Professional Documents
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GENERAL
1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so.
2. The paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back
cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the questions.
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4. The paper CODE is printed on the left part as well as the right part of the ORS. Ensure that both these codes
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are identical and same as that on the question paper booklet. If not, contact the invigilator for change of ORS.
5. Blank spaces are provided within this booklet for rough work.
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6. Write your name, roll number and sign in the space provided on the back cover of this booklet.
7. After breaking the seal of the booklet at 9:00 am, verify that the booklet contains 36 pages and that all the 54
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questions along with the options are legible. If not, contact the invigilator for replacement of the booklet.
8. You are allowed to take away the Question Paper at the end of the examination.
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12. You will be allowed to take away the Candidate’s Sheet at the end of the examination.
13. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
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14. Write your name, roll number and code of the examination center, and sign with pen is the space provided for
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this purpose on the ORS. Do not write any of these details anywhere else on the ORS. Darken the
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Page 1
PART-I: PHYSICS
SECTION 1 (Maximum Marks: 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of
these four option(s) is (are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟒 If only (all) the correct option(s) is (are) chosen.
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Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
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both of which are correct options.
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Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it
is a correct option.
Zero Marks : tib
0 If none of the options is chosen (i.e. the question is unanswered D).
Negative Marks: −𝟐 In all other cases.
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For Example: If first, third and fourth are the ONLY three correct options for a question with
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second option being an incorrect option; selecting only all the three correct options will result in
+4 marks. Selecting only two of the three correct options (e.g. the first and fourth options),
ad
without selecting any incorrect option (second option in this case), will result in +2 marks.
Selecting only one of the three correct options (either first or third or fourth option), without
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selecting any incorrect option (second option in this case), will result in +1 marks. Selecting
any incorrect option(s) (second option in this case), with or without selection of any correct
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1. Two particles of mass m and 2m moving in opposite direction collides head on. They
have same de-Broglie wavelength before collision. After the collision :
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Page 2
2. A soap bubble of radius 1 cm is formed in vacuum. It is filled with a monatomic gas.
Then using a syringe, more gas is pushed inside the soap bubble to double the radius.
The surface tension of soap solution is 0.05 N/m. Assume temperature to remain
constant:
A) The change in surface energy is 6 J .
B) The number of moles inside the bubble have become 4 times the original.
C) If the gas added is also monatomic, internal energy of gas has become 4 times the
original.
D) If the gas added is diatomic, internal energy of gas has become 6 times the original.
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3. A toy plane has a siren installed on it. The siren has a frequency of 100 Hz. The plane
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is moving at a velocity of 160 m/s in the horizontal direction. Assume that vertically
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upward is y direction, direction of motion of plane is x direction and plane is 8m
above the ground. The origin is vertically below the plane on the ground at a particular
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instant. Speed of sound = 320 m/s.
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A) the frequency recorded by a recorder at (0, 0, 6m) is 100 Hz.
500
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4. A block of ice at 0o C was being heated at a constant rate. The volume of sample as a
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function of time is shown in the graph below. Take ρice 0.9 gm/cc, ρ water 1 gm/cc,
γ water 103 / o C . Specific heat capacity of water 1 cal/gm o C , latent heat of fusion
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of ice 80 cal/gm.
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dH
A) V1 90cc B) 24cal/sec
dt
C) tan θ =1.44cc/min D) Water will start boiling at 8.24 min.
Page 3
5. A square loop of side a, resistance R, mass m is sliding as shown on a smooth
horizontal table with speed v0 . It enters a uniform magnetic field of magnitude B0
perpendicular to the table. It is seen that the loop comes to rest after entering a
distance l inside the magnetic field. The value of v0 can be :
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2B2 a 3 B2 a 3 B2 a 2 B2 a 3
A) B) C) D)
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mR 2mR 3mR 6mR
6. In the circuit shown, the battery is ideal. It has a voltage of 21V. The galvanometer G1
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shows 0.42 A. When another identical galvanometer G 2 is connected across R, the
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reading of G1 increases to 0.50 A :
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3
and that of distance has an error of 3 10 % , the relative error in:
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A) Permittivity of free space 0 is 7 103 %
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B) Permittivity of free space 0 is 3 103 %
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C) Permittivity of free space 0 is 4 103 %
D) Permittivity of free space 0 is 5 103 %
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8. Which of the following constants will have no uncertainity according to the new
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accepted system?
