Metabolitos Secundarios / Secondary Metabolites

Rev. Colomb.investig.agroindustriales. 2016 p- 90-99 ISSN 2422-0582 e- ISSN 2422-4456

Volatile Organic Constituents of Clinopodium gilliesii (Benth.) Kuntze:

Analysis by HS-SPME and classic hydrodistillation

Constituyentes Orgnicos Voltiles de Clinopodium gilliesii (Benth.) Kuntze: Anlisis por

HS-SPME e hidrodestilacin clsica

Ana Mara Vzquez 1*, Mario Leandro Aimar2, Mara Florencia Decarlini1, Gabriela Ins Demmel1,
Juan Jos Cantero3 and Gustavo Miguel Ruiz1

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Recibido: 23.08.2016 Aceptado: 27.10.2016

Abstract ,
Clinopodium gilliesii ,

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Keywords: , , ,

Resumen ,
Clinopodium gilliesii ,

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,
,

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Palabras clave: , , ,

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 Volatile Organic Constituents of Clinopodium gilliesii (Benth.) Kuntze: Analysis by HS-SPME and classic hydrodistillation

INTRODUCTION et a l. ,

Clinopodium gilliesii ,
S at ur ej a par v if olia ,
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et al ., et al ., ,
et al .,

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et al ., , ,

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et al ., et ,
al . ,
et al . ,

C. gilliesii

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C. gilliesii ,

C. gilliesii

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et al .,

C. gi lliesii.

, MATERIAL AND METHODS

Plant Samples

C. gilliesii C. gilliesii
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,

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Rev. Colomb.investig.agroindustriales. 2016 p- 90-99

, ,

Gas Chromatography-Mass Spectrometry

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Figure 1. Clinopodium gilliesii
Statistical analysis
HS-SPME technique

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,
Clinopodium odor um ,
et al ., ,
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C. gilliesii were RESULTS AND DISCUSSION

HS-SPME of leaves
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, C.
gilliesii ,
, ,

C. gilliesii
Essential oil of C. gilliesii ,
e
,
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, ,

92
 Volatile Organic Constituents of Clinopodium gilliesii (Benth.) Kuntze: Analysis by HS-SPME and classic hydrodistillation

, , ,
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HS-SPME of combined aerial parts of the whole plant

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, , C. gilliesii were
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,

HS-SPME of stems

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C. , ,
gilliesii and ,
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C. gilliesii , , ,
and , , ,
t r ans
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, , t r ans -limonene oxide Essential oil analysis
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C. gilliesii
t r ans , , ,
,

HS-SPME of flowers C.
gilliesi ,
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C. gilliesii , , ,
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, , , Differences between the composition of flowers, stems
, , and leaves by SPME analysis
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,

93
Rev. Colomb.investig.agroindustriales. 2016 p- 90-99

HS-SPME analysis of whole plant vs. essential oil

, analysis
et
a l. , ,
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, C. gilliesii ,
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observations, , ,
et a l; et a l;
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guillesii et a l. , , , ,

C. guillesii ,
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et a l.

94
 Volatile Organic Constituents of Clinopodium gilliesii (Benth.) Kuntze: Analysis by HS-SPME and classic hydrodistillation

Table 1.

Pea Rt a KI c KI d %e
b
Compound
k (min) (Ex) (Lit) Lf Sg Fh WPi EOj
-Pinene

, , ,
Limonene

t r ans -
-Terpinene

Linalool

t r ans

c is

t r ans

-Terpineol
Dodecane
t r ans
t r ans -Carveol

1233*

Carvone oxide
Anisole

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Rev. Colomb.investig.agroindustriales. 2016 p- 90-99

Pea Rt a KI c KI d %e
Compound b
k (min) (Ex) (Lit) Lf Sg Fh WPi EOj

-Elemene

Piperitenone

-Elemene
-Copaene
c is-Jasmone

-Maaliene


-Elemene
Aromadendrene

t r ans --Farnesene
-Elemene

epi

,
-Cadinene
-Cadinene 4.6
,
-Cadinene
Elemol

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 Volatile Organic Constituents of Clinopodium gilliesii (Benth.) Kuntze: Analysis by HS-SPME and classic hydrodistillation

Pea Rt a KI c KI d %e
Compound b
k (min) (Ex) (Lit) Lf Sg Fh WPi EOj

-Cadinol

-Cadinol
-Cadinol


c is-t r ans -Farnesol
Total

a b c d

, i

Table 2.
Compound Chemical structure Main uses and biological activitiesa
Piperitone oxide O Antibacteria
O
O
O
O
O
O O
O
Piperitenone oxide O
O O , , ,
O
O
O ,
O O
O

O O
O
O

O
O ,
O
O
O
O

O
O
-Pinene

OH
OH

OH
OH

OH
OH

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Rev. Colomb.investig.agroindustriales. 2016 p- 90-99

CONCLUSION
Ocimum tenuiflorum O . sanc t um
, J E ssent O il R es, , ht t p: / /
, dx .doi .or g/ 10.8/ 104295.6

, , , , , , ,
,
Se seli annuum , J
C. E ssent O il R es, , ht t p: / / dx .doi .or g/ 10.8
gilliesii 0/ 09726X 2014.96

ACKNOWLEDGMENTS , , , ,
,

St ac hy s lav andu lif olia

J
, , E ssent O il B ear P l, , ht t p: / / dx .doi .or g/
10.8/ 09726X .201674
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 Volatile Organic Constituents of Clinopodium gilliesii (Benth.) Kuntze: Analysis by HS-SPME and classic hydrodistillation

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