Health Safety Manual

Sustainable nanotechnology
Environment, Health & Safety

(EHS) Handbook
{www.susnanotec.lk VERSION 1 | SEP 2010

(EHS) Handbook
{ Environment, Health & Safety (EHS) Handbook

SRI LANKA INSTITUTE OF NANOTECHNOLOGY (PVT) LTD
This Health and Safety Policy Statement sets out SLINTEC's aims and objectives for the management of health and safety
of its employees within the institutional setting. It comprises a Policy Statement and details pertaining to the organization
and arrangements for implementing and monitoring the policy. Under the authority of this Policy are a series of specific
policies aimed at identified health and safety issues. These policies set the standards for risk control and are further
supported by guidance to assist those responsible to meet these standards.
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> Environment, Health & Safety (EHS) Handbook
Message from the CEO
Sri Lanka embarked on SLINTEC, Sri Lankas most ambitious Science & Technology initiative to drive nanotechnology
Innovation for business competitiveness in 2008. We commenced operations in December 2008 by initially hiring first
science leadership team and completed equipping SLINTEC with the most advanced nanotech equipment by May 2009.
By August 2009 the science team was advanced and we had a team of 25, a combination of science & business develop-
ment cadre at SLINTEC. One of the major challenges for Sri Lankas most advanced science research and innovation centre
would be to manage the unknown in terms of potential risks in the nanotechnology space, specially because it is only in the
year 2000 that the worlds first public sector nanotechnology institute was set up in USA . As at today, 92 countries world-
(EHS) Hand Book

wide have set up nanotechnology institutes and with each day, the world is discovering the potential of nanotechnology
and its ability to impact the environment and society with sustainable solutions. But at the same time, Nano safety is an area
of major concern due to the fact that managing nano particles invisible to the eye can only be done through extremely
robust, proactive policies, procedures & processes, which anticipates potential risks and manage them in a non-
compromising manner.
Our commitment to environment, health & safety at SLINTEC has always been of the highest priority in order to ensure the
safety of every single employee at SLINTEC and all those who in the course of business we come in to contact with. Having
signed up with NIOSH on nano health & safety, we have embarked on a series of training programs and have installed
many preventive processes to manage the risk. Our first nano health surveillance program, where every single research
employee s vital signs were monitored & measured took place on August 2010.
Today, we launch the SLINTEC Environment, Health & Safety Manual which is another key initiative to ensure nano health &
safety at SLINTEC, as we believe that its SLINTECs corporate responsibility to its employees, its community & its society.
It is now imperative that every single one of us to responsibly implement the nano health & safety policy at SLINTEC.
Ravi Fernando
CEO, SLINTEC
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PREFACE
Sri Lanka Institute of Nanotechnology (Pvt) Limited is an institute, which is explicitly committed to Sustainable Nanotech-
nology that built around three sustainability dimensions, namely, Social, Environment and Economic, undertakes to act
responsibly for the health and safety of its employees and the communities and the environment in which it operates.
Environment, Health and Safety Principles are an integral part of our business strategy, and budgets and plans are formu-
lated to achieve the standards required, whilst intending for optimal environmental performance as well.
This handbook states SLINTECs policy on Environment, Health & Safety, and outlines responsibilities and arrangements for
ensuring the safety of all those working in the institute. This information is in accordance with the national and international
Safety Policies, Codes of Practice and associated Guidance, and is specific to Sri Lanka Institute of Nanotechnology (Pvt)
Ltd and the work carried out there in.
It is important that this book is read and understood before starting work in the institute as the guidelines outlined herein
will help to carry out work safely and to avoid accidents.
However, it is noteworthy that accident prevention is mainly common sense, forethought and planning, tidiness and good
housekeeping. Safety within laboratories in particular requires adherence to Good Laboratory Practices (GLP) and also
constant care and attention, seeking advices, in case of any doubt.
Please note that individuals are required to sign and return the declaration issued with this book as a testimonial of
individual understands and the awareness of the contents of this handbook and the responsibilities with respect to
environment, health and safety.
Concerning the novelty of the technology, the contents of this book will be subjected to review as and when necessary
and updates will be issued where necessary. Suggestions for corrections or contributions in further issues should be sent
to the Science Team Leaders or the Manager-Human Resources.
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(EHS) Hand Book
CONTENTS...
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CONTENTS
1. SLINTEC Environment, Health & Safety Policy (EHS Policy)
Emergency Actions (Injuries/Accidents/Illnesses)
2. Definitions
3. General Safety Requirements
4. Chemical Hazard Risk Assessment
5. Chemical Safety Procedure
6. Hazard Management Information System (HMIS System)
7. Personal Protective Equipment Policy (PPE Policy)
8. Nanoscience Surveillance System
9. Electrical and Mechanical Safety
10. Fire Safety
11. Environmental Safety
12. Clean Room Layout and Clean Room Code of Conduct
13. Monitoring of Safety Standards
14. Personal Aspects
15. Training
16. Declaration
Annexure:
1. Chemical Hazard Risk Assessment Form
2. Accident/Incident Report Form
Appendix
1. Fire Wardens
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01
SLINTEC ENVIRONMENT, HEALTH &
SAFETY POLICY
SLINTEC ENVIRONMENT ,
HEALTH & SAFETY POLICY
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SLINTEC ENVIRONMENT, HEALTH & SAFETY POLICY
Sri Lanka Institute of Nanotechnology (Pvt) Ltd (SLINTEC) as an Institute committed to Sustainable Nanotechnology and as
an employer consigned to United Nations Global Compact Principles, is committed to providing and maintaining a healthy
and safe working environment for all its employees, seconded employees, interns and any other people who may be
affected by its activities. The overall responsibility for ensuring establishment and the effective implementation of this policy
lies with the Leadership of the Institute that is the Science Team Leaders and its Chief Executive Officer. However, Senior
Scientists are responsible for ensuring that all activities in their areas are risk assessed where appropriate; and safe systems
of work implemented and monitored.
Despite its observance to best international health and safety practices, this policy is in accordance with the general duties
of employers to their employees as stated in the Factories Ordinance of 1951. SLINTEC will ensure that the policy conforms
to general rules and expectations of the National Science Foundation and its Industry Partners and that it interfaces effec-
tively with all project clusters/divisions involved in research at SLINTEC.
In developing this policy we affirm that:
SLINTEC has a legal responsibility and a duty to ensure, so far as is reasonably practicable, the health, safety
and welfare at work of all staff and its seconded employees having access to its laboratories and of other
persons using the premises and facilities.
SLINTEC considers that high standards of Health and Safety are of importance in enabling it to achieve its
objectives. Compliance with the legal requirements is the minimum standard that is acceptable.
SLINTEC is committed to planning, implementing and reviewing its Health and Safety arrangements in order
to achieve continual improvements in performance by identifying hazards (the potential for harm), assessing
risks (the likelihood of that harm being realized) and managing those risks.
SLINTEC is committed to ensure that this policy and the arrangements in force are extended to its employ-
ees, seconded employees and all those having access to SLINTEC, or visiting the premises and facilities.
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SLINTEC ENVIRONMENT, HEALTH & SAFETY POLICY
In developing this policy we affirm that continuation...
SLINTEC is committed to consult employees, the representatives from National Institute of Occupational Safety
and Health (NIOSH) on Health and Safety matters and Central Environmental Authority (CEA) on Environmental
Issues.
SLINTEC is bounded to safeguard the environment from the effects of its research and development activities.
(EHS) Hand Book

SLINTEC is obligated to ensure that the demands of activities do not exceed the capabilities of its employees or
embeds to carry out the work without risk to themselves or others.
Whilst the Sri Lanka Institute of Nanotechnology (Pvt) Ltd accepts the main responsibility for implementation of this policy,
individuals have an important role in co-operating with those responsible to ensure a healthy and safe working environment
as the successful laboratory maintenance really relies on individual users understanding, participation and self-discipline. As
trust, understanding and shared responsibility among all users ensure the success of every user, all individuals are required
to abide by rules and requirements made under the authority of this policy.
Chief Executive Officer

January 2010

EMERGENCY ACTIONS (INJURIES, ACCIDENTS AND ILLNESSES)
MAJOR ACCIDENTS AND ILLNESSES LOCAL HOSPITAL
1. Check safety do not put your self at risk
2. Maintain a clear airway
3. Summon help see First Aiders (SLINTEC) Biyagama Private Hospital, Walgama, Malwana
listed in page 10 or dial SECURITY 522 or Dr. Palitha 011-2571578
mobile: 0772-612269 or Tel: 011-2571578 (24 hours treatment including minor surgeries)
4. Control bleeding.
5. Move the casualty as little as possible unless in

immediate danger
6. If anyone has been taken to hospital after an

accident, notify the Manager-Human Resources
(HRM) as soon as possible. All accidents, no
matter how minor, must be reported and properly
documented.
.........................................................................................................................................................................................................................................................................................................................
If you sustain ANY MINOR INJURY, the correct procedure is for you to see a recognized First Aider so that appropriate
action can be taken and thus to ensure that accident/incident forms are completed and any other necessary records are
made.
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THE NEAREST FIRST AIDERS AND OTHER IMPORTANT CONTACTS FOR GENERAL EMERGENCY:
NAME TELEPHONE NUMBER

