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Answer Keys:
1 100 2 B 3 C 4 D 5 C 6 71 7 C
8 B 9 D 10 C

1 1 2 C 3 C 4 B 5 D 6 51.41 7 B
8 A 9 28371 10 B 11 71.5 12 D 13 0.91 14 D
15 A 16 7.5 17 A 18 84.8 19 B 20 233 21 B
22 B 23 0.93 24 43.8 25 B 26 0.245 27 30.6 28 B
29 20.13 30 1.81 31 D 32 A 33 C 34 D 35 D
36 0.1 37 A 38 50 39 D 40 2.4 41 5517 42 A
43 C 44 A 45 845 46 2.25 47 26 48 B 49 A
50 C 51 43050 52 B 53 C 54 0.16 55 0.11
Explanations:-
General Aptitude

1. 59 × 59 = 3481
60 × 60 = 3600
Required number = 3600 − 3500 = 100

2. 2 = 27 log 2
log 27

= 27 × 0.3010 = 8.127
Number of digits = 8 + 1 = 9

6. Number of ways of selecting 5 different letters = 5c5 = 1


Number of ways of selecting 2 similar & 3 different letters = 4c1 × 4c3 = 16
Number of ways of selecting 2 similar letters + 2 more similar letters and
1 different letter = 4c2 × 34 = 18
Number of ways of selecting 3 similar letters and another 2 other similar letters
= 3c1 × 3c1 = 9
Number of ways of selecting 4 similar letters and 1 different letter = 2c1 × 4c1 = 8
Number of ways of selecting 5 similar letters = 1c1 = 1
Total number of ways = 1 + 16+18+18+9+8+1 = 71

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7. While buying
He buys 1100 grams instead of 1000 gms.
Suppose he bought 1100 grams for Rs. 1000
While selling
He sell only 900 grams when he takes the money for 1 kg.
Now as per question he sells at a 8% profit. (20% markup & 10 % discount)
Hence his selling price is Rs.1080 for 900 grams, to calculate profit percentage we will
equate the money.
1100 grams for Rs. 1000 (Buying)
1188 grams for Rs. 1080
900 grams for Rs. 1080 (selling)
288
Hence profit % = = 32%
900

8. Rakesh’s birthday has to fall between the 12th & the 28th of July. Anil remembers it to be
after the 20th, while Rahul remember it to be before the 22nd . Hence to satisfy both
conditions, simultaneously, Rakesh birthday must be on the 21st of July.

Chemical Engineering

1. Add the 1st column to the 2nd column, then


 2 1 1
 5 3 2 

 −15 −9 −5
Now subtract the 3rd row from the 1st row, then
 17 10 6 
 5 3 2 

 −15 −9 −5
∴ Determinant of resultant matrix = 17 [ −15 + 18] − 10 [ −25 + 30] + 6 [ −45 + 45]
= 51 − 50 = 1

2. We have identify
curl ( A × B ) = ∇ × ( A × B )
= ( ∇.B ) A − ( A.∇ ) B + (B.∇)A − (∇.A)B

3. Given that f (z) = u + iv is an analytical function and also given that v = 3x 2 y − y3


∂u ∂u
We know that du = dx + dy
∂x ∂y
∂v ∂v
⇒ du = dx − dy , Since from C-R equations
∂y ∂x
du = (3x 2 − 3y 2 )dx − 6xy dy

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Integrating on both sides of above D.E


⇒ u = x 3 − 3xy 2 + k

4. We have L [ f (t)δ(t − a)] = e − as .f (a)


⇒ L  t 2 δ(t − 2)  = e −2s .4

π
∞ x tan θ
5. (i) ∫ dx = ∫ 2
dθ ( putting x = tan θ )
0 (1 + x)(1 + x )
2 0 1 + tan θ

π
sin θ π
= ∫2 dθ =
0 cos θ + sin θ 4
2
2 1  (x − 1)0.9  1
(ii) ∫ 1 (x − 1) 0.1
dx = 
 0.9 1 0.9
 =

π
2
π
(iii) ∫0  x − 2  cos xdx is a proper integral, it will converge.
π π
cos 2x cosx + sin x
(iv) ∫ 0
4
(cosx − sinx) 2
dx = ∫ 4
0 cos x − sin x
dx

= − [ log(cos x − sin x) ]0
π /4

= − ( −∞ − 0 ) = ∞
∴ (i), (ii), (iii) are convergent and (iv) is not convergent

6. Given V = 0.14m3 m = 4kg, T = 303 k


P = 1.4 bar R = ? µ = ?
PV = mRT
PV 1.4 × 102 × 0.14
R= = = 0.01617 kJ kg o k
mT 4 × 303
Molecular weight
RU 8314
µ= = = 514.16
R 0.01617 × 103
∴ Molecular weight ofgas µ = 514.16 kg