A) Universal gas constant R B) Stefan constant
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spherical ball of radius 0.1m is fitted inside them as shown. The inner surfaces are
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sufficiently rough so that there is no slipping any where. On slight displacement, the ball
starts moving along the gap shown in the downward direction. There are 2 possible cases.
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1. The inner pipe is held fixed but outer pipe is free to rotate.
2. The outer pipe is held fixed but inner pipe is free to rotate.
All the 3 bodies (both pipes & ball) have same mass of 1kg.
Page 5
9. When ball reaches the bottom, the pipe which is free to rotate is rotating with angular
1
velocity . Let it be 1 in 1st case & 2 in 2nd case.
2
5 5 2 3
A) B) C) D)
6 6 3 2
10. If the angular velocity of ball at the bottom in the 2 cases is 0 & '0 respectively,
0
'0
27 27
A) 1 B) 1 C) D)
25 25
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SECTION 3 (Maximum Marks: 24)
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This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL
VALUE.
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For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off
to the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) using the mouse and the
onscreen virtual numeric keypad in the place designated to enter the answer.
Full Marks
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Answer to each question will be evaluated according to the following marking scheme:
: +3 If ONLY the correct numerical value is entered as answer.
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Zero Marks : 0 In all other cases.
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19 Ne
23
11Na 23 10 v
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23
Atomic mass of Ne and 23 Na are 22.9945 u and 22.9898u respectively. Mass of
MeV
electron is 0.51 2 . The maximum kinetic energy of particle is ________ MeV.
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e
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3
12. A charge 2 10 C and mass 1 gm is projected from level ground with a velocity of
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10 m/s at an angle of 37o with the horizontal (x direction). The electric potential in
space is given by V 3x 4y. What is the speed of the charge (in m/s) when its y
coordinate is maximum?
Page 6
13. Find the magnetic field due to a spinning spherical shell of radius R, charge/area
rotating about its diameter with an angular velocity at its center. 3rad / s , R =
1.5
2m, C / m2 . Fill B 106 (in tesla) in the OMR sheet.
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14. A string is stretched between a pulley and a wave generator consisting of a plate
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vibrating up and down with small amplitude and frequency 120 Hz. The standing
wave pattern has 4 nodes as shown. What should be the load (in gm) we want a
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standing wave with 5 nodes.
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15. Parallel beam is incident on a thin lens ( ) and radii 25 cm of each of the
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surfaces as shown. What should be the thickness of a slab (in cm) ( 5 ) between
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the lens and the screen so that final image is formed on the screen
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Page 7
16. A dielectric slab of dielectric constant k, mass m, thickness d and area L L is
hanging vertically in equilibrium under the influence of gravity and electrostatic pull
of a capacitor connected to a battery of voltage V. The capacitor has plates of area
L L and distance between plates is d. The capacitor is half filled by the dielectric.
Suddenly a mass of m is attached to dielectric without any impulse on the system. The
slab falls off in time t. Evaluate t (in sec). Take k = 2, V = 4 volts, L = 80 cm, d = 0.1
mm.
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17. A boy of mass 40 kg is on a plank of mass 40 kg moving to right on a smooth floor at
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8 m/s. He wants to jump on to an identical plank travelling in the front at the same
speed. With what minimum speed (in m/s) relative to the plank on which he is
standing, should he jump? tib
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18. A massless spring is suspended from a hook at the top. A small mass of 180 gm is
suspended from the bottom of the hook. At the equilibrium it is at 20 cm from ground.
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It is pulled down to distance 15 cm from ground and released. Find the time (in sec) at
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Page 8
PART-II: CHEMISTRY
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Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered D).
Negative Marks : −𝟐 In all other cases.
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For Example: If first, third and fourth are the ONLY three correct options for a question with second
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option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
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correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
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case), with or without selection of any correct option(s) will result in -2 marks.
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1. In 1.5 litre, 2M NaOH solution, 320 gm bromine and 0.5 mole acetone are added giving
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colourless dense bromoform liquid. Excess NaOH was back titrated against 0.5M
H2SO4 using phenolphthalein as indicator, Volume of H2SO4 required to reach end
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point is (Br = 80) (Assume that excess NaOH does not react with Br2 left and
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bromoform formed)
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1 1 1
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2. Which of the following statements are true about AgI sol prepared by peptization of
AgI with AgNO3 (excess).
