Professional Documents
Culture Documents
L. H. Gevantman
The values in this table are taken almost exclusively from the The equation constants, the standard deviation for ln X1 (except
International Union of Pure and Applied Chemistry “Solubility where noted), and the temperature range over which the equation
Data Series”. Unless noted, they comprise evaluated data fitted applies are given in the column headed Equation constants. There
to a smoothing equation. The data at each temperature are then are two exceptions. The equation for methane has an added term,
derived from the smoothing equation which expresses the mole DT *. The equation for H2Se and H2S takes the form,
fraction solubility X1 of the gas in solution as:
ln X1 = A + B/T + C ln T + DT
ln X1 = A + B/T* + C ln T*
where T is the temperature in kelvin.
where Solubilities given for those gases which react with water, namely
ozone, nitrogen oxides, chlorine and its oxides, carbon dioxide,
T* = T/100 K hydrogen sulfide, hydrogen selenide and sulfur dioxide, are re-
corded as bulk solubilities; i.e., all chemical species of the gas and
All values refer to a partial pressure of the gas of 101.325 kPa (one
its reaction products with water are included.
atmosphere).
8-80
References 5. R. Battino, Ed., IUPAC Solubility Data Series, Vol. 7, Oxygen and
Ozone, Pergamon Press, Oxford, England, 1981.
1. C. L. Young, Ed., IUPAC Solubility Data Series, Vol. 5/6, Hydrogen 6. R. Battino, Ed., IUPAC Solubility Data Series, Vol. 10, Nitrogen and
and Deuterium, Pergamon Press, Oxford, England, 1981. Air, Pergamon Press, Oxford, England, 1982.
2. H. L. Clever, Ed., IUPAC Solubility Data Series, Vol. 1, Helium and 7. C. L. Young, Ed., IUPAC Solubility Data Series, Vol. 8, Oxides of
Neon, Pergamon Press, Oxford, England, 1979. Nitrogen, Pergamon Press, Oxford, England, 1981.
3. H. L. Clever, Ed., IUPAC Solubility Data Series, Vol. 4, Argon, 8. R. W. Cargill, Ed., IUPAC Solubility Data Series, Vol. 43, Carbon
Pergamon Press, Oxford, England, 1980. Monoxide, Pergamon Press, Oxford, England, 1990.
4. H. L. Clever, Ed., IUPAC Solubility Data Series, Vol. 2, Krypton, Xenon 9. R. Crovetto, Evaluation of Solubility Data for the System CO2-H2O, J.
and Radon, Pergamon Press, Oxford, England, 1979. Phys. Chem. Ref. Data, 20, 575, 1991.
10. P. G. T. Fogg and C. L. Young, Eds., IUPAC Solubility Data Series, 13. W. Hayduk, Ed., IUPAC Solubility Data Series, Vol. 9, Ethane,
Vol. 32, Hydrogen Sulfide, Deuterium Sulfide, and Hydrogen Selenide, Pergamon Press, Oxford, England, 1982.
Pergamon Press, Oxford, England, 1988. 14. W. Hayduk, Ed., IUPAC Solubility Data Series, Vol. 24, Propane,
11. C. L. Young, Ed., IUPAC Solubility Data Series, Vol. 12, Sulfur Dioxide, Butane and 2-Methylpropane, Pergamon Press, Oxford, England,
Chlorine, Fluorine and Chlorine Oxides, Pergamon Press, Oxford, 1986.
England, 1983.
12. H. L. Clever and C. L. Young, Eds., IUPAC Solubility Data Series, Vol.
27/28, Methane, Pergamon Press, Oxford, England, 1987.