(Additives) (Plasticizer) (Modifier)

(Filler) (Stabilizer) (Inhibitor)

(Lubricant) (Pigment)

4
(Primary recycling) (Secondary recycling)
(Tertiary recycling) (Quaternary recycling)

1.

2.

o (Mechanical recycling)

o
(Chemical modification)

Compatibilizer

o (Coextrusion and Coinjection moulding)

3.

o (chemical recycling)

(Depolymerisation)
(Monomer) (Oligomer)

o (Thermolysis)

Thermolysis
3 (Pyrolysis ) (Gasification)
(Hydrogenation)

Pyrolysis
(Synthetic crude oil)

Gasification

Pyrolysis Syngas



2 3

Hydrogenation

100 (Cracking)

(Hydrogenation)

4.

(23 MJ/kg)

(Life cycle assessment)

1.

2.







25%

3.
HDPE LDPE
PHA PE

(MJ/Kg)

LDPE 81

PHA-fermentation process 81

HDPE 80

PCL 77
 PVOH 58

PLA 57

TPS + 60% PCL 52

TPS + 52.5% PCL 48

TPS 25

TPS + 15% PVOH 25

: Review of Life Cycle Assessment for Bioplastic by Dr.Matin Patel, Utretch University,
Natherlands, Nov. 2001

4.

*10 (Kg CO2 eq./Kg)

PCL 53

LDPE 50

HDPE 49

PVOH 42

TPS + 60%PCL 36
 TPS + 52.5% PCL 33

TPS + 15% PVOH 17

Mater Bi TM film grade 12

Thermoplastic starch 11

Mater Bi TM foam grade 9

PLA NA

PLA-ferment NA

: Review of Life Cycle Assessments for Bioplastics by Dr. Martin Patel, Department of
Science, Technology and Society, Utrecht University, Nov. 2001.

(biological oxygen demand,

1.
BOD) (chemical oxygen demand, COD)

2.

3.

4.




(toxicity)



5.
AACs

(terephthalic acid (TPA)

6.

methylene diisocyanate (MDI)
glycerol, sorbital, propylene glycol, ethylene
glycol, polyethylene glycol, triethyl citrate triacetine

CaCO3 TiO2 SiO2 talc

Tin PLA, PCL

Antimony Modified PET

Cobalt Modified PET

Chromium PE blends

Cobalt Managanese Prodegradant polyethylene

Titanium Copolyesters