Opsti podaci o barutnoj masi

Preduzece NN
1 Tip I serija baruta Nm
Tehnicki uslovi C

Rastvarac aceton
2 Procenat otpadaka do 20% zelen I do 2% crn
Oblik zrna kvadrican

Dimenzije barutnog zrna

Precnik D u mm
Precnik rupice d u mm
Duzina zrna L u mm
Wo
Dimenzije zidova zrna u mm Wi
3 Wa
Sirina plocice a u mm 100.3
Visina plocice b u mm 0.9-0.03
L/D
Razmera dimenzija D/d
Wa/d
Ujednacenost

Napomena o dimenzijama zrna

4 nepravilna zrna 0.42%
proba sejanja 0.002%
 Analiza fizicko-hemijskih ispitivanja

Analiza:

R.BR. Vrsta ispitivanja Jedinica Dozvoljeno po TU Rezultat

1 Temperatura zapaljivosti C min 168
2 Kolicina toplote J/kg oko 5110
3 Grejanje na 100C dana min 3
4 Bergman-Junk na 132/120C mlNO/59 max 12
5 Proba po Hansenu na 110C pH min 3.3
6 Metivalentan proba na 134.5/120C min min 40
7 Specificna tezina g/cm min 1.54
8 Gravimetrijska gustina kg/L oko 0.74
9 Stisljivost %
10 Modul elasticnosti
11 Lomljivost %
12 Eksudacija

R.BR. Komponente u barutnoj masi Jedinica Dozvoljeno po TU Rezultat

1 Azot nitroceluloze % 12.65-12.85 12.74
OVDE UNETI DATE PODATKE

2 Nitroceluloza %
3 Nitroglicerin % 39-42 40.25
4 Dibutilftalat %
5 Dinitrotoulol %
6 Difenilamin % 0.30-0.70 0.5
7 Vlaga % 0.25-0.75 0.33
8 Isparljive materije % max 0.50 0.32
9 Aceton %
10 Etarski ekstrat % max 44 42.19
11 Centralit % 0.80-1.30 1.03
12 Pepeo % max 0.40 0.028
13 Grafit % max 0.20 0.13
14 Kalijum-sulfat %
15 Vazelin % max 0.50 0.28
 Radni sastav barutne mase za termohemijski

R.BR. Komponenta Hemijska formula Sadrzaj Jedinica

1 Nitroglicerin CHNO 0.4025 %
2 Difenilamin CHN 0.005 %
3 Centralit CHNO 0.0103 %
4 Voda (u pari) HO 0.0033 %
5 Aceton (isparljiva materija) CHO 0.0032 %
6 Grafit C 0.0013 %
7 Vazelin CH 0.0028 %
SUMA 0.4284 %
USLOV (N=12.74%)+=1 %
N=12.74% 0.5716 %
8 Nitroceluloza
CHO
Atomske mase
C 12.0107 g
H 1.00794 g
N 14.0067 g
O 15.9994 g

INTERPOLACIJA

Nitroceluloza 12.74 %N
(%N)1 12.6 (C)1 2203 (B ili H)1
(%N) 12.74 (C) 2186.2 (B ili H)
(%N)2 12.8 (C)2 2179 (B ili H)2

Proracun ukupnog broja molova po gramu barutne mase ato

R.BR. Komponenta pi [%] {C} pi*{C} {N}

1 Nitroceluloza 12.74% 0.5716 0.021862 0.012496 0.00910
2 Nitroglicerin 0.4025 0.013211 0.005317 0.013211
3 Difenilamin 0.005 0.070913 0.000355 0.005909
4 Centralit 0.0103 0.063349 0.000652 0.007453
5 Aceton 0.0032 0.051654 0.000165 0
6 Vazelin 0.0028 0.070785 0.000198 0
7 Voda u pari 0.0033 0 0 0
8 Grafit 0.0013 0.083259 0.000108 0

SUMA 1 0.019292
n 0.037952
mase za termohemijski proracun

nC nN nH nO Mol masa OP
3 3 5 9 227.09 g 227.1007
12 1 11 0 169.22 g 169.1094
17 2 20 1 268.35 g 268.3504
0 0 2 1 18.02 g -
3 0 6 1 58.08 g 58.08325
1 0 0 0 12.01 g 12.00048
20 0 42 0 282.55 g 282.5258
1035.3 g

