1. A compound with the following composition has a molar mass of 60.10g/mol: 39.97% carbon; 13.41% hydrogen; 46.62% nitrogen.

Find the
molecular formula.
a) C3H8N2 b) C2H2N3 c) C2H3N2 d) C2H8N2
2. Bond angle of 109°28’ is found in:
a) NH3 b) H2O c) +CH3 d) NH4+
3. Select correct statement:
a) When a covalent bond is formed, transfer of electrons takes place b) Pure H2O does not contain any ion.
c) A bond is formed when attractive forces overcome repulsive forces. d) HF is less polar than HBr
4. Lattice energy of an ionic compound depends upon:
a) Packing of ions only b) Size of the ions only
c) Charge on the ion and size of the ion d) Charge of the ion only
5. Complete combustion of 1.00 mol of acetone (C3H6O) liberates 1790 kJ:
C3H6O(ℓ) + 4O2(g) → 3CO2(g) + 3H2O(ℓ); ΔH°comb, acetone = -1790 kJ
Calculate the enthalpy of formation of acetone.
a) – 2230 kJ/mol b) – 3500 kJ/mol c) – 248 kJ/mol d) – 1920 kJ/mol e) – 1367 KJ/mol
6. Which of the following reaction is possible at anode?
a) F2 + 2e- → 2F- b) 2H+ + ½O2 + 2e- → H2O
c) 2Cr2 + 7H2O → Cr2O7 + 14H + 6e
3+ 2- + - d) Fe2+ → Fe3+ + e-
7. For a cell given below
Ag | Ag+ || Cu2+ iCu
- +
Ag++e- → Ag, E0 = x
Cu +2e → Cu,
2+ - E0 = y
E0cell is:
a) x+2y b) 2x+y c) y-x d) y-2x
8. A catalyst increases rate of reaction by:
a) decreasing enthalpy b) decreasing internal energy c) decreasing activation energy d) increasing activation energy
9. The rate equation for a chemical reaction is: Rate of reaction = [X] [Y]
Consider the following statements in this regard:
(1) The order of reaction is one
(2) The molecularity of reaction is two
(3) The rate constant depends upon the temperature
Of these statements
a) 1 and 3 are correct b) 1 and 2 are correct c) 2 and 3 are correct d) 1, 2, 3 are correct
10. In a given system, water and ice are in equilibrium. If pressure is applied to the above system, then,
a) More ice is formed b) Amount of ice and water will remain same
c) More ice is melted (d) Either (a) or (c)
11. In which case KP is less than KC?
a) PCl5 ↔ PCl3 + Cl2 b) H2 + Cl2 ↔ 2HCl c) 2SO2 + O2 ↔ 2SO3 d) All of these
12. In the following list, which is the polar compound?
a) CCl4 b) N2 c) BF3 d) CO2 e) H2O
13. 3000 J of heat is added to a system and 2500 J of work is done by the system. What is the change in internal energy of the system?
a) 1500 J b) 500 J c) 5000 J d) 1800 J e) – 500 J
14. In a reaction, CO + 2H2 ↔ CH3OH ∆H = - 92 KJ/mol, concentration of hydrogen, carbon monoxide and methanol become constant at
equilibrium. What will happen if an inert gas is added to the system?
a) reaction becomes fast b) Reaction becomes slow
c) Equilibrium state disturbs d) Equilibrium state remains undisturbed
15. The radius of first orbit of hydrogen atom
a) 0.329 Ao b) 0.429 Ao c) 0.529 Ao d) 0.229 Ao
16. Which of the following have same no. of molecules at STP
a) 1000 cm3 of N2H4 and O2 b) 200 cm3 of CO2 and N2O c) 50 cm3 each of CO and N2 d) All above
17. Weight of one dm3 of O2 at STP is
a) 1.4384 gm b) 1.4394 gm c) 1.6384 gm d) 1.3384 gm
18. Ionic solids are characterized by
a) Low melting points b) Good conductivity in solid state
c) High vapor pressure d) Solubility in polar solvents
19. Amorphous solids.
a) Have sharp melting points b) Undergo clean cleavage when cut with knife
c) Have perfect arrangements of atoms d) can presses small regions of orderly arrangements of atoms
20. Boiling point is low for liquid with
a) High vapor pressure at given temperature b) low vapor pressure at a given temperature
c) Very high vapor pressure d) very low vapor pressure
21. 0.224 L of H2 gas at S.T.P is equivalent to
a) 1 mol b) 6.02 × 1022 molecules c) 1g d) 0.01 mol
22 2.0 g of oxygen contains number of atoms same as in-
a) 4g of S b) 0.5 g of H2 c) 7g of nitrogen d) 12.3 g of Na.
