CO2

OPTIONS: joules

TEMPERATURE SCHEDULE

200.000 298.150 300.000 400.000 500.000 600.000

700.000 800.000 900.000 1000.000 1100.000 1200.000
1300.000 1400.000 1500.000 1600.000 1700.000 1800.000
1900.000 2000.000 2100.000 2200.000 2300.000 2400.000
2500.000 2600.000 2700.000 2800.000 2900.000 3000.000
3100.000 3200.000 3300.000 3400.000 3500.000 3600.000
3700.000 3800.000 3900.000 4000.000 4100.000 4200.000
4300.000 4400.000 4500.000 4600.000 4700.000 4800.000
4900.000 5000.000

NOTE: Thermodynamic properties calculated for temperatures outside the range of

the fitted data may have large errors. This program allows calculations only
for temperatures within 20% above or below the fitted temperature range.

COEFFICIENTS FOR FITTED THERMODYNAMIC FUNCTIONS

CO2 Gurvich,1991 pt1 p27 pt2 p24.

3 g 9/99 C 1.00O 2.00 0.00 0.00 0.00 0 44.00950 -393510.000
200.000 1000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 9365.469
4.943650540E+04-6.264116010E+02 5.301725240E+00 2.503813816E-03-2.127308728E-07
-7.689988780E-10 2.849677801E-13 0.000000000E+00-4.528198460E+04-7.048279440E+00
1000.000 6000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 9365.469
1.176962419E+05-1.788791477E+03 8.291523190E+00-9.223156780E-05 4.863676880E-09
-1.891053312E-12 6.330036590E-16 0.000000000E+00-3.908350590E+04-2.652669281E+01
6000.000 20000.000 7 -2.0 -1.0 0.0 1.0 2.0 3.0 4.0 0.0 9365.469
-1.544423287E+09 1.016847056E+06-2.561405230E+02 3.369401080E-02-2.181184337E-06
6.991420840E-11-8.842351500E-16 0.000000000E+00-8.043214510E+06 2.254177493E+03
THERMODYNAMIC FUNCTIONS CALCULATED FROM COEFFICIENTS FOR CO2

T Cp H-H298 S -(G-H298)/T H delta Hf log K

deg-K J/mol-K kJ/mol J/mol-K J/mol-K kJ/mol kJ/mol

0 0. -9.365 0. INFINITE -402.875 -393.142 INFINITE

200 32.361 -3.412 199.969 217.032 -396.922 -393.389 102.9182
298.15 37.135 0.000 213.787 213.787 -393.510 -393.510 69.0913
300 37.220 0.069 214.017 213.788 -393.441 -393.511 68.6661
400 41.325 4.004 225.309 215.300 -389.506 -393.572 51.5362
500 44.624 8.307 234.898 218.284 -385.203 -393.655 41.2565

600 47.323 12.909 243.280 221.766 -380.601 -393.790 34.4015

700 49.561 17.756 250.748 225.382 -375.754 -393.970 29.5031
800 51.432 22.809 257.492 228.981 -370.701 -394.176 25.8275
900 52.999 28.032 263.643 232.496 -365.478 -394.394 22.9671
1000 54.309 33.400 269.297 235.897 -360.110 -394.613 20.6776

1100 55.420 38.888 274.527 239.174 -354.622 -394.830 18.8033

1200 56.347 44.478 279.390 242.325 -349.032 -395.043 17.2405
1300 57.130 50.153 283.932 245.353 -343.357 -395.252 15.9174
1400 57.798 55.900 288.191 248.262 -337.610 -395.459 14.7828
1500 58.374 61.709 292.199 251.059 -331.801 -395.665 13.7989

1600 58.873 67.572 295.982 253.750 -325.938 -395.875 12.9376

1700 59.310 73.482 299.565 256.340 -320.028 -396.090 12.1772
1800 59.693 79.432 302.966 258.837 -314.078 -396.314 11.5009
1900 60.033 85.419 306.203 261.245 -308.091 -396.548 10.8954
2000 60.335 91.438 309.290 263.571 -302.072 -396.795 10.3501

2100 60.604 97.485 312.240 265.819 -296.025 -397.056 9.8565

2200 60.846 103.558 315.065 267.994 -289.952 -397.334 9.4075
2300 61.065 109.653 317.775 270.099 -283.857 -397.628 8.9971
2400 61.263 115.770 320.378 272.141 -277.740 -397.941 8.6207
2500 61.443 121.905 322.883 274.120 -271.605 -398.272 8.2742
2600 61.608 128.058 325.296 276.043 -265.452 -398.624 7.9540
2700 61.760 134.226 327.624 277.910 -259.284 -398.995 7.6573
2800 61.901 140.410 329.872 279.726 -253.100 -399.387 7.3814
2900 62.033 146.606 332.047 281.493 -246.904 -399.800 7.1244
3000 62.156 152.816 334.152 283.213 -240.694 -400.232 6.8842

3100 62.273 159.037 336.192 284.890 -234.473 -400.686 6.6593

3200 62.385 165.270 338.171 286.524 -228.240 -401.160 6.4482
3300 62.492 171.514 340.092 288.118 -221.996 -401.654 6.2497
3400 62.596 177.769 341.959 289.674 -215.741 -402.168 6.0626
3500 62.697 184.033 343.775 291.194 -209.477 -402.701 5.8859

3600 62.798 190.308 345.543 292.680 -203.202 -403.253 5.7189

3700 62.898 196.593 347.265 294.132 -196.917 -403.823 5.5606
3800 62.998 202.888 348.943 295.552 -190.622 -404.412 5.4105
3900 63.100 209.192 350.581 296.942 -184.318 -405.017 5.2679
4000 63.204 215.508 352.180 298.303 -178.002 -405.639 5.1322

4100 63.310 221.833 353.742 299.636 -171.677 -406.276 5.0029

4200 63.420 228.170 355.269 300.943 -165.340 -406.928 4.8795
4300 63.534 234.517 356.763 302.224 -158.993 -407.595 4.7617
4400 63.652 240.877 358.225 303.480 -152.633 -408.274 4.6491
4500 63.777 247.248 359.656 304.712 -146.262 -408.965 4.5413

4600 63.907 253.632 361.060 305.922 -139.878 -409.668 4.4380

4700 64.045 260.030 362.435 307.110 -133.480 -410.380 4.3390
4800 64.190 266.441 363.785 308.277 -127.069 -411.101 4.2439
4900 64.343 272.868 365.110 309.423 -120.642 -411.830 4.1525
5000 64.505 279.310 366.412 310.550 -114.200 -412.565 4.0646