1097.896

INTERPOLACIJA

2772 (N)1 899 (O)1 3635

2734.2 (N) 909.5 (O) 3640.6
2718 (N)2 914 (O)2 3643

mu barutne mase atomski sastav

pi*{N} {H} pi*{H} {O} pi*{O}

0.005199 0.027342 0.015629 0.036406 0.02081
0.005317 0.022018 0.008862 0.039632 0.015952
2.95E-05 0.065003 0.000325 0 0
7.68E-05 0.074529 0.000768 0.003726 3.84E-05
0 0.103307 0.000331 0.017218 5.51E-05
0 0.148648 0.000416 0 0
0 0.111017 0.000366 0.055508 0.000183
0 0 0 0 0

0.010622 0.026697 0.037038

 Proracun glavnih produkata sagorevanja

ULAZNI PODACI R.BR. Simbol

n (broj molova) 0.03795 1 Tm
Wnitroglicerin 4.54545 2 n
Wnitroceluloza 4.0 3 W
{C} 0.019292462 4 n/W
{O} 0.037038398 5 (n/W)
{H} 0.0266967614 6 -B
{N} 0.0106223704 7 -0.5*B
Interpolacija za -B, -0.5*B i K [Tm] 8 -n/W*B
T [K] -B -0.5*B K [Tm] 9 -(n/W)*0.5*B
I 3700 31.1 210 8.54 10 A=-n/W*B-(n/W)*0.5*B
3796 31.1 205.2 8.626 11 A log e
3800 31.1 205 8.63 12 K [Tm]
13 log K [Tm]
Interpolacija za -B, -0.5*B i K [Tm] 14 log a
T [K] -B -0.5*B K [Tm] 15 a
II 16 2-a
0 0 0 0.000 17 a-1
18 (N)=b
19 f
Interpolacija za -B, -0.5*B i K [Tm] 20 d
T [K] -B -0.5*B K [Tm] 21 e
III 22 e+d
0 0 0 0.000 23 (e+d)*(2-a)
24 f*(a-1)
25 R
26 e-f
27 e+d
28 2*e+d-f
29 d*(2*e+d-f)
30 4*(1-a)
31 S
32 R
33 D
34 D
35 R
36 R-D
37 2*(1-a)
 38 (H)
39 d
40 (HO)
41 -(e-f)
42 (CO)
43 2*e
44 f
45 2e-f
46 (HO)
47 (CO)

IZLAZ IZ PRORACUNA

I
(CO) mol/g (42) 0.00641
(CO) mol/g (47) 0.01289
(HO) mol/g (46) 0.01134
(H) mol/g (38) 0.00201
(N) mol/g (18) 0.00531
ata sagorevanja Unutrasnja e

