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Soal Soal Termo
Soal Soal Termo
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SHEET (6-2)
Thermochemistry
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Question No. (1)
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ΔH°(298k)= - 210100 cal/mole of Al2O3
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Question No. (2)
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Sequence of solving equations
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Question No. (3)
SEQUANCE OF SOLVING
(A) – (B)
LiCl(s)LiCl(l)ΔH°f= 4758 kcal
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Question No. (4)
2Al + 3Cl2Al2Cl6
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Question No. (5)
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Question No. (6)
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ΔH°f(CO2) at 298K = - 94.05 kcal/mole
The atomic weights of Ca and C are 40 and 12,
respectively.
a. CaC2+O2CaO+2CO
ΔH°f at
298K=ΔH°f(CaO)+2ΔH°f(CO)-ΔH°f(CaC2)=-151.8+
2×-26.42+14.1
=-190.54 kcal/mole
ΔH°f at 298K=-190.54×64
=-12194.6kcal/1000kg
ΔH°f(steel) at 298K=333kcal/kg
N=12194.6÷333=36.4 kg of steel
b. CaC2+1.5O2CaO+2CO2
ΔH°f at 298K=ΔH°f(CaO)+2ΔH°f(CO2)
-ΔH°f(CaC2) =-151.8-2×94.05-14.1
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=-325.8kcal/mole
ΔH°f at 298K=-325.8×64
=-20851.2kcal/1000kg
N=20851.2÷333=62.6 kg of steel
c. CaC2+1.4O2CaO+0.8CO2+1.2CO
ΔH°f at 298K=ΔH°f(CaO)+1.2ΔH°f(CO)
+0.8ΔH°f(CO2) -ΔH°f
(CaC2)=-151.8+1.2×-26.42+0.8×-94.5+14.1
=-244.644kcal/mole
ΔH°f at 298K=-244.644×64
=-15657.16kcal/1000kg
N=15657.16÷333=47 kg of steel
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Question No. (7)
at T=273+227=500 K
Pb + 0.5O2 PbO
𝟓𝟎𝟎
ΔH°f=ΔH°f at 298K+∫𝟐𝟗𝟖 𝐂𝐩(𝐑) dT
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Question No. (8)
H2O(l)H2O(v)
𝟑𝟕𝟑
ΔH°T=ΔH°1+∫𝟐𝟕𝟑 𝐂𝐩(𝐑) H2OdT+ΔH°2
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𝟑𝟕𝟑
=1400+∫𝟐𝟕𝟑 𝟏𝟖dT+9700
=1400+18(373-273)+9700
a. ΔH°T =12900cal/mole
ΔU=q+w
ΔH=ΔU+pv
V1 =R T1÷P1 =0.082×273=22.4 lit
V2 =R T2÷P2 =0.082×373=30.6 lit
W=P(V2-V1)=1(30.6-22.4)=8.2 lit .atm
W=8.2×101.325×(1÷4.18)=198.78 cal
b. Wsys=198.78 cal
ΔH=ΔU+Δpv
ΔU=ΔH-Δpv
ΔU=12900-198.8=12701 cal
c. ΔU=12701 cal
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Question No. (9)
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Cp = 1x10-3 Tcal/(deg-mole)
∴ΔH°(1000k)=1556 cal
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Question No.(10)
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Question No. (11)
T=777+273 = 1050 k
ΔH(298k)= ΔH(ZrCl4) + ΔH(CO2) - ΔH(ZrO2)
= - 234.7 +(- 94.05 ) –(- 259.5 )
ΔH(298k)= -69.25 kcal/mole
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1050
ΔH(1050k)=ΔH(298k)+∫298 CpdT
Cp= Cp (CO2)+Cp (ZrCl4) - Cp (C)-2Cp (Cl2) -Cp
(ZrO2)
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