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General
Category Cyclosilicate
Formula (Ca,K,Na, )
(repeating unit) (Al,Fe,Li,Mg,Mn)3(Al,Cr,
Fe,V)6
(BO3)3(Si,Al,B)6O18(OH,F)4
[1][2]
Identification
Cleavage Indistinct
Tenacity brittle
Streak White
Density 2.82–3.32
Etymology
According to the Madras Tamil Lexicon[3]
the name comes from the word
"thoramalli" ( ) or "tōra- molli",
which is applied to a group of gemstones
found in the southern parts of the Indian
Subcontinent. According to the same
source, the Tamil "tuvara-malli"
( வைரம ) and "toramalli" are also
derived from the Sinhalese root word.
This etymology is also given in other
standard dictionaries including the
Oxford English Dictionary.
History
Brightly colored Ceylonese gem
tourmalines were brought to Europe in
great quantities by the Dutch East India
Company to satisfy a demand for
curiosities and gems. At the time, it was
not realised that schorl and tourmaline
were the same mineral, as it was only
about 1703 that it was discovered that
some colored gems were not zircons.
Tourmaline was sometimes called the
"Ceylonese Sri Lankan Magnet" because
it could attract and then repel hot ashes
due to its pyroelectric properties.[2][4]
Schorl species:
Schorl
A single stark green fluorite isolated on top of schorl
crystals
Dravite
Elbaite
Elbaite with quartz and lepidolite on cleavelandite
where:[9]
Bosiite NaFe3+3(Al4Mg2)Si6O18(BO3)3(OH)3O
Chromium-dravite NaMg3Cr6Si6O18(BO3)3(OH)3OH
Chromo-alumino-povondraite NaCr3(Al4Mg2)Si6O18(BO3)3(OH)3O
Darrellhenryite NaLiAl2Al6Si6O18(BO3)3(OH)3O
Dravite NaMg3Al6Si6O18(BO3)3(OH)3OH
Elbaite Na(Li1.5,Al1.5)Al6Si6O18(BO3)3(OH)3OH
Feruvite CaFe2+3(MgAl5)Si6O18(BO3)3(OH)3OH
Fluor-buergerite NaFe3+3Al6Si6O18(BO3)3O3F
Fluor-dravite NaMg3Al6Si6O18(BO3)3(OH)3F
Fluor-elbaite Na(Li1.5,Al1.5)Al6Si6O18(BO3)3(OH)3F
Fluor-liddicoatite Ca(Li2Al)Al6Si6O18(BO3)3(OH)3F
Fluor-schorl NaFe2+3Al6Si6O18(BO3)3(OH)3F
Fluor-tsilaisite NaMn2+3Al6Si6O18(BO3)3(OH)3F
Fluor-uvite CaMg3(Al5Mg)Si6O18(BO3)3(OH)3F
Foitite (Fe2+2Al)Al6Si6O18(BO3)3(OH)3OH
Lucchesiite Ca(Fe2+)3Al6Si6O18(BO3)3(OH)3O
Magnesio-foitite (Mg2Al)Al6Si6O18(BO3)3(OH)3OH
Magnesio-lucchesite Ca(Mg3Al6Si6O18(BO3)3(OH)3O
Maruyamaite K(MgAl2)(Al5Mg)Si6O18(BO3)3(OH)3O
Olenite NaAl3Al6Si6O18(BO3)3O3OH
Oxy-chromium-dravite NaCr3(Mg2Cr4)Si6O18(BO3)3(OH)3O
Oxy-dravite Na(Al2Mg)(Al5Mg)Si6O18(BO3)3(OH)3O
Oxy-foitite (Fe2+Al2)Al6Si6O18(BO3)3(OH)3O
Oxy-schorl Na(Fe2+2Al)Al6Si6O18(BO3)3(OH)3O
Oxy-vanadium-dravite NaV3(V4Mg2)Si6O18(BO3)3(OH)3O
Povondraite NaFe3+3(Fe3+4Mg2)Si6O18(BO3)3(OH)3O
Rossmanite (LiAl2)Al6Si6O18(BO3)3(OH)3OH
Schorl NaFe2+3Al6Si6O18(BO3)3(OH)3OH
Tsilaisite NaMn2+3Al6Si6O18(BO3)3(OH)3OH
Vanadio-oxy-chromium-dravite NaV3(Cr4Mg2)Si6O18(BO3)3(OH)3O
Vanadio-oxy-dravite NaV3(Al4Mg2)Si6O18(BO3)3(OH)3O
Physical properties
Crystal structure
Color
Treatments
Some tourmaline gems, especially pink
to red colored stones, are altered by heat
treatment to improve their color. Overly
dark red stones can be lightened by
careful heat treatment. The pink color in
manganese-containing near-colorless to
pale pink stones can be greatly increased
by irradiation with gamma-rays or
electron beams. Irradiation is almost
impossible to detect in tourmalines, and
does not, currently, affect the value.
