Given:

UREA : 82.4 g

60.06 g/mol

H2O: 212 ml

Temp. 35 degree celcius

Vapor pressure of pure solvent 42.18 mmhg

Formula:

Vapor pressure of solution = molar fraction of solvent X vapor pressure of pure solvent

Mole of Urea= 82.4 g X 1mol/ 60.06g = 1.37 mol

Mole of H2O= 212 ml X 1mol/18.016 ml = 11.77 mole

Molar fraction H2O= 11.77 mole/ 11.77 mole + 1.37 mole

Molar Fraction of H2O= 0.90

Raoult’s Law= 0.90 X 42.28 mmHg = 37.96 mmHg

Vapor pressure of solution = 37.96 mmHg

A 202 mL benzene solution containing 2.47g of an organic polymer has an

osmotic pressure of 8.63mmHg at 21 degree Celcius. Calculate the molar mass
of the polymer.

Given:

Benzene solution = 202ml

Organic polymer= 2.47 g

Temp= 21 degree celcius +273= 294 K

Osmotic pressure= 8.63 mmhg

Convert mmHG to atm= 8.63/760= 0.0114 atm

p = 8.63 /760=0.0114 atm  

T = 21 + 273 =294 K  

Osmotic pressure = CRT  

0.0114 = C x 0.08206 x 294  

C = molar concentration of the solution = 0.000473 M  

moles polymer = 0.000473 M x 0.202 L=0.0000955  moles

molar mass = 2.47 g / 0.0000955 mol=2.59 x 10^4 g/mol