SOLUTIONS TO PAPER – 3

PHYSICS

1. (2) (2) At t = 0, current through R3 will be half of the main current i.e.,
1 V  V
i0  
2  R  R / 2  3R
V
and at t =, current through will be, i 
2R
(4) Maximum charge stored in the capacitor
= CVmax

= CVR (at t = )
3

CV
=
2

2. (3) V = 2t
di
 L  2t
dt
di di
or 2   dt or t
dt dt
or (di) = t (dt)
Integrating we get,
t2
i
2
i.e., i-t graph is a parabola
at t = 2s, i = 2A
1 2 1
U  LI   2  4  4 J
2 2
dU  di 
= LI  
dt  dt 
 r2 
= (2)   (t)
2

= t3
dU
at t = 1 s,  1J / s
dt

1
Solutions for Question Nos. 3 to 5
To find charge stored in capacitor, find PD across its two places via any path preferably including only
batteries.


Energy drawn from E1  q1E1  300  106 (100)  0.03 J 

Energy drawn from E2  q2E2  200  106 (100)  0.02 J 
Net energy drawn from batteries = 0.01 J
 U = Uf  Ui

1 1
=  (3  106 )(100)2   (2  106 ) (100)2
2 2
= 0.005 J
 heat generated in circuit = (0.01 – 0.005)J
= 0.005 J
3. (1)
4. (4)
5. (3)

6. (2) Here, it is given that  A  5 / 3 and B  7 / 5

5 3
 CP  R and CV  R
A 2 A 2
7 5
and CP  R and CVB  R nA  1, nB  n(say)
B 2 2
nA CP  nB CP
 CP(eq)  A B
nA  nB

nA CV  nB CV
CV(eq)  A B
nA  nB

nA CP  nB CP
A B
CP(eq) nA  nB
  … (i)
CV(eq) nA CV  nB CV
A B
nA  nB

CP(eq) 19
Also  eq   … (ii)
CV(eq) 13

From Eqs. (i) and (ii), we get

2
 5 7
1 R  n  R
2 2  19  5  7n  19
3 5 13 3  5n 13
1 R  n  R
2 2
On solving the above equation, we get
n=2

nAMA  nBMB (1 4)  (2  32) 68

7. (1) Me   
nA  nB 1 2 3

 eqRT
Now sound =
Me

19  8.31 300  3
=
13  68  103
= 401 m/s

 1  1
8. (4) % change in T =    100  3
 300 
1
From the relation   T or   T 2

1 1
% change in  = (% change in T) =
2 6

9. (2) Velocity just before striking the ground

= 2 gh  9.8 m / s
 Velocity just after striking the ground
3
=  9.8 m / s  
4
2 3 9.8
 t  2   1.5 s
g 4 9.8

1
10. (2) Time period has increased hence effective value of g might have been decreased as T  .
g
Hence elevator is accelerating downwards

T g g 1.025 9.8
  = 
T g ga 1 9.8  a
Solving this Eq. we get
A = 0.49 m/s2.

3
11. (4) Vs2  (3)2  (8  42 ; Vs  5 Volt
Vs 5
Now, Z   5
I 1
3
Also, VR  IR or R  3
1
R 3
So, PF    0.6 as VL  VC
Z 5
 I lags V so this is a lagging nature.

1 2 1
12. (2) Q = Li =  10  400
2 2
2000
= 200 J = cal = 478.5 cal
4.18
Q 478.5
m=  6g
Lf 80

13. (1) (P2  P1 )A  mg

mg RTi RTi 3RTi

or    … (i)
A V1 4V1 4V1
Similarly in second case,

P1

P2

mg RTf RTf 2RTf

   … (ii)
A V2 3V2 3V2

Further, 5V1  4V2 … (iii)

Eqs. (i) and (ii), we get
3Ti 2Tf

4V1 3V2

9 V2 9 5
or Tf    Ti    320
8 V1 8 4
= 450 K

14. (4) Same speed does not mean relative velocity is zero.
Due to motion of source. Doppler effect is observed by change in wavelength.

4
15. (4) Two antiparallel forces of equal magnitudes can keep a rigid body in equilibrium if they are
concurrent.

16. (4) Path of centre of mss remains unchanged.

m/s
17. (1) SI unit of velocity gradient is per second.
m

18. 1(p), (q), (r); 2(p), (q), (r); 3(p), (q), (r); 4(r)

dK
19. (3) = power
dt
=F
= ma 
=4

20. (2) i  VR / R  65 / 100  0.65 A

VL 204
21. (2) XL    313.8 
i 0.65
or (2  f L) = 313.8 
313.8
L   1H
2  50

VC 415
22. (3) XC    638.46 
i 0.65
1
or  638.46
2fC
1
C =
(2  50)  638.46
= 5  10–6 F = 5  F

1
23. (2)  =
LC
1
or LC = as L = 1H
2
1 1
C=   10.1  F
2
(2  50)2

5
  600  B
24. (4)    400 m / s 
k 15  

B 1.6  105
  2
  1kg / m3
(400) (400)2

25. (3) ( p)max  BAk

( p)max (24 )
A = 
Bk (1.6  103 ) (15 )
= 1.0  10–5 m
= 10  m

26. (3)

27. (2) K  line means, transition of electron from

n1  2 to n2  1
For K series,

1  1 1
= R(Z  1)2  2  2 
 n 
 2 n1 
1 1
= (107 ) (92  1)2   
1 4 
3  91 91 107
=
4
4  1010 o
 = A
3  91  91  10 7

o
= 0.16 A

1  1 1 
28. (3)  (  1)   
f  R1 R2 
1 1 1
  
R1 R2 f(  1)
In water,

1    1 1 
Power =   1   
f  0   R1 R2 

   0  1 
=   
 0   f(  1) 

6
 
29. (4) Phase difference between V and I is
4
Therefore,
XC  R … (i)

 Z= 2R
Further, V = I Z

Or 100 2  5  2 R
 R = 20 

30. (3) Energy conservation holds in L–R circuit too.

