Professional Documents
Culture Documents
SECTION -A
1. (a) Water has the highest density at 4°C temperature. How does this unusual behavior
impact the phase diagram of water? What happens to the phase diagram when you add a
small amount of glucose to pure water? Draw the diagram and ~xplain this effect. (3+3+4=10)
(b) Pure 2-methyl-2-propanol has a freezing point of 25.50°C, however it absorbs water
(as an impurity) on exposure to humid air, If the freezing point of a 100.0 g sample of
2-methyl-2-propanol is 24.59°C, how many grams of water are present in the sample? (8)
(c) Osmotic pressure is a colligative property that can be used to determine the molar
mass of an unknown substance .. The osmotic pressure is determined by measuring 'the
height of the column of solution and converting this value to mm of Hg (1 mm Hg.= I
torr, 760 torr = I atm). Using the concept of osmotic pressure, calculate the molar mass
of insulin if 20.0 mg is dissolved in 10.0 mL of solution to give a resulting osmotic
(d) Calculate the van't Hoff factor (i) for HF if the freezing point of a 0.50 m aqueous
2. (a) Acetic acid is a weak electrolyte and hydrochloric acid is a strong electrolyte. Briefly
describe the electrolytic properties of the equimolar solution of these two electrolytes
with appropriate plots. How can you determine the limiting values of the molar
(b) Using Table 2 provided in the Appendix calculate the limiting molar conductivity of
hydrochloric acid and acetic acid. If the molar conductivity of 0.00241 M acetic acid is
7.896 x 10-5 S cm -1. Calculate the degree of deprotonation and the dissociation constant
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CHEM lOl/EEE
eoutd ... Q. No.2
(c) The boiling point and freezing point of sulfur dioxide are 210°C and 272.7°C (at 1
atm), respectively. The triple point is 275.5°C and 1.65 x 10-3 atm, and its critical point is
at 157°C and 78 atm. On the basis of this infonnation, draw a rough sketch of the phase
diagram of S02 and indicate the degrees of freedom at each equilibrium and regions. (9)
(d) Vapor pressures of liquids depend on the temperature. Estimate the molar heat of
vaporization of a liquid whose vapor pressure doubles when the temperature is raised
3. (a) For the reaction X2 + y + Z ~ XY + XZ, it is found that doubling the concentration
of X2, doubles the reaction rate, tripling the concentration of Y triples the rate, and
(ii) Why is it that the change in the concentration of Z has no effect on the rate?
(iii) Suggest a mechanism for the reaction that is consistent with the rate law.
(b) The decomposition of dinitrogen pentoxide has been studied in carbon tetrachloride
Determine graphically the rate law for the reaction and calculate the rates constant.
(c) At the start of a reaction, there are 0.351 mol N2, 3.67 x 10-2 mol H2 and 7.51 x 10-4
mol NH3 in a 3.75-L reaction vessel at 375°C. If the equilibrium constant (Ke) for the
reaction N2(g) + 3 H2(g) <=> 2NH3(g) is 1.2 at this temperature, decide whether the
system is at equilibrium. If is not, predict which way the net reaction will proceed to
(d) The pressure of the reacting mixture CaC03(s) <=> CaO(s) + C02(g) at equilibrium is
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CHEM lOl/EEE
4. (a) The most familiar example of corrosion is the formation of rust on iron. Oxygen gas
(i) Write down the main half reactions and. the overall redox reaction involved in this
process. Determine the standard emf for this process.
(ii) Similarly write down the reactions involved in hydrogen-oxygen fuel cell and
obtain the standard emf.
(iii) Compare the effect of temperature on the emf of these two cells when the
temperature (T) is doubled, Given that all other parameters remain same.
(b) What is the emf of a galvanic cell consisting of a Cdz+/Cd half-cell and a Pt/H+/Hz
half-cell if [Cdz+] = 0.20 M, [H+] = 0.16 M, and PHZ = 0.80 atm? Would you be able to
construct a pH-meter using these two electrodes? Explain your answer illustrating the
(d) Calculate the standard enthalpy of formation of carbon disulfide (CSz) from its
SECTION -B
5. (a) Give two pieces of evidence for the wave model and two for the particle model of
light. (8)
(b) What new idea about light did Einstein use to explain the photoelectric effect? Why
does the photoelectric effect exhibit a threshold frequency but not a time lag? (2+5=7)
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CHEM lOl/EEE
.
