Professional Documents
Culture Documents
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
✓ Attempt ALL the questions. Answers have to be marked on the OMR sheets.
✓ This question paper contains Three Sections.
✓ Section – I is “Chemistry”, Section – II is “Mathematics” and Section – III is “Physics”.
✓ Each Section is further divided into two Parts: Part – A & Part – C.
✓ Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
✓ Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
Batch: All 1820
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) PART-A (01 – 07) contains 7 Multiple Choice Questions which have One or More Correct answer.
For each question in the group Q. 1 – 7 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −1 In all other cases.
• For example, if (A), (C) and (D) are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening
(A) and (B) will result in −1 marks, as a wrong option is also darkened.
PART-A (08 - 13) contains 2 Tables with 3 Columns and 4 Rows has three questions. Column 1
will be with 4 rows designated (I), (II), (III) and (IV). Column 2 will be with 4 rows designated (i),
(ii), (iii) and (iv). Column 3 will be with 4 rows designated (P), (Q), (R) and (S). Each question has
four options with only one correct.
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened
Zero Marks : 0 If none of the bubbles is darkened
Negative Marks : –1 In all other cases
(ii) PART-B valid for this paper as matrix match is not there.
(iii) PART-C (01 – 05) contains 5 Numerical Based questions with Single Digit Integer as answer, ranging
from 0 to 9 and each question carries +3 marks for correct answer. No negative marks will be
awarded in this section.
Name of Candidate :
Batch ID : Date of Examination : / / 2 0 1
Enrolment Number :
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |2
PART – A
(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.
1. Which of the following reaction(s) will give Anthraquinone as major product?
O OH
OH OH
O
CH3
(i) ,
⎯⎯⎯⎯⎯⎯⎯⎯⎯ →
(C) (ii) Oxidation (D)
( ) (i) AlCl
−4 H ⎯⎯⎯⎯⎯ 3
→
2 ()
ii FeSO 4
2. An ideal gas is expanded from (p1, V1, T1) to (p2, V2, T2) under different conditions. The correct
statement(s) among the following is(are)
(A) The work done on the gas is maximum when it is compressed irreversibly from (p2, V2) to (p1, V1)
against constant pressure p1.
(B) If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic
(C) The work done by the gas is more when it is expanded reversibly form V1 to V2 under adiabatic
conditions as compared to that when expanded reversible from V1 to V2 under isothermal
conditions.
(D) The change in internal energy of the gas is (i) zero, if it is expanded reversibly with T1 = T2 and (ii)
positive, if it is expanded reversibly under adiabatic conditions with T1 T2.
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |3
3. OH
(i) B2H6/THF
(ii) H2O2/OH
(iii) Acetone/dry HCl
O O
4. A compound(X) on heating with dil. Aq NaOH gives(Y). (Y) on reaction with (X) in presence of
− −
Li+ N ( i − Pr )2 gives (Z). (Z) on heating with dil OH gives
O
5. When O2 is adsorbed on a metallic surface, electron transfer occurs form the metal to O2. The TRUE
statement(s) regarding this adsorption is(are)
(A) O2 is physisorbed (B) heat is released
(C) occupancy of 2p of O2 is increased
*
(D) bond length of O2 is decreased
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |4
7. 80 gm salt of weak base & strong acid XY is dissolved in water and formed 2 litre of aqueous
solution. The pH of the resultant solution was found to be 5 at 298K. If XY forms CsCl type
crystal having rx + =1.6Å & ry − = 1.864Å
[Given : Kb (XOH) = 4 10-5 : NA = 6 1023]
(A) Molar mass of salt is 100 gm/mol (B) % degree of hydrolysis of salt is 0.25
(C) Edge length of XY is 4Å (D) Density of Solid salt XY is 2 in gm/cc
N= N
−
10. Which of the following is used for NO 3 group detection?
(A) (II), (iii) & (S) (B) (III), (ii) & (Q)
(C) (IV), (iv) & (P) (D) None of these
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |5
O 2N
(III) OH (iii) Cl2/AlCl3, then Br2/Fe followed by (R) OH
CH3ONa/130oC
OH
Cl Cl Cl OCH 3
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |6
PART – C
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled.
O
2. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and
phenylalanine. Glycine contributes 47.0 % to the total weight of the hydrolyzed products. The number
of glycine units present in the decapeptide is
(i) BuLi.THF
→ P (Major )
3.
CH3C CH ⎯⎯⎯⎯⎯⎯⎯
O
(ii)
D
(iii) H2O
(iv ) H2 /Pd−BaSO 4
Total number of stereoisomers of P is
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |7
PART – A
(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.
1. Let f ( x ) be an even function which is mapped from ( −, ) . Then, the value of
( f ( t ) dt + f ( x ) ) dx
x
can be (where [.] denotes greatest integer function)
− 0
(A) 0 (B)
(C) 2 (D) 4
cos x, 0 x 2
2. Consider f ( x ) = 2 such that f is periodic with period , then
−x , x
2 2
2
(A) the range of f is 0,
4
(B) f is continuous for all real x, but not differentiable for some real x
(C) f is continuous for all real x
2
(D) the area bounded by y = f ( x ) and the x – axis from x = −n to x = n is 2n 1 + for a
24
given n N
dy e − x , if 0 x 2
3. Let + y = f ( x ) where y is a continuous function of x with y ( 0 ) = 1 and f ( x ) = −2
dx e , if x 2
which of the following hold(s) good?
(A) y (1) = 2e (B) y ' (1) = −e
−1 −1
1 2 and Q1Q 2 , two focal chords of a parabola y = 4ax at right angles, then
2
4. If PP
(A) area of the quadrilateral P1Q1P2Q2 is minimum when the chords are inclined at an angle to the
4
axis of the parabola
(B) minimum area is twice the area of the square on the latusrectum of the parabola.
(C) minimum area of quadrilateral P1Q1P2Q2 cannot be found
(D) minimum area is thrice the area of the square on the latusrectum of the parabola
space for rough work
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |8
5. Let A ( ) and B ( ) be the extremities of a chord of an ellipse. If the slope of AB is equal to the slope
of the tangent at a point C ( ) on the ellipse, then the value of is
+ −
(A) (B)
2 2
+ +
(C) + (D) −
2 2
6. The tangent to the hyperbola xy = c 2 at point P(t) intersects the X – axis at T and the Y – axis at T’.
The normal to the hyperbola at P (t) intersects the X – axis at N and the Y – axis at N’ The area of the
1 1
triangle PNT and PN’T’ are and ' respectively, then + is
'
(A) equal to 1 (B) depends on t
(C) depends on c (D) equal to 2
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P age |9
Columns 1, 2 and 3 contains conics, equations of tangents to the conics and points of contact,
respectively.
Column 1 Column 2 Column 3
(I) x = x + 1 has roots ,
3 2 (i) a = 1 (P) b = 7
and , then the equation
whose roots are
2 + 3 + 4 , 4 + 2 + 3 and
2 + 3 + 4 is given by
x3 + ax2 + 33x + b = 0
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 10
Columns 1, 2 and 3 contains conics, equations of tangents to the conics and points of contact, respectively.
Column 1 Column 2 Column 3
=
( )(
)b 1
2010 (P)
/3 sin − cos − cos sin + cos + cos
3 3 2 2
d (i) a =
(I) If
/4 ( sin )
2012 2012
( cos )
2
(a + b ) − (1 − 8 )
n 2011
= ( a,b,c,d N+ )
2011
(ii) a = 10 2
1
(II) If cot −1
1
−1 x
2 ( a− b )( (Q) b =
cot dx = 8
1− x ( )
2
−1 1 − x2
x
4
a,b,c N in their lowest form)
(R) b = 6
2
( )(
(iii) a = 2
2 − cos 1 − x cos (1 − x) )
2
−1 −1
(III) Let f ( x ) =
( )
If
2 x − x
2
( )
f 0 + = a, f 0 − = b ( )
(IV) If W = ( 2 ) (iv) a = 3 (S) b = 3
1/5
and x = w + w2 and x5 = 10x2 + ax + b
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 11
PART – C
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled.
1. If A, B and C are angles of a triangle, then the minimum value of
B −C C−A A −B
cos cos cos
E= 2 + 2 + 2
B + C C+ A A +B
cos cos cos
2 2 2
2. ( )
If lim x −3 sin3x + ax −2 + b exists and is equal to zero, the value of a + 2b is ______
x →0
−
4. The maximum possible integral value of , where 0 3 is
tan − tan−1
−1
5. The point on the curve 4x2 + a2 y2 = 4a2 ; 4 a2 8 that is farthest from the point (0, –2) is ( , ) then
find +
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 12
PART – A
(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.
1. A sphere A moving with a speed u and rotating with an angular velocity , makes a head on elastic
collision with an identical stationary sphere B. There is no friction between the surfaces of A and B.
Disregard gravity. Then
(A) A will stop translating but continue to rotate with an angular speed .
(B) A will come to rest and stop rotating.
(C) B will move with a speed u without rotating.
(D) B will move with a speed u and rotate with an angular velocity .
2. A cylinder is rotated clockwise (as shown in figure) and lowered slowly
on a rough inclined plane with ( = 0.8). Then:
(A) centre of mass cylinder will start moving upwards
(B) centre of mass cylinder will start moving downwards.
(C) frictional force will act upwards.
(D) frictional force will act downwards. 60°
A sufficient friction
3. The spherical ball is released from point A. If C to prevent C
be the point upto which the ball goes on smooth slipping smooth
surface then (assuming hA, hc represent the hA hC
height of point A and C from horizontal level B
and kA, kL and the kinetic energies of sphere at B Fired
points A and C respectively wedges
4. A proton is fired from origin with velocity v = v 0 ˆj + v 0kˆ in a uniform magnetic field B = B0 ˆj .
In the subsequent motion of the proton.
(A) its z coordinate can never be negative.
(B) its x coordinate can never be positive.
(C) its x and z coordinates cannot be zero at the same time.
(D) its y coordinate will be directly proportional to its time of flight.
Space for rough work
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 13
4 12
8
I1 2 6
5. In the circuit shown, the current
(A) I = 8 A
8
(B) I = 7 A 4 12
I
(C) I1 = 3.5 A
(D) I1 = 4 A
S
28 V
(C) the ray will return back to the same medium for all values of n3
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 14
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 15
Figure shows five identical parallel conducting plates A, B, C, D and E of area A each carrying
charges Q, 2Q, –Q, –Q and 3Q respectively. S1 and S2 are ideal switches which are open initially.
Each position of column-1 starts from position described above. Column-2 contains charge on a
surface of a plate and coloumn-3 contains potential difference between two plates. Answer the
d
following questions. (Q = 11 C and = 3 V/C)
A0
A B C D E
Q 2Q –Q –Q 3Q
d 2d d 2d
S2
S1
11. Choose the correct option if column-2 indicates charge on left surface of plate C and coloumn-3
indicates potential difference between plates A and D (VA – VD)
(A) (II) (iii) (S) (B) (I) (iii) (Q)
(C) (III) (ii) (P) (D) (IV) (ii) (P)
12. Choose the correct option if column-2 indicates charge on right surface of plate D and coloumn-3
indicates potential difference between plates B and C (VB – VC)
(A) (III) (iii) (S) (B) (IV) (i) (R)
(C) (II) (iii) (S) (D) (III) (iii) (Q)
13. Choose the correct option if column-2 indicates charge on left surface of plate E and coloumn-3
indicates potential difference between plates C and E (VC – VE)
(A) (II) (i) (P) (B) (I) (iii) (Q)
(C) (IV) (iv) (R) (D) (III) (iv) (S)
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
Paper–1 (Class – XII) P a g e | 16
PART – C
(Integer Type)
This section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled.
1. A solid and rigid sphere of mass m = 80 kg and radius 0.2 m is spun about
a horizontal axis at an angular speed of and then dropped without initial
speed onto a stationary cart of mass M = 200 kg from a height of h = 1.25
m. It hits the cart exactly at the centre. The cart can move smoothly. Its
collision is perfectly elastic, and momentary. The sphere keeps sliding
throughout the entire duration of the collision. The coefficient of kinetic
friction between the sphere and the cart is = 0.1. The sphere rebounds
from the cart and falls back onto it again. The minimum possible length of
10x
the cart is X. The value of is.
4
m Vo = 10 m/s
3. A ball of mass 1 kg moving with velocity 10 m/s collides
perpendicularly on a smooth stationary wedge of mass 2kg
placed on smooth horizontal surface. If the coefficient of
M
restitution is e = 7/20 then find the velocity of ball after the
collision. [in ms–1]
= 30°
4. There are six infinite line currents all in the direction of Z-axis with magnitude I. They pass through the
vertices of a regular hexagon on XY plane. B1 is magnitude of magnetic field at the center of hexagon
when currents through three consecutive vertices are switched off and B 2 is magnitude of magnetic
field at the center of hexagon when currents through two consecutive vertices are switched off. Find
B1
B2
5. The electric field in a region is given by E 2x)iˆ (x3 2y)jˆ V/m. The potential difference
(3x2 y
between the points A (0,0,0) and B(1m,1m,1m) is i.e. VB VA (In volt)
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000