1.

Nu phng php xc nh st theo Standard methods for the Examination of

Water and Wastewater, AWWA_APHA (2005)? V lu phng php xc
nh st.
Xc nh St Trong Nc Bng Phng Php Phenantrolin (3500
Fe B Phenantrolin Method)

Nguyn tc:
un cch thy vi hydroxyamin trong mi trng acid chuyn Fe (III) c
mt v Fe (II) v ln mu vi thuc th 1,10 phenantrolin pH t 3,2 n 3,3.
Mt ion Fe(II) s kt hp vi 3 phn t 1,10 phenantrolin hnh thnh phc c
mu cam. o mt quang ca dung dch phc bc sng 510nm cho php
xc nh c nng st
trong mu.
Yu t nh hng:

Cc cht oxi ha mnh : c th loi tr bng cch thm d cht kh

hydroxyamin.

Xyanua, nitrit, photphat (poly photphat nh hng nhiu hn octo-

photphat): loi tr bng cch un si vi acid.

Cc ion kim loi crom, km ( khi nng ca chng gp 10ln nng

st); coban, ng( khi nng chng gp 5ln nng st); niken (khi nng
ca n gp 2 ln st); bimut, cadimi, thy ngn molypdat to kt ta vi
phenantrolin. Loi tr bng
cchthm d phenantrolin,trong vn khng loi tr c nh hng ca cc ion
kim loi
th phi s dng phng php chit tch cc ion kim loi cn tr.
Lu phng php xc nh st:
 Ly 50ml mu vo
erlen

Thm 2ml ddHCl, 1ml dd hydroxyamin

un si n khi th tch cn 15-20ml

a mu v nhit phng

Thm 10ml m Amonium acetat v 4ml

phenanthroline

nh mc 50ml, i 10p

o quang ph
bc sng 510nm

2. Gii thch ti sao khi lp ng chun st khng cho ha cht HCl v NH-
2OH.HCl nhng khi phn tch mu st li cho vo.

Dung dch HCl m c v NH2OH.HCl cho vo nhm mc ch chuyn

cc hp cht v dng st (II). Khi lm ng chun dung dch chun st
dng st (II) nn khng cho thm hai dung dch vo. Cc phn ng xy
ra:

Fe(OH)3 + 3H+ Fe3+ + H2O

4Fe3++2NH2OH 4Fe2++ N2O+ H2O+4H+