OUT OF OFFICE HOURS FIRST AID
SILUETA MEDICAL CENTRE 011-4768019
EMERGENCY AT ALL TIMES

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BOI FIRE BRIGADE 011-2465333
POLICE BIYAGAMA 011-2487574, 011-2487306
SECURITY SILUETA 011-4768018
SLINTEC FIRST AIDERS
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Emergency Response Checklist
A. IF A TOXIC GAS LEAK OCCURS

1. Evacuate the building immediately
2. Alert others on the way out
3. Meet outside in the Car Park
B. IF YOU HEAR THE FIRE ALARM

1. Evacuate the building immediately
2. Alert others on the way out
3. Meet outside in the Car Park (designated essembly area)
C. IF YOU SEE SOMEONE UNDER THE EMERGENCY SHOWER OR EYE WASH

1. If the victim/s is/are by themselves, stay close to assist.
2. Call Biyagama Private Hospital on 011-2571578 and demand an ambulance.
3. If requested, assist the person in removing contaminated clothing being
careful, that you do not contaminate yourself.
4. Ask the person to stay in shower 5 minutes for Hydrogen Fluoride (HF)
contamination, 15 minutes for all other chemicals.
5. Get the applicable Material Safety Data Sheet (MSDS) and hand it to the
Emergency Response team or fire department.
6. Notify a staff member/HRM immediately.
D. IF A FIRE STARTS
1. Break fire alarm located at emergency exit doors
2. Evacuate the building immediately.
3. Alert others on the way out.
4. Meet outside in the Car Park (designated essembly area)
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02
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DEFINITIONS
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DEFINITIONS
MSDS Material Safety Data Sheet. Information sent out with all newly purchased chemicals. This sheet contains the
dangers associated with the chemical. Copies of MSDS should be available with the Stores-In- Charge, who holds an
extensive database of sheets relating to the chemicals used in the Institute. Moreover, the printed version of each of the
MSDS is avialable near the First Aid Point together with a mini easy to use First Aid Manual for anyone to read through if
they require information about the harzards of a particular chemical.
Maximum Exposure Limit (MEL) The maximum exposure limit approved by the standard practices for that substance in
relation to the specified reference period. It is the maximum concentration of an airborne substance (averaged over a
reference period) to which individuals may be exposed under any circumstances. Exposure must be reduced below the
MEL as far as is reasonably practicable. Exposure must not exceed the MEL. MELs are assigned when theres a serious
concern about the possible effects on the users.
Exposure Standard/Limit Set at a level at which there is no indication of risk to health of exposure by inhalation day after
day.
MELs, Occupational Exposure Limits (OELs), Short Term Exposure Limits (STELs) & Long Term Exposure Limits (LTELs)
are averaged over a long term period (8 hours) and short term (15 minutes). They are quoted in ppm and mg/min. STELs
are used where substances can cause acute effects, and should prevent adverse health effects due to brief exposure.
Sensitiser a substance known to cause, through an allergic reaction, a chronic adverse health effect that becomes
evident in a significant number of people on re-exposure to the same substance. The allergic reaction produced is acute,
and may be life-threatnening.
Asphyxiant a material capable of reducing the level of oxygen in the body to dangerous levels. Usually works by displac-
ing air in a closed environment, so reducing the amount of oxygen available to breathe. Less than 19% oxygen in air is
considered dangerous. Causes unconsciousness or death by suffocation.
Carcinogen substance that has been proven to, or is suspected of, causing cancer through immediate, repeated or
prolonged contact with skin or eyes or inhalation or ingestion.
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DEFINITIONS
Mutagen substance toxic to reproduction loss of fertility, harm to the unborn child, or hereditable genetic damage may
be caused.
Teratogen an agent that can cause malformations of an embryo or foetus.

Nanomaterials are defined as "anything at the nanoscale" i.e. they have at least one dimension between 1nm to 100nm.
Nanomaterials or nanoparticles are human engineered particles with at least one dimension in the range of one to one
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hundred nanometers. They can be composed of many different base materials (carbon, silicon, and various metals).
Naturally created particles of this size range are normally called ultra-fine particles.
Examples are welding fumes, volcanic ash, motor vehicle exhaust, and combustion products.
Nanomaterials come in many different shapes and dimensions, such as:
0 - dimensional: quantum dots
1 - dimensional: nanowires, nanotubes
2 - dimensional: nanoplates, nanoclays
3 - dimensional: Buckyballs, Fullerenes, nanoropes, crystalline structures
However, as the risks and hazards are at present uncertain, more work is needed. Early work on Ultra Fine Particles and
aerosols indicates the main hazard is likely to be from the inhalation of loose powders causing problems with cardio-vascular
and respiratory diseases and the risk of cancer. Studies have shown nanoparticles well distributed throughout the body.
i.e. brain, testicles, 24 hours after inhalation.
The following factors should be considered:

The different physical and chemical properties of nanomaterials to 'bulk' materials i.e. gold isn't a hazard, gold nanopar
ticles may be.
Small particles penetrate the body more easily.
Work in glove boxes and fume hoods.
Collect all contaminated materials separately.
When working with loose material wear respiratory masks.
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Corrosive - destroys living tissue. Presents a hazard through direct contact with the skin or
eyes. If fumes are inhaled or ingested they may also damage the lungs or digestive system.
E.g. Ammonia, hydrochloric acid, hydrogen peroxide.
Flammable - catches fire easily, liquids with a flash point between 21- 55 C e.g. Acetic Acid,
Xylene, Pentanol. Highly Flammable - readily catch fire after brief contact with a source of
ignition and continue to burn, flash point below 21 C e.g. Acetone, acetonitrile, ethanol,
butanol, tetrahydrofuran. Extremely Flammable - have a flash point below 0 C and boiling
point below 35 C.
E.g. Carbon disulfide, diethylether.
Harmful - if inhaled, swallowed or absorbed through skin, can have limited effects on health.
Can cause irreversible effects, possibly after a single exposure, or serious damage after
prolonged or repeated exposure.
E.g. dichloromethane, xylene, formic acid.
Irritant - may cause irreversible inflammation on immediate, repeated or prolonged contact

with skin or eyes. Irritation lasts longer than 24 hours. Irritation is usually localised, and only
extreme where exposure has been excessive. Some irritants may provoke an allergic reaction,
and will also be classified as harmful.
E.g. pentanol, potassium acetate, methyl acetoacetate.

DEFINITIONS

Toxic - can cause serious acute or chronic effects, even death, when inhaled, swallowed or
SRI LANKA INSTITUTE OF
absorbed through NANOTECHNOLOGY
the skin (PVT)methanol.
e.g. ammonia, carbon monoxide, chloroform, LTD Very Toxic -
can cause extremely serious acute or chronic effects even death, when inhaled, swallowed or
absorbed
This Health and Safety Policy Statementthrough the SLINTEC's
sets out skin aims and objectives for the management of health and
E.g. cyanides.
safety of its employees within the institutional setting. It comprises a Policy Statement and details pertaining to the
organization and arrangements for implementing and monitoring the policy. Under the authority of this Policy are a series
of specific policies aimed atDangerous for the

identified health andenvironment
safety issues.- These
substances that
policies setcan
thecause harmfor
standards to wildlife, the ozone
risk control layer,
and are
watercourses and soil organisms
further supported by guidance to assist those responsible to meet these standards.
E.g. cobalt chloride.
Oxidiser - substances that can cause fire even when not in contact with combustible materials
(e.g. some organic peroxides) and substances that can cause fire, or enhance the risk of fire
when in contact with combustible material (e.g. inorganic peroxides). Also includes substances
that may become explosive when mixed with combustible materials (e.g. some chlorates). Nitric
acid is an oxidiser.
Explosive - substances that can cause sudden, almost instantaneous release of pressure, gas,
and heat when subjected to sudden adverse conditions. Heat, light, mechanical shock, detona-
tion, and certain catalysts can initiate explosive reactions. Compounds containing the functional
groups azide , acetylide , diazo , nitroso , haloamine , peroxide, and ozonide are sensitive to
shock and heat and can explode violently.
>> Environment, Health

Environment, & Safety
Health (EHS)
& Safety Hand
(EHS) Book
Handbook 17
03
(EHS) Hand Book

GENERAL SAFETY REQUIREMENTS
Tidiness and general good housekeeping are extremely important in preventing accidents. This is particulary important in
shared work areas, such as the Wet Lab and Clean Room bays, where numbers of different people work on different
experiments and equipment in the same room. Whilst you should be aware of the hazards created by your work, others
may not. It is important to ensure that the area you work in is left tidy and safe at the end of your experiment, and any
hazards are clearly labelled so that others are not put at risk.
There must be no visitors outside the general office hours of 8.00 am to 5.30 pm, Monday to Friday. Visitors to the laboratory
areas are highly discouraged.
Should obey all warning signs, labels, and tags.
You must not use equipment that you are unfamiliar with before you have been properly trained. Only authorised persons
shall operate machinery, equipment/tools. Only perform operations that you have been trained to perform. Do not attempt
to repair or modify any equipment unless you are competent to do so. Faulty or damaged equipment should not be used
and the ManagerIT & Technical Services or the Equipment Champion responsible for that equipment should be notified
to arrange repair.
Do not operate tools/ machinery that are missing safety protective devices such as guards, alarms, interlocks, local
exhaust ventilation etc. (In such cases inform SLINTEC maintenance staff).
Fire exit routes, doors and safety shower/eye wash stations should not be obstructed. Corridors must be kept free of
obstruction at all times in case of emergency. (Do not store or move equipment to these areas.)
Do not remove or in any way tamper with fire extinguishers. It is an offence to use fire equipment in any circumstances other
than to fight a fire.
Everyone working in the institute should look out for activities or situations that are unsafe. Unsafe situations must be
reported to either to Science Team Leaders, Manager-IT & Technical Services or the HRM as soon as possible. They will then
assess the hazard and take appropriate action, which may include shutting down equipment without prior warning.

