Cho kim loi Ag vo dung dch HNO3 long.
(f) Nung nng Cu(NO3)2.
(g) Cho Fe3O4 vo dung dch H2SO4 c, nng.
S th nghim c xy ra s oxi ha kim loi l:
A. 2. B. 3. C. 4. D. 5.
Cu 27: Cht dng lm gia v thc n gi l m chnh hay bt ngt c cng thc cu to l
A. NaOOCCH2CH(NH2)CH2COONa. B. NaOOCCH2CH2CH(NH2)COONa.
C. HOOCCH2CH2CH(NH2)COONa. D. NaOOCCH2CH(NH2)CH2COOH.
Cu 28: Nh t t cho n d dung dch NaOH vo dung dch AlCl 3. Hin tng xy ra l:
A. c kt ta keo trng v c kh bay ln. B. c kt ta keo trng, sau kt ta tan.
C. khng c kt ta, c kh bay ln. D. ch c kt ta keo trng.
Cu 29: C cc dung dch sau (dung mi nc): CH 3NH2 (1), anilin (2), HOOCCH2CH(NH2)-COOH
(3), amoniac (4), H2NCH2CH(NH2)COOH (5), lysin (6), axit glutamic (7). S cht lm qu tm chuyn
thnh mu xanh l:
A. 3. B. 2. C. 5. D. 4.
Cu 30: X l este no, n chc, Y l este n chc, khng no cha mt ni i C = C (X, Y u mch
h). t cht 10,56 gam hn hp E cha X, Y cn dng 10,08 lt O2 (ktc) thu c 6,48 gam nc.
Mt khc, un nng 10,56 gam E vi dung dch NaOH va thu c mt ancol duy nht v hn hp
mui cha a gam mui A v b gam mui B (MA < MB). Bit A, B l cc mui ca cc axit cacboxylic.
T l a : b gn nht vi gi tr no sau y ?
A. 0,9 B. 1,2 C. 1,0 D. 1,5
Cu 31: t chy hon ton m gam FeS 2 bng mt lng O2 va , thu c kh X. Hp th ht X
vo 1 lt dung dch cha Ba(OH) 2 0,15M v KOH 0,1M thu c dung dch Y v 21,7 gam kt ta.
Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l :
A. 23,2 B. 12,6 C. 18,0 D. 24,0

A. Lin kt CONH gia hai n v -amino axit gi l lin kt peptit.
B. Cc peptit u cho phn ng mu biure.
C. Cc peptit u b thy phn trong mi trng axit hoc mi trng kim.
D. Cc peptit thng th rn, c nhit nng chy cao v d tan trong nc.
Cu 33: un nng 4,05 gam este X (C10H10O2) cn dng 35 gam dung dch KOH 8%, c cn dung
dch sau phn ng, thu c m gam mui. Gi tr m l:
Cu 34: un nng 121,5 gam xenluloz vi dung dch HNO 3 c trong H2SO4 c (dng d), thu
c x gam xenluloz trinitrat. Gi tr ca x l:
A. 222,75 gam B. 186,75 gam C. 176,25 D. 129,75
Cu 35: Th nghim no sau y khng to ra n cht ?
A. Cho bt nhm vo dung dch NaOH. B. Cho bt Cu vo dung dch AgNO 3.
C. Cho Na vo dung dch FeCl 2. D. Cho dung dch FeCl3 vo dung dch AgNO 3.
Cu 36: Cp cht no sau y u thuc loi polime tng hp ?
A. poli(metylmetacrylat) v amiloz. B. t visco v t olon.
C. t xenluloz axetat v t lapsan. D. poli(vinylclorua) v t nilon-6,6.
Cu 37: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi
l :
A. 8,96 B. 4,48 C. 10,08 D. 6,72
(1) Trong cc kim loi kim, xesi (Cs) c nhit nng chy thp nht.
(2) dn in ca nhm (Al) tt hn ca ng (Cu).
(3) Nhng kim loi c dn in tt th cng dn nhit tt.
(4) Crom (Cr) l kim loi cng nht trong cc kim loi.
(5) Wonfam (W) c nhit nng chy cao nht trong cc kim loi.
S nhn nh ng l:
A. 5 B. 3 C. 4 D. 2
Cu 39: Cho 8,96 gam bt Fe vo bnh cha 200 ml dung dch NaNO 3 0,4M v H2SO4 0,9M. Sau khi
kt thc cc phn ng, thm tip lng d dung dch Ba(OH) 2 vo bnh (khng c mt oxi), thu c
m gam rn khng tan. Bit kh NO l sn phm kh duy nht ca NO 3-. Gi tr ca m l:
Cu 40: Cho cc dung dch sau: HCl, Na2CO3, AgNO3, Na2SO4, NaOH v KHSO4. S dung dch tc
dng c vi dung dch Fe(NO3)2 l:
A. 4 B. 3 C. 6 D. 5
----------HT----------

THI TH THPT NG GIA T LN 1
Cu 1: Chn D.
ln men
C6H12O6 2 C2H 5OH 2CO2
Cu 2: Chn A.
- Phng trnh: CH 2 CH COOCH 3 (X) NaOH
CH 2 CH COONa(C3H 3O 2 Na) CH 3OH
Metyl acrylat
Cu 3: Chn A.
BTKL mmui mX
nH 2SO4 0,1mol . Xt trng hp to mui trung ha ta c:
98
45n C 2H 5 NH 2 60n C 2H 4 (NH 2 ) 2 m X 7,5
n C 2H 5 NH 2 0,1 mol
%mC2H5NH2 60
n C 2H 5 NH 2 2n C 2H 4 (NH 2 ) 2 2n H 2SO 4 0, 2 n C 2H 4 (NH 2 ) 2 0, 05 mol

Cu 4: Chn C.
Cu 5: Chn C.
BT: e 0,6
2nKL 2nH 2 nkim loi 0,025 M kim loi 24 : Mg
0,025
Cu 6: Chn D.
(3) Sai, T olon thuc loi t nhn to.
(8) Sai, Trng ngng axit aminocaproic thu c nilon 6.
Cu 7: Chn B.
- T lapsan thuc loi t tng hp vy trong 4 loi t trn th t nilon - 6,6 cng loi vi t lapsan.
Cu 8: Chn C.
- Qu trnh : Al Fe(NO3 )3 ,Cu(NO3 ) 2 Al 3 ,Fe2 , NO3 Fe,Cu

0,2mol dung dch X dung dch sau p m(g) rn
BTDT nNO3 3nAl 3 BT:Fe

nFe2 0,075 mol nFe(rn) nFe(NO3 )3 nFe2 0,075 mol
dd sau p 2
mrn 64nCu 56nFe 0,15.64 0,075.56 13,8(g)
Cu 9: Chn C.
H SO

2
- Phn ng: HCOO-CH2CH=CH2 + H2O
4
HCOOH + CH2=CH-CH2-OH
o
t
CH2=CH-CH2-OH + Br2 Br-CH2-CH(Br)-CH2-OH

Cu 10: Chn A.
Cu 11: Chn D.
Cu 12: Chn A.
Hp cht Tn gc chc Tn thay th
CH3-CH2-NH-CH3 Etylmetylamin N-metyletanamin
Cu 13: Chn A.
- Gp cc qu trnh li khi hn hp ban u s l glyxin: 0,08 mol; HCl: 0,02 mol; H 2SO4: 0,03
mol tc dng dng vi dung dch NaOH: 0,17 mol.
m nNaOH p = n H2O n gly 2n H2SO4 n HCl 0,16 mol
BTKL
mrn = mGly 36,5n HCl 98n H 2SO4 + mNaOH 18n H 2O 13,59 (g)
Cu 14: Chn A.
- X l este khng no, mch h, n chc trong phn t c 1 lin kt C=C, khi tham gia phn ng x
phng ho thu c mt anehit v mt mui ca axit hu c nn X c dng: RCOOCH=CH-R.

C 4 CTCT ca X l:
HCOOCH=CH-C2H5 ; HCOOCH=C-(CH3)2 ; CH3COOCH=CH-CH3 ; C2H5COOCH=CH2.
Cu 15: Chn A.
- Dy sp xp tnh baz tng dn: C6H5NH2 < NH3 < CH3NH2.
Cu 16: Chn C.
Thuc th NaCl MgCl2 AlCl3 FeCl3
HCl Khng hin tng Khng hin tng Khng hin tng Khng hin tng
Na2SO4 Khng hin tng Khng hin tng Khng hin tng Khng hin tng
NaOH d Khng hin tng Kt ta trng Kt ta trng keo, Kt ta nu
sau tan.
HNO3 Khng hin tng Khng hin tng Khng hin tng Khng hin tng
Cu 17: Chn B.
Cu 18: Chn A.
Vy dy sp xp theo nhit si gim dn l: (3) > (1) > (5) > (4) > (2).
Cu 19: Chn D.
A. Sai, Cho dung dch NH3 cho n d vo dung dch, lc ly kt ta Fe(OH) 2 ri ho tan vo dung
B. Sai, Cho mt l nhm vo dung dch th khng loi b c CuSO 4.
D. ng, loi b CuSO4 ra khi dung dch ta cho l Fe vo dung dch vi mc ch loi b Cu2+ ra
khi dung dch.
Cu 20: Chn A.
- Phng trnh ha hc n gin biu din qu trnh quang hp ca cy xanh:
nh s ng
6nCO2 + 5nH2O (C6H10O5)n (X) + 6nO2
clorophin
- Khi cho tinh bt to vi dung dch iot to hp cht c mu xanh tm.
Cu 21: Chn D.
108nAg 143,5nAgCl m
108nAg 143,5nAgCl 82,248
nAg 0,06mol
BT:Ag
nAg nAgCl nAgNO3
nAg nAgCl 0,588
nAgCl 0,528mol

BT:Cl nAgCl nHCl
nFeCl 2 0,06mol
2
- Xt dung dch Y ta c :
n 4nNO 2nNO2 nNO nNO2 nNH 4
nNH 4 HCl 0,008mol nFe(NO3 )2 0,04mol
10 2
- Dung dch Z gm Fe3+, Mg2+, Al3+, NH4+ v NO3-. Xt dung dch Z ta c :
+ nNO3 nAgNO3 nNO 0,568mol v mion kim loi mX 71nFeCl 2 2.62nFe(NO3)2 8,54(g)
mmui mion kim lo i 18nNH 4 62nNO3 43,9(g)
Cu 22: Chn B.
- Phng trnh: (CH3)2NH2NO3 + NaOH NaNO3 + (CH3)2NH + H2O
Cu 23: Chn C.
- Khi dng mt lng d FeCl3 th cc kim loi Cu, Ni, Zn, Mg, Fe xy ra phn ng:
M + 2FeCl3
MCl2 + 2FeCl2
- Khi cho Ba vo dung dch FeCl3 th: 3Ba + 6H2O + 2FeCl3 3BaCl2 + 2Fe(OH)3 nu + 2H2
Cu 24: Chn B.
- Phn ng este ha l phn ng thun nghch xy ra chm iu kin thng.
Cu 25: Chn C.

0
t ln men
- Phng trnh: C6H12O6 6O2 6CO2 6H 2O ; C6H12O6 2CO2 2C2H 5OH
Cu 26: Chn B.
(a) Fe + CuSO4
FeSO4 + Cu
t0
(b) 3CO + Fe2O3 2Fe + 3CO2
pdd
(c) 2NaCl + 2H2O
2NaOH + Cl2 + H2
coma
ng nga
n
t0
(d) 6Fe + 4O2 2Fe3O4
(e) 3Ag + 4HNO3
3AgNO3 + NO + 2H2O
t0
(f) 2Cu(NO3)2 2CuO + 4NO2 + O2
t0
(g) 2Fe3O4 + 10H2SO4(c, nng) 3Fe2(SO4)3 + SO2 + 10H2O
- C 3 th nghim xy ra s oxi ha kim loi l (a), (d) v (e).
Cu 27: Chn C.
Cu 28: Chn B.
- Khi cho NaOH d vo dung dch AlCl 3:
+ Ban u : 3NaOH + AlCl3
3NaCl + Al(OH)3(trng keo)
+ Sau : NaOH(d) + Al(OH)3(trng keo) NaAlO2(tan) + H2O
Cu 29: Chn D.
- Cc amin lm qu tm ha xanh; dung dch anilin v ng ng ca anilin khng lm i mu qu tm.
- Tc dng ln thuc th mu ca cc aminoaxit: (H2N)x R (COOH)y. Khi:
x = y th amino axit trung tnh, qu tm khng i mu.
x > y th amino axit c tnh baz, qu tm ha xanh.
x < y th amino axit c tnh axit, qu tm ha .
Vy c 4 dung dch lm qu tm ha xanh l (1), (4), (5) v (6).
Cu 30: Chn C.
- Khi t 10,56 gam E th :
m 32nO2 mH2O nO(trongE) mE 12nCO2 2nH2O

BTKL
nCO2 E 0,42mol nE 0,15mol
44 2 2.16
- p dng bt bo trong phn ng chy c :
nY nCO2 nH2O 0,06mol nX nE nY 0,09mol
- Gi CX v CY ln lt l s nguyn t C ca hai este X v Y (vi CY 4) ta c :

BT:C
nX .CX nY .CY nCO2 0,09CX 0,06CY 0,42 CX 2 v CY 4 (tha)
Vy X l HCOOCH3 (0,09 mol) v Y l CH2=CH-COOCH3 (0,06 mol)
mHCOONa
- Ta c : mHCOONa 0,09.68 6,12(g) v mC2H3COONa 5,64(g) 1,085
mC2H3COONa
Cu 31: Chn C.
- Nhn thy rng nBaSO3 nBa2 v cho dung dch tc dng vi NaOH xut hin thm kt ta.
nOH n
nn nSO2 nOH nSO2 nOH nSO32 0,3mol nFeS2 SO2 0,15mol mFeS2 18(g)
2 2
Cu 32: Chn B.
- Cc peptit c t hai lin kt peptit tr ln (tc l tripeptit) mi tham gia phn ng mu biure.
Cu 33: Chn B.
- X tc dng vi KOH th: RCOOC6H 4R' 2KOH
RCOOK KOC6H 4R' H 2O
0,025mol 0,05mol 0,025mol
BTKL
mmui mX 56nKOH 18nH2O 6,4(g)

Cu 34: Chn A.
H SO
- Phn ng: C6H 7O2 (OH)3 3HONO2
2 4
C6H 7O2 (ONO2 )3 3H 2O
0,75mol 0,75mol
mC6H 7O2 (ONO2 )3 0,75.297 222,75(g)

Cu 35: Chn D.
A. 2Al + 2NaOH + 2H2O
2NaAlO2 + 3H2
B. Cu + 2AgNO3
Cu(NO3)2 + 2Ag
C. 2Na + FeCl2 + 2H2O
2NaCl + Fe(OH)2 + H2
D. FeCl3 + 3AgNO3 Fe(NO3)3 + 3AgCl
Cu 36: Chn D.
Cu 37: Chn A.
- Ta c ne(max) 2nCu nFe(NO3 )2 1,2mol
- Qu trnh kh NO3- xy ra nh sau : NO3 3e 4H NO 2H2O
nemax
- Da vo phng trnh ta suy ra: VNO 22,4.nNO 22,4. 8,96(l)
3
Cu 38: Chn C.
(1) ng, Trong nhm IA th cc kim loi kim c nhit nng chy gim n t trn xung v vy
xesi (Cs) c nhit nng chy thp nht trong nhm IA.
(2) Sai, dn in gim dn theo dy sau : Ag > Cu > Au > Al > Fe
(3) ng, Hu ht cc kim loi c dn in tt th cng dn nhit tt.
(4) ng, Crom (Cr) l kim loi cng nht trong cc kim loi nn c dng m ln cc thit b
bng kim loi.
(5) ng, Wonfram c nhit nng chy cao nht (3410 0C) v vy Wonfam (W) c dng
lm dy tc bng n.
Vy c 4 pht biu ng l (1), (3), (4) v (5).
Cu 39: Chn B.
- Khi cho 0,16 mol Fe tc dng vi dung dch hn hp gm 0,08 mol NaNO 3 v 0,18 mol H2SO4 ta
c cc qu trnh phn ng xy ra nh sau:
S oxi ha S kh
Fe2 2e
Fe NO3 4H 3e
NO 2H 2O
0,08mol 0,36mol 0,24mol 0,08mol
2H 2e
H2
0,04mol 0,04mol 0,02mol
3nNO 2nH2
BT:e
nFe2 0,14mol
2
- Khi cho dung dch thu c tc dng vi lng d dung dch Ba(OH) 2 th:
nFe(OH)2 nFe2 0,14mol v nBaSO4 0,18mol m 90nFe(OH)2 233nBaSO4 54,54(g)
Cu 40: Chn D.
(1) 3Fe 2 4H NO3
3Fe3 NO 2H 2O
(2) Fe(NO3 ) 2 Na 2CO3
FeCO3 2NaNO3
(3) Fe(NO3 ) 2 AgNO3
Fe(NO3 )3 Ag
(4) Fe(NO3 ) 2 2NaOH
Fe(OH) 2 2NaNO3
(5) 3Fe 2 4H NO3
3Fe3 NO H 2O
Vy c 5 dung dch tc dng c vi Fe(NO 3)2 l HCl, Na2CO3, AgNO3, NaOH v KHSO4.

TNH K LK Mn: KHOA HC T NHIN HA HC
THPT NG GIA T Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Amin no sau y thuc loi amin bc hai