23. A sample of phosphrous trichloride (PCl3) contains 1.4 moles of the substance. How many atoms are there is the sample?
a) 5.6 b) 8.431× 1023 c) 4 d) 3.372 × 1024
24. Which of the following contains maximum no. of molecules?
a) 200 cc of NH3 at S.T.P b) 50 cc of SO2 at S.T.P c) 150 cc of N3 at S.T.P d) 150 cc of O2 at S.T.P
25. Which among the following is the heaviest?
a) One mole is oxygen b) 100 amu of uranium
c) One molecule of sulphur trioxide d) 44 g of carbon dioxide.
26. The cathode in the purification of aluminum metal:
a) Cryolite b) Graphite c) Pure aluminum d) Silver
27. The reaction Fe2O3 + 2Al → Al2O3 + 2Fe is known as:
a) Ferrite process b) Thermite process c) Aluminate process d) Cupirite Process
28. Which of the following are the amorphous allotropes of carbon?
a) Charcoal b) Lamp black c) Burnt paper d) All of these
29. The melting point of monoclinic Sulphur:
a) 93.5 °C b) 63.7 °C c) 101.5 °C d) 119.5 °C
30. The most dangerous impurity in SO2 during the manufacture of H2SO4 is;
a) Lithium b) V2O5 c) Pt d) Arsenic
31. K3[Al(C2O4)3]-3
a) Potassium trioxalato aluminate 0 b) Potassium trioxalato aluminium III
c) Potassium trioxalato aluminate II d) Potassium trioxalato aluminate III
32. Pyrolysis of a hydrocarbon form hydrogen gas and:
a) Ammonia Gas b) Water Gas c) CO2 d) Carbon Black e) HCOONa
33. Ca2C + 4NaOH → 2Ca(ONa)2 + ?
a) CH4 b) CH3CH3 c) NH3 d) HCl e) H2 + CO
34. What forms when steam is passed over red hot coke?
a) Ammonia Gas b) Water Gas c) CO2 d) Carbon Black e) HCOONa
35. Which of the following generally have a tetrahedral structure?
a) Ionic hydrides b) Covalent hydrides c) Complex hydrides d) Polymeric hydrides e) Metallic hydrides
36. Traces of CO are removes as - - - - - - when water gas is passed through NaOH”
a) Ammonia Gas b) Water Gas c) CO2 d) Carbon Black e) HCOONa
37. The melting point of NaCl during the manufacture of sodium metal is reduced by adding:
a) CaCO3 b) Gypsum c) CaO d) CaCl2 e) Ammonia
38. Which of the following undergoes nucleophile substitution exclusively by S N1 mechanism?
a) ethyl chloride b) isopropyl chloride c) chlorobenzene d) 2,2- dimethyl propane
39. Which one is correct about SN2 mechanism?
a) Here reaction intermediate is carbocation b) It is favoured by polar solvent.
c) It is favoured by stability of carbocation d) None of these
40. Which of the following alkyl halide would be the most reactive in S N2 reactions?
a) CH3CH2CH2CH2Br b) CH3CH(CH3)-CH2Br c) C6H5-C(CH3)2-Br d) C6H5CH2CHBrCH3
41. Which of the following is an ortho para deactivating agent?
a) –OCH3 b) –Cl c) –SO3H d) –COOH
42. Select the meta directors:
a) –CO2H b) –NO2 c) –CHO d) All of these
43. Which of the following boils at 77 °C?
a) CH3OH b) C2H5OC2H5 c) C2H5OH d) CH3COOC2H5
O O
║ ║
44. CH3 – C – ONa + CH3 – C – Cl → X + NaCl, what is X?
a) CH3COOH b) CH3COONa c) (CH3CO)2O d) (HCOOH)2
45. Acetic acid + PBr5 → CH3(C=O)Br + Y + HBr, what is Y?
a) PO5 b) POBr3 c) H3PO3 d) SO2
46. (CH3COO)2Ca + Dry distillation → Z + CaCO3, what is Z?
a) CH3COOH b) CH3CHO c) CH3COCH2CH3 d) CH3COCH3
47. Formaldehyde condenses into a liquid at:
a) – 7 °C b) – 4 °C c) –21 °C d) 0 °C
48. How much calories are used up in concentrated brain work per hour?
a) 450 b) 100 c) 70 d) Nil
49. What is the color of BILE?
a) Blue b) Deep Purple c) Red d) Green
50. Which of the following is false?
a) Glucose is a disaccharide b) Starch is a polysaccharide
c) Glucose and fructose are not anomers d) Invert sugars consists of glucose and fructose