Aits 1920 PT Iii Jeem Sol PDF

FIITJEE
ALL INDIA TEST SERIES

PART TEST – III
JEE (Main)-2020
TEST DATE: 08-12-2019
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. D
Sol. Using Snell’s law:
R i
sini   i = 30 R
2R
sin i =  sin r
1 r
sinr 
2 2
2. C
10  0.7
Sol.  4.65 k
2  10 3
3. D
2Ids sin2 
Sol. F  c
sin  (90)
(90)

 
2Isin2  2Isin2  L
= 
c 
sin  ds 
c
RL sin 
IR2
 (1  cos 2)
c
R
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AITS-PT-III-PCM(Sol.)-JEE(Main)/20 2
4. A
Sol. y(x, t = t0) = A cos kx
 y(x, t) = A cos k[x + v(t  t0)]
y(x, t) = A cos [kx + t  t0)]
at t = 2t0
y(x, t = 2t0) = A cos [kx + t 0)]
y(x, t = 2t0) = A cos [kx + 2ft0]
5. A
1 2
Sol. A  B  C

dNB
 1NA  2NB  0
dt
N  N
 A  2  1 A 1
NB 1  2NB
6. A
Sol. impulse momentum theorem
v1At = pAt
 p = v1
Also p(2r) = .(2t)
 pr = t
 v1r = t
t
v1 
vr
7. B
Sol. |Q| = 0.00394  931.5 = 3.67 MeV
threshold Kinetic energy
 m  m2   mP 
=  1  | Q |  1   | Q | 3.91 MeV
 m 2   mN 
8. B
Sol. If mirror rotates by angle  image of object M2
rotates by angle 2.
S2
O
2  M1
S1
9. B
Sol. Optical path =  geometrical path
 3 
 
 1   1  3 2  1   = 9/2
1
 2  2 21 2
 
 2 
3 AITS-PT-III-PCM(Sol.)-JEE(Main)/20
10. A
h
Sol. 
2mK
150
   = 1.414 Å
75
For the first maxima
2dsin  
 1.414
 sin  =   0.023
2d 2  30
11. B  
Sol. The direction of ( E  B ) gives the direction of propagation of wave
ˆi  ˆj  kˆ
12. A
2 xT
Sol.  2 T
x
13. C
Sol. TIR will take place
60
14. C
3 1 (0.5)
Sol.  
2v1  20
2 3 0.5
 
f 2v1 30
2 1 1 1 
  
f 2  20 30 
4  20  30
f  48 cm
50
15. B
Sol. Total angular dispersion = ( v  r )A  (v  r )A  = 0
16. C
Sol. In equilibrium
a3g = a2x0g
a
x0 

The work done by the applied force,
a x0

 W  Fdx   a2 xgdx
0
2
a 2 g 2 a2 g   a  
 a  x0   a   
2 2    
 2 
= a4g     
2 2 

17. A
GMm
Sol. Using conservation of energy, K  0
r
GMm 1
K  K  (GMm)
r r
3
GMm  1018
2
3
m=  1018 Kg
2MG
18. B
T T
Sol. t (2  2)  (   )
2 
 vT   4 
  tan1    tan1  
 2x   2  2 
 = /4
3
t  4  3 sec
4
19. C
2T
Sol. P 
r
2T
 P  P0  gH 
r
20. D
Sol. Bernoulli’s theorem
SECTION – B
21. 1
m 
Sol. ma     x  gsin 
 
 gsin  
a   x
  
d2 x  gsin  
   x
dt2
  
 125
T  2  2  2  5  10 sec
gsin  1
10 
2
T 10
Time spent on the inclined track is t 0    5 sec
2 2
22. 4
2 3
Sol. L = [M1L T2] [LT1] [M]
 +  = 0
2  = 0
3 +  = 2
  = 2,  = 4,  = 2
SECTION – C
23. 00062.50
Sol. sin  =  sin 
cos  = /2= 5/8 (since /2 = ) 
F1
5
 100cos   100   62.50  =1
8 
24. 00015.00
mg mg
Sol. p  
A 4A
3mg
 a  
4A
3mg 3  1 10 2
a   15 m/s
4A 4  2.5  10  2  10  1
 4 3
25. 00000.02
V P 99  105
Sol.    0.02
V B 4.95  108
Chemistry PART – II
SECTION – A
26. B
Sol. Balanced reaction is
7
2CrO5  3H2 SO4  Cr2  SO4 3  3H2 O  O2
2
7
So, 1 mole CrO5 liberates moles of O2.
4
It is a redox reaction because oxidation number of Cr decreases and oxidation number of O
increases.
1 O 2 1
O O
Cr
6
O O
1 1
27. A
Sol. Initial weight of H2 O     18 g
PV
nH2O  g 
RT
 24.63 
   7.6
760 
  0.01 mole
0.0821 300
0.01  18
% wt. of H2O vapourised   100
18
= 1%
28. C
  1000
Sol. m 
M
1 1
or  m    1000 [  = specific conductance,  = specific resistance]
 M
1000
or m 
xy
29. A
Sol. NaCl is non-volatile but CH3OH is volatile. So, these solutions would have different boiling points.
Raoult’s law can not be applied to CH3OH solution since it does not form an ideal solution with
H2O.
30. D
Sol. Electrophoresis means movement of colloidal particles (particles of dispersed phase) under the
influence of electric field.
31. D
Sol. (A) Stronger the inter-atomic interaction, higher the enthalpy of atomization.
(B) Cr+ has half-filled valence shell electronic configuration (3d5), so it has higher second
+
ionization energy. Similarly, Cu has completely filled valence shell electronic
10
configuration 3d , so it has higher second ionization energy.
(C) Sum of first two ionization energies (IE1 + IE2) of Ni(II) is less than that of Pt(II), while sum
of first four ionization energies (IE1 + IE2 + IE3 + IE4) of Pt (IV) is less than that of Ni(IV).
(D) Occurs in the middle, e.g. Mn has +7 oxidation state.
32. D
Sol. White precipitates of Hg2Cl2 and AgCl are water insoluble (even in hot water). Copper salts do not
give white precipitate with dilute HCl as CuCl2 is water soluble (at room temperature)
Pb2  2Cl 
 PbCl2
 white precipitate 
 