A. Trimetylamin. B. Metylamin. C. Phenylamin. D. imetylamin.
Cu 2: Trong phn ng este ho gia ancol etylic v axit axetic, axit sunfuric khng ng vai tr:
A. lm cht xc tc B. lm chuyn dch cn bng.
C. lm cht oxi ho. D. lm cht ht nc.
Cu 3: X phng ha hon ton cht bo X trong NaOH (d) un nng thu c 9,2 gam glixerol v
91,2 gam mt mui natri ca axit bo. Tn ca X l
A. tristearin. B. triolein. C. tripanmitin. D. trilinolein.
Cu 4: oxi ha hon ton 0,1 mol hn hp gm Fe v Cr cn dng va V lt O2 (kc). Gi tr ca
V l
A. 2,240 lt . B. 1,680 lt. C. 1,120 lt . D. 2,688 lt.
Cu 5: Cho bit phn ng no khng xy ra nhit thng
A. Mg(HCO3)2 + 2Ca(OH)2
Mg(OH)2 + 2CaCO3 + 2H2O
B. Ca(OH)2 + NaHCO3
CaCO3 + NaOH + H2O
C. Ca(OH)2 + 2NH4Cl
CaCl2 + 2H2O + 2NH3
D. CaCl2 + NaHCO3 CaCO3 + NaCl + HCl.
Cu 6: Loi t no sau y khi t chy hon ton ch thu c CO 2 v H2O.
A. Nilon-6,6 B. T olon C. T tm D. T lapsan
Cu 7: Este X khng tc dng vi Na. X tc dng dd NaOH thu c mt ancol duy nht l CH 3OH
v mui natri aipat. CTPT ca X l:
Cu 8: Trong cc tn gi di y, cht no c lc baz mnh nht ?
A. NH3 B. C6H5CH2NH2 C. C6H5NH2 D. (CH3)2NH
Cu 9: Cho 3,05 gam phenylfomat vo 600 ml dung dch NaOH 0,1M. Sau khi cc phn ng hon
ton, c cn dung dch thu c m gam rn khan. Gi tr ca m l:
A. 4,6 B. 5,2 C. 5,0 D. 3,1
Cu 10: Mt hp cht hu c A c cng thc C3H9O2N. Cho A phn ng vi dd NaOH, un nh, thu
c mui B v kh C lm xanh qu m. Nung B vi NaOH rn (xc tc CaO) thu c mt
hidrocacbon n gin nht. CTCT ca A l:
A. CH3COONH3CH3 B. H2NCH2COOCH3 C. HCOONH3CH2CH3. D. HCOONH2(CH3)2.
A. Cho dung dch Ca(OH)2 tc dng vi dung dch Na2CO3.
B. in phn dung dch NaCl c mng ngn xp, in cc tr.
C. Sc kh NH3 vo dung dch Na2CO3.
D. Cho Na2O tc dng vi nc.
Cu 12: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1
mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v
tripeptit Gly-Ala-Val. Peptit X c th l:
A. Gly-Ala-Val-Val-Phe. B. Gly-Ala-Val-Phe-Gly.
C. Gly-Phe-Gly-Ala-Val. D. Val-Phe-Gly-Ala-Gly.
Cu 13: St ty l st trng thic. Nu lp thic b xc su ti lp st th kim loi b n mn trc l:
A. c hai u b n mn nh nhau. B. thic.
C. khng kim loi no b n mn. D. st.
A. Cht bo l este ca glixerol v cc axit bo.
B. Hiro ha hon ton triolein hoc trilinolein u thu c tristearin.
C. Du m ng thc vt b i thiu do ni i C = C gc axit khng no ca cht bo b oxi ha chm
bi oxi khng kh to thnh peoxit, cht ny b phn hy thnh cc sn phm c mi kh chu.
D. Cht bo nh hn nc v khng tan trong nc.
Cu 15: Chia 2m gam hn hp X gm 2 kim loi c ho tr khng i thnh 2 phn bng nhau. Cho
phn mt tan ht trong dung dch HCl (d) thu c 2,688 lt H 2 (ktc). Nung nng phn hai trong oxi
A. 1,17. B. 4,68. C. 2,34. D. 3,51.
Cu 16: un nng este CH3OOCCH=CH2 vi mt lng va dung dch NaOH thu c sn phm
A. CH3COONa v CH2=CHOH. B. CH2=CHCOONa v CH3OH
C. CH3COONa v CH3CHO. D. C2H5COONa v CH3OH
Cu 17: Phng trnh ha hc no sau y l sai ?
A. Na2SO4 + Mg(HCO3)2 MgSO4 + 2NaHCO3 B. Ca + 2HCl CaCl2 + H2
C. Fe + CuSO4 FeSO4 + Cu. D. CaCO3 + CO2 + H2O Ca(HCO3)2.
Cu 18: Khi cho lng d dung dch NaOH vo ng nghim ng dung dch kali icromat, dung dch
trong ng nghim
A. Chuyn t mu vng sang mu . B. Chuyn t mu vng sang mu da cam.
C. Chuyn t mu da cam sang mu vng. D. Chuyn t mu da cam sang mu xanh lc.
A. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
B. Trong phn t tetrapeptit mch h c 4 lin kt peptit.
C. Trong mi trng kim, ipeptit mch h tc dng vi Cu(OH) 2 cho hp cht mu tm.
D. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu.
Cu 20: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl d thu c dung dch Y
v phn khng tan Z. Cho Y tc dng vi dung dch NaOH long, d thu c kt ta g ?
A. Fe(OH)3. B. Fe(OH)2 v Cu(OH)2.
C. Fe(OH)2, Cu(OH)2 v Zn(OH)2. D. Fe(OH)3 v Zn(OH)2.
Cu 21: Hn hp rn Ca(HCO3)2, NaOH v Ca(OH)2 c t l s mol tng ng ln lt l 2 : 1 : 1.
Khuy k hn hp vo bnh ng nc d. Sau phn ng trong bnh cha ?
A. CaCO3, NaHCO3. B. Na2CO3. C. NaHCO3. D. Ca(OH)2.
Cu 22: X, Y, Z l ba peptit mnh h, c to t Ala, Val. Khi t chy X, Y vi s mol bng nhau
th u c lng CO2 l nh nhau. un nng 37,72 gam hn hp M gm X, Y, Z vi t l mol tng
ng l 5 : 5 : 1 trong dung dch NaOH, thu c dung dch T cha 2 mui D, E vi s mol ln lt l
0,11 mol v 0,35 mol. Bit tng s mt xch ca X, Y, Z bng 14. Phn trm khi lng ca Z trong M
gn nht vi ?
A. 14% B. 8% C. 12% D. 18%
A. Trong hp cht, tt c cc kim loi kim th u c s oxi ha +2.
B. Trong nhm IIA, tnh kh ca cc kim loi gim dn t Be n Ba.
C. Tt c cc hiroxit ca kim loi nhm IIA u d tan trong nc.
D. Tt c cc kim loi nhm IA u c mng tinh th lp phng tm din.
Cu 24: Cho m gam hn hp A gm Fe v Zn vo 200 ml dung dch cha AgNO 3 0,18M v Cu(NO3)2
0,12M, sau mt thi gian thu c 4,21 gam cht rn X v dung dch Y. Cho 1,92 gam bt Mg vo
dung dch Y, sau khi phn ng xy ra hon ton, thu c 4,826 gam cht rn Z v dung dch T. Gi tr

ca m l:
A. 3,124. B. 2,648. C. 2,700. D. 3,280.
Cu 25: Cho hn hp gm Al, BaO v Na2CO3 (c cng s mol) vo nc d thu c dung dch X v
cht kt ta Y. Cht tan trong dung dch X l
A. NaAlO2 B. NaOH v Ba(OH)2 C. Ba(AlO2)2 v Ba(OH)2 D. NaOH v NaAlO2
Cu 26: Trong cc nhn xt di y, nhn xt no ng
A. Dung dch cc amino axit c th lm i mu qu tm sang , xanh hoc khng lm i mu.
B. Dung dch cc amino axit u lm i mu qu tm sang xanh.
C. Dung dch cc amino axit u khng lm i mu qu tm.
D. Tt c cc peptit u tc dng vi Cu(OH)2 trong mi trng kim to ra hp cht c mu tm.
Cu 27: Sc t t kh CO2 vo dung dch natri aluminat n d th
A. khng c phn ng xy ra B. to kt ta Al(OH)3, phn dd cha Na2CO3
C. to kt ta Al(OH)3, phn dd cha NaHCO3 D. to kt ta Al(OH)3, sau kt ta b ha tan
li.
Cu 28: Cho V lt dung dch NaOH 0,5M vo dung dch cha 0,1 mol AlCl3 v 0,1 mol H2SO4 n khi
phn ng hon ton, thu c 5,85 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l
A. 1,05 B. 0,85 C. 0,45 D. 0,525
Cu 29: Khi thy phn tripeptit: H2N-CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc -
amino axit no
A. H2NCH2COOH, CH3CH(NH2)COOH. B. H2NCH(CH3)COOH, H2NCH(NH2)COOH.
C. H2NCH2CH(CH3)COOH, H2NCH2COOH. D. CH3CH(NH2)CH2COOH, H2NCH2COOH.
Cu 30: Cho s phn ng sau:
o
Este X (C6H10O4) + 2NaOH
t
X 1 + X2 + X3
o
X2 + X3
H2SO4 , t
C 3 H8 O + H 2 O
Nhn nh no sau y l sai ?
A. X c hai ng phn cu to.
B. T X1 c th iu ch CH4 bng 1 phn ng.
C. X khng phn ng vi H2 v khng c phn ng trng bc.
D. Trong X cha s nhm -CH2- bng s nhm CH3.
Cu 31: t chy hon ton a gam triglixerit X cn va 3,2 mol O2, thu c 2,28 mol CO2 v
2,08 mol H2O. Mt khc, cho a gam X vo 500 ml NaOH 0,3M, sau phn ng c cn dung dch thu
c cht rn cha m gam mui khan. Gi tr ca m l:
A. 43,14. B. 37,12. C. 36,48. D. 37,68.
lng glucoz cn dng l
Cu 36: Mt mu kh thi c sc vo dung dch CuSO4, thy xut hin kt ta mu en. Hin tng
ny do trong kh thi c ?
A. NO2. B. H2S. C. CO2. D. SO2.
Cu 37: Cho 7,65 gam hn hp X gm Al v Al2O3 tan hon ton trong dung dch HCl va thu
c dung dch Y v 5,712 lt kh (ktc) v dung dch Y. Cho 500 ml dung dch gm Ba(OH) 2 0,6M
v NaOH 0,74M tc dng vi Y thu c dung dch Z. Nh t t dung dch H2SO4 2M vo dung dch
Z th nhn thy khi lng kt ta ln nht khi thm V ml dung dch. Gi tr ca V l
A. 140. B. 70. C. 120. D. 150.
Cu 38: in phn 500 ml dung dch X gm NaCl 0,4M v Cu(NO3)2 0,3M (in cc tr, mng ngn
xp) n khi khi lng dung dch gim 15,1 gam th ngng in phn (gi thit lng nc bay hi
khng ng k). Khi lng kim loi thot ra catot (gam) l
A. 7,68. B. 15,10. C. 6,40. D. 9,60.
Cu 39: Cho 360 gam glucoz ln men to thnh ancol etylic, kh sinh ra c dn vo nc vi trong
d thu c m gam kt ta. Bit hiu sut ca qu trnh ln men t 80%. Gi tr ca m l
A. 320. B. 200. C. 160. D. 400.
Cu 40: So snh tnh cht ca glucoz, tinh bt, saccaroz v xenluloz.
(1) C 4 cht u d tan trong nc v u c cc nhm -OH.
(2) Tr xenluloz, cn li glucoz, tinh bt, saccaroz u c th tham gia phn ng trng bc.
(3) Tinh bt, saccaroz v xenluloz u c cu to bi cc gc glucz
(4) Glucoz v saccarz u kt tinh khng mu.
Trong cc so snh trn, s so snh khng ng l
A. 4. B. 1. C. 2. D. 3.
----------HT----------

THI TH THPT NG GIA T LN 1
Cu 1: Chn D.
NH(CH3)2 (imetyl amin) l amin bc 2.
Cu 2: Chn C.
Cu 3: Chn B.
- Ta c: n RCOONa 3n C3H5 (OH)3 0,3 mol M RCOONa 304 : C17 H33COONa
Cu 4: Chn B.
BT:e 3(n Fe n Cr )
n O2 0, 075 mol VO 2 1, 68(l)
4
Cu 5: Chn D.
0
CaCl2 + NaHCO3 t
CaCO3 + NaCl + HCl.
Cu 6: Chn D.
- Khi t chy hon ton nilon-6,6, t olon, t tm thu c CO2, H2O v N2.
- Khi t chy hon ton t lapsan thu c CO2, H2O.
Cu 7: Chn A.
H SO

2
- Phn ng: HOOC-(CH2)4-COOH + 2CH3OH
4
H3COOC-(CH2)4-COOCH3 + 2H2O
o
t
Cu 8: Chn D.
- Dy sp xp tnh baz gim dn: (CH3)2NH > C6H5CH2NH2 > NH3 > C6H5NH2
Cu 9: Chn C.
- Nhn thy: n HCOOC6H5 0,025 mol n NaOH 0,06 mol n H2O 0,025 mol
BTKL
m mHCOOC6H5 40n NaOH 18n H2O 5 (g)
Cu 10: Chn A.
0
- Phng trnh: CH3COONH3CH3 + NaOH
t
CH3COONa (Y) + CH3NH2 (Z) + H2O
0
CH3COONa (Y) + NaOH
CaO,t
CH4 + Na2CO3
Cu 11: Chn C.
A. Ca(OH)2 + Na2CO3
CaCO3 + 2NaOH
pdd
B. 2NaCl + 2H2O
2NaOH + Cl2 + H2
coma
ng nga
n
C. NH3 + Na2CO3 : khng c phn ng
D. Na2O + H2O 2NaOH
Cu 12: Chn B.
- Ghp cc on mch vi nhau ta thu c X l: Gly-Gly-Ala-Val-Phe hoc Gly-Ala-Val-Phe-Gly
Cu 13: Chn D.
Cu 14: Chn A.
A. Sai, Cht bo l trieste ca glixerol v cc axit bo.
(C17 H 33COO)3 C3H 5 3H 2 Ni,t o
B. ng, Phn ng: (C17 H 35COO)3 C3H 5
(C17 H 31COO)3 C3H 5 6H 2
C. ng, Du m ng thc vt b i thiu do ni i C=C gc axit khng no ca cht bo b oxi ha
D. ng, Cht bo nh hn nc v khng tan trong nc.
Cu 15: Chn C.
BT: e
2n M 2n H 2 4n O2 n O2 0,06 mol . Vy m m oxit 32n O 2 2,34 (g)

Cu 16: Chn B.
- Phn ng: CH=CH2COOCH3 + NaOH
CH=CH2COONa + CH3OH

Cu 17: Chn A.
Cu 18: Chn C.
Cu 19: Chn D.
A. Sai, Cc hp cht peptit km bn c trong mi trng baz ln trong mi trng axit.
B. Sai, Trong phn t tetrapeptit mch h c 3 lin kt peptit.
C. Sai, Trong mi trng kim, ipeptit mch h khng tc dng vi Cu(OH) 2.
D. ng, Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu.
Cu 20: Chn B.
HCl NaOH
- Qu trnh: Fe2O3,ZnO,Cu FeCl 2 ,ZnCl 2 ,CuCl 2
Fe(OH)2 ,Cu(OH)2
Ho
n hp X dung dch Y ke
t tu
a
- Lu : Phn Z khng tan l Cu chng t Cu kh FeCl 3 v FeCl2 v khi cho ZnCl2 vo dung dch
NaOH long d th kt ta Zn(OH) 2 tan ht.
Cu 21: Chn A.
- Da vo t l s mol ta c cc phn ng xy ra nh sau:
Ca(HCO3)2 + Ca(OH)2
2CaCO3 + 2H2O
Ca(HCO3)2 + NaOH CaCO3 + NaHCO3 + H2O
Vy trong bnh cha CaCO 3 v NaHCO3.
Cu 22: Chn C.
- Khi gp X, Y v Z vi t l mol tng ng l 5 : 5 : 1 c 5X 5Y Z
X5Y5 Z 10H 2O
nD 0,11 11
+ Ta c X5Y5 Z l (D)11k (E)35k .
nE 0,35 35
m s mc xch(min) < s mc xch ca X 5Y5Z < s mc xch(max) 14.1 46k 14.5 k 1
14.nZ 11k 35k 14.nX
nE nB nX nY 5nX 5Y5Z 0,05mol

+ Vi k = 1 n(D)11k (E)35k nX 5Y5Z 0,01mol
11 35 nZ nX 5Y5Z 0,01mol
t0
- Khi cho 37,72 gam M tc dng vi NaOH th : M NaOH D E H 2O
+ Vi nH2O nM nX nY nZ 0,11mol v nNaOH nA nB 0,46mol
BTKL
mE mD mM 40n NaOH 18n H2O 54,14( g)
- Xt hn hp mui ta c :
m E m D 139n D
+ Gi s D l ValNa khi ta c M E 111 (AlaNa). Vy ta gi s ng.
nE
n Val 0,11
+ S mt xch Val 1 X, Y v Z u c 1 phn t Val
n X,Y,Z 0,11
X : (Ala)x Val : 0,05 mol

BT: Ala
0,05x 0,05y 0,01z 0,35 x y 3
Hn hp M: Y : (Ala) y Val : 0,05 mol
Z : (Ala) Val : 0,01mol s mc xch=(x 1) (y 1) (z 1) 14 z 5
z
0,01.472
Vy Z l (Ala)5Val, suy ra %mZ .100 12,5
37,72
Cu 23: Chn A.
B. Sai, Trong nhm IIA, tnh kh ca cc kim loi tng dn t Be n Ba.
C. Sai, Mg(OH)2 kt ta v Ca(OH)2 t tan trong nc.
D. Sai, Tt c cc kim loi nhm IA u c mng tinh th lp phng tm khi.
Cu 24: Chn C.
- Khi cho hn hp A gm Fe, Zn tc dng vi dung dch cha AgNO 3, Cu(NO3)2 th:

BTKL
m Y m 170n AgNO3 188n Cu(NO3 ) 2 m X 6, 422 m (1)
- Cho 0,08 mol bt Mg vo dung dch Y thu c dung dch T c cha Mg2+, NO3 v c th c cha
thm cc cation kim loi trong dung dch Y.
+ Theo gi thit: n Mg n Mg 2 0, 08 mol v n NO3 2n Cu(NO3 )2 n AgNO3 0,084 mol
+ Nhn thy: 2 n Mg 2 > n NO3 (v l v khng tha mn BTT)
Dung dch T ch cha Mg(NO3)2: 0,042 mol
BTKL
m Y 24n Mg 148n Mg(NO3 ) 2 m Z , thay (1) vo ta tnh c: m 2, 7 (g)
Cu 25: Chn D.
- Gi 1 mol mi cht trong hn hp ban u.
+ u tin: BaO + H2O
Ba(OH)2
mol: 1 1
+ Sau : Ba(OH)2 + Na2CO3
BaCO3 + 2NaOH
mol: 1 1 1 2
2NaOH + 2Al + 2H2O 2NaAlO2 + 3H2
mol: 2 1 1
Kt ta Y l BaCO3 v dung dch X gm NaOH d: 1 mol ; NaAlO2: 1 mol.
Cu 26: Chn A.
B v C. Sai, NH2CH2COOH (glyxin), NH2CH(CH3)COOH (alanin) khng lm i mu qu tm hoc
NH2C3H5(COOH)2 (axit glutamic) lm qu tm ha .
D. Sai, t tripeptit tr ln th mi c kh nng phn ng mu biure vi Cu(OH)2.
Cu 27: Chn C.
CO2 + NaAlO2 + 2H2O NaHCO3 + Al(OH)3
Cu 28: Chn A.
- VNaOH t gi tr ln nht th lng kt ta phi t cc i sau tan li mt phn
n NaOH 2n H 2SO 4 (4n AlCl3 n Al(OH)3 ) 0,525 mol VNaOH 1, 05(l)
Cu 29: Chn A.

H2N-CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH + 2H2O
H
2H2NCH2COOH +
CH3CH(NH2)COOH
Cu 30: Chn A.
- Khi un vi H2SO4 c thu c sn phm c H2O nn CTCT ca C3H8O l CH3OC2H5 X2, X3 ln
lt l CH3OH v C2H5OH.
Vy este X c to ra t axit no, mch h, 2 chc v 2 ancol CH3OH, C2H5OH.
H3COOCCH2COOC2H5 (X) 2NaOH NaOOCCH2COONa (X1) CH3OH (X2 ) C2H5OH (X3 )
A. Sai, X ch c 1 ng phn cu to duy nht.
CaO
B. ng, Phng trnh: NaOOCCH 2COONa 2NaOH
o CH 4 2Na 2 CO3
t
C. ng.
D. ng, Trong X c 1 nhm -CH2- v 1 nhm CH3.
Cu 31: Chn D.
BT:O n O (X) 2n CO2 n H 2O 2n O2
nX 0, 04 mol
- Khi t X: 6 6

BTKL
a m CO2 18n H 2O 32n O2 35,36 (g)

- Cho m1 (g) X tc dng vi NaOH th: n X n C3H5 (OH)3 0, 04 mol
BTKL
m a 40n NaOH 92n C3H5 (OH)3 37, 68 (g)

Cu 32: Chn C.
Cu 33: Chn D.
Cu 34: Chn B.
nCO2
nC6H12O6 0,3125mol mC6H12O6 56,25(g)
2H%
Cu 35: Chn C.
v trnh gi.
Cu 36: Chn B.
- Phn ng: CuSO4 + H2S CuS den + H2SO4
Cu 37: Chn D.
2n m 27nAl
- Khi cho X tc dng vi HCl th
BT:e
nAl H2 0,17mol nAl 2O3 X 0,03mol .
3 102
Vy dung dch Y ch cha 0,23 mol AlCl3
- Khi cho Y tc dng vi dung dch hn hp cha Ba(OH) 2 v NaOH th :
0,23mol 0,3mol 0,34mol 0,3mol 0,34mol 0,23mol 0,69mol
Ba2 , Na ,AlO2 , Cl ,OH

AlCl 3 Ba(OH)2 ,NaOH
dung dch Y dung dch Z
- Nhn thy rng 4nAl 3 2nBa(OH)2 nNaOH nn ton b lng Al3+ chuyn thnh AlO2-.
- Xt dng dch Z ta c
BTDT
nOH 2nBa2 nNa nAlO2 nCl 0,05mol
- Khi cho H2SO4 tc dng vi dung dch Z n khi lng kt ta cc i th xy ra hai trng hp sau :
n
* TH1 : Al(OH)3(max). Khi : nH nOH nAlO2 0,28mol nH2SO4 H VH2SO4 0,07(l)
2
- Nhn thy nBa2 nSO42 nBaSO4 nSO42 0,14mol m 78nAl(OH)3 233nBaSO4 50,56(g)
* TH2 : BaSO4 (max). Khi ta c : nH 2SO4 nBa2 0,3mol VH 2SO4 0,15(l)
4nAlO2 (2nH 2SO4 nOH ) 37
- Nhn thy: nOH nAlO2 2nH 2SO4 nOH 4nAlO2 nAl(OH)3 mol
3 300
m 233nBaSO4 78nAl(OH)3 79,52(g) .
Vy lng cc ta cc i thu c l 79,52 gam khi VH 2SO4 150(ml)
Cu 38: Chn A.
Ti catot Ti anot
Cu2+ + 2e Cu 2Cl- Cl2 + 2e
a mol 2a mol a mol 0,2 mol 0,1 mol 0,2 mol
H2O 4H +
+ O2 + 4e
4b mol b mol 4b mol
BT:e
2nCl 2 4nO2 2nCu2 2a 4b 0,2 a 0,12
mCu 7,68(g)
64n 32n m 71n 64a 32b 8 b 0,01
Cu O 2 dd gim Cl 2
Cu 39: Chn A.

