ORDEN EC. DE VELOCIDAD EC.

INTEGRADA t½

0 1 𝑑[𝐴] [𝐴] = [𝐴]0 − 𝑘𝐴 . 𝑡 [𝐴]0

𝑟=− =𝑘 𝑡1/2 =
𝑎 𝑑𝑡 2. 𝑘𝐴

1 1 𝑑[𝐴] [𝐴] = [𝐴]0 . 𝑒 −𝑘𝐴.𝑡 ln 2

𝑟=− = 𝑘[𝐴] 𝑡1/2 =
𝑎 𝑑𝑡 𝑘𝐴
ln[𝐴] = ln[𝐴]0 − 𝑘𝐴 . 𝑡

2 1 𝑑[𝐴] [𝐴]0 1
𝑟=− = 𝑘[𝐴]2 [𝐴] = 𝑡1/2 =
𝑎 𝑑𝑡 1 + 𝑘𝐴 . 𝑡. [𝐴]0 [𝐴]0 . 𝑘𝐴

1 1
= 𝑘𝐴 . 𝑡 +
[𝐴] [𝐴]0

2 1 𝑑[𝐴] 1 [𝐵]⁄[𝐵]0
𝑟=− = 𝑘[𝐴][𝐵] . ln = 𝑘. 𝑡
𝑎 𝑑𝑡 𝑎. [𝐵]0 − 𝑏. [𝐴]0 [𝐴]⁄[𝐴]0

3 1 𝑑[𝐴] [𝐴]0 3
𝑟=− = 𝑘[𝐴]3 [𝐴] = 𝑡1/2 =
𝑎 𝑑𝑡 1
2. [𝐴]20 . 𝑘𝐴
(1 + 2. 𝑘𝐴 . 𝑡. [𝐴]20 )2

1 1
= 2. 𝑘𝐴 . 𝑡 +
[𝐴]2 [𝐴]20

1 1
n = (𝑛 − 1)𝑘𝐴 𝑡 + 𝑡1/2
[𝐴]𝑛−1 [𝐴]𝑛−1
0
2𝑛−1
=
(𝑛 − 1)[𝐴]𝑛−1
0 𝑘𝐴

Ec. −𝐸𝑎
Arrhenius 𝑘(𝑇) = 𝐴. 𝑒 𝑅.𝑇

𝑘1 −𝐸𝑎 1 1
𝑙𝑛 = .[ − ]
𝑘2 𝑅 𝑇1 𝑇2