Heavily included tourmalines, such as
rubellite and Brazilian paraiba, are
sometimes clarity-enhanced. A clarity-
enhanced tourmaline (especially the
paraiba variety) is worth much less than
a non-treated gem.[15]
Geology
Tourmaline is found in granite and
granite pegmatites and in metamorphic
rocks such as schist and marble. Schorl
and lithium-rich tourmalines are usually
found in granite and granite pegmatite.
Magnesium-rich tourmalines, dravites,
are generally restricted to schists and
marble. Tourmaline is a durable mineral
and can be found in minor amounts as
grains in sandstone and conglomerate,
and is part of the ZTR index for highly
weathered sediments.[16]
Localities
United States
Brazil
Watermelon Tourmaline mineral on quartz matrix
(crystal approximately 2 cm (0.79 in) wide at face)
World's largest
Africa
Afghanistan
See also
Benjamin Wilson – experimented with
the electrical properties of tourmaline.
References
1. Gemological Institute of America,
GIA Gem Reference Guide 1995,
ISBN 0-87311-019-6
2. "Tourmaline group" . mindat.org.
Archived from the original on 2005-
12-28. Retrieved September 12,
2005.. This website details
specifically and clearly how the
complicated chemical formula is
structured.
3. http://dsalsrv02.uchicago.edu/cgi-
bin/philologic/search3advanced?
dbname=tamillex&query=Tourmaline
&matchtype=exact&display=utf8
Madras Tamil Lexicon, p1994
4. Jiri Erhart, Erwin Kittinger, Jana
Prívratská (2010). Fundamentals of
Piezoelectric Sensorics: Mechanical,
Dielectric, and Thermodynamical
Properties of Piezoelectric
Materials . Springer. p. 4.
5. Draper, John William (1861). A
Textbook on chemistry. New York:
Harper and Brothers. p. 93.
6. Ertl, 2006.
7. Ertl, 2007.
8. Ertl, 2008.
9. Hawthorne, F.C. & Henry, D.J. (1999).
"Classification of the minerals of the
tourmaline group" Archived 2007-
10-16 at the Wayback Machine.
European Journal of Mineralogy, 11,
pp. 201–215.
10. Darrell J. Henry, Milan Novák, Frank
C. Hawthorne, Andreas Ertl, Barbara
L. Dutrow, Pavel Uher, and Federico
Pezzotta (2011). "Nomenclature of
the tourmaline-supergroup
minerals" (PDF). American
Mineralogist. 96: 895–913.
doi:10.2138/am.2011.3636 .
Archived (PDF) from the original on
2012-03-26.
11. Erratum: American Mineralogist
(2013), Volume 98, page 524.
12. Frank C. Hawthorne and Dona M.
Dirlam. "Tourmaline: Tourmaline the
Indicator Mineral: From Atomic
Arrangement to Viking Navigation."
Elements, October 2011, v. 7, p. (5):
307–312,
doi:10.2113/gselements.7.5.307.
13. Reinitz & Rossman, 1988.
14. Kirk Feral Magnetism in Gemstones
Archived 2013-12-03 at the
Wayback Machine
15. Kurt Nassau (1984), Gemstone
Enhancement: Heat, Irradiation,
Impregnation, Dyeing, and Other
Treatments, Butterworth Publishers
16. Hubert, John F. (1962-09-01). "A
zircon-tourmaline-rutile maturity
index and the interdependence of the
composition of heavy mineral
assemblages with the gross
composition and texture of
sandstones" . Journal of
Sedimentary Research. 32 (3).
doi:10.1306/74D70CE5-2B21-11D7-
8648000102C1865D . ISSN 1527-
1404 . Archived from the original on
2018-01-04.
17. Hurlbut; Klien. Manual of Mineralogy
(19th ed.). John Wiley and Sons.
18. Rynerson, Fred. Exploring and Mining
Gems and Gold in the West.
Naturegraph.
19. Johnson, Paul Willard (Winter 1968–
69). "Common Gems of San Diego".
Gems and Gemology. XII: 358.
20. Rossman et al. 1991.
21. "Largest cut Paraiba Tourmaline" .
guinnessworldrecords.com. 2014.
Archived from the original on 26
September 2014. Retrieved 29 April
2018.
22. King, Mike (October 17, 2009). "Giant
jewel breaks record" . Montreal
Gazette. Canwest News Service.
Archived from the original on 2013-
04-02 – via canada.com.
23. Allison Augustyn, Lance Grande
(2009). Gems and Gemstones:
Timeless Natural Beauty of the
Mineral World . University of Chicago
Press. p. 152. ISBN 0226305112.
Archived from the original on 2018-
04-29.
24. "Tourmaline: The gemstone
Tourmaline information and
pictures" . minerals.net. Archived
from the original on 2017-10-16.
Retrieved 2018-01-04.
Additional sources
Ertl, A.; Pertlik, F.; Bernhardt, H.-J.
(1997). "Investigations on olenite with
excess boron from the Koralpe, Styria,
Austria" (PDF). Österreichische
Akademie der Wissenschaften,
Mathematisch-Naturwissenschaftliche
Klasse. Anzeiger. Abt. I (134): 3–10.
Ertl, A. (2006). "About the etymology
and the type localities of schorl"
(PDF). Mitteilungen der
Österreichischen Mineralogischen
Gesellschaft. 152: 7–16.
Ertl, A. (2007). "About the type locality
and the nomenclature of dravite"
(PDF). Mitteilungen der
Österreichischen Mineralogischen
Gesellschaft. 153: 265–271.
Ertl, A. (2008). "About the
nomenclature and the type locality of
elbaite: A historical review" (PDF).
Mitteilungen der Österreichischen
Mineralogischen Gesellschaft. 154:
35–44.
Reinitz, I. M.; Rossman, G. R. (1988).
"Role of natural radiation in tourmaline
coloration" (PDF). American
Mineralogist. 73: 822–825.
Rossman, G. R.; Fritsch, E.; Shigley, J.
E. (1991). "Origin of color in cuprian
elbaite from São José de Batalha,
Paraíba, Brazil" (PDF). American
Mineralogist. 76: 1479–1484.
Schumann, Walter (2006). Gemstones
of the World (3rd ed.). New York:
Sterling Publishing. pp. 126–127.
Further reading
Henry, Darrell J.; Novák, Milan;
Hawthorne, Frank C.; Ertl, Andreas;
Dutrow, Barbara L.; Uher, Pavel;
Pezzotta, Federico (2011).
"Nomenclature of the tourmaline-
supergroup minerals" . American
Mineralogist. 96: 895–913.
doi:10.2138/am.2011.3636 .
External links
Retrieved from
"https://en.wikipedia.org/w/index.php?
title=Tourmaline&oldid=918508107"