I II
Operacija I II III n - br molova
K 3796 (CO) 0.0064 Err:502
Iz prorac 0.03795 0.03795 0.03795 (CO) 0.0129 Err:502
1
4.55 4.55 4.55 (HO) 0.0113 Err:502
(2) : (3) 0.00835 0.00835 0.00835 (H) 0.0020 Err:502
(4)*(4) 0.00006971 0.0000697 0.0000697 (N) 0.0053 0.0053
tablice 31.1 0 0 Cv
tablice 205.2 0 0 (CO) 11.97843 #DIV/0!
(4)*(6) 0.25967 0.00000 0.00000 (CO) 6.445295 #DIV/0!
2
(5)*(7) 0.01431 0.00000 0.00000 (HO) 9.618716 #DIV/0!
(8)+(9) 0.27397 0.00000 0.00000 (H) 6.100869 #DIV/0!
0.4342*(10 0.11898 0.00000 0.00000 (N) 6.384389 #DIV/0!
tablice 8.62640 0.000 0.000 ()*Cv
log(12) 0.93583 Err:502 Err:502 (CO) 0.07675 #DIV/0!
(11)+(13) 1.05481 Err:502 Err:502 (CO) 0.083048 #DIV/0!
10 11.3453 Err:502 Err:502 3 (HO) 0.109063 #DIV/0!
2-(15) -9.34526 Err:502 Err:502 (H) 0.012262 #DIV/0!
(15)-1 10.3453 Err:502 Err:502 (N) 0.033909 #DIV/0!
0.5*{N} 0.00531 0.00531 0.00531 SUMA 0.315031 #DIV/0!
{O} 0.03704 0.03704 0.03704 E1
0.5*{H} 0.01335 0.01335 0.01335 (CO) -29100 #DIV/0!
{C} 0.01929 0.01929 0.01929 (CO) 17480 #DIV/0!
4
(20)+(21) 0.03264 0.03264 0.03264 (HO) -51040 #DIV/0!
(16)*(22) -0.30504 Err:502 Err:502 (H) 17480 #DIV/0!
(17)*(19) 0.38317 Err:502 Err:502 (N) 18440.05 #DIV/0!
(23)+(24) 0.07813 Err:502 Err:502 ()*E1
(21)-(19) -0.01775 -0.01775 -0.01775 (CO) -186.454 #DIV/0!
(22) 0.03264 0.03264 0.03264 (CO) 225.2317 #DIV/0!
(26)+(27) 0.01489 0.01489 0.01489 5 (HO) -578.722 #DIV/0!
(20)*(28) 0.00020 0.00020 0.00020 (H) 35.13134 #DIV/0!
-4*(17) -41.381 Err:502 Err:502 (N) 97.93852 #DIV/0!
(29)*(30) -0.00823 Err:502 Err:502 SUMA -406.874 #DIV/0!
(25)*(25) 0.00611 Err:502 Err:502 E2
(32)-(31) 0.01433 Err:502 Err:502 (CO) 2.2E+06 2.2E+06
(33) 0.11972 Err:502 Err:502 (CO) 3.4E+05 3.4E+05
6
(25) 0.07813 Err:502 Err:502 (HO) 3.5E+05 3.5E+05
(35)-(34) -0.04158 Err:502 Err:502 (H) 3.0E+04 3.0E+04
(30):2 -20.691 Err:502 Err:502 (N) 3.4E+05 3.4E+05
 (36):(37) 0.00201 Err:502 Err:502 ()*E2
(20) 0.01335 0.01335 0.01335 (CO) 1.4E+04 Err:502
(39)-(38) 0.01134 Err:502 Err:502 (CO) 4380.899 Err:502
-1*(26) 0.01775 0.01775 0.01775 7 (HO) 3968.557 Err:502
(41)-(40) 0.00641 Err:502 Err:502 (H) 60.29212 Err:502
2 *(21) 0.03858 0.03858 0.03858 (N) 1805.788 1.8E+03
(19) 0.03704 0.03704 0.03704 SUMA 24311.78 Err:502
(43)-(44) 0.00155 0.00155 0.00155
(40) 0.01134 Err:502 Err:502
(45)+(46) 0.01289 Err:502 Err:502

Z PRORACUNA

II III
Err:502 Err:502
Err:502 Err:502
Err:502 Err:502
Err:502 Err:502
0.00531 0.00531
 Unutrasnja energija gasova Toplota formir

III ENERGIJA Produkti sagorevanja

molova I II III
Err:502 Tm 3796 0 0
Err:502 n/W 0.00835 0.00835 0.00835
Err:502 (n/W) 7.0E-05 7.0E-05 7.0E-05
1
Err:502 E 1099.65 #DIV/0! #DIV/0!
0.0053
Cv INTERPOLACIJA (CO)
#DIV/0! T Cv E1 E2
#DIV/0! 3700 49.99 -131884
#DIV/0! I 3796 50.151 -121836
#DIV/0! 3800 50.158 -121417 2
#DIV/0! (CO) 0
*Cv II 0 #DIV/0! #DIV/0! 9.2E+06
#DIV/0! 0
#DIV/0! 0
#DIV/0! III 0 #DIV/0! #DIV/0!
#DIV/0! 0
#DIV/0! 3
#DIV/0! INTERPOLACIJA (CO)
E1 T Cv E1 E2
#DIV/0! 3700 26.917 71176
#DIV/0! I 3796 26.985 73185.28
#DIV/0! 3800 26.988 73269
Toplota form
#DIV/0! (CO) 0
#DIV/0! II 0 #DIV/0! #DIV/0! 1.4E+06
*E1 0 R.BR.
#DIV/0! 0 1
#DIV/0! III 0 #DIV/0! #DIV/0! 2
#DIV/0! 0 3
#DIV/0! 4
#DIV/0! INTERPOLACIJA (HO) 5
#DIV/0! T Cv E1 E2 6
E2 3700 40.047 -217714 7
2.2E+06 I 3796 40.272 -213694 8
3.4E+05 3800 40.281 -213527
3.5E+05 (HO) 0
3.0E+04 II 0 #DIV/0! #DIV/0! 1.5E+06 Interpolacija
3.4E+05 0 %N
 (HO)
1.5E+06