8. The heating of calcium carbonate can be represented as:


CaCO3 ( s ) 

→ CaO ( s ) + CO 2 ( g )
1mole 1mole 1mole

200
= 2 moles of CaCO3 produces 2 moles of CO 2
100
∴ Number of Oxygen atoms present = 2 × 2 × N ( Avagadro Number )
= 4 × 6.023 × 1023 = 2.4 × 1024

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F = P (1 + i )
h
9.
F
P=
(1 + i )
h

5000
=
(1 + 0.12 )
5

= 28371.00

10. R (s) + +
10
C( s)
s ( s + 1)
− −

10
s ( s + 1) 10
Inner loop = =
× s s ( s + 1) + 10s
10
1+
s ( s + 1)
10
C (s) s ( s + 1) + 10s 10
= =
R (s) 1 + 10 s ( s + 1) + 10s + 1
s ( s + 1) + 10s
C (s) 10
=
R (s) s + 11s + 10
2

11. N1 = 80 rpm
H1 = 25m
H 2 = 20m
N1 N2
=
H1 H2
H2
N 2 = N1
H1
20
= 80 × = 71.5 rpm
25

12. Given that


rB = 1
rC = 2C A
rD = C A2

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dCc dt r
∅(C A) = = C
−dC A dt −rA
rC 2C A
=
rB + rC + rD 1 + 2CA + C A2
2C A
=
(1 + CA )
2

13. A + B + Product
xA
V dX A
FA0
= ∫
S
− rA
V dX A
=
Vo CAo 500C A C B
XA
V dX A
Vo C Ao
= ∫ 500C (1 − X )( C
0 A A Bo − C Ao X A )
XA
0.1 dX A
=
0.05 × 0.01
= ∫ 500 × 0.01(1 − X )( 0.01 − 0.01X )
0 A A

1
10 = −1
1 − XA
X A = 0.91

14. All the given statements are true.

CA 0 x A
15. ε=0 r=
kCA 20 (1 − x A )
2

0.5 V
τCA 0 = =2 τ=
(1 − 0.5 )
2
V0

V2 = 6V1
Volume of reactor
E 2 = E1

V2 v1
= t2 = t1
V0 v0
CA 0 x A
6t =
kCA 20 (1 − x A )
2

xA
6 t kCA 0 =
(1 − x A )
2

xA
6x 2 =
(1 − x A )
2

x A = 1.333

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16. −C A + CA 0 = kt
−C A kt
+1 =
CA 0 CA 0
kt
1 − xA = 1 −
CA 0
kt
xA =
CA 0
 k 0.5 1 
∵ = =  x A = 75%
 CA 0 5 10 
1
0.75 = t ⇒ t = 7.5
10

17. VD = 50 + 30 = 80 lit

FD VD 80 2
= = =
FE VE 120 3

18. Q = UA∆Tℓn , where A = πDL


Q
L=
UπD.ATin
∆T1 − ∆T2 50 − 30
∆Tm = = = 42o C
∆T1 50
ℓn ℓn
∆T2 30
Q = mc p ∆T = 0.15 × 2131 × (100 − 60 ) = 12786ω
−1 −1
 1 1   1 1 
U= +  = + 
 h oil hω   38.8 2250 
= 38.1 ω m 2o C
Q 12786
L= =
UπD∆Tm 38.1 × 3.14 × 0.03 × 42
L = 84.8 mt

4FLV 2
20. hF =
2D g
π
V.A = Q = V. D 2
4
4Q
V=
πD 2
8fLQ 2
hF = 2 5
gπ D

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15
 8FLQ 2 
D= 2 
 gh F π 
f = 0.02, L = 1km, Q = 50 lit sec = 0.05 m3 sec
g = 9.81, h F = 6m
1 15
 8 ( 0.02 )(1)( 0.05 ) 2 × 103 
D= 
 9.8 × 6 × π 2

 
D = 0.2332m
D = 233.2 mm

22. Stagnation pressure head = 8m


Static pressure head = 6m
h = 8 − 6 = 2m
C V = 0.96
γ = C V 2gh = 0.96 ( 2 ( 9.81)( 2 ) )
γ = 6.013 m s

