ANEES HUSSAIN

EXCELLENCE IN EDUCATION SINCE 1989

CH # 4: GASES
1. Gases deviate from ideal behavior at high pressure. Which of the following is correct for non-
ideality?
a. At high pressure, the collision between the gas molecules becomes enormous
b. At high pressure, the gas molecules move only in one direction
c. At high pressure, the volume of gas becomes insignificant
d. At high pressure, the intermolecular interaction become significant
2. The Vander Waal’s equation for real gas is?
a a
a. (P + v2) (V – b) = RT b. (P + v2) (V + b) = nRT
an2 nRT an2
c. (P + ) (b + nV) = nRT d. P = +
v2 V−nb v2
3. The value of compressibility factor for an ideal gas is:
a. Zero c. Unity
b. Fraction d. None of given
4. Which gas is likely to be the most ideal?
a. H2S c. CH4
b. NH3 d. Ne
5. All statements are correct except:
a. At high pressure and low temperature gases behave non-ideally
b. All the gas laws have no significance for real gases
c. Any gas can never be 100% ideal
d. The value of compressibility factor is changed by changing pressure and temperature for an
ideal gas
6. Gases behaves like ideal at
a. Low heat c. High pressure
b. High temperature d. Low temperature
7. Van der Waal’s real gas, act as an ideal gas, at which condition?
a. High temperature, low pressure c. High temperature, high pressure
b. Low temperature, high pressure d. Low temperature, low pressure
8. The compressibility factor for an ideal gas is:
a. 1 c. 4
b. 2 d. 0
9. The term that accounts for intermolecular force in van der Waal’s equation for an ideal gas
is:
a. RT c. (P + 𝛼/ V2)
b. V – b d. (RT)-1
10. If increases in temperature and volume of an ideal gas is two times, then the initial pressure
P changes to:
a. 4P c. P
b. 2P d. 3P

Department of Chemistry:
Sir Asif Izhar Sir Faizan Siddiqui Sir Anas Soorti Sir Naveed Hassan
Sir Fahad Khan Sir Muhammad Talha Sir Saif Ur Rahman
 ANEES HUSSAIN
EXCELLENCE IN EDUCATION SINCE 1989
11. Under what conditions of temperature and pressurewill a real gas behave like an ideal
gas?
Temperature Pressure
a. Low Low
b. Low High
c. High High
d. High Low
12. Which one of the following gases shows more non-ideal behavior?
a. O2 c. CO2
b. N2 d. H2
13. Which one of the following relationship is correct regarding van der waal’s gas equation?
a. aNH > aN but bNH < bN c. aNH < aN but bNH > bN
3 2 3 2 3 2 3 2
b. aNH < aN but bNH < bN d. aNH > aN but bN < bNH
3 2 3 2 3 2 2 3
14. Which of the following is the main causes of deviation ofreal gases from ideal behavior?
a. No force of attraction among the gas molecules
b. The actual volume of gas molecules is negligible ascompared to volume of the vessel
c. A gas cannot be liquefied
d. Both A and B
15. Which of the following gas would behave most like an ideal gas at room temperature?
a. CO2 c. H2
b. He d. N2
16. The compressibility factor, Z i.e. the extent to which a real gas deviated from ideal behavior
is given by (for one mole).
PV PV
a. Z= RT2 c. Z= RT
RT PT
b. Z= PV d. Z= RV
17. “a” is called co-efficient of attraction in Van der Waal’s equation for real gases the unit of
“a” is:
a. Nm-4mol-2 c. Nm+4mol-2
b. Nm+6mol-2 d. Nm+2mol-2
18. Very small values of Van der Waal’s constant in his equation for a particular gas show that:
a. The molecules of the gas are big sized
b. Gas is sufficiently polar
c. Least attractive forces are present among the molecules of the gas
d. The gases are non-ideal
19. Excluded volume is ________ times the actual volume of gas molecules.
a. Two c. Four
b. Three d. Eight
20. The constant ‘a’ in Van der Waal’s equation is maximum for:
a. Helium c. Oxygen
b. Hydrogen d. Ammonia

