GASES 4. A balloon containing 1.47 moles of gas has a volume of 0.783 L. If 3.55 12.

s has a volume of 0.783 L. If 3.55 12. What is the molar mass of a gas that effuses 1.75 times faster than CO2 ?
moles of gas are added into the balloon without changing the temperature ANS14.4 g/mol
The Gas Laws
and pressure, what will be the new volume of the balloon? ANS 2.67L
Boyle’s Law: P1V1 = P2V2 13. *An air bubble rises from the bottom of a well where the temperature is
5. A gas-filled balloon having a v olume of 2.5 L at 1.2 atm and 25 deg C is 25 deg C, to the surface where the temperature is 27 deg C. Find the
Charles’ Law: V1/T1 = V2/T2
allowed to rise to a height where the temperature and pressure are -23 deg percent increase in the volume of the bubble if the depth of the well is 5
Gay-Lussac’s Law: P1/T1 = P2/T2 C and 0.39 atm, respectively. Calculate the final volume of the balloon. m. Atmospheric pressure is 101, 325 Pascal. ANS 0.493 or 49.3 %
ANS 6.45 L
Avogadro’s Law: V = kn or P/n = k
14. *Carbon dioxide which is recognized as the major contributor to global
𝑃1 𝑉1 𝑃2 𝑉2
Combined Gas Law: = 6. How many moles of an ideal gas are there if the volume of the gas is 146 warming as a “greenhouse gas,” is formed when fossil fuels are
𝑇1 𝑇2
L at 14 deg C and a pressure of 3.45 atm? combusted, as in electrical power plants fueled by coal, oil, or natural gas.
Ideal Gas Law: PV = nRT One potential way to reduce the amount of CO 2 added to the atmosphere
7. The pressure gauge of a steel cylinder of methane (CH4) reads 23 atm. is to store it as a compressed gas in underground formations. Consider a
where R = 0.0821 L-atm/mol-K
The cylinder has a volume of 0.5 L at 25 degree Celsius. How many grams 1000-megawatt coal-fired power plant that produces 6 x 106 tons of CO2
Dalton’s Law of Partial Pressure of methane does the cylinder contain? ANS 7.52 g CH4 per year. (a) Assuming ideal-gas behavior, 1.00 atm, and 27 deg C,
PT = PA + PB +PC …, calculate the volume of CO2 produced by this power plant. (b) If the CO2
is stored underground as a liquid at 10 deg C and 120 atm and a density
Graham’s Law of Effusion
𝑟1 𝜌 𝑟 𝑀𝑀
8. Calculate the density of NH 3 (g) at STP. of 1.2 g/cm3, what volume does it possess? (c) If it is stored underground
= √ 2 𝑜𝑟 1 = √ 2 as a gas at 36 deg C and 90 atm, what volume does it occupy? ANS (a)
𝑟2 𝜌1 𝑟2 𝑀𝑀1
9. For a gas sample whose total pressure is 760 Torr, what are the partial 3x1012L (b)5x109L (c) 3x1010L
Standard Temperature and Pressure (STP)
pressures of the following component gases: 1.35 mol N 2, 3.45 mol CO2,
Temperature = 273 K or 273.15 K
Volume = 22.4 L 4.38 mol H2, and 1.49 mol SO2? ANS 756 Torr 15. A gaseous mixture of He and O2 has density of 0.518 g/L at 25 deg C
Pressure = 1 atm Mole = 1 mol and 721 mmHg. What is the mass percent of He in the mixture. ANS
10. H2 (g) generated when Zn (s) reaxts with HCL over water. The volume of 19.9 %
PROBLEMS:
gas collected at 32 deg C and pressure of 938 mmH is 501 mL.(a) What
GAS LAWS is the mass in grams of H2 (g) obtained? The vapor pressure of water at
32 deg C is 35.66 mmHg. (b) What is the volume of H2 (g) at STP.ANS
1. A sample of Gas with a volume of 1.45 L exerts a pressure of 780 Torr.
(a) 0.0483 g (b) 0.534 L
What is its volume if the pressure becomes 740 Torr at constant
temperature and amount of gas? ANS. 1.53L
11. The reaction of aluminum with hydrochloric acid produces hydrogen gas.
The chemical equation for reaction is given below.
2. A sample of gas with a volume of 6L is heated from 35 deg C to 75 deg
Al (s) + HCl (aq)  AlCl3 (aq) + H2 (g)
C. Calculate the new volume of the gas if the pressure remains the same.
If 35.5 mL of H2(g) is collected over water at 26 deg C and a barometric
ANS 6.78L
pressure of 755 mmHg, how many moles of HCl must have been
consumed? (The vapor pressure of water at 26 deg C is 25.2 mmHg). ANS
3. A gas sample exerts a pressure of 5.3 atm at 46 deg C. What is the pressure
0.00278 mol HCl
when the temperature is reduced to 25 deg C? ANS 4.95 atm