23. L = 1000 m D1 = 0.3m


L1 = 200 m D 2 = 0.25m
L 2 = 250 m, D3 = 0.20m
L3 = 250m D 4 = 0.15m
L 4 = 300m,
From equivalent pipe
L L L L L
5
= 15 + 25 + 35 + 45
D D1 D 2 D3 D 4
L
D5 =
 L1 L 2 L3   L 4 
 5 + 5 + 5+ 5
 D1 D 2 D3   D 4 
100
D=
200 250 250
+ +
( 0.2 ) ( 0.25)
5 5
300
( 0.20 ) +
5

( 0.15)
5

D = 0.9393m

24. k = 1.5 ω mk , h = 10 ω m 2 k
At steady state the flux of heat remains constant throughout the slab.
Flux based on (Slab + air film)

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q1 =
∆T
=
( 90 − 30 ) = 138.46ω m 2
L 1 0.5 1
+ +
K h 1.5 10
T
air

90o C 30o C
h

0.5m

Flux based on the two faced of the slab


90 − T
q2 =
0.5 1.5
At steady state q1 = q 2
90 − T
138.46 = ⇒ T = 43.85o C
0.5 1.5

26. +
8.95
1+
s (s + 2)

R (s ) +
8
C (s )
s + 2s + 8as
2

8
C (s) s + ( 2 + 8a ) s
2
8
= = 2
R (s) 1 + 8 s + ( 2 + 8a ) s + 8
s + ( 2 + 8a ) s
2

Characteristic equation is
s 2 + ( 2 + 8a ) s + 8 = 8
Equating with the equation
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s 2 + 2ξωn s + 8
ωn = 2 2
a = 0.245

D AB
27. The equivalent film thickness δ =
k
D AB = 1.24 × 10−9 m 2 sec
D AB
δ= ⇒ DAB = 1.24 × 10−9 m 2 s
k

1.24 × 10−9
k = 4.04 × 10−6 m s ⇒ δ =
4.04 × 10−6
δ = 3.06 × 10−4 m ⇒ δ = 30.6mm

moles B 1
28. Volume ratio = mole ratio =
moles C 2
1 1
XB = = = 0.333
1+ 2 3
2
X C = = 0.667
3
1
D A1m =
XB X
+ C
DAB DAC
D AC = 7 × 10−5 m 2 s DAB = 1.86 × 10−5 m 2 s
1
D Am =
0.333 0.666
−5
+
1.86 × 10 7 × 10−5
D Am = 3.64 × 10−5 m 2 s

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12
29. y1 = = 0.1363
100 − 12
 12 
y2 =   x ( 0.04 ) = 0.0054
 100 − 12 
x 2 = 0,pure water is entering y = 13x
y 13x
In mole ratio terms =
29 18
y
x=
20.9
y1 0.1363
x1 = = = 0.0065
20.9 20.9
L min ( x1 − x 2 ) = G ( y1 − y 2 )
x2 = 0
L min y1 − y 2 0.1363 − 0.0054
= = = 20.13
G x1 0.0065

30. We have to find


Q 2 + Q3
=?
Q1
Q1 Q4
Heat Heat
engine Pump
Q2 Q3
Twiling

η = 0.27
w Q1 − Q 2
η= = = 0.27
Q1 Q1
Q2
1− = 0.27
Q1
Q2
= 0.73
Q1
Q3
COP = 4 = − − − − − (1)
ω
Q 3 = 4ω
Q3 = 4 × 0.27Q1 = 1.08Q1
Q3
= 1.08 − − − − − (2)
Q1
0.73 + 1.08 = 1.81

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1 1 1 1 
31. [ AB] = 1 2 4 µ 
1 4 10 µ 2 

Applying R 2 → R 2 − R 1 ; R 3 → R 3 − R 1
1 1 1 1 
= [ AB] ~  0 1 3 µ − 1 
 0 3 9 µ 2 − 1

Applying R 3 → R 3 − 3R 2 , then
1 1 1 1 
[ AB] ~ 0 1 3 µ − 1 

 0 0 0 µ 2 − 3µ + 2 

∴ ρ ( A ) = 2 and ρ ( AB ) = 3 if µ 2 − 3µ + 2 ≠ 0
∴ ρ ( A ) ≠ ρ ( B ) if µ 2 − 3µ + 2 ≠ 0
The given system has no solution if µ ≠ 1, µ ≠ 2

32. µ = 8, σ = 4
x −µ
We know that Z =
σ
 5−8
P ( x ≤ 5) = P  Z ≤  = P ( Z ≤ −0.75 )
 4 
< 0.5 (from diagram)