GENERAL SAFETY
REQUIREMENTS

GENERAL SAFETY REQUIREMENTS
SLINTEC is a no smoking facility.
Eating and drinking other than in the specified areas are prohibited.
Individual must comply with safe methods of working. In practice, this means obtaining training from experienced users,
reading and filling Risk Assessments (RA) prior to commencing work to familiarize yourself with the hazards and risks, and
using appropriate safety precautions, where instructed. For instance, if it is detailed in a RA that the work should be carried
out in a fume hood wearing gloves and safety glasses, it is up to the individual to follow those precautions. Individuals must
complete RA before commencing work.
Contravention of SLINTECs Environment, Health & Safety Policy and procedures is not acceptable, an appropriate action will
be taken to ensure that correct procedures are complied with.
Minor breaches of procedures will usually be dealt with by immediate superiors, however it may be considered necessary to
issue a written warning.
If breaches of procedure continue, or are considered to be a risk to the safety of the individual concerned or others around
him/her matter will be reported to the HRM, for further action. Persistent and/or flagrant breaches of safety procedures may
result in exclusion from laboratory areas or the institute as a whole.
Personal Protective Equipment (PPE) must be worn where required.
Individuals are required to know the location of emergency and safety equipment in respective areas and as a whole at
SLINTEC. This includes PPE, safety shower/eye wash, first-aid kits spill kits, emergency exits.
No hazardous work may be conducted alone. Especially when working after office hours and non-working days, it is manda-
tory that individuals comply with buddy system.
Any work related injury should be reported to HRM immediately.
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CHEMICAL HAZARD
RISK ASSESSMENT
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CHEMICAL HAZARD RISK ASSESSMENT
Risk Assessments
It is a legal requirement that before individual begin any work activity that carries a significant risk of injury or ill health (and
that would include virtually any laboratory work), individual must carry out a RA.
Risk Assessment is a procedure to assess the likely hazards and risks of an activity. It is the overall process of estimating
the magnitude of risk and deciding whether or not the risk is acceptable. An acceptable risk is one that has been reduced
to a level that is considered safe, having regard to legal obligations and Environment, Health and Safety Policy. The process
of completing a RA helps you to objectively look at what you are working with.
A hazard is a potentially dangerous event. It is a source of a situation with the potential for harm in terms of injury or ill
health, damage to property, damage to the workplace, environment or a combination of these.
Risk is the likelyhood of a hazard occuring and the severity of the harm that would result.
The RA should consider the following:

What the individual is proposing to do overall aim and scope of experiment/work
What hazards are associated with the work
Who could be affected and what the reasonably forseeable injuries/ill health might be
Measures taken to prevent the ill health or accident.
Once the the risk is identified, that need to be controlled. The most obvious way to do this is by removing the hazard,
though this is not often possible. Consider if it is possible to reduce exposure to the hazard this may be by reducing the
time spent doing a hazardous activity to a minimum through careful planning, or by using a precaution such as fume hood
to minimise exposure to chemical fumes.
Finally, consider if PPE is appropriate. In almost all cases of working with chemicals, lab coats, gloves and safety glasses
should be worn. You may also have to use protective shoes, ear plugs and and when necessary.
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Risk Assessments continuation...
In general, engineering controls are preferable to other precautions. These include, fume hoods, barriers, restricted access
and so on. They are less liable to fail due to human error than the use (or misuse) of PPE, and procedural controls. Appropri-

ate information, instruction and training must be given in the proper use of control methods. All PPE, must be routinely exam-
ined to ensure if it is still safe to use. Contaminated clothing should be disposed of or cleaned as appropriate.
(EHS) Hand Book

It is important that engineering controls are maintained in an efficient state, and are checked regularly; some controls, such
as fume hoods, are inspected and tested annually, and records held.
All persons working with hazardous substances must make full and proper use of any control measures provided and must
report any defects discovered either to the Science Team Leaders, the ManagerIT & Technical Services or to the HRM as
soon as possible.
The RA must be recorded in writing. A copy is kept by the HRM, the original (with signatures), is displayed near the equip-
ment or process it relates to. RAs should be reviewed at least annually. In many cases this may simply mean reading through
the RA and confirming that nothing has changed, sign and date to show you have done this priodically as specified. If a
procedure changes significantly, for example different chemicals will be used, then the RA should be revised accordingly. All
persons carrying out a procedure should read, sign and date the RA.
Some activities such as biologocal organisms, work with lasers and radioactive substances have specific legal require-
ments that must be met, if unsure consult your immediate superior, or the Science Team Leaders well before commencing
work.
Do not operate equipment such as pressure vessels, cryogenic equipment, high voltage equipment, lasers etc, unless you
have received proper instructions.
Use the information given on MSDSs to help you compile your assessment. Stores-in-charge is responsible in ensuring that
MSDS are available for all chemicals that the SLINTEC purchased and updating the hard copies available at the file located
near the First Aid Kit for anytime reference.
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Risk Assessments continuation...
The Nanoscience RA should consider the following in coducting risk assessment:
The substances and its characteristics All chemicals are toxic to living organisms under certain conditions. However, a
highly toxic chemical will produce damage even in small amounts, where as a substance of low toxicity is unlikely to
produce any injury unless the exposure involves large quantities, or the accumulation of the substance through repeated
exposure.
Liquids with a low flashpoint become dangerous when the work activity raises their temperature above the flashpoint.
Dust can cause explosive atmospheres eg. Wood, flour. The flammable nature of substance, its potential to form an explo-
sive atmosphere, the likelihood of thermal runaway, and the presence of igntion sources should all be taken into consider-
ation.
The form in which the substance occurs.., e.g. particulate, liquid, gas. This influences way in which it is presented to the
body, and hence the risk. Mixtures and preparations will also be encountered in addition to pure substances. The extent to
which the properties of mixtures may differ from the properties of their individual component substances must be taken into
account.
The exposure, activity, method of production or use of a particular substance influences the quantity absorbed. Conse-
quently, a number of exposures and their duration, the intervals between the exposures and the total length of exposure
must be taken into consideration. Due consideration must also be given to synergistic effects as a result of exposure to two
or more substances at the same time or one after the other. Exposure due to any reasonably forseeable deterioration or
failure of any control measure provided should also be considered, e.g.: rip or hole in gloves worn leading to skin exposure.
Any by-products, emissions, residues and waste must also be considered.
The workplace consideration must be given to how and where the substance is used and under what conditions.
The individuals own physical health and susceptibility to exposure must also be taken into consideration.
Work with nanoscale materials should also be considered.
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(EHS) Hand Book
CHEMICAL SAFETY
PROCEDURE

CHEMICAL SAFETY PROCEDURE
All staff including its seconded employees and interns will be expected to familiarise with the Chemical Safety Procedure
which will be available in each of the laboratories and also in the Company web site.
Laboratories are designated work areas and are not to be adapted into living space or recreation areas.
MSDS pertaining to all the chemicals that are in-house, are available at the First Aid Point for reference and soft
copies of the same will be available on line (LIMS: Laboratory Information Management System ) .
Supervisors have a responsibility for assessing the risk to health and safety from any chemical hazard and for ensuring
that working procedures are assessed and designed to minimise risk. They are responsible for ensuring that all activi
ties involving chemicals or that may release chemicals have been assessed as required by the Company Hazardous
Substances Policy.
Any chemical that a project team receives by different routes should be notified to the STLs/HRM and the MSDS also
should be taken from the same party prior using the particular chemical.
A. Good Chemical Practice
All work should be to the standard of Good Chemical Practice (GChP). GChP sets the minimum standard for ensuring the
protection of people against the adverse effects of chemical substances encountered at work. The main points of GChP
are as follows:
Pipetting by mouth is prohibited.
Entire SLINTEC facility is designated as NO SMOKING.
Benches should be cleaned and tidied regularly; surplus apparatus and chemicals not used for a significant time
period should be returned to the stores or cupboards.
Laboratory coats must be worn when working in the laboratory.
Laboratory coats should be removed on leaving the laboratory area and MUST NOT be worn in tea rooms, common
rooms etc.
As a minimum, Safety spectacles or face visors must be worn to protect the eyes from splashes when handling
hazardous liquids. When the risk from splashing is high, especially from toxic or corrosive liquids or nanoparticles, a
visor or goggles must be worn.
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A. Good Chemical Practice continuation...
Work must be carried out cleanly with the minimum of spilling and splashing to minimise contamination. Contaminated areas
should be cleaned as soon as possible. The work area must be kept tidy and chemicals returned to the approved storage
areas when not in use.
Where it is necessary to avoid the inhalation of fumes and vapours or the buildup of an explosive atmosphere (from highly
flammable liquids or gases) a fume cupboard must be used. Fume cupboards should not be used for storage of chemicals.