360
nCO2 2nglucz 2. .0,8 3,2
BT:C
nCaCO3 nCO2 3,2 mCaCO3 320(g)
180
Cu 40: Chn D
(1) Sai, ch 2 cht tan trong nc l glucoz v saccaroz.
(2) Sai, ch c glucoz tham gia phn ng trng bc
(3) Sai, saccarz c cu to t glucz v fructz

THPT HM RNG Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Cc este thng c mi thm d chu: isoamyl axetat c mi chui chn, etyl butirat c mi da
chn, etyl isovalerat c mi to,Este c mi chui chn c cng thc cu to thu gn l:
A. CH3COOCH2CH(CH3)2. B. CH3COOCH2CH2CH(CH3)2.
C. CH3COOCH2CH(CH3)CH2CH3. D. CH3COOCH(CH3)CH2CH2CH3.
Cu 2: Dung dch cht no di y khng lm i mu qu tm
A. C6H5NH2. B. NH3. C. CH3CH2NH2. D. CH3NHCH2CH3.
Cu 3: Pht biu no sau y l sai :
A. C th phn bit mantoz v saccaroz bng dung dch AgNO3 trong NH3, un nng.
B. Glucoz v mantoz u b kh bi H2 (xc tc Ni, nung nng).
C. Tinh bt v fructz u tham gia phn ng thy phn.
D. Fructoz khng lm mt mu nc brom.
Cu 4: Kim loi ch c iu ch bng phng php in phn nng chy l
A. Fe B. Cu C. Na D. Ag
Cu 5: Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon
ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l
A. 32,50. B. 48,75. C. 29,25. D. 20,80.
Cu 6: Ha tan ht 0,01 mol NaHSO4 vo dung dch cha Ba(HCO3)2 d kt thc phn ng thy khi
lng dung dch gim m gam so vi ban u. Gi tr ca m l :
Cu 7: Amino axit X c phn t khi bng 89. Tn gi ca X l :
A. Glyxin. B. Lysin. C. Alanin. D. Valin
Cu 8: X phng ho hon ton 8,8 gam CH3COOC2H5 trong 150 ml dung dch NaOH 1,0 M. C cn
dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l
A. 14,80. B. 10,20. C. 12,30. D. 8,20.
Cu 9: Nhn nh no sau y khng ng
A. Nhm c tnh kh mnh hn crm
B. ng thanh l hp kim ca ng v thic
C. Cr(VI) oxit va l mt oxit axit c tnh oxi ha mnh.
D. Cho Fe vo dung dch hn hp MgCl2 v HCl th xy ra qu trnh n mn in ha.
Cu 10: Cho 0,54 gam Al vo 40ml dung dch NaOH 1M, sau phn ng thu c dung dch X. Cho t
t dung dch HCl 0,5M vo dung dch X thu c kt ta. thu c kt ta ln nht th th tch
dung dch HCl 0,5M cn dng l:
A. 110 ml. B. 40 ml. C. 70 ml. D. 80 ml.
Cu 11: Tn gi ca peptit H2N-CH2-CONH-CH2-CONHCH(CH3)COOH l :
A. Gly-Ala-Gly B. Gly-Gly-Ala C. Ala-Gly-Gly D. Gly-Ala-Ala
Cu 12: Cht tham gia phn ng cng vi hidro (iu kin thch hp) l:
A. Tripanmitin B. Tristearin C. Etyl Axetat D. Etyl acrylat
Cu 13: Cht X phn ng vi HCl, cht X phn ng vi dung dch Ba(OH) 2 to kt ta .Cht X l:
A. NaCl B. NaHCO3 C. K2SO4 D. Ca(NO3)2
Cu 14: Metyl axetat b kh bi LiAlH 4 thu c sn phm ?

A. Metanol B. Etanol v metanol C. Metanoic D. Metanoic v Etanoic
Cu 15: Nu vt lm bng hp kim Fe - Zn b n mn in ha th trong qu trnh n mn ?
A. Km ng vai tr catot v b oxi ha B. St ng vai tr anot b oxi ha
C. St ng vai tr catot v ion H b oxi ha
+
D. Km ng vai tr anot v b oxi ha
Cu 16: Pht biu no sau y l ng ?
A. Saccaroz lm mt mu nc brom.
B. Xenluloz c cu trc mch phn nhnh, xon vo nhau to thnh si xenluloz.
D. Glucoz b kh bi dung dch AgNO 3 trong NH3.
Cu 17: Hin tng no di y khng ng thc t ?
A. Nh vi git axit nitric c vo dung dch lng trng trng thy xut hin mu vng.
B. Trn ln lng trng trng, dung dch NaOH v c mt t CuSO 4 thy xut hin mu xanh c
trng.
C. un nng dung dch lng trng trng thy xut hin hin tng ng t.
D. t chy da hay tc thy c mi kht.
Cu 18: Cho cc loi t sau: nilon-6, lapsan, visco, xenluloz axetat, nitron, enang. S t thuc t
ha hc l.
A. 6 B. 4 C. 5 D. 3
Cu 19: Nhn nh no sau y l sai ?
A. Glucoz v fructoz u th hin tnh oxi ha khi tc dng vi H2 (xc tc Ni, t0).
B. Glucoz v fructoz u ha tan c Cu(OH)2 iu kin thng, to phc xanh lam.
C. Trong mt ong u c cha glucoz v fructoz.
D. Glucoz v fructoz u th hin tnh kh khi tc dng vi dung dch Br 2.
Cu 20: Nhng thanh Fe ln lt vo cc dung dch sau: (1) AgNO 3, (2) CuCl2, (3) NiCl2, (4) ZnCl2,
(5) hn hp gm HCl v CuSO 4. Nhng trng hp xy ra n mn in ha l.
A. (1), (2), (5) B. (2), (3), (4), (5) C. (1), (2), (3), (5) D. (2), (3), (5)
Cu 21: Pht biu no sau y l ng ?
A. Cc polime u c tng hp bng phn ng trng hp.
B. Polime l hp cht c phn t khi rt ln do nhiu n v nh lin kt vi nhau to nn.
C. Tt c cc polime u b nng chy to ra cht lng nht.
D. Cc polime u c cu trc mch phn nhnh.
Cu 22: Cho t t tng git n ht 100 ml dung dch HCl aM vo 100 ml dung dch Na 2CO3 1M,
thy thot ra 1,344 lt kh CO 2 (ktc). Gi tr ca a l.
A. 1,6 B. 1,2 C. 0,6 D. 0,8
Cu 23: Ha tan hon ton 15,74 gam hn hp X cha Na, K, Ca v Al trong nc d thu c dung
dch cha 26,04 gam cht tan v 9,632 lt kh H 2 (ktc). Phn trm khi lng ca Al trong X l:
A. 17,15% B. 20,58% C. 42,88% D. 15,44%
Cu 24: Cu no sau y khng ng ?
A. Thu phn protein bng axit hoc kim khi un nng ch thu c mt hn hp cc amino axit.
B. Phn t khi ca mt amino axit (gm 1 chc -NH2 v 1 chc -COOH) lun l s l.
C. Cc amino axit u tan trong nc.
D. Mt s loi protein tan trong nc to dung dch keo.
Cu 25: Cho m gam hn hp X gm HCOOC2H5 v CH3COOCH3 tc dng vi lng d dung dch
AgNO3 trong NH3 thu c 21,6 gam Ag. Mt khc, m gam X tc dng vi dung dch NaOH d th thu
c 9,4 gam hn hp 2 ancol. Gi tr m l
A. 25,9. B. 14,8. C. 22,2. D. 18,5.
Cu 26: Cho 14,58 gam hn hp X gm cht bo Y v axit Z (trong Y c to t glixerol v axit
Z) tc dng va vi 0,05 mol NaOH, thu c 0,92 gam glixerol. Khi lng phn t ca axit Z l
A. 284 vC. B. 282 vC. C. 280 vC. D. 256 vC.
A. Kt ta mu tm B. Dung dch mu xanh C. Kt ta mu vng D. Kt ta mu trng

Cu 28: Cho dy cc cation kim loi :Ca2+, Cu2+, Na+, Zn2+ .Cation kim loi no c tnh oxi ha mnh
nht trong dy
A. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn
Cu 30: thu phn ht 7,612 gam hn hp X gm 2 este n chc v 2 este a chc th cn dng
va ht 80ml dung dch KOH aM. Sau phn ng, thu c hn hp Y gm cc mui ca cc axit
cacboxylic v cc ancol. t chy hon ton hn hp Y th thu c mui cacbonat, 4,4352 lt CO2
(ktc) v 3,168 gam H2O. Vy a gn vi gi tr no sau y nht ?
A. 1,25 B. 1,42 C. 1,56 D. 1,63
Cu 31: Cho hn hp X gm Fe, Cu vo dung dch HNO3 long, nng thu c kh NO l sn phm kh
duy nht, dung dch Y v cn li cht rn cha tan Z. Cho Z tc dng vi dung dch H2SO4 long thy c
kh thot ra. Thnh phn cht tan trong dung dch Y l:
A. Fe(NO3)3 v Cu(NO3)2. B. Fe(NO3)2 v Cu(NO3)2.
C. Fe(NO3)2. D. Fe(NO3)3 v Fe(NO3)2.
Cu 32: Cho cc th nghim sau:
(a) Cho dung dch Al(NO3)3 tc dng vi dung dch NH3 d.
(b) Cho dung dch KOH d vo dung dch AlCl3.
(c) Cho dung dch HCl d vo dung dch NaAlO2.
(d) Dn kh CO2 d vo dung dch KAlO2.
S th nghim thu c kt ta khi phn ng kt thc l
A. 3. B. 4. C. 2. D. 1.
Cu 33: Hn hp P gm ancol A, axit cacboxylic B (u no, n chc, mch h) v este C to ra t A v
B. t chy hon ton m gam P cn dng va 0,36 mol O2, sinh ra 0,28 mol CO2. Cho m gam P trn
vo 250 ml dung dch NaOH 0,4M un nng, sau khi kt thc cc phn ng thu c dung dch Q. C
cn dung dch Q cn li 7,36 gam cht rn khan. Ngi ta cho thm bt CaO v 0,96 gam NaOH vo
7,36 gam cht rn khan trn ri nung trong bnh kn khng c khng kh n phn ng hon ton thu
c a gam kh. Gi tr a gn nht vi ?
Cu 34: un nng 100 gam dung dch glucoz 18% vi lng d dung dch AgNO3 trong NH3, n
khi phn ng xy ra hon ton thu c m gam Ag. Gi tr ca m l:
Cu 35: un nng este CH3OOCCH=CH2 vi mt lng va dung dch NaOH, sn phm thu c
l:
A. CH2=CHCOONa v CH3OH. B. CH3COONa v CH2=CHOH.
C. CH3COONa v CH3CHO. D. C2H5COONa v CH3OH.
Cu 36: St ty l st trng thic. Nu lp thic b xc su ti lp st th kim loi b n mn trc l:
A. c hai u b n mn nh nhau. B. thic.
C. khng kim loi no b n mn. D. st.
A. Cht bo l este ca glixerol v cc axit bo.
B. Hiro ha hon ton triolein hoc trilinolein u thu c tristearin.
C. Du m ng thc vt b i thiu do ni i C = C gc axit khng no ca cht bo b oxi ha chm
bi oxi khng kh to thnh peoxit, cht ny b phn hy thnh cc sn phm c mi kh chu.
D. Cht bo nh hn nc v khng tan trong nc.
Cu 38: Chia 2m gam hn hp X gm 2 kim loi c ho tr khng i thnh 2 phn bng nhau. Cho phn
mt tan ht trong dung dch HCl (d) thu c 2,688 lt H2 (o ktc). Nung nng phn hai trong oxi

Cu 39: Pht biu no sau y cha chnh xc ?
A. Glucoz l hp cht hu c tp chc.
B. Metylamin l cht lng iu kin thng, lm qu tm ha xanh.
C. Etyl fomat cho c phn ng trng gng.
D. Amino axit l cht rn iu kin thng v d tan trong nc.
Cu 40: Cho 7,78 gam hn hp X cha Glyxin v Alanin vo 200 ml dung dch KOH 0,4M sau khi
cc phn ng hon ton thu c dung dch Y. C cn Y thu c m gam cht rn khan. Gi tr ca
m l:
A. 0,82 B. 10,18 C. 11,04 D. Khng xc nh
----------HT----------

THI TH THPT HM RNG LN 1
Cu 1: Chn B.
Cu 2: Chn A.
Cu 3: Chn C.
Fructz khng tham gia phn ng thy phn.
Cu 4: Chn C.
Cu 5: Chn D.
mdd tng 65nZn(p v i Fe3 ) nZn(p v i Fe2 ) .M ZnFe nZn(p v i Fe2 ) 0,2 mol
nZn(p ) nZn(p v i Fe3 )
nZn(p v i Fe2 ) 0,12 0,2 0,32 mZn 20,8(g)
Cu 6: Chn B
NaHSO4 Ba(HCO3 )2 NaHCO3 BaSO4 CO2 H 2O
0,01mol 0,01mol 0,01mol
mdd gam 44nCO2 233nBaSO4 2,77(g)

Cu 7: Chn C.
Cu 8: Chn B.
CH3COOC2H 5 NaOH CH 3COONa C2H 5OH
C nNaOH(d ) 0,05 mrn 82nCH3COONa 40nNaOH 10,2(g)

Cu 9: Chn D
Cho Fe vo dung dch hn hp MgCl2 v HCl th xy ra qu trnh n mn ha hc.
Fe + HCl FeCl2 + H2
BT:Al BT:Na
nNaAlO2 nAl 0,02 v nNaOH(d ) nNaOH nNaAlO2 0,02
nHCl nNaOH(d ) nNaAlO2 0,04 VHCl 0,08(l)
Cu 10: Chn D.
Al NaOH NaAlO2 ,NaOH (d )
HCl
NaCl Al(OH)3
dung dch X
C nNaCl nNaOH 0,04

BT:Na BT:Cl
nHCl nNaCl 0,04 VHCl 0,08(l)
Cu 11: Chn B.
Cu 12: Chn D.
Ni,t o
- Phn ng: C2H3COOCH3 + H2 CH3CH2COOCH3
Cu 13: Chn B.
- Phn ng: 2NaHCO3 + Ba(OH)2
BaCO3 + Na2CO3 + 2H2O
NaHCO3 + HCl
NaCl + CO2 + H2O
Cu 14: Chn B.
LiAlH 4
- Phn ng: CH3COOCH3 o C2H5OH CH3OH
metyl axetat t etanol metanol
Cu 15: Chn D
- V Zn c tnh kh mnh hn Fe nn Zn ng vai tr l cc m (anot) v b oxi ha trong qu trnh n
mn bo v cho thanh Fe
Cu 16: Chn C.
A. Sai, Saccaroz khng lm mt mu nc brom.
B. Sai, Xenluloz l mt polime to thnh t cc mt xch glucoz bi cc lin kt 1,4glicozit c
cu trc mch khng phn nhnh, khng xon.
C. ng, Amilopectin c cu to phn nhnh v c ni vi nhau bi lin kt 1,4glicozit v 1,6
glicozit.
D. Sai, Glucoz b oxi ha bi dung dch AgNO 3 trong NH3.
Cu 17: Chn B.
A. ng, khi cho dung dch axit nitric c vo dung dch lng trng trng thy c kt ta mu vng xut
hin.
B. Sai, Trn ln lng trng trng, dung dch NaOH v c mt t CuSO 4 thy xut hin mu tm xanh
c trng.
C. ng, un nng lng trng trng thy xut hin kt ta l do hin tng ng t ng t
protein.
D. ng, V thnh phn ca tc v da l protein nn khi t c mi kht.
Cu 18: Chn A.
Vy c 6 loi t trn u thuc loi t ha hc.
Cu 19: Chn D.
A. ng, Glucoz v fructoz u th hin tnh oxi ha khi tc dng vi H 2 (xc tc Ni, t0).
B. ng, V glucoz v fructoz c nhiu nhm OH lin tip nn c th ha tan Cu(OH)2 iu
kin thng.
C. ng, Fructoz chim phn ln hn glucoz trong mt ong.
D. Sai, Fructoz khng tc dng vi dung dch Br 2.
Cu 20: Chn C.
(1) Xy ra qu trnh n mn in ha: Fe + AgNO3
Fe(NO3)2 + Ag
(2) Xy ra qu trnh n mn in ha: Fe + CuCl2
FeCl2 + Cu
(3) Xy ra qu trnh n mn in ha: Fe + NiCl2 NiCl2 + Cu
(4) Khng xy ra phn ng.
(5) Va xy ra qu trnh n mn in ha v qu trnh n mn ha hc:
Cu 21: Chn B.
A. Sai, Cc polime c th c iu ch bng phn ng trng ngng hoc trng hp:
B. ng, Polime l nhng hp cht c khi lng phn t rt ln do nhiu n v c s (gi l mt xch)
lin kt vi nhau to thnh.
C. Sai, a s cc polime khi nng chy cho cht lng nht, ngui li s rn li nn c gi l cht
nhit do. Mt s polime khng nng chy m b phn hy khi un nng gi l cht nhit rn.
D. Sai, Ch c cc polime thng gp sau: amilopectin, glicogen c cu trc mch phn nhnh.
Cu 22: Chn A.
- Ta c : nH nCO32 nCO2 0,16mol CM (HCl ) 1,6M
Cu 23: Chn B.
m X m c.tan 2n H 2
- Khi cho hn hp X tc dng vi H2O d th: n H 2O 0, 62 mol
18
n H O n H2
- Nhn thy: n H 2O n H 2 suy ra trong cht tan c cha OH - vi n OH 2 0, 095 mol
2
- Dung dch cht tan c cc ion: AlO2 ,OH v M n (M l Na, K, Ca)
m mc.tan (m M n m Al (AlO2 ) ) 16n O (AlO2 ) 17n OH m X 8n AlO2 17n OH n AlO2 0,12 mol
0,12.27
Vy %m Al .100% 20,58
15, 74
Cu 24: Chn A.
A. Sai, Khi thu phn protein n gin th thu c cc gc aminoaxit, cn protein phc tp l
nhng protein c to thnh t cc protein n gin cng vi cc thnh phn phi protein nh axit
nucleic, lipit, cacbohidrat v vy khi thy phn protein phc tp ngoi cc amino axit cn thu c
lipit, cacbohidrat
Cu 25: Chn D.
nAg
- Khi cho m gam X tc dng vi dung dch AgNO 3/NH3 th : nHCOOC2H5 0,1mol
2
mancol 46nC2H5OH
- Khi cho m gam X tc dng vi NaOH d th : nCH3COOCH3 nCH3OH 0,15mol
32
mX 74(nHCOOC2H 5 nCH 3COOCH3 ) 18,5(g)
Cu 26: Chn A.
- Khi cho 14,85 gam X tc dng vi 0,05 mol NaOH ta c : nY nC3H5 (OH)3 0,01mol
nZ nNaOH 3nC3H5(OH)3 0,02mol nH2O nZ 0,02mol
BTKL
mRCOONa(Z) mX 40nNaOH 92nC3H5(OH)3 18nH2O 15,3(g)
15,3
M RCOONa 306 M RCOOH 284
0,05
Cu 27: Chn C.
Cu 28: Chn B.
- Tnh oxi ha gim dn theo dy : Cu2+ > Zn2+ > Ca2+ > Na+ .
Cu 29: Chn B.
B. Sai, Mg tan chm trong nc nhit thng, tan nhanh trong nc nhit cao, Be khng tc
dng vi nc mi iu kin nhit .
Cu 30: Chn D.
- Go x l s mol KOH phn ng khi ta c : nCOO(trongX ) nKOH x mol
BT:C
nC(trongX) nCO2 nK 2CO3 0,198 0,5x v
BT:H
nH(trongX) 2nH2O nNaOH 0,352 x
- Xt X c : mX 12nC nH 32nO2 12(0,198 0,5x) (0,352 x) 32x 7,612 x 0,132mol
0,132
Vy a 1,65
0,08
Cu 31: Chn C.
- Cho Z tc dng vi dung dch H2SO4 long thy c kh thot ra trong Z c cha Fe.
- V lng Fe cn d sau phn ng nn khi cho hn hp X gm Fe, Cu vo dung dch HNO3 long, nng
th dung dch Y thu c ch c cha Fe(NO3)2.
Cu 32: Chn C.
- Cc phn ng xy ra:
(a) Al(NO3)3 + 3NH3 + 3H2O Al(OH)3 + 3NH4NO3
(b) AlCl3 + 3NaOHd Al(OH)3 + 3NaCl ; Al(OH)3 + NaOH Na[Al(OH)4]
(c) NaAlO2 + HCl + H2O Al(OH)3 + NaCl ; Al(OH)3 + 3HCl AlCl3 + 3H2O
(d) CO2 d + KAlO2 + 2H2O Al(OH)3 + KHCO3
Vy c 2 phn ng to kt ta l (a), (d).
Cu 33: Chn D.
- Gi axit cacboxylic B l RCOOH.
- Khi t hn hp P th : nB nC 1,5nCO2 nO2 0,06mol nNaOH(d ) nNaOH (nB nC ) 0,04mol
m rn khan 40nNaOH(d )
- C M RCOONa 94 nn RCOONa l CH 2=CH-COONa
nB nC
- 7,36 gam rn Q cha CH2=CH-COONa (0,06 mol) v NaOH (d) (0,04 mol)
- Khi nung 7,36 gam hn hp rn Q vi 0,024 mol NaOH ta c :
0
CH 2 CH COONa NaOH
CaO,t
C2H 4 Na2CO3
(0,040,024) mol
0,06mol 0,06mol (NaOH d)
Vy mC2H 4 0,06.28 1,68(g)
Cu 34: Chn C.

mdd C6H12O6 .C%
- Ta c: mAg 108.nAg 108.2. .h% 21,6 (g)
180
Cu 35: Chn A.
- Phn ng: CH3OOCCH=CH2 + NaOH CH2=CHCOONa + CH3OH
Cu 36: Chn D.
Cu 37: Chn A.
A. Sai, Cht bo l trieste ca glixerol v cc axit bo.
(C17 H 33COO)3 C3H 5 3H 2 Ni,t o
B. ng, Phn ng: (C17 H 35COO)3 C3H 5
(C17 H 31COO)3 C3H 5 6H 2
C. ng, Du m ng thc vt b i thiu do ni i C=C gc axit khng no ca cht bo b oxi ha
D. ng, Cht bo nh hn nc v khng tan trong nc.
Cu 38: Chn D.
- Ta c: nO(trong oxit) nH 2 0,12mol mkim lo i moxit 16nO 2,34(g)
Cu 39: Chn B.
B. Sai, Metylamin l cht kh iu kin thng, lm qu tm ha xanh.
Cu 40: Chn D.
7, 78
- Nhn thy: n X (min) 0, 087 mol > nKOH = 0,08 mol (KOH ht) nKOH = n H 2O 0, 08 mol
89

BTKL
mrn = mX + (56 18)nKOH = 10,82 (g)

S GD T TNH PH YN THI TH THPT QUC GIA LN 1 NM 2017
LNG VN CHNH Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Kim loi no khng tan trong dung dch FeCl 3 ?