 soluble in hot water 
Pb2  S2  PbS
Black 
33. D

Sol. NH4NO3   N2O  2H2O
34. B
1 n
Sol. t1/2   A 0
1 n
100   0.1
1n
50   0.025 
On dividing
2  41n
1n
2  22 
21  22  2n
 2  2n  1
or 2n = 1
1
or n 
2
1/ 2
100   0.1
1/2
t1/2  1
Divide
1
t1/2  1  2
 
100  0.1 
 t1/2  100 10 minutes.
35. B
Sol. Siderite is an ore of iron (FeCO3).
36. C
Sol. Colour is attributed to the presence of unpaired f-electrons.
Ce 3  4f 1, Sm 3  4f 5
La3  4f 0 , Lu3  4f 14
37. A
PV PV PM
Sol. Z  
nRT w dRT
 RT
M
8.314  10 4  18  10 3 18  10
Z 
0.8  8.314  300 300  0.8
3
Z   0.75
4
38. C
3RT
Sol. U
M
Let new rms speed be U2.
3R  2T 3RT
U2   2
M M
2
 U2  2U
39. B
Sol. CP,m = aT3
CP ,m 0.84
a   0.84  10 3
T3  
10
3
10K
CP,m
Sm   .dT
0K T
10K 10K
aT3 2
Sm   .dT   aT .dT
0K T 0K
a a
Sm  103  0    103
3 3
0.84  10  103
3
Sm   0.28
3
40. B
Sol. Cl OH HO Cl
Cl Cl
Bithionol
26 13
There are 26  bonds and 6 bonds. So, ratio is 
6 3
41. C

Sol. In order to get H3O   1M, H2SO 4 concentration should be = 0.5 M.
W  in g 
M 
H2SO4  Molar mass  V in L
W in g
0.5 
98  0.2
Wt. of H2SO4 = 9.8 g
42. A
Sol. Cu+2 is member of II group cations while Ni+2, Co+2 and Mn+2 are members of IV group cations.
When H2S is passed in presence of dilute HCl, only II group cation (Cu+2) is precipitated.
43. A
Sol. Following reactions are responsible for the depletion of ozone layer
NO  O3 
 NO 2  O 2

h
CFCl3  CF2Cl  Cl
Cl  O3 
 ClO   O2

ClO  O  Cl O2
CH4 is not responsible for ozone layer depletion.
44. A
Sol. H   10 2
m moles of H  10 2  100  1
During electrolysis, following reactions take place.
At cathode
Cu2  aq.  2e  
 Cu  s 
At anode
1
H2O     O 2  g   2H  aq.  2e 
2
+ +2
From above reactions, it is clear that for 1 m mole of H produced at anode, 0.5 m mole of Cu is
reduced at cathode.
Initial m mole of Cu+2 = 100 mL × 0.05
= 5 m mole
After electrolysis
Cu+2 remaining in solution = 5 – 0.5 = 4.5 m moles
2Cu 2  4I 
 Cu2I2  I2
So, according to above reaction
4.5
4.5 m mole Cu+2 will liberate m moles of I2.
2
I2  2Na2S 2O3  Na2S 4O 6  2NaI
4.5
According to above reaction m moles of I2 requires 4.5 m moles of Na2S2O3.
2
m moles
M
V in mL
4.5 450
V  in mL   
0.04 4
V = 112.5 mL
45. C
Sol. Excess of KI is added, I ions are adsorbed on AgI forming a fixed layer and give – ve charge on
colloid particles. It then attracts K+ ions from the medium forming second diffused (mobile) layer.
SECTION – B
46. 8
Sol. Total 8 f-Block elements in 4f-series have odd electrons in f-orbitals in their ground state
configuration.
58 Ce, 59 Pr, 61Pm, 63 Eu, 64 Gd, 65 Tb, 67 Ho, 69 Tm
47. 6
Sol. Sucrolose is 600 times sweet in comparison to cane sugar and Aspartame is 100 times sweet in
comparison to cane sugar.
x 600
So, 
y 100
=6
SECTION – C
48. 00036.85
Ea
Sol. log10 K  log10 A 
2.303RT
Ea
Slope  
2.303R
Ea
8000  
2.303  2
Ea  8000  2  2.303  36 848 calorie
Ea  36.85 Kcal
49. 00018.60
Sol. 2Na2S 2O3  I2  Na2S 4O 6  2NaI
n-factor of I2 = 2
M 15
Therefore, number of m moles of I2 = 15  
40 40
15 15
Number of m moles of Na2S 2O3  2  in 10 mL solution.
40 20
15
Weight of Na2S 2O 3 .5H2O in g in 10 mL solution   10 3  248  0.186 g
20
Therefore, concentration of Na2S2O3.5H2O = 18.6 (in g/L)
50. 00001.09
Sol. Go  nFEocell
2746  1000
Eocell   1.09 V
26  96500
Mathematics PART – III
SECTION – A
51. A
 
