Mock Test-7 Paper-1 (100396.

1)-CMP-IITJEE-25

PART I

AQ 6 P
1. tan .....(i) S B
PA PA 12atm R
AQ 6
tan ....(ii) 9atm Q
TA TA
SB SB
tan(90 ) ....(iii)
BQ 3 P
3atm A
T
BR BR 20cm 3
tan(90 ) ....(iv)
BQ 3
3
So, SB + BR = 10 cm
1
W PQTP = (20 10 6 ) (6 105 ) 6J
2
1 3
WSRQS (10 10 6 ) (3 105 ) J
2 2
3 9
Wnet 6 J
2 2

2. E K U
dE dK dU
dx dx dx
dK dU
0
dx dx
dK dU
dx dx

1
3. dU = stress strain dV
2
1 (stress)2
A 0 dx
2 Y
1 F2
dU dx
2 YA 0
L
1 F2 1
U dx
2 A0 0 1 2x

F2 1 2L
U n
2A 0 2 1

5. for a dark, at P
d sin

d2
1
2 n D
2
For, n = 4
7
= 5 10 m

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Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-26

1
6. (z 1)2

1.5405 (Z 1)2
0.7092 (zCu 1)2
Z = 42
Hence impurity is molybdenum

dp
7. F 2Ati 3Bt 2 j Ck
dt
Force are frame independent

10.-11. For I1 M

3/2 2R
0, V
V R 3
For I2 P
2R I1 R I3 I2
| V | |u| ( 1) 2R
3 3
For I3
3/2 N
2R
( 1)
0 3
V 2R
( 2) 2 R
3 3 2
R 1

Figure-1
M
2
V R 1

For I4
2 P
u R 2 ,V R I2, I3, I4 I1

1 3/2 1 3/2
R 2 R N
R 2 Figure-2

2
Now, if put the value of in figure -1, then we will get figure-2, as follows

1 A
(12-14) at t sec
3
1
0 3 1 rad/sec
3 2
r
2
a0 r r a0
sin90 sin( )
sin
2 r
60
2
a0 2 m/s
2 3
h r r sin
2
aA (2 3 ) m/s2
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 Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-27

SECTION B

1
mg 2
2. (A) T
k
mg
T
mv 2
1
LT 2 2
T
L2 T 2
mg
T2
k
mg
T2
mV 2
T2 V 2 [T]2 [LT 1 ]2 2
A 2
= LT
g LT
x y z 3
hF
(B)
2mk
h2F2 m2L4 T 2
F2 = M2L2 T 4
MxLy T z
2mk 2 mL2 T 2L2
x y z 0
Q2
(C) C
m
Q2 M2L4 T 4 1

2
ML0 T0 1

m C M L4 T 4 2

P MxLy Tz u
x y z u 2
C 0
(D) R
xe

R Xe ML2 T 3 A 2

M3L7 T 11
A 6
C 0 M 1L 2 T 4 A 2 M 1L 3 T 4 A 2
MxLy T z A u
2x + 2y + z + u = 3

SECTION C

4 3 4 4
G R G 2 (2R)3 (R)3
3 3 3
1. EQ
(2R)2 (2R)2
4 3
G R
3
EP
R2
EQ/EP = 15/4

2. PH = PG + g(GB) + a0(AB)

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Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-28

3 4 2
PH PG = 3 10 10 (1) = 3 10 N/m
1
3. 7 = 12t 10 t 2
2
5t 2 12t 7 0
t 1sec, 1.4 sec
So correct answer is 1 sec

I
4. T 2
mgd
T1 I1
T2 I2
2
I1 (mR2 mR2 ) mR 2 m 3R 12mR2

mR2 mR2 2
I2 mR2 m 3R 11mR2
2 2
T1 36
T2 33

nh nh
5. mvr , v
2 2 mr
2 r 4 2mr 2
t
v nh
2 2 2
4 m(r0n ) 4 2mr02n3
=
nh h
8
No. of orbit completed in 10 sec
10 8
= 8 106
T

PART II

SECTION A

1. D
SO3H SO3Na
NaHCO3 H2O CO2

OH ONa
NaHCO3 H2 O CO2
O 2N O 2N

2. D
H2O
Bi3 3I BiI3 BiOI
Black Orange ppt

3. A
x2 4x 3 x 1 x 3
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 Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-29

2
So, 0 when x = 1 or x = 3.

4. A
CH3 CH3 CH3
H2 O
CH3 2
SiCl2 HCl H3C Si O Si O Si O
CH3 CH3 CH3
Linear Chain

R R
H2O
CH3SiCl3 HCl O Si O Si O
O O

O Si O Si O
R R
Cross linked polymer

5. B
[salt]
pH = pKa + log
[Acid]
0.8
6.6 = pKa + log
0.2
pKa = 6 The Let X ml acid be added.
160 0.5
pH = 6 + log x 20mL .
X 0.4