Flammable substances must be kept well away from sources of ignition - naked flames, hot plates etc.
Exposure to fumes and vapours must be minimised by covering vessels and by prompt replacement of caps and stoppers
to bottles when handling volatile or dusty chemicals.
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Winchester bottles (2.5 liter) and liquid nitrogen must be carried in the special carriers.
Hands must be washed before leaving the laboratory area.
Highly toxic chemicals must be stored in a locked container and a record of this must be maintained in the stores.
Containers must be adequately labeled to identify contents and to identify risk phrases.
B. Procurement of Chemicals
The following basic rules should be followed when purchasing new chemicals:
Chemical should be always purchased from a reputed and a reliable supplier.
Must ensure that the chemical that is purchased is not a banned product.
Ensure the actual need to purchase the particular chemical by checking the availability of the same before placing the
purchase order and thus avoid the purchasing of same chemicals which are already in the labs.
Only the optimum amount of chemicals that are required for the process must be purchased, whenever possible.
MSDSs of the Chemicals should be collected from the supplier on or before the actual purchasing of the bulk or the sample.
Upon assessing the risk from the information specified in the MSDS, the containers should be properly labeled with the
Hazard Management Information System (HMIS) sticker.
The First Aid information specified in the MSDS should be filed properly in the First Aid Manual, which is placed near the
First Aid Box.
MSDS should be filed properly in the MSDS Master file.
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C. Chemical Storage and Handling Procedures
The most important reasons for proper chemical storage are to lessen the risk of fire, prevent accidental mixing and to
minimise exposure to corrosive and toxic chemicals.
There must be an inventory list of chemicals, which should indicate the amount received, delivered, expiry date etc.
Chemicals that are currently not in use must be stored separately.
Chemicals should be segregated by hazard class or compatibility while storing.
Wherever possible store chemicals in the original container that has the original label and hazard signs.
All chemicals must be handled in wet benches or in some exhausted enclosure.
Chemicals should always be handled and mixed only by a authorised person and he/ she should be wearing the
appropriate personal protective equipment.
Be cautious while opening chemical containers. Point the top of the container away from your face and body. Pressure
may have developed inside the containers during transport.
To avoid splashing, pour chemicals slowly in a controlled manner.
After pouring chemicals from bottles, wipe the neck of the bottle and clean to prevent the chemical from dripping down
the side of the bottle and damaging work surfaces or personnel.
Always Add Acid (AAA) to water, never the reverse.
Do not mix a solvent with an acid. Solvents and oxidisers must never be stored or mixed. These incompatible chemicals
can react violently.
Immediately clean up chemical residues on work surfaces. Clean up with wipes and dispose the waste properly.
Issue chemicals only if the Chemical Hazard Risk Assessment Form is authorised by Senior Scientist or anyone above.
If there is a need to transfer chemicals into another container other than the original one, please colour code contain-
ers for different chemicals appropriately, using the HMIS System.
All the Chemical containers must be labeled with the minimum information that of chemical name, hazard warnings. etc
using HMIS labeling system.
Be aware of special storage conditions such as temperature, relative humidity or limited shelf life. Refer to MSDS file for
this purpose.
{
C. Chemical Storage and Handling Procedures continuation...
Containers of liquid chemicals should not be stacked on top of one another, unless it is instructed.
Do not store chemical bottles or containers above the shoulder level in the labs.
warning signs. Environment, Health & Safety

Store the chemical in its designated place. Avoid storing chemicals in aisle or other area. Designated area/s should have
Use appropriate PPE when cleaning or mixing glue or transferring into another container, as indicated in the HMIS standard.
Avoid over stocking shelves.
(EHS) Hand Book
Chemical should never be routinely stored on the bench top or in fume hoods or on counter tops. These are work areas
and should be kept clear at all times.
The MSDS should be clearly displayed at all storage locations.
Avoid storing chemicals near sources of heat or in direct sunlight.
Tightly seal the cap and store all chemical bottles in the designated storage cabinet until you use it next time.
Keep cabinet closed and handle latched when not in use.
Ensure the issuance of chemicals in a closed container or a sealed bag in such a way to avoid spillage or ingestion.
Equipped with emergency drainage system, (should not be leading to drainage), should have adequate emergency
fire fighting equipment.
In the presence of highly flammable chemicals, all electrical wiring, lighting, and connecting must be in compliance with
standards.
Lists should be displayed on the doors to all cupboards/cabinets detailing the contents. And this should be updated when
new chemicals are added.
Potential ignition sources in areas where flammable liquids are stored or used should be avoided.
The flammable liquids should be stored in special fire-resistant cabinets and the doors should be kept closed at all times.
Other chemicals should not be stored with flammable substances.
No combustible material should be stored near the chemicals. And no more than 50 liters to be stored in any one room.
Acids and bases should be stored separately in the chemical resistant cabinets.
Dry chemicals should be stored in the normal laboratory cupboards available in the respective laboratories. The lists on the
doors should be kept up to date.
{
4. Chemical Transporting / Spillage Handling
Carry only one chemical bottle per hand at a time so as to prevent possible injury due to strain and also to prevent a
chemical spill due to dropping of the bottle(s). Always use the handle to carry the bottle. Use the available chemical
transportation cart when moving multiple bottles of chemicals.
When transporting large bottles of chemicals, bottles should never be lifted by the top only.
Spillage of chemicals should be dealt with promptly. Simple cases should be dealt with using the chemical spills kits
provided in the wet and dry labs.
Do not transport chemical containers unless the caps are tightly sealed.
Immediately call for help if any of the following applies:
a. someone is injured
b. not sure what the chemical is
c. the spill involves mercury
d. the spill involves more than one chemical
e. the spill involves nanoparticles
f. the spill is of a highly toxic, flammable or reactive substance
g. the spill can spread easily
h. the spill may endanger the environment
i. you are unaware of how to deal with the spill
If any doubt whatsoever, ask for help immediately.
Most importantly, do not waste time. The longer you take to deal with a spill, the larger the contaminated area will
become.
5. Approval to Use Chemical
Prior to using any chemical, the approval should be obtained either by the relevant Senior Scientist or the Science Team
Leader by filling out the Chemical Hazard Risk Assessment Form. This will be available in the Stores. The completely filled
form should be duly filed at the Stores.

(EHS) Hand Book
CHEMICAL SAFETYPROCEDURE
{
F. Disposal of Chemical Waste
SLINTEC is committed to ensure the environmental safety and all chemical discharges should be done as per the
instructions stated in MSDS or in accordance with the Waste Management Guidelines provided by BOI.
All empty containers much be tightly closed before disposal, especially as per the guidelines provided in MSDS on the
acceptable disposal methods.
Do not discharge any residual chemicals to environment without PROPER AUTHORISATION AND APPROVAL.
Approvals should be obtained from the Science Team Leaders for bulk discharge.
It is recommended that one should always work to minimise unnecessary release of chemicals into the environment.
Use sparingly Use only the amount of chemical you really need.
To prevent evaporation of the chemicals, keep everything covered.
G. Discipline
All the staff, who handle/work with chemicals are expected to adhere to safety instructions. The Senior Scientists and the
Science Team Leaders should ensure the safety of the staff and the company.

06
(EHS) Hand Book
HAZARD MANAGEMENT
INFORMATION SYSTEM (HMIS)

HAZARD MANAGEMENT INFORMATION SYSTEM (HMIS)
A. HMIS LABEL Chemical Name
Write Hazard Level -

Health aspects
Colour code for
May Refer from MSDS, HEALTH
0- 5

Colour code for
FLAMMABLE
Flammable Aspects
PHYSICAL HAZARD Colour code for Physical

Safety Hazard Health aspects
Write the code for the

Colour
PPEs requirements code for Personal
PERSONAL PROTECTION
may get from MSDS Protection
and refer the attached Special Instrucons
PPE code sheet
protection
B. Explanation of the HMIS Ratings
a. HMIS III - HEALTH HAZARD RATINGS

* Chronic Hazard - Chronic (long-term) health effects may result from repeated overexposure.
0 Minimal Hazard - No significant risk to health.
1 Slight Hazard - Irritation or minor reversible injury possible.
2 Moderate Hazard - Temporary or minor injury may occur.
3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given.
4 Severe Hazard - Life-threatening, major or permanent damage may result from single or repeated overexposure.
{
B. Explanation of the HMIS Ratings continuation...
b. HMIS III - FLAMMABILITY RATINGS
1 Environment, Health & fety