C) Na 3PO4 is more effective than AlCl3 for bringing about coagulation of sol.
Page 9
3. Which of following reaction sequence is/are given correct set of reaction as major
final product?
A)
B)
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C)
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D)
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C) Only C1 and C2 carbon are involved in osazone formation due to formation of six
membered transition state.
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5. Which of the following species have integral bond order, gerade type HOMO and
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paramagnetic nature.
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2 2
A) O 2 B) N 2 C) O 2 D) O2
6. Which of the following properties is/are common amongst the oxy acids
H2S2O7 , H4 P2O5 and H3P3O9
A) All have chain type open structure
B) All have X-O-X type linkage (X = central atom)
C) Central atom have it’s highest oxidation state
D) Atleast one X=O bond is present (X = central atom)
Page 10
SECTION 2 (Maximum Marks: 12)
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02)
questions.
Each question has FOUR options. ONLY ONE of these four options corresponds to the correct
answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered D).
Negative Marks: −1 In all other cases.
Complex having same molecular formula but different orientation in space are known as
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stereoisomers.
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Answer the following questions.
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7. For the octahedral complex, Ma x bx cx total number of geometrical isomer is:
(where a, b, c are monodenate ligands having achiral center)
8.
A) 6 B) 5 C) 4 tib D) 3
For the octahedral complex M(AB)2 (CD) (where (AB) and (CD) are two different
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bidentate ligands) C M D angle will be in general
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group substitute electrophile on o/p position, while – M on – m position if both group present
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in same aromatic compound substitution takes place according to more activating group.
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A) B)
C) D)
Page 11
10. Why acylation followed by reduction with (Zn – Hg/HCl) is more suitable to get alkyl
benzene in place of direct alkylation in presence of Lewis acid.
A) Direct alkylation not possible
B) Direct alkylation produce alkyl benzene which activates the ring for further
alkylation and gives polyalkylated product.
C) Alkylation follows free radical substitutions
D) Acylation followed by reduction give alcohol in place of alkyl benzene
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This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL
VALUE.
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For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off
to the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) using the mouse and the
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onscreen virtual numeric keypad in the place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks
Zero Marks tib
: +3 If ONLY the correct numerical value is entered as answer.
: 0 In all other cases.
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11. Equivalent conductivity of AgNO3 , CaCl2 and Ca(NO3 ) 2 at infinite dilution are
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1 2 1
110, 230 and 196.5 cm eqv respectively. Conductivity of AgCl(aq.) & H 2 O is
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2.4 106 cm1 and 1.4 106 1 cm1 respectively. Find solubility of AgCl in
mg/litre.
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12. In a parallel first order reaction starting with 1 mol 'A' as:
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o o
If A, B & C are optically active with standard optical rotation 15 , 10 & 20o degree
per mole respectively then give time in sec when solution will be optically inactive.
1
Given : k 0.024 sec , ln 2 0.7, ln5 1.60.
Page 12
13. A point source of light of power 3.2 milli watts emit energy 5eV. If the source is
located at a distance of 0.8m from the centre of metallic sphere of work function 3 eV
and radius 8mm. Number of photoelectrons emitted in 1 sec if efficiency is 1% is
x 10y in significant number, then find value of ' y ' (1 eV 1.6 1019 J )
14. Which of following molecule shows optical isomerism
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15. Total number of ore which concentrated by magnetic separation method: Tin stone
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consisting of Wolframite, Ilmenite, Chromite, Silver glance, Dolomite.
16.
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Any metal ‘A’ (sp. gr = 0.8) crystallizes in ccp arrangement with atomic radius 2 2Å
then give no. of moles of unit cell in 307.2 gm metal. [Use : NA 6 10 ]
23
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17. How many of following reaction gives Hoffmann product as a major product?
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18.
Total number of anions which will give coloured gas will be:
2
NO
2 ,S2 O3 ,Cl , Br , I , NO3 , F
Page 13
PART-III: MATHEMATICS
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of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
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a correct option.
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Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered D).
Negative Marks: −𝟐 In all other cases.