6. B
[Ti(H2O)6]Cl4
Coordination number = 6 octahedral complex
Ti is in +4 oxidations state no unpaired electrons
magnetic moment = 0 B.M

7. A, B, C

bond order
+
(a) CO 3.5
+
(b) N2 2.5
(c) NO 2.5

8. A, B, C, D
O O
O O O
LDA
+ +

enolate ion
OCH3

9. B, C, D
Antibonding and - bonding orbitals are ungerade

10. B
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Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-30

11. A

12. C
NaNH2 CH3CH2Br S
CH3 C C H NH3
CH3C CNa
R

CH3 C C CH2 CH3 H2 /Pd BaSO4 CH3 CH2CH3

C C
H H
Na / liq.NH3
cis isomer

H CH2CH3
C C
CH3 H
trans isomer

13. A
Ozonoly sis
CH3CH2CH CHCH3 CH3CH2CHO CH3CHO
(P) (Q)

14. B
SECTION B

1. (A) (p, s) (B) (q, s) (C) (p, s) (D) (r, t)

CH3 CH3 CH3

HOOC COOH HOOC H H COOH
(A) H D H D
+ H D
+ CO2

Ph Ph Ph
Diastereomer
CH3 CH3 CH3

(B)
HOOC COOH H COOH + HOOC H + CO2
Et Et Et
Racemic
COOH COOH H COOH COOH H

(C) + + CO2

CH3 CH3 CH3

O
COOH C
O (Meso)
+ H2O
COOH C
O

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 Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-31

2. (A) (p, q, s) (B) (p) (C) (q, s) (D) (p, q, s)

O
HO CN HO CH2 NH2
(A) HCN LAH NaNO2

KOH HCl

N OH H H
N O N
(B) H+ LAH

(C)

O
Ph
(D)
CH3

SECTION C
1. 6
CHO

, glucose, Fructose, CH3CHO, HCHO, HCOOH ,reduce Tollen's reagent

2. 3
HCl Ba(OH)2
N1V1 N2V2
0.04 x 10 = N2 x 10
N2 = 0.04 N
N 0.04
Molarity = 0.02M
2 2
2

K sp Mg2 OH
-11 2
1.2 x 10 = S(0.02 + 2S)
2S < < 0.02
-11 -4
1.2 x 10 = (4 x 10 ) S
-8
= 3 x 10 M
x 3

3. 6
3+ 3
[Cr(H2O)6]Cl3 Cr 3d 3 unpaired electrons
3+ 3
[Cr(en)3]Cl3 Cr 3d 3 unpaired electrons
3+ 3
[Cr(NH3)4Cl2]Cl Cr 3d 3 unpaired electrons
3+ 3
[Cr(H2O)5Cl]SO4 Cr 3d 3 unpaired electrons
3+
[Co(H2O)4Cl2]NO3 Co 4 unpaired electrons
+3
K3[Fe(CN)6] Fe 1 unpaired electron

4. 7

5. 8
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Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-32

PART III

SECTION A

1. Let X is image of X about line L

then X PY are collinear

area of PQR Ar GPR GQR GQP

2. Ratio of =
area of ABC Ar ABC

1 1/2 1
1
3. sin 4 x g x dx = sin 4 x g x dx + sin 4 x g x dx For I2 put x = t
0 0 1/2
2
(I1) (I2 )

4. a+c=b+d+1
The number of polynomial will be 2(1 2+3 2+4 3+5 4)

1
5. Slope of axis is and origin lies on directrix
2

7. f(0) > 0 and f(1) < 0

x2 4x , x 0
2
9. f x 4x x , 0 x 2
2
x , x 2

2
10. Let the coordinate of points P are (cos 1, sin ) |k 2h| = 2|cos 1|

11. (1, 0) is focus and its reflection lies on x = 1 (the directrix).

12. The equation of line L is 2(x 1) + 3(y 1) + (z 1) = 0, x + y + z 5 + (2x + y + z 1) = 0

2
is
3

13. The equation of required line will be (2x + 3y + z 6) + (7x + 5y + 5z 17) = 0,

(3x y + z + 2) + (4x + 5y 2z 3) = 0
11 1
= , =
32 2

SECTION B

n 1
n r n n 1
1. =
r 0 r 1 r 2 r 3 4 n 2

2. (0, 4) and (4, 0) are points on asymptotes

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 Mock Test-7 Paper-1 (100396.1)-CMP-IITJEE-33

SECTION C
2 x
1. f(x) < (x x)e x (0, 1)
10 29
2. Coefficient of x in (1 x)

3 2 2
4. e= , b = 2 and a = 20
10

4 4 4 4
C2 C1 C2 C1
5. Probability = 4 4 4 4 4 4
C2 C1 C2 C1 C2 C2

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