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Probs 1-10
The value I will use for Avogadro's Number is 6.022 x 1023 mol¯1.
When the word gram replaces mole, you have a related set of problems which requires one more
step. So keep in mind that there are 4 example problems just above.
These problems use the reverse technique of the above. Once again, replacing mole with gram
adds one step to the procedure.
Pick the box of the data you are given in the problem and follow the steps toward the box
containing what you are asked for in the problem.
In example #10, I do a problem that will require three steps. The first two steps will be laid out
below and I will then introduce the third step at example #10. Make sure to take a look at it.
Start from the box labeled "Moles of Substance" and move (to the right) to the box labeled
"Number of Atoms or Molecules." What do you have to do to get there? That's right - multiply
by Avogadro's Number.
Solution:
The unit on Avogadro's Number might look a bit weird. It is mol¯1 and you would say "per
mole" out loud. The question then is WHAT per mole?
The answer is that it depends on the problem. In the first example, I used iron, an element.
Almost all elements come in the form of individual atoms, so the correct numerator with most
elements is "atoms." (The exceptions would be the diatomic elements plus P4 and S8.)
So, doing the calculation and rounding off to three sig figs, we get 2.71 x 1023 atoms. Notice
"atoms" never gets written until the end. It is assumed to be there in the case of elements. If you
wrote Avogadro's Number with the unit atoms/mol in the problem, you would be correct.
The same type of discussion applies to substances which are molecular in nature, such as water.
So the numerator I would use in example #2 is "molecule" and the answer is 1.20 x 1023
molecules.
Once again, the numerator part of Avogadro's Number depends on what is in the problem. Other
possible numerators include "formula units," ions, or electrons. These, of course, are all specific
to a given problem. When a general word is used, the most common one is "entities," as in 6.022
x 1023 entities/mol.
Keep this in mind: the "atoms" or "molecules" part of the unit is often omitted and simply
understood to be present. However, it will often show up in the answer. Like this:
It's not that a mistake was made, it's that the "atoms" part of atoms per mole was simply assumed
to be there.
Example #3: 0.450 gram of Fe contains how many atoms?
Look at the solution steps in the image above and you'll see we have to go from grams (on the
left of the image above) across to the right through moles and then to how many. So, for example
#3, it would be like this:
Step One (grams ---> moles): 0.450 g divided by 55.85 g/mol = 0.0080573 mol
Step Two (moles ---> how many): 0.0080573 mol x 6.022 x 1023 atoms/mol = 4.85 x 1021 atoms
Step Two: 0.01110186 mol times 6.022 x 1023 molecules/mol = 6.68 x 1021 molecules
Solution:
Solution:
0.750 mol times 6.022 x 1023 atoms/mol = 4.52 x 1023 atoms (to three sig figs)
Solution:
Example #9: Which contains more molecules: 10.0 grams of O2 or 50.0 grams of iodine, I2?
Solution:
Basically, this is just two two-step problems in one sentence. Convert each gram value to its
mole equivalent. Then, multiply the mole value by Avogadro's Number. Finally, compare these
last two values and pick the larger value. That is the one with more molecules.
Example #10: 18.0 g of H2O is present. (a) How many oxygen atoms are present? (b) How
many hydrogen atoms are present?
Solution:
(6.02 x 1023 molecules) (2 H atoms / 1 H2O molecule) = 1.20 x 1024 O atoms (to three sig figs)
Notice that there is an additional step (as seen in step 3 for O and step 4 for H). You multiply the
number of molecules times how many of that atom are present in the molecule. In one molecule
of H2O, there are 2 atoms of H and 1 atom of O.
Sometimes, you will be asked for the total atoms present in the sample. Do it this way:
(6.02 x 1023 molecules) (3 atoms/molecule) = 1.81 x 1024 atoms (to three sig figs)
The 3 represents the total atoms in one molecule of water: one O atom and two H atoms.
Solution to (a):
3 y
––––––– = ––––––––––––––––
8 2.96 x 1024 H atoms
3) By the way, the above ratio and proportion can also be written like this:
3 is to 8 as y is to 2.96 x 1024
Be sure you understand that the two different ways to present the ratio and proportion mean the
same thing.
3.70 x 1023 / 6.022 x 1023 mol¯1 = 0.614414 mol <--- I'll keep some guard digits
0.614414 mol times 44.0962 g/mol = 27.1 g (to three sig figs)
Probs 1-10
Avogadro's number is used in chemistry when you need to work with very large numbers. It's the
basis for the mole unit of measurement, which provides an easy way to convert between moles,
mass, and number of molecules. For example, you can use the number to find the number of
water molecules in a single snowflake. (Hint: It''s an enormous number!)
Question: How many H2O molecules are there in a snowflake weighing 1 mg?
Solution
Snowflakes are made of water, or H2O. To obtain the mass of 1 mole of water, look up the
atomic masses for hydrogen and oxygen from the Periodic Table. There are two hydrogen atoms
and one oxygen for every H2O molecule, so the mass of H2O is:
One mole of H2O is 6.022 x 1023 molecules of H2O (Avogadro's number). This relation is then
used to 'convert' a number of H2O molecules to grams by the ratio:
mass of X molecules of H2O / X molecules = mass of a mole of H20 molecules / 6.022 x 1023
molecules
Answer