PAPER Adva PI Sol PDF

1
AITS-CRT-I(Paper-1)-PCM (Sol)-JEE (Adv)/14
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FIITJEE JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
CRT–I
(Paper-1)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. C C D
2. A D A
3. B D B
4. B C A
5. A B B
6. D D A
7. B C C
8. A. C A
9. B B C
10. C B A
11. A, B, C A, C A, B, C
12. A, B, C, D B, C A, B, C, D
13. B, C, D A, C A, D
14. A, B, C A, B, C B, C
15. A, B, C A, C B, C
1. 2 2 4
2. 1 1 2
3. 5 4 6
4. 1 3 2
5. 2 6 3
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website: www.fiitjee.com
2
Physics PART – I
SECTION – A
1. Urel  g  t  10  1
= 10 m/s
1
S1  g(1)  5m
2
1
Srel  S1  ure  are t 2 = 5 + 10  3 + 0 = 35 m
2
h /2
2. sin  =
 /2

mgh =  mg cos (/2)

h  cos 

 2

tan  =
2
3. Centre of mass does not move in the absence of external force so

m1x1 = m2x2
x1 m 2

x 2 m1
dA1 r 2 d r 2
4. A   
dt 2 dt 2
2
L = Mr 
L = 2MA
Gm(M  m)
5. F  0
r2
dF G
 (M  2m)  0
dm r 2
M = 2m
m = (M/2)
Ag
6. s
A
s

g
h
7. ghr 2   (2rdh)gh
0
h2
ghr 2  2rg
2
h
r2
2
r=h
3
(v r t)2  (v mr t)2
8. Avg. speed 3 
t
 v 2r  5  9
 vr  2m / s
1 t 1
 v  v
2 2 2 3v
9. v avg  
t 4
m m
10. gT  a …(i)
2 2
ma
T cos 60 = …(ii)
cos 60
2g
Solving (i) and (ii) acceleration of ring =
9
2kq2 mv 2
11. mg  2
T  …(i)
R R
1 1
mgR + mu2  mgR  mv 2 …(ii)
2 2
2Kq2
if T = 0  umin  5gR 
mR
dU
12. F  5(2x  4)
dx
At mean position F = 0  x = 2m
Umin  20 J
a = 50  2(x  2)
 = 10 rad/sec
T = /5 sec
V
13. If the volume immersed initially is (V/3). Then
g  mg …(i)
3
If the volume immersed when the system accelerates is V then
 g mg V
V '   g    mg   V' 
 2 2 3
14. The potential of the two surface will be equal when the whole charge Q flows from inner to other
shell.
SECTION –C
1. Consideration refraction at glass-water interface
r
 2   2  1 (27r/20)
 
v u R
4 3 ( 4 / 3)  ( 3 / 2)
   (4/5)r
3v  2r r
4
4 3 1
  
3v 2r 6r
r
 v=
5
Now refraction at water air surface
 4  9r
u = - r  r  
 5  5
 2 1  2  1
 
v u 
1 4  5 1  ( 4 / 3)
  
v 3  9r 
1 20

v 27r
27r
v=-
20
27r
so height above centre = 2r -
20
40r  27r 13
= = r = 13 cm.
20 20
2. Mg  T = Ma …(i)
T  mg = ma …(ii)
2Mmg
T=
(M  m)
T 2Mmg 2mg
    2  109 m
A A(M  m)  m
A 1 
 M M
 M = 1.86 Kg
3. Relative motion between block and table 4 cm

2
will start when  m r
m2 r sin   (mg  m 2r cos  ) …(i)
   t …(ii) 3 cm

solving (i) and (ii)
t  500  22.4 sec .
g
4. = = 1 rad/sec
R
5. N1 + N2 = mg . . . (1) N1

N2
N1 = N2 . . . (2)
mg
N2 = N1
1 2 
mg N2
N1 =
1 2  mg
Torque about centre of mass
5
1
(N1 + N2)R = mR2 
2
2 N1  N2  2  1    g
= =
mR 1   2  R
2 = 20  2
20
=
2
20 1  2  R
=
2  2 1    g
Hence number of turns
 02R 1  2 
N= =
2 4 1    g.2
20R 1  2 
N=
8g 1   
Chemistry PART – II
SECTION – A
1. In ‘A’  bond is at bridge head which is not stabilized in the given structure;
CN
In ‘B’ the product is ;
 ACOH
In ‘D’ the product is

2. HO
O N OH
O NH2 OH HO NH
H 2N OH
H2 O




IMPT

 
 
 

N OH2 OH
N N
 H O
H

 
2

 
HO
 
2
H
5. CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.
6. 

PCl5  g 
 PCl3  g   Cl2  g 
Let initially no. of moles x  
at equilibrium  volume V  x 1    x x
6
x 2 2 n
Kc  , also Kp = Kc(RT) g
x 1    V
V
on reducing volume to , initial concentration of PCl5 doubles and its degree of dissociation is
2
increased but Kp does not change, as it is characteristic constant for a reaction at constant
temperature.
7.  2H3  Al  OH 6   6HCl ;
Al2Cl6  12H2 O 
10. In blast furnace,

In combustion zone, CO is produced ultimately which reduce Fe2O3 to Fe3O4 in reduction zone,
which is uppermost zone.
11. O
P=
Q=
O
Oxidation by XO 
R= CH3 COOH  C 2H5 OH ; C2H5 OH   CH3CHO
O
O
S=
12. Due to hydrogen bonding Gauche conformation of H2C CH2 NH2and H C CH2F
2
NH2 OH
are more stable than their anti-conformations.
In case of ClCH2CH2Cl, on increasing temperature, % of Gauche conformation increases. Hence
dipole moment increases. In case of option (D) boat conformation is most stable.
13. Mn appears colourless in reducing flame in Borax Bead Test.

Fe3   K 4 Fe  CN6   Fe 4 Fe  CN 6   K 
3
Prussian blue

Na2 S2O3 .5H2 O   Na2 S5  Na2 SO4  H2 O
14. At pH = pI, amino acid exists as Zwitter Ion, they are highly soluble in polar solvents.
7
15. pH of 10–8 M HCl (aq) is 6.96 and pH of 10–8 M NaOH (aq) is 7.04
SECTION – C
1.  = CRT × i
hence i = 1.1; so  = 0.1
hence [H+] = c = 0.1  0.1 = 10–2 M
pH = 2
2. It has only one CH2OH group.
3. Three equivalents to remove three hydrogens from CH3 group and one for attack on C of CHO
group.
4. BaCrO4 – Yellow, soluble in dil HNO3

Hg2CrO4 – Red, soluble in conc. HNO3
ZnS – White, soluble in Conc. HNO3
BaSO4 – White, insoluble in all mineral acids
BaS2O3, CH3COOAg and AgNO2 all are white solid and are soluble in dilute HNO3 solution.
Cl
5. Except and Cl
Mathematics PART – III
SECTION – A
1. [y + [y]] = 2 cosx  [y] = cosx

1
y = [sinx + [sinx + [sinx]]] = [sinx]
3
 [sinx] = cosx
Number of solution in [0, 2] is 0
Hence total solution is 0.
 both are periodic with period 2
2. (x  0)2 + (y  k)2 = k2
 x2 + (y  k)2 = k2
dy
2x + 2 (y  k) 0
dx
dy x
 
dx y k
xdx
yk=
dy
xdx
k=y+
dy
8
2 2
  xdx    xdx 
 x2 +  y   y    y  
  dy    dy 
2 2
2  dx   dx  2xydx
 x + x    y2  x 2   
2
 dy   dy  dy
2xydx
x 2 = y2 +
dy
dy
(x2 + y2)  2xy  0
dx
3. Given  <  <  <  also sin  = sin  = sin  = sin  = k

and , , ,  are smallest positive angles
  =   ,  = 2 + ,  = 3  
as sin  = sin  and  > 
sin  = sin  and  > 
sin  = sin  and  > 
Putting these values in the given expansion, we have given expression
  
= 2  sin  cos   2 1  sin   2 1  k
 2 2
2
4. x3 – x < – a2 + a –
3 3
f(x) = x3 – x
f(x) = 3x2 – 1 = 0
1
x=
3
1 1 2
In positive region minimum value of f(x) =  
3 3 3 3 3
2 2
So, – a2 + a – >–
3 3 3 3
a2 – a < 0
a  (0, 1)
5. 3x  2  4x  4  5x  1  4x  5 …(1)
v u p q
u2 – v2 = x + 6 = p2 – q2
u–v=p–q …(2)
solving (1) and (2)
we get, 2 4x  4  2 5x  1
x=3
6. Limit be equal to y
   
1
logy = lim log  n  1   log  n  2   ...
n n   n   n  
n n 1
1   n  r   1  r
= lim   log 
n n r 1   n     = lim
n n 
r 1  n  
 log  1     log 1  x  dx
0
9
 1  4
=  . 2 log2   = [log4 – loge] =  log  
 2 e

 4
logy = log  
 e

7. 0  argz  , represent the region of complex plane lying in the first quadrant and bounded by x-
4
axis and the line y = x
|2z – 4i| = 2|z – 2i|
least value of |z – 2i| is length of perpendicular from (0, 2) to y = x, which is 2
So the least value of 2 |2z – 4i| is 4
8. Let f(x) = 2x3+ 3x2 – 12x + 3

 f(x) = 0 has three real roots (, , )
3
++=–
2
Centroid = 
   

,

,
   1 1 1
 =   ,  ,   which lies on x = y = z.
 3 3 3   2 2 2
 
9. If a > b > c and a2 = b = c then b < 1  cot–1x < 1  x > cot1
a
10. a  4sinA  4 R2
sin A
so for any point (x, y) inside the circumcircle, x 2 +y2 < 4
 |xy| < 2
11. a, b and A are given in ABC,

b2  c 2  a2
 cos A =
2bc
 c2  2bc cos A + (b2  a2) = 0
 c2  (2b cos A)c + (b2  a2) = 0
which is quadratic in c and gives two values of c and let these are c1 and c2
 c1 + c2 = 2b cos A
and c1  c2 = (b2  a2)
c12  c 22  2c1c 2 cos2A
= (c1 + c2)2  2c1c2 (1 + cos 2A)
= 4b2 cos2 A  2 (b2  a2) (2 cos2 A)
= 4b2 cos2 A  4b2 cos2 A + 4a2 cos2 A
= 4a2 cos2 A
1 1 1
12.       n terms
2 5 5 8 8  11
5 2 8 5 11  8 5  (n  1)3  2  (n  1)3
=     
3 3 3 3
3n  2  2 3n  2  2 n
=  
3 
3 3n  2  2  3n  2  2
10
n n
=  n
2  3n  2 3n
 2
13. sin 
24 R  2
  
 R  2  1  cosec
 24 
2
  
 sin  cos 
2 2
(A) is true    1  cosec
sin A
(D) is true
14. x2 + x + 1 = |[x]|
Hence only 2 solutions exist
i.e. x = – 1 and another lie – 2 < x < – 1
15. sin x + cos x = 1 – a sin x cos x

 a2 sin2x cos2x – 2(a + 1) sin x cos x = 0
 2 
 sin2x  a sin 2x  2  a  1  = 0
 2 
Hence sin2x = 0  a  R
n
x= ,nI
2
4  a  1
And sin2x =  a  (–, 2 – 2 2 ]  [2 + 2 2 , )
a2
SECTION – C
 
1 1
1. a= r
r 1
2
, b  (2r  1)
r 1
2
1 1 1 1 1 1 1 1
a= 2
 2
 2
 2
 ... and b = 2
 2
 2
  ...
1 2 3 4 1 3 5 72
1 1 1 1   1 1 1 
b =  2  2  2  2  ...    2  2  2  ... 
1 2 3 4  2 4 6 
1 1 1 1  1 1 1 
b =  2  2  2  2  ...   2  1  2  2  ... 
1 2 3 4  2  2 3 
1
b=a a
4
3
b = a
4
a 4

b 3
 
2.  f 1(x)dx  t f (t)dt

0 0
11


=  t f  t  0   t  sin t  dt

0
2

= 2   1 1
2
2
= 2
2
k=2
3. Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers

4
= 3  P4 = 72
Case II: When we use 5 at ten thousand place and 6, 7 or 8 at thousand place then number of
numbers is
= 1  3  3P3 = 18
hence the required numbers of numbers is 72 + 18 = 90
4. f(x) is an odd function

 g(x) is f –1(x)
2 2
 Area =  f 1  y  dy   x f   x  dx
0 0
 2 
2
= x  f  x  0   x  sin x  dx  = 22



0


 2  2  2      
5. a  b  b  c  c  a = 2  a2  b2  c 2   2  a  b  b  c  c  a 
     
= 2(4 + 9 + 16) – 2  a  b  b  c  c  a 
     
= 58 – 2  a  b  b  c  c  a  .
   2
Now  a  b  c   0
     
 a2 + b2 + c2  – 2  a  b  b  c  c  a 
     
 – 2  a  b  b  c  c  a   29
 2  2  2
 a  b  b  c  c  a  87

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AITS-CRT-I(Paper-1)-PCM (Sol)-JEE (Adv)/14

Q. No. PHYSICS CHEMISTRY MATHEMATICS

3. Centre of mass does not move in the absence of external force so

3. Relative motion between block and table 4 cm

5. N1 + N2 = mg . . . (1) N1

Torque about centre of mass

In ‘D’ the product is

5. CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.

10. In blast furnace,

are more stable than their anti-conformations.

In case of ClCH2CH2Cl, on increasing temperature, % of Gauche conformation increases. Hence

13. Mn appears colourless in reducing flame in Borax Bead Test.

2. It has only one CH2OH group.

4. BaCrO4 – Yellow, soluble in dil HNO3

Mathematics PART – III

1. [y + [y]] = 2 cosx  [y] = cosx

3. Given  <  <  <  also sin  = sin  = sin  = sin  = k

8. Let f(x) = 2x3+ 3x2 – 12x + 3

9. If a > b > c and a2 = b = c then b < 1  cot–1x < 1  x > cot1

11. a, b and A are given in ABC,

15. sin x + cos x = 1 – a sin x cos x

3. Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers

4. f(x) is an odd function

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