0.5

x =5 x =8
Z = −0.75 Z=0

33. Given
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dy  4πx 
= 2cos   − y; y(0) = 1; h = 0.25
dx  3 
i.e., x 0 = 0; y 0 = 1
 4πx 
f (x, y) = 2cos  −y
 3 
By Euler’s method, we have
y1 = y 0 + hf (x 0 , y0 )
  4π(0)  
⇒ y(0.25) = 1 + 0.25  2cos   − 1 = 1 + 0.25[(2)(1) − 1]
  3  
= 1.25 = y1
  4π(0.25)  
⇒ y 2 = y(0.5) = 1.25 + 0.25  2cos   − 1.25
  3  
 π 
= 1.25 + 0.25  2cos   − 1.25 = 1.25 − 0.0625 = 1.1875
 3 
  4π(0.5)  
⇒ y3 = y(0.75) = 1.1875 + 0.25  2cos   − 1.1875
  3  
  2π  
= 1.1875 + 0.25  2cos   − 1.1875
  3  
= 1.1875 + 0.25[−2.1875] = 1.1875 − 0.546875
⇒ y(0.75) = 0.640625 ≃ 0.6406

34. Since e x cos x and e x sin x are L.I solutions of


the D.E y′′ + py′ + qy = 0 ...(1)
∴ C.Fof (1)is e x [ c1 cos x + c2 sin x ] ⇒
1 ± i → α ± iβ are the roots of the A.E
∴ D.E is y′′ − y′{(1 + i) + (1 − i)} + {(1 + i)(1 − i)} y = 0

sec ond order
⇒ y′′ − 2y′ + 2y = 0
∴ p = −2, q = 2.

35. Region R(OAB) lies between x=0 and x = 2y i.e., x 2 = 2y and y=0 to 2 and with
horizontal strip
y
=2
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B x
(2, 2)

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O = (0,0), A = (2, 2), B = (0, 2)


By change of order of integration, R becomes with vertical strip ‘PQ’ so that
x limits = 0 to 2
x2
y limits = to 2
2
2 2
∴ given double integral = ∫ ∫ x2 f (x, y)dydx
x =0 y=
2

x2
⇒ b = 2 and c =
2
∴b × c = x2

36. Given N c = 0.57 × 10−3 kg m 2 − s


X1 = 0.5, X 2 = ?, t = 50000 sec
A = 4m 2 100kg of dry solid
= 8m 2 ( total )
LS  X1 − X 2 
Nc =  
A t 
Substituting values
200 ( 0.2 − X 2 )
0.5 × 10−3 = ×
8 5000
X 2 = 0.1

38. 4000 mol of S +


4000 mol of S Xmol of A

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A+B 200 mol of B
200 mol of B + ( a − x ) mol of A
+ a mol of 'A '
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Given y = 3 × 2

a−x
2
 x 
= 3 
200  400 
3
a−x= ×2
800
The maximum percentage extraction can be achieved
When a − x = x or a = 2x
Maximum extraction
x x
= = = 50%
a 2x

32

ωR 100 = 2.4 kg s
40. φ= =
L 0.80

41. Given R A = 5mm = 0.5cm, and ζ B = 2.2 g / mL


ζ B = 2.2 / 12g / mol, k s = 20cm / s
PAg 0.08
CA = = = 8.3 × 10−4 mol / l
g
RT 0.0821X
= 8.3 × 10−7 mol / ml
ζBR
For reaction control, τR =
bCAg K s
b = 1 ( stoic hom etric coefficient )
 2.2 
  × 0.5
τR =  12 
= 5517 sec
1 × 8.3 × 10−7 × 20

42.

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E (s) = X (s) − y (s) H


G
= x (s) −
H.X ( s )
1 + GH
G
= X (s)
1+ G
1
By equating we get ,a =
4

43.

constant
3 2
P const vol
Iso
1

V
1-2 constant volume process ω12 = 0
2-3 constant pressure process ω23 = P2 ( V3 − V2 )
= P3 V3 − P2 V2
⇒ R ( T3 − T2 ) = R ( T1 − 2T1 )
V1 V1 V3
Isothermal process ω31 = RTℓn =
V3 T2 T3

2T1  V1 T2 
= RTℓn ∵ = 
T1  V3 T3 
= 0.693 RT T3 = T1
Net work done = 0 − RT1 + 0.693 RT1
ω = −0.307 RT1
∴ Net work done ω = −0.307 RT1

44. At t = 0, 1ft 3
t = 1, 2ft 3
H (s) R
q0 = =
Q (s) τs + 1
τ = AR
Q ( s ) = 1 + 2e− s = 1 + 2e − s
R − t τ 2R − ( t −1) τ
H(t) = e + e
τ T
Put ( τ = 1) min, we have

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H ( t ) = R − e − t + 2R.e
− ( t −1)
for t > 1
H ( t ) = R − e for D < t ≤ 1
−t

Here R = 0.5
H ( t ) t = 0.05 min = 0.5e −0.5 = 0.303ft

45. Given data:

5 k g ste am a t 5 0 0 k P a 5 k g ste a m satu rate d


an d 1 8 0 0 C an d 1 8 0 0 C

dU = dQ − dW ⇒ dW = dQ − du = Tds − du ; dw ⇒ m T ( S2 − S1 ) − ( u 2 − u1 ) 
dw = 5 (180 + 273)( 6.622 − 7.055 ) − ( 2579 − 2606 )  = 5 ( 453) × ( −0.433) − ( −27 ) 
= 5 ( −196.149 + 27 )
dw = −845.745kJ Work done on system

46.
300 mm

W
o
200 mm o
d

Mass of wood = 0.075 × 0.075 × 2 × 650 = 7.312 kg


Mass of water displaced = 0.075 × 0.075 ( 2 − 0.3) × 1000
= 9.5625 kg
By Archimedes law,
Mass of water displaced = mass of wood + mass of lead
9.5625 =7.3125 + mass of lead
Therefore, mass of lead to be kept on the top of wood
= 9.5625 – 7.3125 = 2.25 kg

47. Thermal efficiency of Carnot engine

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TC
=1−
TH
27 + 273
=1−
377 + 273
= 0.5385
ηP = 0.5 × 0.53 = 0.26

48. q = m s and n ′ = m′m −1


0.75 kg sec
q= = 0.00114 m3 sec
659 kg m3
( 0.75) (103 )
n= = 8.703 mol sec
86.177 g mol
q
u=
A
π
Circular cross section a =   D 2 for D = 5 cm
4
π
( 5 × 10−2 ) = 0.001962 m 2
2
A=
4
q 0.00114
u= = = 0.582 m sec
A 0.00196

51. Given m = 1kg P1 = 1mpa = 1 × 106 N m 2


T1 = 100o C, T2 = 40o C, Q = 0, ω = ?, γ = 1.4
P
Q = 0 No heat transfer ⇒ Adiabatic process
PVγ = const
mR ( T1 − T2 )
W1− 2 = Wnet =
γ −1

=
(1)( 287 )(100 − 40 )
0.4
W1− 2 = Wnet = 43050J V

52. As mixing is adiabatically, so no heat will transfer outside.

3kg
2kg
80 o
C = 356k
30 o
C = 356k

I II

Applying energy balance equation


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m1c p ( T1 − Tmix ) = m1cp ( Tmix − T2 )


2 × ( 80 − Tmix ) = 3 × ( Tmiv − 30 )
Tmix = 50o c = 323k
( ∆s )system = ( ∆s )1 + ( ∆s ) 11
323 323
dT dT
= ∫
353
m1c p + ∫ m11cp
T 303 T
 323  323
= 2 × 4.187ℓn   + 3 × 4.187 × ℓn
 353  303
= 0.05915 kJ k

µv F µV
53. T= ⇒ =
y A y

( 0.09 ) 
0.5 

µ=
F.Y
=  12 
A.V ( 2 )( 5 )
ℓb.s
µ = 3.75 × 10−4
ft 2

54. Number of moles of Helium


PV 0.63 × 1.2
n He = = = 0.03
RT 0.00821 × 300
No. of moles of Ne
2.8 × 3.4
n Ne = = 0.39
0.0821 × 300
Mole fraction of He
0.03
X He = = 0.0714
0.03 + 0.39
Total pressure after connecting the bulbs
P1V1 + P2 V2
P=
V1 + V2
0.63 × 1.2 + 2.8 × 3.4
P=
1.2 + 3.4
P = 2.33 atm
Partial pressure at He
PHe = X He .P
= 0.0714 × 2.33
= 0.166
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55. Efficiency of stage B = 85%


P2 5
= 0.85, = 0.85
P1 P1
P1 = 5.88 m3 h
Applying the balance around stage B
P1 = P2 + P12
P12 = P1 − P2 = 5.88 − 5 = 0.88 m3 h
Efficiency stage A = 70%
P1 5.88
= 0.7, = 0.7
F + R2 F + 0.88
R 2 0.88
Recycle ratio = =
F 7.52
= 0.117 m3 reject recycle m3 fresh feed

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