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Exercises For The Complexometric Titrati PDF
Exercises For The Complexometric Titrati PDF
Problem 2 (68). A titration of 100 mL solution of CaCl2 requires 40.0 mL of 0.0100 M EDTA solution to the
end point of Erio-T at pH 10.0. Given that at the end point, 50% of indicator exits in the complex with metal
ion.
a) Write the reaction during the titration
b) Calculate the titration error
c) Calculate the concentration of CaCl2 with the consideration of titration error.
Given logβ(CaY2-)=5.0×1010; logβ(CaIn-) 2.5×105; pKa (H4Y): 2.00; 2.67; 6.16; 10.26.
Problem 3. To determine copper concentration in a solution: pipette 25.0 mL of copper ion solution in to a
flask; add amonia solution drop-wise until the light blur precipitate formed dissolves to form a clear blue
solution; add 3-4 drops of murexide indicator; titrate with 0.0010 M EDTA until the color changes from
yellow to purpule. The volume of the EDTA solution to reach the end point is 15.64 mL.
a) Write the reaction during the titration
b) Calculate the concentration of CaCl2 without the consideration of titration error
c) Calculate the titration error, given that at the end point 90% of indicator exits in the free-metal
complexed form and the analytical concentration of NH3 is 0.1 M.
Given logβ(CuY2-)=1018.8; logβ(CuIn-)=1017.9;logβ(Cu(NH3)4)=12.03; pKa(H4Y): 2.00; 2.67; 6.16; 10.26.
Problem 8. A 0.3304-g sample of brass (containing lead, zinc, copper, and tin) was dissolved in nitric acid.
The sparingly soluble SnO2.4H2O was removed by filtration, and the combined filtrate and washings were
then diluted to 500.0 mL. A 10.00-mL aliquot was suitably buffered; titration of the lead, zinc, and copper in
this aliquot required 34.78 mL of 0.002700 M EDTA. The copper in a 25.00-mL aliquot was masked with
thiosulfate; the lead and zinc were then titrated with 25.62 mL of the EDTA solution. Cyanide ion was used to
mask copper and zinc in a 100-mL aliquot; 10.00 mL of the EDTA solution was needed to titrated the lead
ion. Determine the composition of the brass sample; evaluate the percentage of zinc by difference.