 a b 1
Sol. Vector  v     =  5iˆ  3ˆj  kˆ 
ab 35
52. D
 
Sol.  a  b   b  c    c  a  =  a b c   b c a   0
53. C
2
Sol. Required projection is  1  1  3  4  2   6  2  3   8
7 7 7 7
54. C
Sol. D.R. of normal  (2, 1, 1). Let, Q be the image of point P in the plane and PQ meet in R
R  (2r + 3, r + 5, r + 7),  2(2r + 3) + r + 5 + r + 7 = 0,  r = –3
 Using section formula Q  (–9, –1, 1)
55. D
Sol. The number of terms is same as (1 + x + x 2)n which is 2n + 1
56. B
2n  2
1 1 Cr 1 2n  1 1
Sol. 2n 1
 2n 1
 2n 1 2n 1
  2n
Cr Cr 1 Cr  Cr 1 2n  1 Cr
57. C
Sol.  = (1 – ) =  – ( – c)
Also, (1 + 3) =  – 2 + 3, (1 + 3) =  – 2 + 3
 (1 + 3) = (1 + 3) = (1 + 3),  3 = –1,   = –1, –, –2
58. B
Sol. Roots are 3 – i and –2 + i,  product is –6
59. D
3 1
Sol. p , q ,n=5
4 4
3 2 4 5
3  1 3  1 3 459
Probability = 5 C3      5 C4      5 C5   
4 4 4 4 4 512
60. A
1 1 1
Sol. P(E  F) = P(E)P(F) = , P  E  F   , 1  P E   1  P F   
12 2 2
61. D
Sol. C1  C1 – C2, C2  C2 – C3, open by R1, ab + abc + ac + bc = 0
1 1 1
    1
a b c
62. B
 
Sol. Adj  In   n n1
63. B
Sol. Order of B  4  3, order of BA  (4  3)  (3  4)  4  4
64. C
Sol. (x + ) = 1 and x + 1999 = –1   = 1993
x +  = –1 and x + 1991 = 1,  = 1989
Sum = 1993 + 1989
65. D
Sol. Let term be a – 2d, a – d, a, a + d, a + 2d
 3a = –12  a = –4, (a – 2a)(a – d)(a) = 8
 d = –3
 a2 + a4 + a6 = –21
66. C
4
Sol. Required value is 2  4   192
3
67. D
6
Sol. Number of ways is 8 C2   3 
68. A
10 6 10
Sol. Let numbers be a1, a2, ....., a10.  ai  125 ,  ai  90 ,  ai  50
i 1 i 1 i6
 a6 + 125 = 90 + 50  a6 = 15
69. C
2n
1  2  3  .....  2n  1 1 2 n  n  1
Sol. x  n  1 , 2     1  r   1  n   
2n  1 2n  1 r 0 3
n  n  1
 2 
3
70. C
n
Sol. Cr : n Cr 1 : nCr  2  1 : 7 : 35
r 1 1 r 2 1
   8r = n – 7 and 
nr 7 n  1  r  5
 n = 23
SECTION – B
71. 7
22 32  22  210 310  210  1 10
Sol. A2    , A 10    a+b+c+d=2 3
 0 32   0 310 
 Number of factors = 2  11 = 22
72. 5
1
Sol. Let r1 and r2 be the roots r  2   r2 – 2r – 1 = 0  b2 + c2 = 5
r
SECTION – C
73. 16216.20
12
C4  15C4  4
Sol.  16216.20
103
74. 00002.50
Sol. |(x – 4) + i(y – 3)| = 2 ; centre  (4, 3), radius = 2
  = 7 and  = 3
75. 00000.50
1 4 1 6 37
Sol. p    
2 7 2 8 56

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

(D) Occurs in the middle, e.g. Mn has +7 oxidation state.

Mathematics PART – III

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