*E2 0 12.6
Err:502 III 0 #DIV/0! #DIV/0! 12.74
Err:502 0 12.8
Err:502
Err:502 INTERPOLACIJA (H)
1805.788 T Cv E1 E2
Err:502 3700 25.426 71176
I 3796 25.543 73185.28
3800 25.548 73269
(H) 0
II 0 #DIV/0! #DIV/0! 1.3E+05
0
0
III 0 #DIV/0! #DIV/0!
0

INTERPOLACIJA (N)
T Cv E1 E2
3700 26.662 71176
I 3796 26.730 77204.8
3800 26.733 77456
(N) 0
II 0 #DIV/0! #DIV/0! 1.4E+06
0
0
III 0 #DIV/0! #DIV/0!
0
Toplota formiranja gasa

Produkti sagorevanja
(I) (II) (III)
n - br molova
(CO) 0.0064 Err:502 Err:502
(CO) 0.0129 Err:502 Err:502
(HO) 0.0113 Err:502 Err:502
(H) 0.0020 Err:502 Err:502
(N) 0.0053 0.0053 0.0053
Qfg
(CO) 94030.05 94030.05 94030.05
(HO) 57500 70088.37 70088.37
(CO) 26694.37 26694.37 26694.37
(H) 0 0 0
(N) 0 0 0
SUMA 178224.4 190812.8 190812.8
() x Qfg
(CO) 602.4841 Err:502 Err:502
(HO) 651.9683 Err:502 Err:502
(CO) 343.9598 Err:502 Err:502
(H) 0 - 0
(N) 0 0 0
SUMA 1598.412 Err:502 Err:502

Toplota formiranja barutne mase

Komponenta pi% Qf () x Qf
Nitroceluloza 12.74% 0.5716 602.23 344.23
Nitroglicerin 0.4025 348.95 140.45
Difenilamin 0.005 -209.95 -1.05
Centralit 0.0103 49.92 0.51
Aceton 0.0032 991.93 3.17
Vazelin 0.0028 412.96 1.16
Voda u pari 0.0033 3208.31 10.59
Grafit 0.0013 0 0.00
SUMA 1 499.07

Interpolacija 2089.501
Qf
 2562
2521.4
2504
 Toplota reakcije Korekcija temperature

(I) 1099.34 Simbol (I)

Qr = Qfg - Qf (II) Err:502 Tm [K] 3796
(III) Err:502 Cv 0.315
E 0.303
0.9
Kriterijum ravnoteze |Tm|=|E|/Cv 0.866
Tm' = Tm |Tm| 3796.9
(I) 0.303 Tm' = Tm |Tm| 3795.1
E = E -Qr (II) #DIV/0!
(III) #DIV/0!

USLOV 1 E 0.478 [cal/g] DOBRO JE

E < 0 potrebna je veca Tm
USLOV 2
E > 0 potrebna je manja Tm SMANJI Tm
ja temperature