Minimal Hazard - Materials that will not burn.
Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and
semi solids having a flash point above 93.33 C (Class IIIB).
2
(EHS) Hand Book
Moderate Hazard - Materials which must be moderately heated or exposed to high ambient temperatures
before ignition will occur. Includes liquids having a flash point at or above 37. 78C but below 93.33 C
(Classes II & IIIA).
3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions includes
flammable liquids with flash points below 22. 78 C and boiling points above 37. 78 C. as well as liquids with
flash points between 22. 78 C F and 100 F (Classes IB & IC).
4 Severe Hazard - Flammable gases or extremely volatile flammable liquids with flash points below
22. 78 C, and boiling points below 37. 78 C. Materials may ignite spontaneously with air. (Class IA).
c. HMIS III - PHYSICAL HAZARD RATINGS
0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with
water, polymerize, decompose, condense, or self-react. Non-Explosives.
1 Slight Hazard - Materials that are normally stable but those that can become unstable (self-react) at
high temperatures and pressures. Materials may react non-violently with water or undergo hazard
ous polymerisation in the absence of inhibitors.
2 Moderate Hazard - Materials that are unstable and may undergo violent chemical changes at normal
temperature and pressure with low risk for explosion. Materials may react violently with water or form
peroxides upon exposure to air.
3 Serious Hazard - Materials that may form explosive mixtures with water and are capable of detonation
or explosive reaction in the presence of a strong initiating source. Materials may polymerize, decompose,
self-react, or undergo other chemical change at normal temperature and pressure with moderate risk of
explosion.
{
B. Explanation of the HMIS Ratings continuation...
4 Severe Hazard - Materials that are readily capable of explosive water reaction, detonation or explo-
sive decomposition, polymerisation, or self-reaction at normal temperature and pressure.
d. HMIS (SECOND EDITION) REACTIVITY RATINGS
0 Minimal Hazard - Materials which are normally stable even under fire conditions, and which will not
react with water.
1 Slight Hazard - Materials which are normally stable, but can become unstable at high temperatures
and pressures.
2 Moderate Hazard - Materials that undergo violent chemical change at elevated temperatures and
pressures. These materials may also react violently with water.
3 Serious Hazard - Materials that are capable of detonation or explosive reaction, but require a
strong initiating source, or must be heated under confinement before initiation. Materials which react
explosively with water.
4 Severe Hazard - Materials that are readily capable of detonation or explosive decomposition at
normal temperatures and pressures.
{
(EHS) Hand Book
HAZARD MANAGEMENT
INFORMATION SYSTEM (HMIS)

C. HMIS CODE FOR PERSONAL PROTECTIVE EQUIPMENT
HMIS Letter Required Equipment
L through Z
{
Site-specific la bel. Ask your immediate superior or safety specialist for handling instructions

07
(EHS) Hand Book
PERSONAL PROTECTIVE
EQUIPMENT (PPE) POLICY
{
PERSONAL PROTECTIVE EQUIPMENT
The phrase PPE refers to any equipment worn to protect the user whilst they are working. It includes an array of equip-
ment such as safety glasses/goggles/visors, gloves, lab coats, respiratory masks, ear plugs/ear defenders and safety-
shoes.
PPE should be worn after all other methods of reducing risk have been properly considered. PPE only protects the wearer
from harm, and is liable to failure due to incorrect use, damage or being forgotten entirely. The PPE that should be used will
be specified in the Risk Assessment for the activity.
A. Eye Protection:
The eyes are very easily damaged, often resulting in permanent injury. Injuries to the eyes are probably more serious than
to any other organ.
Safety glasses should be worn as specified in Risk Assessments. If in any doubt, it is best to wear them. If you are working
in a shared area such as the Wet Lab, it is mandatory to wear glasses as a matter of routine, even if you are only working
with water, others around you may be using more harmful substances, which could splash and make contact with your
eyes. Those not wearing safety glasses in the Wet Lab may be fined and repeated behavior could result in prohibiting work-
ing there in future.
All the PPEs are available with the Stores-In-Charge and depend on the requirement, the individual may request for neces-
sary PPEs through the immediate superior/Senior Scientist.
3M 6800 Full Face Respirator with 3M 6003 OV/AG Cartridge + 3M 5N11 N95 Filter + 3M 501 Filter retainer (Complete Set) is
provided for those working with hydrofluoric acid.
Normal prescription glasses do not provide adequate protection for laboratory work. Hence, it is mandatory that individuals
wear safety glasses/clear spectacle or the goggles every time they work with hazardous substances.
B. Head protection
Wear protective helmets if you are working in areas where there is the potential for head injury from falling objects.
Wear Hair Covers/Hoods, when necessary, to protect hair from Contamination by Hazardous Materials, prevent it from
getting in the way, or becoming entangled in moving equipment(to prevent injuries). Any long hair should be knotted
properly.
{
C. Gloves (Hand Protection)
Appropriate gloves should be worn when handling substances that may be absorbed through the skin, or that are corro-
sive, harmful, irritant or otherwise damaging to the skin. Users should be aware of the limitations of gloves they should be

inspected regularly for tears or punctures, and removed immediately if they are damaged or contaminated. Disposable
gloves should be worn in routine work.
Contaminated gloves must not be worn when using phones, opening doors and so on. Gloves should not be worn outside
(EHS) Hand Book

the laboratory other than when transferring samples. Be aware that your contaminated glove could transfer chemicals to
door handles etc., thus presenting a hazard to the next person who opens the door.
D. Respiratory Protection
Anyone working with nanoparticles, chemical, acids and dust should wear prescribed respiratory masks, be it full face
respirators, half face respirator or the disposable respirators. The toxic effects of nanoparticles are not fully investigated,
yet, the preliminary work has indicated that they are hazardous to the respiratory system.
The masks considered most suitable for this work are the brand 3M type 9322.
If you feel that you would benefit from wearing a respiratory mask for a particular procedure, please discuss your require-
ments either with Science Team Leaders/Senior Scientist or the HRM.
E. Laboratory Coats (Body Protection)
Lab coats should be properly worn in all labs and one should not roll up the sleves . They should not be worn outside the
laboratory area. Special clean room suits should be worn at all times when working in the Clean Rooms. If lab coats or clean
room suits show wear and tear they should be replaced.
Individuals are expected to keep their own lab coats clean at all times.

F. Hearing Protection
a) Protection against the effects of noise must be used when any user is exposed to noise levels that exceed:
Duration per day, hours Sound level dBA slow response
Time dBA
8 - 90
6 - 92
4 - 95
3 - 97
2 - 100
1 - 1/2 - 102
1 - 105
- 110
or less - 115
G. Protective Footwear
All those working in laboratory areas should wear footwear that adequately covers the feet and offers basic protection
against spills and falling items. Never wear sandals or open shoes in a laboratory, and under no circumstances work in bare
feet except in the nanocharacterisation area. Protective shoes should be worn if regularly handling and moving heavy
equipment. Special overshoes are issued for use in the clean rooms.
{
(EHS) Hand Book
PERSONAL PROTECTIVE
EQUIPMENT (PPE) POLICY
{
PERSONAL PROTECTIVE EQUIPMENT (PPE)
The list of PPEs available and the location/s:

PERSONAL PROTECTIVE
EQUIPMENT
LABORATARY
REMARKS

RE-USABLE
SafetyClearSpectacles-Polycarbonatelens#
WetLab/DryLab
11329
3MAO11356LightVisionSafetyClear NEMS/MEMS/Electronic
Spectacles-Polycarbonatelens Lab

3M AO334 AFAnti-FogChemical Splash
Goggle
WetLab/Stores
3M6200HalfFace Double Cartridge Respirator

3M2091P100(HEPA)Filter ElectronicLab This is
recommendedforLead
and Asbestos

Dust
3M6003OV/AG Cartridge
Thisisrecommended for chemicals
and

acid gases.
3M6800Full Face Respirator with 3M
6003 Forhydrofluoricacids
OV/AG Cartridge +3M5N11N95Filter +3M

501Filter retainer (CompleteSet)
3ME.A.R340-4004Re-UsableEarPlug Industrial Lab
NITTI Safety Shoes
(Mens)

NITTI Chemical Resistant Safety Shoes
(Female)
WetLab
Stainless Steel
Shower
& Eye
Wash
Station

607M (Brand:PRATT) Australia

Kevlar Glove (Heat

resistant)

Chemical Resistant Apron

24"* 36"
30"*48"
DISPOSABLE

3M8210N95ParticulateRespirator WetLab/DryLab ForDust
3M8247R95ParticulateRespirator Loadstar/NEMS/MEMS Forchemicals & Mist

3M8246R95ParticulateRespirator WetLab/DryLab Foracids

3M9322FlatFoldValvedRespirator WetLab/Dry Recommended for mechanically and
Lab/IndustrialLab thermally generatedparticlesandfumes
e.g.:grinding,sanding,crushing,sawing,
smoke,weldingfume.Also,thisisthe
NIOSH recommended Respirator for

nanoparticles.
{
Surgical Gloves

08
(EHS) Hand Book
NANOSCIENCE
SURVEILLANCE SYSTEM

NANOSCIENCE SURVEILLANCE SYSTEM
The CCTV surveillance system operated by SLINTEC is a stand alone fully automated system.
The objectives of the system are to provide coverage of the Institute in order to
Act as a deterrent to theft

