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» Particles with min porosity are classified as clear particles. These particles are seen like glass spheres under microscope and they do not easily melt. These types of particles can create fish
eyes. » Particles which are porous inside but covered with a less permeable outer layer. » Porous particles without any outer layer.
Each PVC particle has its own advantages and draw backs. The target in PVC production is to produce homogeneous shaped porous particles. But for some rigid applications particles with less
permeable shell is preferred.
When PVC is degraded initially its color changes from yellow to dark brown –black. During this the PVC chains cross links and the viscosity of melted mass increases enormously. The processing
temperature is normally selected according to K value of PVC. K value+100 C could be selected as a starting point for processing and temperature is fine tuned according to machine and PVC
properties. The degradation of PVC releases HCl therefore it can be corrosive for the processing equipments.
Color of PVC
The initial color of PVC is also affected with impurities in levels of ppm. The chemicals used during production which are attached to the end of PVC chains of mixed in PVC forms the initial color
of PVC. Optical brighteners could be added to improve initial whiteness. During service sun light degrades PVC and yellowness occurs. To inhibit light degradation additives are added to PVC
which absorbs the light energy.
Fatty acid derived peroxides are preferred for PVC because the decomposition products of these peroxides link to the PVC chains and acts as lubricants. Nowadays high molecular weight PVC is
desired and initiators giving free radicals at lower temperatures are developed. In these processes polymerization is carried out at 30-40C and several initiators are used together to increase
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reactor efficiency.
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