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For Example: If first, third and fourth are the ONLY three correct options for a question with
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second option being an incorrect option; selecting only all the three correct options will result in
+4 marks. Selecting only two of the three correct options (e.g. the first and fourth options),
up
without selecting any incorrect option (second option in this case), will result in +2 marks.
Selecting only one of the three correct options (either first or third or fourth option), without
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selecting any incorrect option (second option in this case), will result in +1 marks. Selecting any
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incorrect option(s) (second option in this case), with or without selection of any correct option(s)
will result in -2 marks.
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B(e x e x 2sin x)
; x0
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A
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2. Let z be a root of x5 1 0 with z 1. The value of z15 z16 z17 ..... z50 is less
than or equals to
A) 1 B) – 1 C) 0 D) 5
Page 14
3. If ABCD is a regular tetrahedron with length of any edge as l , then
l3
A) volume of tetrahedron is
6 2
l3
B) volume of tetrahedron is
6 3
2
C) minimum distance of any vertex from the opposite face is l
3
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D) minimum distance of any vertex from the opposite face is l
2
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x2 y 2
1, which of the following is true
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4. For the ellipse
16 9
A) Radius of auxiliary circle is 4
5. Suppose f (1) 2, f (4) 7, f '(1) 5, f '(4) 4 and f "( x ) is continuous. Then the
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4
value of x f "( x) dx is/are
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1
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3
6. If , are roots of equation 2 x 2 7 x 0 then tan 1 tan 1 is
2
1 1
A) tan (14) B) cot 1
14
1 1
C) tan (6) D) cot 1
6
Page 15
SECTION 2 (Maximum Marks: 12)
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02)
questions.
Each question has FOUR options. ONLY ONE of these four options corresponds to the correct
answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered D).
Negative Marks : −1 In all other cases.
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2t 2 2t
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Consider the curve y f ( x) which is defined parametrically as x ; y
(1 t 2 ) (1 t 2 )
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then
7.
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The value of t for which the tangent to the curve is parallel to x axis is
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A) 0 B) 1 C) 2 D) 3
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2 4
8. The normal at , to the curve y f ( x) intersects the curve agains at the point
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5 5
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8 4 8 4 2 4 4 8
A) , B) , C) , D) ,
5 5 5 5 5 5 5 5
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2 2 2
Consider the curve C1 : x y 1 and C2 : y 4 x then
A) 0 B) 1 C) 2 D) 4
Page 16
SECTION 3 (Maximum Marks: 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL
VALUE.
For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off
to the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) using the mouse and the
onscreen virtual numeric keypad in the place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
1 3
2 2 3 2 2
x x
2 x x 2 2
x2 x p
11. If 3 dx 3 dx 3 dx , where p and
5 x 3x 1 1 x 3x 1 6 x 3x 1 q
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6 5
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(6q p)
q are co-primes, then is
12
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12. Let B is adjoint of matrix A, having order 3 and BT B1 A (where B is non singular),
then
tr (A+B)
4
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is (where tr(A) is sum of diagonal elements of matrix A)
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13. The complete range of k for which equation x 4 2kx 2 x k 2 k 0 has all real
m n
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m
solutions is , , where m and n are relatively prime, then is
n 5
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14. Let the curve y f ( x) is having the property that slope tangent at any point is equal
y0
to twice its abscissa. If the curve passes through the points (1, 2) and (2, y0 ) then
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4
is
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15. Let is number of all possible 8 digit odd numbers formed by using only digits 0, 0,
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2, 2, 3, 3, 4, 5, then is
900
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kx
16. If the sum of all solutions of equations sin x 2cos x 1 3 cos x in [0, 2 x] is
6
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k
then is
2
r r r r r r r r r r r r r r r r r r 2
17. If [a b b c c a] 1 a b c and [a b b c c a] a b c then
(1 2 ) r r r
is (where a, b, c are non zero and non coplanar vectors)
3
1
18. r(r 1) is
r 1
Page 17
JEE ADVANCED – GT
PAPER -1 KEY
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3 AC 3 BD 3 AC
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4 ABC 4 BCD 4 ABCD
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5 BCD 5 BC 5 AC
6 AC 6 BD 6 AB
7 A 7 tib B 7 B
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8 A 8 A 8 B
9 B 9 C 9 A
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10 B 10 B 10 A
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Page 18
JEE ADVANCED – GT
PAPER -1 :: SOLUTIONS
PHYSICS
1. same p same
2mv
mv mv ' 2mv"
2
2. B, C, D
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3. A, C
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Sol. A)
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B)
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4. A, B, C
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H 90 80
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24cal / sec
t 5 60
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1.44cc / min.
5. B, C, D
Bav
Sol. i
R
B2 a 3
v0
mR
Page 19
6. A, C
Sol.
2100
RG
42
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R eq (20 15) 35.
21
i
35
0.6A i each 0.3A
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7. Ans. A
q1q 2
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Sol. F
40 r 2
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4F 24R
103 6 103
F r
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8. A
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9. B
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Sol. w g K
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1 2 1
mg 2.2 m (0.1) 2 2 m 0.12 2
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2 5 2
1 22000
2
5 27
10. Ans. (B)
Page 20
11. 4.37
Sol. Q (M Ne M Na )
c2
0.0047 931.5MeV 4.378MeV
12. Ans. 6.00
V
Sol. Ex 3iˆ
x
vy 0 10sin37 18t c
1
t sec
3
13. 2.40
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Sol. tib
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2 4 1.5 3 2 24 107 2.4
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14. 144.00
3 256g
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Sol. 120
2 1.5
en
m 9
m 9 16 144 gm
256 16
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15. 11.25
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1 2
Sol. 0.4
f 25
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t 3.75 3 11.25 cm
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16. 0.40
dU 1 2 dC
Sol. mg Fs lub V
dx 2 dx
L 1 g 2
t
2 2 2
2L 2 0.8
t 0.16 0.4 sec
g 10
Page 21
17. 10.00
Sol. Srel 5m
2u y uy
T
g 5
vrel 50 50 10m / s
18. 0.50
Sol. A 5cm
kx 0 mg
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1.8
k 7.2N / m.
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1/ 4
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0.18
T 2 1sec
7.20
t
T
2
0.5sec
tib
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CHEMISTRY
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1. Ans. D
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2. A, C, D
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3. B, D
4. B, C, D
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5. B, C
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6. B, D
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Sol.
Page 22
7. Ans. B
Sol. Complex is octahedral and a, b and c are monodentate ligand so value of x will
be 2. Complex is Ma1b2c3 , for the which number of G.I. will be 5
8. Ans. A
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Sol. angle will be approx 90
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9. Ans. C
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10. Ans. B
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11. Ans. 1.00
12. S
104
143.5
14.3log m
1mg
litre
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1.00
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1102 sec1
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y9
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14. 6.00
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15. 3.00
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16. 1.25
5
n BC 1.25
4
17. 5.00
18. 4.00
0
Sol. Cl , Br ,I and NO2
Page 23
MATHEMATICS
1. A, C
ex e x 2cos x e x e x 2cos x
Sol. lim B 2 xlim B
x 0
3x 0
6x 2
10
Sample space C2 45
Favorable (A, B) are (2, 3), (4, 6), (6, 9)
2. A, D
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15 2 35
Sol. z (1 z z .... z )
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z15
z 36
1 (z 1) 1
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(z 1) (z 1)
3. A, C
rr rr rr
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a.a a.b a.c
r r r rr rr rr
Sol. [a b c] b.a b.b b.c
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rr rr rr
c.a c.b c.c
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r r o l2 3
Where | a b| l l sin 60
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2
4. A, B, C, D
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a 4; b 3
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5. A, C
4
(xf '(x)) f '(x)dx = 2
4
6. A, B
7 3
and
2 4
Page 24
7. (B)
dy 2(1 t 2 ) 4t 2
Sol. Use 0 0
dt (1 t 2 )2
t 2 1 t 1
8. (B)
x 1
t t
y 2
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2t
y 2
(1 t )
x 2 y2 2x tib
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9. A
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10. A
en
y mx m2 1
.e
m2 0
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Not possible.
11. 2.50
2 2
x2 x
I2 3 dx
5 x 3x 1
12. 1.50
Page 25
13. 1.40
14. 1.25
15. 1.50
16. 2.30
sin x (2 3)cos x 2
3
sum k 5
6
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17. 1.33
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2, 2 2
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18. 1.00
fx
(r 1) r 1
1 tib
ra
r(r 1) r (r 1)
up
ad
en
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