(II) (III)
0 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
 Proraun produkata disocijacije
R.BR. Simbol Operacija I II
1 Tm K 3796.00 0
2 K1 1.099 #DIV/0!
3 K2 0.595 #DIV/0!
4 K3 0.097 #DIV/0!
TABLICE
5 K4 0.031 #DIV/0!
6 K5 0.383 #DIV/0!
7 K6 0.139 #DIV/0!
8 20(n/W) 20 x [4] 0.16699 0.16699
9 20*(n/W)*log(e) (8) x 0.4342 0.07252 0.07252
10 exp (20*(n/W)) SQRT(9) 0.26930 0.26930
11 exp (-20*(n/W)) 1 / (10) 3.71333 3.71333
12 (H) 1 / [38] 497.56 Err:502
13 (H) (12) x (12) 247567.5 Err:502
14 (H) SQRT[38] 0.04483 Err:502
15 (H) 1/ (14) 22.31 Err:502
16 (HO) [40] 0.0113386 Err:502
17 (HO) (16)x(16) 0.0001286 Err:502
18 (N) SQRT[16] 0.0113386 Err:502
19 R*Tm Rx(1) 296599.34 Err:502
20 W/R*Tm W/(19) 0.0000153 Err:502
21 (W/RTm) SQRT(20) 0.0039147 Err:502
22 (H) (14)x(21)x(2) 0.0001929 Err:502
23 (OH) (16)X(15)X(21)X(3)X(11) 0.0021871 Err:502
24 (NO) (16)X(18)X(12)X(21)X(4)X(11) 0.0000904 Err:502
25 (N) (18)X(21)X(5) 0.0000014 Err:502
26 (O) (16)X(12)X(20)X(6) 0.0000331 Err:502
27 (O) (17)X(13)X(20)X(7) 0.0000679 Err:502
28 (H)+(OH)+(NO)+(N)+(O)+(O) (22)X(23)X(24)X(25)X(26)X(27) 0.0025728 Err:502
 III Interpolacija (I)
0 Tm K1 K2 K3 K4 K5 K6
#DIV/0! 3700 0.9079 0.4693 0.0734 0.0225 0.2516 0.0917
#DIV/0! 3796 1.099 0.595 0.097 0.031 0.383 0.139
#DIV/0! 3800 1.107 0.6001 0.0982 0.0309 0.3886 0.1412
#DIV/0!
#DIV/0! Interpolacija (II)
#DIV/0! Tm K1 K2 K3 K4 K5 K6
0.16699 0
0.07252 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
0.26930 0
3.71333
Err:502 Interpolacija (III)
Err:502 Tm K1 K2 K3 K4 K5 K6
Err:502 0
Err:502 0 #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Err:502 0
Err:502
Err:502
Proraun veliina za korekciju atomskog sastava
Err:502
Err:502
Err:502 (I) (II) (III)
Err:502 1 {H}k = (H) + (OH) 0.00238 Err:502 Err:502
Err:502 2 {O}k = (OH) + (NO) + (O) + 2*(O) 0.00245 Err:502 Err:502
Err:502 3 {N}k = (N) + (NO) 0.00009 Err:502 Err:502
Err:502
Err:502
Err:502
Korigovan atomski sastav
Err:502
(I) (II) (III)
1 {C} = {C} 0.0193 0.019292 0.019292
2 {H} = {H} - {H}k 0.0243 Err:502 Err:502
3 {N} = {N} - {N}k 0.0105 Err:502 Err:502
4 {O} = {O} - {O}k 0.0346 Err:502 Err:502

Ukupan broj molova s obzirom na produkte disocijacije

(I) (II) (III)

broj molova n 0.0393 Err:502 Err:502 mol/g
 Proracun glavnih produkata sagorevanja za vreme disocijacije

R.BR. Simbol Operacija I II III R.BR.

1 Tm K 3796.00 0 0
2 n Iz prorac 0.03929 Err:502 Err:502
3 W 4.55 4.55 4.55
4 n/W (2) : (3) 0.00864 Err:502 Err:502
5 (n/W) (4)*(4) 7.47E-05 Err:502 Err:502
6 -B tablice 31.1 0 0
1
7 -0.5*B tablice 205.2 0 0
8 -n/W*B (4)*(6) 0.26881 Err:502 Err:502
9 -(n/W)*0.5*B (5)*(7) 0.01533 Err:502 Err:502
10 A=-n/W*B-(n/W)*0.5*B (8)+(9) 0.28415 Err:502 Err:502
11 A log e 0.4342*(10 0.12340 Err:502 Err:502
12 K [Tm] tablice 8.62640 0.00000 0.00000
13 log K [Tm] log(12) 0.93583 Err:502 Err:502
14 log a (11)+(13) 1.05923 Err:502 Err:502
15 a 10 11.4613 Err:502 Err:502
16 2-a 2-(15) -9.46126 Err:502 Err:502
17 a-1 (15)-1 10.4613 Err:502 Err:502
18 (N)=b 0.5*{N} 0.00527 Err:502 Err:502
2
19 f {O} 0.03459 Err:502 Err:502
20 d 0.5*{H} 0.01216 Err:502 Err:502
21 e {C} 0.01929 0.01929 0.01929
22 e+d (20)+(21) 0.03145 Err:502 Err:502
23 (e+d)*(2-a) (16)*(22) -0.29756 Err:502 Err:502
24 f*(a-1) (17)*(19) 0.36188 Err:502 Err:502
25 R (23)+(24) 0.06431 Err:502 Err:502
26 e-f (21)-(19) -0.01530 Err:502 Err:502
27 e+d (22) 0.03145 Err:502 Err:502
28 2*e+d-f (26)+(27) 0.01615 Err:502 Err:502
29 d*(2*e+d-f) (20)*(28) 0.00020 Err:502 Err:502
30 4*(1-a) -4*(17) -41.845 Err:502 Err:502
31 S (29)*(30) -0.00822 Err:502 Err:502 3
32 R (25)*(25) 0.00414 Err:502 Err:502
33 D (32)-(31) 0.01235 Err:502 Err:502
34 D (33) 0.11114 Err:502 Err:502
35 R (25) 0.06431 Err:502 Err:502
36 R-D (35)-(34) -0.04683 Err:502 Err:502
37 2*(1-a) (30):2 -20.923 Err:502 Err:502
38 (H) (36):(37) 0.00224 Err:502 Err:502
39 d (20) 0.01216 Err:502 Err:502
40 (HO) (39)-(38) 0.00992 Err:502 Err:502
41 -(e-f) -1*(26) 0.01530 Err:502 Err:502
42 (CO) (41)-(40) 0.00538 Err:502 Err:502
43 2*e 2 *(21) 0.03858 0.03858 0.03858
6
44 f (19) 0.03459 Err:502 Err:502
45 2e-f (43)-(44) 0.00399 Err:502 Err:502
46 (HO) (40) 0.00992 Err:502 Err:502
47 (CO) (45)+(46) 0.01391 Err:502 Err:502

(I) (II) (III)

(CO) (42) 0.00538 Err:502 Err:502
(CO) (47) 0.01391 Err:502 Err:502
(HO) (46) 0.00992 Err:502 Err:502
(H) (38) 0.00224 Err:502 Err:502
(N) (18) 0.00527 Err:502 Err:502

9
9
 Unutranja energija gasova

Element (I) (II) (III)

