UNIT – III

CHEMICAL KINETICS
TYPE- FILL IN THE BLANKS

Remembering
1. Hydrolysis of Ethylacetate in an acidic solution is an example of _________________
Order reaction.
(Ans: Pseudo first)
2. The reaction taking place under the influence of visible light is called _____________
reaction.
(Ans: Photochemical)
3. In a multiple step reaction, the _______________ step determine the rate of reaction.
(Ans : Slowest)
4. The sum of powers to which concentration terms are raised in the rate law is called
___________ of the reaction.
(Ans: Order)

Understanding
5. The rate constant has the same unit as rate of reaction for a ______________ order
reaction.
(Ans : Zero)
6. The rate of reaction increases with ______________ in activation energy of reaction.
(Ans : Decrease)
7. Catalyst speed up the reaction by decreasing the _______________ energy of reaction.
(Ans: Activation )
8. The rate constant is nearly double with rise in temperature by every _____________ º C.
(Ans : - 10)
9. Value of rate constant for a reaction is 5.5 × 10 -14 sec-1, then order of reaction is
_____________.
(Ans : First Order)
10. Molecularity of first order reaction is neither negative nor _______________.
(Ans : Zero)
11. Half life period is independent of initial concentration of reacting species for
______________ order reaction.
(Ans : First)

Application
12. The decomposition of gaseous ammonia on a hot platinum surface is a ___________
order reaction.
(Ans : Zero)
13. All natural and artificial radioactive decay is an example of _________________ order
reaction.
(Ans : First)
 14. For the following reaction , rate of reaction does not depend on concentration of
___________
H+
C12H22O11 + H2O C6H12O6 + C6H12O6
(Ans: H2O)
15. Collision theory is applicable to ______________ reaction.
(Ans :Biomolecular)
16. Branch of Chemistry applied on reaction rates and their mechanism is called _________.
(Ans : Chemical Kinetics)
17. Conversion of vegetable oil into Vanaspati Ghee is an example of ________ order
reaction.
(Ans : First)
18. Molecularity is applicable to only __________ reaction.
(Ans : Elementary)

Evaluation & Analyzing

19. The t0.5 of a first order reaction is __________ the t0.75 of the first order reaction.
(Ans :½)
20. The order of a reaction with respect to B, whose rate law is rate = k[A]3/2[B]1/2 is
__________.
(Ans : 0.5)
21. A first order reaction gets completed in __________time.
(Ans : Infinite)
22. When temperature for a reaction increases from 30ºC to 60ºC, the rate of reaction
increases ___________ times.
(Ans : 8)
23. When initial concentration of the reactant is doubled than the half-life period of zero
order reaction gets __________.
(Ans: Double)
24. Activation energy for a reaction is zero and value of rate constant is 2.5 × 10-6 mol/lit/sec
at 20ºC. Value of rate constant at 30ºC will be ________________.
(Ans : 2.5 × 10-6)