A. Cu B. Fe C. Mg D. Ag
Cu 2: Cht X c cng thc cu to CH2=CHCOOCH=CH2. Tn gi ca X l:
A. Vinyl acrylat. B. Propyl metacrylat. C. Etyl axetat. D. Vinyl metacrylat.
Cu 3: Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng tc dng vi dung
dch HNO3 c, ngui l:
A. Cu, Pb, Ag. B. Cu, Fe, Al. C. Fe, Al, Cr. D. Fe, Mg, Al.
Cu 4: Phenyl axetat c iu ch trc tip t ?
A. Axit axetic v phenol. B. Axit axetic v ancol benzylic.
C. Anhirit axetic v phenol. D. Anhirit axetic v ancol benzylic.
Cu 5: Khi cho lng d dung dch NaOH vo ng nghim ng dung dch kali icromat, dung dch
trong ng nghim
A. Chuyn t mu vng sang mu . B. Chuyn t mu vng sang mu da cam.
C. Chuyn t mu da cam sang mu vng. D. Chuyn t mu da cam sang mu xanh lc.
A. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit.
B. Trong phn t tetrapeptit mch h c 4 lin kt peptit.
C. Trong mi trng kim, ipeptit mch h tc dng vi Cu(OH) 2 cho hp cht mu tm.
D. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu.
Cu 7: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl d thu c dung dch Y
v phn khng tan Z. Cho Y tc dng vi dung dch NaOH long, d thu c kt ta g ?
A. Fe(OH)3. B. Fe(OH)2 v Cu(OH)2.
C. Fe(OH)2, Cu(OH)2 v Zn(OH)2. D. Fe(OH)3 v Zn(OH)2.
Cu 8: Hn hp rn Ca(HCO3)2, NaOH v Ca(OH)2 c t l s mol tng ng ln lt l 2 : 1 : 1.
Khuy k hn hp vo bnh ng nc d. Sau phn ng trong bnh cha ?
A. CaCO3, NaHCO3. B. Na2CO3. C. NaHCO3. D. Ca(OH)2.
Cu 9: Cho cc pht biu sau
(a) C th dng nc brom phn bit dung dch glucoz v fructoz.
(b) Trong mi trng axit, glucoz v fructoz c th chuyn ha ln nhau.
(c) Trong dung dch, fructoz tn ti ch yu dng vng 5 hoc 6 cnh.
(d) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ).
(e) S chuyn ha tinh bt trong c th ngi c sinh ra mantoz.
(g) Saccaroz c cu to t hai gc glucoz v fructoz.
(h) Trong phn ng este ha gia CH 3COOH vi CH3OH, H2O to nn t -OH trong nhm COOH
ca axit v H trong nhm OH ca ancol.
(i) Phn ng gia axit axetic v ancol anlylic ( iu kin thch hp) to thnh este c mi thm
chui chn.
(k) Metyl-, imetyl-, trimetyl- v etylamin l nhng cht kh mi khai, kh chu, c.
(l) Cc amin ng ng ca metylamin c tan trong nc gim dn theo chiu tng dn phn t
khi.
S pht biu ng l
A. 4. B. 5. C. 6. D. 7.

Cu 10: Cho cc cht: C6H5NH2 (1), (C2H5)2NH (2), C2H5NH2 (3), NH3 (4). Trt t gim dn lc baz
gia cc cht l
A. 3, 4, 2, 1. B. 2, 3, 4, 1. C. 2, 1, 4, 3. D. 4, 3, 1, 2.
Cu 11: Phn Crom-Kali c mu:
A. Trng. B. Vng. C. Da cam. D. Xanh tm.
Cu 12: Cho 3,92 lt (ktc) hn hp kh X gm Cl2 v O2 phn ng va vi 5,55 gam hn hp Y
gm Mg v Al, thu c 15,05 gam hn hp Z. Phn trm khi lng ca Mg trong Y l:
A. 51,35%. B. 75,68%. C. 24,32%. D. 48,65%.
Cu 13: t chy 0,15 mol hn hp gm metyl acrylat, etylen glicol, axetanehit v ancol metylic cn
dng x mol O2, thu c 0,38 mol CO2. Gi tr ca x gn nht vi gi tr no sau y ?
A. 0,50. B. 0,45. C. 0,60. D. 0,55.
Cu 14: Tn gi ca peptit H2N-CH2-CONH-CH2-CONHCH(CH3)COOH l :
A. Gly-Ala-Gly B. Gly-Gly-Ala C. Ala-Gly-Gly D. Gly-Ala-Ala
Cu 15: Cht tham gia phn ng cng vi hidro (iu kin thch hp) l:
A. Tripanmitin B. Tristearin C. Etyl Axetat D. Etyl acrylat
Cu 16: Cht X phn ng vi HCl, cht X phn ng vi dung dch Ba(OH) 2 to kt ta .Cht X l:
A. NaCl B. NaHCO3 C. K2SO4 D. Ca(NO3)2
Cu 17: Metyl axetat b kh bi LiAlH 4 thu c sn phm ?
A. Metanol B. Etanol v metanol C. Metanoic D. Metanoic v Etanoic
Cu 18: Nu vt lm bng hp kim Fe - Zn b n mn in ha th trong qu trnh n mn ?
A. Km ng vai tr catot v b oxi ha B. St ng vai tr anot b oxi ha
C. St ng vai tr catot v ion H+ b oxi ha D. Km ng vai tr anot v b oxi ha
Cu 19: Kim loi st tc dng vi dung dch no sau y to ra mui st (II) ?
A. HNO3 c nng, d B. MgSO4 C. CuSO4 D. H2SO4 c nng, d
Cu 20: Khi un nng cht X c cng thc phn t C 5H10O2 vi dung dch NaOH thu c
C2H5COONa v ancol Y. Y c tn l :
A. Kt ta mu tm B. Dung dch mu xanh C. Kt ta mu vng D. Kt ta mu trng
Cu 22: Cho dy cc cation kim loi :Ca2+, Cu2+, Na+, Zn2+ .Cation kim loi no c tnh oxi ha mnh
nht trong dy
A. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn
Cu 24: Cho s sau :
0
HCl (d )
Vy X2 l :
A. ClH3N-CH2COOH B. H2N-CH2-COOH C. H2N-CH2-COONa D. H2N-CH2COOC2H5
u in phn)
Cu 28: Hp cht H2N-CH2-COOH phn ng c vi : (1) NaOH, (2) HCl, (3) C 2H5OH, (4) HNO2

A. (1), (2), (3), (4) B. (2), (3), (4) C. (1), (2), (4) D. (1), (2), (3)
Cu 29: Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v khi lng. Cho
A. Tch nc Y ch thu c 1 anken duy nht B. Tn thay th ca Y l propan-2-ol
C. Phn t X c mch cacbon khng phn nhnh D.Trong phn t X c 1 lin kt
Cu 30: Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l :
Cu 32: Cho Etylamin phn ng vi CH3I (t l mol 1 :1) thu c cht ?
A. imetylamin B. N-Metyletanamin C. N-Metyletylamin D. ietylamin
Cu 33: Cho dy cc cht Gly-Ala-Gly-Gly, glucozo, Ala-Gly, protein, glixerol. S cht trong dy tc
dng c vi Cu(OH)2 l :
A. 2 B. 4 C. 3 D. 5
Cu 34: X, Y, Z l ba peptit mnh h, c to t Ala, Val. Khi t chy X, Y vi s mol bng nhau
th u c lng CO2 l nh nhau. un nng 37,72 gam hn hp M gm X, Y, Z vi t l mol tng
ng l 5 : 5 : 1 trong dung dch NaOH, thu c dung dch T cha 2 mui D, E vi s mol ln lt l
0,11 mol v 0,35 mol. Bit tng s mt xch ca X, Y, Z bng 14. Phn trm khi lng ca Z trong M
gn nht vi ?
A. 14% B. 8% C. 12% D. 18%
Cu 35: Nung m gam hn hp X gm bt Al v Fe3O4 sau mt thi gian thu c cht rn Y. ho
tan ht Y cn V lt dung dch H2SO4 0,7M (long). Sau phn ng thu c dung dch Z v 0,6 mol kh.
Cho dung dch NaOH vo dung dch Z n d, thu c kt ta M. Nung M trong chn khng n
khi lng khng i thu c 44 gam cht rn T. Cho 50 gam hn hp A gm CO v CO2 qua ng s
c cht rn T nung nng. Sau khi T phn ng ht thu c hn hp kh B c khi lng gp 1,208
ln khi lng ca A. Gi tr ca (m - V) gn vi gi tr no sau y nht ?
A. 58,4 B. 61,5 C. 63,2 D. 65,7
Cu 36: X l este no, n chc, Y l este n chc, khng no cha mt ni i C = C (X, Y u mch
h). t cht 10,56 gam hn hp E cha X, Y cn dng 10,08 lt O2 (ktc) thu c 6,48 gam nc.
Mt khc, un nng 10,56 gam E vi dung dch NaOH va thu c mt ancol duy nht v hn hp
mui cha a gam mui A v b gam mui B (MA < MB). Bit A, B l cc mui ca cc axit cacboxylic.
T l a : b gn nht vi gi tr no sau y ?
A. 0,9 B. 1,2 C. 1,0 D. 1,5
Cu 37: X l dung dch cha 4,433 gam hn hp NaCl v BaCl 2. Cn dung dch Y cha 6,059 gam
hn hp Ag2SO4 v NiSO4. Mc ni tip hai bnh in phn cha ln lt hai dung dch X, Y ri in
phn (vi in cc tr c mng ngn) bng dng in I = 9,65A. Sau 9 pht, bnh cha X c nc bt
u c in phn trn c hai cc, ngng in phn, c hai dung dch X v Y, Trn hai dung dch
X v Y vo nhau c 3,262 gam kt ta. Nu trn hai dung dch X v Y vo nhau, lc b kt ta,
thu c dung dch A, ri in phn dung dch A (vi in cc tr) bng dng in I = 5A, khi trn
catot xut hin bt kh, ngng in phn, th kh thot ra trn anot l 0,504 lt (ktc). T l s mol ca
mui Ag2SO4 v mui NiSO4 trong Y gn vi gi tr no sau y nht ?
A. 0,23 B. 0,26 C. 0,31 D. 0,37
Cu 37: Chn A.
It
- Xt qu trnh in phn ni tip 2 bnh X, Y ta c : ne trao i 0,054mol .
96500
Ti catot Ti anot
2H2O + 2e 2OH- + H2 2Cl- Cl2 + 2e

58nNaCl 208nBaCl 2 mX 58nNaCl 208nBaCl 2 4,433 nNaCl 0,026mol
- C
nNaCl 2nBaCl 2 ne trao i nNaCl 2nBaCl 2 0,054 nBaCl 2 0,014mol
- Khi trn hai dung dch X v Y nhn thy rng m 233nBa2 (tc l nBa2 nSO42 v trong kt ta
ch c BaSO4) nn trong dung dch Y ch H2SO4 (tc Ag+ v Ni2+ in phn ht)
Suy ra ne trao i 2nAg2SO4 2nNiSO4
- Khi trn dung dch X vi dung dch Y thu c dung dch A gm Na + (0,026 mol), SO42-, Ni2+ v Cl-.
- Xt qu trnh in phn dung dch A. Gi s ti anot ch c Cl - in phn :
Ti catot Ti anot
Ni 2+
+ 2e Ni 2Cl -
Cl2 + 2e
0,0225 0,045
- Ta c : nNi 2 nCl 2 0,0225mol
nNa 2nNi 2 nCl
-
BTDT(A)
nSO42 (trongZ) 0,013mol
2
Xt dung dch Y ta c : nAg2SO4 nBaSO4 nSO42 (trongZ) nNiSO4 0,014 0,013 0,0225 4,5.103
2nAg2SO4 2nNiSO4 ne trao i
nAg2SO4 4,5.103
0,2
nNiSO4 0,0225
Cu 38: thu phn ht 7,612 gam hn hp X gm 2 este n chc v 2 este a chc th cn dng
va ht 80ml dung dch KOH aM. Sau phn ng, thu c hn hp Y gm cc mui ca cc axit
cacboxylic v cc ancol. t chy hon ton hn hp Y th thu c mui cacbonat, 4,4352 lt CO2
(ktc) v 3,168 gam H2O. Vy a gn vi gi tr no sau y nht ?
A. 1,25 B. 1,42 C. 1,56 D. 1,63
Cu 39: t chy hon ton m gam FeS 2 bng mt lng O2 va , thu c kh X. Hp th ht X
vo 1 lt dung dch cha Ba(OH) 2 0,15M v KOH 0,1M thu c dung dch Y v 21,7 gam kt ta.
Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l :
A. 23,2 B. 12,6 C. 18,0 D. 24,0
Cu 40: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO 3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi
l :
A. 8,96 B. 4,48 C. 10,08 D. 6,72
----------HT----------

THI TH CHUYN LNG VN CHNH PH YN LN 1
Cu 1: Chn D.
Cu 2: Chn A.
Cu 3: Chn C.
- Al, Fe, Cr, Ni b th ng ha khi tc dng vi dung dch H 2SO4, HNO3 c, ngui.
Cu 4: Chn C.
- Phn ng gia phenol v anhirit axetic to phenyl axetat:
H
C6H5OH + (CH3CO)2O CH3COOC6H5 + CH3COOH
Cu 5: Chn C.
Cu 6: Chn D.
A. Sai, Cc hp cht peptit km bn c trong mi trng baz ln trong mi trng axit.
B. Sai, Trong phn t tetrapeptit mch h c 3 lin kt peptit.
C. Sai, Trong mi trng kim, ipeptit mch h khng tc dng vi Cu(OH) 2.
D. ng, Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu.
Cu 7: Chn B.
HCl NaOH
- Qu trnh: Fe2O3,ZnO,Cu FeCl 2 ,ZnCl 2 ,CuCl 2
Fe(OH)2 ,Cu(OH)2
Ho
n hp X dung dch Y ke
t tu
a
Cu 8: Chn A.
- Da vo t l s mol ta c cc phn ng xy ra nh sau:
Ca(HCO3)2 + Ca(OH)2
2CaCO3 + 2H2O
Ca(HCO3)2 + NaOH CaCO3 + NaHCO3 + H2O
Vy trong bnh cha CaCO 3 v NaHCO3.
Cu 9: Chn C.
(a) ng, V glucoz lm mt mu dung dch Br2 trong khi fructoz th khng c phn ng ny.
(b) Sai, Trong mi trng kim th glucoz v fructoz c th chuyn ha ln nhau.
(c) Sai, Trong dung dch, fructoz tn ti ch yu dng vng 5 hoc 6 cnh.
(d) ng, Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ).
(e) ng, S chuyn ha tinh bt trong c th ngi c sinh ra mantoz.
(g) Sai, Saccaroz c cu to t hai gc glucoz v fructoz.
(h) ng, Phn ng este ha gia CH 3COOH vi CH3OH, H2O to nn t -OH trong nhm COOH
ca axit v H trong nhm OH ca ancol.
(i) Sai, Phn ng gia axit axetic v ancol isoamylic ( iu kin thch hp) to thnh este c mi thm
chui chn l isoamyl axetat.
(k) ng, Metyl-, imetyl-, trimetyl- v etylamin l nhng cht kh mi khai, kh chu, c.
(l) ng, Cc amin ng ng ca metylamin c tan trong nc gim dn theo chiu tng dn phn
t khi.
Vy c 6 pht biu ng l: (a), (d), (e), (h), (k), (l).
Cu 10: Chn B.
Cu 11: Chn D.
- Phn crom-kali K2SO4.Cr2(SO4)3.24H2O c mu xanh tnh, c dng thuc da, lm cht cm mu
trong ngnh nhum vi.
Cu 12: Chn B.
n Cl2 n O2 0,175 n Cl 0,1 mol
- Xt hn hp kh X ta c: 2
71n Cl2 32n O2 15, 05 5,55 n O2 0, 075 mol
2n Mg 3n Al 2n Cl 2 4n O 2 0,5 n Mg 0,175 mol

- Ta c h sau: %m Mg 75, 68%
24n Mg 27n Al 5,55
n Al 0, 05 mol
Cu 13: Chn B.
- Hn hp C2H3COOCH3; C2H4(OH)2; CH3CHO; CH3OH quy i v CxH6O2 (a mol); CyH4O (b mol).
BT: O 2n CO 2 n H 2O 2a b 2.0,38 3a 2b 2a b
vi a + b = 0,15 n O 2 x 0, 455 mol
2 2
Cu 14: Chn B.
Cu 15: Chn D.
o
Ni,t
- Phn ng: C2H3COOCH3 + H2 CH3CH2COOCH3
Cu 16: Chn B.
- Phn ng: 2NaHCO3 + Ba(OH)2
BaCO3 + Na2CO3 + 2H2O
NaHCO3 + HCl
NaCl + CO2 + H2O
Cu 17: Chn B.
LiAlH 4
- Phn ng: CH3COOCH3 o C2H5OH CH3OH
metyl axetat t etanol metanol
Cu 18: Chn D
- V Zn c tnh kh mnh hn Fe nn Zn ng vai tr l cc m (anot) v b oxi ha trong qu trnh n
mn bo v cho thanh Fe
Cu 19: Chn C.
A. Fe + 6HNO3 Fe(NO3)3 + 3NO2 + 3H2O
B. Fe + MgSO4 : khng phn ng
C. Fe + CuSO4
FeSO4 + Cu
D. 2Fe + 6H2SO4(c, nng)
Fe2(SO4)3 + 3SO2 + 6H2O
Cu 20: Chn A.
0
- Phn ng C2H 5COOC2H 5 NaOH
t
C2H 5COONa C2H 5OH
Cu 21: Chn C.
Cu 22: Chn B.
- Tnh oxi ha gim dn theo dy : Cu2+ > Zn2+ > Ca2+ > Na+ .
Cu 23: Chn B.
B. Sai, Mg tan chm trong nc nhit thng, tan nhanh trong nc nhit cao, Be khng tc
dng vi nc mi iu kin nhit .
Cu 24: Chn A.
- Cc phn ng xy ra :
NH2CH2COOC2H5 (X) + NaOH
H2N-CH2-COONa (X1) + C2H5OH
H2N-CH2-COONa (X1) + HCl
ClH3N-CH2-COOH (X2) + NaCl
ClH3N-CH2-COOH (X2) + CH3OH
ClH3N-CH2-COOCH3 (X3) + H2O
Cu 25: Chn C.
Ag,Cu :hn h p rn Y
Zn,Fe AgNO3,Cu(NO3 )2 Zn2 ,Fe2 ,Cu2 ,NO3
NaOH
Vy dung dch Z cha: Zn(NO3)2, Fe(NO3)2 v Cu(NO3)2
Cu 26: Chn C.
Fe2O3 CrO Cr2O3 CrO3
Cu 27: Chn C.
- Bn cht ca in phn dung dch K 2SO4 l c cn dung dch.
Ti catot Ti anot
H2O + 2e 2OH + H2 -
H2O 4H+ + O2 + 4e