Help deter improper use of the facilities
Help deter unsociable behavior
Assist in safety of staff including seconded employees, interns etc.
Help improve overall security
Provide quality evidence sufficient to assist the Management, the Police or other enforcing bodies in any investiga
tion leading to possible disciplinary action.
A. Coverage
The cameras used in SLINTEC are of a fixed variety and are positioned in such a way to monitor persons intending to use
the facility.
B. Incident Reporting
Requests to examine incidents covered under the objectives of the system should be reported to the ManagerIT &
Technical Services as soon as such a violation is observed.
C. Incident Handling
Full colour motion AVI files are stored in 15 minute intervals. The digital recordings are stored for approximately 30 days
before being automatically deleted unless required for incident investigation. Images will only be viewed by staff when an
incident is reported or alarmed on the building access systems.
D. System Maintenance
Maintenance of the system will follow the normal custom and practice as carried out by the ManagerIT & Technical
Services.
E. Human Resources
Access to the communications room is restricted and unauthorised persons will not have access without a member of
SLINTEC staff being present.
{
09
(EHS) Hand Book
ELECTRICAL AND
MECHANICAL SAFETY
{
ELECTRICAL AND MECHANICAL SAFETY
This advice is of a general nature and is relevant to what might be regarded as the ordinary use of electrical equipment. For
special situations, such as testing of live equipment and use of equipment under adverse conditions, additional precautions
are required and specialist advice must be sought via the ManagerIT & Technical Services (ext. 504).
A. Electrical Safety:
When equipment is purchased or hired, written confirmation should be obtained from the suppliers that it complies with
relevant standards, and that safety information is provided in accordance with Factories Ordinance. 13A plug tops will be
fitted by members of the technical staff who have received instruction. All items of portable electrical equipment will be
checked by a competent person at appropriate intervals and records kept of the checks.
It is essential that all equipment is installed and connected correctly and the correct cables and fuses used. Installation and
maintenance of all electrical equipment must only be carried out by a competent personnel, this usually means a qualified
electrician. Consult the Manger - IT & Technical Services in the first instance for advice and help. Never attempt to modify
equipment if you are unsure of what you are doing.
Never remove earth connections. If equipment is not earthed for technical reasons, ensure that areas of high voltage are
clearly labeled.
All equipment must have a means of isolation (switch) that is easily accessible and easily identifiable with the specific
items of equipment.
All terminals including low voltage lines must be electrically and mechanically sound and no undue strain put on them
(e.g. plugs and sockets hanging unsupported).
All terminals must be securely covered to prevent persons touching them.
All lead acid and alkaline batteries should have protective insulated covers over the terminals and be used in
well-ventilated areas.
All flexes (Flexible wires) must be kept clear of the floor or protected to prevent heavy objects being placed or dropped
on them or people walking or tripping on them.
{
All flexes must have extra protection where they pass over or round sharp objects or corners or pass through metalwork
(e.g. points of entry of equipment, etc.). Take care not to trap flexes in doors. Flex lengths should not normally exceed 2
metres.
All flexes must be kept clear of radiators or other sources of heat and must not be wrapped round or fastened to pipe
work.
All flexes must be continuous from wall socket to the place where power is used. If joints are used, they must be checked
and approved by the Manager - IT & Technical Services prior to supply of power.
(EHS) Hand Book

Keep all electrical equipment clear of water taps. Containers of water or other liquids must not be placed on electrical
equipment other than those items of equipment specifically designed for the purpose.
Plugs and sockets used for 220/ 240V AC must not be of the same type as plugs and sockets used for other voltages
such as 100V & DC. Plugs and sockets should conform to appropriate British Standard specifications, e.g. BS 1363: 1984
for 13A supplies.
Where parts are replaced, it is essential that the correct type of replacement part is used (e.g. double insulated parts for
double insulated equipment, cartridge fuses not fuse wire in plugs, fuses of correct ratings. etc.).
Ensure that any items of equipment that are interconnected are fed from the same phase of the mains supply and have
a single isolation point.
Ensure that all equipment has a clear air space round it for cooling purposes.
All equipment, not on standby, should be switched off when not in use. Equipment on standby, e.g. pH meters, should be
marked with a numbered yellow tab. A list of all such equipment should be displayed in each laboratory on the appropri-
ate yellow form Proprietary Equipment Normally Left On.
All equipment must be provided with safety covers or switches that prevent access to tanks and electrically live parts
during operation.
It is expressly forbidden to bypass safety covers/switches/protection equipment.
{
B. Mechanical Safety
This advice is of a general nature and draws attention to mechanical safety implications in the use of moving machinery
and equipment. Specialist advice and information is available both from manufacturers and from the Local Agent.
All moving parts of machinery and equipment must be adequately guarded. Do not use if guards are missing or defective. Report
defects to the Manger - IT & Technical Services. Isolate defective equipment and post notices to prevent others from using it.
No machinery, apparatus or equipment must be used or serviced unless the operator/user has received the Equipment Back up
Training by the relevant Equipment Champion and read the Standard Operating Procedures (SOP) for use and has indicated this by
signing a checklist.
Instructions regarding the use of eye protectors, ear defenders and protective clothing must be adhered to.
Prototype and modified equipment should not be commissioned or used without reference to the Manger - Technical Services.
Centrifuges. All heads and rotors must be properly secured and tubes balanced before operation. High-speed heads and rotors will
be checked by the manufacturer once a year.
Autoclaves, compressed gases and pressure vessels must only be used by trained personnel and operating instructions adhered to.
Equipment is subject to periodic checks by the Technical Services Department.
Power tools - Eye protection must be worn when using power tools.
Vacuum systems - All components in or attached to vacuum systems must be designed or manufactured to withstand the pressures
involved. Eye protection is required when glassware is used. Safety netting must always be used on evacuated vessels as a guard in
case of implosion.
Microwave Ovens - In the event of failure the Manger - IT & Technical Services must be informed; he will arrange for servicing by the
manufacturer. Such ovens must never be used to heat sealed or metal-containing containers or to melt large volumes of agar where
pressure may build up due to local boiling of parts of the melting gel. Follow instructions displayed on each oven.
Ultrasonic Equipment - Ear defenders must be provided for use with ultrasonic probes and sonic emission limited by insulation if
hazardous to others.
High/low temperature equipment - Gloves must be provided and precautions taken to protect operators and others from burns, or in
the case of very low temperature freezers, freezing of hands or sticking to cold surfaces. Warning notices must be displayed where
hot surfaces are exposed.
{
10
(EHS) Hand Book
FIRE SAFETY
{
FIRE SAFETY
SLINTEC is protected by a Defensor Fire Alarm System which is set off by smoke and heat detectors located in all rooms
and laboratories. There are also a number of manual call points (red break glass boxes) located adjacent to all exits and
throughout the building.
You should familiarize yourself with your nearest fire alarm and fire exits.
The action you should take if you encounter a fire is as follows:
Never enter a room that is smoke filled.

Never enter a room if the top half of the door is warm to touch.
If an individuals clothing is on fire, extinguish the fire by rolling the person around on the floor, covering the person with
a heavy cloth (blanket/wet blanket), or drenching the person in a safety shower if the shower is nearby. Use the stop,
drop, and roll method.
If the fire is a small one, tackle it with a fire extinguisher of the correct type
If you have difficulty in extinguishing the fire or if it is a large one then SOUND THE FIRE ALARM. If fire is suspected
in a closed room do NOT open the door.
Phone Security on extension 522 or Siluetta General Number 4768000 and give details of the incident.
Leave the building and proceed to the fire assembly point.
From time to time it is necessary to test the fire alarms in the premises.
Only short intermittent ringing of the bells is required for testing. A long continuous ring must be treated as an alarm.
A list of current fire wardens is in Appendix 1 and will be updated regularly.
However, if you spot a fire and the alarm is not sounding, activate it by breaking one of the manual call points (red break
glass boxes). You may tackle the fire yourself using the fire extinguishers located around the building, but take care not to
use the wrong type of extinguisher on a fire. For example a water extinguisher is fine to use on a paper fire, but would make
the situation much worse if used on burning solvents. Never put yourself at risk attempting to tackle a fire.
* Important - Report any problems with fire alarms, fire extinguishers, or other fire protection devices to the Manager - IT
& Technical Services.
{
11
(EHS) Hand Book
ENVIRONMENT SAFETY

ENVIRONMENT SAFETY
SLINTEC is committed to excellence in environmental stewardship in research and operations and the key objectives
include the following:
The promotion of sound environmental management policies and practices.