Contd ... Q. No.5
(d) A sodium flame has a characteristic yellow color due to emission of wavelength 589
nm. What is the mass equivalence of one photon with this wavelength (l J = 1 kg.m2/s2
(e) Explain what it means for the peak in the radial probability distribution plot for the
6. (a) How many electrons in a single atom can have the following two quantum numbers:
(b) Consider both the filled unfilled and unfilled orbitals of element X. Determine the
nuniber of (i) total nodes in a 3d orbital (ii) angular nodes in the 4py orbital
(c) Define iso-electronic species. Explain why the anions are larger than the cation.
Arrange the following species as iso-electronic pairs with electron configurations: 0+, Ar,
(2+2+8=12)
(d) Define effective nuclear charge Zeff Sketch the outline of the periodic table and
(e) Comment on the following observations: (i) First ionization energy of 'N' is more
than '0' (ii) Electron affinities of Noble gases are positive but for 'Be' is almost zero. (2+2=4)
7. (a) Write Lewis structures for the following species, including all resonance forms, show
formal charges, name the geometry around the central atom: (i) S02 (ii) OCN- (iii) NNO
(b) Draw shapes of H20, SF4, XeF4 and CO2 molecule showing hybridization, all bonding
(c) Sketch the shapes of the following molecular orbitals: (i) GIs; Gls* and (ii) 7t2p;7t2p*' (4)
Contd PIS
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=5=
CHEM lOl/EEE
(b) Draw molecular orbital diagram for N2 + molecule. Write the valence electron
configuration of this molecule and compare it's bond energy and bond length with N2
molecule. (8)
(ii) What are the strongest acid and base that can exist in NH3(l)?
(d) What will be the ratio of H2C03 and HC03- needed to maintain the blood pH 7.4.
(e) Explain why (i) aqueous solutions of metal ions are acidic (ii) aluminum hydroxide
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SECTION-A
1. (a) Find the differential equation satisfied by all central conics whose principal axes
(i) dy = x- y-2
dx x+y+6
(ii) (t - x2 ): + xy = xy2
2. (a) Is the differential equation y(2xy + l)dx + x(l + 2xy - x3 i}ty =0 exact? If not then
2
(b) Solve the differential equation d ;; - 6 dy + 9y = x2e3x cos2x. (12)
dx dx
(c) Solve the initial value problem (D3._ 6D2 + 9D)y = 0, y(O) = 0, y,(O) = 2, y"(O) = -6. (12)
.3. (a) According to the Newton's law of cooling, the rate at which a substance cools in
moving air is proportional to the difference between the temperature of the substance and that
of the air. If the temperature of the. air is 300 K and the substance cools from 370 K to 340 K
2 1 = x2
(b) Reduce the differential equation ~ + 2)2 D + 3(3x + 2)D - 36 JY
r(3x +x into
d2
--f+
dx
y=tanx
(12)
Contd P/2
:j
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,:
MATH 257(EEE)
(b) A particle starts from rest, at a distance 10 cm from a fixed point P. It moves along a
horizontal straight line towards P under the influence of an attractive force at P. This force at
any time varies as the distance of the particle from P. The acceleration of the particle is 9
cm/s2 directed towards P. Wh~n the particle is 1 cm from P, describe the motion. (12)
(12)
SECTION-B
(b) Form the partial differential equation by eliminating arbitrary constants a, b, c from the
2 2 2
equation of ellipsoid .;-
abc
+~ +;.. = 1 (10)
6. (a) Find the integral surface of the equation 2y(z - 3)p + (2x - z)q = y(2x - 3) which
contains the circle z = 0, x2 + y2 = 2x . (12)
(b) Find the complete and singular integral of the equation (p2 + q2 ~ = pz. (12)
(11)
(12)
8. (a) Solve the following liner PDE: (x2 D; + 2xyDxDy - xDx ~ = x3 y4. (15)
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MATH 257(EEE}
(b) The vibrations of a violin string are governed by the following boundary value problem
u(o,t) = u(lZ",t)= 0
SECTION-A
1. (a) Determine an expression for ic(t) valid for t>O in the circuit of Figure for Q.
(b) In the circuit of Figure For Q. l(b) find the value of X that will transfer maximum
2. (a) Obtain vet) and i(t) for the circuit of Figure for Q. 2(a). (18)
(b) The full wave rectified sinuloidal voltage in Figure for Q. 2(b) (i) is applied to
the lowpass filter in Figure for Q. 2(b )(ii), Obtain the output voltage vo(t) of the
filter. The Fourier series for the full-wave rectified voltage waveform is (17)
2400
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L
n-l
1
2
4n -1
cos(2nt)
3. (a) In the circuit of Figure for Q. 3(a), with R1 = R2 = 5 n, C = 500 ~F and Vs = 100fi
(b) For the magnetic circuit in Figure for Q. 4(b), if <Pg = 80~Wb, find 1. Use the B-H
Contd P/2
"
=2=
EEE 105
SECTION-B
5. (a) The two wattmeter method gives PI = 1300 W and P2 = -400 W for a three phase
motor running on a 220 V line. Assume that the motor is wye-connected and that it draws
a line current of 6 A. Calculate the power factor of the motor and its phase impedance. (17)
(b) A store contains three balanced three-phase loads. The three loads are: (18)
The line voltage at the loads is 220 V at 60 Hz, and the line impedance is (0.4 +jO.8) Q
per phase. Determine the line currents and the complex power delivered to the loads.
6. (a) The source in Fig. for Q. No. 6(a) is balanced and exhibits abc phase sequence.
(b) Sketch the straight-line approximation for the transfer function (18)
7. (a) Consider the circuit shown in Fig. for Q. No. 7(a). (18)
(b) Draw the equivalent parallel circuit for the circuit shown in Fig. for Q. No. 7(b).
Contd P/3
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EEE 105
8. (a) Design a series RLC type bandpass filter with cutoff frequencies of 10 kHz and 11
(b) Find the bandwidth and center frequency of the bandstop filter of Fig. for Q. No. 8(b). (18)
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L-l/T -2/EEE Date: 28/02/2018
BANGLADESH UNIVERSITY OF ENGINEERING AND TECHNOLOGY, DHAKA
SECTION-A
1. (a) What are the assumptions of a perfectly competitive market? Explain them. (10)
(b) Explain the short run equilibrium of a firm under perfect competition. Graphically explain
(c) From the following revenue and cost functions, calculate profit maximization level of
R = 1200Q - 2Q2
2. (a) Why is there no unique supply curve for the monopolist derived from his marginal cost
curve? (10)
(b) What are the relation among marginal revenue (MR), price (P) and price elasticity of
demand (e) of a firm under monopoly? (10)
(c) Explain the long run equilibrium of a firm under monopoly which is operating with a
suboptimal plant and excess capacity. What will happen if its plant is larger than the optimal
and is being over utilized? How the monopolist will use its full capacity? (15)
3. (a) What is GDP? Discuss problems with GDP measurement for developing economies.. (10)
(c) What is recession? Why does recession happen? What happens in recession? (10)
(d) What do you mean by demand-pull inflation and cost-push inflation? Explain. (8)
Contd P12
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HUM 277/EEE
4. (a) Complete the following table and sketch the graph explaining the relations among the
various short run cost curves. (15)
(c) How would you derive the long run average cost (LAC) curve of a firm from its short run
average cost curves? Explain graphically. (10)
SECTION -B
5. (a) Briefly describe the basic economic problems that every economy has to face. How are
(b) Illustrate the law of diminishing marginal utility with numerical and graphical
presentations. How the demand curve of the consumer is derived using the law. Explain the
condition for consumer equilibrium for a single commodity under the cardinal approach to
6. (a) What is a market supply curve? Describe the factors that determine supply of electricity
in Bangladesh. (15)
(b) The demand and supply functions of Supreme ball pen are given respectively
Find the equilibrium price and quantity of Supreme ball pen. If 33% supplementary tax is
imposed on unit price, what would be the new equilibrium price and quantity? What is the
proportion of this tax that the consumers are likely to bear? What would happen if a subsidy
Contd P/3
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HUM 277&EE)
7. (a) Define Gross Domestic Product (GDP). Discuss various methods of calculating GDP with
examples. (15)
(b) Distinguish between Consumer Price Index (CPI) and deflator. Consider that a basket
contains 20 Kg rice and lO Kg wheat. Prices of these goods at different periods are as
follows: (20)
Year Price
Rice Wheat
2002 $1.0 $1.5
2003 $1.1 $1.5
2004 $1.2 $1.6
Using 2002 as base year, find inflation rate for each period with respect to the preceding
year.
(b) Marginal rate of substitution (MRS) and its relationship with marginal utility
SECTION-A
(b) 'Sociology is a categorical discipline not a normative discipline' -explain this highlighting
(b) Define family. Briefly explain different types of family system in human society. (10)
(c) What is human migration? Explain the causes and effects of urban-sub urban migration. (15) .
(b) 'Culture is a normative system ofa society' - critically discuss with relevant examples. (18)
,
4. i'Write short notes of any three of the following: (35)
Contd P/2
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HUM 127/EEE
SECTION-B
5. (a) What do you mean by natural green-house and man-made green house? (8)
(b) Define environment. Briefly discuss the types of environment with examples. (8)
(c) How can we save the environment and make it greener? (9)
(d) What is meant by pollution? Discuss the different types of pollution with examples. (10)
6.. (a) What are the major advantages and disadvantages of globalization? (15)
(b) What function do mass media perform in an individual's life in our society? (10)
7. (a) Define juvenile delinquency. Discuss the factors affecting juvenile delinquency in a
society. (10)
(c) Write down the characteristics of pre-industrial societies, industrial societies and post-
Sub: PRY 165 (Electricity and Magnetism, M~dem Physics and Mechanics)
SECTION-A
1. (a) What were the difficulties in physics which led to the concept of the relativity theory? (6)
(b) Describe the Michelson-Morley experiment. Why is the result of this experiment
(c) A meter stick is held at 45° with the direction of motion in a system moving with a
velocity 0.8c (where c = 3.0 x 108ms.I). What are its length and orientation measured in
(b) Describe Compton's experiment and obtain an expression for the' Compton Shift
(c) A ray of ultraviolet light of wave length 300 nm falling on the surface of a material,
whose work function is 2.28 eV, ejects an electron. What will be the velocity of the
3. (a) What are soft and hard x-rays? Explain Bragg theory of diffraction of x-rays by
crystals. (10)
(b) Describe with neat diagrams, the experiment of Davison and Germer on the
diffraction of electrons. How do they establish the wave nature of matter? (20)
(c) Calculate the wavelength of x-rays if the glancing angle for the second order
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=2=
PRY 165/EEE
4. (a) Discuss charge and matter in terms of law of conservation. Distinguish electrostatic
~ ~
force F , electric field E and electric potential V. (10)
(b) An electric quadrapole is an assembly of two dipoles as shown in the figure 4(b).
Show that the value ofE on the axis of the quadrapole for point P distant r from its center
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(c) A cube of edge 'a' carries a point charge q at each corner. Show that the magnitude of
. . Q26~2
the resultant force on anyone of the charges is F = 2 (10)
Boa
~
Show the direction of F relative to the cube edges.
Contd P/3
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PHY 165/EEE
SECTION-B
5. (a) Discuss quantization and conservation of electric charge. Write down Coulombs law
in its vector form. Distinguish Coulomb force, nuclear force and gravitational force. (10)
~
(b) Define electric field E and the electric potential V. How are these two electrical
parameters related? Fig. 5(b) shows a circular plastic disk of radius R with a uniform
surface charge density cr. Derive an expression for potential V(z) at any point P on the
central axis. (15)
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(c) The potential at the center of the disk shown in Fig. 5(b) is Vo = 550 Volt. The radius
R of the disk is 3.50 cm (i) calculate the total charge q on the disk) (ii) what is the
potential at a point on the axis of the disk at a distance z = 5 R from the center of the
disk? (10)
6. (a) Write down Gauss's law and apply this law to a parallel plate capacitor filled with a
a distance R from the center of the strip at right angles to the strip. (15)
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Contd P/4
=4=
PHY 165/EEE
Contd ... Q. No.6
7. (a) What do you mean by wave function? Write down the properties of wave function. (7)
(b) State and prove Ehrenfest theorem. Briefly explain the physical significance of
(c) Consider the Gaussian distribution p(x) = Ae -A,(x-a)2 where A, a, and A, 'are constants. (10)
(i) Use the normalization condition and find out the values of A.
(b) Consider that an electron having mass m is trapped inside an infinite square well
ad
potential defined by V(x) = o ' --<x<-
2- 2 (18)
{ 00, otherwise
Use time dependent Schrodinger equation to find out the normalized wave function for
the electron.
(c) Find the expectation value of kinetic energy for the third (3rd) stationary state of an
electron trapped inside the infinite square well potential mentioned in question 8(b). (10)