31. (1) Whole ice will not melt and the temperature of mixture will be 0C.

32. (4) Car will acquire maximum sped i.e., 20 m/s in

20 s with an acceleration of 1 m/s2.
In retardation it will take 10 s. Suppose it moves
with constant speed of 20 m/s for t seconds.
Then,
Area of v–t graph = total displacement
1
or [t  30  t]  20  1000
2
or t = 35 s
 Total time of journey = (30 + t) = 65 s

33. (3) Suppose  is the speed of particle at that instant, then

 X  uX

or  cos  =  cos 2 
u cos 2
or  =
cos 

u(2 cos2   1)
=
cos 

= u(2 cos  – sec )

7
 CHEMISTRY

34. (3) Beryllium and magnesium don’t give flame test because of high heat required to excite.
35. (1) XeOF2, sp3 d-T shaped and NH2 sp3 –V-shaped.

36. (2)

37. (4) pV = nRT

V
 p.  RT
n
pVm  RT or pVm  T

m
pV  nRT  pV  RT
M
m
pm  RT  pM  dRT
V
pM  dT

n
pV  nRT  p  RT
V
p  CRT  p  CT
38. (2) Sulphur valence shell is less dense than oxygen.
39. (2) Aqueous HF mainly exists H3O+ and F– because HF is more acidic than H2O.
40. (3) Aldehyddes and ketones are more reactive than acyl halide.
41. (1)
42. (3) H+ is displaced by Br+, Electrophilic substitution.
43. (3) As reaction proceeds through enolate, racemization occurs.
44. (2)
45. (1)  G = (– 5.40) + (– 0.84) = – 6.24 kJ
46. (2)  G = – 0.84 kJ
47. (4) 2NO2 N2O4 ; G   6.24 kJ

2NO2 
 N2O4 ; G   5.40 kJ

48. (4) S2 O72

O O

S S

O –O O – O
O

8
49. (2) H 2Fe(s)  3CO(g)
3C(s)  Fe2O3 (s) 

3X – 110 – 82
3 CO(g)  Fe2O3 (s)


HBr CH  CH
50. (2) CH3  CH  CH  CH3  3  CH2  CH3

Br– and CH3OH both

can attack, but CH3OH
is in excess gives
major products

CH3  CH  CH2  CH3

|
OCH3

51. (2) In the presence of phosphoric acid R – OH gets

converted into R – O+ H2 and H2O is better leaving group than – OH.
52. (1)

53. (1) , It is rigid cis-oid, most favourable.

54. (1)

55. (2)

56. 1(p), (q), (r), (s); 2(r), (s); 3(p), (q), (s); 4(p), (s)

57. 1(p), (q), (s); 2(p), (r), (s); 3(q), (s); 4(q), (s)

58. (1) Mass = volume  density = 20 g, T = 7.6C

Heat evolved = 4.18  20  7.6 = 6.4  102 J
1
Moles of Ag+ = 10.0   102 mol
1000
= moles of AgCl

9
 Heat evolved per mole of AgCl
6.4  102
=
1  102 of AgCl
= 64 kJ/mol AgCl
H = – 64 kJ

59. (1) Step-II is rds; Rate = k3 [NOBr2 ][NO]

NOBr2 is assumed in steady state in equilibrium
k1 [NOBr2 ]
K  
k 2 [NO][Br2 ]

 [NOBr2 ]  K[NO][Br2 ]
Putting value in rate expression
Rate  k3  K[NO][Br2 ][NO]

or Rate  k[NO]2 [Br2 ]

60. (3) Complex A is cis-isomer which can easily form a chelate ring with oxalate group. On boiling in
HCl there will be conversion of cis intro trans.
61. (2)

62. (3)  E =q – W; work done = 0; Heat is given out = –q.

63. (1) Temperature falls, thus the internal energy decreases.

64. (2)

65. (1) [H2CO3 ] in blood = 2 M; volume of blood = 10 mL; [NaHCO3 ]  5 M

Suppose volume of NaHCO3 required = V mL;
Total volume = V + 10 mL
2 V
[H2CO3 ] after mixing =
V  10

10
 5 V
[NaHCO3 ] after mixing =
V  10
[salt]
pH  pK a  log
[acid]
k = 1.28  106 given; Ka = 7.8  10–7
5V
7.4 = – log (7.8  10–7) + log
2V
V = 78.36 mL
66. (2) Addition of H2PO4 will consume the available H+ drive the hydrogen carbonate equilibrium
backward.
[H2CO3 ] will decrease hence, dissociation into H2O and CO2 will decrease.
Thus, exhaling of CO2 will decrease.
67. (2) H2CO3 H2O  CO2
Its dissociation of carbonic acid.

BIOLOGY

68. (1) 85. (2)

69. (4) 86. (3)
70. (3) 87. (3)
71. (4) 88. (2)
72. (2) 89. (4)
73. (2) 90. (3)
74. (2) 91. (3)
75. (3) 92. (2)
76. (3) 93. (1)
77. (4) 94. (3)
78. (3) 95. (2)
79. (1) 96. (1)
80. (2) 97. (3)
81. (4) 98. (2)
82. (4) 99. (4)
83. (3) 100. (1)
84. (2)

11