Compliance with the requirements of relevant legislation.
The promotion of environmentally responsible procurement.
To minimise waste production, to reuse or recycle waste where appropriate and to regulate the treatment and
disposal of residual waste as per BOI guidelines. (Attempt to keep the generation of waste Hazardous Materials
at a level As low as reasonably achievable (ALARA).).
The promotion of good individual practice in an environmentally friendly manner.
A duty of care on individuals to co-operate with SLINTEC in complying with policy requirements.
A duty of care on individuals to report incidents at work that may cause harm to the environment.
A. Hazardous Waste Management
Attempt to keep the generation of waste Hazardous Materials at a (minimum) level As Low As Reasonably
Achievable (ALARA).
Minimise the amount of unavoidable Hazardous Materials waste if possible.
Make sure you separate the Hazardous Materials waste streams to make further management activities more
feasible and economical.
Recycle or reclaim Hazardous Materials of value within your laboratory.
Manage remaining Hazardous Materials wastes and treatment residues by secure disposal methods.
Do not place empty potentially contaminated Hazardous Materials Containers/bottles (metal, plastic, or glass)
into normal trash baskets.
{
ENVIRONMENT SAFETY
Hazardous Waste Management continuation...
If possible reuse or recycle containers, if not, dispose of them as follows:
a) Rinse/clean container until it is free of any hazardous material residue.

b) Remove all labels before containers are reused, recycled, or disposed.
c) Remove all lids of containers before throwing into the dumpster. (this should be done only after the containers
have been properly cleaned)
(EHS) Hand Book

d) Collect empty containers (metal, plastic, or glass) smaller than 2.5 liters in size into an appropriate temporary
holding/collection vessel .
e) Set empty containers (metal, plastic, or glass) 2.5 liters or greater in size in a safe area. (A holding vessel is not
required.) Authorised users shall take the containers to the appropriate building dumpster for disposal. House
keeping personnel are not responsible for removing these empty containers, but may be willing to do so if
contacted.
Do not keep any Non-Contaminated Sharps (broken glass or glassware, slides, capillary tubes, needles, or other
sharp objects which are not hazardous) into any normal trash receptacles unless packaged as follows:
a) Place Non-Contaminated Sharps into a plastic - lined heavy cardboard box (Glass Disposal Box) or an imper
meable plastic sharps container.
b) When full or reasonably heavy (<25kg), seal it in the box and mark as being broken glass or non- contami-
nated sharps for disposal.
c) Take the box or container of non-contaminated sharps to the appropriate building dumpster for disposal . Do
not allow housekeeping personnel to do this.
{
ENVIRONMENT SAFETY
DO NOT DISPOSE ANY OF THE FOLLOWING SUBSTANCES INTO THE SEWER SYSTEM.
a) Prohibited flammable or explosive materials include, but are not limited to: Gasoline, Kerosene, Naphtha, Benzene,
Toluene, Xylene, Ethers, Alcohols, Ketones, Aldehydes, Peroxides, Chlorates, Perchlorates, Bromates, Carbides,
Hydrides, and Sulphides.Additionally, any waste material with a flash point of less than 60oC, and all aqueous alcohol
solutions with > 24% alcohol by volume.
b) Any noxious or malodorous liquids, solids, nanomaterials or gases that singly or by interaction with other wastes are
sufficient to create a public nuisance or hazard to life or are sufficient to prevent entry into the sewers for mainte-
nance or repair. Examples: Thiols (Mercaptans), Pyridine, Sulphides, Cyanides, Phenols, etc.
c) Solid or viscous substances that may cause obstruction to the flow in the sewer (block the sewer).
d) Any waste water containing toxic pollutants in sufficient quantity that can cause hazard to humans or animals, or
create a toxic effect in the receiving stream.
e) Any waste water with objectionable colour. Example: inks, dye wastes, food and pet food colorings, and vegetable
tanning solutions.
f) Any waste water containing fats, wax, grease, or oils whether emulsified or not, in excess of 100 mg/l or containing
substances that may solidify or become viscous at temperatures between 0 and 65.56 degrees Celsius.
g) Any waste water containing contaminants above the specified National / International standards This list includes:
Antimony, Arsenic, Beryllium, Cadmium, Copper, Cyanide, Lead, Mercury, Nickel, Selenium, Silver, Total Chromium,
Thallium, Zinc, Organic Priority Pollutants, Total Organic Halogens, and Phenolic Compounds. Contact EHS for specific
pollutant limitations.
h) Any radioactive materials .
i) Any untreated hazardous biological materials/agents.
j) Nanomaterials.
The following are important as well to minimise pollution that occurs through Hazardous materials.
Substitute non-hazardous or less-Hazardous Materials for Hazardous Materials as much as possible.

Have techniques that minimise the amount of Hazardous Materials used and/or minimise waste generation.
{
12
(EHS)
CLEAN ROOM HandAND
LAYOUT Book
CLEAN ROOM CODE
OF CONDUCT
{
CLEAN ROOM LAYOUT AND CODE OF CONDUCT
To be inserted upon completing the Clean Room in 2011
{
13
(EHS) Hand Book
MONITORING OF
SAFETY STANDARDS

MONITORING OF SAFETY STANDARDS
Senior Science Team Leaders/Senior Scientists should ensure that their junior scientists are following safety instructions and
are aware of the hazards associated with their work.
The laboratories are subjected to impromptu Safety Inspections by the Manager-IT & Technical Services and the Science
Team Leaders any time.
{
14
(EHS) Hand Book
PERSONAL ASPECTS

PERSONAL ASPECTS
SLINTEC is committed to provide a conducive work environment to its employees and therefore explicitly request employ-
ees to bring to its Managements notice if theres anything that would put the persons health and safety at risk.
For instance there could be risks, which may affect the health and safety of expectant and new mothers and of their child.
Working conditions normally considered acceptable may no longer be so during pregnancy or breastfeeding.
If you are pregnant you may be at risk from different physical, chemical and biological agents, working conditions and
processes. These risks will vary depending on your health and the stage of pregnancy. You should inform your PI/supervisor
if you become pregnant, and all relevant risk assessments should be reviewed to ensure you are working safely. Certain
tasks may not be allowed.

15
(EHS) Hand Book

TRAINING
Training is an essential part of maintaining a safe and healthy environment and therefore to comply with the general duty
to provide such information, instruction, training and supervision as is necessary to ensure, so far as is reasonably practi-
cable, the health, safety and welfare of employees/seconded employees (including interns), health and safety training will
be provided as follows;
At induction
Repeat training as appropriate
On transfer to new duties
On introduction of new technology
On changes in systems of work
When specific training needs are identified during risk assessments
Training should be given on all equipment and apparatus before use, and Self Evaluation Checklist together with the
Researcher Assessment Checklist should be filled and handed over to HRM by the Equipment-In-Charge.
Staff and Supervisors are expected to review safety training needs annually, as part of the review process. All Senior Scien-
tists will be involved in the implementation of health and safety training of staff for which they are responsible.
Records of all health and safety training will be maintained by the HRM.

16
(EHS) Hand Book
DECLARATION

DECLARATION
I hereby declare that I have received, read and understood the information included in this Environment, Health and
Safety Book for Sri Lanka Institute of Nanotechnology (Pvt) Ltd.
Signature : _______________________________
Name : ___________________________________________________________
Date : _______________________________
Kindly return this page to the Human Resources Manager.

(EHS) Hand Book
ANNEXURE

I CHEMICAL HAZARD RISK ASSESSMENT FORM
Consult the MSDS for EACH chemical and complete following for EACH hazardous chemical. If no MSDS is
available go to PLEASE PRINT CLEARLY.
Substance Name: __________________________________________ Date of Assessment:________________

CAS No: ______________________________
Risk Phrases (list full): ________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
Safety Phrases (list in full): ____________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
Summary of process/method: _____________________________ Quan ty used in procedure:_________ ___
Assessed by (PRINT your name): ____________________________________________ Ph EXT:_____________
A. Concentra on Used:__________________________________ (A concentra on cut o level for a

substance represents a level [expressed as a percentage on a weight/weight basis] at above which that substance must be
considered hazardous).
Is the concentra on above level listed as hazardous?

YES Go to B NO Go to I ck 1
B. Dangerous Goods Class Labeling

All products must be labeled in accordance with regula ons.
(i) Which (if any) Dangerous Goods Class does the substance belong?
3(Flammable) 4(Flammable solid) 5(Oxidising) 6(Toxic) 8(Corrosive) (Other)
(ii) Has the product been decanted? YES NO Go to C

If YES then has it been labeled in accordance with regula ons? YES Go to C NO Go to I ck 3
C. Method of Use and Exposure Risks

Is the chemical used in way in which fumes, gases or dust par cles are given o? YES NO
Are any of the following, Eyes, Skin, Inhala on, or Inges on an exposure risk? YES NO
Is the substance a Carcinogen or a Mutagen or a Teratogen? YES NO
If you answered yes to any ques on in C then go to D. If you answered NO to all, go to E
D.1 Protec ve Controls

Is it necessary to work in fume hood/nano enclosure Glove Box? YES Go to D2 NO

Is it necessary to wear suitable protec ve clothing, gloves or eye/face protec on?
YES Go to D2 NO Go to I ck 3
D.2 Are all these protec ve controls readily available, clean and func onal?
YES Go to E NO Go to I ck 3
E. First Aid
What rst aid measures should be taken in case of an accident involving this chemical?___________________
__________________________________________________________________________________________
__________________________________________________________________________________________
__________________________________________________________________________________________
F. Spills
What steps should be taken in the event of a spill of this chemical? ___________________________________
_________________________________________________________________________________________
_________________________________________________________________________________________
Are the required resources and facili es in place? YES Go to G NO Go to I ck 3
G. Training
What training been given in the correct handling of this substance? ___________________________________
_________________________________________________________________________________________
Are you sa s ed you understand the hazards involved in the use of this chemical?
YES Go to H NO Go to I ck 3
H. Disposal
What are the disposal methods?______________________________________________________________
________________________________________________________________________________________
Are the required resources and facili es in place? YES Go to I NO Go to I ck 3
I. RISK ASSESSMENT CLASSIFICATIONS (Tick appropriate Risk Class box)