Cu 28: Chn A.
- Cc phn ng xy ra :
H2N-CH2-COOH + NaOH
H2N-CH2-COONa + H2O
H2N-CH2-COOH + HCl
ClH3N-CH2-COOH

H
05 C
0
H2N-CH2-COOH + HONO HO-CH2-COOH + N2 + H2O
Cu 29: Chn C.
14
- Trong phn t X c 1 nguyn t N, khi : M X 73 nn X l C4H11N
0,1918
- Da vo cc gii thit ca bi ta suy ra CTCT ca X: CH3CH(NH2)CH2CH3
05 C o
CH3CH(NH2)CH2CH3 (X) + HNO2 CH3CH(OH)CH2CH3 (Y) + N2 + H2O
to
CH3CH(OH)CH2CH3 (Y) + CuO CH3COCH2CH3 + Cu + H2O
A. Sai, Tch nc Y ch thu c 3 anken (k c ng phn hnh hc).
B. Sai, Tn thay th ca Y l butan-2-ol.
C. ng, Phn t X c mch cacbon khng phn nhnh.
D. Sai, Trong phn t X khng lin kt .
Cu 30: Chn D.
- Dy kim loi u c th iu ch bng phng php in phn dung dch mui ca chng l nhng
kim loi hot ng mnh nh kim loi kim, kim th v nhm.
Cu 31: Chn D.
A. ng, Bn cht ca enzim l nhng cht hu cht c bn cht protein.
05 C 0
C. ng, Phc ng saccarozo c cng thc l (C 12H21O11)2Cu.
2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + 2H2O
D. Sai, Peptit c chia thnh hai loi :
Cu 32: Chn B.
- Phn ng : C2H 5NH 2 CH3I 1:1
C2H 5NHCH3
etylamin N metylet anamin
Cu 33: Chn B.
Vy c 4 cht trong dy tc dng c vi Cu(OH) 2 l : Gly-Ala-Gly-Gly, glucoz, protein, glixerol.
Cu 34: Chn C.
- Khi gp X, Y v Z vi t l mol tng ng l 5 : 5 : 1 c 5X 5Y Z
X5Y5 Z 10H 2O
nD 0,11 11
+ Ta c X5Y5 Z l (D)11k (E)35k .
nE 0,35 35
m s mc xch(min) < s mc xch ca X 5Y5Z < s mc xch(max) 14.1 46k 14.5 k 1
14.nZ 11k 35k 14.nX
nE nB nX nY 5nX 5Y5Z 0,05mol

+ Vi k = 1 n(D)11k (E)35k nX 5Y5Z 0,01mol
11 35 nZ nX 5Y5Z 0,01mol
t0
- Khi cho 37,72 gam M tc dng vi NaOH th : M NaOH D E H 2O
+ Vi nH2O nM nX nY nZ 0,11mol v nNaOH nA nB 0,46mol
BTKL
mE mD mM 40n NaOH 18n H2O 54,14( g)

- Xt hn hp mui ta c :
m E m D 139n D
+ Gi s D l ValNa khi ta c M E 111 (AlaNa). Vy ta gi s ng.
nE
n Val 0,11
+ S mt xch Val 1 X, Y v Z u c 1 phn t Val
n X,Y,Z 0,11
X : (Ala)x Val : 0,05 mol

BT: Ala
0,05x 0,05y 0,01z 0,35 x y 3
Hn hp M: Y : (Ala) y Val : 0,05 mol
Z : (Ala) Val : 0,01mol s mc xch=(x 1) (y 1) (z 1) 14 z 5
z
0,01.472
Vy Z l (Ala)5Val, suy ra %mZ .100 12,5
37,72
Cu 35: Chn A.
mB mA 1,208mA mA
- Khi cho nung T vi hn hp kh A th nO(trongT) 0,65
16 16
- Xt hn hp rn T ta c :
160nFe2O3 72nFeO mT 44 nFe O 0,05 2n nFeO
2 3 nFe3O4 (X) Fe2O3 0,2mol
3nFe2O3 nFeO nO(trongT) 0,65 nFeO 0,5 3
1,4
- Khi cho m gam X tc dng vi H2SO4 th : nH2SO4 4nFe3O4 nH2 1,4mol VH2SO4 2(l)
0,7
- Dung dch Z gm Al3+, SO42- (1,4 mol), Fe2+ v Fe3+ (vi nFe3 2nFe2O3 v nFe2 nFeO )
nSO42 2nFe2 3nFe3 mX 27nAl 232nFe3O4 59,9(g)

BTDT(Z)
nAl 3 0,5mol
3 mX V 57,9(g)

Cu 36: Chn C.
- Khi t 10,56 gam E th :
m 32nO2 mH2O nO(trongE) mE 12nCO2 2nH2O

BTKL
nCO2 E 0,42mol nE 0,15mol
44 2 2.16
- p dng bt bo trong phn ng chy c :
nY nCO2 nH2O 0,06mol nX nE nY 0,09mol
- Gi CX v CY ln lt l s nguyn t C ca hai este X v Y (vi CY 4) ta c :

BT:C
nX .CX nY .CY nCO2 0,09CX 0,06CY 0,42 CX 2 v CY 4 (tha)
Vy X l HCOOCH3 (0,09 mol) v Y l CH2=CH-COOCH3 (0,06 mol)
mHCOONa
- Ta c : mHCOONa 0,09.68 6,12(g) v mC2H3COONa 5,64(g) 1,085
mC2H3COONa
Cu 38: Chn D.
- Go x l s mol KOH phn ng khi ta c : nCOO(trongX ) nKOH x mol
BT:C
nC(trongX) nCO2 nK 2CO3 0,198 0,5x v
BT:H
nH(trongX) 2nH2O nNaOH 0,352 x
- Xt X c : mX 12nC nH 32nO2 12(0,198 0,5x) (0,352 x) 32x 7,612 x 0,132mol
0,132
Vy a 1,65
0,08
Cu 39: Chn C.
- Nhn thy rng nBaSO3 nBa2 v cho dung dch tc dng vi NaOH xut hin thm kt ta.
nOH n
nn nSO2 nOH nSO2 nOH nSO32 0,3mol nFeS2 SO2 0,15mol mFeS2 18(g)
2 2
Cu 40: Chn A.

- Ta c ne(max) 2nCu nFe(NO3 )2 1,2mol
- Qu trnh kh NO3- xy ra nh sau : NO3 3e 4H NO 2H2O
nemax
- Da vo phng trnh ta suy ra: VNO 22,4.nNO 22,4. 8,96(l)
3
S GD T TNH NG NAI THI TH THPT QUC GIA LN 1 NM 2017

LNG TH VINH Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Kim loi no sau y phn ng mnh vi nc nhit thng ?

A. Ca B. Fe C. Cu D. Ag
Cu 2: Tin hnh cc th nghim sau
(1) Ngm l ng trong dung dch AgNO3
(2) Ngm l km trong dung dch HCl long
(3) Ngm l nhm trong dung dch NaOH
(4) Ngm l st c cun dy ng trong ddHCl
(5) mt vt bng gang ngoi khng kh m
(6) Ngm mt ming ng vo dung dch Fe2(SO4)3
S th nghim xy ra n mn in ha l
A. 2 B. 1 C. 3 D. 4
Cu 3: iu kin thng, cht no sau y khng c kh nng phn ng vi dung dch H2SO4 long?
A. FeCl3. B. Fe2O3. C. Fe3O4. D. Fe(OH)3.
Cu 4: Kim loi no sau y khng tc dng vi dung dch Fe(NO3)3 ?
A. Ag B. Fe C. Cu D. Zn
A. Thnh phn chnh ca qung olomit l CaCO3.MgCO3
B. Cc kim loi kim u c cu trc mng tinh th lp phng tm khi
C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh.
D. Thch cao nung(CaSO4.2H2O) c dng b bt, c tng.
Cu 7: Cht X c cc c im sau: Phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH)2 nhit
thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l:
A. Saccaroz B. Mantoz C. Glucoz D. Tinh bt
Cu 8: Pht biu sai l:
A. Lc baz ca anilin ln hn lc baz ca amoniac.
B. Anilin c kh nng lm mt mu nc brom.
C. Dung dch anilin trong nc khng lm i mu qu tm.
D. Anilin phn ng vi axit nitr nhit thng cho phenol v gii phng kh nit.

0 0
t
t

0 0

Cu 10: S nguyn t hidro c trong mt phn t Lysin l:
A. 10 B. 14 C. 12 D. 8
Cu 11: t chy 0,01 mol este X n chc bng lng oxi va , thu c 448 ml kh CO2 (ktc).
Mt khc un nng 6,0 gam X vi dung dch KOH va , thu c lng mui l :
A. Tnh kh ca cc kim loi kim th tng dn t Be n Ba.
B. Cc kim loi kali v natri dng lm cht trao i nhit trong mt vi loi l phn ng ht nhn.
C. Theo chiu tng dn in tch ht nhn, cc kim loi kim (t liti n xesi) c bn knh nguyn t tng
dn.
D. Cc kim loi kim th u tc dng vi nc nhit thng.
Cu 13: S este c cng thc phn t C4H8O2 l
A. 6. B. 3. C. 4. D. 2.
Cu 14: Cho cc pht biu sau
(1) Tt c cc peptit u c phn ng mu biur
(2) Cho HNO3 vo dung dch protein to thnh dung dch mu vng
(3) Mui phenylamoni clorua khng tan trong nc
(4) iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai
S pht biu ng l:
A. 1 B. 4 C. 3 D. 2
Cu 15: Cho cc th nghim sau:
(1) Khi cho Cu vo dung dch FeCl3; (2) H2S vo dung dch CuSO4;
(3) HI vo dung dch FeCl3; (4) Dung dch AgNO3 vo dung dch FeCl3;
(5) Dung dch NaHSO4 vo dung dch Fe(NO3)2; (6) CuS vo dung dch HCl.
S cp cht phn ng c vi nhau l:
A. 2 B. 5 C. 4 D. 3
Cu 16: Ho tan m gam hn hp gm KHCO3 v CaCO3 trong lng d dung dch HCl. Sau khi cc
phn ng xy ra hon ton, thu c 11,2 lt kh CO2 (ktc). Gi tr ca m l:
A. 40 B. 50 C. 60 D. 100
Cu 17: Mt hc sinh nghin cu mt dung dch X ng trong l khng dn nhn v thu c kt qu
sau:
- X u c phn ng vi c 3 dung dch: NaHSO4, Na2CO3 v AgNO3.
- X khng phn ng vi c 3 dung dch: NaOH, Ba(NO3)2, HNO3.
Vy dung dch X l dung dch no sau y ?
A. BaCl2. B. CuSO4. C. Mg(NO3)2 D. FeCl2.
Cu 18: Trung ha 6,75 gam amin no, n chc, mch h X bng lng d dung dch HCl. Sau khi phn
ng xy ra hon ton, thu c 12,225 gam mui. S ng phn cu to ca X l:
A. 2 B. 4 C. 3 D. 1
Cu 19: Cht no sau y cn c tn gi l ng nho
A. Glucoz. B. Saccaroz. C. Fructoz. D. Tinh bt.
Cu 20: Cho cc cht sau: H2NCH2COOH (X), CH3COOH3NCH3 (Y), C2H5NH2 (Z),
H2NCH2COOC2H5 (T). Dy gm cc cht u tc dng c vi dung dch NaOH v dung dch HCl l:
A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T.
(1) Cho dung dch NaI vo dung dch AgNO3.
(2) Cho dung dch Na2SO4 vo dung dch BaCl2.
(3) Sc kh NH3 ti d vo dung dch AlCl3.
(4) Cho dung dch Na2CO3 vo dung dch CaCl2.
(5) Cho dung dch NaOH ti d vo dung dch CrCl3.

Sau khi cc phn ng xy ra hon ton, c bao nhiu th nghim thu c kt ta?
A. 5 B. 2 C. 4 D. 3
Cu 22: iu kin thng, dy gm cc kim loi ha tan c trong dung dch NaOH long l.
A. Cr, Zn. B. Al, Zn, Cr. C. Al, Zn. D. Al, Cr.
Cu 23: un nng axit acrylic vi ancol etylic c mt H2SO4 c lm xc tc, thu c este c cng thc
cu to l.
A. CH2=CHCOOC2H5 B. CH3COOCH=CH2 C. C2H5COOC2H5 D. C2H5COOCH3
Cu 24: Cho 16,8 gam st tc dng vi dung dch H2SO4 long d thu c V lt H2 (ktc). Gi tr ca V
l:
A. 13,44 B. 10,08 C. 4,48 D. 6,72
E Qy tm Ha xanh
Cu 26: Cho Ba d tc dng vi dung dch cha x mol HCl thu c a1 mol H2. Cho Fe d tc dng vi
dung dch cha x mol HCl thu c a2 mol H2. Quan h ca a1 v a2 l:
A. a1 = a2 B. a1 > a2 C. a2 a1 D. a1 < a2
Cu 27: Cho dy cc cht sau: axit axetic, anehit fomic, ancol benzylic, etyl axetat, axit benzoic,
glucoz, etylamin; alanin. iu kin thng, s cht trong dy c th tc dng vi Cu(OH)2 l.
A. 3 B. 2 C. 4 D. 5
Cu 28: ha tan va ht 24,4 gam hn hp MgO v Al2O3 cn va 700 ml dung dch H2SO4 1M.
C cn dung dch sau phn ng c m gam mui. Gi tr ca m l
A. 93,0 B. 80,4 C. 67,8 D. 91,6
Cu 29: Hn hp X gm M2CO3, MHCO3 v MCl vi M l kim loi kim, nung nng 20,29 gam hn
hp X, sau khi phn ng xy ra hon ton thy cn li 18,74 gam cht rn. Cng em 20,29 gam hn hp
X trn tc dng ht vi 500ml dung dch HCl 1M th thot ra 3,36 lt kh (ktc) v thu c dung dch Y.
Cho Y tc dng vi dung dch AgNO3 d th thu c 74,62 gam kt ta. Kim loi M l:
A. Na B. Li C. Cs D. K
Cu 30: Tripeptit mch h c to bi t glyxin v valin l hp cht m phn t c:
A. ba nguyn t oxi v ba nguyn t nit. B. ba lin kt peptit, ba gc -aminoaxit.
C. hai lin kt peptit, hai gc -aminoaxit. D. hai lin kt peptit, ba gc -aminoaxit
Cu 31: Cho dung dch cha FeCl2, ZnCl2 v CuCl2 tc dng vi lng d dung dch NaOH. Sau khi cc
phn ng xy ra hon ton, em ton b lng kt ta thu c nung trong khng kh n khi lng
khng i, thu c hn hp rn gm:
A. FeO, CuO, ZnO. B. Fe2O3, ZnO, CuO. C. FeO, CuO. D. Fe2O3, CuO.
sau phn ng thu c m gam rn khan. Gi tr m l:
Cu 33: Hn hp E cha 2 peptit X, Y u mch h, c t l mol tng ng l 4 : 1 v c tng s lin kt
peptit nh hn 8. un nng m gam E vi dung dch NaOH va , thu c 0,48 mol mui Gly v 0,08
mol mui Ala. Gi tr m l:
Cu 34: Cho cc s phn ng sau:
C8H14O4 + NaOH X1 + X2 + H2O X1 + H2SO4 X3 + Na2SO4
X3 + X4 Nilon-6,6 + H2O
Pht biu no sau y ng?
A. Cc cht X2, X3 v X4 u c mch cacbon khng phn nhnh.
B. Nhit si ca X2 cao hn axit axetic.
C. Dung dch X4 c th lm qu tm chuyn mu hng.
D. Nhit nng chy ca X3 cao hn X1.
Cu 35: Ha tan hon ton 7,5 gam hn hp gm Mg v Al bng lng va V lt dung dch HNO3
1M. Sau khi cc phn ng kt thc, thu c 0,672 lt N2 ( ktc) duy nht v dung dch cha 54,9 gam
mui. Gi tr ca V l
A. 0,72. B. 0,65. C. 0,70. D. 0,86.
(a) Thp l hp kim ca st cha t 2-5% khi lng cacbon.
(b) Bt nhm trn vi bt st(III) oxit dng hn ng ray bng phn ng nhit nhm.
(c) Dng Na2CO3 lm mt tnh cng tm thi v tnh cng vnh cu ca nc.
(d) Dng bt lu hunh x l thy ngn ri vi khi nhit k b v.
(e) Khi lm th nghim kim loi ng tc dng vi dung dch HNO3, ngi ta nt ng nghim bng
bng tm dung dch kim.
S pht biu ng l :
A. 2. B. 3. C. 4. D. 5.
Cu 37: in phn dung dch AgNO3 vi in cc tr mt thi gian, thu c dung dch X cha 2 cht
tan c cng nng mol, ng thi thy khi lng dung dch gim 9,28 gam so vi ban u. Cho tip
2,8 gam bt Fe vo dung dch X, un nng khuy u thu c NO l sn phm kh duy nht, dung dch
Y v cht rn Z. Cc phn ng xy ra hon ton. Khi lng mui to thnh trong dung dch Y l:
A. 11,48 B. 15,08 C. 10,24 D. 13,64
Cu 39: Hn hp X cha hai hp cht hu c gm cht Y (C H O
2 7 2 N) v cht Z (C 4H12O2N2). un nng
9,42 gam X vi dung dch NaOH d, thu c hn hp T gm hai amin k tip c t khi so vi He bng
9,15. Nu cho 9,42 gam X tc dng vi dung dch HCl long d, thu c dung dch c cha m gam
mui ca cc hp cht hu c. Gi tr ca m l:
Cu 40: Nh t t dung dch Ba(OH)2 0,2M vo ng nghim cha dung dch Al2(SO4)3. th biu din
s ph thuc khi lng kt ta theo th tch dung dch Ba(OH)2 nh sau:
Gi tr ca V gn nht vi gi tr no sau y
A. 1,7. B. 2,1. C. 2,4. D. 2,5.

----------HT----------

THI TH THPT CHUYN LNG TH VINH NG NAI LN 1
Cu 1: Chn A.
- Cc kim loi tc dng c vi H2O iu kin thng l cc kim loi mnh nh Li, K, Na, Ca, Sr,Ba.
Cu 2: Chn C.
Nhng th nghim xy ra n mn in ha l :
(1) Ngm l ng trong dung dch AgNO3
- Ta c AgNO3 l dung dch cht in li, 2 in cc ln lt l Cu-cc m, Ag-cc dng.
(4) Ngm l st c cun dy ng trong dung dch HCl
- C 2 cc l st v ng, hai in cc cng tip xc vi dung dch HCl.
(5) mt vt bng gang ngoi khng kh m
- Gang l hp kim ca Fe-C, khng kh m cha H2O, CO2, O2, ... to ra lp dung dch cht in li ph
trn b mt gang lm xut hin v s pin in ha m Fe-cc m, C-cc dng.
Cu 3: Chn A.
Cu 4: Chn A.
Cu 5: Chn D.
- Thch cao nung (CaSO4.0,5H2O hoc CaSO4.H2O) c dng b bt, c tng.
Cu 6: Chn C.
- T nhn to (t bn tng hp) l t c ngun gc t thin nhin c pha ch thm bng phng php
ha hc nh t visco, t xenluloz axetat
Cu 7: Chn B.
- Saccaroz v tinh bt khng lm mt mu nc brom.
- Lin kt gilozit ch c th l cc cht: saccaroz, mantoz, tinh bt, xenluloz.
Vy cht X l mantoz.
Cu 8: Chn A.
- Lc baz ca anilin nh hn lc baz ca ammoniac. V gc C6H5 l gc ht e nn lm gim lc baz
ca anilin, cn ammoniac khng c gc ht hay y e nn n gi nguyn.
Cu 9: Chn D.
0
t
HCOONa + CH3CH2CHO
0
t
HCOONa + CH3COCH3
0
t
0
Cu 10: Chn B.
- Lysin HOOC-CH(NH2)(CH2)4-NH2 s nguyn t H trong phn t l 14
Cu 11: Chn D.
n
- Ta c: C X CO2 2 : X l C2H4O2 c cng thc cu to: HCOOCH3
nX
Cu 12: Chn D.
- Cc kim loi kim th u tc dng vi H2O nhit thng l sai v Be khng phn ng vi H2O
bt k nhit no.
Cu 13: Chn C.
- C 4 cng thc cu to ca este c cng thc phn t C4H8O2 l:
HCOOCH2CH2CH3 ; HCOOCH(CH3 )CH3 ; CH3COOCH2CH3 ; CH3CH2COOCH3
Hoc tnh nhanh s ng phn ca este, no, n, chc mch h bng cng thc: 2n2 (n < 5).
Cu 14: Chn A.
- C 1 pht biu ng l (d).

(1) Sai, Tripeptit tr ln mi c phn ng ny.
(2) Sai, Sn phm khng phi dung dch m l kt ta mu vng.
(3) Sai, Mui ny c tnh phn cc s tan trong nc l dung mi phn cc C6 H5 NH3 Cl .
Cu 15: Chn B.
- C 5 cp cht phn ng c vi nhau l:
(1) Cu + 2FeCl3 CuCl2 + 2FeCl2
(2) H2S + CuSO4 CuS + H2SO4
(3) 3HI + FeCl3 FeI2 + 0,5I2 + 3HCl
(4) 3AgNO3 + FeCl3 3AgCl + Fe(NO3)3
(5) 4HSO 4 NO3 3Fe 2 3Fe3 NO 2H 2 O 4SO 42
(6) CuS khng tan trong dung dch HCl.
Cu 16: Chn B,
- Ta c: n HCO n CO2 n CO2 0,5 mol m KHCO3 mCaCO3 0,5.100 50 (g)
3 3
Cu 17: Chn A.
- Dung dch X l BaCl2. Cc phn ng xy ra l:
BaCl2 2NaHSO4 2HCl BaSO 4
BaCl2 Na 2CO3 2HCl Na 2SO 4 BaSO 4
BaCl2 AgNO3 AgCl Ba NO3 2
Cu 18: Chn A.
6, 75 12, 225
- Ta c namin = nmui R 29 C2H5 NH2 hoc CH3 NHCH3
R 16 R 16 36,5
Cu 19: Chn A.
Cu 20: Chn B.
- C 3 u tc dng c vi dung dch NaOH v dung dch HCl l X, Y, T.
Cu 21: Chn C.
- C 4 phn ng to kt ta l:
(1) NaI + AgNO3
AgI vng + NaNO3
(2) Na2SO4 + BaCl2
BaSO4 trng + 2NaCl
(3) 3NH3 + AlCl3 + 3H2O
Al(OH)3 trng keo + 3NH4Cl
(4) Na2CO3 + CaCl2
CaSO3 trng + 2NaCl
(5) 4NaOH + CrCl3 NaCrO2 + 3NaCl + 2H2O
Cu 22: Chn C.
- Lu : Cr khng tan trong dung dch kim long.
Cu 23: Chn A.
Cu 24: Chn D.
VH 2 22, 4.n Fe 6, 72 (l)
Cu 25: Chn B.
Cu 26: Chn B.
BaCl2 H 2 . V Ba d nn: Ba 2H 2O
- Phn ng: Ba 2HCl Ba(OH)2 H 2

x n H 2O x
a1 1 v a 2 (2). T (1) v (2) ta suy ra c: a1 a 2
2 2 2
Cu 27: Chn C.
- C 4 cht c th tc dng vi Cu(OH)2 l: axit axetic, axit benzoic, glucoz, alanin.
Cu 28: Chn B.
BTKL
- Ta c: n H2O n H2SO4 0,7mol mmui = 80, 4 (g)
Cu 29: Chn D.
TGKL 20, 29 18, 74
- Khi nung hn hp X th: n MHCO3 2. 0, 05 mol
44 18
- Khi cho hn hp X tc dng vi HCl th: n M2CO3 nCO2 n MHCO3 0,1 mol
- Khi cho dung dch Y tc dng vi dung dch AgNO3 d th: n MCl n AgCl n HCl 0,02 mol
m m M 2CO3 m MHCO3 m MCl 20, 29 0,1 2M 60 0,05 M 61 0,02 M 35,5 20, 29
M = 39. Vy M l Kali
Cu 30: Chn D.
Cu 31: Chn D.
NaOH O
- Qu trnh: FeCl 2 , ZnCl 2 ,CuCl 2
Fe(OH) 2 , Cu(OH) 2
o Fe 2O3 , CuO
2
t
Cu 32: Chn A.
89n Ala 147n Glu 15,94 n Ala 0, 08 mol
- Ta c:
n Ala 2n Glu n NaOH 0, 2 n Glu 0, 06 mol
BT:Na
n NaCl n NaOH 0, 2 mol mX 125,5n AlaHCl 183,5n GluHCl 58,5n NaCl 32,75(g)
Cu 33: Chn A.
- Khi gp X, Y vi t l mol tng ng l 4 : 1 th: 4X Y X4Y1 4H2O (1)
+ T: nGly : nAla 0,48: 0,08 6:1 th: X4Y1 (7k 1)H2O 6kGly kAla (2)
- Gi s tng s lin kt peptit bng 8 ta c:
s mc xch(min) < s mc xch ca X 4Y1 < s mc xch(max) 10 7k 40 k 2,3,4,5
(82).1 6k k (82).4
nGly nAla nX 4nX 4Y1 0,16 mol

V i k =2 n(Gly)6 (Ala)1 nX 4Y1 0,04 mol
12 2 nY nX 4Y1 0,04 mol
- Ta c: m E m X 4Y1 4n H 2O (1) m Gly m Ala 13n H 2O (2) 4n H 2O (1) 36, 64 (g)
Cu 34: Chn A.
- Cc phn ng xy ra:
o
t
axit aipic hexametyleniamin t nilon 6,6
Na OOC[CH 2 ]4 COONa (X1 ) H 2SO 4
H OOC[CH 2 ]4 COOH (X 3 ) Na 2SO 4
H OOCCH 2 [CH 2 ]2 CH 2COOC 2 H 5 NaOH Na OOC[CH 2 ]4 COONa (X1 ) C 2 H 5 OH (X 2 ) H 2 O
A. ng.
B. Sai, Nhit si ca C2H5OH (X2) thp hn so vi CH3COOH.
C. Sai, NH2[CH2 ]6 NH2 (X4 ) lm qu tm ha xanh.
D. Sai, Na OOC[CH2 ]4 COONa (X1 ) cha lin kt ion nn c nhit si ca hn
HOOC[CH2 ]4 COOH (X3 ) ch cha lin kt cng ha tr.
Cu 35: Chn D.

7,5 (g) V (l) 54,9 (g) hn h p mui 0,03 mol
24n Mg 27n Al 7,5 n Mg 0, 2

BT: e
BT: N
Cu 36: Chn C.
(a) Sai, Thp l hp kim ca st cha t 0,01 - 2% khi lng cacbon.
(b) ng, Bt nhm trn vi bt st(III) oxit (bt tecmit) c dng hn ng ray bng phn ng
0
nhit nhm: 2Al + Fe2O3
t
Al2O3 + 2Fe
(c) ng, Nguyn tc lm mm nc cng l lm gim nng ca Ca2+ v Mg2+ trong nc cng. V
vy Na2CO3 c dng lm mm nc cng tm thi, vnh cu v ton phn:
Mg 2 CO32
(d) ng, V S phn ng Hg (d bay hi, c) iu kin thng nn dng S x l Hg ri vi.
Hg + S HgS
(e) ng, Trong qu trnh lm th nghim Cu + HNO3 th sn phm kh thu c c c c th l NO
hoc NO2 (c) (v Cu c tnh kh yu nn sn phm kh thng l NO hoc NO2) nn ta dng bng tm
bng kim hn ch thot ra ngoi khng kh theo phn ng sau:
2NaOH + 2NO2 NaNO3 + NaNO2 + H2O.
Vy c 4 nhn nh ng l (b), (c), (d) v (e).
Cu 37: Chn A.
1
- in phn dung dch: 2AgNO3 H 2O 2Ag 2HNO3 O 2
2
mol: a a a 0,25a
+ Ta c: mgim = 108a + 0,25a.32 = 9,28 n Ag n HNO3 a 0,08 mol
- Trong dung dch X c 0,08 mol HNO3 v 0,08 mol AgNO3 d.
- Khi cho 0,05 mol Fe vo dung dch X, dung dch Y thu c cha a mol Fe(NO3)3 v b mol Fe(NO3)2 .

BT: Fe
a b n Fe 0, 05
a 0, 04
+ Ta c h sau: BT: N n H mmui = 11, 48 (g)
3a 2b n HNO3 n NO 0,14 b 0, 01
4
Cu 38: Chn C.
Vi
n CO 2
0, 2
BTKL
Cu 39: Chn B.

x mol y mol
Y : HCOONH 3CH 3 NaOH

T (M T 36, 6) : CH 3 NH 2 v C 2H 5 NH 2
- Cho 9, 42 (g)X
x mol
x mol y mol y mol
Z : H 2 NCH 2COONH 3C 2 H 5 HCl
CH 3 NH 3 Cl, Cl H 3 NCH 2COOH , C 2H 5 NH 3Cl

y mol
m (g )
77x 120y 9, 42 x 0, 06
+ Ta c: mmui = 11, 77 (g)
31x 45y 36, 6.(x y) y 0, 04
Cu 40: Chn B.
69,9 n
- Ti V th kt ta ch cha BaSO4 vi n BaSO 4 0,3 mol n Al2 (SO 4 )3 BaSO 4 0,1 mol
233 3
4n 3 8n
nBa(OH)2 Al Al 2 (SO4 )3 0,4 mol VBa(OH)2 2 (l)
2 2

TNH BC LIU Mn: KHOA HC T NHIN HA HC
THPT CHUYN BC LIU Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Khi un nng protein vi dung dch (1) v dung dch (2) hay nh xc tc ca (3),
cc lin kt peptit trong phn t protein b phn ct dn, to thnh cc chui (4) v cui cng thnh
hn hp cc (5). . in t thch hp vo cc ch trng trong cu trn:
(1) (2) (3) (4) (6)
Cu A. axit baz enzim oligopeptit amino axit
Cu B. baz axit enzim polipeptit amino axit
Cu C. axit baz enzim oligopeptit - amino axit
Cu D. baz axit enzim polipeptit - amino axit
Cu 2: Dy gm cc kim loi c xp theo chiu tnh kh tng dn l
A. Cu, Zn, Al, Mg B. Mg, Cu, Zn, Al C. Cu, Mg, Zn, Al D. Al, Zn, Mg, Cu
Cu 3: Cht no sau y tc dng vi dung dch NaOH sinh ra glixerol
A. Glucoz B. Metyl axetat C. Triolein D. Saccaroz
A. kh mi tanh ca c ngi ta dng mui n. B. ipeptit c 2 lin kt peptit.
C. Isopropanol v N-metylmetanamin c cng bc. D. Anilin c tnh baz yu v lm xanh qu tm
m.
Cu 5: Hn hp X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch
A. NaOH (d) B. HCl (d) C. AgNO3 (d) D. NH3 (d)
Cu 6: Ha tan hon ton 5,6 gam kim loi M trong dung dch HNO3 c ,nng d thu c 3,92 lt kh
NO2 (ktc) l sn phm kh duy nht . Vy M l
A. Cu B. Pb C. Fe D. Mg
Cu 7: Thuc th dng phn bit FeCl2 v FeCl3 l dung dch
A. NaOH B. H2SO4 long. C. Cu(NO3)2 D. K2SO4.
Cu 8: Ion kim loi X khi vo c th vt mc cho php s gy nguy him vi s pht trin c v tr
tu v th cht con ngi. cc lng ngh ti ch cqui c, nhiu ngi b ung th, tr em chm pht
trin tr tu, ci cc v nhim c ion kim loi ny. Kim loi X y l:
A. ng. B. Magie. C. St. D. Ch.
Cu 9: Polime no sau y l polime tng hp ?
A. Thy tinh hu c Plexiglas. B. Tinh bt.
C. T visco. D. T tm.
Cu 10: sn xut nhm trong cng nghip ngi ta thng
A. in phn dung dch AlCl3. B. Cho Mg vo dung dch Al2(SO4)3.
C. Cho CO d i qua Al2O3 nung nng. D. in phn Al2O3 nng chy c mt criolit.
Cu 11: Trong khng kh m, cc vt dng bng ng b bao ph bi lp g mu xanh. Lp g ng l
A. (CuOH)2.CuCO3. B. CuCO3. C. Cu2O. D. CuO.
Cu 12: Hn hp X gm glyxin v lysin. Cho m gam X tc dng hon ton vi dung dch NaOH d, thu
c dung dch Y cha (m + 6,6) gam mui. Mt khc nu cho m gam X tc dng hon ton vi dung
dch HCl, thu c dung dch Z cha (m + 14,6) gam mui. Gi tr ca m l
A. 36,7. B. 49,9. C. 32,0. D. 35,3.

Cu 13: Cho 200 ml dung dch Al2(SO4)3 0,5M tc dng vi 200 gam dung dch NaOH thu c 11,7
gam kt ta trng. Nng dung dch NaOH dng l
A. 9% B. 12% C. 13% D. Phng n khc
Cu 14: in phn dung dch cha 23,4 gam mui n (vi in cc tr, mng ngn xp), thu c 2,5 lt
dung dch c pH=13. Phn trm mui n b in phn l
A. 62,5%. B. 65%. C. 70%. D. 80%.
Cu 15: Khi lm th nghim vi HNO3 c nng thng sinh ra kh NO2. hn ch tt nht kh NO2
thot ra gy nhim mi trng ngi ta nt ng nghim bng bng tm dung dch no sau y
A. Cn B. Gim n C. Mui n D. Xt
Cu 16: Thc hin cc th nghim sau nhit thng:
(a) Cho bt Al vo dung dch NaOH. (b) Cho bt Fe vo dung dch AgNO3.
(c) Cho CaO vo nc. (d) Cho dung dch Na2CO3 vo dung dch CaCl2.
S th nghim c xy ra phn ng l
A. 4. B. 2. C. 3. D. 1.
Cu 17: Trong cc loi ht go, ng, la m c cha nhiu tinh bt, cng thc phn t ca tinh bt l:
A. (C6H12O6)n B. (C12H22O11)n C. (C6H10O5)n D. (C12H24O12)n
Cu 18: Ha tan hon ton 15,4 gam hn hp Mg v Zn trong dung dch HCl d thy c 0,6 gam kh H2
bay ra. Khi lng mui to thnh trong dung dch l
A. 35,7 gam B. 36,7 gam C. 53,7gam D. 63,7 gam
Cu 19: X, Y, Z u c cng thc phn t l C3H6O2. Trong : X lm qu tm ha . Y tc dng vi
dung dch NaOH nhng khng tc dng vi Na kim loi. Z tc dng c Na v cho c phn ng
trng gng.
Tng s ng phn cu to tha mn ca X, Y, Z l:
A. 3 B. 6 C. 4 D. 5
(a) Trong bng tun hon cc nguyn t ha ha hc, crom thuc chu k 4,nhm VIB.
(b) Cc oxit ca crom u l oxit baz
(c) Trong cc hp cht, s oxi ha cao nht ca crom l +6.
(d) Trong cc phn ng ha hc, hp cht crom(III) ch ng vai tr cht oxi ha.
(e) Khi phn ng vi kh Cl2 d, crom to ra hp cht crom (III).
Trong cc pht biu trn nhng pht biu ng l:
A. (a), (c) v (e) B. (a), (b) v (e) C. (b), (d) v (e) D. (b), (c) v (e).
Cu 21: Dy cc cht no di y u phn ng c vi Cu(OH)2 iu kin thng
A. Etylen glicol, glixerol v ancol etylic. B. Glixerol, glucoz v etyl axetat.
C. Glucoz, glixerol v saccaroz D. Glucoz, glixerol v metyl axetat.
Cu 22: Trong s cc kim loi Al, Zn, Fe, Ag. Kim loi no khng tc dng c vi O2 nhit
thng
A. Ag B. Zn C. Al D. Fe
(1) Glucoz, fructoz v mantoz u c kh nng tham gia phn ng trng bc.
(2) Saccaroz, mantoz, tinh bt v xemluloz u b thy phn khi c axit H2SO4 (long) lm xc
tc.
(3) Tinh bt v xenluloz u c to thnh trong cy xanh nh qu trnh quang hp.
(4) Glucoz, fructoz v mantoz u c kh nng ha tan Cu(OH)2 thnh dung dch mu xanh.
Pht biu ng l
A. (1) v (4). B. (1), (2) v (4) C. (1), (2) v (3) D. (1), (2), (3) v (4)
Cu 24: Kim loi no sau y c th tc dng vi nc iu kin thng to ra dung dch lm xanh
giy qu tm l
A. Be B. Ba C. Zn D. Fe
Cu 25: Cho th nghim nh hnh v:

Th nghim trn dng nh tnh nguyn t no c trong glucoz
A. Cacbon. B. hiro v oxi. C. Cacbon v hiro. D. Cacbon v oxi.
Cu 26. Nhn nh no sau y l sai
A. Kim loi natri, kali tc dng c vi nc iu kin thng, thu c dung dch kim
B. Sc kh CO2 vo dung dch natri aluminat, thy xut hin kt ta keo trng.
C. St l kim loi nh, c tnh dn in, dn nhit tt, c bit c tnh nhim t.
D. Nhm tc dng c vi dung dch natri hiroxit.
Cu 27: t chy hon ton m gam C2H5NH2 thu c sn phm gm H2O, CO2 v 1,12 lt kh N2
(ktc). Gi tr ca m l
A. 18,0. B. 9,0. C. 4,5. D. 13,5.
Cu 28: Cho s sau :
X X1 PE
M
Y Y1 Y2 thu tinh hu c
Cng thc cu to ca X l
A. CH2=CHCOOCH=CH2. B. CH2=C(CH3)COOCH2CH3
C. C6H5COOCH2CH3. D. CH2=CHCOOCH2CH2CH3.
Cu 29: Nhn xt no sau y khng ng
A. Cc kim loi kim u c nhit nng chy rt cao.
B. Cc nguyn t kim loi kim u c cu hnh electron lp ngoi cng l ns1.
C. Cc kim loi kim u c tnh kh mnh.
D. Cc kim loi kim u mm v nh.
Cu 30: Trong thnh phn ca gang, nguyn t chim hm lng cao nht l
A. Mn. B. S. C. Si. D. Fe.
Cu 31: Cho 0,10 mol Ba vo dung dch cha 0,10 mol CuSO4 v 0,12 mol HCl. Sau khi cc phn ng
xy ra hon ton, lc ly kt ta nung nhit cao n khi lng khng i thu c m gam cht
rn. Gi tr ca m l
Cu 32: Hn hp X gm 3 cht : CH2O2, C2H4O2, C4H8O2. t chy hon ton mt lng hn hp X,
thu c 0,8 mol H2O v m gam CO2. Gi tr ca m l
A. 17,92. B. 70,40. C. 35,20. D. 17,60.
Cu 33: Cho dung dch NaOH vo dung dch mui clorua X, lc u thy xut hin kt ta mu trng
hi xanh, sau chuyn dn sang mu nu . Cng thc ca X l
A. FeCl2. B. CrCl3. C. MgCl2. D. FeCl3.
Cu 34: Hn hp X gm Al v kim loi M (trong s mol M ln hn s mol Al). Ha tan hon ton
1,08 gam hn hp X bng 100 ml dung dch HCl thu c 0,0525 mol kh H2 v dung dch Y. Cho dung
dch Y tc dng vi dung dch AgNO3 d thu c 17,9375g cht rn. Bit M c ha tr II trong mui to
thnh, nhn xt no sau y ng
A. Nng dung dch HCl dng l 1,05M.
B. Kim loi M l st (Fe).
C. Thnh phn % v khi lng ca mi kim loi trong X l 50%.
D. S mol kim loi M l 0,025 mol.

Cu 35: Thi kh CO i qua ng s ng m gam Fe2O3 nung nng. Sau phn ng thu c m1 gam cht
rn Y gm 4 cht. Ho tan ht cht rn Y bng dung dch HNO3 d, thu c 0,448 lt kh NO (sn
phm kh duy nht, o iu kin chun) v dung dch Z. C cn dung dch Z thu c (m1 + 16,68)
gam mui khan. Gi tr ca m l :
A. 16,0 gam. B. 12,0 gam. C. 8,0 gam. D. 4 gam.
Cu 36: Thc hin phn ng nhit nhm m gam hn hp X gm Al v Fe3O4 n khi phn ng hon
ton thu c hn hp Y (bit Fe3O4 ch b kh v Fe). Chia Y thnh hai phn:
- Phn 1: cho tc dng vi dung dch NaOH d thu c 0,15 mol H2, dung dch Z v phn khng tan T.
Cho ton b phn khng tan T tc dng vi dung dch HCl d thu c 0,45 mol H2.
- Phn 2: cho tc dng vi dung dch HCl thu c 1,2 mol H2.
Gi tr ca m l
A. 164,6. B. 144,9. C. 135,4. D. 173,8.
Cu 37: Cho hn hp A gm 2 cht hu c mch h X, Y (ch cha C, H, O v MX < MY) tc dng va
vi 200 ml dung dch NaOH 1M, thu c 0,2 mol mt ancol n chc v 2 mui ca hai axit hu c
n chc, k tip nhau trong dy ng ng. Mt khc t chy 20,56 gam A cn 1,26 mol O2 thu c
CO2 v 0,84 mol H2O. Phn trm s mol ca X trong A l
A. 20%. B. 80%. C. 40%. D. 75%.
Cu 38: Dung dch X gm 0,02 mol Cu(NO3)2 v x mol HCl. Khi lng Fe ti a phn ng c vi
dung dch X l 5,6 gam (bit NO l sn phm kh duy nht NO3-). Th tch kh thu c sau phn ng l
A. 0,672 lt B. 2,24 lt C. 1,12 lt D. 1,344 lt
Cu 39: un nng m gam hn hp X gm glyxin v alanin thu c m1 gam hn hp Y gm cc
ipeptit mch h. Nu un nng 2m gam X trn thu c m2 gam hn hp Z gm cc tetrapeptit mch
h. t chy hon ton m1 gam Y thu uc 0,76 mol H2O; nu t chy hon ton m2 gam Z th thu
c 1,37 mol H2O. Gi tr ca m l
Cu 40: t chy hon ton 4,03 gam triglixerit X bng mt lng oxi va , cho ton b sn phm
chy hp th ht vo bnh ng nc vi trong d thu c 25,5 gam kt ta v khi lng dung dch thu
c gim 9,87 gam so vi khi lng nc vi trong ban u. Mt khc, khi thy phn hon ton 8,06
gam X trong dng dch NaOH (d) un nng, thu c dung dch cha a gam mui. Gi tr ca a l
A. 4,87. B. 9,74. C. 8,34. D. 7,63.
----------HT----------

THI TH THPT CHUYN BC LIU LN 1
Cu 1: Chn D.
- Khi un nng protein vi dung dch baz v dung dch axit hay nh xc tc ca enzim,
cc lin kt peptit trong phn t protein b phn ct dn, to thnh cc chui polipeptit v cui cng
thnh hn hp cc -amino axit.
Cu 2: Chn A.
Cu 3: Chn C.
- Glucoz, saccaroz khng tc dng vi NaOH.
- Metyl axetat tc dng vi NaOH: CH 3COOCH 3 NaOH
CH 3COONa CH 3OH
ancol metylic
- Triolein tc dng vi NaOH: (C17 H 33COO)3 C3H 5 NaOH

C17 H 33COONa C3H 5 (OH)3
Glyxerol
Cu 4: Chn C.
A. Sai, Trong mi tanh ca c l hn hp cc amin (nhiu nht l trimetylamin) v mt s cht khc,
chnh v vy ngi ta dng gim n (thnh phn c cha CH3COOH) kh mi tanh ca c trc khi
nu.
B. Sai, ipeptit th ch c 1 lin kt peptit.
C. ng, Bc ca ancol chnh l bc ca nguyn t cacbon lin kt vi nhm OH trong khi bc ca
amin c tnh bng s nguyn t hiro b thay th trong NH3 bi cc gc hirocacbon.
D. Sai. Anilin (C6H5NH2) c tnh baz yu v khng lm xanh qu tm m.

Cu 5: Chn B.
- Gi s mol mi cht trong X l 1 mol.
Ha tan X vo NaOH d th ch c Al tan trong Fe2O3 v Cu khng tan.
2Al 6HCl
2AlCl3 3H 2
Ha tan X vo HCl d: Cu 2 FeCl3
CuCl 2 2FeCl 2
Fe 2O3 6HCl
2FeCl3 3H 2O 1 mol 2 mol
1 mol 2 mol
Hn hp tan hon ton trong dung dch HCl d.
Ha tan X vo AgNO3 d th Al v Cu tan trong khi Fe2O3 khng tan.
Ha tan X vo NH3 (d) th khng c cht no tan.
Cu 6: Chn A.
- Gi n v a ln lt l ha tr v s mol ca M
- Qu trnh oxi ha: M M n ne Qu trnh kh:NO3 2H e NO2 H 2O
a an 0,175 0,175
BT: e 5, 6 n 2
n.x 0,175 M n 32n M 64 (Cu)

0,175
Cu 7: Chn A.
Thuc th FeCl2 FeCl3
NaOH To kt ta trng xanh To kt ta nu
H2SO4 long, Cu(NO3)2, K2SO4 Khng hin tng
Cu 8: Chn D.

- Ch l mt kim loi mm, nng, c hi v c th to hnh. Ch c mu trng xanh khi mi ct nhng
bt u xn mu thnh xm kh tip xc vi khng kh. Ch dng trong xy dng, c quy ch, n, v l
mt phn ca nhiu hp kim. Ch c s nguyn t cao nht trong cc nguyn t bn.
- Khi tip xc mt mc nht nh, ch l cht c i vi ng vt cng nh con ngi. N gy tn
thng cho h thn kinh v gy ra ri lon no. Tip xc mc cao cng gy ra ri lon mu ng vt.
Ging vi thy ngn, ch l cht c thn kinh tch t trong m mm v trong xng.
Cu 9: Chn A.
Cu 10: Chn D.
pnc
- Phng trnh in phn Al2O3 nng chy: 2Al2O3 4Al + 3O2
Cu 11: Chn A.
Cu 12: Chn A.
NaOH
H 2 N(CH 2 )4 CH(NH 2 ) COONa, NH 2CH 2COONa (1)
H 2 N(CH 2 )4 CH(NH 2 ) COOH : x mol (m 6,6) gam Y

NH 2CH 2COOH : y mol HCl

ClH3 N(CH 2 )4 CH(NH3Cl) COOH, NH3ClCH 2COOH (2)
m gam X (m 14,6) gam Z
- p dng phng php tng gim khi lng ta c h sau:
mY mX 6, 6
(1) : x y 22

22
0,3
x 0,1 mol
m 36, 7 gam
(2) : 2x y m Z mX 14, 6 0, 4 y 0, 2 mol
36,5 36,5
Cu 13: Chn D.
- Trng hp 1: Al2(SO4)3 d
40n NaOH
+ Ta c: n NaOH 3n Al(OH)3 0, 45 mol C% NaOH .100% 9 %
200
40n NaOH
+ Ta c: n NaOH 4n Al3 n Al(OH)3 0, 65 mol C% NaOH .100% 13 %
200
Vy c 2 gi tr tha mn.
Cu 14: Chn A.
- Dung dch sau in phn c pH = 13 tc l [OH-] = 0,1 nOH 2,5.0,1 0,25mol
- Phng trnh in phn: 2NaCl + 2H2O 2NaOH + Cl2 + H2
0,25 0,25
0,25.58,5
nNaCl (bin phn) 0,25mol %mNaCl bin phn .100% 62,5%
23,4
Cu 15: Chn D.
- hn ch kh NO2 b thot ra khi mi trng th dung dch dng loi b kh phi phn ng c
vi kh v to sn phm khng gy c hi cho mi trng. Do trong qu trnh lm th nghim ngi
ta dng bng tm dung dch kim (xt) hn ch tt nht kh NO2 theo phng trnh sau:
2NO2 + 2NaOH
NaNO3 + NaNO2 + H2O
Cu 16: Chn A.
Cu 17: Chn C.
Cu 18: Chn B.
- Ta c: mmui = mkim loi + 35,5n Cl vi n Cl n HCl 2n H 2 0, 6 mol mmui = 36, 7 (g)
Cu 19: Chn D.
- X lm qu tm ha nn X cha chc axit cacboxylic COOH X c 1 ng phn l C2H5COOH.

- Y tc dng vi NaOH nhng khng tc dng vi Na nn Y cha chc este COO Y c 2 ng phn
l HCOOC2H5 v CH3COOC2H5.
- Z tc dng c Na v cho c phn ng trng gng nn Z cha ng thi 2 nhm chc ancol OH
v anehit CHO Z c 2 ng phn l HOCH2CH2CHO, HOCH(CH3)CHO.
Vy tng s ng phn ca X, Y, Z l 5 ng phn.
Cu 20: Chn A.
(a) ng, Cu hnh Cr (Z=24): [Ar] 3d54s1 Cr nm 24, chu k 4, nhm VIB.
(b) Sai, CrO l oxit baz ; Cr2O3 l oxit lng tnh ; CrO3 l oxit axit.
(c) ng, Cc hp cht ca CrO42- v Cr2O72- s oxi ha cao nht ca Cr l +6.
(d) Sai, Trong cc phn ng ha hc, hp cht crom(III) va ng vai tr cht oxi ha va ng vai tr l
cht kh.
(e) ng, Phng trnh: 2Cr 3Cl 2
2CrCl3
Vy pht biu ng l (a), (c), (e)
Cu 21: Chn C.
Vy cc cht tc dng c vi Cu(OH)2 nhit thng l:
Glucoz: C6H12O6 Etylen glycol: C2H4(OH)2 Glixerol: C3H5(OH)3 Saccaroz: C12H22O11
Cu 22: Chn A.
- Hu ht cc kim loi u tc dng vi O2 tr Ag, Au, Pt.
Cu 23: Chn B.
(3) Sai, Trong qu trnh quang hp ca cy xanh c to thnh tinh bt t CO2, H2O nh nh sng mt tri
anh sang
6nCO2 + 5nH2O (C6H10O5)n + 6nO2
clorophin
Vy cc pht biu ng l (1),(2),(4)

Cu 24: Chn B.
Vy khi cho Ba tc dng vi H2O to thnh dung dch Ba(OH)2 lm qu tm ha xanh.
Cu 25: Chn C.
Cu 26: Chn C.
A. ng, Phng trnh: 2M 2H 2O
2MOH H 2 (M l Na, K)
B. ng, Phng trnh: CO 2 NaAlO 2 2H 2O Al(OH)3 trng keo + NaHCO3
C. Sai, Fe l kim loi nng c mu trng hi xm, c tnh dn in, dn nhit tt, c bit c tnh nhim
t.
D. ng, Phng trnh: 2Al 2NaOH 2H 2O
2NaAlO 2 3H 2
Cu 27: Chn C.
BT: N
n C2H7 N 2n N2 0,1 mol mC2H7 N 4,5 (g)
Cu 28: Chn B.
- Cc phn ng xy ra:
to
CH2 C(CH3 ) COOC2 H5 (M) NaOH CH2 C(CH3 ) COONa (Y) C2 H5OH (X)
H SO , t o
C2H5OH (X)
2 4
CH 2 CH 2 (X1) H 2O
t o , p, xt
nCH 2 CH 2 (X1 )
( CH 2 CH 2 ) n (P.E)
2CH2 C(CH3 ) COONa (Y) H2SO4
2CH2 C(CH3 ) COOH (Y1) Na 2SO4
H SO , t o

CH2 C(CH3 ) COOH (Y1) CH3OH
2 4
CH2 C(CH3 ) COOCH3 (Y2 )


xt,p,t o
nCH2 C(CH3 ) COOCH3 (Y2 ) [ CH2 (CH3 )C(COOCH3 ) ] n (thy tinh hu c)
Cu 29: Chn A.
Cu 30: Chn D.
Cu 31: Chn D.
2 2
- Kt ta ca BaSO4: Ba SO 4
BaSO 4
mol: 0,1 0,1 0,1

Kt ta ca Cu(OH)2: H OH H 2O Cu 2 2OH
Cu(OH) 2
mol: 0,12 0,12 mol: 0,1 0,08 0,04
o
t
- Nung BaSO4 : 0,1 mol ; Cu(OH) 2 : 0,04 mol BaSO4 : 0,1 mol ; CuO : 0,04 mol mrn =
26,5 (g)
Cu 32: Chn C.
- Khi t chy hn hp X lun thu c n CO 2 n H 2O 0,8 mol m CO 2 35, 2 (g)
Cu 33: Chn A.
NaOH O H O
- Qu trnh: FeCl2 (X) Fe(OH)2 trng xanh
2 2
Fe(OH)3 nu
Cu 34: Chn C.
- p dng phng php chn khong gi tr nh sau :
2 1, 08
+ Nu X ch cha Al ta c: n Al n H 2 0, 035 mol MX = 30,86
3 0, 035
1, 08
+ Nu X ch cha M ta c: n M n H 2 0, 0525 mol MX = 20,57
0, 0525
- Kt hp 2 gi tr: 20,57 < MX < 30,86 M l Mg. Khi :
27n Al 24n Mg 1, 08 n Al 0, 02 mol

3n Al 2n Mg 2n H 2 n Mg 0, 0225 mol
BT:H
- Xt dung dch Y:
BT:Cl
n HCl n AgCl 0,125 mol v nHCl (d ) nHCl 2nH2 0,02mol
0,125
Cu A. Sai, Nng HCl cn dng l: C M 1, 25 M
0,1
Cu B. Sai, Kim loi M l Mg
Cu C. ng, Thnh phn % v khi lng ca mi kim loi trong X l 50%
Cu D. Sai, S mol kim loi M l 0, 0225 mol
Cu 35: Chn C.
0,02 mol
to HNO3 3
- Qu trnh: CO Fe2O3 Fe,O
Fe ,NO3 NO H 2O
m (g) m1 (g) hh Y (m1 16,68) g mui Z
- Ta c: ne nhn = n NO3 3n NO 2n O 0,06 2n O m Z m1 16,68 56n Fe 62n NO3 (1)
m mY m1 56n Fe 16n O thay m1 vo (1) suy ra: nO = 0,12 mol
BT: e 3n 2n O BT: Fe n
n Fe NO 0,1 mol n Fe 2O3 Fe 0, 05 mol m Fe 2O3 8 (g)
3 2
Cu 36: Chn B.

H 2 : 0,15 mol
Al 2O3 Z : NaAlO 2
P1 : Y NaOH
Al to
- Qu trnh: X Y Fe
Fe3O 4 Al T: Fe + HCl
H 2 : 0, 45 mol
d
P2 : Y HCl
H 2 :1, 2 mol
o
- Phng trnh: 8Al 3Fe3O 4
t
4Al 2O 3 9Fe
2 2
nAl d nH 2 .0,15 0,1 mol 4
- Phn 1:
BT: e
3 3 n Al2O3 n Fe 0, 2 mol m P1 48,3 gam
nFe nH 2 0,45 mol 9

BTe
3nAl d 2nFe 2nH 2 2,4
nAl 0,2 mol
- Phn 2:
Phn 1 nAl d 0,1 2 d
nFe 0,9 mol
nFe 0,45 9
- Nhn thy: n Fe (P2 ) 2n Fe (P1 ) m P2 2m P1 96, 6 gam m m P1 m P2 144,9 gam
Cu 37: Chn B.
- V nNaOH nROH v hn hp thu c cha hai mui ca hai axit hu c nn hn hp A cha 2 este
n chc, mch h c s C lin tip nhau.

BTKL
mA mO2 mCO2 mH2O n CO 1, 04 mol

- Khi t 20,56 gam A, ta c: BT: O 2

2n A 2n O2 2n CO2 n H2O n A 0, 2 mol
n CO2 X : C5 H x O 2 n X n Y 0, 2
n X 0,16
- Ta c: CA 5, 2 BT:C % n X 80%
nA Y : C6 H y O 2
5n X 6n Y 1, 04 n Y 0, 04
Cu 38: Chn D.
S oxi ha S kh
Fe Fe + 2e
2+
4H + NO3 + 3e
+ -
NO + 2H2O
0,1 0,2 0,16 0,04 0,12 0,04
(v lng Fe phn ng ti a nn Fe chuyn Cu2+ + 2e Cu
ln Fe2+) 0,02 0,04
2H+(d) + 2e H2
BT:e
2n Fe 3n NO 2n Cu 2n H 2 n H 2 0, 02 mol V 22, 4(n NO n H 2 ) 1,344 (l)
Cu 39: Chn A.
- Trng ngng m (g) hn hp X: 2CnH2n+1O2N C2nH4nO3N2 (Y) + H2O
mol: a 0,5a
+ t m1 (g) Y thu c: n H 2O (Y) na 0, 76 (1)
- Trng ngng 2m (g) hn hp X: 4CnH2n+1O2N C4nH8n - 2 O5N4 (Z) + 3H2O
mol: 2a 0,5a
+ t m2 (g) Z thu c: n H 2O (Z) (4n 1).0,5a 1,37 (2)
(1) na 0, 76 38
- Lp t l : n . Thay n vo (1) ta tnh c: a = 0,3 mol
(2) 2na 0,5a 1,37 15
m 24, 74 (g)
Cu 40: Chn C.
- Gi a l s mol trong 4,03 gam X. Khi t chy 4,03 gam X, ta c: n CO2 n CaCO3 0, 255 mol
m mdung dch gim m (44nCO2 18nH 2O ) nH 2O 0,245 mol

- Li c: m X 12n CO2 2n H 2O 16n O 12.0, 255 2.0, 245 16.6a = 4,03 a = 0,005 mol
- Trong 8,06 gam X c: n X 2a 0,01 mol
BTKL
mmui mX 40nNaOH 92nC3H 5(OH)3 8,34(g)
8,06 0,03 0,01

TNH THI NGUYN Mn: KHOA HC T NHIN HA HC
THPT CHU VN AN Thi gian lm bi: 50 pht, khng k thi gian pht
M : 132
Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba=137.
Cu 1: Cacbonhidrat no c nhiu trong cy ma v c ci ng ?

A. Glucoz B. Mantoz C. Fructoz D. Saccaroz
Cu 2: Cho cc kim loi sau: Li, Na, Al, Ca. S kim loi kim trong dy l:
A. 1 B. 3 C. 2 D. 4
Cu 3: ung nng 100 gam dung dch Glucoz 18% vi lng d dung dch AgNO3 trong NH3 n khi
phn ng xy ra hon ton thu c m gam Ag. Gi tr ca m l:
A. 16,2 B. 21,6 C. 10,8 D. 32,4
Cu 4: Loi t no sau y t chy ch thu c CO2 v H2O?
A. T olon B. T Lapsan C. T nilon-6,6 D. T tm
Cu 5: Kim loi c dng ph bin to trang sc, c tc dng bo v sc khe l:
A. ng B. Bc C. St D. St ty
Cu 6: Kt lun no sau y ng?
A. in phn dung dch CuSO4 vi anot ng, nng Cu2+ trong dung dch khng i
B. t l st trong kh Cl2 xy ra n mn in ha
C. Thanh km nhng trong dung dch CuSO4 khng xy n mn in ha
D. Kim loi c tnh kh, n b kh thnh ion dng.
Cu 7: Trong iu kin thng, cht trng thi kh l:
A. etanol B. glyxin C. Metylamin D. anilin
Cu 8: Ha tan hon ton 6,5 gam Zn bng dung dch H2SO4 long thu c V lt H2 (ktc). Gi tr ca
V l:
A. 4,48 lt B. 3,36 lt C. 2,24 lt D. 1,12 lt
Cu 9: Phn ng thy phn este trong mi trng kim gi l phn ng
A. Este ha B. X phng ha C. Trng gng D. Trng ngng
Cu 10: Cng thc ha hc ca st (III) hidroxit l:
A. Fe2O3 B. Fe(OH)3 C. Fe3O4 D. Fe2(SO4)3
Cu 11: Khi lm th nghim vi H2SO4 c nng thng sinh ra kh SO2. hn ch kh SO2 thot ra
gy nhim mi trng, ngi ta thng nt ng nghim bng bng tm dung dch.
A. Mui n B. gim n C. kim D. ancol
Cu 12: Cho cc cht sau: glucoz, fructoz, saccaroz, tinh bt, matri fomat, axit fomic, metyl glicozit.
S cht va tham gia phn ng trng bc, va lm mt mu nc brom l :
A. 5 B. 3 C. 2 D. 4
Cu 13: kh mi tanh ca c (gy ra do mt s amin), ta c th ra c vi:
A. nc B. nc mui C. cn D. gim
Cu 14: Khi lu trong khng kh m mt vt bng st ty (st trng thic) b sy st su ti lp st bn
trong, s xy ra qu trnh
A. Sn b n mn in ha. B. Fe b n mn in ha.
C. Fe b n mn ha hc. D. Sn b n mn ha hc.
Cu 15: Cht khng thy phn trong mi trng axit l:
A. Glucoz B. Saccaroz C. Xenluloz D. Tinh bt
Cu 16: C cc dung dch ring bit khng dn nhn: NH4Cl, AlCl3, FeCl3, (NH4)2SO4. Dung dch thuc
th cn thit nhn bit cc dung dch trn l:
A. NaOH B. Ba(OH)2 C. NaHSO4 D. BaCl2

