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Chemistry, Mathematics & Physics All India Internal Test Series
Chemistry, Mathematics & Physics All India Internal Test Series
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
Each Section is further divided into two Parts: Part – A & Part – B.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
(i) PART-A (01 – 06) contains 6 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
PART-A (07 – 09) contains 3 Assertion-Reasoning Questions (MCQs) which have Only One Correct answer.
Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
PART-A (10 – 15) contains 2 Paragraphs. Based upon each paragraph, 3 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +4 marks for the correct answer and
–1 mark for a wrong answer.
(ii) PART-B (01 – 02) contains 2 Matrix Match Type Questions which have statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. There may be
One or More Than One Correct choices. Each question carries +8 marks for all correct answer however for
each correct row +2 marks will be awarded and –1 mark for each row matched incorrectly.
Name of Candidate :
Enrolment Number :
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |1
SECTION – I: CHEMISTRY
SECTION – A
Straight Objective Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is
correct.
1. Which of the following compounds will be suitable for Kjeldah1’s method for nitrogen estimation?
(A) N2Cl (B)
N
(C) NH 2 (D) NO 2
2H O
2 B
2CH3COOH 2CO2
2
(A) (B)
(C) (D)
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |2
4. Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br 2 to form product
B. A and B are respectively:
(A) OH
OH
and
OCH3
OCH3
Br O
O
(B) OH
Br OH
and
OCH3
OCH3
O
O
(C) O O O O
and
O O
Br
(D) O O O O
and
O O
Br
0
5. At 518 C the rate of decomposition of a sample of gaseous acetaldehyde initially at a pressure of 363 Torr, was 1.00
–1 –1
Torr s when 5% had reacted and 0.5 Torr s when 33% had reacted. The order of the reaction is
(A) 0 (B) 2
(C) 3 (D) 1
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |3
D-glucose
The correct structures(s) of -L-glucopyranose is(are)
(A) (B)
(C) (D)
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |4
Reasoning Type
This section contains 3 questions numbered 7 to 9. Each question contains Statement – 1 (Assertion) and Statement
– 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of which ONLY ONE is correct.
(A) Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
9. STATEMENT-1: Cl
NaCN
CN for this reaction on changing the solvent from.
MeOH
MeOH to DMSO, the rate of reaction becomes faster.
STATEMENT-2: SN2 reaction is favoured in polar protic medium.
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |5
Comprehension Type
This part contains 2 comprehension based question. Each group has 3 multiple choice question based on a paragraph. Each
question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
Aldehydes and ketones are polar molecule. Nucleophiles attack >C = O at carbon (positively charged) and electrophiles attacked
at oxygen. The characteristic reaction of aldehyde and ketone is nucleophilic addition to the carbon of carbonyl group.
+ -
O H Y Y O
Aldehydes and ketones undergo condensation only when it consist -hydrogen atom. The reaction will take place in presence
of dilute alkali and one aldehyde molecule is partially converted to its enolate anion by the base. The enolate ion undergoes
nucleophilic addition to the carbonyl group. The alkoxide formed in nucleophilic addition step, abstracts a proton from the
solvent to give aldol, which consist aldehydic and hydroxyl group.
O
H O
+ HO R + H2O
R Base Enolate
O O O OH O
H O H H2O
H
R
R R R R R
Aldol
The reactivity of carbonyl compounds for nucleophilic addition reaction is inversely proportional to +I effect.
(A) H3 C (B) Cl
H O O
Cl
Cl
H
(C) (D)
CHO
O
O CH 3
11.
+ A
CH 3 N
H3C
CH 3
H3C
A is
(A) (CH3)2NH (B) (CH3)3N
(C) (CH3)3CNH2 (D) None of the above
12. Which one is most reactive for addition of alcohol on carbonyl group?
(A) C6H5CHO (B) HCHO
(C) H3C CH 3 (D) CH3.CHO
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |6
Two aliphatic aldehydes P and Q react in the presence of aqueous K 2CO3 to give compound R, which upon treatment with HCN
provides compound S. On acidification and heating, S gives the product shown below:
H3C OH
H3C
O O
13. The compounds P and Q respectively are
CH3 CH3
H3C H H H
CH H and C CH H and C
(A) H3C
(B)
C H3C C
O O
O O
H3C CH2 H H3C H H3C CH2 H H H
CH C and C CH C and C
(C) (D)
CH3 O O CH3 O O
H3C C H3C C
(A) H (B) C H
C
H3C H3C
H2 C CH
OH H3C OH
CH3 O CH3 O
CH C CH C
(C) H3C H (D) H3C H
CH CH
H2C CH
OH H3C OH
CH C H3C C
(A) H3C H (B)
CH C H
H3C
H2C H2 C
CN CN
CH3 CN CN
CH CH H3C CH
(C) H3C OH (D)
CH C OH
H3C
H2C H2 C
OH OH
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |7
SECTION – B
Matrix Match Type
This Section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q,
r, s, t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in
Column II. For example, if for a given question, statement B matches with the statements given in q and r, then for the particular
question, against statement B, darken the bubbles corresponding to q and r in the ORS.
CH3
i Hg OAc
CH2
ii NaBH4
/ HOH
(B) H3C C
2 (q) CH3 – CH = CH – CH3
CH3
Cl CH3
(B) NH 4 (q) sp 3
(C) BF3 (r) Lewis acid
(D) SF6 (s) sp3d 2
(t) Coordinate bond
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This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C) and (D). ONLY ONE of these
four options is correct.
1. Let A = {x l x be a prime number and x < 30} .The number of different rational numbers whose numerator and
denominator belong to A is
(A) 90 (B) 180
(C) 91 (D) none of these
n n
2. If (1 + x) =
n
r 0
n
Cr xr , then
r m
r
Cm is equal to
n+1 n+1
(A) Cm (B) Cm + 1
n+2
(C) Cm + 1 (D) none of these
sin[x]
for [x] 0
3. If f(x) = [x] , where [x] denotes the greatest integer less than or equal to x, then lim f x equals
x 0
0 for [x] 0
to
(A) 1 (B) 0
(C) –1 (D) none of these
dx
4. The value of the integral xx x
is equal to
(A) 1 x c (B) 4 1 x c
(C) 2 1 x c (D) none of these
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | Page |9
e
cos2 x 3
5. For an integer n, the integral cos (2n +1) x dx has the value
0
(A) (B) 1
(C) 0 (D) none of these
2
6. The order of the differential equation of all tangent lines to the parabola y = x is
(A) 1 (B) 2
(C) 3 (D) 4
This section contains 2 questions numbered 7 to 8. Each question contains Statement – 1 (Assertion) and Statement
– 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of which ONLY ONE is correct.
(A) Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
7. Statement – 1: If N the number of positive integral solutions of x1.x2.x3.x4 = 770 then N is divisible by 4 distinct prime
numbers.
Statement – 2: Prime numbers are 2, 3, 5, 7, 11, 13
Statement – 1: The equation f(x) = 4x + 20x 9 = 0 has only one real root.
5
8.
4
Statement – 2: f(x) = 20x + 20 = 0 has no real root.
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 10
This section contains 6 questions. Based on each paragraph, there will be three questions. Each question has FOUR options (A),
(B), (C) and (D). ONLY ONE of these four options is correct
x 2 4x a , x3
Consider function f(x) = ax b , 3x4
b
x6 , x4
4
11. If x = 3 is the only point of minima in its neighbourhood and x = 4 is neither a point of maxima or minima then which of
the following can be true
(A) a > 0, b < 0 (B) a < 0, b < 0
(C) a > 0, b r (D) none of these
12. If x = 3 is the point of minima and x = 4 is a point of maxima then which of the following is true ?
(A) a < 0, b > 0 (B) a > 0, b < 0
(C) a > 0, b > 0 (D) none of these
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 11
(C) 2 C49
99 99
(D) none of these
99 2 99 2 99 2
15. The value of ( C0) + ( C1) + ……. ( C99) is
(A) 2a98 a99
2 2
(B) a99 a98
2
(C) a99 2a98 (D) none of these
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 12
SECTION – B
Matrix Match Type
This Section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q,
r, s, t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in
Column II. For example, if for a given question, statement B matches with the statements given in q and r, then for the particular
question, against statement B, darken the bubbles corresponding to q and r in the ORS.
1. Match the values of x in Column-II where derivative of the function in Column-I is negative.
Column I Column II
y = |x 2|x||
2
(A) (p) (1, 2)
(t) (1, 0)
2. Function is defined as f : {x1, x2, x3, x4, x5, x6} {y1, y2, y3}.
Column I Column II
(A) Number of surjective function (p) 552
(t) 540
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 13
This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C) and (D). ONLY ONE
of these four options is correct.
1. A particle of specific charge q/m is projected from the origin of coordinates with initial velocity v1ˆi v 2 ˆj in
space having uniform electric field and magnetic field as E ĵ and B ĵ respectively. The particle will definitely
return to the origin once if
v1B v 2B
(A) is an integer (B) is an integer
E E
v12 v 22 B q v1 v 2 B
2 2
2. An infinitely long current carrying wire carrying current i. A charge of mass m & charge q is projected with
speed v parallel to direction of current at a distance r from it. Then the radius of curvature at point of projection
is
2rmv 2rmv
(A) (B)
q 0 i q 0 i
(C) r (D) cannot be determined
3. Two identical thin rings, each of radius R meters, are coaxially placed at a distance R meters apart. If Q 1 C
and Q2 C are the charges uniformly spread on the two rings, the work done in moving a charge q from the
centre of the first ring to that of the other is
(A) zero (B) q(Q1 Q2) (2 1) / (2 4oR)
(C) q2 (Q1 + Q2) / (4oR) (D) q(Q1 + Q2) (2 + 1) / (2 4oR)
Space for rough work
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 14
C C
(A) (B)
x x
(a- b) (a - b)
C C
(C) (D)
x x
(a – b) (a – b)
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 15
This section contains 3 questions numbered 7 to 9. Each question contains Statement – 1 (Assertion) and Statement
– 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of which ONLY ONE is correct.
(A) Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
7 STATEMENT-1 : The sensitivity of a moving coil galvanometer is increased by placing a suitable magnetic
material as a core inside the coil.
and
STATEMENT-2 : Soft iron has a high magnetic permeability and cannot be easily magnetized or demagnetized.
8. STATEMENT -1 : Half of the electric field at a point just outside the surface of a charged conductor is due to the charge
on the surface in the immediate vicinity of that point.
because
STATEMENT -2 : Only half the charge resides on the surface of a charged conductor.
9. STATEMENT-1: Newton’s law of gravitation can be used to calculate the force of attractions between two
planets in two different galaxies.
and
STATEMENT-2: Newton’s law of gravitation is universal.
Space for rough work
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 16
This section contains 6 questions. Based on each paragraph, there will be three questions. Each question has FOUR
options (A), (B), (C) and (D). ONLY ONE of these four options is correct
10. When the magnetic field B0 is switched on, what force will be exerted on one moving charge carrier?
2
(A) QvB0 (B) n QvB0
3
(C) nQvB0 (D) n QvB0
D C area A
12. After a time there will be higher density of negative charge near the front E F
edge than near the rear edge. Why? G
(A) Due to drifting of negative charge towards the face ABCD due to I A B I
magnetic force D C
(B) Due to drifting of positive charge towards the face EFGH due to magnetic force
(C) Due to drifting of negative charge towards the face ABCD due to electrostatic force
(D) Due to drifting of positive charge towards the face EFGH due to electrostatic force
Space for rough work
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 17
near the origin and becomes a constant equal to V0 for |x| X0 (see figure).
13. If the total energy of the particle is E, it will perform periodic motion only if
(A) E < 0 (B) E > 0
(C) V0 > E > 0 (D) E > V0
14. For periodic motion of small amplitude A, the time period T of this particle is proportional to
m 1 m
(A) A (B)
A
(C) A (D) A
2m m
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SECTION – B
Matrix Match Type
This Section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q,
r, s, t) in Column II. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in
Column II. For example, if for a given question, statement B matches with the statements given in q and r, then for the particular
question, against statement B, darken the bubbles corresponding to q and r in the ORS.
1. Two wires each carrying a steady current I are shown in four configurations in Column I. Some of the
resulting effects are described in Column II. Match the statements in Column I with the statements in
Column II and indicate your answer.
Column I Column II
(A) Point P is situated midway between the (p) The magnetic fields (B) at P due to the currents
P
wires. in the wires are in the same direction.
(B) Point P is situated at the mid-point of the (q) The magnetic fields (B) at P due to the currents
line joining the centers of the circular wires, P in the wires are in opposite directions.
which have same radii.
(C) Point P is situated at the mid-point of the P (r) There is no magnetic field at P.
line joining the centers of the circular wires,
which have same radii.
(D) Point P is situated at the common center of (s) The wires repel each other.
P
the wires.
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Ai TS – 2 ( XII ) | SET – A | APT – 2 | P a g e | 19
2. Some rigid bodies connected with springs are shown in Column – I. All the rigid bodies shown are in
equilibrium and their time periods of oscillation are given in Column– II.
Column I Column II
2k
m m
(A) R/2
k (p)
6k 2k
A solid sphere of mass m and radius ‘R’ are connected
with two springs and friction is sufficient to prevent
slipping. Now solid sphere is slightly displaced then its
time period is
4k
2m
(B) (q) 2
k
k
k
5m
(D) (s) 2
k k
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