ChE 123 WFW/WFX

Jan. 19/24, 2017

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 Superheated
vapor

Two-phase
Saturated
region vapor

Saturated
liquid
Subcooled
liquid
x1 y1

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Subcooled
liquid

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Subcooled
liquid

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Saturated
Tb
liquid

y1 = 0.8

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Two-phase region

Tb

x1=0.45 y1=0.75

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Two-phase region

Tb

x1=0.35 y1=0.65

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Two-phase region

Tb

x1=0.25 y1=0.6

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Saturated
Td
vapor

Tb

x1=0.2

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
 Superheated
vapor

Td

Tb

Txy diagram at 1 atm for furan (1)/carbon

tetrachloride (2)
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 Subcooled
liquid

Saturated
liquid Two-phase
Pb
region
Saturated
vapor
Pd
Superheated
vapor

x1 y1

Pxy diagram at 30ᵒC for furan (1)/carbon tetrachloride (2)

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Pxy diagram at 65°C for ethanol(1) / Txy diagram at 1 atm for ethanol(1) /
toluene (2) toluene (2)
Pxy diagram at 30°C for chloroform(1) / Txy diagram at 1 atm for chloroform(1) /
tetrahydrofuran (2) tetrahydrofuran(2)
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 140
130 T-x1
120 T-y1 Txy diagram for 1-
110 chlorobutane(1)/

T, °C
100
chlorobenzene(2) at
90
80 102 kPa.
70
60
0.00 0.20 0.40 0.60 0.80 1.00
x1, y1
x1
y1
1.00

0.80
yx diagram for 1-
0.60 chlorobutane(1)/
y1 chlorobenzene(2) at
0.40
102 kPa.
0.20

0.00
0.00 0.20 0.40 0.60 0.80 1.00
x1
 140
130 T-x1
120 T-y1 Txy diagram for 1-
110 chlorobutane(1)/

T, °C
100
chlorobenzene(2) at
90
80 102 kPa.
70
60
0.00 0.20 0.40 0.60 0.80 1.00
x1, y1
x1
y1
1.00

0.80
yx diagram for 1-
0.60 chlorobutane(1)/
y1 chlorobenzene(2) at
0.40
102 kPa.
0.20

0.00
0.00 0.20 0.40 0.60 0.80 1.00
x1
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37

35 Pxy diagram for

33 benzene(1)/

P, kPa
31 P-x1
P-y1
acetonitrile(2) at
29
45°C
27

25
0 0.2 0.4 0.6 0.8 1
1.00
x1, y1

0.80 yx diagram for

0.60 benzene(1)/
y1
0.40
acetonitrile(2) at
0.20
45°C
0.00
0.00 0.20 0.40 0.60 0.80 1.00
x1
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 2

Single
phase

1
3
Pxy diagram at 30ᵒC for furan (1)/carbon tetrachloride (2)
 Vapor and
liquid at
equilibrium 2

x1 y1
1
Pxy diagram at 30ᵒC for furan (1)/carbon tetrachloride (2)