Cu 17: Este X c cng thc phn t C2H4O2. un nng 9,0 gam X trong dung dch NaOH va n
khi phn ng xy ra hon ton thu c m gam mui. Gi tr ca m l:
A. 12,3 B. 8,2 C. 15,0 D. 10,2
Cu 18: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh
o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch BaOH thu c sn phm c mui H2N
CH2 COONa. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16).
A. H2N CH2 COO C3H7. B. H2N CH2 COO CH3.
C. H2N CH2 CH2 COOH. D. H2N CH2 COO C2H5.
Cu 19: S ng phn amin bc 1 ca cng thc C4H11N l:
A. 8 B. 3 C. 4 D. 2
Cu 20: Cho 2,0 gam hn hp X gm metylamin, imetylamin phn ng va vi 0,05 mol HCl, thu
c m gam mui. Gi tr ca m l :
A. 3,425. B. 4,725. C. 2,550. D. 3,825.
Cu 21: Mt mu kh thi ra c cho qua dung dch CuSO4, thy xut hin kt ta mu en. Hin tng
ny do kh thi c ?
A. SO2 B. H2S C. CO2 D. NO2
Cu 22: Protetin tham gia phn ng mu biure to sn phm c mu ?
A. trng B. C. tm D. vng
A. Dng nc kh bo qun thc phm l phng php an ton nht
B. Dng nc x l cc ion kim loi nng gy nhim ngun nc
C. mt trnh b kh do thiu vitamin A nn n c rt, gc, c chua.
D. Cc amin u khng c, c s dng ch bin thc phm.
Cu 24: Kim loi Ag khng tan trong dung dch:
A. HNO3 long B. HNO3 c nng C. H2SO4 c nng D. H2SO4 long
Cu 25: Phng trnh ha hc no sau y vit sai?
A. Cu + 2FeCl3 CuCl2 + 2FeCl2. B. Cu + 2AgNO3 Cu(NO3)2 + 2Ag.
C. Fe + CuCl2 FeCl2 + Cu. D. Cu + 2HNO3 Cu(NO3)2 + H2.
(d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag.
(g) Glucoz v fructoz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l :
A. 5. B. 3. C. 6. D. 4.
Cu 27: t chy hon ton m gam 1 cht bo triglixerit cn 1,61 mol O2, sinh ra 1,14 mol CO2 v 1,06
mol H2O. Cho 7,088 gam cht bo tc dng va vi dung dch NaOH th khi lng mui to thnh
l:
Cu 28: Cho dy cht sau: H2NCH(CH3)COOH, C6H5OH (phenol), CH3COOCH3, C2H5OH, CH3NH3Cl.
S cht trong dy tc dng c vi dung dch KOH un nng l:
A. 5 B. 3 C. 4 D. 2
Cu 29: C 5 dung dch NH3, HCl, NH4Cl, Na2CO3, CH3COOH cng nng c nh ngu nhin l
A, B, C, D, E. Gi tr pH v kh nng dn in ca dung dch theo bng sau:
Dung dch A B C D E
pH 5,25 11,53 3,01 1,25 11,00
Kh nng dn in Tt Tt Km Tt Km
Cc dung dch A, B, C, D, E ln lt l
A. NH4Cl, NH3, CH3COOH, HCl, Na2CO3 B. CH3COOH, NH3, NH4Cl, HCl, Na2CO3

C. NH4Cl, Na2CO3, CH3COOH, HCl, NH3 D. Na2CO3, HCl, NH3, NH4Cl, CH3COOH
Cu 30: Dung dch X gm 0,02 mol Cu(NO3)2 v 0,1 mol H2SO4. Khi lng Fe ti a phn ng c
vi dung dch X l (bit NO l sn phm kh duy nht ca NO3-).
A. 4,48 gam. B. 5,60 gam. C. 3,36 gam. D. 2,24 gam. `
Cu 31: Ha tan ht 3,264 gam hn hp X gm FeS2, FeS, Fe, CuS v Cu trong 600ml dung dch HNO3
1M ung nng, sau khi kt thc cc phn ng thu c dung dch Y v 1,8816 lt (ktc) mt cht kh
thot ra. Cho Y tc dng vi lng d dung dch BaCl2 thu c 5,92 gam kt ta. Mt khc, dung dch
Y c th ha tan ti a m gam Fe. Bit trong qu trnh trn, sn phm kh duy nht ca N+5 l NO. Gi tr
ca m l:
A. 9,760 B. 9,120 C. 11,712 D. 11,256
A. 0,6 B. 1,25 C. 1,20 D. 1,50
Cu 34: X l mt peptit c 16 mt xch c to t cc -amino axit cng dy ng ng vi glyxin.
t chy m gam X cn dng 45,696 lt O2. Nu cho m gam X tc dng vi lng va dung dch
NaOH ri c cn cn thn th thu c hn hp rn Y. t chy Y trong bnh cha 12,5 mol khng kh,
ton b kh sau phn ng chy c ngng t hi nc th cn li 271,936 lt hn hp kh Z. Bit cc
phn ng xy ra hon ton, cc kh o ktc, trong khng kh c 1/5 th tch O2 cn li l N2. Gi tr gn
nht ca m l :
(a) Cho dung dch AgNO3 vo dung dch HCl (b) Cho Al2O3 vo dung dch HCl long d
(c) Cho Cu vo dung dch HCl c nng d (d) Cho Ba(OH)2 vo dung dch KHCO3
Sau khi kt thc cc phn ng, s th nghim thu c cht rn l :
A. 2 B. 3 C. 1 D. 4
Cu 36: Cho 0,3 mol hn hp X gm H2NC3H5(COOH)2 (axit glutamic) v (H2N)2C5H9COOH (lysin)
vo 400ml dung dch HCl 0,1 M, thu c dung dch Y. Bit Y phn ng vi va ht 800ml dung dch
NaOH 1M. S mol lysin trong hn hp X l:
A. 0,2 B. 0,25 C. 0,1 D. 0,15
Cu 37: Hn hp M gm axit cacbonxylic X v este Y (u n chc v cng s nguyn t cacbon).
Cho m gam M phn ng va vi dung dch cha 0,25 mol NaOH, sinh ra 18,4 gam hn hp hai mui.
Mt khc, cng cho m gam M trn tc dng vi lng d dung dch AgNO3 trong NH3 ung nng kt
thc phn ng thu c 32,4 gam Ag. Cng thc ca X v gi tr ca m ln lt l:
A. C2H5COOH v 18,5. B. CH3COOH v 15,0. C. C2H3COOH v 18,0 D. HCOOH v 11,5.
Cu 38: Hn hp M gm H2NR(COOH)x v CnH2n+1COOH. t chy hon ton 0,5 mol M thu c
26,88 lt CO2 (ktc) v 24,3 gam H2O. Mt khc, cho 0,1 mol M phn ng va vi dung dch cha a
mol HCl. Gi tr ca a l:
(1) Cho xenlulozo vo ng nghim cha nc Svayde, khuy u thy xenluloz tan ra.
(2) T visco, t axetat l t tng hp
(3) t nitron (hay olon) c dng dt vi may qun o m hoc bn thnh si len an o rt
(4) Cc hp cht hu c thng c nhit nng chy, nhit si cao (kh bay hi)
(5) Trong phn ng trng gng, glucozo ng vai tr cht oxi ha
S pht biu ng l :
A. 2 B. 3 C. 5 D. 4
Cu 40: Cho m gam hn hp X gm Fe, Fe3O4 v Fe(NO3)2 tan ht trong 320 ml dung dch KHSO4 1M.
Sau phn ng, thu c dung dch Y cha 59,04 gam mui trung ha v 896 ml NO (sn phm kh duy
nht ca N+5, ktc). Y phn ng va vi 0,44 mol NaOH. Bit cc phn ng xy ra hon ton. Phn
trm khi lng ca Fe(NO3)2 trong X c gi tr gn nht vi gi tr no sau y ?
A. 63. B. 18. C. 73. D. 20.
----------HT----------

THI TH THPT CHU VN AN QUNG TR LN 1
Cu 1: Chn D.
Cu 2: Chn C.
Cu 3: Chn C.
- Ta c: nAg = 2nGlucoz = 0,2 mol mAg = 21, 6 g
Cu 4: Chn B.
- Cc loi t olon, t nilon-6,6 v t tm trong thnh phn c cha N nn khi t chy hon ton th c
to sn phm kh N2.
Cu 5: Chn B.
- Bc c ng dng rt ph bin trong vic to trang sc, ngoi ra bc cn c tc dng bo v sc khe ca
con ngi.
Cu 6: Chn A.
A. ng, Khi in phn dung dch CuSO4 vi anot bng Cu th nng ca Cu2+ trong dung dch
khng i: Cu + Cu2+ Cu2+ + Cu
B. Sai, t Fe trong kh Cl2 khng c tip xc vi cht in li.
C. Sai, Thanh km nhng trong dung dch CuSO4 c xy ra n mn in ha
D. Sai, Kim loi c tnh kh, n b oxi ha thnh ion dng.
Cu 7: Chn C.
Cu 8: Chn C.
VH 2 22, 4.n Zn 2, 24 (l)
Cu 9: Chn B.
Cu 10: Chn B.
Cu 11: Chn C.
- trnh SO2 thot ra khi cn tm bng vi kim: 2OH SO 2 SO32 H 2O
- Phn ng to mui khng bay hi v khng c nh SO2.
Cu 12: Chn B.
- C 3 cht tha mn bi l: glucoz, natri fomat, axit fomic.
Cu 13: Chn D.
- Dng gim l axit nh to mui vi amin, d ra tri. ng thi axit yu nn khng nh hng ln
n cht lng tht c.
Cu 14: Chn B.
- Khi lu trong khng kh m mt vt bng st ty (st trng thic) b sy st su ti lp st bn trong, s
xy ra qu trnh Fe b n mn in ha.
Cu 15: Chn A.
Cu 16: Chn B.
Thuc th NH4Cl AlCl3 FeCl3 (NH4)2SO4
Ba(OH)2 dng d C kh mi khai Ban u c kt ta C kt ta mu Va c kh mi
trng keo sau tan nu khai thot ra va
dn. to kt ta trng
Cu 17: Chn D.
- Este X ch c 1 cng thc cu to duy nht l: HCOOCH3 nn n X n HCOONa 0,15mol m 10, 2 g
Cu 18: Chn B.
n CO2
- Khi t chy X tac c: n N2 0, 025 n X 0, 05mol v C =3
nX
- Khi X tc dng vi NaOH thu c sn phm c mui H2N CH2 COONa
Vy X l: H 2 N CH 2 COONa
Cu 19: Chn C.
Bc ca C4H11N Bc 1 Bc 2 Bc 3
S ng phn 4 3 1
Cu 20: Chn D.
BTKL
m mX 36,5.n HCl 3,825 (g)
Cu 21: Chn B.
- Khi cho dung dch CuSO4 tc dng vi H2S th thy c kt ta CuS mu en.
Cu 22: Chn C.
Cu 23: Chn D.
D. Sai, Cc cht kh metyl-, etyl-, imetyl-, trimetyl- u l cc kh c; ngoi ra cn c c anilin cng l
mt cht lng rt c.
Cu 24: Chn D.
Cu 25: Chn D.
- Phn ng ca Cu v HNO3 khng to sn phm l H2 v ion H+ khng oxi ha c Cu.
Cu 26: Chn A.
- Cc pht biu ng l: (a), (b), (c), (e), (g);
- Pht biu (d) sai v thy phn saccaroz thu c 2 loi monosaccarit l glucoz v fructoz.
Cu 27: Chn A.
BTKL
- Khi t chy cht bo trn th: m 44nCO2 18n H2O 32nO2 17,72g
BT: O
n O X 2n CO2 n H2O 2n O2
n X 0,02 mol
6 6
- Xt trong 7,088 gam X th: n X 0,008mol n NaOH 0,024 mol
mmui = mX m NaOH mC H OH 7,312g
3 5 3
Cu 28: Chn C.
- C 4 cht tha mn l: H2NCH(CH3)COOH; C6H5OH; CH3COOC2H5; CH3NH3Cl.
Cu 29: Chn C.
- Kh nng dn in ph thuc vo kh nng phn ly ra ion ca cc cht do vy cc cht in ly tt th s
dn in tt v ngc li. Xt 5 dung dch trn:
Kh nng dn in tt: NH4Cl, Na2CO3, HCl Kh nng dn in km: NH3, CH3COOH
- Gi tr pH cc dung dch theo th t: Na2CO3 > NH3 > NH4Cl > CH3COOH > HCl.
Vy cc dung trn l:
Dung dch NH4Cl (A) Na2CO3 (B) CH3COOH (C) HCl (D) NH3 (E)
Cu 30: Chn B.
S oxi ha S kh
Fe Fe + 2e
2+
4H + NO3 + 3e
+ -
NO + 2H2O
0,02 0,04
2H+(d) + 2e H2
0,04 0,04 0,02
3n NO 2n Cu 2 2n H2

BT:e
n Fe 0,1 mol m Fe 5,6 (g)
2
Cu 31: Chn D.
- Khi cho Y tc dng vi BaCl2 th: n BaSO4 nS X 0,024 mol
- Trong Y c: n NO 0, 084 mol n NO n HNO3 n NO 0,516 mol
3
BT: O
n H2O 3n HNO3 n NO 3n NO 4nSO 2 0, 072 mol
3 4
BT: H
n H du n HNO3 2n H2O 0, 456mol

3n Fe 2n Cu 6n S 3n NO 0, 252 mol n Fe 0, 024 mol
- Qui hn hp X v Fe, Cu, S th
56n Fe 64n Cu 32n S 3, 264 n Cu 0, 018mol
V ha tan ti a Fe nn Fe chuyn thnh Fe . Cc qu trnh oxi ha kh:
2+
3Fe 8H 2NO3 3Fe2 2NO 4H 2O ; Fe Cu 2 Fe 2 Cu ; Fe 2Fe3 3Fe2

n Fe 0,375n H n Cu 2 0,5n Fe3 0, 201 mol m Fe 11, 256 (g)
Cu 32: Chn B.
- V 2nFe nAgNO3 3nFe nn trong dung dch sau phn ng ch cha Fe(NO3)2 v Fe(NO3)3.
Cu 33: Chn B.
n O 2 0, 64 mol n X CO 2 0, 2 mol
32 2
0,56
0, 2
cacboxylic k tip nn 2 este trong X ln lt l:

CH 3COOC 2 H5 : y mol 2x 4y 0,56 y 0, 08
Cu 34: Chn C.
- Ta c: nO2 (ot Y) nO2 (ot X) 2,04 mol nO2 (d) nO2 (kk) nO2 (ot Y) 0,46mol
2,5 2,04
- Xt qu trnh t hn hp Y.
amol 2,5mol 10mol anmol anmol (0,5a10)mol 0,46mol anmol (0,5a10)mol 0,46mol
ng ng t
CnH2nO2NNa O2 ; N2 Na2CO3 CO2 , H2O, N2 ,O2(d ) CO2 , N2 ,O2( d )
Y khng kh 0,5amol hn h p khv hi (hn h p Z) 12,14mol
nCO2 nN2 nO2 (d ) 12,14 an 1,68 an 1,68
+ Ta c: BT:O
2nY 2nO2 3nNa2CO3 2nCO2 nH2O 1,5a 3an 4.08 a 0,64
+ Khi cho m gam X + NaOH ta c: mY a.(14n 69) 67, 68(g) v
a
nH2O nX 0,08 mol
BT:Na
nNaOH nCnH2nO2NNa 0,64 mol
s mc xch
BTKL
mX mY 18n H2O 40n NaOH 42,8(g)
Cu 35: Chn B.
- C 3 phn ng thu c cht rn l:
(a) AgNO3 HCl AgCl HNO3
(c) Cu khng phn ng vi HCl nn sau phn ng thu c cht rn l Cu.
(d) Ba OH 2 2KHCO3 K 2CO3 BaCO3 2H2O
Cu 36: Chn A.
- Gi a, b ln lt l s mol ca axit glutamic v lysin, ta c: a + b = 0,3 (1)
- Thc hin gp qu trnh ta suy ra: n COOH n HCl n NaOH n COOH 2a b 0,8 0, 4 0, 4 (2)
- T (1), (2) ta tnh c a 0,1 mol ; b 0, 2 mol
Cu 37: Chn B.

- V M phn ng vi AgNO3/NH3 to Ag nn este Y l este ca HCOOH (X khng th l HCOOH v X
n Ag
v Y c cng s nguyn t C nn s nguyn t C ca Y t nht l 2) nY = = 0,15 mol
2
- M phn ng va vi 0,25 mol NaOH nn nX = 0,25 - nY = 0,1 mol
- Gi cng thc ca X l RCOOH th cng thc ca Y l HCOOR mui gn RCOONa v HCOONa.
vi mmui = 0,1(R + 67) + 0,15.68 = 18,4 R = 15 l CH3-
Vy X l CH3COOH v Y l HCOOCH3 m = 15 (g)
Cu 38: Chn A.
- Nhn thy: n H2O 1,35 mol n CO2 1, 2 mol amino axit l no, n chc.
- t cng thc chung ca amino axit l CmH2m+1O2N. Khi t chy:
- p dng bt bo ha: na.a 2(nCO2 n H2O ) 0,3 mol
Vy 0,1 mol M tc dng vi HCl th c 0,06 mol amino axit a = 0, 06 mol
Cu 39: Chn B.
- C 3 pht biu sai l: (2), (4), (5).
(2) Sai, T visco v t axetat l t bn tng hp
(4) Sai, Cc hp cht hu c khng bn nhit, d bay hi, d chy.
(5) Sai, Glucoz trong phn ng ny ng vai tr l cht kh.
Cu 40: Chn C.
0,04 mol
NO H 2O
Fe, Fe3O 4 , Fe(NO 3 ) 2 KHSO 4 0,32 mol 0,32 mol
NaOH
m (g) X 0,32 mol K , Fe 2 , Fe 3 , NO 3 ,SO 4 2 Fe(OH) 2 , Fe(OH) 3
59,04(g) dd Y
n KHSO 4
BT:H
n H 2O 0,16 mol
BTKL
m X m Y 30n NO 18n H 2O 136n KHSO 4 19, 6 (g)
2
- Ta c: 2nFe2 3nFe3 nNaOH 0,44 mol
BTDT(Y)
nNO3 nK 2nFe2 3nFe3 2nSO42 0,12 mol
n NO n NO3
BT:N
n Fe(NO3 )2 0,08 mol %m Fe(NO3 ) 2 73, 46
2
Cm n qu thy c v cc bn c b 50 thi th ny! Mong qu thy c v cc bn gp ti

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n CH2 C COOCH3 to, p, xt

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mrn khan 40nNaOH(d ) 82nCH 3COONa 6,94(g)

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D. Sai, Cc polime khng bay hi.

3nAl nNa 2nH2 3x 2x 0,4 x 0,08 m 27nAl 23nNa 5,84(g)

nA .x nB.y nGly 0,06x 0,04y 0,26 x 3 v y = 2 (tha)

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nA .CA nB.CB nCO2 0,015CA 0,025CB 0,125 CA 5 v CB 2(tha)

mBaCO3 0,3.197 59,1(g)

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mrn 138nK 2CO3 56nKOH(d ) 16,6(g)

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Cu 1: Khi ni v kim loi, pht biu no sau y sai ?

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nZn nH2 0,2mol m 65nZn mCu(rn khng tan) 15(g)

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nGly nAla nX nXY3 0,12mol

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nCuSO4 nMg nFe(p ) 0,01mol CM(CuSO4 ) 0,04M

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Cho bit nguyn t khi ca cc nguyn t :

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p dng nh lut bo ton khi lng ta c

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Cho bit nguyn t khi ca cc nguyn t :

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Cc cht X, T (u c cha nguyn t C trong phn t) c th ln lt l

C. CO2 , NH 4 2 CO3 D. CO2 , Ca HCO3 2

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m 0, 03.197 5,91 gam

b. Fe2O3+ H2SO4 f, glucozo

c. FeS + dung dch HCl g, C2 H 6 Cl2

d. NO2 + dung dch NaOh h, glixerol + Cu OH 2

C. CH 3COOC2 H 5 D. CH 2 C CH3 COOCH3

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nCO2 0,05 2.0,05 0,05 0, 2mol

nCO2 1 0,1 5mol

C6 H10O5 n nH2O nC6 H12O6

admin tha mn : C3 H9 N CH3 NHCH 2CH3 : etyl metylamin

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nancol nH 2O nCO2 0,1mol CH 3OH

nHCHO nHCOOH nCH3OH 0,1

mCH3COOH mCH 2CHCOOH mCH 3CH 2COOH 3,15

mx mkim loai mCl mSO2 38,93 gam

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3Cu 8H 2 NO3 3Cu 2 2 NO 4 H 2O

NH2 2 CO2 H2O NH4 2 CO3

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Gi s mol CaCO3 l a, s mol Ca(HCO3)2 l b, ta c: