PART B: VOLUMETRIC EXPERIMENTS

Sl.
No. Experiments. PART A: Preparation of Standard Solution. Part B: Estimation / Preparation / Determination.

^ In 250 25cm3 water.

Determination of 10 ml.
EDTA cm3 Standard 5cm3 NH3-NH4Cl Wine Red
1 TOTAL HARDNESS NH3
crystals volumetric EDTA buffer soln. (Eriochrome to
of a sample of water soln.
flask. Molarity of EDTA = soln. (pH=10) Black-T) CLEAR BLUE.
^ Dissolve 𝑊𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝐸𝐷𝑇𝐴 𝑡𝑎𝑘𝑒𝑛 ∗ 4
in diluted 𝑀𝑜𝑙. 𝑤𝑡. 𝑜𝑓 𝐸𝐷𝑇𝐴 (372.24) 25cm3 Cement
Determination of water, up sample.
10 ml. Standard Wine Red
CALCIUM OXIDE in EDTA to the 5cm3 Diethyl
2 NH3 EDTA to
the given sample of crystals mark. Amine. .
soln. soln. CLEAR BLUE.
cement ^ Mix well. 5cm3 Glycerol.
10cm3 4N NaOH.
^ in Conical Flask.
Standard Brass soln.
Determination of
1/4th test-tube conc. HNO3. Few drops NH4OH. 2cm3 Disappearance
percentage of Standard
Brass Boil, till brown fumes are expelled. Dil. CH3COOH. soln, of Blue
3 COPPER IN BRASS Na2S2O3
sample 1 TT distilled water. 20ml. of 10% KI. to give
using standard soln.
1 gm. Urea. 1 TT Distilled at end point. WHITE ppt.
sodium
Boil for 2 min. Water.
Cool to room temp.
25cm3 Haematite
^ In 250 soln.
Estimation of iron in
cm3 1/4th TT conc. HCl.
HAEMATITE ORE Normality of K2Cr2O7 = Standard Indicator drop
K2Cr2O7 volumetric 𝑊𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 K2Cr2O7 𝑡𝑎𝑘𝑒𝑛 ∗ 4 SNCl2 drop-wise on a Wax
4 SOLUTION using K2Cr2O7 doesn’t
crystals flask. till colourless. Paper.
K2Cr2O7 by external 𝐸𝑞. 𝑤𝑡. 𝑜𝑓 K2Cr2O7 (49) soln. change colour.
Cool.
indicator method
^ Dissolve 1/4th TT HgCl2 External.
in diluted >>silky white ppt.
water, up
Determination of
to the 25cm3 waste Blue Green
CHEMICAL 2 TT of Normality of FAS = Standard
FAS mark. water sample. To
5 OXYGEN DEMAND dil. 𝑊𝑒𝑖𝑔ℎ𝑡 𝑜𝑓 𝐹𝐴𝑆 𝑡𝑎𝑘𝑒𝑛 ∗ 4 FAS .
crystals 10cm3 K2Cr2O7. REDDISH
of a given industrial H2SO4. 𝐸𝑞. 𝑤𝑡. 𝑜𝑓 𝐹𝐴𝑆 (392) soln.
^ Mix well. 1 TT 1:1 H2SO4. BROWN.
waste water sample
 PART A: INSTRUMENTAL EXPERIMENTS

Sl.
Observations /
No Experiment Beaker Electrode Instrument Burette Graphs
Formulas…
.

^ Equivalence point.
^ Half Equivalence
Glass point.
Determination of
Electrode
pKa VALUE of a Weak
1 + pH meter NaOH ^ pH at half-
weak acid Acid equivalence point.
Calomel
using pH meter. =
Electrode pKa value of given
weak acid.

^ Normality =
FAS K2Cr2O7 (𝑁∗𝑉)𝑜𝑓 K2Cr2O7
.
Estimation of FAS Calomel 𝑉𝑜𝑙. 𝑜𝑓 𝐹𝐴𝑆
soln. 2 TT solution
POTENTIOMETRICALLY electode – Pt
2 dil. Potentiometer .
using standard electrode ^ Weight of FAS
(25 H2SO4
K2Cr2O7 solution assembly per liter
cm3) (0.5 N) = Normality * Eq.
wt. of FAS (392).

^ NNaOH =
𝑁(𝑁𝑎𝑂𝐻)∗𝑉1
𝑉(𝐻𝐶𝑙) [50𝑚𝑙.]
.

(HCl + ^ NCH3COOH =
CH3C 𝑁(𝑁𝑎𝑂𝐻)∗(𝑉2−𝑉1)
.
Estimation of acids in OOH) NaOH 𝑉(𝐶𝐻3𝐶𝑂𝑂𝐻) [50𝑚𝑙.]
Conductivity Conductivity
3 acid-mixture solution
cell meter ^ Wt. of HCl in 1 L of
CONDUCTOMETRICALLY Acid . soln.
mixtur = NHCl * Eq. wt. of
e. HCl (36.5)

^ Wt. of CH3COOH in
1 L of soln.
= NCH3COOH * Eq. wt. of
CH3COOH (60).
 ^ CuSO4 soln. into 5 volumetric flasks. ^ Weight of Cu
(5, 10, 15, 20, 25 cm3) in the given test
Colorimetric
4 ^ 5cm NH3 to all flasks and test soln. flask.
3
soln.
Determination of Copper.
^ Distilled water, up to the mark. = ‘a’ *
^ Measure Absorbance from instrument. 1.0185 mg.

^ 20cm3 Distilled water in viscometer (wide limb).

^ Record time of flow btwn. Two fixed points.

Estimation of VISCOSITY ^ Pour out, rinse with Acetone, dry in hot air oven. 𝑡𝑙 ∗ 𝑑𝑙
^ Viscosity Coefficient, nl = 𝑡𝑤 ∗ 𝑑𝑤 ∗ 𝑛𝑤. millipoise.
COEFFICIENT of a given
5
liquid using Ostwald’s ^ 20cm3 Given Liquid in viscometer. 𝐶𝑉−𝑂𝑉
Viscometer. ^ Record time of flow btwn. Two fixed points. ^ % error = 𝐶𝑉
∗ 100.

^ Record Laboratory Temperature.