n- broj molova (I) (II) (III)
E
(CO) 0.00538 Err:502 Err:502 4550.55 Err:502 Err:502
(CO) 0.01391 Err:502 Err:502
(HO) 0.00992 Err:502 Err:502
(H) 0.00224 Err:502 Err:502
(H) 0.00019 Err:502 Err:502
(OH) 0.00219 Err:502 Err:502
(NO) 0.00009 Err:502 Err:502 Cv Interpolacija (I)
(N) 0.00009 Err:502 Err:502 Tm (CO) (HO) (CO) (H)
(N) 0.00527 Err:502 Err:502 3700 49.990 40.047 26.917 25.426
(O) 0.00003 Err:502 Err:502 3796.00 50.151 40.272 26.985 25.543
(O) 0.00002 Err:502 Err:502 3800 50.158 40.281 26.988 25.548
Cv
(CO) 50.15 0.00 0.00 Cv Interpolacija (II)
(CO) 26.99 0.00 0.00 Tm (CO) (HO) (CO) (H)
(HO) 40.27 0.00 0.00 0 0.000 0 0 0
(H) 25.54 0.00 0.00 0.00 0.000 0.000 0.000 0.000
(H) 12.47 2.98 2.98 0 0 0 0 0
(OH) 25.95 0.00 0.00
(NO) 27.50 0.00 0.00 Cv Interpolacija (III)
(N) 12.47 2.98 2.98 Tm (CO) (HO) (CO) (H)
(N) 26.73 0.00 0.00 0 0.000 0 0 0
(O) 12.47 2.98 2.98 0.00 0.000 0.000 0.000 0.000
(O) 28.97 0.00 0.00 0 0 0 0 0
() x Cv
(CO) 0.269792 Err:502 Err:502 E Interpolacija (I)
(CO) 0.375442 Err:502 Err:502 Tm (CO) (HO) (H) (N)
(HO) 0.399492 Err:502 Err:502 3700 -131884 -217714 71176 71176
(H) 0.057177 Err:502 Err:502 3796.00 -121836 -213694 73185 77205
(H) 0.002405 Err:502 Err:502 3800 -121417 -213527 73269 77456
(OH) 0.056746 Err:502 Err:502
(NO) 0.002486 Err:502 Err:502 E Interpolacija (II)
(N) 0.001127 Err:502 Err:502 Tm (CO) (HO) (H) I (CO)
(N) 0.140743 Err:502 Err:502 0 0.000 0 0 0
(O) 0.000413 Err:502 Err:502 0.00 0.000 0.000 0.000 0.000
(O) 0.00048 Err:502 Err:502 0 0 0 0 0
SUMA 1.306302 Err:502 Err:502
E E Interpolacija (III)
(CO) -121836 0 0 Tm (CO) (HO) (H) (N) I (CO)
(CO) 0 0 0 0 0.000 0 0 0
(HO) -213694 0 0 0.00 0.000 0.000 0.000 0.000
(H) 73185 0 0 0 0 0 0 0
(H) 0 0 0
(OH) 0 0 0
(NO) 0 0 0
(N) 0 0 0
(N) 0 0 0
(O) 0 0 0
(O) 0 0 0
() x E
(CO) -655.422 Err:502 Err:502
(CO) 0 Err:502 Err:502
(HO) -2119.84 Err:502 Err:502
(H) 163.8216 Err:502 Err:502
(H) 0 Err:502 Err:502
(OH) 0 Err:502 Err:502
(NO) 0 Err:502 Err:502
(N) 0 Err:502 Err:502
(N) 0 Err:502 Err:502
(O) 0 Err:502 Err:502
(O) 0 Err:502 Err:502
SUMA -2611.44 Err:502 Err:502
E
(CO) 9211000 2200010 2200010
(CO) 1423500 339997.1 339997.1
(HO) 1465400 350004.8 350004.8
(H) 125600 29999.04 29999.04
(H) 0 0 0
(OH) 0 0 0
(NO) 0 0 0
(N) 0 0 0
(N) 0 81206.92 81206.92
(O) 0 0 0
(O) 0 0 0
() x E
(CO) 49551.12 Err:502 Err:502
(CO) 19805.02 Err:502 Err:502
(HO) 14536.67 Err:502 Err:502
(H) 281.1493 Err:502 Err:502
(H) 0 Err:502 Err:502
(OH) 0 Err:502 Err:502
(NO) 0 Err:502 Err:502
(N) 0 Err:502 Err:502
(N) 0 Err:502 Err:502
(O) 0 Err:502 Err:502
(O) 0 Err:502 Err:502
SUMA 84173.96 Err:502 Err:502
 Toplota formiranja gasa
R.BR. Element (I) (II) (III)
n- broj molova
(CO) 0.00538 Err:502 Err:502
(CO) 0.01391 Err:502 Err:502
(HO) 0.00992 Err:502 Err:502
(H) 0.00224 Err:502 Err:502
(H) 0.00019 Err:502 Err:502
1
(OH) 0.00219 Err:502 Err:502
terpolacija (I) (NO) 0.00009 Err:502 Err:502
(N) (OH) (NO) (O) (N) 0.00009 Err:502 Err:502
26.662 25.837 27.44 28.868 (N) 0.00527 Err:502 Err:502
26.730 25.945 27.500 28.973 (O) 0.00003 Err:502 Err:502
26.733 25.95 27.503 28.977 (O) 0.00002 Err:502 Err:502
Qfg
erpolacija (II) (CO) 393685 94030 94030
(N) (OH) (NO) (O) (CO) 111746 26690 26690
0 0 0 0 (HO) 283446 67700 67700
0.000 0.000 0.000 0.000 (H) 240741 57500 57500
0 0 0 0 (H) -215746 -51530 -51530
2
(OH) -41462 -9903 -9903
erpolacija (III) (NO) -90016 -21500 -21500
(N) (OH) (NO) (O) (N) -352319 -84150 -84150
0 0 0 0 (N)
0.000 0.000 0.000 0.000 (O) -246393 -58850 -58850
0 0 0 0 (O) 0 1 2
() x Qfg
(CO) 2117.852 Err:502 Err:502
(CO) 1554.711 Err:502 Err:502
(HO) 2811.766 Err:502 Err:502
(H) 538.8867 Err:502 Err:502
(H) -41.6136 Err:502 Err:502
3 (OH) -90.6819 Err:502 Err:502
(NO) -8.13679 Err:502 Err:502
(N) -31.8471 Err:502 Err:502
(N) 0 Err:502 Err:502
(O) -8.16161 Err:502 Err:502
(O) 0 Err:502 Err:502
SUMA 6842.775 Err:502 Err:502
 Toplota reakcije Korekcija temperature

(I) 4753.27 Simbol (I)

Qr = Qfg - Qf (II) Err:502 Tm [K] 3796
(III) Err:502 Cv 1.306
E -202.726
0.9
Kriterijum ravnoteze |Tm|=|E|/Cv 139.671
Tm' = Tm + |Tm| 3935.7
(I) -202.7 Tm' = Tm +- |Tm| 3656.3
E = E -Qr (II) Err:502
(III) Err:502

USLOV 1 E 0.478 [cal/g] DOBRO JE

E < 0 potrebna je veca Tm
USLOV 2
E > 0 potrebna je manja Tm POVECAJ Tm
ja temperature

(II) (III)
0 0
Err:502 Err:502
Err:502 Err:502
Err:502 Err:502
Err:502 Err:502
Err:502 Err:502
Err:502 Err:502
 Virijelni koeficijenti B i C Specificne topl
B C
Produkti () x B () x C Produkti
sagorevanja cm/mol cm/mol sagorevanja
(CO) #DIV/0! #DIV/0! #DIV/0! #DIV/0! (CO)
(CO) #DIV/0! #DIV/0! #DIV/0! #DIV/0! (CO)
(HO) #DIV/0! #DIV/0! #DIV/0! #DIV/0! (HO)
(H) #DIV/0! #DIV/0! #DIV/0! #DIV/0! (H)
(N) #DIV/0! #DIV/0! #DIV/0! #DIV/0! (N)
(H)
Interpolacija B (OH)
Tm (CO) (CO) (HO) (H) (N) (ON)
(N)
#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! (O)
(O)

Interpolacija C
Tm (CO) (CO) (HO) (H) (N)

#DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

 Sila baruta
Specificne toplote f n*R*Tm
Specificna (normalna) zapremina gasova
Cv Cp W1 n*Wm
() x Cv () x Cp
J/mol J/mol Wm= 22410 cm/mol
0 0 Maksimalni pritisak na gustini = 0.22 g/cm^3
0 0 Pm = *f*(1+B*+n*C*)
0 0 Specificna toplota na p=const
0 0 Cp =
0 0 Specificna toplota na w=const
0 0 Cv =
0 0 Odnos specificnih toplota
0 0 = Cp/Cv
0 0 Kovolumen gasova
0 0 = 1
0 0 = b
= W1 (1- 1/(1+B/W1+n*C/W1^2))
= 1.18+6.9*{C}-11.5*{O}
= W1/1000
 Proracunske vrednosti toplotnih I balistickih karakteristika

R.BR. Karakteristika Znak Vrednost

1 Gustina produkta (g/cm^3)
2 Temperatura sagorevanja (K) Tm
3 Unutrasnja energija gasova (J/g) E
4 Toplota formiranja mase (J/g) Qf
5 Toplota formiranja gasova (J/g) Qfg
6 Toplota reakcije (J/g) Qr
7 Ukupan broj molova (mol/g) n
8 Ukupni azot % N
9 Atomski sastav (g at/g) {C}
{N}
{H}
{O}
10 Produkti sagorevanja (mol/g) (CO)
(CO)
(HO)
(H)
(N)
(H)
(OH)
(NO)
(N)
(O)
(O)
11 Reakcija vodenog gasa (nulta gustina) K0
12 Korigovana K0 d
13 Virijelni koeficijenti cm^3/mol B
C
14 Maksimalni pritisak gasova g/cm^3 Pm
15 Specificna toplota na p=const J/mol Cp
16 Specificna toplota na v=const J/mol Cv
17 Odnost specificnih toplota
18 Kovolumen barutnih gasova
19 Sila baruta f
20 Specificna zapremina gasova W1