Su tm: Nguyn nh Hnh THCS Chu Vn An, k P, Gia Lai 1

S GIO DC V O TO K THI TUYN SINH VO LP 10 THPT CHUYN

H NI Nm hc 2014 - 2015
Mn thi: HO HC
CHNH Ngy thi: 25 thng 6 nm 2014
THC Thi gian lm bi: 120 pht.
Cu I (2,0 im)
1/ Cho cc s phn ng: Oxit (X1) + dung dch axit (X2) (X3) +
Oxit (Y1) + dung dch baz (Y2) (Y3) +
t
Mui (Z1) (X1) + (Z2) +
t
Mui (Z1) + dung dch axit (X2) (X3) +
Bit kh X3 c mu vng lc, mui Z1 mu tm, phn t khi ca cc cht tho mn iu kin: M Y1 + MZ1 =
300; MY2 MX2 = 37,5. Xc nh cc cht X1, X2, X3, Y1, Y2. Y3, Z1, Z2. Vit cc phng trnh ho hc minh
ho.
2/ C 3 mu phn bn ho hc th rn ng trong cc l ring bit khng ghi nhn l NH 4NO3, NH4Cl v
(NH4)2SO4. Hy phn bit cc mu phn bn trn bng phng php ho hc, vit phng trnh ho hc minh
ho.
Cu II (2,5 im)
1/ t chy hon ton 15,68 gam kim loi M trong bnh ng kh clo d thu c 45,5 gam mui clorua.
a) Xc nh tn kim loi M.
b) ho tan hon ton 9,2 gam hn hp X gm kim loi M v mt oxit ca kim loi M cn dng va
ht 160ml dung dch HCl 2M, cn nu dn lung H2 d i qua 9,2 gam hn hp X nung nng, sau khi phn
ng xy ra hon ton thu c 7,28 gam cht rn. Tm cng thc ca oxit kim loi trong hn hp X.
2/ Ho tan ht 11,1 gam hn hp A gm Al v Fe trong 200 gam dung dch H 2SO4 19,6% (long) thu c
dung dch B v 6,72 lt H2(ktc). Thm t t 420 ml dung dch Ba(OH)2 1M vo dung dch B, sau phn ng
lc ly kt ta em nung trong khng kh n khi lng khng i thu c m gam cht rn khan.
a) Vit cc phng trnh ho hc xy ra.
b) Tnh thnh phn phn trm theo khi lng cc cht trong hn hp A v tnh gi tr ca m.
Cu III (3,0 im)
1/ Trong mt bnh kn dung tch khng i cha hn hp X gm 0,07 mol CHCH; 0,05 mol CHC
CH=CH2; 0,1 mol H2 v mt t bt Ni. Nung nng bnh thc hin phn ng thu c hn hp Y gm 7
hirocacbon c t khi hi i vi H2 l 19,25. Bng phng php thch hp tch lng hn hp Y thu c
m gam hn hp Y1 (gm CHCH v CHCCH=CH2) v 1,568 lt hn hp kh Y 2 (ktc) gm 5
hirocacbon. Bit ton b lng hn hp Y2 tch c c kh nng phn ng vi ti a 600 ml dung dch Br 2
0,1M. Tm gi tr ca m.
2/ Hn hp M gm hai cht hu c A v B (phn t A c nhiu hn phn t B mt nguyn t cacbon). t
chy hon ton 12,96 gam hn hp M bng lng kh oxi d thu c sn phm chy gm H 2O v 36,96
gam CO2.
a) Tm cng thc phn t v tnh thnh phn phn trm theo khi lng mi cht c trong hn hp M/
b) Khi dn ton b sn phm chy vo 552,9 gam dung dch Ba(OH) 2 20,72% thu c m gam cht kt
ta v dung dch Z. Tm gi tr ca m v tnh nng C% ca cht tan c trong dung dch Z.
Cu IV (2,5 im)
1/ Ho tan hon ton 8,56 gam mt mui clorua vo nc thu c 200 ml dung dch Y. Ly 25 ml dung dch
Y em tc dng vi dung dch AgNO3 d thu c 2,87 gam mui kt ta trng.
a) Tm cng thc ho hc ca mui clorua dng (mui X).
b) T mui X, vit cc phng trnh ho hc thc hin s :
+ n cht A
Kh (G1)
NaOH H2 O KOH
(X) (Y1) (Y2)kh (Y3)
+ n cht B
Kh (G2)
2/ Cho m gam hn hp A gm Fe v Mg tc dng vi dung dch HCl d thu c 3,808 lt H 2 (ktc). Mt
khc nu cho m gam hn hp A vo 200 ml dung dch cha AgNO 3 0,5M v Cu(NO3)2 0,8M, phn ng xong,
lc b phn cht rn thu c dung dch B cha ba mui. Khi thm dung dch NaOH d vo dung dch B ri
lc b kt ta em nung ngoi khng kh n khi lng khng i thu c 10,4 gam cht rn. Tm gi tr
ca m v tnh khi lng mi mui trong dung dch B.
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