Department of Chemistry:
Sir Asif Izhar Sir Faizan Siddiqui Sir Anas Soorti Sir Naveed Hassan
Sir Fahad Khan Sir Muhammad Talha Sir Saif Ur Rahman
 ANEES HUSSAIN
EXCELLENCE IN EDUCATION SINCE 1989
21. There are four gases H2, He, N2 and CO2 at 0˚C. Which gas shown greater non-ideal
behavior?He
a. H2
b. CO2
22. N2Which gas is likely to deviate most from ideal gas behavior?
a. HCI d. N2
b. He e. O
c. CH4
BOOK LINES
23. Which statement is true regarding states of matter
a. Plasma is not a state of matter
b. There are only three states of matter
c. Liquids are more common than solids
d. Liquid state of any substance can exist only within a narrow range of temperature and pressure
24. Joule Thomson effect is defined as:
a. Cooling happens when contraction of gas takes place
b. Cooling happens when expansion of gas takes place
c. Heating happens when expansion of gas takes place
d. Heating happens when contraction of gas takes place
25. Gases bubbles through liquids because
a. Gases have low densities
b. Gases are more common than liquids
c. Gases take up the volume of the whole container
d. Gases experience Joule - Thomson effect
26. A gas at zero Kelvin:
a. Is super cooled c. Liquefies
b. Freezes d. Vanishes
27. Which of the following is not associated with general gas equation?
a. PV/T = R (for 1 mole) c. PV= (m/M) RT
b. d=PM/RT d. R = nT/PV
28. The vapour pressure of water at 100°C is:
a. 760 torr c. 76 torr
b. 760 atm d. 76 atm
29. In S.I. system, the unit of pressure is:
a. Kg/ms2 c. Kg/m
b. Kg/ms d. Kg/m2.s
30. The volume of gas would theoretically be zero at:
a. O°C c. 273K
b. OK d. 273°C
31. The value of R (Gas constant), when pressure is expressed in N/m2 (Newton per square metre) is:
a. 0.0821 dm3 Atmosphere c. 8.213 dm3 Atmosphere K-1 mole-1
-1 -1
b. 8.3143 J.K mole d. 9.8 joule K-1 mole-1

Department of Chemistry:
Sir Asif Izhar Sir Faizan Siddiqui Sir Anas Soorti Sir Naveed Hassan
Sir Fahad Khan Sir Muhammad Talha Sir Saif Ur Rahman
 ANEES HUSSAIN
EXCELLENCE IN EDUCATION SINCE 1989
32. If absolute temperature is doubled and pressure increased to 4 times, the volume:
a. is halved c. Becomes four times
b. is doubled d. Remains unchanged
23
33. At STP, the volume of 3.01 X 10 molecules of H2 gas is:The rate of diffusion of CO2 is equal
to that of:Ammonia gas diffuses Faster than
a. He gas c. CO2 gas
b. Propane gas d. Both b & cgases
34. Oxygen gas diffuse faster than
a. H2 c. CO2
b. NH3 d. CH4
35. When external pressure is lowered, water boils at
a. Same c. Lower
b. Higher d. None
36. The volume of gas would theoretically be zero at:
a. 0°C c. 0K
b. 0°F d. -200°C
37. Which of the following is representation of Boyle’s law
a. P α 1/V c. Vα T
b. V α P d. P α 1/T
38. Which of the following is known as standard temperature and pressure (STP)
a. 0 K and 1 atm c. 0°F and 760 atm
b. 0°C and 760 torr d. 273 K & 25 atm
39. Which of the following is the lowest possible temperature
a. 0 K c. 0°F
b. 0°C d. -273 K
40. Absolute zero temperature regarded as that temperature at which
a. All gases becomes liquid c. Molecular motion in a gas would cense
b. All substance are solids d. Water freezes
41. By which process does the smell of the cooked food spread in the surrounding?
a. Distillation c. Diffusion
b. Condensation d. Evaporation
42. An ideal gas obeys gas laws under:
a. High temperature and high pressure c. High temperature and low pressure
b. Low temperature and high pressure d. All temperature and pressure
43. Equal volume of two gases under the same temperature and pressure contain the same
number of
a. Molecules c. Electron
b. Ions d. Protons
44. Density of a gas may be express by:
a. PM/RT c. V/M
b. M/V d. nPM/RT

Department of Chemistry:
Sir Asif Izhar Sir Faizan Siddiqui Sir Anas Soorti Sir Naveed Hassan
Sir Fahad Khan Sir Muhammad Talha Sir Saif Ur Rahman
 ANEES HUSSAIN
EXCELLENCE IN EDUCATION SINCE 1989
45. The rate of diffusion of a gas is inversely proportional to the square root of its molar mass or
density is thestatement of Law
a. Dalton’s c. Rutherford
b. Graham’s d. Avogadro’s
46. Lighter gasses diffuse than heavier gasses
a. Faster c. Same rate
b. Slower d. None
47. At boiling point vapour pressure of a liquid is equal to
a. Liquid pressure c. Internal pressure
b. Atmospheric pressure
48. 22.4 dm3 volume of a gas STP is called
a. Gaseous volume c. Fixed volume
b. Molar volume
49. According to law, volume of a gas is inversely proportional to the pressure at constant
temperature
a. Graham’s c. Charles
b. Boyle’s d. Dalton’s
50. law established a relationship between volume and temperature
a. Graham’s c. Charles
b. Boyle’s d. Dalton’s
51. Oxygen takes time to diffuse than helium
a. More c. Same
b. Less d. None

Department of Chemistry:
Sir Asif Izhar Sir Faizan Siddiqui Sir Anas Soorti Sir Naveed Hassan
Sir Fahad Khan Sir Muhammad Talha Sir Saif Ur Rahman