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Question 1

A mole of He (g) is maintained in a 10 L container at 298K. If the gas is compressed


at constant temperature to a volume of 5.0 L, which of the following would be
expected to change?

the average number of molecule-wall collisions per unit area per


a.
unit time

b
the average molecular translational kinetic energy
.

c. the average molecular weight 

d
the average molecular speed 
.

e. the average momentum change per molecule-wall collision

1 points  

Question 2

Real gases will behave most ideally

a. high P and T

b
low P and T
.

high P  and low


c.
T

d low P and high


. T

1 points  

Question 3

Which of the following gases is expected to have the smallest value for its van der
Waals       constant “a”?
a. N2

b
O2
.

H2
c.
O

d
Ne
.

1 points  

Question 4

An open-tube manometer is used to measure the pressure in flask.  The


atmospheric pressure is 756 torr and the Hg column is 10.5 cm higher on the open
end.  What is the pressure in the flask ?

a. 861 torr

b
649 torr
.

c. 861 cm Hg

d 766.5
. mmHg

1 points  

Question 5

Absolute zero is the temperature at which

a. a graph of V versus 1/P intersects the 1/P-axis

b the straight line graph of V versus T intersects the


. T-axis

c. gaseous helium liquefies.

d a graph of P versus 1/V intersects the 1/V-axis


.

1 points  

Question 6

Which of the following statements about the Ideal Gas Law and the van der Waals
equation of state is false?

The van der Waals equation of state is more descriptive for real
a.
gases.

b
The van der Waals equation corrects for the volume of molecules
.

At a given T and V, one mole of Ne and CH4 have the same pressure
c.
according to the Ideal Gas Law

d
The van der Waals equation corrects for the value of “R”.
.

1 points  

Question 7

A gaseous mixture contains equal numbers of HCl and HBr molecules and no other
kind of molecules. Which one of the following statements is true? Assume ideal gas
behavior for both HCl and HBr.

a. The masses of HCl and HBr are equal.

b
The partial pressures of HCl and HBr are equal.
.

If the temperature is increased while the volume is held constant, the


c. partial                   pressure of HBr will rise more rapidly than the
partial pressure of HCl.

Since HCl molecules are lighter, they have higher velocities, collide
d with each                   other and with the walls of the container more
. frequently, and therefore contribute             more to the total pressure
of the mixture than do HBr molecules.

1 points  
Question 8

Which gas would be expected to behave most ideally?

a. F2

b PCl
. 3

c. N2

d
Ne
.

1 points  

Question 9

At 150.°C and 1.00 atm, 500. mL of a vapor has a mass of 0.4183 g. What is the      
molecular weight of the compound ?

58.0
a.
g/mol     

b 65.0
. g/mol     

c. 29.1 g/mol

d
62.0 g/mol
.

1 points  

Question 10

Which is an intensive property ?

melting
a.
point

b pressure
.

c. volume

d
mass     
.

1 points  

Question 11

Consider a sample of oxygen gas at 800K. The Maxwell-Boltzmann distribution tells


us that

a. molecules may have speeds ranging from zero to very large values.

b the average molecular speed is directly proportional to absolute


. temperature.

c. all of the molecules have the same translational kinetic energy.

d
all of the molecules have the same molecular speed.
.

average translational kinetic energy is directly proportional to the


e.
square of absolute temperature

1 points  

Question 12

A sample of oxygen occupies 47.2 liters under a pressure of 1240. torr at 25°C. By
what       percent does the volume of this sample change if the pressure were
decreased to 730. torr
at 25°C

a. 43.4%

b
69.9%
.

c. 46.1%
41.1%    
d.
 

1 points  

Question 13

A mixture of 0.75 mol H 2 (g) and 0.75 mol N 2 (g) is introduced into a 15.0-liter
container       having a pinhole leak at 30°C. After a period of time which of the
following is true?

a. The partial pressure of H2 exceeds that of N2 in the container

b
The partial pressure of N2 exceeds that of H2 in the container.
.

The partial pressures of both gases increase above their initial


c.
values

d
The partial pressures of the two gases remain equal.
.

1 points  

Question 14

Which of the following statements is false? An increase in temperature will

a. increase the velocity of the gas molecules

b
increase the number of collisions per second
.

increase the average kinetic energy of the


c.
molecules

d
increase the molecular weight of the gas
.

1 points  

Question 15

 
A sample of oxygen collected over water at 32.0°C and 752 torr has a volume of
0.627 liters. What volume would the dry oxygen occupy under standard conditions?
The vapor pressure of water at 32.0°C is 35.7 torr

0.556
a.
L

b 0.609
. L

0.644
c.
L

d 0.529
. L

1 points  

Question 16

At lower temperature, Maxwell Boltzmann distribution curve

a. becomes steeper

b has a higher temperature


. range

c. becomes broader

d
All
.

1 points  

Question 17

A sample of helium occupies 5.00 L at STP. What volume will the sample occupy at
0.0°C and 890. torr ?

4.06
a.
L     

b
4.27 L
.
3.56
c.
L     

d
3.72 L
.

1 points  

Question 18

Repulsive forces in gas molecules  predominate at

a. low temperature

b intermediate
. pressure

c. high pressure

d
high temperature
.

1 points  

Question 19

A 10.0-liter vessel contains gas A at a pressure of 300. torr. A 3.0-liter vessel


contains gas       B at a pressure of 400. torr. Gas A is forced into the second vessel.
Calculate the resulting       pressure in torr. Assume temperature remains

1400
a.
torr

b 1000
. torr

1800
c.
torr

d 2000
. torr

1 points  

Question 20
 

Nitric oxide, NO reacts with O2 to produce NO2 according to the equation 2NO (g) +
O2 (g) ==> 2NO2 (g). If complete reaction of a sample of NO consumes 6.0 liters of
O2 (g), what volume of NO2 (g) is produced? All gases are measured at the same
temperature and pressure. 

12
a.
L

b
3L
.

c. 6 L

d 24
. L

1 points  

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