1. Risks are not signi cant and are not likely to increase.
2. Risks are signi cant but are eec vely controlled.
3. Risks are signi cant and are not adequately controlled.
4. There is insucient informa on to assess risk and level of exposure.
Select 1. if you are using a concentra on less than which is considered hazardous or no precau ons are required.
Select 2. if you are sa s ed that adequate controls are in place.
Select 3. if you answered anywhere where you answered NO go to I 3
Select 4. if you are uncertain about risks, and no MSDS is available.
If you select 3. or 4. the chemical MUST NOT be used, un l the risk can be reduced to 1. or 2.
If risk/s cannot be reduced then protocol may have to be changed or an alterna ve chemical found.
ASSESSMENT APROVAL: I am sa s ed that the risks are not signi cant and/ or adequately controlled.
Assessors signature:_____________________________________________________ Date_____/_____/____
Supervisor Name: __________________________Signature._____________________ Date____/_____/____

ACCIDENT/INCIDENT REPORT FORM
Send to the ManagerHuman Resources or in his/her absence the

Date:
Science Team Leaders who will send copies to the Director of the
Labour Departments Health and Safety Unit and to the Companys Time:
Insurance Oce.
Loca on where the accident/incident occurred:
Descrip on of Accident/Incident
Inves ga on and ac on/measures taken to prevent a recurrence Inves ga on complete? Y/N

If no, indicate when inves ga on
should be completed
In the event of an injury

Name of person involved Status:
Senior Scien st/Scien st/Industry Embed/contractor/visitor/other
(state):
Loca on they work in Job Telephone number
Back to work? Y/N

If no, indicated expected Time loss others
me o
Time loss
Nature of injury Immediate treatment: Further treatment:
First aid/hospital/ First aid/hospital/
own GP/home/none own GP/home/none
other (state): other (state):
Names of witnesses Telephone number
Form completed by Posi on Telephone number
Signed Science Team Telephone number

Leader/Senior
Scien st/Scien st
Print name other (state):
For Health & Safety Accident No Classi ca on

Unit use only
* For guidance on comple ng form see overleaf

Notes on the comple on of the Accident/Incident form:

As much of the form should be completed as soon as possible a er the event and a copy sent to the Human
Resources Manager or in her/his absence to the Science Team Leader who will forward copies to the Director
of the Labour Departments Health and Safety Unit and to the Companys Insurance Oce. Addi onally one
will be kept in with the ManagerIT & Technical Services for further remedial ac on if necessary.
If all the informa on is not immediately available (e.g. the inves ga on is s ll on going) it may be necessary to
re submit a completed form at a later date.
The form should be signed o either by the Senior Scien st or a Science Team Leader. However, in order not
to slow down the repor ng procedure a Junior Scien st or an industry embed can sign o the form.
The following should be reported:

All accidents resul ng in personal injury or me loss
Incidents whether damage occurs of not
Near misses where injury or damage could have occurred
Ill health that may be due to, or made worse by, research ac vi es
Loca on where the accident/incident occurred

The loca on should be given as accurately as possible.
Descrip on of Accident/Incident
A full descrip on of the events causing the accident/incident should be given.
Ac on/measures taken to prevent a recurrence

In most cases some ac on will be appropriate, e.g. a request for rec ca on of an unsafe condi on, altera on
of a procedure, reminding people of safety requirements, undertaking further inves ga ons etc.
Time loss
In even the most trivial accident or incident there will be some me loss, both to the injured person and others
who become involved. The following should be indicated:
the me loss (to date) of the injured person;
any other me loss associated with the accident or incident, e.g. taking the person to hospital,
administering rst aid, clearing up debris, making safe, inves ga ng , report wri ng etc.

(EHS) Hand Book
A PPENDIX

Appendix 1:
Fire Wardens:
Names Contact Numbers
1. Chaminda Peiris
2. Sameera NanayakkaraEnvironment, Health & Safety

(EHS) Hand Book
THE NEAREST FIRST AIDERS AND OTHER IMPORTANT CONTACTS FOR GENERAL EMERGENCY:
NAME TELEPHONE NUMBER
SILUETA MEDICAL CENTRE

OUT OF OFFICE HOURS FIRST AID
011-4768019
EMERGENCY AT ALL TIMES

(EHS) Hand Book
BOI FIRE BRIGADE 011-2465333
POLICE BIYAGAMA 011-2487574, 011-2487306
SECURITY SILUETA 011-4768018
SLINTEC FIRST AIDERS

(EHS) Hand Book
BIBLIOGRA PHY

BIBLIOGRAPHY
University of Birmingham, School of Biosciences. Safety Hand Book October 2009,.
ISO/TR 12885, First Edition 2008. NanotechnologiesHealth and Safety Practices in Occupational Settings Relevant
to Nanotechnologies, Technical Report.
Harvard University, Centre for Nanoscale Systems. Safety Manual.

University of Cambridge, Nanoscience Centre Safety Information.
Kulinowski KM, PhD, The Good Nano Guide A new tool for collaboration on workplace safety,
Paik S, PhD, CIH, Control Banding Approach to Safe Handling of Nanoparticles, October 21, 2009
(EHS) Hand Book

Aitken RJ, Creely KS, Tran CL, Nanoparticles: An occupational hygiene review, Institute of Occupational Medicine for
the Health and Safety Executive 2004
Nanofabrication Centre (NFC), University of Minnesota. Safety Manual and Emergency Response Procedure.
Draft Occupational Safety Health and Welfare Act 2005.
Gibbs L, MPH CIH, Tang M PhD2004. Nanotechnology: Safety and Risk Management Overview.
Ahn K, Ellenbecker MJ. Dermal and Respiratory Protection in Handling Nanomaterials at the Centre for High-Rate
Nanomanufacturing (CHN), Department of Work Environment, The University of Massachusetts Lowell.
German Chemical Industry Association, 2008. Responsible Production and Use of Nanomaterials.
NIOSH 2009. Approaches to Safe Nanotechnology: Managing the Health and Safety Concerns Associated with Engi-
neered Nanomaterials, Department of Health and Human Services.
Ellenbecker MJ. Controls and Practices Overview, Department of Work Environment, The University of Massachusetts
Lowell.
Hallock MF, Greenley P, DiBerardinis L, Kallin D 2008. Potential risks of nanomaterials and how to safely handle materials
of uncertain toxicity.
Gago JM 2004. Introduction: Science policy for risk governance, EMBO reports VOL 5 | SPECIAL ISSUE.

Environment, Health & Safety (EHS) Handbook Design & Concept by : Ruwan Gunawardana - SLINTEC
Sri Lanka Institute of Nanotechnology
(Private) Limited
Lot No: 14, Zone 1,
BEPZ, Walgama, Malwana
Tel: +94 11 4650500 Fax: +94 11 4741995
{www.susnanotec.lk

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Sustainable nanotechnology

Environment, Health & Safety

{www.susnanotec.lk VERSION 1 | SEP 2010

{ Environment, Health & Safety (EHS) Handbook

supported by guidance to assist those responsible to meet these standards.

(EHS) Hand Book

In developing this policy we affirm that:

(EHS) Hand Book

Chief Executive Officer

> Environment, Health & Safety (EHS) Handbook

1. Check safety do not put your self at risk

2. Maintain a clear airway

5. Move the casualty as little as possible unless in

6. If anyone has been taken to hospital after an

NAME TELEPHONE NUMBER

Environment, Health & Safety

SILUETA MEDICAL CENTRE 011-4768019

EMERGENCY AT ALL TIMES

POLICE BIYAGAMA 011-2487574, 011-2487306

SECURITY SILUETA 011-4768018

SLINTEC FIRST AIDERS

Emergency Response Checklist

A. IF A TOXIC GAS LEAK OCCURS

B. IF YOU HEAR THE FIRE ALARM

C. IF YOU SEE SOMEONE UNDER THE EMERGENCY SHOWER OR EYE WASH

Teratogen an agent that can cause malformations of an embryo or foetus.

Environment, Health & Safety

(EHS) Hand Book

The following factors should be considered:

Irritant - may cause irreversible inflammation on immediate, repeated or prolonged contact

> Environment, Health & Safety (EHS) Handbook

> Environment, Health & Safety (EHS) Handbook

of specific policies aimed atDangerous for the

>> Environment, Health

> Environment, Health & Safety (EHS) Handbook

Should obey all warning signs, labels, and tags.

> Environment, Health & Safety (EHS) Handbook

> Environment, Health & Safety (EHS) Handbook

SLINTEC is a no smoking facility.

Personal Protective Equipment (PPE) must be worn where required.

Any work related injury should be reported to HRM immediately.

The RA should consider the following:

Environment, Health & Safety

(EHS) Hand Book

The Nanoscience RA should consider the following in coducting risk assessment:

Any by-products, emissions, residues and waste must also be considered.

Work with nanoscale materials should also be considered.

> Environment, Health & Safety (EHS) Handbook

A. Good Chemical Practice

Environment, Health & Safety

(EHS) Hand Book

warning signs. Environment, Health & Safety

5. Approval to Use Chemical

> Environment, Health & Safety (EHS) Handbook

To prevent evaporation of the chemicals, keep everything covered.

> Environment, Health & Safety (EHS) Handbook

> Environment, Health & Safety (EHS) Handbook

Write Hazard Level -

PHYSICAL HAZARD Colour code for Physical

B. Explanation of the HMIS Ratings

a. HMIS III - HEALTH HAZARD RATINGS

1 Slight Hazard - Irritation or minor reversible injury possible.

2 Moderate Hazard - Temporary or minor injury may occur.

b. HMIS III - FLAMMABILITY RATINGS

Substance Name: __________________________ Date of Assessment: